#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/81/7018189.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7018189
loop_
_publ_author_name
'Vajpayee, Vaishali'
'Song, Young Ho'
'Jung, Young Jun'
'Kang, Se Chan'
'Kim, Hyunuk'
'Kim, In Su'
'Wang, Ming'
'Cook, Timothy R.'
'Stang, Peter J.'
'Chi, Ki-Whan'
_publ_section_title
;
 Coordination-driven self-assembly of ruthenium-based
 molecular-rectangles: Synthesis, characterization, photo-physical and
 anticancer potency studies.
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3046
_journal_page_last               3052
_journal_paper_doi               10.1039/c2dt11811d
_journal_volume                  41
_journal_year                    2012
_chemical_formula_moiety         'C72 H72 N4 O8 Ru4, 4(F6 P), C H3 N O2'
_chemical_formula_sum            'C36.5 H37.5 F12 N2.5 O5 P2 Ru2'
_chemical_formula_weight         1083.27
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 97.55(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   8.6300(17)
_cell_length_b                   35.969(7)
_cell_length_c                   13.430(3)
_cell_measurement_reflns_used    17417
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      30.36
_cell_measurement_theta_min      1.43
_cell_volume                     4132.7(15)
_computing_cell_refinement       'DENZO (Z. Otwinowski and W. Minor, 1997)'
_computing_data_collection       'ADSC Quantum software'
_computing_data_reduction        'HKL2000 (Z. Otwinowski and W. Minor, 1997)'
_computing_molecular_graphics    'Materials Studio 4.1'
_computing_publication_material  'Materials Studio 4.1'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.841
_diffrn_measurement_device_type  'ADSC Quantum 210'
_diffrn_measurement_method       ω-scan
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         synchrotron-PAL
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.90000
_diffrn_reflns_av_R_equivalents  0.0339
_diffrn_reflns_av_sigmaI/netI    0.0312
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       39
_diffrn_reflns_limit_k_min       -40
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            17417
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         30.36
_diffrn_reflns_theta_min         1.43
_exptl_absorpt_coefficient_mu    1.697
_exptl_absorpt_correction_T_max  0.9200
_exptl_absorpt_correction_T_min  0.6300
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   HKL2000
_exptl_crystal_density_diffrn    1.741
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2160
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.040
_refine_diff_density_min         -1.025
_refine_diff_density_rms         0.127
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     561
_refine_ls_number_reflns         5158
_refine_ls_number_restraints     20
_refine_ls_restrained_S_all      1.028
_refine_ls_R_factor_all          0.0679
_refine_ls_R_factor_gt           0.0550
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1180P)²+8.0115P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1557
_refine_ls_wR_factor_ref         0.1656
_reflns_number_gt                4202
_reflns_number_total             5158
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt11811d.txt
_cod_data_source_block           p21n
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        4132.7(14)
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_original_formula_sum        'C36.50 H37.50 F12 N2.50 O5 P2 Ru2'
_cod_database_code               7018189
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ru1 Ru 0.56203(7) 0.147503(15) 0.02158(4) 0.0477(2) Uani 1 1 d .
Ru2 Ru 0.28678(7) 0.161439(15) 0.36621(4) 0.0451(2) Uani 1 1 d .
P1 P 0.3329(3) 0.06285(6) 0.67826(14) 0.0661(7) Uani 1 1 d .
P2 P 0.0382(3) 0.22830(6) -0.27824(15) 0.0614(6) Uani 1 1 d .
F1 F 0.4418(7) 0.05057(13) 0.7781(3) 0.0879(17) Uani 1 1 d .
F2 F 0.2839(7) 0.09931(14) 0.7334(4) 0.0907(16) Uani 1 1 d .
F3 F 0.4747(6) 0.08448(16) 0.6427(4) 0.0889(16) Uani 1 1 d .
F4 F 0.1851(8) 0.04169(15) 0.7132(4) 0.1006(19) Uani 1 1 d .
F5 F 0.3758(7) 0.02598(14) 0.6240(4) 0.101(2) Uani 1 1 d .
F6 F 0.2203(6) 0.07556(12) 0.5783(3) 0.0709(13) Uani 1 1 d .
F7 F 0.1378(6) 0.19223(13) -0.2424(4) 0.0807(15) Uani 1 1 d .
F8 F 0.0950(6) 0.24873(14) -0.1744(4) 0.0811(15) Uani 1 1 d .
