#------------------------------------------------------------------------------
#$Date: 2016-03-25 14:23:13 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179893 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/89/7018903.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7018903
loop_
_publ_author_name
'Kong, Fang'
'Hu, Chun-Li'
'Xu, Xiang'
'Zhou, Tian-Hua'
'Mao, Jiang-Gao'
_publ_section_title
;
 Syntheses, crystal structures and SHG properties of a series of polar
 alkali-metal molybdenum(vi) selenites based on strandberg-type
 [Mo(5)O(15)(SeO(3))(2)](4-) polyanion.
;
_journal_issue                   18
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5687
_journal_page_last               5695
_journal_paper_doi               10.1039/c2dt12437h
_journal_volume                  41
_journal_year                    2012
_chemical_formula_sum            'H4 Mo5 O23 Rb4 Se2'
_chemical_formula_weight         1351.53
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 114.052(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.0975(19)
_cell_length_b                   23.503(4)
_cell_length_c                   10.669(2)
_cell_measurement_reflns_used    6194
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.5011
_cell_measurement_theta_min      2.2627
_cell_volume                     2312.1(7)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.967
_diffrn_measured_fraction_theta_max 0.967
_diffrn_measurement_device_type  Mercury70
_diffrn_measurement_method       CCD_Profile_fitting
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0254
_diffrn_reflns_av_sigmaI/netI    0.0244
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            17911
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.49
_diffrn_reflns_theta_min         2.26
_exptl_absorpt_coefficient_mu    14.250
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.7546
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    3.882
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2456
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.1
_refine_diff_density_max         3.427
_refine_diff_density_min         -2.750
_refine_diff_density_rms         0.153
_refine_ls_extinction_coef       0.00339(8)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.015
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     308
_refine_ls_number_reflns         5138
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.015
_refine_ls_R_factor_all          0.0279
_refine_ls_R_factor_gt           0.0250
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0289P)²+8.3706P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0571
_refine_ls_wR_factor_ref         0.0585
_reflns_number_gt                4786
_reflns_number_total             5138
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt12437h.txt
_cod_data_source_block           Rb4Mo5O15(SeO3)2(H2O)2-2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        2312.2(7)
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7018903
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Rb2 Rb 0.59063(5) 0.39593(2) 0.44920(5) 0.02402(11) Uani 1 1 d .
Rb3 Rb 0.93437(5) 0.25598(2) 0.52748(5) 0.02564(12) Uani 1 1 d .
Mo1 Mo 0.79205(4) 0.104284(15) 0.58206(4) 0.01247(9) Uani 1 1 d .
Mo2 Mo 0.54405(4) 0.209995(15) 0.46040(4) 0.01327(9) Uani 1 1 d .
Mo3 Mo 0.30079(4) 0.196215(15) 0.60375(4) 0.01360(9) Uani 1 1 d .
Mo4 Mo 0.39484(4) 0.085979(15) 0.82491(4) 0.01297(9) Uani 1 1 d .
Mo5 Mo 0.72736(4) 0.038368(14) 0.86656(4) 0.01207(9) Uani 1 1 d .
Se1 Se 0.67765(4) 0.187963(16) 0.81595(4) 0.01159(9) Uani 1 1 d .
Se2 Se 0.42708(4) 0.067029(16) 0.51553(4) 0.01149(9) Uani 1 1 d .
O1 O 0.7736(3) 0.13420(12) 0.9131(3) 0.0153(6) Uani 1 1 d .
O2 O 0.5057(3) 0.17110(12) 0.7965(3) 0.0149(6) Uani 1 1 d .
O2W O 0.6314(5) 0.3583(2) 0.7105(4) 0.0452(11) Uani 1 1 d .
H2WA H 0.5769 0.3772 0.7386 0.068 Uiso 1 1 d R
H2WB H 0.7195 0.3632 0.7654 0.068 Uiso 1 1 d R
O3 O 0.6747(3) 0.16875(12) 0.6591(3) 0.0153(6) Uani 1 1 d .
O4 O 0.5736(3) 0.05615(12) 0.4842(3) 0.0147(6) Uani 1 1 d .
O5 O 0.4014(3) 0.13889(12) 0.4894(3) 0.0150(6) Uani 1 1 d .
O6 O 0.5032(3) 0.06163(12) 0.6924(3) 0.0144(6) Uani 1 1 d .
O7 O 0.1467(3) 0.20113(14) 0.4559(3) 0.0217(7) Uani 1 1 d .
O8 O 0.4364(3) 0.24042(12) 0.5630(3) 0.0177(6) Uani 1 1 d .
O9 O 0.8068(3) 0.05905(12) 0.7368(3) 0.0151(6) Uani 1 1 d .
O10 O 0.5837(3) 0.05490(13) 0.9367(3) 0.0175(6) Uani 1 1 d .
O11 O 0.3730(3) 0.12431(14) 0.9532(3) 0.0208(7) Uani 1 1 d .
O12 O 0.6770(3) 0.15555(12) 0.4367(3) 0.0156(6) Uani 1 1 d .
O13 O 0.8784(3) 0.03238(14) 1.0172(3) 0.0197(7) Uani 1 1 d .
O14 O 0.8427(4) 0.05583(14) 0.4886(3) 0.0218(7) Uani 1 1 d .
O15 O 0.2858(4) 0.02784(14) 0.8052(4) 0.0232(7) Uani 1 1 d .
O16 O 0.2644(3) 0.12276(13) 0.6604(3) 0.0170(6) Uani 1 1 d .
O17 O 0.9463(3) 0.14367(14) 0.6597(4) 0.0226(7) Uani 1 1 d .
O18 O 0.6914(3) -0.03172(13) 0.8193(4) 0.0220(7) Uani 1 1 d .
O19 O 0.2634(4) 0.24187(13) 0.7108(4) 0.0221(7) Uani 1 1 d .
O20 O 0.6414(4) 0.27077(13) 0.4772(4) 0.0244(7) Uani 1 1 d .
O21 O 0.4195(4) 0.21130(16) 0.2942(3) 0.0267(8) Uani 1 1 d .
Rb4 Rb 0.57846(5) 0.07640(2) 0.21216(5) 0.02302(11) Uani 1 1 d .
