#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:53:59 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179869 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/65/7016501.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7016501
loop_
_publ_author_name
'Xue, Shufang'
'Zhao, Lang'
'Guo, Yun-Nan'
'Deng, Ruiping'
'Guo, Yang'
'Tang, Jinkui'
_publ_section_title
;
 A series of tetranuclear lanthanide complexes comprising two
 edge-sharing triangular units with field-induced slow magnetic
 relaxation for Dy(4) species.
;
_journal_issue                   33
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8347
_journal_page_last               8352
_journal_paper_doi               10.1039/c1dt10654f
_journal_volume                  40
_journal_year                    2011
_chemical_formula_sum            'C54 H66 Gd4 N14 O26'
_chemical_formula_weight         1956.21
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 118.5560(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   25.3556(15)
_cell_length_b                   12.8097(7)
_cell_length_c                   24.642(2)
_cell_measurement_temperature    191(2)
_cell_volume                     7030.0(8)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      191(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0799
_diffrn_reflns_av_sigmaI/netI    0.0999
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -31
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            19141
_diffrn_reflns_theta_full        26.06
_diffrn_reflns_theta_max         26.06
_diffrn_reflns_theta_min         1.83
_exptl_absorpt_coefficient_mu    3.811
_exptl_absorpt_correction_T_max  0.5635
_exptl_absorpt_correction_T_min  0.4877
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_density_diffrn    1.848
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3808
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.17
_refine_diff_density_max         1.755
_refine_diff_density_min         -1.081
_refine_diff_density_rms         0.203
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.003
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     449
_refine_ls_number_reflns         6960
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.003
_refine_ls_R_factor_all          0.0909
_refine_ls_R_factor_gt           0.0469
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0412P)²+0.4579P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0939
_refine_ls_wR_factor_ref         0.1120
_reflns_number_gt                4549
_reflns_number_total             6960
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c1dt10654f.txt
_cod_data_source_block           1
_cod_original_cell_volume        7029.9(8)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7016501
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Gd1 Gd 0.413647(18) 0.69485(3) 0.716213(19) 0.02028(12) Uani 1 1 d .
Gd2 Gd 0.471623(18) 0.75485(3) 0.603314(19) 0.02057(12) Uani 1 1 d .
N1 N 0.3016(3) 0.6223(6) 0.6365(3) 0.0264(18) Uani 1 1 d .
N2 N 0.3209(3) 0.6722(6) 0.5055(3) 0.0268(18) Uani 1 1 d .
N3 N 0.3691(3) 0.7192(5) 0.5017(3) 0.0255(18) Uani 1 1 d .
N4 N 0.4581(3) 0.8076(5) 0.4927(3) 0.0225(16) Uani 1 1 d .
N5 N 0.5524(3) 0.8741(5) 0.5954(3) 0.0215(16) Uani 1 1 d .
N6 N 0.6018(3) 0.9140(6) 0.6474(3) 0.0309(19) Uani 1 1 d .
N7 N 0.6627(3) 0.8462(5) 0.8049(3) 0.0247(17) Uani 1 1 d .
O1 O 0.3814(2) 0.7010(5) 0.6087(2) 0.0243(14) Uani 1 1 d .
O2 O 0.5650(2) 0.8093(5) 0.6976(3) 0.0250(14) Uani 1 1 d .
O3 O 0.4961(2) 0.6541(4) 0.6922(2) 0.0209(13) Uani 1 1 d .
H3A H 0.4954 0.5782 0.6824 0.025 Uiso 1 1 calc .
O4 O 0.3778(3) 0.4209(5) 0.7482(3) 0.050(2) Uani 1 1 d .
O5 O 0.4210(3) 0.5130(5) 0.7034(3) 0.0332(16) Uani 1 1 d .
O6 O 0.4326(3) 0.9285(5) 0.5967(3) 0.0317(15) Uani 1 1 d .
O7 O 0.4478(2) 0.8514(5) 0.6825(3) 0.0275(14) Uani 1 1 d .
O8 O 0.4614(3) 0.5719(5) 0.5643(3) 0.0383(17) Uani 1 1 d .
O9 O 0.5503(3) 0.6447(5) 0.6008(3) 0.0346(16) Uani 1 1 d .
O11 O 0.3067(3) 0.7436(6) 0.2400(4) 0.059(2) Uani 1 1 d .
H11 H 0.3302 0.6969 0.2405 0.089 Uiso 1 1 calc R
O10 O 0.3698(2) 0.6173(5) 0.7755(3) 0.0283(15) Uani 1 1 d .
