#------------------------------------------------------------------------------
#$Date: 2016-03-25 14:01:52 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179876 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/72/7017210.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7017210
loop_
_publ_author_name
'Yoshinari, Nobuto'
'Konno, Takumi'
_publ_section_title
;
 Self-assembly of d-penicillaminato M(6)M'(8) (M = Ni(ii), Pd(ii), Pt(ii);
 M' = Cu(i), Ag(i)) clusters and their organization into extended
 La(iii)M(6)M'(8) supramolecular structures.
;
_journal_issue                   45
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12191
_journal_page_last               12200
_journal_paper_doi               10.1039/c1dt10778j
_journal_volume                  40
_journal_year                    2011
_chemical_absolute_configuration rm
_chemical_formula_moiety         'C62 H111 Ag8 I La2 N12 O35 Pd6 S12, 22(O)'
_chemical_formula_sum            'C62 H173 Ag8 I La2 N12 O57 Pd6 S12'
_chemical_formula_weight         4289.92
_chemical_name_systematic
;
?
;
_space_group_IT_number           92
_symmetry_cell_setting           tetragonal
_symmetry_Int_Tables_number      92
_symmetry_space_group_name_Hall  'P 4abw 2nw'
_symmetry_space_group_name_H-M   'P 41 21 2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   24.6140(19)
_cell_length_b                   24.6140(19)
_cell_length_c                   47.332(2)
_cell_measurement_reflns_used    78454
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      25.35
_cell_measurement_theta_min      3.02
_cell_volume                     28676(3)
_computing_cell_refinement       'RAPID AUTO'
_computing_data_collection       'RAPID AUTO (Rigaku, ????)'
_computing_data_reduction        'RAPID AUTO'
_computing_molecular_graphics
'Yadokari-XG 2009 (Wakita Nemoto et al., 2009)'
_computing_publication_material
'Yadokari-XG 2009 (Wakita,Nemoto et al., 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      200(2)
_diffrn_detector_area_resol_mean 10.000
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.1825
_diffrn_reflns_av_sigmaI/netI    0.1525
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       54
_diffrn_reflns_limit_l_min       -55
_diffrn_reflns_number            152269
_diffrn_reflns_theta_full        24.50
_diffrn_reflns_theta_max         24.50
_diffrn_reflns_theta_min         3.01
_exptl_absorpt_coefficient_mu    2.847
_exptl_absorpt_correction_T_max  0.798
_exptl_absorpt_correction_T_min  0.278
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR (Rigaku, 1995)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.987
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             16768
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.04
_refine_diff_density_max         1.202
_refine_diff_density_min         -0.681
_refine_diff_density_rms         0.139
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.00(3)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.955
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1327
_refine_ls_number_reflns         23731
_refine_ls_number_restraints     53
_refine_ls_restrained_S_all      0.955
_refine_ls_R_factor_all          0.1572
_refine_ls_R_factor_gt           0.0723
_refine_ls_shift/su_max          0.010
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0870P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1496
_refine_ls_wR_factor_ref         0.1806
_reflns_number_gt                12309
_reflns_number_total             23731
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c1dt10778j.txt
_cod_data_source_block           La2[3](CH3COO)
_cod_database_code               7017210
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z+1/2'
'x+1/2, -y+1/2, -z+3/4'
'-x+1/2, y+1/2, -z+1/4'
'-y, -x, -z+1/2'
'y, x, -z'
'y+1/2, -x+1/2, z+3/4'
'-y+1/2, x+1/2, z+1/4'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.717936(19) 0.659076(19) 0.228181(9) 0.07150(16) Uani 1 1 d . . .
Ag2 Ag 0.853989(18) 0.610565(18) 0.249127(9) 0.06612(15) Uani 1 1 d . . .
Ag3 Ag 0.81303(2) 0.49880(2) 0.287912(9) 0.07751(17) Uani 1 1 d . . .
Ag4 Ag 0.671566(18) 0.556065(18) 0.272300(9) 0.06393(15) Uani 1 1 d . . .
Ag5 Ag 0.727968(19) 0.742947(18) 0.289907(9) 0.06993(16) Uani 1 1 d . . .
Ag6 Ag 0.87462(2) 0.71386(2) 0.311552(11) 0.0941(2) Uani 1 1 d . . .
Ag7 Ag 0.80004(2) 0.592472(19) 0.347453(9) 0.07521(17) Uani 1 1 d . . .
Ag8 Ag 0.65111(2) 0.641641(19) 0.342564(10) 0.07954(18) Uani 1 1 d . . .
Pd1 Pd 0.758140(18) 0.497999(18) 0.205053(8) 0.05873(14) Uani 1 1 d . . .
Pd2 Pd 0.83731(2) 0.77653(2) 0.230600(10) 0.07966(18) Uani 1 1 d . . .
Pd3 Pd 0.954740(18) 0.568337(18) 0.313864(9) 0.05934(14) Uani 1 1 d . . .
Pd4 Pd 0.684348(19) 0.476017(18) 0.346359(9) 0.06294(15) Uani 1 1 d . . .
Pd5 Pd 0.572407(18) 0.686490(18) 0.267969(9) 0.06074(14) Uani 1 1 d . . .
Pd6 Pd 0.761949(18) 0.748318(18) 0.373982(9) 0.06704(15) Uani 1 1 d . . .
I1 I 0.763453(15) 0.626437(14) 0.290527(7) 0.05601(11) Uani 1 1 d . . .
La1 La 0.579295(15) 0.880022(14) 0.135718(7) 0.06711(12) Uani 1 1 d . . .
S1 S 0.69781(6) 0.56069(6) 0.21995(3) 0.0603(5) Uani 1 1 d . . .
S2 S 0.82641(6) 0.51481(6) 0.23611(3) 0.0601(5) Uani 1 1 d . . .
S3 S 0.81357(6) 0.68939(6) 0.22138(3) 0.0701(5) Uani 1 1 d . . .
S4 S 0.82221(7) 0.77552(6) 0.27806(4) 0.0816(6) Uani 1 1 d . . .
S5 S 0.92259(6) 0.63690(6) 0.28584(3) 0.0670(5) Uani 1 1 d . . .
S6 S 0.87347(6) 0.53151(6) 0.32666(3) 0.0557(5) Uani 1 1 d . . .
S7 S 0.71457(6) 0.48055(6) 0.30141(3) 0.0593(5) Uani 1 1 d . . .
S8 S 0.70610(7) 0.56097(6) 0.36026(3) 0.0679(5) Uani 1 1 d . . .
S9 S 0.60264(6) 0.61811(6) 0.29622(3) 0.0611(5) Uani 1 1 d . . .
S10 S 0.65404(6) 0.71944(6) 0.25419(3) 0.0621(5) Uani 1 1 d . . .
S11 S 0.69739(6) 0.73346(6) 0.34074(3) 0.0584(5) Uani 1 1 d . . .
S12 S 0.82647(6) 0.69084(6) 0.35796(3) 0.0676(5) Uani 1 1 d . . .
O1 O 0.60938(16) 0.45656(19) 0.14878(8) 0.1069(18) Uani 1 1 d . . .
O2 O 0.59175(19) 0.5380(2) 0.13414(9) 0.137(2) Uani 1 1 d . . .
O3 O 0.88507(17) 0.39146(17) 0.16288(8) 0.1009(17) Uani 1 1 d . . .
O4 O 0.9364(2) 0.3708(2) 0.20107(11) 0.182(2) Uani 1 1 d . . .
O5 O 0.87646(13) 0.76655(16) 0.13268(8) 0.0968(17) Uani 1 1 d D . .
O6 O 0.79845(14) 0.7267(2) 0.12396(8) 0.138(2) Uani 1 1 d D . .
O7A O 0.8465(3) 0.9601(3) 0.24293(11) 0.1369(18) Uiso 0.50 1 d PD A 1
O7B O 0.8816(3) 0.9573(3) 0.25247(10) 0.1369(18) Uiso 0.50 1 d PD B 2
O8A O 0.8940(3) 0.9537(4) 0.28214(11) 0.1369(18) Uiso 0.50 1 d PD A 1
O8B O 0.9150(3) 0.9435(4) 0.29543(10) 0.1369(18) Uiso 0.50 1 d PD B 2
O9 O 1.1164(2) 0.63160(16) 0.27573(14) 0.2022(15) Uani 1 1 d DU . .
O10 O 1.0989(2) 0.71931(16) 0.28206(16) 0.214(3) Uani 1 1 d DU . .
O11 O 1.02099(14) 0.42716(14) 0.37083(7) 0.0666(13) Uani 1 1 d . . .
O12 O 0.95677(15) 0.36757(16) 0.35794(8) 0.0847(15) Uani 1 1 d . . .
O13 O 0.63557(16) 0.30034(14) 0.31532(8) 0.0851(15) Uani 1 1 d . . .
O14 O 0.71390(17) 0.28610(13) 0.29348(10) 0.0960(17) Uani 1 1 d D . .
O15 O 0.6638(2) 0.45212(19) 0.44306(9) 0.133(2) Uani 1 1 d . . .
O16 O 0.6286(3) 0.5318(2) 0.45217(9) 0.166(3) Uani 1 1 d . . .
O17 O 0.4104(2) 0.5943(3) 0.29129(14) 0.163(3) Uani 1 1 d . . .
O18 O 0.4308(2) 0.5916(3) 0.33895(14) 0.202(3) Uani 1 1 d . . .
O19 O 0.51455(15) 0.82545(14) 0.20648(7) 0.0777(13) Uani 1 1 d . . .
O20 O 0.58195(16) 0.81334(15) 0.17592(7) 0.0785(14) Uani 1 1 d . . .
O21 O 0.64384(19) 0.88817(17) 0.39585(9) 0.1120(18) Uani 1 1 d . . .
O22 O 0.56603(16) 0.84180(17) 0.39027(8) 0.0949(16) Uani 1 1 d . . .
O23 O 0.88674(18) 0.7667(2) 0.44499(9) 0.176(3) Uani 1 1 d D . .
O24 O 0.96191(12) 0.7542(2) 0.42123(10) 0.124(2) Uani 1 1 d D . .
N1 N 0.70461(19) 0.48373(19) 0.17426(9) 0.0811(18) Uani 1 1 d . . .
H1A H 0.7234 0.4790 0.1576 0.097 Uiso 1 1 calc R . .
H1B H 0.6871 0.4516 0.1782 0.097 Uiso 1 1 calc R . .
N2 N 0.80682(17) 0.43594(18) 0.19052(9) 0.0695(16) Uani 1 1 d . . .
H2A H 0.7867 0.4045 0.1902 0.083 Uiso 1 1 calc R . .
H2B H 0.8167 0.4436 0.1722 0.083 Uiso 1 1 calc R . .
N3 N 0.8434(2) 0.7851(2) 0.18818(10) 0.106(2) Uani 1 1 d . . .
H3A H 0.8301 0.8187 0.1832 0.128 Uiso 1 1 calc R . .
H3B H 0.8796 0.7841 0.1832 0.128 Uiso 1 1 calc R . .
N4 N 0.8699(2) 0.85282(19) 0.23704(11) 0.116(2) Uani 1 1 d . . .
H4A H 0.9035 0.8541 0.2286 0.140 Uiso 1 1 calc R . .
H4B H 0.8481 0.8779 0.2281 0.140 Uiso 1 1 calc R . .
N5 N 1.03035(17) 0.60004(18) 0.30457(9) 0.0745(17) Uani 1 1 d . . .
H5A H 1.0509 0.6002 0.3208 0.089 Uiso 1 1 calc R . .
H5B H 1.0473 0.5774 0.2918 0.089 Uiso 1 1 calc R . .
N6 N 0.98800(15) 0.50725(16) 0.33724(8) 0.0561(14) Uani 1 1 d . . .
H6A H 1.0201 0.4967 0.3290 0.067 Uiso 1 1 calc R . .
H6B H 0.9959 0.5202 0.3550 0.067 Uiso 1 1 calc R . .
N7 N 0.66944(19) 0.39553(15) 0.33850(8) 0.0685(16) Uani 1 1 d . . .
H7A H 0.6805 0.3753 0.3538 0.082 Uiso 1 1 calc R . .
H7B H 0.6326 0.3905 0.3363 0.082 Uiso 1 1 calc R . .
N8 N 0.6566(2) 0.46863(18) 0.38691(9) 0.0908(18) Uani 1 1 d . . .
H8A H 0.6233 0.4517 0.3862 0.109 Uiso 1 1 calc R . .
H8B H 0.6798 0.4456 0.3963 0.109 Uiso 1 1 calc R . .
N9 N 0.4976(2) 0.66333(19) 0.28290(11) 0.095(2) Uani 1 1 d . . .
H9A H 0.4786 0.6943 0.2874 0.114 Uiso 1 1 calc R . .
H9B H 0.4793 0.6466 0.2684 0.114 Uiso 1 1 calc R . .
N10 N 0.54258(17) 0.74080(16) 0.23719(9) 0.0700(16) Uani 1 1 d . . .