Rb1 Rb 0.01890(7) 0.04741(3) 0.32569(7) 0.04946(18) Uani 1 1 d .
O1W O 0.8143(5) 0.13876(16) 0.1935(4) 0.0366(9) Uani 1 1 d .
H1WB H 0.8477 0.1204 0.1440 0.055 Uiso 1 1 d R
H1WA H 0.7839 0.1711 0.1575 0.055 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rb Rb -0.9393 2.9676 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2W Rb2 O11 101.03(11) . 4_665
O2W Rb2 O17 138.41(12) . 4_565
O11 Rb2 O17 91.54(9) 4_665 4_565
O2W Rb2 O20 68.77(12) . .
O11 Rb2 O20 72.90(9) 4_665 .
O17 Rb2 O20 77.69(10) 4_565 .
O2W Rb2 O9 124.56(10) . 4_565
O11 Rb2 O9 134.39(9) 4_665 4_565
O17 Rb2 O9 54.49(8) 4_565 4_565
O20 Rb2 O9 119.44(9) . 4_565
O2W Rb2 O13 76.60(11) . 4_565
O11 Rb2 O13 151.73(9) 4_665 4_565
O17 Rb2 O13 109.05(9) 4_565 4_565
O20 Rb2 O13 129.27(9) . 4_565
O9 Rb2 O13 55.96(8) 4_565 4_565
O2W Rb2 O18 66.79(12) . 2_656
O11 Rb2 O18 72.40(9) 4_665 2_656
O17 Rb2 O18 153.66(9) 4_565 2_656
O20 Rb2 O18 115.40(9) . 2_656
O9 Rb2 O18 123.95(8) 4_565 2_656
O13 Rb2 O18 81.08(8) 4_565 2_656
O2W Rb2 O1 77.25(11) . 4_565
O11 Rb2 O1 156.73(9) 4_665 4_565
O17 Rb2 O1 76.05(8) 4_565 4_565
O20 Rb2 O1 85.12(8) . 4_565
O9 Rb2 O1 51.79(8) 4_565 4_565
O13 Rb2 O1 51.11(8) 4_565 4_565
O18 Rb2 O1 125.75(8) 2_656 4_565
O2W Rb2 O13 103.62(12) . 2_656
O11 Rb2 O13 96.44(8) 4_665 2_656
O17 Rb2 O13 114.22(9) 4_565 2_656
O20 Rb2 O13 164.72(9) . 2_656
O9 Rb2 O13 75.84(8) 4_565 2_656
O13 Rb2 O13 57.88(10) 4_565 2_656
O18 Rb2 O13 49.79(8) 2_656 2_656
O1 Rb2 O13 106.57(8) 4_565 2_656
O2W Rb2 O15 136.93(11) . 4_665
O11 Rb2 O15 49.44(9) 4_665 4_665
O17 Rb2 O15 80.06(9) 4_565 4_665
O20 Rb2 O15 116.79(8) . 4_665
O9 Rb2 O15 91.34(8) 4_565 4_665
O13 Rb2 O15 113.87(8) 4_565 4_665
O18 Rb2 O15 73.64(9) 2_656 4_665
O1 Rb2 O15 143.06(8) 4_565 4_665
O13 Rb2 O15 59.13(8) 2_656 4_665
O2W Rb2 Mo5 95.59(9) . 4_565
O11 Rb2 Mo5 160.72(7) 4_665 4_565
O17 Rb2 Mo5 82.30(6) 4_565 4_565
O20 Rb2 Mo5 122.92(6) . 4_565
O9 Rb2 Mo5 30.81(6) 4_565 4_565
O13 Rb2 Mo5 26.79(6) 4_565 4_565
O18 Rb2 Mo5 105.91(6) 2_656 4_565
O1 Rb2 Mo5 38.04(5) 4_565 4_565
O13 Rb2 Mo5 69.96(6) 2_656 4_565
O15 Rb2 Mo5 111.33(6) 4_665 4_565
O2W Rb2 Mo4 124.62(9) . 4_665
O11 Rb2 Mo4 24.97(7) 4_665 4_665
O17 Rb2 Mo4 78.36(6) 4_565 4_665
O20 Rb2 Mo4 90.85(6) . 4_665
O9 Rb2 Mo4 110.48(6) 4_565 4_665
O13 Rb2 Mo4 139.82(6) 4_565 4_665
O18 Rb2 Mo4 78.68(6) 2_656 4_665
O1 Rb2 Mo4 154.37(6) 4_565 4_665
O13 Rb2 Mo4 82.71(6) 2_656 4_665
O15 Rb2 Mo4 26.54(5) 4_665 4_665
Mo5 Rb2 Mo4 136.056(18) 4_565 4_665
O2W Rb2 H2WA 14.6 . .
O11 Rb2 H2WA 113.5 4_665 .
O17 Rb2 H2WA 140.2 4_565 .
O20 Rb2 H2WA 80.8 . .
O9 Rb2 H2WA 111.9 4_565 .
O13 Rb2 H2WA 62.0 4_565 .
O18 Rb2 H2WA 66.1 2_656 .
O1 Rb2 H2WA 69.1 4_565 .
O13 Rb2 H2WA 94.0 2_656 .
O15 Rb2 H2WA 139.8 4_665 .
Mo5 Rb2 H2WA 81.9 4_565 .
Mo4 Rb2 H2WA 135.2 4_665 .
O2W Rb2 H2WB 14.6 . .
O11 Rb2 H2WB 88.3 4_665 .
O17 Rb2 H2WB 147.3 4_565 .
O20 Rb2 H2WB 71.0 . .
O9 Rb2 H2WB 137.1 4_565 .
O13 Rb2 H2WB 84.5 4_565 .
O18 Rb2 H2WB 55.3 2_656 .
O1 Rb2 H2WB 91.8 4_565 .
O13 Rb2 H2WB 98.3 2_656 .
O15 Rb2 H2WB 122.5 4_665 .
Mo5 Rb2 H2WB 106.8 4_565 .
Mo4 Rb2 H2WB 110.8 4_665 .
