#------------------------------------------------------------------------------
#$Date: 2016-03-25 14:13:09 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179885 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/81/7018153.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7018153
loop_
_publ_author_name
'Lin, Shuang-Yan'
'Zhao, Lang'
'Ke, Hongshan'
'Guo, Yun-Nan'
'Tang, Jinkui'
'Guo, Yang'
'Dou, Jianmin'
_publ_section_title
;
 Steric hindrances create a discrete linear Dy(4) complex exhibiting SMM
 behaviour.
;
_journal_issue                   11
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3248
_journal_page_last               3252
_journal_paper_doi               10.1039/c2dt11539e
_journal_volume                  41
_journal_year                    2012
_chemical_formula_sum            'C126 H112 Dy4 N4 O34'
_chemical_formula_weight         2876.20
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                111.3530(10)
_cell_angle_beta                 97.8070(10)
_cell_angle_gamma                118.4660(10)
_cell_formula_units_Z            1
_cell_length_a                   15.3812(10)
_cell_length_b                   15.6120(10)
_cell_length_c                   15.9042(11)
_cell_measurement_reflns_used    5006
_cell_measurement_temperature    185(2)
_cell_measurement_theta_max      26.07
_cell_measurement_theta_min      2.6
_cell_volume                     2895.1(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      187(2)
_diffrn_detector_area_resol_mean 8.366
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0415
_diffrn_reflns_av_sigmaI/netI    0.1035
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            16228
_diffrn_reflns_theta_full        26.11
_diffrn_reflns_theta_max         26.11
_diffrn_reflns_theta_min         1.48
_exptl_absorpt_coefficient_mu    2.636
_exptl_absorpt_correction_T_max  0.6778
_exptl_absorpt_correction_T_min  0.6207
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2000)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.650
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       stick
_exptl_crystal_F_000             1432
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.16
_refine_diff_density_max         0.959
_refine_diff_density_min         -1.042
_refine_diff_density_rms         0.161
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.962
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     760
_refine_ls_number_reflns         11381
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.962
_refine_ls_R_factor_all          0.0946
_refine_ls_R_factor_gt           0.0487
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0479P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0955
_refine_ls_wR_factor_ref         0.1225
_reflns_number_gt                7257
_reflns_number_total             11381
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt11539e.txt
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      p-1
_cod_database_code               7018153
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Dy1 Dy 0.59188(3) -0.29789(3) 0.10683(3) 0.02557(12) Uani 1 1 d .
Dy2 Dy 0.76275(3) 0.12328(3) 0.31245(3) 0.02177(11) Uani 1 1 d .
N1 N 0.8496(5) 0.1234(5) 0.4597(4) 0.0235(14) Uani 1 1 d .
N2 N 1.0295(5) 0.4276(5) 0.3415(5) 0.0274(15) Uani 1 1 d .
O1 O 0.9291(4) 0.2814(4) 0.3950(4) 0.0273(13) Uani 1 1 d .
H1 H 0.9555 0.3043 0.3510 0.033 Uiso 1 1 calc R
O2 O 0.9378(5) 0.0210(5) 0.5490(4) 0.0426(16) Uani 1 1 d .
O3 O 1.2207(5) 0.4884(5) 0.2970(4) 0.0447(16) Uani 1 1 d .
O4 O 0.6476(4) 0.1839(4) 0.2977(4) 0.0296(13) Uani 1 1 d .
O5 O 0.7258(4) 0.2237(4) 0.4452(4) 0.0310(13) Uani 1 1 d .
O6 O 0.8207(4) 0.1964(4) 0.2043(4) 0.0300(13) Uani 1 1 d .
O7 O 0.6670(4) 0.0323(4) 0.1375(4) 0.0294(13) Uani 1 1 d .
O8 O 0.8227(4) 0.0152(4) 0.2489(4) 0.0344(14) Uani 1 1 d .
O9 O 0.7511(4) -0.1525(4) 0.1241(4) 0.0354(14) Uani 1 1 d .
O10 O 0.6170(4) -0.0243(4) 0.3003(4) 0.0329(14) Uani 1 1 d .
O11 O 0.5569(4) -0.2043(4) 0.2290(4) 0.0369(15) Uani 1 1 d .
O12 O 0.7132(4) -0.2529(4) 0.2543(4) 0.0359(14) Uani 1 1 d .
O13 O 0.5538(4) -0.4099(4) 0.1929(4) 0.0360(14) Uani 1 1 d .
O14 O 0.6447(5) -0.4135(5) 0.0464(4) 0.0491(17) Uani 1 1 d .
O15 O 0.5577(5) -0.3612(5) -0.0698(4) 0.0478(17) Uani 1 1 d .
H15 H 0.5081 -0.4395 -0.1126 0.057 Uiso 1 1 calc R
O16 O 0.5487(4) -0.1901(4) 0.0554(4) 0.0367(14) Uani 1 1 d .
H16 H 0.6071 -0.1159 0.0768 0.044 Uiso 1 1 calc R
O17 O 0.4078(4) -0.4126(4) 0.0358(4) 0.0407(15) Uani 1 1 d .
C1 C 0.9998(6) 0.3507(6) 0.4816(6) 0.0205(16) Uani 1 1 d .
C2 C 0.9989(5) 0.3212(6) 0.5559(6) 0.0231(17) Uani 1 1 d .
C3 C 1.0785(6) 0.3998(6) 0.6475(6) 0.0316(19) Uani 1 1 d .
H3 H 1.0796 0.3769 0.6952 0.038 Uiso 1 1 calc R
C4 C 1.1581(7) 0.5109(6) 0.6753(6) 0.031(2) Uani 1 1 d .
C5 C 1.1583(6) 0.5371(6) 0.6017(6) 0.031(2) Uani 1 1 d .
H5 H 1.2125 0.6105 0.6166 0.037 Uiso 1 1 calc R
C6 C 1.0817(6) 0.4606(6) 0.5044(6) 0.0234(18) Uani 1 1 d .
C7 C 0.9281(6) 0.2083(6) 0.5391(6) 0.0242(17) Uani 1 1 d .
H7 H 0.9413 0.1960 0.5923 0.029 Uiso 1 1 calc R
C8 C 0.7934(6) 0.0124(6) 0.4561(6) 0.0282(18) Uani 1 1 d .
H8A H 0.7194 -0.0119 0.4500 0.034 Uiso 1 1 calc R
H8B H 0.7890 -0.0427 0.3963 0.034 Uiso 1 1 calc R
C9 C 0.8426(6) 0.0084(6) 0.5409(6) 0.0278(19) Uani 1 1 d .
C10 C 0.8171(7) -0.0026(6) 0.6149(6) 0.032(2) Uani 1 1 d .
H10 H 0.7555 -0.0108 0.6270 0.038 Uiso 1 1 calc R
C11 C 0.8973(7) 0.0001(7) 0.6716(7) 0.042(2) Uani 1 1 d .
H11 H 0.9010 -0.0066 0.7288 0.051 Uiso 1 1 calc R
C12 C 0.9674(7) 0.0140(8) 0.6283(7) 0.049(3) Uani 1 1 d .
