#------------------------------------------------------------------------------
#$Date: 2016-03-25 14:18:03 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179889 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/85/7018585.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7018585
loop_
_publ_author_name
'Shen, Xiaodong'
'Zhang, Yong'
'Xue, Mingqiang'
'Shen, Qi'
_publ_section_title
;
 Reduction of Sterically Hindered β-Diketiminato Europium(iii) Complexes
 by the β-Diketiminato Anion: A Convenient Route for the Synthesis of
 β-Diketiminato Europium(ii) Complexes.
;
_journal_issue                   13
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3668
_journal_page_last               3674
_journal_paper_doi               10.1039/c2dt12176j
_journal_volume                  41
_journal_year                    2012
_chemical_formula_moiety         'C46 H58 N4, C6 H14'
_chemical_formula_sum            'C52 H72 N4'
_chemical_formula_weight         753.14
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                100.318(9)
_cell_angle_beta                 90.767(8)
_cell_angle_gamma                113.822(16)
_cell_formula_units_Z            1
_cell_length_a                   8.566(4)
_cell_length_b                   9.953(5)
_cell_length_c                   15.152(6)
_cell_measurement_reflns_used    4258
_cell_measurement_temperature    223(2)
_cell_measurement_theta_max      27.4
_cell_measurement_theta_min      3.1
_cell_volume                     1157.4(9)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      223(2)
_diffrn_detector_area_resol_mean 14.63
_diffrn_measured_fraction_theta_full 0.969
_diffrn_measured_fraction_theta_max 0.969
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0772
_diffrn_reflns_av_sigmaI/netI    0.1196
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            9209
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         3.06
_exptl_absorpt_coefficient_mu    0.062
_exptl_absorpt_correction_T_max  0.988
_exptl_absorpt_correction_T_min  0.697
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.080
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             412
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.286
_refine_diff_density_min         -0.228
_refine_diff_density_rms         0.047
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.063
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     254
_refine_ls_number_reflns         4183
_refine_ls_number_restraints     5
_refine_ls_restrained_S_all      1.067
_refine_ls_R_factor_all          0.2176
_refine_ls_R_factor_gt           0.1067
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1199P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2291
_refine_ls_wR_factor_ref         0.2896
_reflns_number_gt                1917
_reflns_number_total             4183
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt12176j.txt
_cod_data_source_block           complex3
_cod_original_cell_volume        1157.5(10)
_cod_database_code               7018585
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
N1 N 0.3178(4) 0.1151(4) 0.4423(2) 0.0542(10) Uani 1 1 d .
N2 N 0.6715(4) 0.2257(4) 0.6685(2) 0.0562(10) Uani 1 1 d .
C1 C 0.5890(6) 0.3432(6) 0.4915(4) 0.0687(14) Uani 1 1 d .
H1A H 0.6758 0.3543 0.4495 0.103 Uiso 1 1 calc R
H1B H 0.6438 0.3813 0.5526 0.103 Uiso 1 1 calc R
H1C H 0.5239 0.3991 0.4793 0.103 Uiso 1 1 calc R
C2 C 0.4708(5) 0.1803(5) 0.4807(3) 0.0518(11) Uani 1 1 d .
C3 C 0.5449(5) 0.0837(5) 0.5207(3) 0.0494(11) Uani 1 1 d .
H3 H 0.6669 0.1182 0.5089 0.059 Uiso 1 1 calc R
C4 C 0.5383(5) 0.1179(5) 0.6231(3) 0.0505(11) Uani 1 1 d .
C5 C 0.3784(5) 0.0253(6) 0.6612(3) 0.0609(13) Uani 1 1 d .
H5A H 0.3911 0.0582 0.7261 0.091 Uiso 1 1 calc R
H5B H 0.3595 -0.0794 0.6464 0.091 Uiso 1 1 calc R
H5C H 0.2814 0.0371 0.6357 0.091 Uiso 1 1 calc R
C6 C 0.2408(5) 0.2001(5) 0.4058(3) 0.0533(12) Uani 1 1 d .
C7 C 0.1237(5) 0.2397(5) 0.4569(3) 0.0525(12) Uani 1 1 d .
C8 C 0.0375(5) 0.3101(5) 0.4174(3) 0.0590(13) Uani 1 1 d .
H8 H -0.0387 0.3394 0.4512 0.071 Uiso 1 1 calc R
C9 C 0.0581(6) 0.3390(6) 0.3317(3) 0.0637(14) Uani 1 1 d .