O12 O 0.6346(8) 0.5926(17) 0.4968(10) 0.257(12) Uani 1 1 d .
H12 H 0.6046 0.5968 0.4614 0.385 Uiso 1 1 calc R
O13 O 0.2899(3) 0.1794(5) 0.5463(3) 0.051(2) Uani 1 1 d .
C1 C 0.2615(3) 0.5808(7) 0.6518(4) 0.025(2) Uani 1 1 d .
H1 H 0.2702 0.5835 0.6938 0.030 Uiso 1 1 calc R
C2 C 0.2087(4) 0.5347(8) 0.6095(5) 0.041(3) Uani 1 1 d .
H2 H 0.1819 0.5050 0.6220 0.050 Uiso 1 1 calc R
C3 C 0.1960(4) 0.5327(8) 0.5488(5) 0.041(3) Uani 1 1 d .
H3 H 0.1595 0.5027 0.5184 0.049 Uiso 1 1 calc R
C4 C 0.2362(4) 0.5743(7) 0.5320(4) 0.032(2) Uani 1 1 d .
H4 H 0.2282 0.5725 0.4902 0.039 Uiso 1 1 calc R
C5 C 0.2877(3) 0.6181(7) 0.5768(4) 0.021(2) Uani 1 1 d .
C6 C 0.3340(4) 0.6678(6) 0.5631(4) 0.022(2) Uani 1 1 d .
C7 C 0.3620(4) 0.7283(7) 0.4468(4) 0.031(2) Uani 1 1 d .
H7 H 0.3268 0.7027 0.4121 0.037 Uiso 1 1 calc R
C8 C 0.4095(4) 0.7789(7) 0.4393(4) 0.027(2) Uani 1 1 d .
C9 C 0.4045(4) 0.7958(7) 0.3817(4) 0.029(2) Uani 1 1 d .
H9 H 0.3696 0.7734 0.3457 0.034 Uiso 1 1 calc R
C10 C 0.4496(4) 0.8445(7) 0.3765(4) 0.030(2) Uani 1 1 d .
H10 H 0.4470 0.8560 0.3372 0.036 Uiso 1 1 calc R
C11 C 0.4998(4) 0.8771(7) 0.4308(4) 0.032(2) Uani 1 1 d .
H11A H 0.5319 0.9126 0.4292 0.038 Uiso 1 1 calc R
C12 C 0.5019(4) 0.8566(7) 0.4866(4) 0.027(2) Uani 1 1 d .
C13 C 0.5514(4) 0.8930(7) 0.5442(4) 0.032(2) Uani 1 1 d .
H13 H 0.5833 0.9311 0.5437 0.038 Uiso 1 1 calc R
C14 C 0.6030(4) 0.8759(7) 0.6965(4) 0.025(2) Uani 1 1 d .
C15 C 0.6532(3) 0.9098(7) 0.7572(4) 0.0214(19) Uani 1 1 d .
C16 C 0.6853(4) 1.0003(7) 0.7645(4) 0.034(2) Uani 1 1 d .
H16 H 0.6767 1.0435 0.7299 0.041 Uiso 1 1 calc R
C17 C 0.7295(4) 1.0272(8) 0.8220(5) 0.039(3) Uani 1 1 d .
H17 H 0.7520 1.0895 0.8279 0.047 Uiso 1 1 calc R
C18 C 0.7413(4) 0.9627(7) 0.8715(4) 0.033(2) Uani 1 1 d .
H18 H 0.7724 0.9791 0.9118 0.040 Uiso 1 1 calc R
C19 C 0.7066(4) 0.8733(7) 0.8611(4) 0.029(2) Uani 1 1 d .
H19 H 0.7144 0.8295 0.8952 0.035 Uiso 1 1 calc R
C20 C 0.4024(4) 0.4295(8) 0.7149(5) 0.041(3) Uani 1 1 d .
C21 C 0.4116(7) 0.3321(9) 0.6838(7) 0.097(5) Uani 1 1 d .
H21A H 0.4334 0.2789 0.7152 0.145 Uiso 1 1 calc R
H21B H 0.4348 0.3510 0.6629 0.145 Uiso 1 1 calc R
H21C H 0.3724 0.3043 0.6535 0.145 Uiso 1 1 calc R
C22 C 0.4351(4) 0.9322(7) 0.6482(4) 0.025(2) Uani 1 1 d .
C23 C 0.4226(5) 1.0341(7) 0.6710(5) 0.045(3) Uani 1 1 d .
