#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:53:59 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179869 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/65/7016579.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7016579
loop_
_publ_author_name
'Niu, Jingyang'
'Yang, Linping'
'Zhao, Junwei'
'Ma, Pengtao'
'Wang, Jingping'
_publ_section_title
;
 Novel octatungstate-supported tricarbonyl metal derivatives:
 {[H(2)W(8)O(30)][M(CO)(3)](2)}(8-) (M = Mn(I) and Re(I)).
;
_journal_issue                   33
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8298
_journal_page_last               8300
_journal_paper_doi               10.1039/c1dt11042j
_journal_volume                  40
_journal_year                    2011
_chemical_formula_sum            'C6 H50 Mn3 Na6 O60 W8'
_chemical_formula_weight         2856.00
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   notdet
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                98.291(5)
_cell_angle_beta                 103.668(5)
_cell_angle_gamma                105.798(5)
_cell_formula_units_Z            1
_cell_length_a                   11.118(4)
_cell_length_b                   11.519(4)
_cell_length_c                   12.269(4)
_cell_measurement_reflns_used    4461
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.43
_cell_measurement_theta_min      2.27
_cell_volume                     1432.1(9)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0210
_diffrn_reflns_av_sigmaI/netI    0.0394
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            7288
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.88
_exptl_absorpt_coefficient_mu    16.802
_exptl_absorpt_correction_T_max  0.2020
_exptl_absorpt_correction_T_min  0.1131
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    3.309
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rod
_exptl_crystal_F_000             1297
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.14
_refine_diff_density_max         3.339
_refine_diff_density_min         -1.936
_refine_diff_density_rms         0.290
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.027
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     377
_refine_ls_number_reflns         4993
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.027
_refine_ls_R_factor_all          0.0385
_refine_ls_R_factor_gt           0.0342
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0571P)²+5.3625P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0882
_refine_ls_wR_factor_ref         0.0909
_reflns_number_gt                4492
_reflns_number_total             4993
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c1dt11042j.txt
_cod_data_source_block           njy3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        1432.0(8)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7016579
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
W1 W 0.66029(3) 0.76603(3) 0.95254(3) 0.01451(11) Uani 1 1 d .
W2 W 0.67497(3) 0.97576(3) 0.78536(3) 0.01380(11) Uani 1 1 d .
W3 W 0.91765(3) 0.84197(3) 0.83928(3) 0.01199(11) Uani 1 1 d .
W4 W 0.98626(3) 0.81590(3) 1.15441(3) 0.01305(11) Uani 1 1 d .
Mn1 Mn 0.63707(14) 0.69729(13) 0.68787(12) 0.0190(3) Uani 1 1 d .
Mn2 Mn 0.5000 1.0000 1.0000 0.0214(5) Uani 1 2 d S
Na1 Na 1.0838(5) 0.8923(4) 1.5022(4) 0.0368(11) Uani 1 1 d .
Na2 Na 0.7717(5) 1.3104(4) 0.8660(5) 0.0426(12) Uani 1 1 d .
Na3 Na 0.9980(7) 1.5109(5) 0.7874(5) 0.0666(17) Uani 1 1 d .
O1 O 0.5564(7) 0.6174(6) 0.9349(6) 0.0265(16) Uani 1 1 d .
O2 O 0.5733(6) 0.9723(6) 0.6526(6) 0.0228(15) Uani 1 1 d .
O3 O 0.9734(6) 0.7517(6) 0.7513(6) 0.0196(14) Uani 1 1 d .
O4 O 0.9715(7) 0.8255(6) 1.2919(6) 0.0244(15) Uani 1 1 d .
O5 O 1.0150(6) 1.0008(6) 0.8436(5) 0.0158(13) Uani 1 1 d .
O6 O 0.9927(6) 0.6647(6) 1.1218(6) 0.0205(15) Uani 1 1 d .
O7 O 0.5882(7) 0.8594(7) 1.0248(6) 0.0263(16) Uani 1 1 d .
O8 O 0.6111(7) 1.0492(6) 0.8831(6) 0.0234(15) Uani 1 1 d .
O9 O 1.0002(6) 0.8325(6) 0.9825(5) 0.0134(13) Uani 1 1 d .
O10 O 1.1757(6) 0.8909(6) 1.1989(5) 0.0160(13) Uani 1 1 d .
O11 O 0.7996(6) 0.7718(6) 1.0761(5) 0.0161(13) Uani 1 1 d .
O12 O 0.5808(6) 0.8066(6) 0.8016(5) 0.0180(14) Uani 1 1 d .