H2WA Rb2 H2WB 25.2 . .
O20 Rb3 O7 148.42(10) . 1_655
O20 Rb3 O11 74.81(9) . 4_665
O7 Rb3 O11 117.47(9) 1_655 4_665
O20 Rb3 O17 92.08(9) . .
O7 Rb3 O17 80.60(9) 1_655 .
O11 Rb3 O17 161.35(9) 4_665 .
O20 Rb3 O21 72.18(10) . 4_666
O7 Rb3 O21 134.40(10) 1_655 4_666
O11 Rb3 O21 85.61(10) 4_665 4_666
O17 Rb3 O21 77.65(10) . 4_666
O20 Rb3 O19 73.42(10) . 4_665
O7 Rb3 O19 82.03(9) 1_655 4_665
O11 Rb3 O19 74.14(9) 4_665 4_665
O17 Rb3 O19 115.34(9) . 4_665
O21 Rb3 O19 143.57(9) 4_666 4_665
O20 Rb3 O19 155.03(10) . 1_655
O7 Rb3 O19 52.77(9) 1_655 1_655
O11 Rb3 O19 109.12(9) 4_665 1_655
O17 Rb3 O19 77.33(9) . 1_655
O21 Rb3 O19 83.40(9) 4_666 1_655
O19 Rb3 O19 131.56(11) 4_665 1_655
O20 Rb3 O2 109.00(9) . 4_665
O7 Rb3 O2 67.71(8) 1_655 4_665
O11 Rb3 O2 52.13(8) 4_665 4_665
O17 Rb3 O2 146.46(8) . 4_665
O21 Rb3 O2 132.91(9) 4_666 4_665
O19 Rb3 O2 51.33(8) 4_665 4_665
O19 Rb3 O2 91.30(8) 1_655 4_665
O20 Rb3 O12 53.00(8) . .
O7 Rb3 O12 100.54(9) 1_655 .
O11 Rb3 O12 123.15(8) 4_665 .
O17 Rb3 O12 52.25(8) . .
O21 Rb3 O12 96.98(9) 4_666 .
O19 Rb3 O12 71.04(8) 4_665 .
O19 Rb3 O12 127.65(8) 1_655 .
O2 Rb3 O12 121.87(8) 4_665 .
O20 Rb3 Mo3 164.80(7) . 1_655
O7 Rb3 Mo3 26.12(7) 1_655 1_655
O11 Rb3 Mo3 120.32(6) 4_665 1_655
O17 Rb3 Mo3 73.55(6) . 1_655
O21 Rb3 Mo3 108.53(7) 4_666 1_655
O19 Rb3 Mo3 107.82(6) 4_665 1_655
O19 Rb3 Mo3 27.26(6) 1_655 1_655
O2 Rb3 Mo3 81.95(5) 4_665 1_655
O12 Rb3 Mo3 112.47(5) . 1_655
O20 Rb3 Mo2 23.37(7) . .
O7 Rb3 Mo2 130.08(7) 1_655 .
O11 Rb3 Mo2 97.56(6) 4_665 .
O17 Rb3 Mo2 71.35(6) . .
O21 Rb3 Mo2 78.82(7) 4_666 .
O19 Rb3 Mo2 74.35(6) 4_665 .
O19 Rb3 Mo2 146.56(6) 1_655 .
O2 Rb3 Mo2 121.44(5) 4_665 .
O12 Rb3 Mo2 30.23(5) . .
Mo3 Rb3 Mo2 141.523(18) 1_655 .
O20 Rb3 Mo1 73.92(7) . .
O7 Rb3 Mo1 89.42(7) 1_655 .
O11 Rb3 Mo1 148.71(6) 4_665 .
O17 Rb3 Mo1 23.21(6) . .
O21 Rb3 Mo1 86.00(7) 4_666 .
O19 Rb3 Mo1 95.75(6) 4_665 .
O19 Rb3 Mo1 99.76(6) 1_655 .
O2 Rb3 Mo1 140.73(5) 4_665 .
O12 Rb3 Mo1 29.03(5) . .
Mo3 Rb3 Mo1 90.916(16) 1_655 .
Mo2 Rb3 Mo1 51.206(9) . .
O17 Mo1 O14 102.24(16) . .
O17 Mo1 O9 98.47(15) . .
O14 Mo1 O9 101.21(14) . .
O17 Mo1 O12 100.51(14) . .
O14 Mo1 O12 99.85(14) . .
O9 Mo1 O12 147.82(12) . .
O17 Mo1 O3 88.29(14) . .
O14 Mo1 O3 166.19(14) . .
O9 Mo1 O3 85.83(12) . .
O12 Mo1 O3 69.10(11) . .
O17 Mo1 O4 175.27(13) . .
O14 Mo1 O4 82.47(13) . .
O9 Mo1 O4 80.95(12) . .
O12 Mo1 O4 78.01(12) . .
O3 Mo1 O4 86.99(10) . .
O17 Mo1 Rb4 129.25(12) . .
O14 Mo1 Rb4 56.48(11) . .
O9 Mo1 Rb4 128.79(9) . .
O12 Mo1 Rb4 49.99(9) . .
O3 Mo1 Rb4 109.88(8) . .
O4 Mo1 Rb4 53.05(7) . .
O17 Mo1 Rb2 47.59(11) . 4_666
O14 Mo1 Rb2 107.09(11) . 4_666
O9 Mo1 Rb2 50.89(9) . 4_666
O12 Mo1 Rb2 141.51(9) . 4_666
O3 Mo1 Rb2 86.59(8) . 4_666
O4 Mo1 Rb2 131.74(8) . 4_666
Rb4 Mo1 Rb2 163.502(15) . 4_666
O17 Mo1 Rb1 96.60(11) . 3_656
O14 Mo1 Rb1 47.49(11) . 3_656
O9 Mo1 Rb1 55.15(9) . 3_656
O12 Mo1 Rb1 145.97(9) . 3_656
O3 Mo1 Rb1 140.98(8) . 3_656
O4 Mo1 Rb1 86.93(7) . 3_656
Rb4 Mo1 Rb1 96.747(16) . 3_656
Rb2 Mo1 Rb1 69.433(15) 4_666 3_656
O17 Mo1 Rb3 43.31(11) . .