H23A H 0.4320 1.0926 0.6514 0.068 Uiso 1 1 calc R
H23B H 0.4477 1.0386 0.7160 0.068 Uiso 1 1 calc R
H23C H 0.3802 1.0371 0.6606 0.068 Uiso 1 1 calc R
C24 C 0.5159(5) 0.5644(8) 0.5815(4) 0.033(2) Uani 1 1 d .
C25 C 0.5431(5) 0.4595(8) 0.5835(5) 0.061(4) Uani 1 1 d .
H25A H 0.5112 0.4093 0.5595 0.092 Uiso 1 1 calc R
H25B H 0.5655 0.4357 0.6265 0.092 Uiso 1 1 calc R
H25C H 0.5704 0.4650 0.5659 0.092 Uiso 1 1 calc R
C26 C 0.2512(6) 0.7035(10) 0.2182(9) 0.106(6) Uani 1 1 d .
H26A H 0.2518 0.6483 0.2461 0.159 Uiso 1 1 calc R
H26B H 0.2380 0.6743 0.1770 0.159 Uiso 1 1 calc R
H26C H 0.2234 0.7587 0.2158 0.159 Uiso 1 1 calc R
C27 C 0.6325(11) 0.6736(15) 0.5340(18) 0.25(2) Uani 1 1 d .
H27A H 0.6321 0.6439 0.5704 0.371 Uiso 1 1 calc R
H27B H 0.5961 0.7151 0.5104 0.371 Uiso 1 1 calc R
H27C H 0.6679 0.7183 0.5471 0.371 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Gd Gd -0.1653 3.9035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Gd1 O1 83.7(2) . .
O5 Gd1 O3 79.0(2) . 2_656
O1 Gd1 O3 136.73(18) . 2_656
O5 Gd1 O2 135.5(2) . 2_656
O1 Gd1 O2 140.7(2) . 2_656
O3 Gd1 O2 65.82(18) 2_656 2_656
O5 Gd1 O10 76.5(2) . .
O1 Gd1 O10 132.27(18) . .
O3 Gd1 O10 81.34(18) 2_656 .
O2 Gd1 O10 72.21(19) 2_656 .
O5 Gd1 O7 133.5(2) . .
O1 Gd1 O7 65.66(19) . .
O3 Gd1 O7 99.42(18) 2_656 .
O2 Gd1 O7 80.61(19) 2_656 .
O10 Gd1 O7 149.9(2) . .
O5 Gd1 O3 68.48(19) . .
O1 Gd1 O3 67.71(18) . .
O3 Gd1 O3 69.1(2) 2_656 .
O2 Gd1 O3 118.40(18) 2_656 .
O10 Gd1 O3 137.37(19) . .
O7 Gd1 O3 67.79(18) . .
O5 Gd1 N7 143.3(2) . 2_656
O1 Gd1 N7 85.8(2) . 2_656
O3 Gd1 N7 129.6(2) 2_656 2_656
O2 Gd1 N7 63.8(2) 2_656 2_656
O10 Gd1 N7 85.1(2) . 2_656
O7 Gd1 N7 71.2(2) . 2_656
O3 Gd1 N7 137.5(2) . 2_656
O5 Gd1 N1 72.0(2) . .
O1 Gd1 N1 61.54(19) . .
O3 Gd1 N1 143.7(2) 2_656 .
O2 Gd1 N1 123.8(2) 2_656 .
O10 Gd1 N1 71.1(2) . .
O7 Gd1 N1 116.4(2) . .
O3 Gd1 N1 117.5(2) . .
N7 Gd1 N1 72.1(2) 2_656 .
O5 Gd1 Gd1 84.99(14) . 2_656
O1 Gd1 Gd1 101.26(12) . 2_656
O3 Gd1 Gd1 38.26(12) 2_656 2_656
O2 Gd1 Gd1 83.69(12) 2_656 2_656
O10 Gd1 Gd1 119.35(13) . 2_656
O7 Gd1 Gd1 68.88(13) . 2_656
O3 Gd1 Gd1 36.36(12) . 2_656
N7 Gd1 Gd1 131.64(15) 2_656 2_656
N1 Gd1 Gd1 152.08(15) . 2_656
O5 Gd1 Gd2 105.77(16) . 2_656
O1 Gd1 Gd2 154.40(12) . 2_656
O3 Gd1 Gd2 30.87(13) 2_656 2_656
O2 Gd1 Gd2 34.99(13) 2_656 2_656
O10 Gd1 Gd2 73.33(13) . 2_656
O7 Gd1 Gd2 91.82(13) . 2_656
O3 Gd1 Gd2 93.25(12) . 2_656
N7 Gd1 Gd2 98.77(15) 2_656 2_656
N1 Gd1 Gd2 143.82(15) . 2_656
Gd1 Gd1 Gd2 57.143(12) 2_656 2_656
O3 Gd2 O6 119.1(2) . .