F9 F 0.1881(6) 0.24466(15) -0.3236(4) 0.0896(16) Uani 1 1 d .
F10 F -0.0617(6) 0.26463(12) -0.3148(3) 0.0737(13) Uani 1 1 d .
F11 F -0.1093(6) 0.21243(13) -0.2312(3) 0.0728(13) Uani 1 1 d .
F12 F -0.0199(6) 0.20855(13) -0.3824(3) 0.0782(14) Uani 1 1 d .
O1 O 0.2270(6) 0.15934(12) 0.2087(4) 0.0496(13) Uani 1 1 d .
O2 O 0.5101(6) 0.15899(12) 0.3187(3) 0.0500(13) Uani 1 1 d .
O3 O 0.3399(6) 0.15478(12) 0.0673(3) 0.0483(12) Uani 1 1 d .
O4 O 0.6206(7) 0.15305(13) 0.1780(4) 0.0513(13) Uani 1 1 d .
N1 N 0.3016(7) 0.10307(16) 0.3553(4) 0.0466(15) Uani 1 1 d .
N2 N -0.5167(7) -0.09110(16) -0.0556(4) 0.0486(15) Uani 1 1 d .
C1 C 0.3444(10) 0.15746(18) 0.1620(6) 0.0469(19) Uani 1 1 d .
C2 C 0.5042(10) 0.15697(18) 0.2243(5) 0.0436(18) Uani 1 1 d .
C3 C 0.1516(9) 0.2119(2) 0.3725(5) 0.054(2) Uani 1 1 d .
H3 H 0.1153 0.2251 0.3081 0.065 Uiso 1 1 calc R
C4 C 0.3029(9) 0.21920(19) 0.4198(5) 0.0527(19) Uani 1 1 d .
H4 H 0.3704 0.2373 0.3887 0.063 Uiso 1 1 calc R
C5 C 0.1288(10) 0.1585(2) 0.4791(6) 0.056(2) Uani 1 1 d .
H5 H 0.0777 0.1342 0.4902 0.067 Uiso 1 1 calc R
C6 C 0.0617(9) 0.1812(2) 0.4002(5) 0.054(2) Uani 1 1 d .
C7 C 0.3734(9) 0.1944(2) 0.4994(5) 0.0509(19) Uani 1 1 d .
C8 C 0.2831(10) 0.16502(19) 0.5288(5) 0.0510(19) Uani 1 1 d .
H8 H 0.3357 0.1451 0.5729 0.061 Uiso 1 1 calc R
C9 C 0.5402(9) 0.2018(2) 0.5425(6) 0.059(2) Uani 1 1 d .
H9 H 0.5968 0.2102 0.4862 0.070 Uiso 1 1 calc R
C10 C 0.6244(11) 0.1674(3) 0.5888(7) 0.083(3) Uani 1 1 d .
H10A H 0.7325 0.1738 0.6149 0.124 Uiso 1 1 calc R
H10B H 0.6242 0.1480 0.5375 0.124 Uiso 1 1 calc R
H10C H 0.5706 0.1582 0.6438 0.124 Uiso 1 1 calc R
C11 C 0.5406(11) 0.2336(3) 0.6152(8) 0.094(3) Uani 1 1 d .
H11A H 0.6483 0.2390 0.6445 0.141 Uiso 1 1 calc R
H11B H 0.4787 0.2268 0.6687 0.141 Uiso 1 1 calc R
H11C H 0.4951 0.2556 0.5797 0.141 Uiso 1 1 calc R
C12 C -0.0962(10) 0.1730(2) 0.3452(7) 0.070(2) Uani 1 1 d .
H12A H -0.1206 0.1466 0.3531 0.106 Uiso 1 1 calc R
H12B H -0.0973 0.1787 0.2738 0.106 Uiso 1 1 calc R
H12C H -0.1745 0.1883 0.3727 0.106 Uiso 1 1 calc R
C13 C 0.1946(9) 0.08365(19) 0.2964(5) 0.0513(19) Uani 1 1 d .
H13 H 0.1102 0.0967 0.2596 0.062 Uiso 1 1 calc R
C14 C 0.4213(10) 0.0842(2) 0.4051(5) 0.054(2) Uani 1 1 d .
H14 H 0.5002 0.0978 0.4457 0.064 Uiso 1 1 calc R
C15 C 0.4361(10) 0.0461(2) 0.4006(5) 0.056(2) Uani 1 1 d .