O14 Mo1 Rb3 107.33(11) . .
O9 Mo1 Rb3 135.85(9) . .
O12 Mo1 Rb3 57.20(9) . .
O3 Mo1 Rb3 74.22(8) . .
O4 Mo1 Rb3 135.01(8) . .
Rb4 Mo1 Rb3 95.214(15) . .
Rb2 Mo1 Rb3 88.296(14) 4_666 .
Rb1 Mo1 Rb3 132.466(18) 3_656 .
O20 Mo2 O21 104.12(17) . .
O20 Mo2 O12 99.57(14) . .
O21 Mo2 O12 97.61(15) . .
O20 Mo2 O8 93.61(14) . .
O21 Mo2 O8 103.40(15) . .
O12 Mo2 O8 151.63(13) . .
O20 Mo2 O3 100.01(15) . .
O21 Mo2 O3 154.57(15) . .
O12 Mo2 O3 70.28(12) . .
O8 Mo2 O3 82.80(12) . .
O20 Mo2 O5 163.56(14) . .
O21 Mo2 O5 85.21(14) . .
O12 Mo2 O5 92.44(11) . .
O8 Mo2 O5 70.83(11) . .
O3 Mo2 O5 73.45(11) . .
O20 Mo2 Rb3 40.83(11) . .
O21 Mo2 Rb3 116.88(12) . .
O12 Mo2 Rb3 60.11(9) . .
O8 Mo2 Rb3 123.32(9) . .
O3 Mo2 Rb3 77.30(8) . .
O5 Mo2 Rb3 145.42(7) . .
O20 Mo2 Rb4 119.98(11) . .
O21 Mo2 Rb4 64.82(12) . .
O12 Mo2 Rb4 35.85(9) . .
O8 Mo2 Rb4 145.86(9) . .
O3 Mo2 Rb4 96.09(8) . .
O5 Mo2 Rb4 76.15(7) . .
Rb3 Mo2 Rb4 89.178(13) . .
O7 Mo3 O19 101.97(16) . .
O7 Mo3 O8 102.77(15) . .
O19 Mo3 O8 100.61(14) . .
O7 Mo3 O16 97.62(15) . .
O19 Mo3 O16 103.36(14) . .
O8 Mo3 O16 144.36(12) . .
O7 Mo3 O5 89.01(13) . .
O19 Mo3 O5 167.92(14) . .
O8 Mo3 O5 71.71(12) . .
O16 Mo3 O5 79.82(12) . .
O7 Mo3 O2 169.11(14) . .
O19 Mo3 O2 85.86(14) . .
O8 Mo3 O2 82.94(12) . .
O16 Mo3 O2 72.98(12) . .
O5 Mo3 O2 83.96(11) . .
O7 Mo3 Rb3 47.42(11) . 1_455
O19 Mo3 Rb3 56.05(11) . 1_455
O8 Mo3 Rb3 119.14(9) . 1_455
O16 Mo3 Rb3 96.17(9) . 1_455
O5 Mo3 Rb3 135.69(8) . 1_455
O2 Mo3 Rb3 137.44(7) . 1_455
O7 Mo3 Rb3 136.80(11) . 4_566
O19 Mo3 Rb3 36.75(11) . 4_566
O8 Mo3 Rb3 98.66(10) . 4_566
O16 Mo3 Rb3 85.53(10) . 4_566
O5 Mo3 Rb3 133.54(8) . 4_566
O2 Mo3 Rb3 49.58(7) . 4_566
Rb3 Mo3 Rb3 89.380(12) 1_455 4_566
O15 Mo4 O11 103.31(16) . .
O15 Mo4 O16 94.56(15) . .
O11 Mo4 O16 103.19(14) . .
O15 Mo4 O10 101.39(15) . .
O11 Mo4 O10 96.95(14) . .
O16 Mo4 O10 150.64(13) . .
O15 Mo4 O6 100.23(14) . .
O11 Mo4 O6 155.28(13) . .
O16 Mo4 O6 82.21(12) . .
O10 Mo4 O6 70.86(12) . .
O15 Mo4 O2 166.02(14) . .
O11 Mo4 O2 83.14(13) . .
O16 Mo4 O2 71.75(12) . .
O10 Mo4 O2 89.96(12) . .
O6 Mo4 O2 75.62(11) . .
O15 Mo4 Rb4 95.23(12) . 1_556
O11 Mo4 Rb4 47.88(11) . 1_556
O16 Mo4 Rb4 150.96(9) . 1_556
O10 Mo4 Rb4 51.90(9) . 1_556
O6 Mo4 Rb4 122.59(8) . 1_556
O2 Mo4 Rb4 98.22(8) . 1_556
O15 Mo4 Rb2 64.25(11) . 4_566
O11 Mo4 Rb2 44.63(11) . 4_566
O16 Mo4 Rb2 85.30(9) . 4_566
O10 Mo4 Rb2 123.82(9) . 4_566
O6 Mo4 Rb2 159.24(8) . 4_566
O2 Mo4 Rb2 115.91(7) . 4_566
Rb4 Mo4 Rb2 74.571(17) 1_556 4_566
O15 Mo4 Rb4 42.82(11) . 3_656
O11 Mo4 Rb4 129.37(11) . 3_656
O16 Mo4 Rb4 113.75(9) . 3_656
O10 Mo4 Rb4 66.23(10) . 3_656
O6 Mo4 Rb4 66.46(8) . 3_656
O2 Mo4 Rb4 139.93(7) . 3_656
Rb4 Mo4 Rb4 91.690(13) 1_556 3_656
Rb2 Mo4 Rb4 104.153(13) 4_566 3_656
O15 Mo4 Rb3 133.22(11) . 4_566
O11 Mo4 Rb3 32.15(11) . 4_566
O16 Mo4 Rb3 87.62(9) . 4_566
O10 Mo4 Rb3 98.78(10) . 4_566
O6 Mo4 Rb3 126.27(8) . 4_566
O2 Mo4 Rb3 51.23(7) . 4_566
Rb4 Mo4 Rb3 65.947(14) 1_556 4_566
Rb2 Mo4 Rb3 69.404(12) 4_566 4_566
Rb4 Mo4 Rb3 157.567(15) 3_656 4_566
O13 Mo5 O18 101.40(16) . .
