#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/75/7017559.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7017559
loop_
_publ_author_name
'Kobayashi, Atsushi'
'Hara, Hirofumi'
'Yonemura, Tsubasa'
'Chang, Ho-Chol'
'Kato, Masako'
_publ_section_title
;
 Systematic structural control of multichromic platinum(ii)-diimine
 complexes ranging from ionic solid to coordination polymer.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1878
_journal_page_last               1888
_journal_paper_doi               10.1039/c1dt11155h
_journal_volume                  41
_journal_year                    2012
_chemical_formula_moiety         'C14 H24 Mg N4 O13 Pt '
_chemical_formula_sum            'C14 H24 Mg N4 O13 Pt'
_chemical_formula_weight         675.76
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                114.208(5)
_cell_angle_beta                 95.815(4)
_cell_angle_gamma                104.400(4)
_cell_formula_units_Z            2
_cell_length_a                   6.924(4)
_cell_length_b                   13.689(8)
_cell_length_c                   13.933(7)
_cell_measurement_reflns_used    3059
_cell_measurement_temperature    173.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     1135.3(11)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  SHELXL
_computing_structure_solution    SIR2004
_diffrn_ambient_temperature      173.1
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       ω
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.040
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            9040
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    6.254
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.025
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
;
Higashi, T. (1999). Program for Absorption Correction.
Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.977
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
_exptl_crystal_F_000             660.00
_exptl_crystal_size_max          0.80
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_refine_diff_density_max         5.37
_refine_diff_density_min         -2.18
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.104
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     299
_refine_ls_number_reflns         5085
_refine_ls_R_factor_gt           0.0518
_refine_ls_shift/su_max          0.0020
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.0806P)²+5.3501P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1549
_reflns_number_gt                4310
_reflns_number_total             5085
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            c1dt11155h.txt
_cod_data_source_block           '__MgPt-9H2O'
_cod_original_cell_volume        1135.4(10)
_cod_original_formula_sum        'C14 H24 Mg N4 O13 Pt '
_cod_database_code               7017559
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 +X,+Y,+Z
2 -X,-Y,-Z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt(1) Pt 0.71794(5) 1.00328(3) 1.09336(2) 0.01703(13) Uani 1.00 1 d .
Mg(1) Mg 0.4849(4) 0.3013(2) 0.5579(2) 0.0190(6) Uani 1.00 1 d .
O(1) O 0.5015(10) 0.4679(5) 0.6542(5) 0.0202(13) Uani 1.00 1 d .
O(2) O 0.7609(9) 0.5716(5) 0.6167(5) 0.0209(13) Uani 1.00 1 d .
O(3) O 0.8638(12) 1.0542(6) 0.6271(5) 0.0319(16) Uani 1.00 1 d .
O(4) O 0.9853(11) 1.2407(5) 0.7403(5) 0.0293(15) Uani 1.00 1 d .
O(5) O 0.4844(11) 0.1405(5) 0.4605(6) 0.0332(16) Uani 1.00 1 d .
O(6) O 0.1955(10) 0.2721(6) 0.4706(5) 0.0278(15) Uani 1.00 1 d .
O(7) O 0.6191(10) 0.3592(5) 0.4566(5) 0.0230(13) Uani 1.00 1 d .
O(8) O 0.7754(10) 0.3344(6) 0.6441(6) 0.0334(17) Uani 1.00 1 d .
O(9) O 0.3450(12) 0.2485(7) 0.6610(7) 0.0392(19) Uani 1.00 1 d .
O(10) O 0.8615(10) 1.1061(5) 1.4592(5) 0.0237(13) Uani 1.00 1 d .
O(11) O 0.8796(12) 1.4931(7) 1.3187(8) 0.047(2) Uani 1.00 1 d .
O(12) O 0.948(2) 1.4441(12) 1.1074(12) 0.112(5) Uani 1.00 1 d .
O(13) O 0.671(2) 1.602(2) 1.0950(17) 0.161(9) Uani 1.00 1 d .
N(1) N 0.6756(11) 0.8525(6) 0.9626(5) 0.0154(14) Uani 1.00 1 d .
N(2) N 0.7964(10) 1.0601(6) 0.9824(5) 0.0129(13) Uani 1.00 1 d .
N(3) N 0.6151(14) 0.8980(7) 1.2471(7) 0.0306(19) Uani 1.00 1 d .