H12 H 1.0307 0.0185 0.6508 0.059 Uiso 1 1 calc R
C13 C 1.2438(7) 0.5919(6) 0.7740(6) 0.043(2) Uani 1 1 d .
H13A H 1.2825 0.5609 0.7887 0.064 Uiso 1 1 calc R
H13B H 1.2120 0.6058 0.8224 0.064 Uiso 1 1 calc R
H13C H 1.2935 0.6623 0.7761 0.064 Uiso 1 1 calc R
C14 C 1.0928(6) 0.4929(6) 0.4329(6) 0.0255(18) Uani 1 1 d .
H14 H 1.1501 0.5670 0.4524 0.031 Uiso 1 1 calc R
C15 C 1.0503(6) 0.4644(6) 0.2691(6) 0.032(2) Uani 1 1 d .
H15A H 1.0821 0.5457 0.2999 0.038 Uiso 1 1 calc R
H15B H 0.9817 0.4251 0.2151 0.038 Uiso 1 1 calc R
C16 C 1.1238(7) 0.4416(6) 0.2288(6) 0.034(2) Uani 1 1 d .
C17 C 1.1219(8) 0.3938(7) 0.1385(6) 0.042(2) Uani 1 1 d .
H17 H 1.0643 0.3558 0.0786 0.050 Uiso 1 1 calc R
C18 C 1.2238(8) 0.4119(8) 0.1512(8) 0.049(3) Uani 1 1 d .
H18 H 1.2477 0.3891 0.1008 0.058 Uiso 1 1 calc R
C19 C 1.2794(8) 0.4669(8) 0.2470(8) 0.053(3) Uani 1 1 d .
H19 H 1.3496 0.4880 0.2760 0.064 Uiso 1 1 calc R
C20 C 0.6544(6) 0.2132(6) 0.3850(6) 0.0260(18) Uani 1 1 d .
C21 C 0.5731(6) 0.2310(6) 0.4142(6) 0.0272(18) Uani 1 1 d .
C22 C 0.5695(6) 0.2495(6) 0.5056(6) 0.034(2) Uani 1 1 d .
H22 H 0.6203 0.2535 0.5510 0.041 Uiso 1 1 calc R
C23 C 0.4920(7) 0.2620(7) 0.5306(8) 0.048(3) Uani 1 1 d .
H23 H 0.4898 0.2744 0.5931 0.057 Uiso 1 1 calc R
C24 C 0.4184(7) 0.2567(7) 0.4660(8) 0.050(3) Uani 1 1 d .
H24 H 0.3642 0.2635 0.4829 0.060 Uiso 1 1 calc R
C25 C 0.4236(7) 0.2414(8) 0.3766(8) 0.052(3) Uani 1 1 d .
H25 H 0.3737 0.2398 0.3325 0.062 Uiso 1 1 calc R
C26 C 0.4998(7) 0.2284(7) 0.3495(7) 0.040(2) Uani 1 1 d .
H26 H 0.5022 0.2177 0.2874 0.048 Uiso 1 1 calc R
C27 C 0.7395(6) 0.1125(6) 0.1304(6) 0.0243(17) Uani 1 1 d .
C28 C 0.7268(6) 0.1050(6) 0.0333(6) 0.0269(18) Uani 1 1 d .
C29 C 0.8163(7) 0.1751(8) 0.0206(7) 0.046(2) Uani 1 1 d .
H29 H 0.8842 0.2259 0.0727 0.056 Uiso 1 1 calc R
C30 C 0.8040(8) 0.1693(8) -0.0708(7) 0.057(3) Uani 1 1 d .
H30 H 0.8646 0.2156 -0.0810 0.068 Uiso 1 1 calc R
C31 C 0.7053(8) 0.0974(8) -0.1461(7) 0.052(3) Uani 1 1 d .
H31 H 0.6972 0.0954 -0.2072 0.063 Uiso 1 1 calc R
C32 C 0.6194(8) 0.0290(7) -0.1311(6) 0.046(2) Uani 1 1 d .
H32 H 0.5511 -0.0208 -0.1827 0.055 Uiso 1 1 calc R
C33 C 0.6291(7) 0.0304(7) -0.0436(6) 0.036(2) Uani 1 1 d .
H33 H 0.5686 -0.0199 -0.0358 0.044 Uiso 1 1 calc R
C34 C 0.5487(6) -0.1261(6) 0.2728(5) 0.0230(17) Uani 1 1 d .
C35 C 0.4514(5) -0.1527(6) 0.2966(5) 0.0214(17) Uani 1 1 d .
C36 C 0.4496(6) -0.0684(7) 0.3670(6) 0.0321(19) Uani 1 1 d .
H36 H 0.5110 0.0067 0.4009 0.039 Uiso 1 1 calc R
C37 C 0.3593(8) -0.0945(8) 0.3870(7) 0.044(2) Uani 1 1 d .
H37 H 0.3588 -0.0378 0.4364 0.053 Uiso 1 1 calc R
C38 C 0.2686(7) -0.2032(9) 0.3353(8) 0.053(3) Uani 1 1 d .
H38 H 0.2058 -0.2206 0.3488 0.064 Uiso 1 1 calc R
C39 C 0.2691(7) -0.2859(8) 0.2650(7) 0.043(2) Uani 1 1 d .
H39 H 0.2063 -0.3600 0.2290 0.052 Uiso 1 1 calc R
C40 C 0.3614(6) -0.2611(6) 0.2464(6) 0.031(2) Uani 1 1 d .
H40 H 0.3625 -0.3188 0.1991 0.038 Uiso 1 1 calc R
C41 C 0.8252(6) -0.0510(6) 0.1779(6) 0.0238(17) Uani 1 1 d .
C42 C 0.9258(6) -0.0079(6) 0.1572(6) 0.0278(19) Uani 1 1 d .
C43 C 1.0050(6) 0.1058(7) 0.2058(7) 0.041(2) Uani 1 1 d .
H43 H 0.9945 0.1562 0.2509 0.049 Uiso 1 1 calc R
C44 C 1.0977(8) 0.1462(10) 0.1896(9) 0.066(3) Uani 1 1 d .
H44 H 1.1503 0.2247 0.2229 0.080 Uiso 1 1 calc R
C45 C 1.1162(8) 0.0770(12) 0.1274(10) 0.077(4) Uani 1 1 d .
H45 H 1.1818 0.1062 0.1180 0.092 Uiso 1 1 calc R
C46 C 1.0379(9) -0.0379(11) 0.0772(8) 0.063(3) Uani 1 1 d .
H46 H 1.0505 -0.0869 0.0331 0.075 Uiso 1 1 calc R
C47 C 0.9405(7) -0.0825(8) 0.0908(6) 0.038(2) Uani 1 1 d .
H47 H 0.8866 -0.1607 0.0559 0.046 Uiso 1 1 calc R
C48 C 0.6628(6) -0.4849(6) 0.0215(6) 0.0281(19) Uani 1 1 d .
C49 C 0.7761(6) -0.4501(6) 0.0581(5) 0.0245(17) Uani 1 1 d .
C50 C 0.8574(6) -0.3388(6) 0.1262(6) 0.032(2) Uani 1 1 d .