H15 H 0.5219 0.0339 0.4385 0.067 Uiso 1 1 calc R
C16 C 0.2001(9) 0.04484(19) 0.2860(5) 0.0522(19) Uani 1 1 d .
C17 C 0.3243(10) 0.0260(2) 0.3402(5) 0.062(2) Uani 1 1 d .
H17 H 0.3322 -0.0003 0.3358 0.074 Uiso 1 1 calc R
C18 C 0.0868(10) 0.0264(2) 0.2185(6) 0.057(2) Uani 1 1 d .
C19 C -0.0102(10) 0.0112(2) 0.1597(6) 0.060(2) Uani 1 1 d .
C20 C -0.1229(10) -0.0061(2) 0.0920(5) 0.056(2) Uani 1 1 d .
C21 C -0.2233(10) -0.02064(19) 0.0371(5) 0.055(2) Uani 1 1 d .
C22 C -0.3517(9) -0.03795(19) -0.0239(5) 0.053(2) Uani 1 1 d .
C23 C -0.3975(9) -0.07424(19) -0.0016(5) 0.0496(18) Uani 1 1 d .
H23 H -0.3415 -0.0870 0.0538 0.060 Uiso 1 1 calc R
C24 C -0.4372(10) -0.0196(2) -0.1050(6) 0.060(2) Uani 1 1 d .
H24 H -0.4095 0.0050 -0.1219 0.072 Uiso 1 1 calc R
C25 C -0.5614(9) -0.03716(19) -0.1600(5) 0.053(2) Uani 1 1 d .
H25 H -0.6214 -0.0249 -0.2149 0.064 Uiso 1 1 calc R
C26 C -0.5975(9) -0.0732(2) -0.1338(5) 0.0529(19) Uani 1 1 d .
H26 H -0.6822 -0.0856 -0.1724 0.064 Uiso 1 1 calc R
C27 C 0.4903(11) 0.1639(2) -0.1334(6) 0.059(2) Uani 1 1 d .
H27 H 0.3803 0.1592 -0.1647 0.071 Uiso 1 1 calc R
C28 C 0.5259(10) 0.1967(2) -0.0740(5) 0.056(2) Uani 1 1 d .
C29 C 0.6729(10) 0.1990(2) -0.0140(6) 0.057(2) Uani 1 1 d .
H29 H 0.6899 0.2189 0.0386 0.068 Uiso 1 1 calc R
C30 C 0.7829(10) 0.1693(2) -0.0114(6) 0.060(2) Uani 1 1 d .
H30 H 0.8740 0.1691 0.0429 0.072 Uiso 1 1 calc R
C31 C 0.7518(10) 0.1372(2) -0.0702(6) 0.059(2) Uani 1 1 d .
C32 C 0.4019(10) 0.2251(2) -0.0693(6) 0.064(2) Uani 1 1 d .
H32A H 0.4350 0.2427 -0.0149 0.097 Uiso 1 1 calc R
H32B H 0.3049 0.2129 -0.0568 0.097 Uiso 1 1 calc R
H32C H 0.3840 0.2386 -0.1333 0.097 Uiso 1 1 calc R
C33 C 0.8626(11) 0.1054(2) -0.0684(6) 0.071(2) Uani 1 1 d .
H33 H 0.7985 0.0822 -0.0750 0.085 Uiso 1 1 calc R
C34 C 0.9442(17) 0.1083(4) -0.1623(10) 0.160(7) Uani 1 1 d .
H34A H 1.0175 0.0875 -0.1637 0.240 Uiso 1 1 calc R
H34B H 1.0014 0.1318 -0.1613 0.240 Uiso 1 1 calc R
H34C H 0.8661 0.1073 -0.2222 0.240 Uiso 1 1 calc R
C35 C 0.6024(10) 0.1352(2) -0.1326(6) 0.060(2) Uani 1 1 d .
H35 H 0.5674 0.1106 -0.1618 0.071 Uiso 1 1 calc R
C36 C 0.9737(11) 0.1021(2) 0.0264(7) 0.080(3) Uani 1 1 d .