C10 C 0.1724(6) 0.2970(6) 0.2839(3) 0.0662(14) Uani 1 1 d .
H10 H 0.1872 0.3141 0.2250 0.079 Uiso 1 1 calc R
C11 C 0.2676(5) 0.2295(6) 0.3198(3) 0.0582(12) Uani 1 1 d .
C12 C 0.0953(6) 0.2120(6) 0.5504(3) 0.0653(14) Uani 1 1 d .
H12A H -0.0073 0.2239 0.5685 0.098 Uiso 1 1 calc R
H12B H 0.1931 0.2832 0.5916 0.098 Uiso 1 1 calc R
H12C H 0.0818 0.1108 0.5518 0.098 Uiso 1 1 calc R
C13 C -0.0414(6) 0.4113(7) 0.2907(4) 0.0859(18) Uani 1 1 d .
H13A H 0.0374 0.4975 0.2688 0.129 Uiso 1 1 calc R
H13B H -0.1050 0.4434 0.3359 0.129 Uiso 1 1 calc R
H13C H -0.1206 0.3395 0.2409 0.129 Uiso 1 1 calc R
C14 C 0.3972(6) 0.1912(7) 0.2660(3) 0.0727(15) Uani 1 1 d .
H14A H 0.3826 0.2006 0.2042 0.109 Uiso 1 1 calc R
H14B H 0.3799 0.0891 0.2673 0.109 Uiso 1 1 calc R
H14C H 0.5122 0.2594 0.2922 0.109 Uiso 1 1 calc R
C15 C 0.6809(5) 0.2727(5) 0.7637(3) 0.0534(11) Uani 1 1 d .
C16 C 0.8030(6) 0.2539(6) 0.8158(3) 0.0623(13) Uani 1 1 d .
C17 C 0.8194(6) 0.3029(7) 0.9093(3) 0.0746(16) Uani 1 1 d .
H17 H 0.8976 0.2865 0.9453 0.089 Uiso 1 1 calc R
C18 C 0.7223(7) 0.3755(7) 0.9501(3) 0.0761(16) Uani 1 1 d .
C19 C 0.6130(6) 0.3999(7) 0.8965(3) 0.0739(15) Uani 1 1 d .
H19 H 0.5520 0.4541 0.9233 0.089 Uiso 1 1 calc R
C20 C 0.5864(6) 0.3488(6) 0.8033(3) 0.0600(13) Uani 1 1 d .
C21 C 0.9217(6) 0.1877(6) 0.7718(3) 0.0696(14) Uani 1 1 d .
H21A H 0.8625 0.1158 0.7170 0.104 Uiso 1 1 calc R
H21B H 0.9552 0.1378 0.8130 0.104 Uiso 1 1 calc R
H21C H 1.0230 0.2672 0.7573 0.104 Uiso 1 1 calc R
C22 C 0.7413(8) 0.4254(8) 1.0525(4) 0.103(2) Uani 1 1 d .
H22A H 0.6521 0.3504 1.0780 0.154 Uiso 1 1 calc R
H22B H 0.7313 0.5202 1.0681 0.154 Uiso 1 1 calc R
H22C H 0.8528 0.4373 1.0765 0.154 Uiso 1 1 calc R
C23 C 0.4593(6) 0.3808(6) 0.7491(3) 0.0691(14) Uani 1 1 d .
H23A H 0.5065 0.4097 0.6942 0.104 Uiso 1 1 calc R
H23B H 0.4373 0.4616 0.7845 0.104 Uiso 1 1 calc R
H23C H 0.3529 0.2914 0.7341 0.104 Uiso 1 1 calc R
C24 C -0.357(3) 0.018(4) 0.081(2) 0.191(4) Uiso 0.50 1 d PD
C25 C -0.195(3) -0.008(3) 0.0968(18) 0.191(4) Uiso 0.50 1 d PD
C26 C -0.056(3) 0.073(3) 0.0466(16) 0.191(4) Uiso 0.50 1 d PD
C27 C 0.074(3) 0.026(3) 0.0034(17) 0.191(4) Uiso 0.50 1 d PD
C28 C 0.249(3) 0.100(3) -0.0277(17) 0.191(4) Uiso 0.50 1 d PD
C29 C 0.288(3) -0.027(3) -0.086(2) 0.191(4) Uiso 0.50 1 d PD
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 N1 C6 120.1(4) . .
C4 N2 C15 122.3(4) . .
C2 C1 H1A 109.5 . .
C2 C1 H1B 109.5 . .
H1A C1 H1B 109.5 . .