N(4) N 0.7876(14) 1.2413(7) 1.2791(7) 0.0306(19) Uani 1.00 1 d .
C(1) C 0.6130(14) 0.7493(8) 0.9570(7) 0.0234(19) Uani 1.00 1 d .
C(2) C 0.5928(15) 0.6532(8) 0.8651(7) 0.0232(19) Uani 1.00 1 d .
C(3) C 0.6486(13) 0.6620(7) 0.7753(6) 0.0184(17) Uani 1.00 1 d .
C(4) C 0.7150(12) 0.7686(7) 0.7795(6) 0.0177(17) Uani 1.00 1 d .
C(5) C 0.7217(13) 0.8613(7) 0.8727(6) 0.0166(16) Uani 1.00 1 d .
C(6) C 0.7821(12) 0.9772(7) 0.8837(7) 0.0175(17) Uani 1.00 1 d .
C(7) C 0.8231(12) 1.0009(7) 0.7975(6) 0.0143(15) Uani 1.00 1 d .
C(8) C 0.8724(14) 1.1121(8) 0.8140(8) 0.0225(19) Uani 1.00 1 d .
C(9) C 0.8902(14) 1.1962(7) 0.9162(7) 0.0214(18) Uani 1.00 1 d .
C(10) C 0.8479(14) 1.1678(8) 0.9982(8) 0.0238(19) Uani 1.00 1 d .
C(11) C 0.6360(14) 0.5586(7) 0.6720(7) 0.0192(17) Uani 1.00 1 d .
C(12) C 0.9078(14) 1.1346(8) 0.7189(7) 0.0215(18) Uani 1.00 1 d .
C(13) C 0.6475(13) 0.9364(7) 1.1906(6) 0.0175(17) Uani 1.00 1 d .
C(14) C 0.7598(14) 1.1529(8) 1.2122(7) 0.0204(18) Uani 1.00 1 d .
H(1) H 0.5812 0.7423 1.0191 0.028 Uiso 1.00 1 c R
H(2) H 0.5410 0.5811 0.8630 0.028 Uiso 1.00 1 c R
H(3) H 0.7550 0.7775 0.7196 0.021 Uiso 1.00 1 c R
H(4) H 0.8173 0.9420 0.7293 0.017 Uiso 1.00 1 c R
H(5) H 0.9315 1.2732 0.9300 0.026 Uiso 1.00 1 c R
H(6) H 0.8554 1.2259 1.0673 0.029 Uiso 1.00 1 c R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.003 0.002
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.000 0.000
;
International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.4)
;
Mg Mg 0.049 0.036
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
N N 0.006 0.003
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
O O 0.011 0.006
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Pt Pt -1.703 8.390
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
N(1) Pt(1) N(2) 80.2(3) yes
N(1) Pt(1) C(13) 94.9(3) yes
N(1) Pt(1) C(14) 176.1(4) yes
N(2) Pt(1) C(13) 174.8(3) yes
N(2) Pt(1) C(14) 95.9(3) yes
C(13) Pt(1) C(14) 89.0(4) yes
O(1) Mg(1) O(5) 176.6(3) yes
O(1) Mg(1) O(6) 89.8(3) yes
O(1) Mg(1) O(7) 86.8(3) yes
O(1) Mg(1) O(8) 89.2(3) yes
O(1) Mg(1) O(9) 91.2(3) yes
O(5) Mg(1) O(6) 92.1(3) yes
O(5) Mg(1) O(7) 90.4(3) yes
O(5) Mg(1) O(8) 88.9(3) yes
O(5) Mg(1) O(9) 91.7(3) yes
O(6) Mg(1) O(7) 89.8(3) yes
O(6) Mg(1) O(8) 178.4(4) yes
O(6) Mg(1) O(9) 89.0(3) yes
O(7) Mg(1) O(8) 89.0(3) yes