H50 H 0.8409 -0.2852 0.1500 0.038 Uiso 1 1 calc R
C51 C 0.9613(7) -0.3064(8) 0.1589(7) 0.042(2) Uani 1 1 d .
H51 H 1.0169 -0.2304 0.2046 0.051 Uiso 1 1 calc R
C52 C 0.9841(7) -0.3836(9) 0.1255(7) 0.049(3) Uani 1 1 d .
H52 H 1.0562 -0.3603 0.1485 0.059 Uiso 1 1 calc R
C53 C 0.9050(7) -0.4962(8) 0.0585(7) 0.044(2) Uani 1 1 d .
H53 H 0.9220 -0.5495 0.0373 0.053 Uiso 1 1 calc R
C54 C 0.8000(6) -0.5280(6) 0.0234(6) 0.0313(19) Uani 1 1 d .
H54 H 0.7450 -0.6033 -0.0244 0.038 Uiso 1 1 calc R
C55 C 0.6475(7) -0.3378(7) 0.2585(6) 0.031(2) Uani 1 1 d .
C56 C 0.6799(7) -0.3531(7) 0.3417(6) 0.033(2) Uani 1 1 d .
C57 C 0.7797(7) -0.2738(7) 0.4145(6) 0.037(2) Uani 1 1 d .
H57 H 0.8289 -0.2099 0.4110 0.044 Uiso 1 1 calc R
C58 C 0.8090(8) -0.2871(8) 0.4940(7) 0.049(3) Uani 1 1 d .
H58 H 0.8776 -0.2315 0.5446 0.059 Uiso 1 1 calc R
C59 C 0.7396(9) -0.3796(9) 0.4993(8) 0.056(3) Uani 1 1 d .
H59 H 0.7600 -0.3885 0.5531 0.067 Uiso 1 1 calc R
C60 C 0.6394(9) -0.4603(9) 0.4254(8) 0.060(3) Uani 1 1 d .
H60 H 0.5909 -0.5250 0.4283 0.072 Uiso 1 1 calc R
C61 C 0.6103(8) -0.4469(7) 0.3486(7) 0.049(3) Uani 1 1 d .
H61 H 0.5412 -0.5025 0.2987 0.059 Uiso 1 1 calc R
C62 C 0.4498(7) -0.2218(7) -0.0015(8) 0.060(3) Uani 1 1 d .
H62A H 0.4055 -0.3027 -0.0467 0.090 Uiso 1 1 calc R
H62B H 0.4608 -0.1818 -0.0386 0.090 Uiso 1 1 calc R
H62C H 0.4138 -0.2031 0.0409 0.090 Uiso 1 1 calc R
C63 C 0.6017(8) -0.2971(7) -0.1149(7) 0.052(3) Uani 1 1 d .
H63A H 0.6540 -0.2184 -0.0650 0.079 Uiso 1 1 calc R
H63B H 0.5447 -0.3036 -0.1587 0.079 Uiso 1 1 calc R
H63C H 0.6370 -0.3245 -0.1525 0.079 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O11 Dy1 O14 149.6(2) . .
O11 Dy1 O9 100.68(19) . .
O14 Dy1 O9 88.7(2) . .
O11 Dy1 O17 81.7(2) . .
O14 Dy1 O17 104.7(2) . .
O9 Dy1 O17 149.3(2) . .
O11 Dy1 O12 75.31(19) . .
O14 Dy1 O12 78.5(2) . .
O9 Dy1 O12 78.4(2) . .
O17 Dy1 O12 130.8(2) . .
O11 Dy1 O16 74.4(2) . .
O14 Dy1 O16 135.9(2) . .
O9 Dy1 O16 74.09(19) . .
O17 Dy1 O16 77.22(18) . .
O12 Dy1 O16 133.94(17) . .
O11 Dy1 O15 140.6(2) . .
O14 Dy1 O15 69.0(2) . .
O9 Dy1 O15 82.1(2) . .
O17 Dy1 O15 77.4(2) . .
O12 Dy1 O15 142.2(2) . .
O16 Dy1 O15 68.57(19) . .
O11 Dy1 O13 78.43(19) . .
O14 Dy1 O13 73.7(2) . .
O9 Dy1 O13 130.56(19) . .
O17 Dy1 O13 80.08(19) . .
O12 Dy1 O13 53.19(18) . .
O16 Dy1 O13 146.63(19) . .
O15 Dy1 O13 129.17(17) . .
O11 Dy1 C55 74.9(2) . .
O14 Dy1 C55 74.8(2) . .
O9 Dy1 C55 104.4(2) . .
O17 Dy1 C55 105.7(2) . .
O12 Dy1 C55 26.38(19) . .
O16 Dy1 C55 148.4(2) . .
O15 Dy1 C55 143.1(2) . .
O13 Dy1 C55 26.81(19) . .
O10 Dy2 O1 153.0(2) . .
O10 Dy2 O8 90.28(19) . .
O1 Dy2 O8 92.89(19) . .
O10 Dy2 O4 82.99(18) . .
O1 Dy2 O4 105.22(17) . .
O8 Dy2 O4 152.37(19) . .
O10 Dy2 O6 136.60(18) . .
O1 Dy2 O6 70.40(17) . .
O8 Dy2 O6 84.32(18) . .
O4 Dy2 O6 82.41(18) . .
O10 Dy2 O7 83.09(18) . .
O1 Dy2 O7 123.77(18) . .
O8 Dy2 O7 77.48(18) . .
O4 Dy2 O7 75.12(18) . .
O6 Dy2 O7 53.67(16) . .
O10 Dy2 O5 81.47(18) . .
O1 Dy2 O5 83.06(18) . .
O8 Dy2 O5 151.53(19) . .
O4 Dy2 O5 53.71(18) . .
O6 Dy2 O5 120.05(17) . .
O7 Dy2 O5 127.82(17) . .
O10 Dy2 N1 82.59(19) . .
O1 Dy2 N1 72.00(18) . .
O8 Dy2 N1 77.36(19) . .
O4 Dy2 N1 127.76(19) . .
O6 Dy2 N1 136.95(18) . .
O7 Dy2 N1 150.87(18) . .
O5 Dy2 N1 74.59(18) . .
O10 Dy2 C20 77.6(2) . .
O1 Dy2 C20 97.8(2) . .
O8 Dy2 C20 167.9(2) . .
O4 Dy2 C20 27.2(2) . .
O6 Dy2 C20 104.5(2) . .
O7 Dy2 C20 100.9(2) . .
O5 Dy2 C20 27.0(2) . .
N1 Dy2 C20 100.6(2) . .
O10 Dy2 C27 110.1(2) . .
O1 Dy2 C27 96.8(2) . .
O8 Dy2 C27 79.7(2) . .
O4 Dy2 C27 77.6(2) . .
O6 Dy2 C27 26.58(17) . .
O7 Dy2 C27 27.09(18) . .
O5 Dy2 C27 128.70(19) . .
N1 Dy2 C27 153.8(2) . .
C20 Dy2 C27 104.4(2) . .
C7 N1 C8 117.5(6) . .