O13 O 0.7732(6) 0.8650(6) 0.7196(5) 0.0147(13) Uani 1 1 d .
O14 O 0.7598(6) 0.7088(6) 0.8435(5) 0.0143(13) Uani 1 1 d .
O15 O 0.8035(6) 0.9335(6) 0.9349(5) 0.0156(13) Uani 1 1 d .
O16 O 0.4364(9) 0.4651(8) 0.6742(8) 0.058(3) Uani 1 1 d .
O17 O 0.4753(10) 0.7167(10) 0.4697(8) 0.059(3) Uani 1 1 d .
O18 O 0.7497(10) 0.5484(9) 0.5549(8) 0.052(2) Uani 1 1 d .
C1 C 0.7088(10) 0.6111(10) 0.6074(9) 0.027(2) Uani 1 1 d .
C2 C 0.5390(12) 0.7116(11) 0.5575(12) 0.040(3) Uani 1 1 d .
C3 C 0.5148(12) 0.5561(11) 0.6810(9) 0.035(3) Uani 1 1 d .
O1W O 0.3448(8) 0.8614(8) 0.8486(7) 0.041(2) Uani 1 1 d .
O2W O 1.1259(8) 1.1020(8) 1.4729(7) 0.0377(19) Uani 1 1 d .
O3W O 1.3008(9) 0.9027(9) 1.4927(8) 0.046(2) Uani 1 1 d .
O4W O 1.1950(7) 0.9728(7) 1.7114(7) 0.0347(18) Uani 1 1 d .
O5W O 1.0462(9) 0.6929(8) 1.5494(8) 0.049(2) Uani 1 1 d .
O6W O 0.5621(10) 1.3157(11) 0.8620(9) 0.065(3) Uani 1 1 d .
O7W O 0.8304(10) 1.3239(11) 1.0671(9) 0.065(3) Uani 1 1 d .
O8W O 0.8552(8) 1.5270(7) 0.8984(7) 0.039(2) Uani 1 1 d .
O9W O 0.7949(10) 1.3351(9) 0.6753(8) 0.056(3) Uani 1 1 d .
O10W O 1.1155(10) 1.4876(10) 0.6536(8) 0.063(3) Uani 1 1 d .
O11W O 1.3030(10) 1.2098(10) 1.6905(9) 0.066(3) Uani 1 1 d .
O12W O 0.2915(10) 0.4702(11) 0.8566(10) 0.069(3) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 W1 O7 103.0(4) . .
O1 W1 O11 101.0(3) . .
O7 W1 O11 99.5(3) . .
O1 W1 O12 100.4(3) . .
O7 W1 O12 90.1(3) . .
O11 W1 O12 153.9(3) . .
O1 W1 O14 93.4(3) . .
O7 W1 O14 160.3(3) . .
O11 W1 O14 87.8(3) . .
O12 W1 O14 76.1(2) . .
O1 W1 O15 165.1(3) . .
O7 W1 O15 90.4(3) . .
O11 W1 O15 82.9(3) . .
O12 W1 O15 72.7(2) . .
O14 W1 O15 72.3(2) . .
O1 W1 Mn1 87.3(2) . .
O7 W1 Mn1 129.9(2) . .
O11 W1 Mn1 126.9(2) . .
O12 W1 Mn1 39.86(18) . .
O14 W1 Mn1 39.13(16) . .
O15 W1 Mn1 79.05(16) . .
O2 W2 O8 102.8(3) . .
O2 W2 O10 102.5(3) . 2_777
O8 W2 O10 98.0(3) . 2_777
O2 W2 O12 97.9(3) . .
O8 W2 O12 92.6(3) . .
O10 W2 O12 154.2(3) 2_777 .
O2 W2 O13 95.5(3) . .
O8 W2 O13 159.9(3) . .
O10 W2 O13 85.6(3) 2_777 .
O12 W2 O13 76.8(3) . .
O2 W2 O15 165.8(3) . .
O8 W2 O15 88.3(3) . .
O10 W2 O15 84.2(2) 2_777 .
O12 W2 O15 72.5(2) . .
O13 W2 O15 72.3(2) . .
O2 W2 Mn1 86.7(2) . .
O8 W2 Mn1 132.9(2) . .
O10 W2 Mn1 125.18(19) 2_777 .
O12 W2 Mn1 40.34(19) . .
O13 W2 Mn1 39.54(17) . .
O15 W2 Mn1 79.29(16) . .
O2 W2 Na2 91.8(2) . .
O8 W2 Na2 59.3(2) . .
O10 W2 Na2 43.4(2) 2_777 .
O12 W2 Na2 151.7(2) . .