H36A H 1.0416 0.0805 0.0221 0.119 Uiso 1 1 calc R
H36B H 0.9147 0.0991 0.0834 0.119 Uiso 1 1 calc R
H36C H 1.0377 0.1247 0.0360 0.119 Uiso 1 1 calc R
O1N O -0.1974(16) 0.0624(6) 0.5445(12) 0.124(6) Uani 0.50 1 d PDU
O2N O -0.1433(16) 0.0706(4) 0.3889(12) 0.093(4) Uani 0.50 1 d PDU
N1N N -0.155(2) 0.0660(10) 0.4712(12) 0.139(9) Uani 0.50 1 d PDU
C1N C -0.079(4) 0.0339(11) 0.4774(14) 0.194(15) Uani 0.50 1 d PDU
H1N1 H -0.0294 0.0302 0.4165 0.291 Uiso 0.50 1 calc PR
H1N2 H -0.1528 0.0136 0.4838 0.291 Uiso 0.50 1 calc PR
H1N3 H 0.0012 0.0342 0.5362 0.291 Uiso 0.50 1 calc PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C -0.0020 0.0028 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N -0.0031 0.0056 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O -0.0042 0.0102 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1274 0.1530 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -0.9454 1.2848 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F -0.0055 0.0172 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O4 Ru1 O3 78.8(2) . .
O4 Ru1 N2 84.40(19) . 3
O3 Ru1 N2 81.7(2) . 3
O4 Ru1 C30 93.9(3) . .
O3 Ru1 C30 151.3(2) . .
N2 Ru1 C30 125.6(3) 3 .
O4 Ru1 C29 94.8(2) . .
O3 Ru1 C29 113.8(2) . .
N2 Ru1 C29 164.1(3) 3 .
C30 Ru1 C29 38.5(3) . .
O4 Ru1 C27 158.6(2) . .
O3 Ru1 C27 95.2(3) . .
N2 Ru1 C27 115.3(2) 3 .
C30 Ru1 C27 81.6(3) . .
C29 Ru1 C27 68.7(3) . .
O4 Ru1 C28 120.4(2) . .
O3 Ru1 C28 90.3(3) . .
N2 Ru1 C28 152.0(3) 3 .
C30 Ru1 C28 69.3(3) . .
C29 Ru1 C28 37.9(3) . .
C27 Ru1 C28 38.5(3) . .
O4 Ru1 C35 156.3(3) . .
O3 Ru1 C35 124.4(3) . .
N2 Ru1 C35 93.9(3) 3 .
C30 Ru1 C35 68.0(3) . .
C29 Ru1 C35 80.5(3) . .
C27 Ru1 C35 37.8(3) . .
C28 Ru1 C35 68.7(3) . .
O4 Ru1 C31 118.4(3) . .
O3 Ru1 C31 162.8(3) . .
N2 Ru1 C31 97.5(3) 3 .
C30 Ru1 C31 37.5(3) . .
C29 Ru1 C31 68.9(3) . .
C27 Ru1 C31 69.5(3) . .
C28 Ru1 C31 82.4(3) . .
C35 Ru1 C31 38.4(3) . .
O1 Ru2 N1 84.48(18) . .
O1 Ru2 O2 78.9(2) . .
N1 Ru2 O2 82.6(2) . .
O1 Ru2 C3 90.4(2) . .
N1 Ru2 C3 151.0(3) . .
O2 Ru2 C3 124.4(2) . .
O1 Ru2 C5 127.2(3) . .
N1 Ru2 C5 92.9(2) . .
O2 Ru2 C5 153.1(3) . .
C3 Ru2 C5 67.8(3) . .
O1 Ru2 C6 96.6(2) . .
N1 Ru2 C6 113.9(3) . .
O2 Ru2 C6 162.6(2) . .
C3 Ru2 C6 38.4(3) . .
C5 Ru2 C6 37.7(3) . .
O1 Ru2 C7 148.0(2) . .
N1 Ru2 C7 125.3(2) . .
O2 Ru2 C7 92.4(2) . .
C3 Ru2 C7 69.0(3) . .
C5 Ru2 C7 68.6(3) . .
C6 Ru2 C7 82.5(3) . .
O1 Ru2 C4 111.0(2) . .
N1 Ru2 C4 164.2(2) . .
O2 Ru2 C4 96.8(2) . .
C3 Ru2 C4 37.4(3) . .
C5 Ru2 C4 80.5(3) . .
C6 Ru2 C4 69.0(3) . .
C7 Ru2 C4 38.9(3) . .
O1 Ru2 C8 165.1(3) . .
N1 Ru2 C8 97.9(2) . .