H10A H 0.5156 0.7238 0.2270 0.084 Uiso 1 1 calc R . .
H10B H 0.5274 0.7703 0.2461 0.084 Uiso 1 1 calc R . .
N11 N 0.70726(18) 0.79876(19) 0.39164(9) 0.0795(18) Uani 1 1 d . . .
H11A H 0.7060 0.7911 0.4107 0.095 Uiso 1 1 calc R . .
H11B H 0.7204 0.8336 0.3898 0.095 Uiso 1 1 calc R . .
N12 N 0.81932(19) 0.7676(2) 0.40349(12) 0.109(2) Uani 1 1 d . F .
H12A H 0.8202 0.8048 0.4054 0.131 Uiso 1 1 calc R . .
H12B H 0.8085 0.7534 0.4206 0.131 Uiso 1 1 calc R . .
C1 C 0.6398(2) 0.5440(2) 0.19598(10) 0.0679(19) Uani 1 1 d . . .
C2 C 0.6644(2) 0.5251(3) 0.16989(11) 0.074(2) Uani 1 1 d . . .
H1 H 0.6832 0.5569 0.1611 0.089 Uiso 1 1 calc R . .
C3 C 0.6175(3) 0.5061(3) 0.14827(13) 0.092(2) Uani 1 1 d . . .
C4 C 0.6030(2) 0.5023(2) 0.20976(10) 0.077(2) Uani 1 1 d . . .
H2 H 0.5876 0.5174 0.2271 0.116 Uiso 1 1 calc R . .
H3 H 0.6240 0.4696 0.2143 0.116 Uiso 1 1 calc R . .
H4 H 0.5735 0.4928 0.1967 0.116 Uiso 1 1 calc R . .
C5 C 0.6077(3) 0.6035(3) 0.19154(15) 0.111(3) Uani 1 1 d . . .
H5 H 0.5915 0.6149 0.2095 0.167 Uiso 1 1 calc R . .
H6 H 0.5792 0.5994 0.1773 0.167 Uiso 1 1 calc R . .
H7 H 0.6338 0.6311 0.1853 0.167 Uiso 1 1 calc R . .
C6 C 0.88175(19) 0.47626(19) 0.21771(11) 0.0567(17) Uani 1 1 d . . .
C7 C 0.85713(19) 0.42589(19) 0.20735(11) 0.0600(18) Uani 1 1 d . . .
H8 H 0.8466 0.4038 0.2242 0.072 Uiso 1 1 calc R . .
C8 C 0.8962(3) 0.3900(2) 0.18879(12) 0.092(2) Uani 1 1 d . . .
C9 C 0.9030(2) 0.5155(3) 0.19370(11) 0.091(2) Uani 1 1 d . . .
H9 H 0.9192 0.5479 0.2023 0.137 Uiso 1 1 calc R . .
H10 H 0.8726 0.5263 0.1816 0.137 Uiso 1 1 calc R . .
H11 H 0.9305 0.4967 0.1823 0.137 Uiso 1 1 calc R . .
C10 C 0.9242(3) 0.4685(4) 0.24108(12) 0.132(4) Uani 1 1 d . . .
H12 H 0.9397 0.5038 0.2462 0.198 Uiso 1 1 calc R . .
H13 H 0.9531 0.4445 0.2343 0.198 Uiso 1 1 calc R . .
H14 H 0.9069 0.4522 0.2577 0.198 Uiso 1 1 calc R . .
C11 C 0.8329(2) 0.6835(2) 0.18280(11) 0.087(2) Uani 1 1 d . . .
C12 C 0.8132(3) 0.7418(4) 0.17137(9) 0.126(4) Uani 1 1 d D . .
H15 H 0.7729 0.7462 0.1727 0.151 Uiso 1 1 calc R . .
C13 C 0.83455(16) 0.7456(3) 0.13919(8) 0.096(3) Uani 1 1 d D . .
C14 C 0.8971(2) 0.6763(3) 0.18210(10) 0.094(2) Uani 1 1 d . . .
H16 H 0.9144 0.7084 0.1904 0.141 Uiso 1 1 calc R . .
H17 H 0.9092 0.6721 0.1625 0.141 Uiso 1 1 calc R . .
H18 H 0.9072 0.6440 0.1930 0.141 Uiso 1 1 calc R . .
C15 C 0.8007(2) 0.6355(2) 0.16973(10) 0.085(2) Uani 1 1 d . . .
H19 H 0.8152 0.6011 0.1770 0.127 Uiso 1 1 calc R . .
H20 H 0.8044 0.6364 0.1491 0.127 Uiso 1 1 calc R . .
H21 H 0.7623 0.6387 0.1749 0.127 Uiso 1 1 calc R . .
C16 C 0.8256(3) 0.8493(3) 0.28392(12) 0.094(3) Uani 1 1 d . . .
C17 C 0.8756(3) 0.86837(15) 0.26540(18) 0.122(3) Uani 1 1 d D . .
H22 H 0.9117 0.8589 0.2737 0.183 Uiso 0.50 1 calc PR C 1
H23 H 0.9053 0.8438 0.2721 0.183 Uiso 0.50 1 calc PR C 2
C18A C 0.8644(3) 0.9325(2) 0.26360(13) 0.1369(18) Uiso 0.50 1 d PD A 1
C18B C 0.9004(4) 0.9274(2) 0.27156(11) 0.1369(18) Uiso 0.50 1 d PD B 2
C19 C 0.7740(3) 0.8761(3) 0.27568(15) 0.120(3) Uani 1 1 d . . .
H24 H 0.7695 0.8739 0.2551 0.180 Uiso 1 1 calc R A .
H25 H 0.7749 0.9143 0.2815 0.180 Uiso 1 1 calc R . .
H26 H 0.7435 0.8578 0.2850 0.180 Uiso 1 1 calc R . .
C20 C 0.8312(3) 0.8555(3) 0.31199(17) 0.158(4) Uani 1 1 d . . .
H27 H 0.8656 0.8393 0.3181 0.237 Uiso 1 1 calc R A .
H28 H 0.8010 0.8374 0.3217 0.237 Uiso 1 1 calc R . .
H29 H 0.8310 0.8943 0.3167 0.237 Uiso 1 1 calc R . .
C21 C 0.9869(3) 0.6588(2) 0.26856(12) 0.087(2) Uani 1 1 d . . .
C22 C 1.02942(18) 0.6566(3) 0.29259(12) 0.088(2) Uani 1 1 d D . .
H30 H 1.0196 0.6832 0.3077 0.106 Uiso 1 1 calc R . .
C23 C 1.0875(2) 0.67103(19) 0.27998(19) 0.2049(16) Uani 1 1 d DU . .
C24 C 0.9994(3) 0.6168(3) 0.24467(11) 0.091(3) Uani 1 1 d . . .
H31 H 0.9715 0.6195 0.2299 0.136 Uiso 1 1 calc R . .
H32 H 0.9993 0.5801 0.2526 0.136 Uiso 1 1 calc R . .
H33 H 1.0351 0.6247 0.2365 0.136 Uiso 1 1 calc R . .
C25 C 0.9745(3) 0.7157(2) 0.25579(16) 0.120(3) Uani 1 1 d . . .
H34 H 0.9470 0.7121 0.2409 0.180 Uiso 1 1 calc R . .
H35 H 1.0078 0.7310 0.2477 0.180 Uiso 1 1 calc R . .
H36 H 0.9609 0.7398 0.2707 0.180 Uiso 1 1 calc R . .
C26 C 0.8953(2) 0.4767(2) 0.35118(10) 0.064(2) Uani 1 1 d . . .
C27 C 0.95172(19) 0.4589(2) 0.33993(11) 0.0574(18) Uani 1 1 d . . .
H37 H 0.9464 0.4434 0.3206 0.069 Uiso 1 1 calc R . .
C28 C 0.9825(2) 0.4140(2) 0.35869(12) 0.073(2) Uani 1 1 d . . .
C29 C 0.89961(19) 0.4980(2) 0.38095(10) 0.0648(19) Uani 1 1 d . . .
H38 H 0.8635 0.5087 0.3877 0.097 Uiso 1 1 calc R . .
H39 H 0.9237 0.5297 0.3813 0.097 Uiso 1 1 calc R . .
H40 H 0.9144 0.4696 0.3933 0.097 Uiso 1 1 calc R . .
C30 C 0.8495(2) 0.4297(2) 0.34915(11) 0.075(2) Uani 1 1 d . . .
H41 H 0.8151 0.4435 0.3567 0.112 Uiso 1 1 calc R . .
H42 H 0.8611 0.3981 0.3602 0.112 Uiso 1 1 calc R . .
H43 H 0.8446 0.4192 0.3294 0.112 Uiso 1 1 calc R . .
C31 C 0.6924(2) 0.41173(18) 0.28819(10) 0.0503(17) Uani 1 1 d . . .
C32 C 0.6981(2) 0.3756(2) 0.31255(11) 0.0620(19) Uani 1 1 d . . .
H44 H 0.7377 0.3752 0.3173 0.074 Uiso 1 1 calc R . .
C33 C 0.6817(2) 0.3152(2) 0.30741(11) 0.075(2) Uani 1 1 d . . .
C34 C 0.6335(2) 0.4177(2) 0.28199(11) 0.081(2) Uani 1 1 d . . .
H45 H 0.6140 0.4265 0.2994 0.122 Uiso 1 1 calc R . .
H46 H 0.6194 0.3836 0.2742 0.122 Uiso 1 1 calc R . .
H47 H 0.6282 0.4469 0.2682 0.122 Uiso 1 1 calc R . .
C35 C 0.7228(2) 0.3981(2) 0.26278(11) 0.071(2) Uani 1 1 d . . .
H48 H 0.7616 0.3956 0.2673 0.106 Uiso 1 1 calc R . .
H49 H 0.7172 0.4264 0.2485 0.106 Uiso 1 1 calc R . .
H50 H 0.7102 0.3631 0.2554 0.106 Uiso 1 1 calc R . .
C36 C 0.6987(2) 0.5481(3) 0.39856(11) 0.084(2) Uani 1 1 d . . .
C37 C 0.6504(3) 0.5174(3) 0.40415(13) 0.098(3) Uani 1 1 d . . .
H51 H 0.6173 0.5382 0.3984 0.117 Uiso 1 1 calc R . .
C38 C 0.6449(4) 0.4962(3) 0.43596(12) 0.123(3) Uani 1 1 d . . .
C39 C 0.7512(3) 0.5232(3) 0.40910(11) 0.108(3) Uani 1 1 d . . .
H52 H 0.7815 0.5480 0.4052 0.162 Uiso 1 1 calc R . .
H53 H 0.7575 0.4885 0.3994 0.162 Uiso 1 1 calc R . .
H54 H 0.7486 0.5169 0.4295 0.162 Uiso 1 1 calc R . .
C40 C 0.6976(3) 0.6043(3) 0.41231(11) 0.099(3) Uani 1 1 d . . .
H55 H 0.7322 0.6228 0.4089 0.149 Uiso 1 1 calc R . .
H56 H 0.6919 0.6004 0.4327 0.149 Uiso 1 1 calc R . .
H57 H 0.6679 0.6257 0.4042 0.149 Uiso 1 1 calc R . .
C41 C 0.5363(2) 0.5830(2) 0.30176(10) 0.066(2) Uani 1 1 d . . .
C42 C 0.4960(2) 0.62679(19) 0.30762(11) 0.0648(18) Uani 1 1 d . . .
H58 H 0.5063 0.6471 0.3251 0.078 Uiso 1 1 calc R . .
C43 C 0.4384(3) 0.6021(3) 0.31082(17) 0.124(3) Uani 1 1 d . . .
C44 C 0.52465(19) 0.5463(2) 0.27655(11) 0.071(2) Uani 1 1 d . . .
H59 H 0.5537 0.5193 0.2747 0.107 Uiso 1 1 calc R . .
H60 H 0.5229 0.5683 0.2593 0.107 Uiso 1 1 calc R . .
H61 H 0.4898 0.5278 0.2794 0.107 Uiso 1 1 calc R . .
C45 C 0.5459(3) 0.5491(2) 0.32904(13) 0.097(3) Uani 1 1 d . . .
H62 H 0.5531 0.5737 0.3449 0.146 Uiso 1 1 calc R . .
H63 H 0.5771 0.5250 0.3263 0.146 Uiso 1 1 calc R . .
H64 H 0.5135 0.5274 0.3331 0.146 Uiso 1 1 calc R . .
C46 C 0.6334(2) 0.7787(2) 0.23183(11) 0.0603(18) Uani 1 1 d . . .
C47 C 0.5829(2) 0.7592(2) 0.21838(10) 0.0626(18) Uani 1 1 d . . .
H65 H 0.5931 0.7276 0.2061 0.075 Uiso 1 1 calc R . .
C48 C 0.5575(2) 0.8031(2) 0.19870(12) 0.0629(19) Uani 1 1 d . . .
C49 C 0.6246(2) 0.8261(2) 0.25066(12) 0.080(2) Uani 1 1 d . . .