O13 W2 Na2 128.78(18) . .
O15 W2 Na2 101.57(18) . .
Mn1 W2 Na2 167.72(8) . .
O3 W3 O9 103.2(3) . .
O3 W3 O5 103.3(3) . .
O9 W3 O5 98.0(3) . .
O3 W3 O14 97.9(3) . .
O9 W3 O14 88.7(3) . .
O5 W3 O14 155.7(3) . .
O3 W3 O13 99.3(3) . .
O9 W3 O13 155.0(3) . .
O5 W3 O13 87.3(3) . .
O14 W3 O13 77.5(2) . .
O3 W3 O15 168.4(3) . .
O9 W3 O15 83.0(2) . .
O5 W3 O15 85.4(3) . .
O14 W3 O15 72.2(2) . .
O13 W3 O15 73.0(2) . .
O3 W3 Mn1 88.5(2) . .
O9 W3 Mn1 129.2(2) . .
O5 W3 Mn1 127.60(19) . .
O14 W3 Mn1 40.54(17) . .
O13 W3 Mn1 40.29(18) . .
O15 W3 Mn1 80.01(16) . .
O4 W4 O6 100.9(3) . .
O4 W4 O10 96.7(3) . .
O6 W4 O10 93.6(3) . .
O4 W4 O11 96.2(3) . .
O6 W4 O11 95.1(3) . .
O10 W4 O11 162.8(3) . .
O4 W4 O5 92.1(3) . 2_777
O6 W4 O5 167.0(3) . 2_777
O10 W4 O5 84.2(2) . 2_777
O11 W4 O5 84.1(2) . 2_777
O4 W4 O9 170.9(3) . .
O6 W4 O9 88.2(3) . .
O10 W4 O9 83.6(2) . .
O11 W4 O9 81.8(2) . .
O5 W4 O9 78.8(2) 2_777 .
O4 W4 Na2 108.7(2) . 2_777
O6 W4 Na2 45.2(2) . 2_777
O10 W4 Na2 48.9(2) . 2_777
O11 W4 Na2 135.5(2) . 2_777
O5 W4 Na2 129.44(19) 2_777 2_777
O9 W4 Na2 78.40(18) . 2_777
C1 Mn1 C2 89.0(5) . .
C1 Mn1 C3 89.0(5) . .
C2 Mn1 C3 89.7(5) . .
C1 Mn1 O13 98.0(4) . .
C2 Mn1 O13 95.5(4) . .
C3 Mn1 O13 171.4(4) . .
C1 Mn1 O14 95.4(4) . .
C2 Mn1 O14 171.5(4) . .
C3 Mn1 O14 97.7(4) . .
O13 Mn1 O14 76.7(3) . .
C1 Mn1 O12 171.0(4) . .
C2 Mn1 O12 98.8(4) . .
C3 Mn1 O12 95.4(4) . .
O13 Mn1 O12 77.0(3) . .
O14 Mn1 O12 76.3(2) . .
C1 Mn1 W3 86.2(4) . .
C2 Mn1 W3 133.4(4) . .
C3 Mn1 W3 136.4(4) . .
O13 Mn1 W3 39.98(18) . .
O14 Mn1 W3 40.01(18) . .
O12 Mn1 W3 85.26(19) . .
C1 Mn1 W2 138.0(4) . .
C2 Mn1 W2 87.2(4) . .
C3 Mn1 W2 132.7(4) . .
O13 Mn1 W2 41.04(17) . .
O14 Mn1 W2 84.63(18) . .
O12 Mn1 W2 39.05(17) . .
W3 Mn1 W2 67.13(3) . .
C1 Mn1 W1 133.8(3) . .
C2 Mn1 W1 137.0(4) . .
C3 Mn1 W1 86.8(4) . .
O13 Mn1 W1 84.72(18) . .
O14 Mn1 W1 40.08(17) . .
O12 Mn1 W1 39.15(17) . .
W3 Mn1 W1 66.60(3) . .
W2 Mn1 W1 65.02(3) . .
O7 Mn2 O7 180.000(4) 2_677 .
O7 Mn2 O8 91.7(3) 2_677 .
O7 Mn2 O8 88.3(3) . .
O7 Mn2 O8 88.3(3) 2_677 2_677
O7 Mn2 O8 91.7(3) . 2_677
O8 Mn2 O8 180.000(3) . 2_677
O7 Mn2 O1W 92.2(3) 2_677 .
O7 Mn2 O1W 87.8(3) . .
O8 Mn2 O1W 87.5(3) . .
O8 Mn2 O1W 92.5(3) 2_677 .