O2 Ru2 C8 115.9(3) . .
C3 Ru2 C8 80.4(3) . .
C5 Ru2 C8 38.2(3) . .
C6 Ru2 C8 69.0(3) . .
C7 Ru2 C8 37.2(3) . .
C4 Ru2 C8 68.1(3) . .
F3 P1 F5 92.1(4) . .
F3 P1 F2 89.9(3) . .
F5 P1 F2 178.0(4) . .
F3 P1 F6 90.9(3) . .
F5 P1 F6 90.4(3) . .
F2 P1 F6 89.2(3) . .
F3 P1 F4 178.4(3) . .
F5 P1 F4 88.9(4) . .
F2 P1 F4 89.1(3) . .
F6 P1 F4 87.9(3) . .
F3 P1 F1 89.8(3) . .
F5 P1 F1 90.4(3) . .
F2 P1 F1 90.0(3) . .
F6 P1 F1 179.0(3) . .
F4 P1 F1 91.5(3) . .
F8 P2 F7 91.1(3) . .
F8 P2 F12 179.0(3) . .
F7 P2 F12 89.9(3) . .
F8 P2 F11 89.3(3) . .
F7 P2 F11 90.9(3) . .
F12 P2 F11 90.7(3) . .
F8 P2 F9 89.6(3) . .
F7 P2 F9 89.1(3) . .
F12 P2 F9 90.4(3) . .
F11 P2 F9 178.9(3) . .
F8 P2 F10 89.0(3) . .
F7 P2 F10 179.7(3) . .
F12 P2 F10 90.0(3) . .
F11 P2 F10 89.3(3) . .
F9 P2 F10 90.7(3) . .
C1 O1 Ru2 113.2(4) . .
C2 O2 Ru2 112.8(5) . .
C1 O3 Ru1 113.1(5) . .
C2 O4 Ru1 113.7(4) . .
C14 N1 C13 117.4(6) . .
C14 N1 Ru2 121.3(5) . .
C13 N1 Ru2 121.3(5) . .
C23 N2 C26 119.6(6) . .
C23 N2 Ru1 118.0(5) . 3
C26 N2 Ru1 122.2(5) . 3
O1 C1 O3 125.5(7) . .
O1 C1 C2 117.3(7) . .
O3 C1 C2 117.2(8) . .
O4 C2 O2 125.0(7) . .
O4 C2 C1 117.1(7) . .
O2 C2 C1 117.8(8) . .
C4 C3 C6 122.3(7) . .
C4 C3 Ru2 72.5(4) . .
C6 C3 Ru2 71.1(4) . .
C3 C4 C7 119.4(7) . .
C3 C4 Ru2 70.1(4) . .
C7 C4 Ru2 70.4(4) . .
C6 C5 C8 121.7(7) . .
C6 C5 Ru2 71.2(5) . .
C8 C5 Ru2 71.7(5) . .
C5 C6 C3 117.6(7) . .
C5 C6 C12 121.3(8) . .
C3 C6 C12 121.2(7) . .
C5 C6 Ru2 71.1(5) . .
C3 C6 Ru2 70.5(4) . .
C12 C6 Ru2 128.0(5) . .
C8 C7 C4 118.3(7) . .
C8 C7 C9 124.3(7) . .
C4 C7 C9 117.4(7) . .
C8 C7 Ru2 71.3(4) . .
C4 C7 Ru2 70.7(4) . .
C9 C7 Ru2 128.0(5) . .
C7 C8 C5 120.7(7) . .
C7 C8 Ru2 71.4(4) . .
C5 C8 Ru2 70.1(4) . .
C11 C9 C7 107.7(7) . .
C11 C9 C10 113.1(7) . .
C7 C9 C10 113.3(7) . .
N1 C13 C16 123.4(7) . .
N1 C14 C15 123.5(7) . .
C17 C15 C14 119.0(7) . .
C17 C16 C13 117.7(7) . .
C17 C16 C18 122.0(7) . .
C13 C16 C18 120.2(7) . .
C15 C17 C16 118.9(7) . .
C19 C18 C16 178.8(8) . .
C18 C19 C20 179.5(9) . .
C21 C20 C19 177.2(9) . .
C20 C21 C22 176.0(9) . .
C24 C22 C23 118.0(7) . .
C24 C22 C21 122.0(7) . .
C23 C22 C21 120.0(7) . .