H66 H 0.5951 0.8181 0.2639 0.121 Uiso 1 1 calc R . .
H67 H 0.6150 0.8580 0.2393 0.121 Uiso 1 1 calc R . .
H68 H 0.6580 0.8336 0.2612 0.121 Uiso 1 1 calc R . .
C50 C 0.6765(2) 0.7866(2) 0.21037(10) 0.0801(19) Uani 1 1 d . . .
H69 H 0.6791 0.7540 0.1985 0.120 Uiso 1 1 calc R . .
H70 H 0.7113 0.7929 0.2198 0.120 Uiso 1 1 calc R . .
H71 H 0.6675 0.8180 0.1985 0.120 Uiso 1 1 calc R . .
C51 C 0.6486(2) 0.7915(2) 0.34927(11) 0.077(2) Uani 1 1 d . . .
C52 C 0.6506(2) 0.7985(2) 0.38091(11) 0.071(2) Uani 1 1 d . . .
H72 H 0.6320 0.7663 0.3894 0.086 Uiso 1 1 calc R . .
C53 C 0.6196(3) 0.8477(3) 0.38976(11) 0.086(2) Uani 1 1 d . . .
C54 C 0.6697(3) 0.8433(2) 0.33564(11) 0.087(2) Uani 1 1 d . . .
H73 H 0.6687 0.8395 0.3150 0.130 Uiso 1 1 calc R . .
H74 H 0.7072 0.8498 0.3417 0.130 Uiso 1 1 calc R . .
H75 H 0.6469 0.8740 0.3414 0.130 Uiso 1 1 calc R . .
C55 C 0.5949(2) 0.7770(3) 0.33633(14) 0.148(3) Uani 1 1 d . . .
H76 H 0.5988 0.7746 0.3158 0.222 Uiso 1 1 calc R . .
H77 H 0.5680 0.8049 0.3410 0.222 Uiso 1 1 calc R . .
H78 H 0.5827 0.7418 0.3437 0.222 Uiso 1 1 calc R . .
C56 C 0.8735(2) 0.68971(18) 0.38809(12) 0.071(2) Uani 1 1 d . F .
C57 C 0.8785(2) 0.7472(3) 0.39716(11) 0.120(3) Uani 1 1 d D . .
H79 H 0.8949 0.7694 0.3816 0.144 Uiso 1 1 calc R F .
C58 C 0.91450(16) 0.7525(3) 0.42516(10) 0.136(3) Uani 1 1 d D F .
C59 C 0.8532(4) 0.6522(3) 0.40863(16) 0.176(4) Uani 1 1 d . . .
H80 H 0.8179 0.6649 0.4156 0.264 Uiso 1 1 calc R F .
H81 H 0.8788 0.6498 0.4244 0.264 Uiso 1 1 calc R . .
H82 H 0.8490 0.6163 0.3999 0.264 Uiso 1 1 calc R . .
C60 C 0.9301(3) 0.6747(4) 0.37579(16) 0.166(4) Uani 1 1 d . . .
H83 H 0.9299 0.6367 0.3696 0.249 Uiso 1 1 calc R F .
H84 H 0.9579 0.6797 0.3904 0.249 Uiso 1 1 calc R . .
H85 H 0.9382 0.6983 0.3596 0.249 Uiso 1 1 calc R . .
O25 O 0.9490(2) 0.7768(2) 0.32568(12) 0.151(3) Uani 1 1 d . . .
O26 O 0.5748(2) 0.6548(2) 0.37878(10) 0.147(2) Uani 1 1 d . . .
O27 O 0.6635(2) 0.9133(2) 0.16502(13) 0.1607(15) Uani 1 1 d U . .
C61 C 0.6256(4) 0.9392(3) 0.1871(2) 0.1545(12) Uani 1 1 d U . .
C62 C 0.6711(4) 0.9625(4) 0.2105(2) 0.189(3) Uani 1 1 d U . .
H86 H 0.7078 0.9579 0.2028 0.283 Uiso 1 1 calc R . .
H87 H 0.6677 0.9422 0.2282 0.283 Uiso 1 1 calc R . .
H88 H 0.6643 1.0012 0.2140 0.283 Uiso 1 1 calc R . .
O28 O 0.5837(2) 0.9345(2) 0.18560(11) 0.1360(14) Uani 1 1 d U . .
O29 O 0.49924(16) 0.89134(16) 0.10115(7) 0.0811(15) Uani 1 1 d . . .
O30 O 0.48766(14) 0.89064(13) 0.16247(7) 0.0607(12) Uani 1 1 d . . .
O31 O 0.6608(2) 0.81475(19) 0.12869(11) 0.149(2) Uani 1 1 d . . .
O32 O 0.5448(2) 0.78644(18) 0.11841(10) 0.160(2) Uani 1 1 d . . .
O33 O 0.42821(16) 0.97597(16) 0.11103(8) 0.0856(12) Uiso 1 1 d . . .
La2 La 0.92901(16) 1.03236(16) 0.29266(8) 0.1031(11) Uiso 0.13 1 d P A 1
La6 La 1.22075(17) 0.65052(17) 0.25807(9) 0.1584(14) Uiso 0.17 1 d P . 1
La3 La 0.86137(19) 1.06581(19) 0.23385(10) 0.1332(15) Uiso 0.13 1 d P B 2
La4 La 0.9555(2) 1.0424(2) 0.23922(9) 0.1420(17) Uiso 0.13 1 d P D 3
La5 La 0.8830(2) 1.0543(2) 0.26727(12) 0.173(2) Uiso 0.13 1 d P E 4
O34 O 0.7866(4) 0.6802(4) 0.0752(2) 0.273(4) Uiso 1 1 d . . .
La7 La 0.8284(2) 0.7713(2) 0.49071(10) 0.1926(18) Uiso 0.17 1 d P F 2
La8 La 0.8567(3) 0.8188(3) 0.48419(14) 0.271(3) Uiso 0.17 1 d P . 3
O35 O 0.7846(2) 0.4889(2) 0.12865(12) 0.146(2) Uiso 1 1 d . . .
O36 O 0.4868(2) 0.8135(2) 0.28408(12) 0.157(2) Uiso 1 1 d . . .
O37 O 0.5063(2) 0.9326(2) 0.23110(10) 0.1190(16) Uiso 1 1 d . . .
O38 O 0.7559(3) 0.8678(3) 0.11849(14) 0.183(3) Uiso 1 1 d . . .
O39 O 0.6846(3) 0.7138(3) 0.14255(16) 0.200(3) Uiso 1 1 d . . .
O40 O 0.5138(4) 0.7439(4) 0.38097(19) 0.254(4) Uiso 1 1 d . . .
O41 O 0.4830(4) 0.6729(4) 0.19973(19) 0.253(4) Uiso 1 1 d . . .
O42 O 0.5275(4) 0.4651(4) 0.4023(2) 0.287(5) Uiso 1 1 d . . .
O43 O 0.5330(3) 0.6993(2) 0.15254(17) 0.244(4) Uiso 1 1 d D . .
O44 O 0.7805(4) 0.6799(4) 0.47163(19) 0.259(4) Uiso 1 1 d . . .
O45 O 0.5261(4) 0.9181(4) 0.29250(19) 0.274(4) Uiso 1 1 d . . .
O46 O 0.8387(7) 0.9049(6) 0.1741(3) 0.480(9) Uiso 1 1 d . . .
O47 O 0.5012(6) 0.6080(3) 0.1338(3) 0.526(10) Uiso 1 1 d D . .
O48 O 0.8122(4) 0.8860(5) 0.4103(2) 0.317(5) Uiso 1 1 d . . .
O49 O 0.7084(4) 0.7658(4) 0.4517(2) 0.275(4) Uiso 1 1 d . . .
O50 O 0.7260(4) 0.9016(4) 0.4488(2) 0.298(5) Uiso 1 1 d . . .
O51 O 0.4596(6) 0.7689(6) 0.0869(3) 0.416(8) Uiso 1 1 d . . .
O52 O 0.6147(5) 0.4929(5) 0.5042(3) 0.345(6) Uiso 1 1 d . . .
O53 O 0.6316(4) 0.6329(4) 0.1182(2) 0.302(5) Uiso 1 1 d . . .
O54 O 0.6397(4) 0.9508(4) 0.2898(2) 0.276(4) Uiso 1 1 d . . .
O55 O 0.6252(3) 0.7408(3) 0.07124(18) 0.369(6) Uiso 1 1 d D . .
O56 O 0.8158(2) 0.3019(4) 0.2095(2) 0.575(12) Uiso 1 1 d . . .
O57 O 0.6809(6) 0.6243(6) 0.4834(3) 0.432(8) Uiso 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
La La -0.2871 2.4523 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
S10 Ag1 S3 118.84(5) . .
S10 Ag1 S1 121.97(5) . .
S3 Ag1 S1 117.19(5) . .
S10 Ag1 I1 85.21(3) . .
S3 Ag1 I1 82.29(4) . .
S1 Ag1 I1 88.31(3) . .
S5 Ag2 S2 126.18(5) . .
S5 Ag2 S3 115.07(5) . .
S2 Ag2 S3 118.67(5) . .
S5 Ag2 I1 90.80(4) . .
S2 Ag2 I1 94.66(4) . .
S3 Ag2 I1 86.98(4) . .
S6 Ag3 S2 126.18(5) . .
S6 Ag3 S7 116.10(5) . .
S2 Ag3 S7 113.49(5) . .
S7 Ag4 S9 118.31(5) . .
S7 Ag4 S1 116.82(5) . .
S9 Ag4 S1 124.80(5) . .
S7 Ag4 I1 87.25(4) . .
S9 Ag4 I1 91.62(4) . .
S1 Ag4 I1 93.60(4) . .
S4 Ag5 S11 120.99(5) . .
S4 Ag5 S10 125.59(5) . .
S11 Ag5 S10 113.39(5) . .
S4 Ag5 I1 92.20(4) . .
S11 Ag5 I1 89.37(3) . .
S10 Ag5 I1 89.85(3) . .
O25 Ag6 S5 104.52(14) . .
O25 Ag6 S4 99.72(14) . .
S5 Ag6 S4 112.43(5) . .
O25 Ag6 S12 104.34(14) . .
S5 Ag6 S12 117.45(5) . .
S4 Ag6 S12 115.58(6) . .
S8 Ag7 S6 124.36(5) . .
S8 Ag7 S12 118.66(5) . .
S6 Ag7 S12 116.91(5) . .
S8 Ag7 I1 91.53(3) . .
S6 Ag7 I1 91.75(3) . .
S12 Ag7 I1 89.26(4) . .
S11 Ag8 S8 117.92(5) . .
S11 Ag8 O26 103.87(13) . .
S8 Ag8 O26 105.56(13) . .
S11 Ag8 S9 112.44(5) . .
S8 Ag8 S9 110.66(5) . .
O26 Ag8 S9 105.06(12) . .
N1 Pd1 N2 90.55(17) . .
N1 Pd1 S1 85.07(14) . .
N2 Pd1 S1 174.37(13) . .
N1 Pd1 S2 173.39(13) . .
N2 Pd1 S2 85.46(12) . .
S1 Pd1 S2 99.22(5) . .
N3 Pd2 N4 91.3(2) . .
N3 Pd2 S3 85.79(15) . .
N4 Pd2 S3 171.83(17) . .
N3 Pd2 S4 172.62(16) . .
N4 Pd2 S4 85.84(15) . .
S3 Pd2 S4 97.91(6) . .
N6 Pd3 N5 91.86(16) . .
N6 Pd3 S6 85.11(11) . .
N5 Pd3 S6 176.50(13) . .
N6 Pd3 S5 176.17(12) . .
N5 Pd3 S5 84.81(13) . .
S6 Pd3 S5 98.28(5) . .
N8 Pd4 N7 91.41(17) . .
N8 Pd4 S8 83.58(13) . .
N7 Pd4 S8 172.50(12) . .
N8 Pd4 S7 177.71(13) . .
N7 Pd4 S7 86.31(12) . .
S8 Pd4 S7 98.67(5) . .
N9 Pd5 N10 95.85(18) . .
N9 Pd5 S10 174.35(14) . .
N10 Pd5 S10 83.27(12) . .
N9 Pd5 S9 83.42(14) . .
N10 Pd5 S9 171.44(12) . .
S10 Pd5 S9 98.28(5) . .
N11 Pd6 N12 92.02(19) . .
N11 Pd6 S12 175.01(13) . .
N12 Pd6 S12 83.61(15) . .
N11 Pd6 S11 85.35(13) . .
N12 Pd6 S11 175.86(15) . .
S12 Pd6 S11 99.14(5) . .
Ag7 I1 Ag4 109.297(17) . .
Ag7 I1 Ag2 109.417(17) . .
Ag4 I1 Ag2 107.459(16) . .
Ag7 I1 Ag5 111.564(16) . .
Ag4 I1 Ag5 109.417(17) . .
Ag2 I1 Ag5 109.594(16) . .