O(7) Mg(1) O(9) 177.7(4) yes
O(8) Mg(1) O(9) 92.2(3) yes
Mg(1) O(1) C(11) 129.2(6) yes
Pt(1) N(1) C(1) 127.3(7) yes
Pt(1) N(1) C(5) 114.6(6) yes
C(1) N(1) C(5) 118.0(7) yes
Pt(1) N(2) C(6) 114.2(7) yes
Pt(1) N(2) C(10) 126.4(6) yes
C(6) N(2) C(10) 119.3(9) yes
N(1) C(1) C(2) 122.6(10) yes
C(1) C(2) C(3) 119.6(10) yes
C(2) C(3) C(4) 118.7(8) yes
C(2) C(3) C(11) 122.1(9) yes
C(4) C(3) C(11) 119.2(9) yes
C(3) C(4) C(5) 118.6(9) yes
N(1) C(5) C(4) 122.3(9) yes
N(1) C(5) C(6) 114.9(7) yes
C(4) C(5) C(6) 122.7(9) yes
N(2) C(6) C(5) 115.9(9) yes
N(2) C(6) C(7) 121.6(9) yes
C(5) C(6) C(7) 122.5(7) yes
C(6) C(7) C(8) 118.7(7) yes
C(7) C(8) C(9) 118.8(11) yes
C(7) C(8) C(12) 117.6(7) yes
C(9) C(8) C(12) 123.6(10) yes
C(8) C(9) C(10) 119.9(10) yes
N(2) C(10) C(9) 121.6(8) yes
O(1) C(11) O(2) 127.3(8) yes
O(1) C(11) C(3) 115.4(8) yes
O(2) C(11) C(3) 117.2(7) yes
O(3) C(12) O(4) 124.2(11) yes
O(3) C(12) C(8) 119.7(9) yes
O(4) C(12) C(8) 116.2(7) yes
Pt(1) C(13) N(3) 177.1(9) yes
Pt(1) C(14) N(4) 177.6(10) yes
N(1) C(1) H(1) 118.7 no
C(2) C(1) H(1) 118.7 no
C(1) C(2) H(2) 120.2 no
C(3) C(2) H(2) 120.2 no
C(3) C(4) H(3) 120.7 no
C(5) C(4) H(3) 120.7 no
C(6) C(7) H(4) 120.7 no
C(8) C(7) H(4) 120.7 no
C(8) C(9) H(5) 120.0 no
C(10) C(9) H(5) 120.0 no
N(2) C(10) H(6) 119.2 no
C(9) C(10) H(6) 119.2 no
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Pt(1) N(1) 2.043(6) yes
Pt(1) N(2) 2.058(9) yes
Pt(1) C(13) 1.960(11) yes
Pt(1) C(14) 1.961(8) yes
Mg(1) O(1) 2.084(7) yes
Mg(1) O(5) 2.057(7) yes
Mg(1) O(6) 2.089(8) yes
Mg(1) O(7) 2.074(9) yes
Mg(1) O(8) 2.075(8) yes
Mg(1) O(9) 2.076(11) yes
O(1) C(11) 1.262(11) yes
O(2) C(11) 1.243(12) yes
O(3) C(12) 1.241(10) yes
O(4) C(12) 1.308(13) yes
N(1) C(1) 1.336(15) yes
N(1) C(5) 1.368(13) yes
N(2) C(6) 1.351(10) yes
N(2) C(10) 1.344(14) yes
N(3) C(13) 1.124(16) yes
N(4) C(14) 1.137(12) yes
C(1) C(2) 1.371(12) yes
C(2) C(3) 1.389(15) yes
C(3) C(4) 1.391(15) yes
C(3) C(11) 1.525(11) yes
C(4) C(5) 1.380(11) yes
C(5) C(6) 1.475(15) yes
C(6) C(7) 1.404(15) yes
C(7) C(8) 1.388(15) yes
C(8) C(9) 1.384(12) yes
C(8) C(12) 1.508(17) yes
C(9) C(10) 1.385(17) yes
C(1) H(1) 0.950 no
C(2) H(2) 0.950 no
C(4) H(3) 0.950 no
C(7) H(4) 0.950 no
C(9) H(5) 0.950 no
C(10) H(6) 0.950 no
loop_
_geom_contact_atom_site_label_1
_geom_contact_atom_site_label_2
_geom_contact_distance