C7 N1 Dy2 127.5(5) . .
C8 N1 Dy2 114.6(4) . .
C14 N2 C15 121.1(6) . .
C1 O1 Dy2 140.8(5) . .
C1 O1 H1 109.6 . .
Dy2 O1 H1 109.6 . .
C12 O2 C9 105.8(7) . .
C19 O3 C16 106.6(7) . .
C20 O4 Dy2 93.0(5) . .
C20 O5 Dy2 90.7(5) . .
C27 O6 Dy2 93.2(4) . .
C27 O7 Dy2 92.5(4) . .
C41 O8 Dy2 150.8(5) . .
C41 O9 Dy1 144.6(5) . .
C34 O10 Dy2 157.4(5) . .
C34 O11 Dy1 150.5(5) . .
C55 O12 Dy1 95.2(5) . .
C55 O13 Dy1 90.9(5) . .
C48 O14 Dy1 168.9(6) . .
C63 O15 Dy1 129.0(5) . .
C63 O15 H15 115.5 . .
Dy1 O15 H15 115.5 . .
C62 O16 Dy1 129.1(5) . .
C62 O16 H16 115.5 . .
Dy1 O16 H16 115.5 . .
C48 O17 Dy1 136.7(5) 2_645 .
O1 C1 C2 121.8(6) . .
O1 C1 C6 119.3(7) . .
C2 C1 C6 118.8(7) . .
C3 C2 C1 118.7(7) . .
C3 C2 C7 116.8(7) . .
C1 C2 C7 123.9(7) . .
C2 C3 C4 124.9(8) . .
C2 C3 H3 117.6 . .
C4 C3 H3 117.6 . .
C5 C4 C3 115.2(7) . .
C5 C4 C13 121.4(7) . .
C3 C4 C13 123.1(8) . .
C4 C5 C6 123.7(7) . .
C4 C5 H5 118.1 . .
C6 C5 H5 118.1 . .
C14 C6 C5 119.4(7) . .
C14 C6 C1 122.0(7) . .
C5 C6 C1 118.5(7) . .
N1 C7 C2 126.7(7) . .
N1 C7 H7 116.6 . .
C2 C7 H7 116.6 . .
C9 C8 N1 116.3(6) . .
C9 C8 H8A 108.2 . .
N1 C8 H8A 108.2 . .
C9 C8 H8B 108.2 . .
N1 C8 H8B 108.2 . .
H8A C8 H8B 107.4 . .
C10 C9 O2 109.4(7) . .
C10 C9 C8 135.3(8) . .
O2 C9 C8 115.3(7) . .
C9 C10 C11 107.8(8) . .
C9 C10 H10 126.1 . .
C11 C10 H10 126.1 . .
C12 C11 C10 105.2(8) . .
C12 C11 H11 127.4 . .
C10 C11 H11 127.4 . .
C11 C12 O2 111.8(8) . .
C11 C12 H12 124.1 . .
O2 C12 H12 124.1 . .
C4 C13 H13A 109.5 . .
C4 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C4 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
N2 C14 C6 124.0(7) . .
N2 C14 H14 118.0 . .
C6 C14 H14 118.0 . .
N2 C15 C16 112.2(6) . .
N2 C15 H15A 109.2 . .
C16 C15 H15A 109.2 . .
N2 C15 H15B 109.2 . .
C16 C15 H15B 109.2 . .
H15A C15 H15B 107.9 . .
C17 C16 O3 110.2(8) . .
C17 C16 C15 134.5(8) . .
O3 C16 C15 114.9(7) . .
C16 C17 C18 105.8(9) . .
C16 C17 H17 127.1 . .
C18 C17 H17 127.1 . .
C19 C18 C17 107.3(9) . .
C19 C18 H18 126.3 . .
C17 C18 H18 126.3 . .
C18 C19 O3 110.0(9) . .
C18 C19 H19 125.0 . .
O3 C19 H19 125.0 . .
O5 C20 O4 120.6(7) . .
O5 C20 C21 120.7(8) . .
O4 C20 C21 118.7(7) . .
O5 C20 Dy2 62.3(4) . .
O4 C20 Dy2 59.9(4) . .
C21 C20 Dy2 165.3(5) . .
C22 C21 C26 119.3(8) . .
C22 C21 C20 120.5(8) . .
C26 C21 C20 120.2(8) . .
C23 C22 C21 120.0(9) . .
C23 C22 H22 120.0 . .
C21 C22 H22 120.0 . .
C24 C23 C22 120.6(10) . .
C24 C23 H23 119.7 . .
C22 C23 H23 119.7 . .
C23 C24 C25 119.4(9) . .
C23 C24 H24 120.3 . .
C25 C24 H24 120.3 . .
C24 C25 C26 121.3(9) . .
C24 C25 H25 119.4 . .
C26 C25 H25 119.4 . .
C25 C26 C21 119.3(9) . .
C25 C26 H26 120.3 . .
C21 C26 H26 120.3 . .
O6 C27 O7 120.6(7) . .
O6 C27 C28 120.4(7) . .
O7 C27 C28 119.0(7) . .
O6 C27 Dy2 60.2(4) . .
O7 C27 Dy2 60.4(4) . .
C28 C27 Dy2 179.1(5) . .
C33 C28 C29 120.0(8) . .
C33 C28 C27 121.5(7) . .
C29 C28 C27 118.5(7) . .
C28 C29 C30 118.5(9) . .
C28 C29 H29 120.8 . .
C30 C29 H29 120.8 . .
C31 C30 C29 121.1(9) . .
C31 C30 H30 119.4 . .
C29 C30 H30 119.4 . .
C32 C31 C30 118.6(9) . .
C32 C31 H31 120.7 . .
C30 C31 H31 120.7 . .
C31 C32 C33 121.7(9) . .
C31 C32 H32 119.1 . .
C33 C32 H32 119.1 . .
C32 C33 C28 119.9(8) . .
C32 C33 H33 120.0 . .
C28 C33 H33 120.0 . .
O11 C34 O10 125.2(7) . .
O11 C34 C35 118.2(6) . .
O10 C34 C35 116.5(6) . .
C40 C35 C36 119.8(7) . .
C40 C35 C34 119.5(7) . .
C36 C35 C34 120.8(7) . .
C37 C36 C35 119.7(8) . .
C37 C36 H36 120.1 . .
C35 C36 H36 120.1 . .
C36 C37 C38 120.3(8) . .
C36 C37 H37 119.9 . .
C38 C37 H37 119.9 . .
C39 C38 C37 120.3(8) . .
C39 C38 H38 119.8 . .
C37 C38 H38 119.8 . .
C38 C39 C40 120.0(8) . .
C38 C39 H39 120.0 . .
C40 C39 H39 120.0 . .
C35 C40 C39 119.9(8) . .
C35 C40 H40 120.0 . .
C39 C40 H40 120.0 . .
O8 C41 O9 124.6(7) . .
O8 C41 C42 118.0(7) . .
O9 C41 C42 117.4(7) . .
C43 C42 C47 119.9(8) . .
C43 C42 C41 120.0(7) . .
C47 C42 C41 120.1(7) . .