Ag7 I1 Ag1 176.926(19) . .
Ag4 I1 Ag1 67.640(14) . .
Ag2 I1 Ag1 72.250(14) . .
Ag5 I1 Ag1 69.817(14) . .
O11 La1 O3 78.08(13) 5_675 4_655
O11 La1 O20 138.02(11) 5_675 .
O3 La1 O20 140.15(13) 4_655 .
O11 La1 O29 76.33(12) 5_675 .
O3 La1 O29 70.66(13) 4_655 .
O20 La1 O29 124.84(12) . .
O11 La1 O32 145.07(14) 5_675 .
O3 La1 O32 85.61(15) 4_655 .
O20 La1 O32 70.56(13) . .
O29 La1 O32 69.14(15) . .
O11 La1 O31 130.34(14) 5_675 .
O3 La1 O31 71.17(15) 4_655 .
O20 La1 O31 70.88(14) . .
O29 La1 O31 125.28(14) . .
O32 La1 O31 70.25(17) . .
O11 La1 O30 84.60(11) 5_675 .
O3 La1 O30 138.40(12) 4_655 .
O20 La1 O30 73.71(11) . .
O29 La1 O30 68.59(11) . .
O32 La1 O30 87.63(15) . .
O31 La1 O30 142.79(13) . .
O11 La1 O27 78.97(15) 5_675 .
O3 La1 O27 100.11(17) 4_655 .
O20 La1 O27 77.48(16) . .
O29 La1 O27 154.93(15) . .
O32 La1 O27 134.76(17) . .
O31 La1 O27 69.50(17) . .
O30 La1 O27 113.35(15) . .
O11 La1 O28 67.90(13) 5_675 .
O3 La1 O28 137.46(15) 4_655 .
O20 La1 O28 70.31(13) . .
O29 La1 O28 121.92(14) . .
O32 La1 O28 136.63(15) . .
O31 La1 O28 112.75(16) . .
O30 La1 O28 63.99(13) . .
O27 La1 O28 49.90(17) . .
O11 La1 C61 69.65(18) 5_675 .
O3 La1 C61 123.6(2) 4_655 .
O20 La1 C61 72.48(18) . .
O29 La1 C61 137.65(19) . .
O32 La1 C61 143.0(2) . .
O31 La1 C61 96.3(2) . .
O30 La1 C61 83.54(19) . .
O27 La1 C61 30.3(2) . .
O28 La1 C61 19.7(2) . .
C1 S1 Pd1 99.35(17) . .
C1 S1 Ag1 117.31(18) . .
Pd1 S1 Ag1 125.50(6) . .
C1 S1 Ag4 112.61(17) . .
Pd1 S1 Ag4 115.97(6) . .
Ag1 S1 Ag4 86.70(4) . .
C6 S2 Pd1 98.32(16) . .
C6 S2 Ag3 118.08(17) . .
Pd1 S2 Ag3 120.51(6) . .
C6 S2 Ag2 112.95(16) . .
Pd1 S2 Ag2 121.75(6) . .
Ag3 S2 Ag2 86.76(4) . .
C11 S3 Pd2 101.1(2) . .
C11 S3 Ag1 109.86(18) . .
Pd2 S3 Ag1 120.17(7) . .
C11 S3 Ag2 109.97(19) . .
Pd2 S3 Ag2 121.43(6) . .
Ag1 S3 Ag2 94.27(5) . .
C16 S4 Pd2 97.5(2) . .
C16 S4 Ag5 108.9(2) . .
Pd2 S4 Ag5 111.94(7) . .
C16 S4 Ag6 118.1(2) . .
Pd2 S4 Ag6 122.56(7) . .
Ag5 S4 Ag6 97.95(6) . .
C21 S5 Pd3 100.0(2) . .
C21 S5 Ag2 110.0(2) . .
Pd3 S5 Ag2 116.36(6) . .
C21 S5 Ag6 112.95(19) . .
Pd3 S5 Ag6 115.64(6) . .
Ag2 S5 Ag6 102.21(6) . .
C26 S6 Pd3 101.57(18) . .
C26 S6 Ag3 113.42(18) . .
Pd3 S6 Ag3 117.16(6) . .
C26 S6 Ag7 113.05(17) . .
Pd3 S6 Ag7 119.43(6) . .
Ag3 S6 Ag7 92.92(5) . .
C31 S7 Pd4 99.96(15) . .
C31 S7 Ag4 110.84(16) . .
Pd4 S7 Ag4 114.18(6) . .
C31 S7 Ag3 110.53(16) . .
Pd4 S7 Ag3 123.99(6) . .
Ag4 S7 Ag3 97.54(5) . .
C36 S8 Pd4 96.0(2) . .
C36 S8 Ag7 112.3(2) . .
Pd4 S8 Ag7 115.72(6) . .
C36 S8 Ag8 113.8(2) . .
Pd4 S8 Ag8 120.06(7) . .
Ag7 S8 Ag8 99.75(5) . .
C41 S9 Pd5 97.98(18) . .
C41 S9 Ag4 111.58(18) . .
Pd5 S9 Ag4 113.59(6) . .
C41 S9 Ag8 113.05(16) . .
Pd5 S9 Ag8 119.22(6) . .
Ag4 S9 Ag8 101.88(5) . .
C46 S10 Pd5 101.58(17) . .
C46 S10 Ag1 110.93(17) . .
Pd5 S10 Ag1 119.32(6) . .
C46 S10 Ag5 113.05(17) . .
Pd5 S10 Ag5 121.59(6) . .
Ag1 S10 Ag5 90.72(5) . .
C51 S11 Pd6 99.97(17) . .
C51 S11 Ag5 108.60(17) . .
Pd6 S11 Ag5 115.89(6) . .
C51 S11 Ag8 112.20(19) . .
Pd6 S11 Ag8 115.83(6) . .
Ag5 S11 Ag8 104.39(5) . .
C56 S12 Pd6 101.06(18) . .
C56 S12 Ag7 107.29(15) . .
Pd6 S12 Ag7 118.67(6) . .
C56 S12 Ag6 112.21(19) . .
Pd6 S12 Ag6 118.37(6) . .
Ag7 S12 Ag6 99.23(5) . .
C8 O3 La1 145.6(4) . 4_645
C18B O7B La3 146.6(5) . .
C18A O8A La2 139.5(6) . .
C23 O9 La6 117.5(4) . .
C28 O11 La1 137.0(4) . 5_765
C43 O17 La8 119.7(5) . 3_465
C48 O20 La1 139.9(3) . .
C58 O23 La8 159.5(5) . .
C58 O23 La7 165.6(5) . .
C2 N1 Pd1 115.9(3) . .
C7 N2 Pd1 115.3(3) . .
C12 N3 Pd2 114.1(4) . .
C17 N4 Pd2 115.4(4) . .
C22 N5 Pd3 114.6(3) . .
C27 N6 Pd3 113.2(3) . .
C32 N7 Pd4 112.3(3) . .
C37 N8 Pd4 119.1(4) . .
C42 N9 Pd5 117.8(3) . .
C47 N10 Pd5 113.3(3) . .
C52 N11 Pd6 118.9(3) . .
C57 N12 Pd6 115.9(4) . .
C2 C1 C4 113.4(5) . .
C2 C1 C5 111.7(5) . .
C4 C1 C5 111.3(4) . .
C2 C1 S1 105.6(4) . .
C4 C1 S1 110.2(3) . .
C5 C1 S1 104.1(4) . .
N1 C2 C1 113.1(4) . .
N1 C2 C3 112.3(5) . .
C1 C2 C3 109.6(4) . .
O2 C3 O1 124.5(6) . .
O2 C3 C2 122.5(6) . .
O1 C3 C2 112.9(5) . .
C7 C6 C10 114.7(5) . .
C7 C6 C9 114.5(4) . .
C10 C6 C9 111.6(4) . .
C7 C6 S2 106.5(3) . .
C10 C6 S2 102.9(4) . .
C9 C6 S2 105.4(3) . .
C6 C7 N2 112.4(4) . .
C6 C7 C8 114.1(4) . .
N2 C7 C8 107.6(4) . .
O4 C8 O3 129.9(6) . .
O4 C8 C7 116.1(5) . .
O3 C8 C7 113.3(5) . .
C15 C11 C14 114.4(5) . .
C15 C11 C12 113.0(5) . .
C14 C11 C12 113.1(5) . .
C15 C11 S3 108.3(4) . .
C14 C11 S3 106.2(3) . .
C12 C11 S3 100.4(3) . .
N3 C12 C11 107.5(4) . .
N3 C12 C13 107.1(5) . .
C11 C12 C13 105.7(5) . .
O5 C13 O6 129.4(4) . .
O5 C13 C12 123.3(4) . .
O6 C13 C12 107.2(4) . .
C20 C16 C19 107.2(6) . .
C20 C16 C17 115.8(6) . .
C19 C16 C17 112.8(5) . .
C20 C16 S4 105.4(5) . .
C19 C16 S4 111.1(5) . .
C17 C16 S4 104.2(4) . .
N4 C17 C16 111.8(5) . .
N4 C17 C18B 117.3(5) . .
C16 C17 C18B 117.7(5) . .
N4 C17 C18A 101.5(5) . .
C16 C17 C18A 100.8(5) . .
O8A C18A O7A 121.1(7) . .
O8A C18A C17 105.8(6) . .
O7A C18A C17 128.9(6) . .
O8B C18B O7B 124.9(7) . .
O8B C18B C17 124.1(6) . .
O7B C18B C17 105.1(6) . .
C22 C21 C25 116.7(5) . .
C22 C21 C24 112.1(5) . .
C25 C21 C24 110.6(5) . .
C22 C21 S5 104.0(4) . .
C25 C21 S5 105.4(4) . .
C24 C21 S5 107.2(4) . .
N5 C22 C21 108.6(4) . .
N5 C22 C23 109.6(4) . .
C21 C22 C23 109.0(5) . .
O9 C23 O10 130.7(6) . .
O9 C23 C22 114.1(5) . .
O10 C23 C22 113.1(5) . .
C29 C26 C27 110.9(4) . .
C29 C26 C30 110.7(4) . .
C27 C26 C30 113.7(4) . .
C29 C26 S6 110.6(4) . .
C27 C26 S6 104.5(3) . .
C30 C26 S6 106.3(3) . .
N6 C27 C26 109.8(4) . .
N6 C27 C28 108.3(4) . .
C26 C27 C28 115.3(4) . .
O11 C28 O12 131.1(5) . .
O11 C28 C27 117.9(5) . .
O12 C28 C27 110.9(5) . .
C35 C31 C32 117.5(4) . .
C35 C31 C34 111.2(4) . .
C32 C31 C34 108.1(4) . .
C35 C31 S7 109.4(3) . .
C32 C31 S7 104.8(3) . .
C34 C31 S7 105.0(3) . .
C31 C32 N7 113.7(4) . .
C31 C32 C33 115.5(4) . .
N7 C32 C33 108.5(4) . .
O13 C33 O14 124.3(5) . .
O13 C33 C32 117.9(5) . .
O14 C33 C32 117.5(5) . .
C37 C36 C39 115.7(5) . .
C37 C36 C40 112.5(5) . .
C39 C36 C40 104.0(5) . .
C37 C36 S8 110.6(4) . .
C39 C36 S8 108.0(4) . .
C40 C36 S8 105.3(4) . .
C36 C37 N8 104.1(5) . .
C36 C37 C38 114.5(6) . .
N8 C37 C38 105.6(5) . .
O15 C38 O16 125.6(6) . .
O15 C38 C37 120.9(6) . .
O16 C38 C37 112.5(6) . .
C42 C41 C44 116.7(4) . .
C42 C41 C45 109.5(4) . .
C44 C41 C45 111.2(5) . .
C42 C41 S9 105.9(4) . .
C44 C41 S9 109.2(3) . .
C45 C41 S9 103.4(4) . .
N9 C42 C41 106.0(4) . .
N9 C42 C43 109.9(5) . .
C41 C42 C43 110.0(4) . .
O17 C43 O18 131.1(7) . .
O17 C43 C42 121.8(7) . .
O18 C43 C42 107.1(6) . .
C47 C46 C50 110.4(4) . .
C47 C46 C49 113.2(4) . .
C50 C46 C49 114.4(4) . .
C47 C46 S10 102.6(3) . .
C50 C46 S10 107.1(3) . .
C49 C46 S10 108.2(4) . .
N10 C47 C46 115.2(4) . .
N10 C47 C48 108.5(4) . .
C46 C47 C48 111.7(4) . .
O19 C48 O20 124.7(5) . .
O19 C48 C47 118.0(5) . .
O20 C48 C47 117.2(4) . .
C55 C51 C52 117.5(5) . .
C55 C51 C54 109.2(5) . .
C52 C51 C54 108.4(5) . .
C55 C51 S11 106.8(4) . .
C52 C51 S11 105.9(4) . .
C54 C51 S11 108.8(4) . .
N11 C52 C53 112.3(4) . .