O7 Mn2 O1W 87.8(3) 2_677 2_677
O7 Mn2 O1W 92.2(3) . 2_677
O8 Mn2 O1W 92.5(3) . 2_677
O8 Mn2 O1W 87.5(3) 2_677 2_677
O1W Mn2 O1W 180.000(2) . 2_677
O5W Na1 O3W 92.2(3) . .
O5W Na1 O2W 174.8(4) . .
O3W Na1 O2W 88.8(3) . .
O5W Na1 O2W 90.0(3) . 2_778
O3W Na1 O2W 174.7(4) . 2_778
O2W Na1 O2W 88.6(3) . 2_778
O5W Na1 O4W 84.5(3) . .
O3W Na1 O4W 83.4(3) . .
O2W Na1 O4W 90.6(3) . .
O2W Na1 O4W 92.0(3) 2_778 .
O5W Na1 O4 99.1(3) . .
O3W Na1 O4 97.6(3) . .
O2W Na1 O4 85.8(3) . .
O2W Na1 O4 86.8(3) 2_778 .
O4W Na1 O4 176.2(3) . .
O5W Na1 Na1 134.0(3) . 2_778
O3W Na1 Na1 133.0(3) . 2_778
O2W Na1 Na1 44.4(2) . 2_778
O2W Na1 Na1 44.2(2) 2_778 2_778
O4W Na1 Na1 91.8(3) . 2_778
O4 Na1 Na1 84.9(2) . 2_778
O6W Na2 O8W 92.3(4) . .
O6W Na2 O7W 92.1(4) . .
O8W Na2 O7W 90.1(4) . .
O6W Na2 O9W 105.7(4) . .
O8W Na2 O9W 79.2(3) . .
O7W Na2 O9W 159.4(4) . .
O6W Na2 O6 172.4(4) . 2_777
O8W Na2 O6 80.2(3) . 2_777
O7W Na2 O6 87.1(3) . 2_777
O9W Na2 O6 73.9(3) . 2_777
O6W Na2 O10 123.8(4) . 2_777
O8W Na2 O10 142.1(3) . 2_777
O7W Na2 O10 98.7(4) . 2_777
O9W Na2 O10 80.1(3) . 2_777
O6 Na2 O10 63.7(2) 2_777 2_777
O6W Na2 Na3 127.1(3) . .
O8W Na2 Na3 44.5(3) . .
O7W Na2 Na3 112.3(3) . .
O9W Na2 Na3 48.4(3) . .
O6 Na2 Na3 47.0(2) 2_777 .
O10 Na2 Na3 98.9(2) 2_777 .
O6W Na2 W4 158.0(4) . 2_777
O8W Na2 W4 109.7(3) . 2_777
O7W Na2 W4 89.6(3) . 2_777
O9W Na2 W4 77.8(2) . 2_777
O6 Na2 W4 29.57(15) 2_777 2_777
O10 Na2 W4 34.42(15) 2_777 2_777
Na3 Na2 W4 71.73(15) . 2_777
O6W Na2 W2 94.7(3) . .
O8W Na2 W2 170.9(3) . .
O7W Na2 W2 95.6(3) . .
O9W Na2 W2 93.2(3) . .
O6 Na2 W2 92.90(19) 2_777 .
O10 Na2 W2 29.74(15) 2_777 .
Na3 Na2 W2 126.36(17) . .
W4 Na2 W2 63.33(8) 2_777 .
O8W Na3 O10W 172.0(5) . .
O8W Na3 O7W 88.8(4) . 2_787
O10W Na3 O7W 97.8(4) . 2_787
O8W Na3 O6 81.5(3) . 2_777
O10W Na3 O6 101.6(4) . 2_777
O7W Na3 O6 99.6(4) 2_787 2_777
O8W Na3 O9W 78.1(4) . .
O10W Na3 O9W 95.6(4) . .
O7W Na3 O9W 166.1(4) 2_787 .
O6 Na3 O9W 74.1(3) 2_777 .
O8W Na3 O3 82.1(3) . 1_565
O10W Na3 O3 95.9(4) . 1_565
O7W Na3 O3 70.4(3) 2_787 1_565
O6 Na3 O3 161.0(3) 2_777 1_565
O9W Na3 O3 111.7(4) . 1_565
O8W Na3 Na2 44.5(2) . .
O10W Na3 Na2 133.1(4) . .
O7W Na3 Na2 119.6(3) 2_787 .
O6 Na3 Na2 48.5(2) 2_777 .
O9W Na3 Na2 47.0(3) . .
O3 Na3 Na2 121.5(3) 1_565 .