O13 Mo5 O10 100.13(14) . .
O18 Mo5 O10 101.83(14) . .
O13 Mo5 O9 102.90(14) . .
O18 Mo5 O9 97.56(14) . .
O10 Mo5 O9 146.15(13) . .
O13 Mo5 O1 81.59(13) . .
O18 Mo5 O1 175.59(14) . .
O10 Mo5 O1 80.69(12) . .
O9 Mo5 O1 78.54(12) . .
O13 Mo5 O6 166.05(13) . .
O18 Mo5 O6 88.31(14) . .
O10 Mo5 O6 67.78(12) . .
O9 Mo5 O6 85.49(12) . .
O1 Mo5 O6 89.33(10) . .
O13 Mo5 Rb2 53.10(11) . 4_666
O18 Mo5 Rb2 122.35(11) . 4_666
O10 Mo5 Rb2 130.37(10) . 4_666
O9 Mo5 Rb2 53.75(9) . 4_666
O1 Mo5 Rb2 56.92(7) . 4_666
O6 Mo5 Rb2 129.12(7) . 4_666
O13 Mo5 Rb4 117.81(11) . 3_656
O18 Mo5 Rb4 39.12(11) . 3_656
O10 Mo5 Rb4 64.52(10) . 3_656
O9 Mo5 Rb4 122.82(9) . 3_656
O1 Mo5 Rb4 141.98(7) . 3_656
O6 Mo5 Rb4 64.37(7) . 3_656
Rb2 Mo5 Rb4 160.909(14) 4_666 3_656
O13 Mo5 Rb2 53.52(11) . 2_646
O18 Mo5 Rb2 48.01(11) . 2_646
O10 Mo5 Rb2 104.49(9) . 2_646
O9 Mo5 Rb2 109.11(9) . 2_646
O1 Mo5 Rb2 135.11(7) . 2_646
O6 Mo5 Rb2 134.47(7) . 2_646
Rb2 Mo5 Rb2 91.143(16) 4_666 2_646
Rb4 Mo5 Rb2 71.877(16) 3_656 2_646
O1 Se1 O2 101.76(14) . .
O1 Se1 O3 100.40(14) . .
O2 Se1 O3 101.93(14) . .
O4 Se2 O5 101.93(14) . .
O4 Se2 O6 99.90(14) . .
O5 Se2 O6 102.72(14) . .
O4 Se2 Rb1 137.12(11) . .
O5 Se2 Rb1 88.49(10) . .
O6 Se2 Rb1 118.38(10) . .
O4 Se2 Rb4 37.21(11) . .
O5 Se2 Rb4 84.23(10) . .
O6 Se2 Rb4 136.16(10) . .
Rb1 Se2 Rb4 104.89(2) . .
Se1 O1 Mo5 126.01(16) . .
Se1 O1 Rb2 123.41(14) . 4_666
Mo5 O1 Rb2 85.04(9) . 4_666
Se1 O2 Mo3 122.87(15) . .
Se1 O2 Mo4 133.56(15) . .
Mo3 O2 Mo4 91.79(10) . .
Se1 O2 Rb3 107.92(13) . 4_566
Mo3 O2 Rb3 98.17(9) . 4_566
Mo4 O2 Rb3 94.85(9) . 4_566
Rb2 O2W Rb1 104.54(13) . 4_666
Rb2 O2W H2WA 109.5 . .
Rb1 O2W H2WA 19.2 4_666 .
Rb2 O2W H2WB 109.4 . .
Rb1 O2W H2WB 94.8 4_666 .
H2WA O2W H2WB 109.5 . .
Se1 O3 Mo2 125.73(15) . .
Se1 O3 Mo1 136.12(16) . .
Mo2 O3 Mo1 98.09(12) . .
Se2 O4 Mo1 126.59(16) . .
Se2 O4 Rb4 122.92(15) . .
Mo1 O4 Rb4 88.29(9) . .
Se2 O5 Mo2 132.37(15) . .
Se2 O5 Mo3 123.94(15) . .
Mo2 O5 Mo3 94.66(11) . .
Se2 O6 Mo4 124.72(15) . .
Se2 O6 Mo5 137.91(15) . .
Mo4 O6 Mo5 97.19(11) . .
Se2 O6 Rb4 108.92(13) . 3_656
Mo4 O6 Rb4 79.64(8) . 3_656
Mo5 O6 Rb4 79.81(8) . 3_656
Mo3 O7 Rb3 106.46(14) . 1_455
Mo3 O8 Mo2 122.75(16) . .
Mo1 O9 Mo5 148.29(17) . .
Mo1 O9 Rb2 99.68(11) . 4_666
Mo5 O9 Rb2 95.44(11) . 4_666
Mo1 O9 Rb1 96.17(11) . 3_656
Mo5 O9 Rb1 111.67(12) . 3_656
Rb2 O9 Rb1 89.77(8) 4_666 3_656
Mo5 O10 Mo4 123.17(16) . .
Mo5 O10 Rb4 137.01(14) . 1_556
Mo4 O10 Rb4 97.67(11) . 1_556
Mo5 O10 Rb4 86.22(11) . 3_656
Mo4 O10 Rb4 83.88(11) . 3_656
Rb4 O10 Rb4 113.26(9) 1_556 3_656
Mo4 O11 Rb2 110.40(15) . 4_566
Mo4 O11 Rb3 129.51(15) . 4_566
Rb2 O11 Rb3 105.26(10) 4_566 4_566
Mo4 O11 Rb4 106.12(13) . 1_556
Rb2 O11 Rb4 105.56(10) 4_566 1_556
Rb3 O11 Rb4 97.14(10) 4_566 1_556
Mo1 O12 Mo2 121.81(15) . .
Mo1 O12 Rb4 98.98(11) . .
Mo2 O12 Rb4 120.79(14) . .
Mo1 O12 Rb3 93.76(11) . .
Mo2 O12 Rb3 89.66(10) . .