N11 C52 C51 111.8(4) . .
C53 C52 C51 110.8(5) . .
O21 C53 O22 125.5(6) . .
O21 C53 C52 119.3(6) . .
O22 C53 C52 115.2(5) . .
C59 C56 C57 116.6(5) . .
C59 C56 C60 114.5(6) . .
C57 C56 C60 105.1(5) . .
C59 C56 S12 108.5(5) . .
C57 C56 S12 105.2(4) . .
C60 C56 S12 106.1(4) . .
C56 C57 N12 106.4(5) . .
C56 C57 C58 111.3(5) . .
N12 C57 C58 109.3(4) . .
O24 C58 O23 131.9(5) . .
O24 C58 C57 114.8(4) . .
O23 C58 C57 110.6(4) . .
C61 O27 La1 90.5(4) . .
O28 C61 O27 120.4(8) . .
O28 C61 C62 138.4(9) . .
O27 C61 C62 100.6(6) . .
O28 C61 La1 61.4(5) . .
O27 C61 La1 59.2(4) . .
C62 C61 La1 159.7(6) . .
C61 O28 La1 99.0(6) . .
O50 La6 O44 157.1(4) 3_565 7_564
O50 La6 O9 72.7(3) 3_565 .
O44 La6 O9 87.2(3) 7_564 .
O50 La6 O49 79.8(3) 3_565 3_565
O44 La6 O49 86.0(3) 7_564 3_565
O9 La6 O49 79.5(2) . 3_565
O7B La3 La3 107.5(2) . 5_775
La7 La7 O23 136.3(3) 6_556 .
La7 La7 O44 113.1(2) 6_556 .
O23 La7 O44 85.7(3) . .
La8 La8 O23 170.0(3) 6_556 .
La8 La8 O17 100.8(3) 6_556 3_565
O23 La8 O17 85.9(3) . 3_565
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 S10 2.4892(15) .
Ag1 S3 2.4902(17) .
Ag1 S1 2.5023(16) .
Ag1 I1 3.2571(6) .
Ag2 S5 2.5082(16) .
Ag2 S2 2.5289(15) .
Ag2 S3 2.5454(16) .
Ag2 I1 2.9931(6) .
Ag3 S6 2.4951(14) .
Ag3 S2 2.5052(14) .
Ag3 S7 2.5463(15) .
Ag4 S7 2.5444(15) .
Ag4 S9 2.5480(15) .
Ag4 S1 2.5631(14) .
Ag4 I1 2.9766(6) .
Ag5 S4 2.5175(19) .
Ag5 S11 2.5316(13) .
Ag5 S10 2.5502(15) .
Ag5 I1 2.9980(6) .
Ag6 O25 2.490(6) .
Ag6 S5 2.5424(16) .
Ag6 S4 2.5456(18) .
Ag6 S12 2.5596(16) .
Ag7 S8 2.5129(17) .
Ag7 S6 2.5470(15) .
Ag7 S12 2.5560(16) .
Ag7 I1 2.9614(6) .
Ag8 S11 2.5324(15) .
Ag8 S8 2.5449(16) .
Ag8 O26 2.563(5) .
Ag8 S9 2.5633(15) .
Pd1 N1 1.996(4) .
Pd1 N2 2.060(4) .
Pd1 S1 2.2547(15) .
Pd1 S2 2.2707(15) .
Pd2 N3 2.025(5) .
Pd2 N4 2.064(5) .
Pd2 S3 2.2655(17) .
Pd2 S4 2.2771(17) .
Pd3 N6 2.038(4) .
Pd3 N5 2.065(4) .
Pd3 S6 2.2782(15) .
Pd3 S5 2.2876(15) .
Pd4 N8 2.045(4) .
Pd4 N7 2.049(4) .
Pd4 S8 2.2564(15) .
Pd4 S7 2.2565(14) .
Pd5 N9 2.052(5) .
Pd5 N10 2.109(4) .
Pd5 S10 2.2629(15) .
Pd5 S9 2.2747(15) .
Pd6 N11 2.013(4) .
Pd6 N12 2.042(5) .
Pd6 S12 2.2580(16) .
Pd6 S11 2.2661(14) .
La1 O11 2.461(3) 5_675
La1 O3 2.478(4) 4_655
La1 O20 2.514(4) .
La1 O29 2.576(4) .
La1 O32 2.588(5) .
La1 O31 2.592(5) .
La1 O30 2.600(3) .
La1 O27 2.625(6) .
La1 O28 2.717(5) .
La1 C61 3.057(9) .
S1 C1 1.869(5) .
S2 C6 1.875(5) .
S3 C11 1.892(5) .
S4 C16 1.839(7) .
S5 C21 1.860(7) .
S6 C26 1.858(5) .
S7 C31 1.887(5) .
S8 C36 1.850(6) .
S9 C41 1.867(6) .
S10 C46 1.874(5) .
S11 C51 1.910(6) .
S12 C56 1.837(6) .
O1 C3 1.235(8) .
O2 C3 1.210(8) .
O3 C8 1.257(7) .
O3 La1 2.478(4) 4_645
O4 C8 1.241(8) .
O5 C13 1.194(5) .
O6 C13 1.235(6) .
O7A C18A 1.270(8) .
O7B C18B 1.253(8) .
O7B La3 2.857(9) .
O8A C18A 1.256(9) .
O8A La2 2.176(9) .
O8B C18B 1.250(8) .
O9 C23 1.220(6) .
O9 La6 2.740(7) .
O10 C23 1.225(6) .
O11 C28 1.154(7) .
O11 La1 2.461(3) 5_765
O12 C28 1.307(7) .
O13 C33 1.250(7) .
O14 C33 1.256(7) .
O15 C38 1.227(9) .
O16 C38 1.232(9) .
O17 C43 1.170(10) .
O17 La8 2.789(9) 3_465
O18 C43 1.369(10) .
O19 C48 1.247(6) .
O20 C48 1.260(6) .
O21 C53 1.197(8) .
O22 C53 1.328(7) .
O23 C58 1.212(6) .
O23 La8 2.374(8) .
O23 La7 2.600(6) .
O24 C58 1.182(5) .
N1 C2 1.435(7) .
N2 C7 1.493(6) .
N3 C12 1.523(9) .
N4 C17 1.403(9) .
N5 C22 1.503(7) .
N6 C27 1.493(6) .
N7 C32 1.499(7) .
N8 C37 1.459(8) .
N9 C42 1.476(7) .
N10 C47 1.408(6) .
N11 C52 1.484(7) .
N12 C57 1.569(7) .
C1 C2 1.451(7) .
C1 C4 1.517(8) .
C1 C5 1.678(8) .
C2 C3 1.612(8) .
C6 C7 1.464(7) .
C6 C10 1.533(8) .
C6 C9 1.581(7) .
C7 C8 1.574(8) .
C11 C15 1.551(8) .
C11 C14 1.590(8) .
C11 C12 1.608(10) .
C12 C13 1.614(6) .
C16 C20 1.344(10) .
C16 C19 1.484(10) .
C16 C17 1.581(10) .
C17 C18B 1.604(7) .
C17 C18A 1.604(6) .
C21 C22 1.547(8) .
C21 C25 1.556(8) .
C21 C24 1.561(8) .
C22 C23 1.590(7) .
C26 C29 1.507(7) .
C26 C27 1.550(7) .
C26 C30 1.618(8) .
C27 C28 1.608(7) .
C31 C35 1.456(7) .
C31 C32 1.462(7) .
C31 C34 1.486(8) .
C32 C33 1.560(8) .
C36 C37 1.435(9) .
C36 C39 1.515(9) .
C36 C40 1.529(9) .
C37 C38 1.599(8) .
C41 C42 1.490(7) .
C41 C44 1.524(7) .
C41 C45 1.555(8) .
C42 C43 1.551(8) .
C46 C47 1.476(7) .
C46 C50 1.481(7) .
C46 C49 1.483(7) .
C47 C48 1.559(7) .
C51 C55 1.501(8) .
C51 C52 1.508(7) .
C51 C54 1.520(8) .
C52 C53 1.491(8) .
C56 C59 1.430(9) .
C56 C57 1.484(8) .
C56 C60 1.555(9) .
C57 C58 1.599(7) .
O27 C61 1.541(11) .
C61 O28 1.041(10) .
C61 C62 1.674(13) .
La6 O50 2.416(11) 3_565
La6 O44 2.620(10) 7_564
La6 O49 2.820(11) 3_565
La3 La3 2.960(9) 5_775
La4 La4 1.022(8) 5_775
La5 La5 2.727(12) 5_775
La7 La7 2.172(10) 6_556
La7 O44 2.696(11) .
La8 La8 1.996(13) 6_556
La8 O17 2.790(9) 3_565
O44 La6 2.620(10) 8_645
O49 La6 2.820(11) 3_465
O50 La6 2.416(11) 3_465
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N1 H1A O35 0.92 2.05 2.924(7) 157.8 .
N1 H1B O13 0.92 2.19 2.980(6) 143.5 5_665
N2 H2A O13 0.92 2.37 3.183(6) 147.0 5_665
N2 H2B O35 0.92 2.47 3.251(7) 142.4 .
N3 H3A O46 0.92 2.18 3.026(16) 153.3 .
N3 H3B O15 0.92 2.25 2.965(8) 134.5 7_564
N4 H4A O15 0.92 2.11 2.933(7) 148.2 7_564
N4 H4A O52 0.92 2.63 3.236(14) 124.3 7_564
N4 H4B O7A 0.92 2.14 2.716(9) 119.5 .
N4 H4B O46 0.92 2.65 3.333(16) 131.5 .
N5 H5A O22 0.92 2.36 3.105(6) 137.9 3_565
N5 H5B O37 0.92 2.38 3.245(7) 156.3 5_765
N6 H6A O30 0.92 2.27 2.990(5) 135.2 5_765
N6 H6A O28 0.92 2.37 3.133(6) 139.9 5_765
N6 H6B O33 0.92 2.16 3.050(5) 161.9 5_765
N7 H7A O5 0.92 1.89 2.660(6) 140.0 8_645
N7 H7B O1 0.92 2.31 3.161(7) 154.5 5_665
N8 H8A O42 0.92 2.50 3.260(11) 140.1 .
N8 H8B O5 0.92 2.25 2.961(6) 133.8 8_645
N9 H9A O24 0.92 2.37 3.100(7) 136.4 3_465
N9 H9A O23 0.92 2.59 3.393(7) 145.6 3_465
N4 H4B O7A 0.92 2.14 2.716(9) 119.5 .
N4 H4B O7A 0.92 2.14 2.716(9) 119.5 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
S8 Ag7 I1 Ag4 -29.93(4) . .
S6 Ag7 I1 Ag4 94.52(4) . .
S12 Ag7 I1 Ag4 -148.58(4) . .
S8 Ag7 I1 Ag2 -147.35(4) . .
S6 Ag7 I1 Ag2 -22.90(4) . .
S12 Ag7 I1 Ag2 94.00(4) . .
S8 Ag7 I1 Ag5 91.21(4) . .
S6 Ag7 I1 Ag5 -144.34(4) . .
S12 Ag7 I1 Ag5 -27.44(4) . .
S7 Ag4 I1 Ag7 -30.82(4) . .
S9 Ag4 I1 Ag7 87.45(4) . .
S1 Ag4 I1 Ag7 -147.53(4) . .
S7 Ag4 I1 Ag2 87.83(3) . .
S9 Ag4 I1 Ag2 -153.91(3) . .
S1 Ag4 I1 Ag2 -28.89(4) . .
S7 Ag4 I1 Ag5 -153.25(3) . .
S9 Ag4 I1 Ag5 -34.98(4) . .
S1 Ag4 I1 Ag5 90.03(4) . .
S7 Ag4 I1 Ag1 149.47(3) . .
S9 Ag4 I1 Ag1 -92.26(3) . .
S1 Ag4 I1 Ag1 32.76(3) . .
S5 Ag2 I1 Ag7 -35.60(4) . .
S2 Ag2 I1 Ag7 90.80(4) . .
S3 Ag2 I1 Ag7 -150.66(4) . .
S5 Ag2 I1 Ag4 -154.17(4) . .
S2 Ag2 I1 Ag4 -27.76(4) . .
S3 Ag2 I1 Ag4 90.77(4) . .
S5 Ag2 I1 Ag5 87.02(4) . .
S2 Ag2 I1 Ag5 -146.57(3) . .
S3 Ag2 I1 Ag5 -28.04(4) . .
S5 Ag2 I1 Ag1 147.12(4) . .
S2 Ag2 I1 Ag1 -86.47(3) . .
S3 Ag2 I1 Ag1 32.06(4) . .
S4 Ag5 I1 Ag7 89.89(4) . .
S11 Ag5 I1 Ag7 -31.10(4) . .
S10 Ag5 I1 Ag7 -144.49(4) . .
S4 Ag5 I1 Ag4 -149.04(4) . .
S11 Ag5 I1 Ag4 89.97(4) . .
