#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:58:42 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179873 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/69/7016922.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7016922
loop_
_publ_author_name
'Yang, Xiaoping'
'Lam, Daniel'
'Chan, Christopher'
'Stanley, Julie M.'
'Jones, Richard A.'
'Holliday, Bradley J.'
'Wong, Wai-Kwok'
_publ_section_title
;
 Construction of 1-D 4f and 3d-4f coordination polymers with flexible
 Schiff base ligands.
;
_journal_issue                   38
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9795
_journal_page_last               9801
_journal_paper_doi               10.1039/c1dt11036e
_journal_volume                  40
_journal_year                    2011
_chemical_formula_moiety         'C24 H30 Cl N2 Ni O9 Yb'
_chemical_formula_sum            'C24 H30 Cl N2 Ni O9 Yb'
_chemical_formula_weight         757.70
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 96.85(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.064(2)
_cell_length_b                   29.115(6)
_cell_length_c                   9.1293(18)
_cell_measurement_reflns_used    7018
_cell_measurement_temperature    223(1)
_cell_measurement_theta_max      31.8078
_cell_measurement_theta_min      2.0380
_cell_volume                     2655.9(9)
_computing_cell_refinement       'Collect software, Nonius B.V. 1998'
_computing_data_collection       'Collect software, Nonius B.V. 1998'
_computing_data_reduction
;
DENZO and Scalepack (Otwinoski and Minor, 1997)
;
_computing_molecular_graphics    'XP SHELXTL/PC, Siemens Analytical'
_computing_structure_refinement  'XL SHELXTL/PC, Siemens Analytical'
_computing_structure_solution
;

SIR97 - Altomare A., Burla M.C., Camalli M., Cascarano G.L., Giacovazzo C.,
Guagliardi A., Moliterni A.G.G., Polidori G.,Spagna R.
;
_diffrn_ambient_temperature      223(1)
_diffrn_detector_area_resol_mean 13.6612
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Mercury2 (2x2 bin mode)'
_diffrn_measurement_method       dtprofit.ref
_diffrn_radiation_monochromator  'Graphite Monochromator'
_diffrn_radiation_source         'Sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.710747
_diffrn_reflns_av_R_equivalents  0.0480
_diffrn_reflns_av_sigmaI/netI    0.0636
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       34
_diffrn_reflns_limit_k_min       -34
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            13521
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.40
_exptl_absorpt_coefficient_mu    4.363
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.6339
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'DENZO and Scalepack (Otwinoski and Minor, 1997)'
_exptl_crystal_colour            Blue
_exptl_crystal_density_diffrn    1.895
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1500
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.655
_refine_diff_density_min         -1.610
_refine_diff_density_rms         0.597
_refine_ls_extinction_coef       0.0040(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.204
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     344
_refine_ls_number_reflns         4656
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.204
_refine_ls_R_factor_all          0.0660
_refine_ls_R_factor_gt           0.0483
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0853P)²+0.5994P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1270
_refine_ls_wR_factor_ref         0.1672
_reflns_number_gt                3764
_reflns_number_total             4656
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c1dt11036e.txt
_cod_data_source_block           complex-3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        2656.1(9)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7016922
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Yb1 Yb 0.50248(4) 0.186598(13) 0.87827(4) 0.0263(2) Uani 1 1 d .
Ni1 Ni 0.40183(11) 0.08296(4) 0.74795(13) 0.0259(3) Uani 1 1 d .
Cl1 Cl 0.5229(3) 0.08870(9) 0.5306(3) 0.0422(6) Uani 1 1 d .
O1 O 0.7463(6) 0.1712(2) 0.9414(7) 0.0336(15) Uani 1 1 d .
O2 O 0.5600(6) 0.1126(2) 0.8732(6) 0.0258(14) Uani 1 1 d .
O3 O 0.3446(6) 0.1506(2) 0.7211(7) 0.0321(15) Uani 1 1 d .
O4 O 0.2938(7) 0.2309(2) 0.8216(7) 0.0362(16) Uani 1 1 d .
O5 O 0.5752(7) 0.2610(2) 0.8379(7) 0.0342(16) Uani 1 1 d .
O6 O 0.5509(7) 0.2771(2) 0.6012(7) 0.0357(16) Uani 1 1 d .
O7 O 0.3027(6) 0.0832(2) 0.9403(7) 0.0303(15) Uani 1 1 d .
O8 O 0.3661(7) 0.1536(2) 1.0297(7) 0.0326(15) Uani 1 1 d .