Rb4 O12 Rb3 131.46(10) . .
Mo5 O13 Rb1 148.72(15) . 1_656
Mo5 O13 Rb2 100.11(13) . 4_666
Rb1 O13 Rb2 97.54(9) 1_656 4_666
Mo5 O13 Rb2 101.24(13) . 2_646
Rb1 O13 Rb2 90.79(8) 1_656 2_646
Rb2 O13 Rb2 122.12(10) 4_666 2_646
Mo1 O14 Rb1 140.88(17) . 1_655
Mo1 O14 Rb1 108.19(14) . 3_656
Rb1 O14 Rb1 95.81(9) 1_655 3_656
Mo1 O14 Rb4 95.97(13) . .
Rb1 O14 Rb4 86.67(9) 1_655 .
Rb1 O14 Rb4 136.22(12) 3_656 .
Mo4 O15 Rb4 113.06(15) . 3_656
Mo4 O15 Rb1 156.18(17) . 3_556
Rb4 O15 Rb1 84.41(8) 3_656 3_556
Mo4 O15 Rb2 89.21(13) . 4_566
Rb4 O15 Rb2 148.40(11) 3_656 4_566
Rb1 O15 Rb2 82.21(7) 3_556 4_566
Mo3 O16 Mo4 123.15(16) . .
Mo1 O17 Rb3 113.48(15) . .
Mo1 O17 Rb2 107.34(14) . 4_666
Rb3 O17 Rb2 132.71(12) . 4_666
Mo5 O18 Rb4 118.19(15) . 3_656
Mo5 O18 Rb2 107.39(15) . 2_646
Rb4 O18 Rb2 103.40(10) 3_656 2_646
Mo3 O19 Rb3 123.93(15) . 4_566
Mo3 O19 Rb3 96.69(14) . 1_455
Rb3 O19 Rb3 131.29(10) 4_566 1_455
Mo2 O20 Rb3 115.80(15) . .
Mo2 O20 Rb2 138.57(16) . .
Rb3 O20 Rb2 105.45(10) . .
Mo2 O21 Rb3 133.44(17) . 4_565
O18 Rb4 O15 98.02(9) 3_656 3_656
O18 Rb4 O1W 166.85(10) 3_656 .
O15 Rb4 O1W 89.99(10) 3_656 .
O18 Rb4 O12 109.34(9) 3_656 .
O15 Rb4 O12 126.77(9) 3_656 .
O1W Rb4 O12 73.27(10) . .
O18 Rb4 O11 75.56(9) 3_656 1_554
O15 Rb4 O11 116.43(10) 3_656 1_554
O1W Rb4 O11 91.56(10) . 1_554
O12 Rb4 O11 114.23(9) . 1_554
O18 Rb4 O4 69.78(9) 3_656 .
O15 Rb4 O4 97.23(9) 3_656 .
O1W Rb4 O4 119.71(10) . .
O12 Rb4 O4 54.90(8) . .
O11 Rb4 O4 134.41(8) 1_554 .
O18 Rb4 O10 102.90(9) 3_656 1_554
O15 Rb4 O10 65.87(9) 3_656 1_554
O1W Rb4 O10 70.86(10) . 1_554
O12 Rb4 O10 141.90(9) . 1_554
O11 Rb4 O10 55.15(8) 1_554 1_554
O4 Rb4 O10 161.07(8) . 1_554
O18 Rb4 O14 118.12(9) 3_656 .
O15 Rb4 O14 71.21(9) 3_656 .
O1W Rb4 O14 74.31(10) . .
O12 Rb4 O14 55.72(8) . .
O11 Rb4 O14 164.32(9) 1_554 .
O4 Rb4 O14 52.76(8) . .
O10 Rb4 O14 123.53(8) 1_554 .
O18 Rb4 O10 51.21(8) 3_656 3_656
O15 Rb4 O10 50.96(8) 3_656 3_656
O1W Rb4 O10 131.07(9) . 3_656
O12 Rb4 O10 151.15(8) . 3_656
O11 Rb4 O10 83.78(8) 1_554 3_656
O4 Rb4 O10 96.30(8) . 3_656
O10 Rb4 O10 66.74(9) 1_554 3_656
O14 Rb4 O10 110.53(8) . 3_656
O18 Rb4 O6 51.20(8) 3_656 3_656
O15 Rb4 O6 54.16(8) 3_656 3_656
O1W Rb4 O6 140.59(9) . 3_656
O12 Rb4 O6 112.94(8) . 3_656
O11 Rb4 O6 117.33(8) 1_554 3_656
O4 Rb4 O6 58.67(7) . 3_656
O10 Rb4 O6 102.88(8) 1_554 3_656
O14 Rb4 O6 78.34(8) . 3_656
O10 Rb4 O6 39.21(7) 3_656 3_656
O18 Rb4 Mo1 107.98(7) 3_656 .
O15 Rb4 Mo1 97.74(7) 3_656 .
O1W Rb4 Mo1 81.05(8) . .
O12 Rb4 Mo1 31.03(6) . .
O11 Rb4 Mo1 145.11(7) 1_554 .
O4 Rb4 Mo1 38.66(6) . .
O10 Rb4 Mo1 146.88(6) 1_554 .
O14 Rb4 Mo1 27.55(6) . .
O10 Rb4 Mo1 126.33(5) 3_656 .
O6 Rb4 Mo1 87.65(5) 3_656 .
O18 Rb4 Mo4 82.64(7) 3_656 1_554
O15 Rb4 Mo4 90.86(7) 3_656 1_554
O1W Rb4 Mo4 86.85(8) . 1_554
O12 Rb4 Mo4 136.18(6) . 1_554
O11 Rb4 Mo4 26.00(6) 1_554 1_554
O4 Rb4 Mo4 152.05(6) . 1_554
O10 Rb4 Mo4 30.43(6) 1_554 1_554
O14 Rb4 Mo4 153.60(6) . 1_554
O10 Rb4 Mo4 68.40(5) 3_656 1_554
O6 Rb4 Mo4 107.22(5) 3_656 1_554
Mo1 Rb4 Mo4 165.117(16) . 1_554
O18 Rb4 H1WB 161.7 3_656 .