_geom_contact_site_symmetry_2
Pt(1) N(2) 3.391(7) 2_677
Pt(1) C(6) 3.574(9) 2_677
Pt(1) C(6) 3.377(9) 2_777
Pt(1) C(7) 3.405(9) 2_777
O(1) O(7) 3.521(12) 2_666
O(1) O(11) 2.851(12) 2_677
O(2) O(6) 2.835(13) 2_666
O(2) O(7) 3.218(11) 2_666
O(2) O(11) 3.014(13) 2_777
O(2) N(4) 3.239(9) 2_777
O(3) O(5) 2.819(9) 2_666
O(3) O(9) 3.556(11) 1_665
O(3) O(10) 2.708(12) 1_554
O(3) O(10) 3.202(12) 2_777
O(4) O(8) 2.738(13) 1_565
O(4) O(9) 2.821(12) 1_665
O(4) O(10) 3.476(9) 1_554
O(4) O(13) 2.803(17) 2_787
O(5) O(3) 2.819(9) 2_666
O(5) O(10) 2.767(11) 1_544
O(5) C(7) 3.449(10) 2_666
O(6) O(2) 2.835(13) 2_666
O(6) O(10) 2.749(10) 1_444
O(6) O(11) 3.553(11) 2_677
O(6) N(4) 3.497(13) 1_444
O(6) C(4) 3.443(13) 2_666
O(7) O(1) 3.521(12) 2_666
O(7) O(2) 3.218(11) 2_666
O(7) O(11) 3.500(14) 1_544
O(7) N(4) 2.886(12) 1_544
O(7) C(3) 3.422(12) 2_666
O(7) C(4) 3.311(10) 2_666
O(7) C(11) 3.098(14) 2_666
O(8) O(4) 2.738(13) 1_545
O(8) O(10) 3.376(10) 1_544
O(8) O(11) 2.737(11) 2_777
O(8) O(12) 3.465(13) 2_777
O(8) C(12) 3.577(16) 1_545
O(9) O(3) 3.556(11) 1_445
O(9) O(4) 2.821(12) 1_445
O(9) O(13) 3.20(2) 2_677
O(9) N(3) 2.836(17) 2_667
O(9) C(12) 3.380(13) 1_445
O(10) O(3) 2.708(12) 1_556
O(10) O(3) 3.202(12) 2_777
O(10) O(4) 3.476(9) 1_556
O(10) O(5) 2.767(11) 1_566
O(10) O(6) 2.749(10) 1_666
O(10) O(8) 3.376(10) 1_566
O(10) N(3) 3.069(8) .
O(10) C(12) 3.448(13) 1_556
O(10) C(13) 3.411(9) .
O(11) O(1) 2.851(12) 2_677
O(11) O(2) 3.014(13) 2_777
O(11) O(6) 3.553(11) 2_677
O(11) O(7) 3.500(14) 1_566
O(11) O(8) 2.737(11) 2_777
O(11) O(12) 2.86(2) .
O(11) N(4) 3.142(14) .
O(11) C(2) 3.480(11) 2_677
O(11) C(3) 3.533(11) 2_677
O(11) C(11) 3.489(13) 2_677
O(11) C(11) 3.596(14) 2_777
O(12) O(8) 3.465(13) 2_777
O(12) O(11) 2.86(2) .
O(12) O(13) 3.27(3) .
O(12) C(9) 3.236(16) .
O(12) C(10) 3.296(18) .
O(13) O(4) 2.803(17) 2_787
O(13) O(9) 3.20(2) 2_677
O(13) O(12) 3.27(3) .
O(13) O(13) 3.13(2) 2_687
O(13) C(1) 3.37(3) 1_565
O(13) C(2) 3.57(3) 1_565
N(1) N(2) 3.448(10) 2_777
N(1) C(10) 3.388(13) 2_777
N(2) Pt(1) 3.391(7) 2_677
N(2) N(1) 3.448(10) 2_777
N(2) C(5) 3.381(11) 2_777
N(2) C(6) 3.560(13) 2_777
N(3) O(9) 2.836(17) 2_667
N(3) O(10) 3.069(8) .
N(3) C(8) 3.351(14) 2_677
N(3) C(9) 3.581(13) 2_677
N(3) C(12) 3.453(15) 2_777
N(4) O(2) 3.239(9) 2_777
N(4) O(6) 3.497(13) 1_666
N(4) O(7) 2.886(12) 1_566
N(4) O(11) 3.142(14) .