O3 Gd2 O1 68.51(18) . .
O6 Gd2 O1 84.3(2) . .
O3 Gd2 O9 81.56(19) . .
O6 Gd2 O9 146.8(2) . .
O1 Gd2 O9 128.8(2) . .
O3 Gd2 O2 64.94(18) . .
O6 Gd2 O2 89.0(2) . .
O1 Gd2 O2 121.50(18) . .
O9 Gd2 O2 76.4(2) . .
O3 Gd2 O8 77.1(2) . .
O6 Gd2 O8 151.2(2) . .
O1 Gd2 O8 80.2(2) . .
O9 Gd2 O8 52.4(2) . .
O2 Gd2 O8 119.8(2) . .
O3 Gd2 O7 67.50(18) . .
O6 Gd2 O7 51.6(2) . .
O1 Gd2 O7 62.51(17) . .
O9 Gd2 O7 140.12(19) . .
O2 Gd2 O7 68.16(17) . .
O8 Gd2 O7 135.5(2) . .
O3 Gd2 N5 121.18(19) . .
O6 Gd2 N5 76.6(2) . .
O1 Gd2 N5 160.8(2) . .
O9 Gd2 N5 70.3(2) . .
O2 Gd2 N5 58.81(19) . .
O8 Gd2 N5 117.1(2) . .
O7 Gd2 N5 104.23(19) . .
O3 Gd2 N3 119.2(2) . .
O6 Gd2 N3 84.8(2) . .
O1 Gd2 N3 58.89(19) . .
O9 Gd2 N3 108.5(2) . .
O2 Gd2 N3 173.7(2) . .
O8 Gd2 N3 66.4(2) . .
O7 Gd2 N3 108.35(19) . .
N5 Gd2 N3 118.4(2) . .
O3 Gd2 N4 159.6(2) . .
O6 Gd2 N4 81.3(2) . .
O1 Gd2 N4 117.34(19) . .
O9 Gd2 N4 80.2(2) . .
O2 Gd2 N4 118.79(19) . .
O8 Gd2 N4 84.5(2) . .
O7 Gd2 N4 132.9(2) . .
N5 Gd2 N4 60.1(2) . .
N3 Gd2 N4 59.3(2) . .
O3 Gd2 Gd1 31.22(13) . 2_656
O6 Gd2 Gd1 107.80(15) . 2_656
O1 Gd2 Gd1 94.93(13) . 2_656
O9 Gd2 Gd1 75.79(14) . 2_656
O2 Gd2 Gd1 33.76(13) . 2_656
O8 Gd2 Gd1 97.62(15) . 2_656
O7 Gd2 Gd1 64.65(13) . 2_656
N5 Gd2 Gd1 90.90(14) . 2_656
N3 Gd2 Gd1 150.36(15) . 2_656
N4 Gd2 Gd1 147.43(14) . 2_656
C5 N1 C1 116.9(7) . .
C5 N1 Gd1 116.1(5) . .
C1 N1 Gd1 126.6(6) . .
C6 N2 N3 108.5(6) . .
C7 N3 N2 114.9(7) . .
C7 N3 Gd2 124.2(6) . .
N2 N3 Gd2 120.2(5) . .
C12 N4 C8 115.9(8) . .
C12 N4 Gd2 121.5(5) . .
C8 N4 Gd2 122.4(5) . .
C13 N5 N6 115.1(7) . .
C13 N5 Gd2 122.4(6) . .
N6 N5 Gd2 122.3(5) . .
C14 N6 N5 109.3(7) . .
C19 N7 C15 117.1(7) . .
C19 N7 Gd1 124.6(6) . 2_656
C15 N7 Gd1 117.8(5) . 2_656
C6 O1 Gd1 130.9(5) . .
C6 O1 Gd2 124.3(5) . .
Gd1 O1 Gd2 103.75(19) . .
C14 O2 Gd1 124.1(5) . 2_656
C14 O2 Gd2 123.2(5) . .
Gd1 O2 Gd2 111.3(2) 2_656 .
Gd2 O3 Gd1 117.9(2) . 2_656
Gd2 O3 Gd1 103.20(19) . .
Gd1 O3 Gd1 105.4(2) 2_656 .
C20 O5 Gd1 138.2(7) . .
C22 O6 Gd2 98.4(5) . .
C22 O7 Gd1 149.3(5) . .