O15 Rb4 H1WB 78.0 3_656 .
O1W Rb4 H1WB 14.2 . .
O12 Rb4 H1WB 86.8 . .
O11 Rb4 H1WB 90.1 1_554 .
O4 Rb4 H1WB 128.2 . .
O10 Rb4 H1WB 59.0 1_554 .
O14 Rb4 H1WB 77.8 . .
O10 Rb4 H1WB 116.8 3_656 .
O6 Rb4 H1WB 131.2 3_656 .
Mo1 Rb4 H1WB 90.3 . .
Mo4 Rb4 H1WB 79.6 1_554 .
O18 Rb4 H1WA 153.2 3_656 .
O15 Rb4 H1WA 102.6 3_656 .
O1W Rb4 H1WA 14.3 . .
O12 Rb4 H1WA 71.2 . .
O11 Rb4 H1WA 80.0 1_554 .
O4 Rb4 H1WA 123.5 . .
O10 Rb4 H1WA 70.9 1_554 .
O14 Rb4 H1WA 85.0 . .
O10 Rb4 H1WA 136.5 3_656 .
O6 Rb4 H1WA 154.8 3_656 .
Mo1 Rb4 H1WA 86.2 . .
Mo4 Rb4 H1WA 80.1 1_554 .
H1WB Rb4 H1WA 24.6 . .
O1W Rb1 O14 75.97(10) 1_455 1_455
O1W Rb1 O2W 64.27(12) 1_455 4_565
O14 Rb1 O2W 127.98(11) 1_455 4_565
O1W Rb1 O13 68.53(10) 1_455 1_454
O14 Rb1 O13 121.28(9) 1_455 1_454
O2W Rb1 O13 74.13(10) 4_565 1_454
O1W Rb1 O14 159.55(10) 1_455 3_656
O14 Rb1 O14 84.19(9) 1_455 3_656
O2W Rb1 O14 134.60(11) 4_565 3_656
O13 Rb1 O14 119.71(9) 1_454 3_656
O1W Rb1 O9 142.83(9) 1_455 3_656
O14 Rb1 O9 132.20(8) 1_455 3_656
O2W Rb1 O9 99.05(10) 4_565 3_656
O13 Rb1 O9 75.08(8) 1_454 3_656
O14 Rb1 O9 52.42(8) 3_656 3_656
O1W Rb1 O15 80.58(10) 1_455 3_556
O14 Rb1 O15 66.84(9) 1_455 3_556
O2W Rb1 O15 131.84(10) 4_565 3_556
O13 Rb1 O15 62.46(9) 1_454 3_556
O14 Rb1 O15 87.18(9) 3_656 3_556
O9 Rb1 O15 89.45(8) 3_656 3_556
O1W Rb1 Se2 124.64(8) 1_455 .
O14 Rb1 Se2 117.34(7) 1_455 .
O2W Rb1 Se2 67.46(9) 4_565 .
O13 Rb1 Se2 121.24(6) 1_454 .
O14 Rb1 Se2 69.18(6) 3_656 .
O9 Rb1 Se2 69.29(5) 3_656 .
O15 Rb1 Se2 154.71(6) 3_556 .
O1W Rb1 Mo1 162.77(8) 1_455 3_656
O14 Rb1 Mo1 104.94(7) 1_455 3_656
O2W Rb1 Mo1 123.02(9) 4_565 3_656
O13 Rb1 Mo1 97.45(6) 1_454 3_656
O14 Rb1 Mo1 24.32(6) 3_656 3_656
O9 Rb1 Mo1 28.68(5) 3_656 3_656
O15 Rb1 Mo1 84.01(6) 3_556 3_656
Se2 Rb1 Mo1 70.751(15) . 3_656
O1W Rb1 Rb4 43.59(8) 1_455 1_455
O14 Rb1 Rb4 48.14(7) 1_455 1_455
O2W Rb1 Rb4 107.49(9) 4_565 1_455
O13 Rb1 Rb4 74.39(6) 1_454 1_455
O14 Rb1 Rb4 117.82(6) 3_656 1_455
O9 Rb1 Rb4 131.61(6) 3_656 1_455
O15 Rb1 Rb4 42.96(6) 3_556 1_455
Se2 Rb1 Rb4 158.70(2) . 1_455
Mo1 Rb1 Rb4 124.58(2) 3_656 1_455
O1W Rb1 Rb2 109.47(8) 1_455 2_545
O14 Rb1 Rb2 113.14(7) 1_455 2_545
O2W Rb1 Rb2 110.94(8) 4_565 2_545
O13 Rb1 Rb2 46.42(6) 1_454 2_545
O14 Rb1 Rb2 73.75(7) 3_656 2_545
O9 Rb1 Rb2 42.83(5) 3_656 2_545
O15 Rb1 Rb2 50.16(6) 3_556 2_545
Se2 Rb1 Rb2 111.800(17) . 2_545
Mo1 Rb1 Rb2 53.953(16) 3_656 2_545
Rb4 Rb1 Rb2 89.435(17) 1_455 2_545
O1W Rb1 Rb1 118.98(8) 1_455 3_556
O14 Rb1 Rb1 43.17(6) 1_455 3_556
O2W Rb1 Rb1 152.73(9) 4_565 3_556
O13 Rb1 Rb1 133.10(7) 1_454 3_556
O14 Rb1 Rb1 41.02(6) 3_656 3_556
O9 Rb1 Rb1 91.36(6) 3_656 3_556
O15 Rb1 Rb1 72.95(6) 3_556 3_556
Se2 Rb1 Rb1 93.36(2) . 3_556
Mo1 Rb1 Rb1 62.830(17) 3_656 3_556
Rb4 Rb1 Rb1 83.146(19) 1_455 3_556
Rb2 Rb1 Rb1 93.83(3) 2_545 3_556
Rb4 O1W Rb1 91.99(11) . 1_655
Rb4 O1W H1WB 109.5 . .
Rb1 O1W H1WB 62.9 1_655 .
Rb4 O1W H1WA 109.3 . .
Rb1 O1W H1WA 158.6 1_655 .
H1WB O1W H1WA 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rb2 O2W 2.791(4) .