N(4) C(4) 3.449(13) 2_677
N(4) C(5) 3.531(12) 2_677
C(1) O(13) 3.37(3) 1_545
C(1) C(9) 3.453(14) 2_777
C(1) C(10) 3.529(13) 2_777
C(2) O(11) 3.480(11) 2_677
C(2) O(13) 3.57(3) 1_545
C(3) O(7) 3.422(12) 2_666
C(3) O(11) 3.533(11) 2_677
C(4) O(6) 3.443(13) 2_666
C(4) O(7) 3.311(10) 2_666
C(4) N(4) 3.449(13) 2_677
C(4) C(14) 3.501(12) 2_777
C(5) N(2) 3.381(11) 2_777
C(5) N(4) 3.531(12) 2_677
C(5) C(10) 3.517(15) 2_777
C(5) C(14) 3.353(13) 2_677
C(6) Pt(1) 3.574(9) 2_677
C(6) Pt(1) 3.377(9) 2_777
C(6) N(2) 3.560(13) 2_777
C(6) C(14) 3.570(11) 2_677
C(7) Pt(1) 3.405(9) 2_777
C(7) O(5) 3.449(10) 2_666
C(7) C(13) 3.572(14) 2_677
C(7) C(13) 3.521(12) 2_777
C(8) N(3) 3.351(14) 2_677
C(8) C(13) 3.483(13) 2_677
C(8) C(13) 3.550(15) 2_777
C(9) O(12) 3.236(16) .
C(9) N(3) 3.581(13) 2_677
C(9) C(1) 3.453(14) 2_777
C(9) C(13) 3.560(12) 2_677
C(10) O(12) 3.296(18) .
C(10) N(1) 3.388(13) 2_777
C(10) C(1) 3.529(13) 2_777
C(10) C(5) 3.517(15) 2_777
C(11) O(7) 3.098(14) 2_666
C(11) O(11) 3.489(13) 2_677
C(11) O(11) 3.596(14) 2_777
C(12) O(8) 3.577(16) 1_565
C(12) O(9) 3.380(13) 1_665
C(12) O(10) 3.448(13) 1_554
C(12) N(3) 3.453(15) 2_777
C(13) O(10) 3.411(9) .
C(13) C(7) 3.572(14) 2_677
C(13) C(7) 3.521(12) 2_777
C(13) C(8) 3.483(13) 2_677
C(13) C(8) 3.550(15) 2_777
C(13) C(9) 3.560(12) 2_677
C(14) C(4) 3.501(12) 2_777
C(14) C(5) 3.353(13) 2_677
C(14) C(6) 3.570(11) 2_677
Pt(1) H(4) 3.563 2_777
O(5) H(3) 3.563 2_666
O(5) H(4) 2.809 2_666
O(6) H(3) 2.534 2_666
O(6) H(4) 3.080 2_666
O(7) H(3) 2.962 2_666
O(10) H(4) 3.574 2_777
O(11) H(2) 3.293 2_677
O(12) H(2) 3.403 2_677
O(12) H(5) 2.581 .
O(12) H(6) 2.693 .
O(13) H(1) 2.706 1_565
O(13) H(2) 3.142 1_565
O(13) H(2) 2.885 2_677
O(13) H(5) 2.994 2_787
N(1) H(6) 3.493 2_677
N(4) H(3) 3.239 2_777
C(1) H(5) 3.521 2_777
C(1) H(6) 3.341 2_677
C(3) H(6) 3.472 2_777
C(4) H(6) 3.447 2_777
C(5) H(6) 3.572 2_777
C(9) H(1) 3.477 2_777
C(10) H(1) 3.509 2_677
C(13) H(4) 3.510 2_777
C(14) H(3) 3.180 2_777
H(1) O(13) 2.706 1_545
H(1) C(9) 3.477 2_777
H(1) C(10) 3.509 2_677
H(1) H(5) 3.453 2_777
H(1) H(6) 3.335 2_677
H(2) O(11) 3.293 2_677
H(2) O(12) 3.403 2_677
H(2) O(13) 3.142 1_545
H(2) O(13) 2.885 2_677
H(3) O(5) 3.563 2_666
H(3) O(6) 2.534 2_666
H(3) O(7) 2.962 2_666
H(3) N(4) 3.239 2_777
H(3) C(14) 3.180 2_777
H(4) Pt(1) 3.563 2_777
H(4) O(5) 2.809 2_666
H(4) O(6) 3.080 2_666
H(4) O(10) 3.574 2_777
H(4) C(13) 3.510 2_777
H(5) O(12) 2.581 .