O9 O 0.5962(7) 0.1834(2) 0.6541(8) 0.0332(16) Uani 1 1 d .
H9D H 0.5524 0.1644 0.5964 0.040 Uiso 1 1 d R
H9C H 0.5937 0.2089 0.6160 0.050 Uiso 1 1 d R
N1 N 0.4852(8) 0.0187(3) 0.7942(8) 0.0298(18) Uani 1 1 d .
N2 N 0.2383(8) 0.0644(3) 0.6060(9) 0.0358(19) Uani 1 1 d .
C1 C 0.8448(14) 0.2036(5) 1.0060(18) 0.074(5) Uani 1 1 d .
H1A H 0.8574 0.1997 1.1112 0.111 Uiso 1 1 calc R
H1B H 0.8145 0.2343 0.9827 0.111 Uiso 1 1 calc R
H1C H 0.9281 0.1984 0.9672 0.111 Uiso 1 1 calc R
C2 C 0.7921(10) 0.1266(4) 0.9132(13) 0.043(3) Uani 1 1 d .
C3 C 0.9213(10) 0.1131(4) 0.9192(12) 0.044(3) Uani 1 1 d .
H3A H 0.9897 0.1344 0.9409 0.052 Uiso 1 1 calc R
C4 C 0.9512(11) 0.0685(4) 0.8934(14) 0.051(3) Uani 1 1 d .
H4A H 1.0400 0.0592 0.8982 0.061 Uiso 1 1 calc R
C5 C 0.8498(10) 0.0371(4) 0.8603(13) 0.042(3) Uani 1 1 d .
H5A H 0.8715 0.0066 0.8433 0.051 Uiso 1 1 calc R
C6 C 0.7131(9) 0.0500(4) 0.8513(10) 0.032(2) Uani 1 1 d .
C7 C 0.6825(9) 0.0953(3) 0.8770(11) 0.032(2) Uani 1 1 d .
C8 C 0.6145(10) 0.0147(3) 0.8275(10) 0.031(2) Uani 1 1 d .
H8A H 0.6467 -0.0153 0.8370 0.038 Uiso 1 1 calc R
C9 C 0.4114(11) -0.0263(3) 0.7925(12) 0.038(2) Uani 1 1 d .
H9A H 0.4424 -0.0432 0.8816 0.046 Uiso 1 1 calc R
H9B H 0.4329 -0.0444 0.7091 0.046 Uiso 1 1 calc R
C10 C 0.2578(10) -0.0208(3) 0.7821(12) 0.039(2) Uani 1 1 d U
H10A H 0.2211 -0.0466 0.8311 0.046 Uiso 1 1 calc R
H10B H 0.2376 0.0069 0.8341 0.046 Uiso 1 1 calc R
C11 C 0.1901(11) -0.0181(4) 0.6250(12) 0.044(3) Uani 1 1 d .
H11A H 0.2018 -0.0473 0.5768 0.053 Uiso 1 1 calc R
H11B H 0.0949 -0.0136 0.6275 0.053 Uiso 1 1 calc R
C12 C 0.2413(12) 0.0195(4) 0.5343(12) 0.046(3) Uani 1 1 d .
H12A H 0.3325 0.0125 0.5176 0.055 Uiso 1 1 calc R
H12B H 0.1872 0.0207 0.4391 0.055 Uiso 1 1 calc R
C13 C 0.1365(12) 0.0912(4) 0.5693(12) 0.051(3) Uani 1 1 d .
H13A H 0.0699 0.0799 0.4993 0.061 Uiso 1 1 calc R
C14 C 0.1159(10) 0.1361(4) 0.6247(11) 0.036(2) Uani 1 1 d .
C15 C -0.0161(11) 0.1539(4) 0.5971(15) 0.056(3) Uani 1 1 d .
H15A H -0.0828 0.1362 0.5452 0.067 Uiso 1 1 calc R
C16 C -0.0472(14) 0.1969(5) 0.6457(18) 0.067(4) Uani 1 1 d .
H16A H -0.1344 0.2078 0.6272 0.080 Uiso 1 1 calc R
C17 C 0.0540(12) 0.2250(5) 0.7244(15) 0.063(4) Uani 1 1 d .
H17A H 0.0331 0.2540 0.7570 0.075 Uiso 1 1 calc R
C18 C 0.1841(10) 0.2082(3) 0.7518(11) 0.033(2) Uani 1 1 d .
C19 C 0.2191(9) 0.1629(3) 0.6983(11) 0.031(2) Uani 1 1 d .