Rb2 O11 2.873(3) 4_665
Rb2 O17 2.977(3) 4_565
Rb2 O20 2.980(3) .
Rb2 O9 3.029(3) 4_565
Rb2 O13 3.037(3) 4_565
Rb2 O18 3.067(3) 2_656
Rb2 O1 3.145(3) 4_565
Rb2 O13 3.228(3) 2_656
Rb2 O15 3.453(3) 4_665
Rb2 Mo5 3.7391(8) 4_565
Rb2 Mo4 3.8335(8) 4_665
Rb2 H2WA 3.1776 .
Rb2 H2WB 3.1760 .
Rb3 O20 2.805(3) .
Rb3 O7 2.860(3) 1_655
Rb3 O11 2.920(3) 4_665
Rb3 O17 2.972(3) .
Rb3 O21 3.010(3) 4_666
Rb3 O19 3.106(4) 4_665
Rb3 O19 3.111(3) 1_655
Rb3 O2 3.313(3) 4_665
Rb3 O12 3.348(3) .
Rb3 Mo3 3.7243(8) 1_655
Rb3 Mo2 3.8620(9) .
Rb3 Mo1 3.9747(8) .
Mo1 O17 1.708(3) .
Mo1 O14 1.723(3) .
Mo1 O9 1.918(3) .
Mo1 O12 1.933(3) .
Mo1 O3 2.274(3) .
Mo1 O4 2.315(3) .
Mo1 Rb4 3.7038(9) .
Mo1 Rb2 3.8480(9) 4_666
Mo1 Rb1 3.9739(9) 3_656
Mo2 O20 1.701(3) .
Mo2 O21 1.706(3) .
Mo2 O12 1.944(3) .
Mo2 O8 1.965(3) .
Mo2 O3 2.212(3) .
Mo2 O5 2.308(3) .
Mo2 Rb4 4.2124(8) .
Mo3 O7 1.710(3) .
Mo3 O19 1.717(3) .
Mo3 O8 1.905(3) .
Mo3 O16 1.914(3) .
Mo3 O5 2.312(3) .
Mo3 O2 2.322(3) .
Mo3 Rb3 3.7243(8) 1_455
Mo3 Rb3 4.3070(10) 4_566
Mo4 O15 1.713(3) .
Mo4 O11 1.727(3) .
Mo4 O16 1.918(3) .
Mo4 O10 1.934(3) .
Mo4 O6 2.187(3) .
Mo4 O2 2.371(3) .
Mo4 Rb4 3.7835(9) 1_556
Mo4 Rb2 3.8335(8) 4_566
Mo4 Rb4 3.8576(9) 3_656
Mo4 Rb3 4.2337(9) 4_566
Mo5 O13 1.712(3) .
Mo5 O18 1.718(3) .
Mo5 O10 1.923(3) .
Mo5 O9 1.924(3) .
Mo5 O1 2.313(3) .
Mo5 O6 2.334(3) .
Mo5 Rb2 3.7391(8) 4_666
Mo5 Rb4 3.9247(8) 3_656
Mo5 Rb2 3.9374(8) 2_646
Se1 O1 1.671(3) .
Se1 O2 1.710(3) .
Se1 O3 1.722(3) .
Se2 O4 1.664(3) .
Se2 O5 1.714(3) .
Se2 O6 1.728(3) .
Se2 Rb1 3.8076(10) .
Se2 Rb4 4.1103(9) .
O1 Rb2 3.145(3) 4_666
O2 Rb3 3.313(3) 4_566
O2W Rb1 2.974(5) 4_666
O2W H2WA 0.8501 .
O2W H2WB 0.8501 .
O4 Rb4 2.961(3) .
O6 Rb4 3.595(3) 3_656
O7 Rb3 2.860(3) 1_455
O9 Rb2 3.029(3) 4_666
O9 Rb1 3.280(3) 3_656
O10 Rb4 3.004(3) 1_556
O10 Rb4 3.551(3) 3_656
O11 Rb2 2.873(3) 4_566
O11 Rb3 2.920(3) 4_566
O11 Rb4 2.921(3) 1_556
O12 Rb4 2.872(3) .
O13 Rb1 3.028(3) 1_656
O13 Rb2 3.037(3) 4_666
O13 Rb2 3.228(3) 2_646
O14 Rb1 2.958(3) 1_655
O14 Rb1 3.083(3) 3_656
O14 Rb4 3.105(3) .
O15 Rb4 2.850(3) 3_656
O15 Rb1 3.323(3) 3_556
O15 Rb2 3.453(3) 4_566
O17 Rb2 2.977(3) 4_666
O18 Rb4 2.810(3) 3_656
O18 Rb2 3.067(3) 2_646
O19 Rb3 3.106(4) 4_566
O19 Rb3 3.111(3) 1_455
O21 Rb3 3.010(3) 4_565
Rb4 O18 2.810(3) 3_656
Rb4 O15 2.850(3) 3_656
Rb4 O1W 2.871(4) .
Rb4 O11 2.921(3) 1_554
Rb4 O10 3.004(3) 1_554
Rb4 O10 3.551(3) 3_656
Rb4 O6 3.595(3) 3_656
Rb4 Mo4 3.7835(9) 1_554
Rb4 H1WB 3.2559 .
Rb4 H1WA 3.2529 .
Rb1 O1W 2.914(4) 1_455
Rb1 O14 2.958(3) 1_455
Rb1 O2W 2.974(5) 4_565
Rb1 O13 3.028(3) 1_454
Rb1 O14 3.083(3) 3_656
Rb1 O9 3.280(3) 3_656
Rb1 O15 3.323(3) 3_556
Rb1 Mo1 3.9739(9) 3_656
Rb1 Rb4 4.1616(11) 1_455
Rb1 Rb2 4.4559(11) 2_545
Rb1 Rb1 4.4837(14) 3_556
O1W Rb1 2.914(4) 1_655
O1W H1WB 0.8501 .
O1W H1WA 0.8498 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1W H1WA O19 0.85 2.16 2.872(5) 141.7 4_665
O1W H1WB O1 0.85 2.29 2.851(5) 124.0 1_554