C44 C43 C42 120.8(10) . .
C44 C43 H43 119.6 . .
C42 C43 H43 119.6 . .
C45 C44 C43 121.3(11) . .
C45 C44 H44 119.4 . .
C43 C44 H44 119.4 . .
C44 C45 C46 119.2(10) . .
C44 C45 H45 120.4 . .
C46 C45 H45 120.4 . .
C45 C46 C47 121.0(10) . .
C45 C46 H46 119.5 . .
C47 C46 H46 119.5 . .
C42 C47 C46 117.6(9) . .
C42 C47 H47 121.2 . .
C46 C47 H47 121.2 . .
O14 C48 O17 123.9(7) . 2_645
O14 C48 C49 119.1(7) . .
O17 C48 C49 117.0(7) 2_645 .
C54 C49 C50 120.0(7) . .
C54 C49 C48 120.1(7) . .
C50 C49 C48 119.9(7) . .
C51 C50 C49 120.1(8) . .
C51 C50 H50 120.0 . .
C49 C50 H50 120.0 . .
C52 C51 C50 119.7(8) . .
C52 C51 H51 120.2 . .
C50 C51 H51 120.2 . .
C51 C52 C53 122.1(8) . .
C51 C52 H52 119.0 . .
C53 C52 H52 119.0 . .
C52 C53 C54 118.0(8) . .
C52 C53 H53 121.0 . .
C54 C53 H53 121.0 . .
C49 C54 C53 120.2(8) . .
C49 C54 H54 119.9 . .
C53 C54 H54 119.9 . .
O12 C55 O13 120.7(8) . .
O12 C55 C56 119.4(8) . .
O13 C55 C56 119.9(8) . .
O12 C55 Dy1 58.4(4) . .
O13 C55 Dy1 62.3(4) . .
C56 C55 Dy1 177.3(5) . .
C57 C56 C61 118.4(8) . .
C57 C56 C55 120.2(8) . .
C61 C56 C55 121.4(8) . .
C56 C57 C58 120.1(9) . .
C56 C57 H57 120.0 . .
C58 C57 H57 120.0 . .
C59 C58 C57 120.6(10) . .
C59 C58 H58 119.7 . .
C57 C58 H58 119.7 . .
C58 C59 C60 119.4(10) . .
C58 C59 H59 120.3 . .
C60 C59 H59 120.3 . .
C61 C60 C59 120.1(10) . .
C61 C60 H60 119.9 . .
C59 C60 H60 119.9 . .
C60 C61 C56 121.4(10) . .
C60 C61 H61 119.3 . .
C56 C61 H61 119.3 . .
O16 C62 H62A 109.5 . .
O16 C62 H62B 109.5 . .
H62A C62 H62B 109.5 . .
O16 C62 H62C 109.5 . .
H62A C62 H62C 109.5 . .
H62B C62 H62C 109.5 . .
O15 C63 H63A 109.5 . .
O15 C63 H63B 109.5 . .
H63A C63 H63B 109.5 . .
O15 C63 H63C 109.5 . .
H63A C63 H63C 109.5 . .
H63B C63 H63C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O11 2.273(5) .
Dy1 O14 2.278(5) .
Dy1 O9 2.300(5) .
Dy1 O17 2.307(5) .
Dy1 O12 2.417(6) .
Dy1 O16 2.421(5) .
Dy1 O15 2.495(6) .
Dy1 O13 2.502(5) .
Dy1 C55 2.825(9) .
Dy2 O10 2.238(5) .
Dy2 O1 2.252(5) .
Dy2 O8 2.284(5) .
Dy2 O4 2.396(5) .
Dy2 O6 2.435(5) .
Dy2 O7 2.438(5) .
Dy2 O5 2.450(5) .
Dy2 N1 2.533(6) .
Dy2 C20 2.766(7) .
Dy2 C27 2.802(8) .
N1 C7 1.284(9) .
N1 C8 1.496(9) .
N2 C14 1.300(9) .
N2 C15 1.471(9) .
O1 C1 1.280(8) .
O1 H1 0.9500 .
O2 C12 1.342(10) .
O2 C9 1.363(9) .
O3 C19 1.359(10) .
O3 C16 1.371(9) .
O4 C20 1.264(9) .
O5 C20 1.256(9) .
O6 C27 1.256(8) .
O7 C27 1.277(8) .
O8 C41 1.243(9) .
O9 C41 1.252(8) .
O10 C34 1.264(8) .
O11 C34 1.242(8) .
O12 C55 1.261(9) .
O13 C55 1.274(9) .
O14 C48 1.216(8) .
O15 C63 1.409(10) .
O15 H15 0.9500 .
O16 C62 1.401(10) .
O16 H16 0.9500 .
O17 C48 1.258(8) 2_645
C1 C2 1.414(10) .
C1 C6 1.424(9) .
C2 C3 1.382(10) .
C2 C7 1.453(9) .
C3 C4 1.405(10) .
C3 H3 0.9500 .
C4 C5 1.373(11) .
C4 C13 1.485(10) .
C5 C6 1.423(10) .
C5 H5 0.9500 .
C6 C14 1.401(10) .
C7 H7 0.9500 .
C8 C9 1.491(11) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C9 C10 1.334(11) .
C10 C11 1.400(11) .
C10 H10 0.9500 .
C11 C12 1.331(12) .
C11 H11 0.9500 .
C12 H12 0.9500 .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C14 H14 0.9500 .
C15 C16 1.494(11) .
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C16 C17 1.343(11) .
C17 C18 1.424(12) .
C17 H17 0.9500 .
C18 C19 1.336(13) .
C18 H18 0.9500 .
C19 H19 0.9500 .
C20 C21 1.501(10) .
C21 C22 1.390(11) .
C21 C26 1.393(11) .
C22 C23 1.382(11) .
C22 H22 0.9500 .
C23 C24 1.370(13) .
C23 H23 0.9500 .
C24 C25 1.374(13) .
C24 H24 0.9500 .
C25 C26 1.378(12) .
C25 H25 0.9500 .
C26 H26 0.9500 .
C27 C28 1.483(11) .
C28 C33 1.380(10) .
C28 C29 1.390(11) .
C29 C30 1.404(13) .
C29 H29 0.9500 .
C30 C31 1.379(12) .
C30 H30 0.9500 .
C31 C32 1.368(13) .
C31 H31 0.9500 .
C32 C33 1.371(11) .
C32 H32 0.9500 .
C33 H33 0.9500 .
C34 C35 1.493(10) .
C35 C40 1.379(9) .
C35 C36 1.399(10) .
C36 C37 1.368(11) .
C36 H36 0.9500 .
C37 C38 1.385(12) .
C37 H37 0.9500 .
C38 C39 1.370(13) .
C38 H38 0.9500 .
C39 C40 1.388(11) .
C39 H39 0.9500 .
C40 H40 0.9500 .
C41 C42 1.505(10) .
C42 C43 1.383(10) .
C42 C47 1.393(11) .
C43 C44 1.363(12) .
C43 H43 0.9500 .
C44 C45 1.349(16) .
C44 H44 0.9500 .
C45 C46 1.393(15) .