C2 C1 H1C 109.5 . .
H1A C1 H1C 109.5 . .
H1B C1 H1C 109.5 . .
N1 C2 C1 126.9(4) . .
N1 C2 C3 117.7(4) . .
C1 C2 C3 115.4(4) . .
C3 C3 C4 112.9(4) 2_656 .
C3 C3 C2 113.6(4) 2_656 .
C4 C3 C2 106.8(3) . .
C3 C3 H3 107.8 2_656 .
C4 C3 H3 107.8 . .
C2 C3 H3 107.8 . .
N2 C4 C5 125.9(4) . .
N2 C4 C3 116.3(4) . .
C5 C4 C3 117.9(4) . .
C4 C5 H5A 109.5 . .
C4 C5 H5B 109.5 . .
H5A C5 H5B 109.5 . .
C4 C5 H5C 109.5 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
C11 C6 C7 121.0(4) . .
C11 C6 N1 121.3(4) . .
C7 C6 N1 117.4(4) . .
C8 C7 C6 117.2(4) . .
C8 C7 C12 120.8(4) . .
C6 C7 C12 122.0(4) . .
C9 C8 C7 123.7(4) . .
C9 C8 H8 118.2 . .
C7 C8 H8 118.2 . .
C10 C9 C8 117.2(4) . .
C10 C9 C13 120.9(4) . .
C8 C9 C13 121.9(5) . .
C9 C10 C11 122.6(4) . .
C9 C10 H10 118.7 . .
C11 C10 H10 118.7 . .
C6 C11 C10 118.4(4) . .
C6 C11 C14 121.0(4) . .
C10 C11 C14 120.6(4) . .
C7 C12 H12A 109.5 . .
C7 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C7 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C9 C13 H13A 109.5 . .
C9 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C9 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
C11 C14 H14A 109.5 . .
C11 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C11 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C20 C15 C16 120.4(4) . .
C20 C15 N2 122.1(4) . .
C16 C15 N2 117.1(4) . .
C15 C16 C17 118.7(4) . .
C15 C16 C21 120.8(4) . .
C17 C16 C21 120.5(4) . .
C18 C17 C16 121.4(4) . .
C18 C17 H17 119.3 . .
C16 C17 H17 119.3 . .
C19 C18 C17 118.0(5) . .
C19 C18 C22 122.0(5) . .
C17 C18 C22 120.0(5) . .
C18 C19 C20 123.3(5) . .
C18 C19 H19 118.4 . .
C20 C19 H19 118.4 . .
C15 C20 C19 118.1(4) . .
C15 C20 C23 122.7(4) . .
C19 C20 C23 119.2(4) . .
C16 C21 H21A 109.5 . .
C16 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C16 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
C18 C22 H22A 109.5 . .
C18 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C18 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C20 C23 H23A 109.5 . .
C20 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C20 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C29 C24 C25 18(5) 2 .
C29 C24 C28 51(5) 2 2
C25 C24 C28 40.3(12) . 2
C29 C25 C28 89(2) 2 2
C29 C25 C26 105(3) 2 .
C28 C25 C26 85(2) 2 .
C29 C25 C24 10(3) 2 .
C28 C25 C24 85(2) 2 .
C26 C25 C24 113(2) . .
C29 C25 C27 114(3) 2 2
C28 C25 C27 53.1(15) 2 2
C26 C25 C27 35.4(14) . 2
C24 C25 C27 116.8(18) . 2
C27 C26 C25 94(2) 2 .
C27 C26 C27 50(2) 2 .
C25 C26 C27 129(2) . .
C27 C26 C28 55.7(17) 2 2
C25 C26 C28 41.4(14) . 2
C27 C26 C28 103(2) . 2
C27 C26 C29 103(2) 2 2
C25 C26 C29 29.6(14) . 2
C27 C26 C29 151(2) . 2
C28 C26 C29 48.4(10) 2 2
C26 C27 C27 83(3) 2 2
C26 C27 C26 130(2) 2 .
C27 C27 C26 46.2(19) 2 .
C26 C27 C28 88(3) 2 .
C27 C27 C28 155(4) 2 .
C26 C27 C28 137(2) . .
C26 C27 C25 51.0(18) 2 2
C27 C27 C25 121(3) 2 2
C26 C27 C25 148.9(17) . 2
C28 C27 C25 39.9(14) . 2
C25 C28 C27 87(2) 2 .
C25 C28 C29 40.4(14) 2 .
C27 C28 C29 107(2) . .