W3 O3 Na3 122.9(3) . 1_545
W4 O4 Na1 147.1(4) . .
W3 O5 W4 145.5(3) . 2_777
W4 O6 Na3 140.4(4) . 2_777
W4 O6 Na2 105.2(3) . 2_777
Na3 O6 Na2 84.5(3) 2_777 2_777
W1 O7 Mn2 140.1(4) . .
W2 O8 Mn2 138.1(4) . .
W3 O9 W4 146.9(3) . .
W2 O10 W4 150.9(4) 2_777 .
W2 O10 Na2 106.8(3) 2_777 2_777
W4 O10 Na2 96.7(3) . 2_777
W1 O11 W4 152.0(4) . .
W2 O12 W1 113.7(3) . .
W2 O12 Mn1 100.6(3) . .
W1 O12 Mn1 101.0(3) . .
W3 O13 Mn1 99.7(3) . .
W3 O13 W2 114.1(3) . .
Mn1 O13 W2 99.4(3) . .
W3 O14 Mn1 99.5(3) . .
W3 O14 W1 114.3(3) . .
Mn1 O14 W1 100.8(3) . .
W1 O15 W2 98.6(2) . .
W1 O15 W3 99.5(2) . .
W2 O15 W3 99.0(2) . .
O18 C1 Mn1 175.7(10) . .
O17 C2 Mn1 177.3(11) . .
O16 C3 Mn1 178.5(10) . .
Na1 O2W Na1 91.4(3) . 2_778
Na2 O7W Na3 126.6(5) . 2_787
Na2 O8W Na3 90.9(3) . .
Na2 O9W Na3 84.6(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
W1 O1 1.735(7) .
W1 O7 1.765(7) .
W1 O11 1.873(6) .
W1 O12 2.033(6) .
W1 O14 2.072(6) .
W1 O15 2.217(6) .
W1 Mn1 3.1605(18) .
W2 O2 1.738(7) .
W2 O8 1.758(6) .
W2 O10 1.878(6) 2_777
W2 O12 2.008(6) .
W2 O13 2.085(6) .
W2 O15 2.245(6) .
W2 Mn1 3.1330(18) .
W2 Na2 3.624(5) .
W3 O3 1.724(6) .
W3 O9 1.814(6) .
W3 O5 1.841(6) .
W3 O14 2.009(6) .
W3 O13 2.009(6) .
W3 O15 2.275(6) .
W3 Mn1 3.0817(17) .
W4 O4 1.724(7) .
W4 O6 1.754(6) .
W4 O10 1.952(6) .
W4 O11 1.957(6) .
W4 O5 2.112(6) 2_777
W4 O9 2.183(6) .
W4 Na2 3.430(5) 2_777
Mn1 C1 1.765(11) .
Mn1 C2 1.768(14) .
Mn1 C3 1.790(13) .
Mn1 O13 2.022(6) .
Mn1 O14 2.030(6) .
Mn1 O12 2.063(7) .
Mn2 O7 2.131(7) 2_677
Mn2 O7 2.131(7) .
Mn2 O8 2.144(7) .
Mn2 O8 2.144(7) 2_677
Mn2 O1W 2.260(8) .
Mn2 O1W 2.260(8) 2_677
Na1 O5W 2.401(10) .
Na1 O3W 2.414(10) .
Na1 O2W 2.427(10) .
Na1 O2W 2.439(9) 2_778
Na1 O4W 2.482(9) .
Na1 O4 2.488(8) .
Na1 Na1 3.484(9) 2_778
Na2 O6W 2.337(11) .
Na2 O8W 2.350(9) .
Na2 O7W 2.368(11) .
Na2 O9W 2.463(12) .
Na2 O6 2.523(8) 2_777
Na2 O10 2.603(8) 2_777
Na2 Na3 3.350(8) .
Na2 W4 3.430(5) 2_777
Na3 O8W 2.350(11) .
Na3 O10W 2.356(11) .
Na3 O7W 2.425(13) 2_787
Na3 O6 2.460(9) 2_777
Na3 O9W 2.516(12) .
Na3 O3 2.945(9) 1_565
O3 Na3 2.945(9) 1_545
O5 W4 2.112(6) 2_777
O6 Na3 2.460(9) 2_777
O6 Na2 2.523(8) 2_777
O10 W2 1.878(6) 2_777
O10 Na2 2.603(8) 2_777
O16 C3 1.143(14) .
O17 C2 1.160(15) .
O18 C1 1.153(13) .
O2W Na1 2.439(9) 2_778
O7W Na3 2.425(13) 2_787