C45 H45 0.9500 .
C46 C47 1.407(12) .
C46 H46 0.9500 .
C47 H47 0.9500 .
C48 O17 1.258(8) 2_645
C48 C49 1.505(10) .
C49 C54 1.382(10) .
C49 C50 1.395(10) .
C50 C51 1.377(11) .
C50 H50 0.9500 .
C51 C52 1.358(12) .
C51 H51 0.9500 .
C52 C53 1.397(12) .
C52 H52 0.9500 .
C53 C54 1.398(11) .
C53 H53 0.9500 .
C54 H54 0.9500 .
C55 C56 1.491(11) .
C56 C57 1.375(11) .
C56 C61 1.399(11) .
C57 C58 1.404(12) .
C57 H57 0.9500 .
C58 C59 1.369(13) .
C58 H58 0.9500 .
C59 C60 1.386(13) .
C59 H59 0.9500 .
C60 C61 1.366(13) .
C60 H60 0.9500 .
C61 H61 0.9500 .
C62 H62A 0.9800 .
C62 H62B 0.9800 .
C62 H62C 0.9800 .
C63 H63A 0.9800 .
C63 H63B 0.9800 .
C63 H63C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O10 Dy2 N1 C7 -148.2(6) . .
O1 Dy2 N1 C7 22.5(6) . .
O8 Dy2 N1 C7 119.9(6) . .
O4 Dy2 N1 C7 -73.0(6) . .
O6 Dy2 N1 C7 52.7(7) . .
O7 Dy2 N1 C7 150.7(5) . .
O5 Dy2 N1 C7 -65.0(6) . .
C20 Dy2 N1 C7 -72.3(6) . .
C27 Dy2 N1 C7 90.4(7) . .
O10 Dy2 N1 C8 24.4(5) . .
O1 Dy2 N1 C8 -164.9(5) . .
O8 Dy2 N1 C8 -67.6(5) . .
O4 Dy2 N1 C8 99.5(5) . .
O6 Dy2 N1 C8 -134.7(4) . .
O7 Dy2 N1 C8 -36.8(7) . .
O5 Dy2 N1 C8 107.5(5) . .
C20 Dy2 N1 C8 100.2(5) . .
C27 Dy2 N1 C8 -97.1(6) . .
O10 Dy2 O1 C1 -8.8(10) . .
O8 Dy2 O1 C1 -105.1(7) . .
O4 Dy2 O1 C1 96.0(7) . .
O6 Dy2 O1 C1 172.0(8) . .
O7 Dy2 O1 C1 178.1(7) . .
O5 Dy2 O1 C1 46.6(7) . .
N1 Dy2 O1 C1 -29.4(7) . .
C20 Dy2 O1 C1 69.3(7) . .
C27 Dy2 O1 C1 174.9(7) . .
O10 Dy2 O4 C20 76.6(4) . .
O1 Dy2 O4 C20 -77.2(4) . .
O8 Dy2 O4 C20 153.6(4) . .
O6 Dy2 O4 C20 -144.4(4) . .
O7 Dy2 O4 C20 161.2(4) . .
O5 Dy2 O4 C20 -8.0(4) . .
N1 Dy2 O4 C20 1.6(5) . .
C27 Dy2 O4 C20 -171.0(5) . .
O10 Dy2 O5 C20 -79.5(4) . .
O1 Dy2 O5 C20 122.7(4) . .
O8 Dy2 O5 C20 -154.1(4) . .
O4 Dy2 O5 C20 8.0(4) . .
O6 Dy2 O5 C20 60.1(5) . .
O7 Dy2 O5 C20 -5.2(5) . .
N1 Dy2 O5 C20 -164.1(5) . .
C27 Dy2 O5 C20 29.5(5) . .
O10 Dy2 O6 C27 -6.0(5) . .
O1 Dy2 O6 C27 173.5(5) . .
O8 Dy2 O6 C27 78.4(4) . .
O4 Dy2 O6 C27 -77.3(4) . .
O7 Dy2 O6 C27 -0.3(4) . .
O5 Dy2 O6 C27 -117.2(4) . .
N1 Dy2 O6 C27 143.0(4) . .
C20 Dy2 O6 C27 -93.2(4) . .
O10 Dy2 O7 C27 176.3(4) . .
O1 Dy2 O7 C27 -6.9(5) . .
O8 Dy2 O7 C27 -91.9(4) . .
O4 Dy2 O7 C27 91.7(4) . .
O6 Dy2 O7 C27 0.2(4) . .
O5 Dy2 O7 C27 102.7(4) . .
N1 Dy2 O7 C27 -122.7(5) . .
C20 Dy2 O7 C27 100.3(4) . .
O10 Dy2 O8 C41 85.8(11) . .
O1 Dy2 O8 C41 -121.1(11) . .
O4 Dy2 O8 C41 10.5(13) . .
O6 Dy2 O8 C41 -51.1(11) . .
O7 Dy2 O8 C41 2.9(11) . .
O5 Dy2 O8 C41 158.2(10) . .
N1 Dy2 O8 C41 168.1(11) . .
C20 Dy2 O8 C41 86.5(15) . .
C27 Dy2 O8 C41 -24.6(11) . .
O11 Dy1 O9 C41 10.5(9) . .
O14 Dy1 O9 C41 -140.4(9) . .
O17 Dy1 O9 C41 102.2(9) . .
O12 Dy1 O9 C41 -61.9(9) . .
O16 Dy1 O9 C41 80.7(9) . .
O15 Dy1 O9 C41 150.6(9) . .
O13 Dy1 O9 C41 -73.3(9) . .
C55 Dy1 O9 C41 -66.5(9) . .
O1 Dy2 O10 C34 -111.0(14) . .
O8 Dy2 O10 C34 -14.1(14) . .
O4 Dy2 O10 C34 139.0(14) . .
O6 Dy2 O10 C34 67.9(14) . .
O7 Dy2 O10 C34 63.2(14) . .
O5 Dy2 O10 C34 -166.8(14) . .
N1 Dy2 O10 C34 -91.3(14) . .
C20 Dy2 O10 C34 166.0(14) . .
C27 Dy2 O10 C34 65.0(14) . .
O14 Dy1 O11 C34 155.4(9) . .
O9 Dy1 O11 C34 49.5(10) . .
O17 Dy1 O11 C34 -99.5(10) . .
O12 Dy1 O11 C34 124.4(10) . .
O16 Dy1 O11 C34 -20.5(10) . .
O15 Dy1 O11 C34 -41.0(11) . .
O13 Dy1 O11 C34 179.0(10) . .
C55 Dy1 O11 C34 151.7(10) . .
O11 Dy1 O12 C55 85.6(4) . .
O14 Dy1 O12 C55 -78.9(5) . .
O9 Dy1 O12 C55 -169.9(5) . .
O17 Dy1 O12 C55 20.7(5) . .
O16 Dy1 O12 C55 135.9(4) . .
O15 Dy1 O12 C55 -109.6(5) . .
O13 Dy1 O12 C55 -0.8(4) . .
O11 Dy1 O13 C55 -79.5(4) . .
O14 Dy1 O13 C55 88.4(4) . .