C25 C28 C26 53.2(14) 2 2
C27 C28 C26 36.8(15) . 2
C29 C28 C26 71.3(16) . 2
C25 C28 C24 55.1(18) 2 2
C27 C28 C24 119(2) . 2
C29 C28 C24 16.0(15) . 2
C26 C28 C24 85.6(18) 2 2
C24 C29 C25 152(8) 2 2
C24 C29 C28 113(6) 2 .
C25 C29 C28 50(2) 2 .
C24 C29 C26 154(7) 2 2
C25 C29 C26 45.4(19) 2 2
C28 C29 C26 60.3(14) . 2
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
N1 C2 1.278(5) .
N1 C6 1.438(5) .
N2 C4 1.286(6) .
N2 C15 1.424(5) .
C1 C2 1.502(7) .
C1 H1A 0.9700 .
C1 H1B 0.9700 .
C1 H1C 0.9700 .
C2 C3 1.545(5) .
C3 C3 1.529(9) 2_656
C3 C4 1.534(6) .
C3 H3 0.9900 .
C4 C5 1.500(6) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C5 H5C 0.9700 .
C6 C11 1.387(6) .
C6 C7 1.412(6) .
C7 C8 1.396(6) .
C7 C12 1.497(6) .
C8 C9 1.379(6) .
C8 H8 0.9400 .
C9 C10 1.378(7) .
C9 C13 1.507(6) .
C10 C11 1.405(6) .
C10 H10 0.9400 .
C11 C14 1.516(6) .
C12 H12A 0.9700 .
C12 H12B 0.9700 .
C12 H12C 0.9700 .
C13 H13A 0.9700 .
C13 H13B 0.9700 .
C13 H13C 0.9700 .
C14 H14A 0.9700 .
C14 H14B 0.9700 .
C14 H14C 0.9700 .
C15 C20 1.392(6) .
C15 C16 1.393(6) .
C16 C17 1.399(7) .
C16 C21 1.521(6) .
C17 C18 1.391(7) .
C17 H17 0.9400 .
C18 C19 1.353(6) .
C18 C22 1.527(7) .
C19 C20 1.394(6) .
C19 H19 0.9400 .
C20 C23 1.520(6) .
C21 H21A 0.9700 .
C21 H21B 0.9700 .
C21 H21C 0.9700 .
C22 H22A 0.9700 .
C22 H22B 0.9700 .
C22 H22C 0.9700 .
C23 H23A 0.9700 .
C23 H23B 0.9700 .
C23 H23C 0.9700 .
C24 C29 0.56(3) 2
C24 C25 1.525(18) .
C24 C28 1.85(4) 2
C25 C29 1.01(3) 2
C25 C28 1.20(3) 2
C25 C26 1.457(17) .
C25 C27 1.87(4) 2
C26 C27 1.09(4) 2
C26 C27 1.495(18) .
C26 C28 1.81(4) 2
C26 C29 1.98(4) 2
C27 C26 1.09(4) 2
C27 C27 1.16(4) 2
C27 C28 1.500(16) .
C27 C25 1.87(4) 2
C28 C25 1.20(3) 2
C28 C29 1.560(19) .
C28 C26 1.81(4) 2
C28 C24 1.85(4) 2
C29 C24 0.56(3) 2
C29 C25 1.01(3) 2
C29 C26 1.98(4) 2
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C6 N1 C2 C1 -1.5(7) . .
C6 N1 C2 C3 178.5(4) . .
N1 C2 C3 C3 22.1(6) . 2_656
C1 C2 C3 C3 -157.9(5) . 2_656
N1 C2 C3 C4 -103.1(4) . .
C1 C2 C3 C4 76.9(5) . .
C15 N2 C4 C5 -1.3(7) . .
C15 N2 C4 C3 178.0(3) . .
C3 C3 C4 N2 144.0(5) 2_656 .
C2 C3 C4 N2 -90.4(4) . .
C3 C3 C4 C5 -36.6(6) 2_656 .
C2 C3 C4 C5 89.0(4) . .
C2 N1 C6 C11 84.7(6) . .
C2 N1 C6 C7 -101.4(5) . .
C11 C6 C7 C8 -0.4(7) . .
N1 C6 C7 C8 -174.3(4) . .
C11 C6 C7 C12 -178.7(4) . .
N1 C6 C7 C12 7.4(7) . .
C6 C7 C8 C9 1.6(7) . .
C12 C7 C8 C9 179.9(5) . .
C7 C8 C9 C10 -0.9(7) . .