S10 Ag5 I1 Ag4 -23.42(4) . .
S4 Ag5 I1 Ag2 -31.45(4) . .
S11 Ag5 I1 Ag2 -152.44(4) . .
S10 Ag5 I1 Ag2 94.17(4) . .
S4 Ag5 I1 Ag1 -93.05(4) . .
S11 Ag5 I1 Ag1 145.96(4) . .
S10 Ag5 I1 Ag1 32.57(3) . .
S10 Ag1 I1 Ag4 88.68(4) . .
S3 Ag1 I1 Ag4 -151.33(4) . .
S1 Ag1 I1 Ag4 -33.60(3) . .
S10 Ag1 I1 Ag2 -153.13(4) . .
S3 Ag1 I1 Ag2 -33.15(4) . .
S1 Ag1 I1 Ag2 84.58(4) . .
S10 Ag1 I1 Ag5 -33.60(4) . .
S3 Ag1 I1 Ag5 86.38(4) . .
S1 Ag1 I1 Ag5 -155.89(4) . .
N1 Pd1 S1 C1 8.6(2) . .
S2 Pd1 S1 C1 -176.50(17) . .
N1 Pd1 S1 Ag1 -124.94(15) . .
S2 Pd1 S1 Ag1 49.99(8) . .
N1 Pd1 S1 Ag4 129.47(14) . .
S2 Pd1 S1 Ag4 -55.60(7) . .
S10 Ag1 S1 C1 67.06(19) . .
S3 Ag1 S1 C1 -129.22(19) . .
I1 Ag1 S1 C1 150.34(19) . .
S10 Ag1 S1 Pd1 -166.59(6) . .
S3 Ag1 S1 Pd1 -2.87(9) . .
I1 Ag1 S1 Pd1 -83.31(7) . .
S10 Ag1 S1 Ag4 -46.75(6) . .
S3 Ag1 S1 Ag4 116.98(5) . .
I1 Ag1 S1 Ag4 36.53(3) . .
S7 Ag4 S1 C1 112.3(2) . .
S9 Ag4 S1 C1 -64.5(2) . .
I1 Ag4 S1 C1 -159.00(19) . .
S7 Ag4 S1 Pd1 -1.23(8) . .
S9 Ag4 S1 Pd1 -178.00(6) . .
I1 Ag4 S1 Pd1 87.51(6) . .
S7 Ag4 S1 Ag1 -129.46(5) . .
S9 Ag4 S1 Ag1 53.77(6) . .
I1 Ag4 S1 Ag1 -40.72(4) . .
N2 Pd1 S2 C6 17.3(2) . .
S1 Pd1 S2 C6 -165.85(16) . .
N2 Pd1 S2 Ag3 -112.37(13) . .
S1 Pd1 S2 Ag3 64.48(7) . .
N2 Pd1 S2 Ag2 140.92(13) . .
S1 Pd1 S2 Ag2 -42.22(8) . .
S6 Ag3 S2 C6 73.17(19) . .
S7 Ag3 S2 C6 -131.04(18) . .
S6 Ag3 S2 Pd1 -166.52(6) . .
S7 Ag3 S2 Pd1 -10.73(9) . .
S6 Ag3 S2 Ag2 -41.19(7) . .
S7 Ag3 S2 Ag2 114.60(5) . .
S5 Ag2 S2 C6 -68.98(18) . .
S3 Ag2 S2 C6 107.50(18) . .
I1 Ag2 S2 C6 -163.40(17) . .
S5 Ag2 S2 Pd1 174.48(6) . .
S3 Ag2 S2 Pd1 -9.03(9) . .
I1 Ag2 S2 Pd1 80.07(6) . .
S5 Ag2 S2 Ag3 50.23(7) . .
S3 Ag2 S2 Ag3 -133.29(5) . .
I1 Ag2 S2 Ag3 -44.19(4) . .
N3 Pd2 S3 C11 13.0(2) . .
S4 Pd2 S3 C11 -173.45(18) . .
N3 Pd2 S3 Ag1 -108.02(18) . .
S4 Pd2 S3 Ag1 65.56(8) . .
N3 Pd2 S3 Ag2 134.85(18) . .
S4 Pd2 S3 Ag2 -51.57(8) . .
S10 Ag1 S3 C11 -128.9(2) . .
S1 Ag1 S3 C11 66.8(2) . .
I1 Ag1 S3 C11 150.9(2) . .
S10 Ag1 S3 Pd2 -12.35(9) . .
S1 Ag1 S3 Pd2 -176.60(6) . .
I1 Ag1 S3 Pd2 -92.52(6) . .
S10 Ag1 S3 Ag2 118.05(5) . .
S1 Ag1 S3 Ag2 -46.20(6) . .
I1 Ag1 S3 Ag2 37.88(3) . .
S5 Ag2 S3 C11 116.1(2) . .
S2 Ag2 S3 C11 -60.8(2) . .
I1 Ag2 S3 C11 -154.5(2) . .
S5 Ag2 S3 Pd2 -1.50(9) . .
S2 Ag2 S3 Pd2 -178.36(6) . .
I1 Ag2 S3 Pd2 87.97(7) . .
S5 Ag2 S3 Ag1 -131.01(5) . .
S2 Ag2 S3 Ag1 52.13(6) . .
I1 Ag2 S3 Ag1 -41.54(4) . .
N4 Pd2 S4 C16 20.0(3) . .
S3 Pd2 S4 C16 -167.3(2) . .
N4 Pd2 S4 Ag5 133.89(17) . .
S3 Pd2 S4 Ag5 -53.41(7) . .
N4 Pd2 S4 Ag6 -110.38(18) . .
S3 Pd2 S4 Ag6 62.32(9) . .
S11 Ag5 S4 C16 -75.4(2) . .
S10 Ag5 S4 C16 102.7(2) . .
I1 Ag5 S4 C16 -166.0(2) . .
S11 Ag5 S4 Pd2 178.01(5) . .
S10 Ag5 S4 Pd2 -3.97(10) . .
I1 Ag5 S4 Pd2 87.42(6) . .
S11 Ag5 S4 Ag6 48.06(7) . .
S10 Ag5 S4 Ag6 -133.91(5) . .
I1 Ag5 S4 Ag6 -42.53(5) . .
O25 Ag6 S4 C16 -27.9(3) . .
S5 Ag6 S4 C16 -138.1(2) . .
S12 Ag6 S4 C16 83.3(3) . .
O25 Ag6 S4 Pd2 93.26(15) . .
S5 Ag6 S4 Pd2 -16.97(10) . .
S12 Ag6 S4 Pd2 -155.60(7) . .
O25 Ag6 S4 Ag5 -144.27(14) . .
S5 Ag6 S4 Ag5 105.49(6) . .
S12 Ag6 S4 Ag5 -33.14(7) . .
N5 Pd3 S5 C21 13.6(2) . .
S6 Pd3 S5 C21 -168.10(19) . .
N5 Pd3 S5 Ag2 131.97(14) . .
S6 Pd3 S5 Ag2 -49.69(7) . .
N5 Pd3 S5 Ag6 -108.05(14) . .
S6 Pd3 S5 Ag6 70.29(7) . .
S2 Ag2 S5 C21 104.4(2) . .
S3 Ag2 S5 C21 -72.2(2) . .
I1 Ag2 S5 C21 -159.2(2) . .
S2 Ag2 S5 Pd3 -8.41(10) . .
S3 Ag2 S5 Pd3 174.99(6) . .
I1 Ag2 S5 Pd3 87.96(6) . .
S2 Ag2 S5 Ag6 -135.38(5) . .
S3 Ag2 S5 Ag6 48.03(7) . .
I1 Ag2 S5 Ag6 -39.01(4) . .
O25 Ag6 S5 C21 -28.3(3) . .
S4 Ag6 S5 C21 78.9(2) . .
S12 Ag6 S5 C21 -143.3(2) . .
O25 Ag6 S5 Pd3 86.09(15) . .
S4 Ag6 S5 Pd3 -166.72(6) . .
S12 Ag6 S5 Pd3 -28.92(9) . .
O25 Ag6 S5 Ag2 -146.49(14) . .
S4 Ag6 S5 Ag2 -39.29(7) . .
S12 Ag6 S5 Ag2 98.50(6) . .
N6 Pd3 S6 C26 4.4(2) . .
S5 Pd3 S6 C26 -177.38(17) . .
N6 Pd3 S6 Ag3 -119.71(12) . .
S5 Pd3 S6 Ag3 58.49(7) . .
N6 Pd3 S6 Ag7 129.48(12) . .
S5 Pd3 S6 Ag7 -52.32(7) . .
S2 Ag3 S6 C26 -127.67(19) . .
S7 Ag3 S6 C26 77.09(19) . .
S2 Ag3 S6 Pd3 -9.77(9) . .
S7 Ag3 S6 Pd3 -165.01(6) . .
S2 Ag3 S6 Ag7 115.63(6) . .
S7 Ag3 S6 Ag7 -39.61(6) . .
S8 Ag7 S6 C26 -64.3(2) . .
S12 Ag7 S6 C26 112.56(19) . .
I1 Ag7 S6 C26 -157.38(19) . .
S8 Ag7 S6 Pd3 176.31(5) . .
S12 Ag7 S6 Pd3 -6.81(8) . .
I1 Ag7 S6 Pd3 83.25(6) . .
S8 Ag7 S6 Ag3 52.69(6) . .
S12 Ag7 S6 Ag3 -130.42(5) . .
I1 Ag7 S6 Ag3 -40.36(4) . .
N7 Pd4 S7 C31 9.6(2) . .
S8 Pd4 S7 C31 -176.03(16) . .
N7 Pd4 S7 Ag4 127.95(14) . .
S8 Pd4 S7 Ag4 -57.68(7) . .
N7 Pd4 S7 Ag3 -113.62(14) . .
S8 Pd4 S7 Ag3 60.75(8) . .
S9 Ag4 S7 C31 113.20(17) . .
S1 Ag4 S7 C31 -63.79(18) . .
I1 Ag4 S7 C31 -156.44(17) . .
S9 Ag4 S7 Pd4 1.25(8) . .
S1 Ag4 S7 Pd4 -175.74(6) . .
I1 Ag4 S7 Pd4 91.61(6) . .
S9 Ag4 S7 Ag3 -131.41(5) . .
S1 Ag4 S7 Ag3 51.60(6) . .
I1 Ag4 S7 Ag3 -41.04(4) . .
S6 Ag3 S7 C31 -131.02(16) . .
S2 Ag3 S7 C31 70.61(17) . .
S6 Ag3 S7 Pd4 -12.64(9) . .
S2 Ag3 S7 Pd4 -171.01(6) . .
S6 Ag3 S7 Ag4 113.34(5) . .
S2 Ag3 S7 Ag4 -45.03(6) . .
N8 Pd4 S8 C36 14.6(2) . .
S7 Pd4 S8 C36 -164.9(2) . .
N8 Pd4 S8 Ag7 132.92(15) . .
S7 Pd4 S8 Ag7 -46.65(7) . .
N8 Pd4 S8 Ag8 -107.35(16) . .
S7 Pd4 S8 Ag8 73.08(8) . .
S6 Ag7 S8 C36 100.0(2) . .
S12 Ag7 S8 C36 -76.8(2) . .
I1 Ag7 S8 C36 -166.8(2) . .
S6 Ag7 S8 Pd4 -8.74(9) . .
S12 Ag7 S8 Pd4 174.43(6) . .
I1 Ag7 S8 Pd4 84.43(6) . .
S6 Ag7 S8 Ag8 -139.05(5) . .
S12 Ag7 S8 Ag8 44.12(6) . .
I1 Ag7 S8 Ag8 -45.88(4) . .
S11 Ag8 S8 C36 92.9(2) . .
O26 Ag8 S8 C36 -22.5(3) . .
S9 Ag8 S8 C36 -135.6(2) . .
S11 Ag8 S8 Pd4 -154.32(6) . .
O26 Ag8 S8 Pd4 90.26(14) . .
S9 Ag8 S8 Pd4 -22.90(8) . .
S11 Ag8 S8 Ag7 -26.86(6) . .
O26 Ag8 S8 Ag7 -142.28(13) . .
S9 Ag8 S8 Ag7 104.56(5) . .
N9 Pd5 S9 C41 15.9(2) . .
S10 Pd5 S9 C41 -169.50(17) . .
N9 Pd5 S9 Ag4 133.74(15) . .
S10 Pd5 S9 Ag4 -51.70(7) . .
N9 Pd5 S9 Ag8 -106.16(15) . .
S10 Pd5 S9 Ag8 68.41(7) . .
S7 Ag4 S9 C41 -74.08(18) . .
S1 Ag4 S9 C41 102.65(18) . .
I1 Ag4 S9 C41 -161.83(18) . .
S7 Ag4 S9 Pd5 176.32(5) . .
S1 Ag4 S9 Pd5 -6.96(9) . .
I1 Ag4 S9 Pd5 88.57(6) . .
S7 Ag4 S9 Ag8 46.81(7) . .