C22 O7 Gd2 87.9(5) . .
Gd1 O7 Gd2 96.3(2) . .
C24 O8 Gd2 92.7(6) . .
C24 O9 Gd2 93.0(6) . .
N1 C1 C2 123.1(9) . .
C3 C2 C1 118.2(9) . .
C2 C3 C4 119.8(9) . .
C5 C4 C3 118.4(9) . .
N1 C5 C4 123.5(8) . .
N1 C5 C6 113.8(7) . .
C4 C5 C6 122.6(8) . .
O1 C6 N2 126.4(7) . .
O1 C6 C5 117.1(7) . .
N2 C6 C5 116.4(7) . .
N3 C7 C8 117.8(8) . .
N4 C8 C9 123.2(8) . .
N4 C8 C7 115.1(8) . .
C9 C8 C7 121.7(8) . .
C10 C9 C8 120.0(8) . .
C9 C10 C11 117.9(8) . .
C12 C11 C10 118.8(8) . .
N4 C12 C11 124.1(8) . .
N4 C12 C13 114.6(8) . .
C11 C12 C13 121.2(8) . .
N5 C13 C12 120.4(8) . .
N6 C14 O2 125.7(8) . .
N6 C14 C15 117.1(8) . .
O2 C14 C15 117.2(8) . .
N7 C15 C16 122.9(8) . .
N7 C15 C14 114.1(7) . .
C16 C15 C14 122.9(8) . .
C17 C16 C15 119.3(9) . .
C16 C17 C18 119.2(9) . .
C17 C18 C19 118.6(9) . .
N7 C19 C18 122.9(9) . .
O4 C20 O5 125.7(10) . .
O4 C20 C21 119.8(10) . .
O5 C20 C21 114.5(10) . .
O6 C22 O7 121.4(8) . .
O6 C22 C23 119.7(9) . .
O7 C22 C23 118.9(9) . .
O8 C24 O9 120.9(9) . .
O8 C24 C25 120.1(10) . .
O9 C24 C25 119.0(10) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Gd1 O5 2.370(6) .
Gd1 O1 2.371(5) .
Gd1 O3 2.380(5) 2_656
Gd1 O2 2.419(6) 2_656
Gd1 O10 2.432(6) .
Gd1 O7 2.480(6) .
Gd1 O3 2.485(5) .
Gd1 N7 2.611(7) 2_656
Gd1 N1 2.730(7) .
Gd1 Gd1 3.8701(8) 2_656
Gd1 Gd2 4.0574(7) 2_656
Gd2 O3 2.356(5) .
Gd2 O6 2.409(6) .
Gd2 O1 2.452(5) .
Gd2 O9 2.469(6) .
Gd2 O2 2.496(5) .
Gd2 O8 2.499(6) .
Gd2 O7 2.613(6) .
Gd2 N5 2.635(7) .
Gd2 N3 2.649(7) .
Gd2 N4 2.668(7) .
Gd2 Gd1 4.0574(7) 2_656
N1 C5 1.341(10) .
N1 C1 1.351(10) .
N2 C6 1.297(11) .
N2 N3 1.404(9) .
N3 C7 1.281(11) .
N4 C12 1.343(10) .
N4 C8 1.354(10) .
N5 C13 1.273(10) .
N5 N6 1.393(9) .
N6 C14 1.291(10) .
N7 C19 1.343(10) .
N7 C15 1.354(10) .
N7 Gd1 2.611(7) 2_656
O1 C6 1.264(9) .
O2 C14 1.298(10) .
O2 Gd1 2.419(6) 2_656
O3 Gd1 2.380(5) 2_656
O4 C20 1.249(12) .
O5 C20 1.256(12) .
O6 C22 1.241(10) .
O7 C22 1.276(10) .
O8 C24 1.239(11) .
O9 C24 1.285(11) .
O11 C26 1.345(13) .
O12 C27 1.40(3) .
C1 C2 1.376(12) .
C2 C3 1.371(14) .
C3 C4 1.378(13) .
C4 C5 1.365(11) .
C5 C6 1.507(11) .
C7 C8 1.456(12) .
C8 C9 1.382(12) .
C9 C10 1.361(11) .
C10 C11 1.399(12) .
C11 C12 1.377(12) .
C12 C13 1.450(12) .
C14 C15 1.491(11) .
C15 C16 1.377(12) .
C16 C17 1.366(12) .
C17 C18 1.383(13) .
C18 C19 1.390(12) .
C20 C21 1.539(15) .
C22 C23 1.514(12) .
C24 C25 1.501(13) .