O9 Dy1 O13 C55 14.8(5) . .
O17 Dy1 O13 C55 -162.9(5) . .
O12 Dy1 O13 C55 0.8(4) . .
O16 Dy1 O13 C55 -115.3(5) . .
O15 Dy1 O13 C55 132.3(4) . .
O11 Dy1 O14 C48 39(3) . .
O9 Dy1 O14 C48 148(3) . .
O17 Dy1 O14 C48 -60(3) . .
O12 Dy1 O14 C48 70(3) . .
O16 Dy1 O14 C48 -146(3) . .
O15 Dy1 O14 C48 -130(3) . .
O13 Dy1 O14 C48 15(3) . .
C55 Dy1 O14 C48 43(3) . .
O11 Dy1 O15 C63 72.0(8) . .
O14 Dy1 O15 C63 -116.8(8) . .
O9 Dy1 O15 C63 -25.2(7) . .
O17 Dy1 O15 C63 131.8(7) . .
O12 Dy1 O15 C63 -84.5(8) . .
O16 Dy1 O15 C63 50.8(7) . .
O13 Dy1 O15 C63 -162.4(7) . .
C55 Dy1 O15 C63 -128.7(7) . .
O11 Dy1 O16 C62 -92.5(8) . .
O14 Dy1 O16 C62 90.5(8) . .
O9 Dy1 O16 C62 161.3(8) . .
O17 Dy1 O16 C62 -7.7(8) . .
O12 Dy1 O16 C62 -143.1(7) . .
O15 Dy1 O16 C62 73.7(8) . .
O13 Dy1 O16 C62 -55.9(9) . .
C55 Dy1 O16 C62 -106.9(8) . .
O11 Dy1 O17 C48 -147.8(8) . 2_645
O14 Dy1 O17 C48 1.9(8) . 2_645
O9 Dy1 O17 C48 115.2(8) . 2_645
O12 Dy1 O17 C48 -85.4(8) . 2_645
O16 Dy1 O17 C48 136.5(8) . 2_645
O15 Dy1 O17 C48 65.9(8) . 2_645
O13 Dy1 O17 C48 -68.2(8) . 2_645
C55 Dy1 O17 C48 -76.1(8) . 2_645
Dy2 O1 C1 C2 21.0(11) . .
Dy2 O1 C1 C6 -158.9(5) . .
O1 C1 C2 C3 179.1(7) . .
C6 C1 C2 C3 -0.9(11) . .
O1 C1 C2 C7 8.2(11) . .
C6 C1 C2 C7 -171.9(7) . .
C1 C2 C3 C4 4.3(12) . .
C7 C2 C3 C4 175.9(7) . .
C2 C3 C4 C5 -5.0(12) . .
C2 C3 C4 C13 -178.6(8) . .
C3 C4 C5 C6 2.5(12) . .
C13 C4 C5 C6 176.3(8) . .
C4 C5 C6 C14 -175.7(8) . .
C4 C5 C6 C1 0.4(12) . .
O1 C1 C6 C14 -5.3(11) . .
C2 C1 C6 C14 174.7(7) . .
O1 C1 C6 C5 178.7(7) . .
C2 C1 C6 C5 -1.3(10) . .
C8 N1 C7 C2 174.7(7) . .
Dy2 N1 C7 C2 -13.0(11) . .
C3 C2 C7 N1 -179.9(7) . .
C1 C2 C7 N1 -8.8(12) . .
C7 N1 C8 C9 -7.4(10) . .
Dy2 N1 C8 C9 179.3(5) . .
C12 O2 C9 C10 1.7(9) . .
C12 O2 C9 C8 -179.6(7) . .
N1 C8 C9 C10 109.5(10) . .
N1 C8 C9 O2 -68.8(9) . .
O2 C9 C10 C11 -1.5(9) . .
C8 C9 C10 C11 -179.9(8) . .
C9 C10 C11 C12 0.7(10) . .
C10 C11 C12 O2 0.3(11) . .
C9 O2 C12 C11 -1.2(10) . .
C15 N2 C14 C6 -175.6(7) . .
C5 C6 C14 N2 177.3(7) . .
C1 C6 C14 N2 1.3(12) . .
C14 N2 C15 C16 86.7(9) . .
C19 O3 C16 C17 -1.0(9) . .
C19 O3 C16 C15 -175.1(7) . .
N2 C15 C16 C17 131.1(10) . .
N2 C15 C16 O3 -56.7(9) . .
O3 C16 C17 C18 0.0(10) . .
C15 C16 C17 C18 172.4(9) . .
C16 C17 C18 C19 1.1(10) . .
C17 C18 C19 O3 -1.8(11) . .
C16 O3 C19 C18 1.7(10) . .
Dy2 O5 C20 O4 -14.3(7) . .
Dy2 O5 C20 C21 163.5(6) . .
Dy2 O4 C20 O5 14.7(7) . .
Dy2 O4 C20 C21 -163.2(5) . .
O10 Dy2 C20 O5 95.5(4) . .
O1 Dy2 C20 O5 -57.5(4) . .
O8 Dy2 C20 O5 94.7(11) . .
O4 Dy2 C20 O5 -165.7(7) . .
O6 Dy2 C20 O5 -129.2(4) . .
O7 Dy2 C20 O5 175.8(4) . .
N1 Dy2 C20 O5 15.6(5) . .
C27 Dy2 C20 O5 -156.6(4) . .
O10 Dy2 C20 O4 -98.8(4) . .
O1 Dy2 C20 O4 108.2(4) . .
O8 Dy2 C20 O4 -99.6(11) . .
O6 Dy2 C20 O4 36.6(4) . .
O7 Dy2 C20 O4 -18.5(4) . .
O5 Dy2 C20 O4 165.7(7) . .
N1 Dy2 C20 O4 -178.7(4) . .
C27 Dy2 C20 O4 9.1(5) . .
O10 Dy2 C20 C21 -10(2) . .
O1 Dy2 C20 C21 -163(2) . .
O8 Dy2 C20 C21 -11(3) . .
O4 Dy2 C20 C21 88(2) . .
O6 Dy2 C20 C21 125(2) . .
O7 Dy2 C20 C21 70(2) . .
O5 Dy2 C20 C21 -106(2) . .
N1 Dy2 C20 C21 -90(2) . .
C27 Dy2 C20 C21 97(2) . .
O5 C20 C21 C22 -5.9(10) . .
O4 C20 C21 C22 172.0(7) . .
Dy2 C20 C21 C22 92(2) . .
O5 C20 C21 C26 174.6(7) . .
O4 C20 C21 C26 -7.5(10) . .
Dy2 C20 C21 C26 -88(2) . .
C26 C21 C22 C23 1.7(11) . .
C20 C21 C22 C23 -177.8(7) . .
C21 C22 C23 C24 -0.2(13) . .
C22 C23 C24 C25 -1.6(14) . .
C23 C24 C25 C26 1.7(14) . .
C24 C25 C26 C21 -0.2(14) . .
C22 C21 C26 C25 -1.6(12) . .
C20 C21 C26 C25 177.9(7) . .
Dy2 O6 C27 O7 0.4(7) . .