H(5) O(13) 2.994 2_787
H(5) C(1) 3.521 2_777
H(5) H(1) 3.453 2_777
H(6) O(12) 2.693 .
H(6) N(1) 3.493 2_677
H(6) C(1) 3.341 2_677
H(6) C(3) 3.472 2_777
H(6) C(4) 3.447 2_777
H(6) C(5) 3.572 2_777
H(6) H(1) 3.335 2_677
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
N(1) Pt(1) N(2) C(6) 0.5(6)
N(1) Pt(1) N(2) C(10) 176.8(8)
N(2) Pt(1) N(1) C(1) -179.7(7)
N(2) Pt(1) N(1) C(5) 1.7(6)
N(1) Pt(1) C(13) N(3) 83(14)
C(13) Pt(1) N(1) C(1) 2.1(8)
C(13) Pt(1) N(1) C(5) -176.6(6)
N(1) Pt(1) C(14) N(4) -26(28)
C(14) Pt(1) N(1) C(1) -167(4)
C(14) Pt(1) N(1) C(5) 14(5)
N(2) Pt(1) C(13) N(3) 64(14)
C(13) Pt(1) N(2) C(6) 20(3)
C(13) Pt(1) N(2) C(10) -164(3)
N(2) Pt(1) C(14) N(4) -13(19)
C(14) Pt(1) N(2) C(6) -178.7(6)
C(14) Pt(1) N(2) C(10) -2.3(8)
C(13) Pt(1) C(14) N(4) 165(21)
C(14) Pt(1) C(13) N(3) -98(14)
O(5) Mg(1) O(1) C(11) -1(4)
O(6) Mg(1) O(1) C(11) -123.7(9)
O(7) Mg(1) O(1) C(11) -33.9(9)
O(8) Mg(1) O(1) C(11) 55.1(9)
O(9) Mg(1) O(1) C(11) 147.3(9)
Mg(1) O(1) C(11) O(2) 19.8(17)
Mg(1) O(1) C(11) C(3) -158.1(7)
Pt(1) N(1) C(1) C(2) -178.9(7)
Pt(1) N(1) C(5) C(4) 175.6(7)
Pt(1) N(1) C(5) C(6) -3.4(10)
C(1) N(1) C(5) C(4) -3.2(13)
C(1) N(1) C(5) C(6) 177.8(8)
C(5) N(1) C(1) C(2) -0.3(11)
Pt(1) N(2) C(6) C(5) -2.4(10)
Pt(1) N(2) C(6) C(7) 177.8(6)
Pt(1) N(2) C(10) C(9) -177.4(7)
C(6) N(2) C(10) C(9) -1.2(14)
C(10) N(2) C(6) C(5) -179.1(8)
C(10) N(2) C(6) C(7) 1.1(13)
N(1) C(1) C(2) C(3) 3.3(16)
C(1) C(2) C(3) C(4) -2.9(15)
C(1) C(2) C(3) C(11) 178.1(9)
C(2) C(3) C(4) C(5) -0.4(11)
C(2) C(3) C(11) O(1) 28.1(14)
C(2) C(3) C(11) O(2) -150.1(10)
C(4) C(3) C(11) O(1) -151.0(9)
C(4) C(3) C(11) O(2) 30.9(14)
C(11) C(3) C(4) C(5) 178.7(8)
C(3) C(4) C(5) N(1) 3.5(13)
C(3) C(4) C(5) C(6) -177.6(8)
N(1) C(5) C(6) N(2) 3.9(12)
N(1) C(5) C(6) C(7) -176.3(8)
C(4) C(5) C(6) N(2) -175.1(8)
C(4) C(5) C(6) C(7) 4.7(14)
N(2) C(6) C(7) C(8) -2.3(13)
C(5) C(6) C(7) C(8) 177.9(8)
C(6) C(7) C(8) C(9) 3.5(13)
C(6) C(7) C(8) C(12) -177.7(8)
C(7) C(8) C(9) C(10) -3.6(15)
C(7) C(8) C(12) O(3) 10.4(14)
C(7) C(8) C(12) O(4) -169.5(9)
C(9) C(8) C(12) O(3) -170.9(10)
C(9) C(8) C(12) O(4) 9.3(15)
C(12) C(8) C(9) C(10) 177.7(9)
C(8) C(9) C(10) N(2) 2.5(15)