S1 Ag4 S9 Ag8 -136.46(5) . .
I1 Ag4 S9 Ag8 -40.94(4) . .
S11 Ag8 S9 C41 -141.1(2) . .
S8 Ag8 S9 C41 84.7(2) . .
O26 Ag8 S9 C41 -28.8(2) . .
S11 Ag8 S9 Pd5 -26.88(8) . .
S8 Ag8 S9 Pd5 -161.08(6) . .
O26 Ag8 S9 Pd5 85.44(15) . .
S11 Ag8 S9 Ag4 99.01(6) . .
S8 Ag8 S9 Ag4 -35.20(7) . .
O26 Ag8 S9 Ag4 -148.68(14) . .
N10 Pd5 S10 C46 11.0(2) . .
S9 Pd5 S10 C46 -177.51(17) . .
N10 Pd5 S10 Ag1 -111.26(13) . .
S9 Pd5 S10 Ag1 60.25(7) . .
N10 Pd5 S10 Ag5 137.51(13) . .
S9 Pd5 S10 Ag5 -50.98(7) . .
S3 Ag1 S10 C46 74.26(19) . .
S1 Ag1 S10 C46 -122.28(18) . .
I1 Ag1 S10 C46 152.73(18) . .
S3 Ag1 S10 Pd5 -168.27(6) . .
S1 Ag1 S10 Pd5 -4.80(9) . .
I1 Ag1 S10 Pd5 -89.79(6) . .
S3 Ag1 S10 Ag5 -40.83(6) . .
S1 Ag1 S10 Ag5 122.63(5) . .
I1 Ag1 S10 Ag5 37.64(3) . .
S4 Ag5 S10 C46 -61.98(19) . .
S11 Ag5 S10 C46 116.18(18) . .
I1 Ag5 S10 C46 -154.57(18) . .
S4 Ag5 S10 Pd5 176.83(6) . .
S11 Ag5 S10 Pd5 -5.01(9) . .
I1 Ag5 S10 Pd5 84.24(6) . .
S4 Ag5 S10 Ag1 51.20(7) . .
S11 Ag5 S10 Ag1 -130.64(5) . .
I1 Ag5 S10 Ag1 -41.39(4) . .
N11 Pd6 S11 C51 13.2(2) . .
S12 Pd6 S11 C51 -169.02(18) . .
N11 Pd6 S11 Ag5 129.62(14) . .
S12 Pd6 S11 Ag5 -52.58(7) . .
N11 Pd6 S11 Ag8 -107.56(14) . .
S12 Pd6 S11 Ag8 70.24(7) . .
S4 Ag5 S11 C51 106.0(2) . .
S10 Ag5 S11 C51 -72.3(2) . .
I1 Ag5 S11 C51 -161.82(19) . .
S4 Ag5 S11 Pd6 -5.50(9) . .
S10 Ag5 S11 Pd6 176.25(6) . .
I1 Ag5 S11 Pd6 86.69(6) . .
S4 Ag5 S11 Ag8 -134.15(6) . .
S10 Ag5 S11 Ag8 47.60(7) . .
I1 Ag5 S11 Ag8 -41.96(4) . .
S8 Ag8 S11 C51 -145.19(18) . .
O26 Ag8 S11 C51 -28.9(2) . .
S9 Ag8 S11 C51 84.19(18) . .
S8 Ag8 S11 Pd6 -31.29(8) . .
O26 Ag8 S11 Pd6 85.05(14) . .
S9 Ag8 S11 Pd6 -161.90(6) . .
S8 Ag8 S11 Ag5 97.39(6) . .
O26 Ag8 S11 Ag5 -146.27(13) . .
S9 Ag8 S11 Ag5 -33.22(7) . .
N12 Pd6 S12 C56 15.0(2) . .
S11 Pd6 S12 C56 -168.07(17) . .
N12 Pd6 S12 Ag7 131.92(16) . .
S11 Pd6 S12 Ag7 -51.20(7) . .
N12 Pd6 S12 Ag6 -107.87(16) . .
S11 Pd6 S12 Ag6 69.02(7) . .
S8 Ag7 S12 C56 107.0(2) . .
S6 Ag7 S12 C56 -70.0(2) . .
I1 Ag7 S12 C56 -161.6(2) . .
S8 Ag7 S12 Pd6 -6.51(9) . .
S6 Ag7 S12 Pd6 176.42(6) . .
I1 Ag7 S12 Pd6 84.83(6) . .
S8 Ag7 S12 Ag6 -136.12(5) . .
S6 Ag7 S12 Ag6 46.81(7) . .
I1 Ag7 S12 Ag6 -44.78(4) . .
O25 Ag6 S12 C56 -32.6(2) . .
S5 Ag6 S12 C56 82.56(17) . .
S4 Ag6 S12 C56 -140.95(17) . .
O25 Ag6 S12 Pd6 84.57(15) . .
S5 Ag6 S12 Pd6 -160.31(6) . .
S4 Ag6 S12 Pd6 -23.82(9) . .
O25 Ag6 S12 Ag7 -145.61(14) . .
S5 Ag6 S12 Ag7 -30.50(7) . .
S4 Ag6 S12 Ag7 105.99(6) . .
O11 La1 O20 C48 46.8(6) 5_675 .
O3 La1 O20 C48 -165.0(5) 4_655 .
O29 La1 O20 C48 -63.2(5) . .
O32 La1 O20 C48 -108.3(5) . .
O31 La1 O20 C48 176.6(6) . .
O30 La1 O20 C48 -15.0(5) . .
O27 La1 O20 C48 104.2(5) . .
O28 La1 O20 C48 52.6(5) . .
C61 La1 O20 C48 73.2(5) . .
N2 Pd1 N1 C2 -166.5(4) . .
S1 Pd1 N1 C2 17.0(4) . .
N1 Pd1 N2 C7 -178.6(3) . .
S2 Pd1 N2 C7 6.7(3) . .
N4 Pd2 N3 C12 -168.3(5) . .
S3 Pd2 N3 C12 19.4(4) . .
N3 Pd2 N4 C17 -179.3(5) . .
S4 Pd2 N4 C17 7.5(4) . .
N6 Pd3 N5 C22 -165.7(4) . .
S5 Pd3 N5 C22 16.2(3) . .
N5 Pd3 N6 C27 -157.0(3) . .
S6 Pd3 N6 C27 24.8(3) . .
N8 Pd4 N7 C32 -163.8(3) . .
S7 Pd4 N7 C32 16.0(3) . .
N7 Pd4 N8 C37 -172.5(4) . .
S8 Pd4 N8 C37 13.0(4) . .
N10 Pd5 N9 C42 -175.0(4) . .
S9 Pd5 N9 C42 13.5(4) . .
N9 Pd5 N10 C47 -169.6(3) . .
S10 Pd5 N10 C47 16.0(3) . .
N12 Pd6 N11 C52 -172.8(4) . .
S11 Pd6 N11 C52 10.4(4) . .
N11 Pd6 N12 C57 -168.8(4) . .
S12 Pd6 N12 C57 13.7(4) . .
Pd1 S1 C1 C2 -32.3(4) . .
Ag1 S1 C1 C2 106.1(4) . .
Ag4 S1 C1 C2 -155.6(3) . .
Pd1 S1 C1 C4 90.5(4) . .
Ag1 S1 C1 C4 -131.1(3) . .
Ag4 S1 C1 C4 -32.8(4) . .
Pd1 S1 C1 C5 -150.0(3) . .
Ag1 S1 C1 C5 -11.7(4) . .
Ag4 S1 C1 C5 86.7(3) . .
Pd1 N1 C2 C1 -46.1(6) . .
Pd1 N1 C2 C3 -170.8(3) . .
C4 C1 C2 N1 -70.3(6) . .
C5 C1 C2 N1 162.9(5) . .
S1 C1 C2 N1 50.5(5) . .
C4 C1 C2 C3 55.9(6) . .
C5 C1 C2 C3 -70.9(6) . .
S1 C1 C2 C3 176.6(4) . .
N1 C2 C3 O2 -153.2(6) . .
C1 C2 C3 O2 80.2(7) . .
N1 C2 C3 O1 29.9(7) . .
C1 C2 C3 O1 -96.7(6) . .
Pd1 S2 C6 C7 -40.8(3) . .
Ag3 S2 C6 C7 90.4(3) . .
Ag2 S2 C6 C7 -170.6(3) . .
Pd1 S2 C6 C10 -161.8(4) . .
Ag3 S2 C6 C10 -30.5(4) . .
Ag2 S2 C6 C10 68.5(4) . .
Pd1 S2 C6 C9 81.1(3) . .
Ag3 S2 C6 C9 -147.6(3) . .
Ag2 S2 C6 C9 -48.6(3) . .
C10 C6 C7 N2 165.0(4) . .
C9 C6 C7 N2 -64.1(5) . .
S2 C6 C7 N2 51.9(5) . .
C10 C6 C7 C8 -72.1(6) . .
C9 C6 C7 C8 58.8(6) . .
S2 C6 C7 C8 174.8(4) . .
Pd1 N2 C7 C6 -37.6(5) . .
Pd1 N2 C7 C8 -164.1(3) . .
La1 O3 C8 O4 -14.4(12) 4_645 .
La1 O3 C8 C7 155.5(5) 4_645 .
C6 C7 C8 O4 65.3(7) . .
N2 C7 C8 O4 -169.2(5) . .
C6 C7 C8 O3 -106.1(6) . .
N2 C7 C8 O3 19.4(6) . .
Pd2 S3 C11 C15 -158.9(3) . .
Ag1 S3 C11 C15 -30.9(4) . .
Ag2 S3 C11 C15 71.5(4) . .
Pd2 S3 C11 C14 77.8(4) . .
Ag1 S3 C11 C14 -154.2(3) . .
Ag2 S3 C11 C14 -51.8(4) . .
Pd2 S3 C11 C12 -40.2(4) . .
Ag1 S3 C11 C12 87.8(4) . .
Ag2 S3 C11 C12 -169.8(3) . .
Pd2 N3 C12 C11 -52.7(5) . .
Pd2 N3 C12 C13 -165.9(4) . .
C15 C11 C12 N3 173.8(4) . .
C14 C11 C12 N3 -54.1(5) . .
S3 C11 C12 N3 58.6(5) . .
C15 C11 C12 C13 -72.0(6) . .
C14 C11 C12 C13 60.0(6) . .
S3 C11 C12 C13 172.7(4) . .
N3 C12 C13 O5 19.9(8) . .
C11 C12 C13 O5 -94.6(7) . .
N3 C12 C13 O6 -155.7(5) . .
C11 C12 C13 O6 89.9(6) . .
Pd2 S4 C16 C20 -164.9(5) . .
Ag5 S4 C16 C20 78.8(5) . .
Ag6 S4 C16 C20 -31.6(6) . .
Pd2 S4 C16 C19 79.3(4) . .
Ag5 S4 C16 C19 -37.0(5) . .
Ag6 S4 C16 C19 -147.4(4) . .
Pd2 S4 C16 C17 -42.5(4) . .
Ag5 S4 C16 C17 -158.8(4) . .
Ag6 S4 C16 C17 90.8(4) . .
Pd2 N4 C17 C16 -39.3(6) . .
Pd2 N4 C17 C18B -179.7(5) . .
Pd2 N4 C17 C18A -146.1(4) . .
C20 C16 C17 N4 170.8(6) . .
C19 C16 C17 N4 -65.1(6) . .
S4 C16 C17 N4 55.5(5) . .
C20 C16 C17 C18B -49.0(9) . .
C19 C16 C17 C18B 75.1(8) . .
S4 C16 C17 C18B -164.2(5) . .
C20 C16 C17 C18A -82.0(7) . .
C19 C16 C17 C18A 42.1(7) . .
S4 C16 C17 C18A 162.8(4) . .
La2 O8A C18A O7A 1.3(14) . .
La2 O8A C18A C17 160.1(6) . .
N4 C17 C18A O8A -146.5(6) . .
C16 C17 C18A O8A 98.3(7) . .
C18B C17 C18A O8A -24.9(5) . .
N4 C17 C18A O7A 10.1(10) . .
C16 C17 C18A O7A -105.1(9) . .
C18B C17 C18A O7A 131.7(11) . .
La3 O7B C18B O8B 9.5(18) . .
La3 O7B C18B C17 163.1(8) . .
N4 C17 C18B O8B -169.2(8) . .
C16 C17 C18B O8B 52.7(11) . .
C18A C17 C18B O8B 120.7(11) . .
N4 C17 C18B O7B 36.8(9) . .
C16 C17 C18B O7B -101.2(7) . .
C18A C17 C18B O7B -33.2(6) . .
Pd3 S5 C21 C22 -40.3(4) . .
Ag2 S5 C21 C22 -163.3(3) . .
Ag6 S5 C21 C22 83.2(4) . .
Pd3 S5 C21 C25 -163.6(4) . .
Ag2 S5 C21 C25 73.4(4) . .
Ag6 S5 C21 C25 -40.1(4) . .