C20 C 0.2701(15) 0.2758(4) 0.8781(16) 0.068(4) Uani 1 1 d .
H20A H 0.1869 0.2758 0.9199 0.103 Uiso 1 1 calc R
H20B H 0.2657 0.2978 0.7993 0.103 Uiso 1 1 calc R
H20C H 0.3417 0.2838 0.9528 0.103 Uiso 1 1 calc R
C21 C 0.5865(10) 0.2881(3) 0.7351(10) 0.031(2) Uani 1 1 d .
C22 C 0.6375(13) 0.3358(4) 0.7720(12) 0.049(3) Uani 1 1 d .
H22A H 0.6596 0.3385 0.8769 0.074 Uiso 1 1 calc R
H22B H 0.5696 0.3578 0.7385 0.074 Uiso 1 1 calc R
H22C H 0.7159 0.3414 0.7242 0.074 Uiso 1 1 calc R
C23 C 0.3064(10) 0.1158(3) 1.0349(11) 0.033(2) Uani 1 1 d .
C24 C 0.2388(11) 0.1066(4) 1.1728(13) 0.043(3) Uani 1 1 d .
H24A H 0.1850 0.1325 1.1925 0.065 Uiso 1 1 calc R
H24B H 0.3058 0.1015 1.2552 0.065 Uiso 1 1 calc R
H24C H 0.1830 0.0798 1.1574 0.065 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Yb Yb -0.3850 5.5486 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 Yb1 O3 72.8(2) . .
O2 Yb1 O8 77.4(2) . .
O3 Yb1 O8 76.2(2) . .
O2 Yb1 O6 115.8(2) . 4_566
O3 Yb1 O6 146.5(2) . 4_566
O8 Yb1 O6 74.6(2) . 4_566
O2 Yb1 O5 143.8(2) . .
O3 Yb1 O5 122.7(2) . .
O8 Yb1 O5 135.4(2) . .
O6 Yb1 O5 71.0(2) 4_566 .
O2 Yb1 O9 79.2(2) . .
O3 Yb1 O9 75.8(2) . .
O8 Yb1 O9 147.7(2) . .
O6 Yb1 O9 136.4(2) 4_566 .
O5 Yb1 O9 74.6(2) . .
O2 Yb1 O4 135.8(2) . .
O3 Yb1 O4 66.0(2) . .
O8 Yb1 O4 77.7(2) . .
O6 Yb1 O4 91.8(2) 4_566 .
O5 Yb1 O4 75.9(2) . .
O9 Yb1 O4 105.0(2) . .
O2 Yb1 O1 65.2(2) . .
O3 Yb1 O1 131.2(2) . .
O8 Yb1 O1 115.6(2) . .
O6 Yb1 O1 77.2(2) 4_566 .
O5 Yb1 O1 83.4(2) . .
O9 Yb1 O1 73.1(2) . .
O4 Yb1 O1 158.9(2) . .
O2 Yb1 C19 89.9(2) . .
O3 Yb1 C19 19.7(2) . .
O8 Yb1 C19 69.8(2) . .
O6 Yb1 C19 129.7(3) 4_566 .
O5 Yb1 C19 113.4(2) . .
O9 Yb1 C19 88.3(2) . .
O4 Yb1 C19 47.0(2) . .
O1 Yb1 C19 151.0(2) . .
O2 Yb1 Ni1 36.20(15) . .
O3 Yb1 Ni1 36.91(16) . .
O8 Yb1 Ni1 69.97(16) . .
O6 Yb1 Ni1 138.77(17) 4_566 .
O5 Yb1 Ni1 150.13(15) . .
O9 Yb1 Ni1 77.95(15) . .
O4 Yb1 Ni1 100.49(17) . .
O1 Yb1 Ni1 99.62(15) . .
C19 Yb1 Ni1 53.85(17) . .
O2 Yb1 H9D 71.2 . .
O3 Yb1 H9D 59.5 . .
O8 Yb1 H9D 131.2 . .
O6 Yb1 H9D 153.3 4_566 .
O5 Yb1 H9D 88.5 . .
O9 Yb1 H9D 16.9 . .
O4 Yb1 H9D 99.9 . .
O1 Yb1 H9D 83.7 . .
C19 Yb1 H9D 73.7 . .
Ni1 Yb1 H9D 62.6 . .
O2 Yb1 H9C 95.5 . .
O3 Yb1 H9C 80.8 . .
O8 Yb1 H9C 156.9 . .