C7 C8 C9 C13 178.2(5) . .
C8 C9 C10 C11 -1.0(8) . .
C13 C9 C10 C11 179.9(5) . .
C7 C6 C11 C10 -1.3(7) . .
N1 C6 C11 C10 172.3(4) . .
C7 C6 C11 C14 178.1(5) . .
N1 C6 C11 C14 -8.2(7) . .
C9 C10 C11 C6 2.1(8) . .
C9 C10 C11 C14 -177.4(5) . .
C4 N2 C15 C20 -71.1(6) . .
C4 N2 C15 C16 115.7(5) . .
C20 C15 C16 C17 4.8(7) . .
N2 C15 C16 C17 178.1(5) . .
C20 C15 C16 C21 -172.6(5) . .
N2 C15 C16 C21 0.7(7) . .
C15 C16 C17 C18 -3.0(8) . .
C21 C16 C17 C18 174.4(5) . .
C16 C17 C18 C19 -1.2(9) . .
C16 C17 C18 C22 179.1(6) . .
C17 C18 C19 C20 3.7(9) . .
C22 C18 C19 C20 -176.6(6) . .
C16 C15 C20 C19 -2.5(7) . .
N2 C15 C20 C19 -175.4(4) . .
C16 C15 C20 C23 176.2(4) . .
N2 C15 C20 C23 3.3(7) . .
C18 C19 C20 C15 -1.9(8) . .
C18 C19 C20 C23 179.3(5) . .
C28 C24 C25 C29 117(17) 2 2
C29 C24 C25 C28 -117(17) 2 2
C29 C24 C25 C26 -34(17) 2 .
C28 C24 C25 C26 83(3) 2 .
C29 C24 C25 C27 -73(17) 2 2
C28 C24 C25 C27 43.7(17) 2 2
C29 C25 C26 C27 -110(3) 2 2
C28 C25 C26 C27 -22(3) 2 2
C24 C25 C26 C27 -104(3) . 2
C29 C25 C26 C27 -150(3) 2 .
C28 C25 C26 C27 -62(3) 2 .
C24 C25 C26 C27 -144(3) . .
C27 C25 C26 C27 -40(3) 2 .
C29 C25 C26 C28 -88(3) 2 2
C24 C25 C26 C28 -82(3) . 2
C27 C25 C26 C28 22(3) 2 2
C28 C25 C26 C29 88(3) 2 2
C24 C25 C26 C29 6(3) . 2
C27 C25 C26 C29 110(3) 2 2
C27 C26 C27 C26 0.000(2) 2 2
C25 C26 C27 C26 56(4) . 2
C28 C26 C27 C26 19(3) 2 2
C29 C26 C27 C26 25(5) 2 2
C25 C26 C27 C27 56(4) . 2
C28 C26 C27 C27 19(3) 2 2
C29 C26 C27 C27 25(5) 2 2
C27 C26 C27 C28 145(5) 2 .
C25 C26 C27 C28 -159(3) . .
C28 C26 C27 C28 164(2) 2 .
C29 C26 C27 C28 170(3) 2 .
C27 C26 C27 C25 78(4) 2 2
C25 C26 C27 C25 134(3) . 2
C28 C26 C27 C25 97(4) 2 2
C29 C26 C27 C25 103(5) 2 2
C26 C27 C28 C25 21(3) 2 2
C27 C27 C28 C25 -47(9) 2 2
C26 C27 C28 C25 -132(3) . 2
C26 C27 C28 C29 -14(3) 2 .
C27 C27 C28 C29 -82(9) 2 .
C26 C27 C28 C29 -168(3) . .
C25 C27 C28 C29 -35.6(17) 2 .
C27 C27 C28 C26 -68(8) 2 2
C26 C27 C28 C26 -153(4) . 2
C25 C27 C28 C26 -21(3) 2 2
C26 C27 C28 C24 -25(3) 2 2
C27 C27 C28 C24 -93(9) 2 2
C26 C27 C28 C24 -179(2) . 2
C25 C27 C28 C24 -46.5(19) 2 2
C25 C28 C29 C24 153(9) 2 2
C27 C28 C29 C24 -143(7) . 2
C26 C28 C29 C24 -152(7) 2 2
C27 C28 C29 C25 64(3) . 2
C26 C28 C29 C25 55(2) 2 2
C24 C28 C29 C25 -153(9) 2 2
C25 C28 C29 C26 -55(2) 2 2
C27 C28 C29 C26 9.0(18) . 2
C24 C28 C29 C26 152(7) 2 2