Pd3 S5 C21 C24 78.5(4) . .
Ag2 S5 C21 C24 -44.4(4) . .
Ag6 S5 C21 C24 -157.9(3) . .
Pd3 N5 C22 C21 -48.3(5) . .
Pd3 N5 C22 C23 -167.2(4) . .
C25 C21 C22 N5 172.7(5) . .
C24 C21 C22 N5 -58.3(6) . .
S5 C21 C22 N5 57.2(5) . .
C25 C21 C22 C23 -67.9(6) . .
C24 C21 C22 C23 61.1(6) . .
S5 C21 C22 C23 176.5(4) . .
La6 O9 C23 O10 -13.1(14) . .
La6 O9 C23 C22 -175.2(4) . .
N5 C22 C23 O9 17.5(9) . .
C21 C22 C23 O9 -101.2(8) . .
N5 C22 C23 O10 -147.8(7) . .
C21 C22 C23 O10 93.5(8) . .
Pd3 S6 C26 C29 88.6(4) . .
Ag3 S6 C26 C29 -144.8(3) . .
Ag7 S6 C26 C29 -40.6(4) . .
Pd3 S6 C26 C27 -30.7(3) . .
Ag3 S6 C26 C27 95.9(3) . .
Ag7 S6 C26 C27 -160.0(3) . .
Pd3 S6 C26 C30 -151.2(3) . .
Ag3 S6 C26 C30 -24.6(4) . .
Ag7 S6 C26 C30 79.6(3) . .
Pd3 N6 C27 C26 -53.4(4) . .
Pd3 N6 C27 C28 179.9(3) . .
C29 C26 C27 N6 -65.8(5) . .
C30 C26 C27 N6 168.8(4) . .
S6 C26 C27 N6 53.4(4) . .
C29 C26 C27 C28 56.8(6) . .
C30 C26 C27 C28 -68.6(5) . .
S6 C26 C27 C28 176.0(4) . .
La1 O11 C28 O12 83.3(8) 5_765 .
La1 O11 C28 C27 -99.5(6) 5_765 .
N6 C27 C28 O11 12.6(7) . .
C26 C27 C28 O11 -110.8(6) . .
N6 C27 C28 O12 -169.6(4) . .
C26 C27 C28 O12 67.0(6) . .
Pd4 S7 C31 C35 -161.2(3) . .
Ag4 S7 C31 C35 78.0(4) . .
Ag3 S7 C31 C35 -29.0(4) . .
Pd4 S7 C31 C32 -34.4(3) . .
Ag4 S7 C31 C32 -155.2(3) . .
Ag3 S7 C31 C32 97.8(3) . .
Pd4 S7 C31 C34 79.4(3) . .
Ag4 S7 C31 C34 -41.4(3) . .
Ag3 S7 C31 C34 -148.4(3) . .
C35 C31 C32 N7 174.7(4) . .
C34 C31 C32 N7 -58.5(5) . .
S7 C31 C32 N7 53.1(5) . .
C35 C31 C32 C33 -58.8(6) . .
C34 C31 C32 C33 67.9(6) . .
S7 C31 C32 C33 179.5(4) . .
Pd4 N7 C32 C31 -46.8(5) . .
Pd4 N7 C32 C33 -176.8(3) . .
C31 C32 C33 O13 -99.0(6) . .
N7 C32 C33 O13 30.0(6) . .
C31 C32 C33 O14 75.1(6) . .
N7 C32 C33 O14 -155.8(5) . .
Pd4 S8 C36 C37 -44.1(5) . .
Ag7 S8 C36 C37 -165.1(4) . .
Ag8 S8 C36 C37 82.5(5) . .
Pd4 S8 C36 C39 83.4(4) . .
Ag7 S8 C36 C39 -37.6(5) . .
Ag8 S8 C36 C39 -150.0(4) . .
Pd4 S8 C36 C40 -166.0(4) . .
Ag7 S8 C36 C40 73.1(4) . .
Ag8 S8 C36 C40 -39.3(5) . .
C39 C36 C37 N8 -66.9(6) . .
C40 C36 C37 N8 173.8(5) . .
S8 C36 C37 N8 56.3(5) . .
C39 C36 C37 C38 47.8(7) . .
C40 C36 C37 C38 -71.5(7) . .
S8 C36 C37 C38 171.0(5) . .
Pd4 N8 C37 C36 -43.4(6) . .
Pd4 N8 C37 C38 -164.3(4) . .
C36 C37 C38 O15 -89.3(9) . .
N8 C37 C38 O15 24.6(9) . .
C36 C37 C38 O16 79.9(9) . .
N8 C37 C38 O16 -166.3(7) . .
Pd5 S9 C41 C42 -44.4(3) . .
Ag4 S9 C41 C42 -163.7(3) . .
Ag8 S9 C41 C42 82.2(3) . .
Pd5 S9 C41 C44 82.1(4) . .
Ag4 S9 C41 C44 -37.3(4) . .
Ag8 S9 C41 C44 -151.4(3) . .
Pd5 S9 C41 C45 -159.5(3) . .
Ag4 S9 C41 C45 81.2(4) . .
Ag8 S9 C41 C45 -33.0(4) . .
Pd5 N9 C42 C41 -46.3(5) . .
Pd5 N9 C42 C43 -165.1(4) . .
C44 C41 C42 N9 -63.8(6) . .
C45 C41 C42 N9 168.8(4) . .
S9 C41 C42 N9 57.9(4) . .
C44 C41 C42 C43 55.0(6) . .
C45 C41 C42 C43 -72.4(6) . .
S9 C41 C42 C43 176.7(4) . .
La8 O17 C43 O18 105.4(8) 3_465 .
La8 O17 C43 C42 -76.6(7) 3_465 .
N9 C42 C43 O17 30.2(8) . .
C41 C42 C43 O17 -86.1(8) . .
N9 C42 C43 O18 -151.4(5) . .
C41 C42 C43 O18 92.3(6) . .
Pd5 S10 C46 C47 -35.0(3) . .
Ag1 S10 C46 C47 92.9(3) . .
Ag5 S10 C46 C47 -166.9(3) . .
Pd5 S10 C46 C50 -151.3(3) . .
Ag1 S10 C46 C50 -23.4(4) . .
Ag5 S10 C46 C50 76.8(4) . .
Pd5 S10 C46 C49 84.9(4) . .
Ag1 S10 C46 C49 -147.3(3) . .
Ag5 S10 C46 C49 -47.0(4) . .
Pd5 N10 C47 C46 -48.4(5) . .
Pd5 N10 C47 C48 -174.4(3) . .
C50 C46 C47 N10 168.8(4) . .
C49 C46 C47 N10 -61.5(6) . .
S10 C46 C47 N10 54.9(5) . .
C50 C46 C47 C48 -66.9(5) . .
C49 C46 C47 C48 62.8(6) . .
S10 C46 C47 C48 179.2(3) . .
La1 O20 C48 O19 8.9(9) . .
La1 O20 C48 C47 -171.3(3) . .
N10 C47 C48 O19 18.9(6) . .
C46 C47 C48 O19 -109.1(5) . .
N10 C47 C48 O20 -160.9(4) . .
C46 C47 C48 O20 71.1(6) . .
Pd6 S11 C51 C55 -160.7(4) . .
Ag5 S11 C51 C55 77.5(4) . .
Ag8 S11 C51 C55 -37.4(4) . .
Pd6 S11 C51 C52 -34.7(4) . .
Ag5 S11 C51 C52 -156.5(3) . .
Ag8 S11 C51 C52 88.6(4) . .
Pd6 S11 C51 C54 81.6(4) . .
Ag5 S11 C51 C54 -40.2(4) . .
Ag8 S11 C51 C54 -155.1(3) . .
Pd6 N11 C52 C53 -163.4(4) . .
Pd6 N11 C52 C51 -38.1(6) . .
C55 C51 C52 N11 165.5(5) . .
C54 C51 C52 N11 -70.3(6) . .
S11 C51 C52 N11 46.3(5) . .
C55 C51 C52 C53 -68.4(7) . .
C54 C51 C52 C53 55.8(6) . .
S11 C51 C52 C53 172.5(4) . .
N11 C52 C53 O21 23.3(7) . .
C51 C52 C53 O21 -102.5(6) . .
N11 C52 C53 O22 -156.3(4) . .
C51 C52 C53 O22 77.9(6) . .
Pd6 S12 C56 C59 81.9(4) . .
Ag7 S12 C56 C59 -43.0(5) . .
Ag6 S12 C56 C59 -151.0(4) . .
Pd6 S12 C56 C57 -43.5(4) . .
Ag7 S12 C56 C57 -168.5(3) . .
Ag6 S12 C56 C57 83.5(4) . .
Pd6 S12 C56 C60 -154.6(4) . .
Ag7 S12 C56 C60 80.5(4) . .
Ag6 S12 C56 C60 -27.5(4) . .
C59 C56 C57 N12 -64.2(7) . .
C60 C56 C57 N12 167.9(5) . .
S12 C56 C57 N12 56.1(5) . .
C59 C56 C57 C58 54.8(7) . .
C60 C56 C57 C58 -73.1(6) . .
S12 C56 C57 C58 175.1(3) . .
Pd6 N12 C57 C56 -45.9(5) . .
Pd6 N12 C57 C58 -166.2(4) . .
La8 O23 C58 O24 35.0(19) . .
La7 O23 C58 O24 -98.6(17) . .
La8 O23 C58 C57 -125.1(11) . .
La7 O23 C58 C57 101.3(15) . .
C56 C57 C58 O24 84.4(7) . .
N12 C57 C58 O24 -158.4(6) . .
C56 C57 C58 O23 -111.8(6) . .
N12 C57 C58 O23 5.4(8) . .
O11 La1 O27 C61 68.4(4) 5_675 .
O3 La1 O27 C61 144.0(4) 4_655 .
O20 La1 O27 C61 -76.6(4) . .
O29 La1 O27 C61 78.3(6) . .
O32 La1 O27 C61 -122.2(4) . .
O31 La1 O27 C61 -150.7(4) . .
O30 La1 O27 C61 -10.8(4) . .
O28 La1 O27 C61 -1.9(4) . .
La1 O27 C61 O28 4.5(9) . .
La1 O27 C61 C62 177.5(5) . .
O11 La1 C61 O28 81.1(6) 5_675 .
O3 La1 C61 O28 140.4(5) 4_655 .
O20 La1 C61 O28 -80.4(6) . .
O29 La1 C61 O28 42.5(7) . .
O32 La1 C61 O28 -82.8(7) . .
O31 La1 C61 O28 -148.1(6) . .
O30 La1 C61 O28 -5.5(6) . .
O27 La1 C61 O28 -175.6(9) . .
O11 La1 C61 O27 -103.3(4) 5_675 .
O3 La1 C61 O27 -44.0(5) 4_655 .
O20 La1 C61 O27 95.1(4) . .
O29 La1 C61 O27 -142.0(3) . .
O32 La1 C61 O27 92.7(5) . .
O31 La1 C61 O27 27.5(4) . .
O30 La1 C61 O27 170.1(4) . .
O28 La1 C61 O27 175.6(9) . .
O11 La1 C61 C62 -110.3(16) 5_675 .
O3 La1 C61 C62 -51.0(17) 4_655 .
O20 La1 C61 C62 88.2(16) . .
O29 La1 C61 C62 -149.0(15) . .
O32 La1 C61 C62 85.8(17) . .
O31 La1 C61 C62 20.5(16) . .
O30 La1 C61 C62 163.1(16) . .
O27 La1 C61 C62 -7.0(14) . .
O28 La1 C61 C62 169(2) . .
O27 C61 O28 La1 -4.4(9) . .
C62 C61 O28 La1 -174.1(11) . .
O11 La1 O28 C61 -91.2(6) 5_675 .
O3 La1 O28 C61 -51.8(6) 4_655 .
O20 La1 O28 C61 92.9(6) . .
O29 La1 O28 C61 -147.6(6) . .
O32 La1 O28 C61 119.6(6) . .
O31 La1 O28 C61 34.8(6) . .
O30 La1 O28 C61 173.9(6) . .
O27 La1 O28 C61 2.9(6) . .
C23 O9 La6 O50 122.3(7) . 3_565
C23 O9 La6 O44 -46.7(7) . 7_564
C23 O9 La6 O49 39.8(7) . 3_565
C18B O7B La3 La3 20.1(12) . 5_775
C58 O23 La7 La7 -162.5(14) . 6_556
La8 O23 La7 La7 46.0(4) . 6_556
C58 O23 La7 O44 -42.9(16) . .
La8 O23 La7 O44 165.5(5) . .
C58 O23 La8 La8 158(3) . 6_556
La7 O23 La8 La8 -41(3) . 6_556
C58 O23 La8 O17 26.2(14) . 3_565
La7 O23 La8 O17 -173.6(5) . 3_565
La7 La7 O44 La6 -115.9(4) 6_556 8_645
O23 La7 O44 La6 104.9(3) . 8_645