N2 C23 C22 121.8(7) . .
C25 C24 C22 119.8(7) . .
C24 C25 C26 118.5(7) . .
N2 C26 C25 122.3(7) . .
C28 C27 C35 120.0(8) . .
C28 C27 Ru1 71.2(4) . .
C35 C27 Ru1 71.7(4) . .
C29 C28 C27 118.4(7) . .
C29 C28 C32 122.2(7) . .
C27 C28 C32 119.1(8) . .
C29 C28 Ru1 70.4(4) . .
C27 C28 Ru1 70.3(4) . .
C32 C28 Ru1 125.5(5) . .
C28 C29 C30 120.9(7) . .
C28 C29 Ru1 71.7(4) . .
C30 C29 Ru1 70.4(4) . .
C31 C30 C29 121.7(8) . .
C31 C30 Ru1 73.1(5) . .
C29 C30 Ru1 71.0(4) . .
C30 C31 C35 117.2(7) . .
C30 C31 C33 123.2(8) . .
C35 C31 C33 119.6(8) . .
C30 C31 Ru1 69.4(5) . .
C35 C31 Ru1 70.2(5) . .
C33 C31 Ru1 130.0(5) . .
C31 C33 C36 114.4(7) . .
C31 C33 C34 107.5(7) . .
C36 C33 C34 113.3(9) . .
C31 C35 C27 121.8(8) . .
C31 C35 Ru1 71.4(4) . .
C27 C35 Ru1 70.5(4) . .
O1N N1N O2N 165(2) . .
O1N N1N C1N 94(2) . .
O2N N1N C1N 95(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ru1 O4 2.105(5) .
Ru1 O3 2.104(5) .
Ru1 N2 2.127(6) 3
Ru1 C30 2.160(8) .
Ru1 C29 2.168(7) .
Ru1 C27 2.174(8) .
Ru1 C28 2.184(7) .
Ru1 C35 2.190(8) .
Ru1 C31 2.206(8) .
Ru2 O1 2.112(5) .
Ru2 N1 2.109(6) .
Ru2 O2 2.110(6) .
Ru2 C3 2.166(7) .
Ru2 C5 2.171(8) .
Ru2 C6 2.172(8) .
Ru2 C7 2.194(7) .
Ru2 C4 2.197(7) .
Ru2 C8 2.192(7) .
P1 F3 1.576(6) .
P1 F5 1.580(5) .
P1 F2 1.591(5) .
P1 F6 1.617(5) .
P1 F4 1.607(6) .
P1 F1 1.596(5) .
P2 F8 1.595(5) .
P2 F7 1.595(5) .
P2 F12 1.590(5) .
P2 F11 1.599(5) .
P2 F9 1.611(6) .
P2 F10 1.607(5) .
O1 C1 1.261(9) .
O2 C2 1.264(8) .
O3 C1 1.271(9) .
O4 C2 1.257(9) .
N1 C14 1.340(9) .
N1 C13 1.331(9) .
N2 C23 1.326(9) .
N2 C26 1.345(9) .
N2 Ru1 2.127(6) 3
C1 C2 1.516(11) .
C3 C4 1.399(10) .
C3 C6 1.427(11) .
C4 C7 1.462(10) .
C5 C6 1.401(10) .
C5 C8 1.428(11) .
C6 C12 1.492(11) .
C7 C8 1.401(10) .
C7 C9 1.503(11) .
C9 C11 1.503(10) .
C9 C10 1.526(12) .
C13 C16 1.405(10) .
C14 C15 1.378(10) .
C15 C17 1.380(11) .
C16 C17 1.390(11) .
C16 C18 1.409(11) .
C18 C19 1.204(10) .
C19 C20 1.388(11) .
C20 C21 1.184(10) .
C21 C22 1.431(11) .
C22 C24 1.398(10) .
C22 C23 1.408(10) .
C24 C25 1.374(10) .
C25 C26 1.390(10) .
C27 C28 1.436(10) .
C27 C35 1.413(11) .
C28 C29 1.414(11) .
C28 C32 1.488(11) .
C29 C30 1.428(11) .
C30 C31 1.404(11) .
C31 C35 1.444(11) .
C31 C33 1.488(11) .
C33 C36 1.496(12) .
C33 C34 1.526(13) .
O1N N1N 1.103(14) .
O2N N1N 1.136(14) .
N1N C1N 1.32(5) .