O6 Yb1 H9C 127.4 4_566 .
O5 Yb1 H9C 59.8 . .
O9 Yb1 H9C 16.4 . .
O4 Yb1 H9C 93.4 . .
O1 Yb1 H9C 79.7 . .
C19 Yb1 H9C 88.5 . .
Ni1 Yb1 H9C 91.2 . .
H9D Yb1 H9C 28.8 . .
O2 Ni1 N2 169.9(3) . .
O2 Ni1 O3 81.4(2) . .
N2 Ni1 O3 89.1(3) . .
O2 Ni1 N1 89.9(3) . .
N2 Ni1 N1 99.6(3) . .
O3 Ni1 N1 171.3(3) . .
O2 Ni1 O7 87.0(2) . .
N2 Ni1 O7 95.9(3) . .
O3 Ni1 O7 86.7(3) . .
N1 Ni1 O7 93.1(3) . .
O2 Ni1 Cl1 89.71(18) . .
N2 Ni1 Cl1 86.9(2) . .
O3 Ni1 Cl1 89.87(19) . .
N1 Ni1 Cl1 89.9(2) . .
O7 Ni1 Cl1 175.52(19) . .
O2 Ni1 Yb1 40.33(17) . .
N2 Ni1 Yb1 130.5(3) . .
O3 Ni1 Yb1 41.43(17) . .
N1 Ni1 Yb1 129.9(2) . .
O7 Ni1 Yb1 81.66(17) . .
Cl1 Ni1 Yb1 93.86(7) . .
C2 O1 C1 116.9(9) . .
C2 O1 Yb1 117.2(5) . .
C1 O1 Yb1 125.9(8) . .
C7 O2 Ni1 121.0(6) . .
C7 O2 Yb1 127.4(6) . .
Ni1 O2 Yb1 103.5(3) . .
C19 O3 Ni1 122.3(6) . .
C19 O3 Yb1 124.4(6) . .
Ni1 O3 Yb1 101.7(3) . .
C18 O4 C20 116.4(9) . .
C18 O4 Yb1 117.6(5) . .
C20 O4 Yb1 125.1(8) . .
C21 O5 Yb1 140.3(6) . .
C21 O6 Yb1 138.0(6) . 4_565
C23 O7 Ni1 125.6(6) . .
C23 O8 Yb1 135.9(6) . .
Yb1 O9 H9D 109.5 . .
Yb1 O9 H9C 109.7 . .
H9D O9 H9C 109.8 . .
C8 N1 C9 113.6(8) . .
C8 N1 Ni1 119.7(7) . .
C9 N1 Ni1 126.6(6) . .
C13 N2 C12 118.6(9) . .
C13 N2 Ni1 123.8(7) . .
C12 N2 Ni1 117.4(7) . .
O1 C1 H1A 109.5 . .
O1 C1 H1B 109.5 . .
H1A C1 H1B 109.5 . .
O1 C1 H1C 109.5 . .
H1A C1 H1C 109.5 . .
H1B C1 H1C 109.5 . .
C3 C2 O1 126.3(10) . .
C3 C2 C7 122.2(10) . .
O1 C2 C7 111.5(8) . .
C2 C3 C4 120.1(11) . .
C2 C3 H3A 120.0 . .
C4 C3 H3A 120.0 . .
C3 C4 C5 119.9(10) . .
C3 C4 H4A 120.0 . .
C5 C4 H4A 120.0 . .
C4 C5 C6 121.6(10) . .
C4 C5 H5A 119.2 . .
C6 C5 H5A 119.2 . .
C7 C6 C5 118.5(9) . .
C7 C6 C8 123.3(8) . .
C5 C6 C8 118.0(9) . .
O2 C7 C6 125.6(9) . .
O2 C7 C2 116.8(9) . .
C6 C7 C2 117.6(9) . .
N1 C8 C6 128.8(9) . .
N1 C8 H8A 115.6 . .
C6 C8 H8A 115.6 . .
N1 C9 C10 113.4(8) . .
N1 C9 H9A 108.9 . .
C10 C9 H9A 108.9 . .
N1 C9 H9B 108.9 . .
C10 C9 H9B 108.9 . .
H9A C9 H9B 107.7 . .
C11 C10 C9 113.4(9) . .
C11 C10 H10A 108.9 . .
C9 C10 H10A 108.9 . .
C11 C10 H10B 108.9 . .
C9 C10 H10B 108.9 . .
H10A C10 H10B 107.7 . .