Dy2 O6 C27 C28 -179.2(6) . .
Dy2 O7 C27 O6 -0.4(7) . .
Dy2 O7 C27 C28 179.2(6) . .
O10 Dy2 C27 O6 175.6(4) . .
O1 Dy2 C27 O6 -6.2(4) . .
O8 Dy2 C27 O6 -97.9(4) . .
O4 Dy2 C27 O6 98.0(4) . .
O7 Dy2 C27 O6 179.6(7) . .
O5 Dy2 C27 O6 80.4(5) . .
N1 Dy2 C27 O6 -68.7(6) . .
C20 Dy2 C27 O6 93.7(4) . .
O10 Dy2 C27 O7 -3.9(5) . .
O1 Dy2 C27 O7 174.3(4) . .
O8 Dy2 C27 O7 82.6(4) . .
O4 Dy2 C27 O7 -81.6(4) . .
O6 Dy2 C27 O7 -179.6(7) . .
O5 Dy2 C27 O7 -99.2(4) . .
N1 Dy2 C27 O7 111.8(5) . .
C20 Dy2 C27 O7 -85.8(4) . .
O10 Dy2 C27 C28 -53(36) . .
O1 Dy2 C27 C28 125(36) . .
O8 Dy2 C27 C28 34(36) . .
O4 Dy2 C27 C28 -131(36) . .
O6 Dy2 C27 C28 132(36) . .
O7 Dy2 C27 C28 -49(36) . .
O5 Dy2 C27 C28 -148(36) . .
N1 Dy2 C27 C28 63(36) . .
C20 Dy2 C27 C28 -135(36) . .
O6 C27 C28 C33 -163.2(7) . .
O7 C27 C28 C33 17.2(11) . .
Dy2 C27 C28 C33 66(36) . .
O6 C27 C28 C29 16.9(11) . .
O7 C27 C28 C29 -162.7(7) . .
Dy2 C27 C28 C29 -114(36) . .
C33 C28 C29 C30 1.1(13) . .
C27 C28 C29 C30 -179.0(8) . .
C28 C29 C30 C31 1.3(15) . .
C29 C30 C31 C32 -1.9(16) . .
C30 C31 C32 C33 0.1(15) . .
C31 C32 C33 C28 2.3(14) . .
C29 C28 C33 C32 -2.8(13) . .
C27 C28 C33 C32 177.3(8) . .
Dy1 O11 C34 O10 -48.7(15) . .
Dy1 O11 C34 C35 132.0(8) . .
Dy2 O10 C34 O11 9(2) . .
Dy2 O10 C34 C35 -171.2(10) . .
O11 C34 C35 C40 -19.3(11) . .
O10 C34 C35 C40 161.4(7) . .
O11 C34 C35 C36 162.6(7) . .
O10 C34 C35 C36 -16.8(11) . .
C40 C35 C36 C37 1.3(12) . .
C34 C35 C36 C37 179.4(7) . .
C35 C36 C37 C38 -2.2(13) . .
C36 C37 C38 C39 1.0(14) . .
C37 C38 C39 C40 1.1(14) . .
C36 C35 C40 C39 0.9(12) . .
C34 C35 C40 C39 -177.3(7) . .
C38 C39 C40 C35 -2.1(13) . .
Dy2 O8 C41 O9 -74.4(13) . .
Dy2 O8 C41 C42 108.3(10) . .
Dy1 O9 C41 O8 -11.1(14) . .
Dy1 O9 C41 C42 166.2(6) . .
O8 C41 C42 C43 -10.6(11) . .
O9 C41 C42 C43 171.9(7) . .
O8 C41 C42 C47 167.8(7) . .
O9 C41 C42 C47 -9.7(11) . .
C47 C42 C43 C44 0.0(13) . .
C41 C42 C43 C44 178.5(8) . .
C42 C43 C44 C45 -1.3(16) . .
C43 C44 C45 C46 1.4(17) . .
C44 C45 C46 C47 -0.3(16) . .
C43 C42 C47 C46 1.0(12) . .
C41 C42 C47 C46 -177.4(8) . .
C45 C46 C47 C42 -0.9(14) . .
Dy1 O14 C48 O17 64(3) . 2_645
Dy1 O14 C48 C49 -118(3) . .
O14 C48 C49 C54 -173.7(8) . .
O17 C48 C49 C54 4.7(11) 2_645 .
O14 C48 C49 C50 5.4(12) . .
O17 C48 C49 C50 -176.2(7) 2_645 .
C54 C49 C50 C51 -0.1(12) . .
C48 C49 C50 C51 -179.1(8) . .
C49 C50 C51 C52 -0.8(13) . .
C50 C51 C52 C53 -0.1(14) . .
C51 C52 C53 C54 1.9(14) . .
C50 C49 C54 C53 1.9(12) . .
C48 C49 C54 C53 -179.1(7) . .
C52 C53 C54 C49 -2.7(13) . .
Dy1 O12 C55 O13 1.4(7) . .
Dy1 O12 C55 C56 -178.2(6) . .
Dy1 O13 C55 O12 -1.3(7) . .
Dy1 O13 C55 C56 178.3(6) . .
O11 Dy1 C55 O12 -87.2(4) . .
O14 Dy1 C55 O12 94.7(5) . .
O9 Dy1 C55 O12 10.2(5) . .
O17 Dy1 C55 O12 -163.9(4) . .
O16 Dy1 C55 O12 -72.8(6) . .
O15 Dy1 C55 O12 106.2(5) . .
O13 Dy1 C55 O12 178.6(7) . .
O11 Dy1 C55 O13 94.1(4) . .
O14 Dy1 C55 O13 -83.9(4) . .
O9 Dy1 C55 O13 -168.5(4) . .
O17 Dy1 C55 O13 17.5(5) . .
O12 Dy1 C55 O13 -178.6(7) . .
O16 Dy1 C55 O13 108.5(5) . .
O15 Dy1 C55 O13 -72.4(6) . .
O11 Dy1 C55 C56 -51(12) . .
O14 Dy1 C55 C56 130(12) . .
O9 Dy1 C55 C56 46(12) . .
O17 Dy1 C55 C56 -128(12) . .
O12 Dy1 C55 C56 36(12) . .
O16 Dy1 C55 C56 -37(13) . .
O15 Dy1 C55 C56 142(12) . .
O13 Dy1 C55 C56 -146(13) . .
O12 C55 C56 C57 1.7(11) . .
O13 C55 C56 C57 -177.9(7) . .
Dy1 C55 C56 C57 -33(13) . .
O12 C55 C56 C61 -178.9(8) . .
O13 C55 C56 C61 1.5(12) . .
Dy1 C55 C56 C61 146(12) . .
C61 C56 C57 C58 -1.0(12) . .
C55 C56 C57 C58 178.4(7) . .
C56 C57 C58 C59 1.0(13) . .
C57 C58 C59 C60 -0.3(14) . .
C58 C59 C60 C61 -0.4(15) . .
C59 C60 C61 C56 0.5(15) . .
C57 C56 C61 C60 0.2(14) . .
C55 C56 C61 C60 -179.2(9) . .