C12 C11 C10 114.5(8) . .
C12 C11 H11A 108.6 . .
C10 C11 H11A 108.6 . .
C12 C11 H11B 108.6 . .
C10 C11 H11B 108.6 . .
H11A C11 H11B 107.6 . .
N2 C12 C11 112.2(9) . .
N2 C12 H12A 109.2 . .
C11 C12 H12A 109.2 . .
N2 C12 H12B 109.2 . .
C11 C12 H12B 109.2 . .
H12A C12 H12B 107.9 . .
N2 C13 C14 127.0(10) . .
N2 C13 H13A 116.5 . .
C14 C13 H13A 116.5 . .
C19 C14 C15 120.3(10) . .
C19 C14 C13 123.3(9) . .
C15 C14 C13 116.3(10) . .
C16 C15 C14 121.2(12) . .
C16 C15 H15A 119.4 . .
C14 C15 H15A 119.4 . .
C15 C16 C17 120.4(12) . .
C15 C16 H16A 119.8 . .
C17 C16 H16A 119.8 . .
C18 C17 C16 119.2(13) . .
C18 C17 H17A 120.4 . .
C16 C17 H17A 120.4 . .
O4 C18 C17 126.9(10) . .
O4 C18 C19 112.0(8) . .
C17 C18 C19 121.0(11) . .
O3 C19 C14 124.7(9) . .
O3 C19 C18 117.5(8) . .
C14 C19 C18 117.8(9) . .
O3 C19 Yb1 35.9(4) . .
C14 C19 Yb1 158.5(7) . .
C18 C19 Yb1 82.5(6) . .
O4 C20 H20A 109.5 . .
O4 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
O4 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
O5 C21 O6 121.7(9) . .
O5 C21 C22 118.5(8) . .
O6 C21 C22 119.7(8) . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
O8 C23 O7 126.8(9) . .
O8 C23 C24 116.6(8) . .
O7 C23 C24 116.5(9) . .
C23 C24 H24A 109.5 . .
C23 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C23 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Yb1 O2 2.233(6) .
Yb1 O3 2.267(6) .
Yb1 O8 2.274(6) .
Yb1 O6 2.293(7) 4_566
Yb1 O5 2.330(6) .
Yb1 O9 2.355(7) .
Yb1 O4 2.466(7) .
Yb1 O1 2.493(7) .
Yb1 C19 3.192(10) .
Yb1 Ni1 3.3556(13) .
Yb1 H9D 2.7572 .
Yb1 H9C 2.7423 .
Ni1 O2 2.038(6) .
Ni1 N2 2.042(8) .
Ni1 O3 2.058(7) .
Ni1 N1 2.074(8) .
Ni1 O7 2.121(6) .
Ni1 Cl1 2.455(3) .
O1 C2 1.412(13) .
O1 C1 1.444(13) .
O2 C7 1.329(11) .
O3 C19 1.306(11) .
O4 C18 1.376(13) .
O4 C20 1.436(13) .
O5 C21 1.241(11) .
O6 C21 1.273(11) .
O6 Yb1 2.293(6) 4_565
O7 C23 1.280(11) .
O8 C23 1.258(11) .
O9 H9D 0.8499 .
O9 H9C 0.8200 .
N1 C8 1.306(12) .
N1 C9 1.506(12) .
N2 C13 1.299(15) .
N2 C12 1.465(13) .
C1 H1A 0.9600 .
C1 H1B 0.9600 .
C1 H1C 0.9600 .
C2 C3 1.353(14) .
C2 C7 1.437(14) .
C3 C4 1.360(16) .
C3 H3A 0.9300 .
C4 C5 1.376(15) .
C4 H4A 0.9300 .
C5 C6 1.419(13) .
C5 H5A 0.9300 .
C6 C7 1.381(14) .
C6 C8 1.428(14) .
C8 H8A 0.9300 .
C9 C10 1.546(14) .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C10 C11 1.514(15) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C11 C12 1.500(15) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C12 H12A 0.9700 .
C12 H12B 0.9700 .
C13 C14 1.426(17) .
C13 H13A 0.9300 .
C14 C19 1.405(14) .
C14 C15 1.421(15) .
C15 C16 1.38(2) .
C15 H15A 0.9300 .
C16 C17 1.430(19) .
C16 H16A 0.9300 .
C17 C18 1.392(15) .
C17 H17A 0.9300 .
C18 C19 1.463(14) .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C21 C22 1.505(14) .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C23 C24 1.525(14) .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
