#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/89/7018926.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7018926
loop_
_publ_author_name
'Li, Suzhi'
'Guo, Yuan Yuan'
'Zhang, Dongdi'
'Ma, Pengtao'
'Qiu, Xiaoyang'
'Wang, Jingping'
'Niu, Jingyang'
_publ_section_title
;
 Four di-Cu(II)-substituted sandwich-type germanomolybdates obtained under
 different reaction conditions: from zero-dimensional to two-dimensional
 structure.
;
_journal_issue                   17
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5235
_journal_page_last               5240
_journal_paper_doi               10.1039/c2dt12491b
_journal_volume                  41
_journal_year                    2012
_chemical_formula_sum            'Cu2 Ge2 H74 Mo18 Na8 O101'
_chemical_formula_weight         3873.74
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   notdet
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                101.422(14)
_cell_angle_beta                 98.402(13)
_cell_angle_gamma                115.982(10)
_cell_formula_units_Z            1
_cell_length_a                   12.482(7)
_cell_length_b                   12.791(8)
_cell_length_c                   17.272(15)
_cell_measurement_reflns_used    2487
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.98
_cell_measurement_theta_min      2.49
_cell_volume                     2343(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0673
_diffrn_reflns_av_sigmaI/netI    0.1081
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            11682
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.25
_exptl_absorpt_coefficient_mu    3.558
_exptl_absorpt_correction_T_max  0.5083
_exptl_absorpt_correction_T_min  0.3165
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            'light green'
_exptl_crystal_density_diffrn    2.742
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1844
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.22
_refine_diff_density_max         1.335
_refine_diff_density_min         -1.849
_refine_diff_density_rms         0.262
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.020
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     631
_refine_ls_number_reflns         8112
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.022
_refine_ls_R_factor_all          0.0671
_refine_ls_R_factor_gt           0.0538
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0372P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1284
_refine_ls_wR_factor_ref         0.1323
_reflns_number_gt                5553
_reflns_number_total             8112
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt12491b.txt
_cod_data_source_block           861299
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'H74 Cu2 Ge2 Mo18 Na8 O101'
_cod_database_code               7018926
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Mo1 Mo 0.45080(9) 0.50780(8) 0.34572(6) 0.0181(2) Uani 1 1 d .
Mo2 Mo 0.27767(8) 0.50843(9) 0.15565(6) 0.0185(2) Uani 1 1 d .
Mo3 Mo 0.32867(9) 0.27906(8) 0.16985(6) 0.0181(2) Uani 1 1 d .
Mo4 Mo 0.65155(9) 0.36884(9) 0.28803(6) 0.0219(2) Uani 1 1 d .
Mo5 Mo 0.88366(9) 0.62968(9) 0.29628(6) 0.0217(2) Uani 1 1 d .
Mo6 Mo 0.72256(9) 0.81115(8) 0.35660(6) 0.0187(2) Uani 1 1 d .
Mo7 Mo 0.82569(9) 0.83825(8) 0.19030(6) 0.0191(2) Uani 1 1 d .
Mo8 Mo 0.54518(9) 0.81130(8) 0.16814(6) 0.0186(2) Uani 1 1 d .
Mo9 Mo 0.42824(9) 0.74723(9) 0.32679(6) 0.0214(2) Uani 1 1 d .
Ge1 Ge 0.58457(10) 0.55254(10) 0.17738(7) 0.0137(3) Uani 1 1 d .
Cu1 Cu 0.60520(12) 0.61900(11) 0.00410(8) 0.0185(3) Uani 1 1 d .
O1 O 0.4257(7) 0.5302(7) 0.4415(4) 0.0273(19) Uani 1 1 d .
O2 O 0.3248(6) 0.5711(6) 0.2959(4) 0.0195(17) Uani 1 1 d .
O3 O 0.3277(6) 0.3468(6) 0.2922(4) 0.0204(17) Uani 1 1 d .
O4 O 0.5575(6) 0.6774(6) 0.3492(4) 0.0205(18) Uani 1 1 d .
O5 O 0.5796(7) 0.4805(6) 0.3565(4) 0.0242(18) Uani 1 1 d .
O6 O 0.4467(6) 0.4844(6) 0.2056(4) 0.0152(16) Uani 1 1 d .
O7 O 0.1483(7) 0.5258(7) 0.1488(5) 0.031(2) Uani 1 1 d .
O8 O 0.2105(7) 0.3446(6) 0.1565(4) 0.0233(18) Uani 1 1 d .
O9 O 0.4104(6) 0.6785(6) 0.1927(4) 0.0183(17) Uani 1 1 d .
O10 O 0.2942(7) 0.4865(6) 0.0570(4) 0.0265(19) Uani 1 1 d .
O11 O 0.2205(7) 0.1304(6) 0.1580(5) 0.0284(19) Uani 1 1 d .
O12 O 0.4785(6) 0.2858(6) 0.2185(4) 0.0212(17) Uani 1 1 d .
O13 O 0.3499(7) 0.2783(6) 0.0702(4) 0.0212(18) Uani 1 1 d .
O14 O 0.6276(8) 0.2934(7) 0.3612(5) 0.036(2) Uani 1 1 d .
O15 O 0.6996(7) 0.2912(7) 0.2197(5) 0.035(2) Uani 1 1 d .
O16 O 0.8102(6) 0.5049(6) 0.3502(4) 0.0203(17) Uani 1 1 d .
O17 O 0.8343(7) 0.9138(6) 0.3124(4) 0.0253(19) Uani 1 1 d .
O18 O 1.0139(7) 0.7261(7) 0.3746(5) 0.034(2) Uani 1 1 d .
O19 O 0.9346(7) 0.5556(7) 0.2297(5) 0.035(2) Uani 1 1 d .
O20 O 0.8852(6) 0.7463(6) 0.2341(4) 0.0227(18) Uani 1 1 d .
O21 O 0.7869(6) 0.7142(6) 0.3634(4) 0.0216(18) Uani 1 1 d .
O22 O 0.7619(7) 0.8998(6) 0.4555(4) 0.0259(19) Uani 1 1 d .
O23 O 0.6469(6) 0.7133(6) 0.2137(4) 0.0129(15) Uani 1 1 d .
O24 O 0.5858(7) 0.8616(6) 0.3083(4) 0.0257(19) Uani 1 1 d .
O25 O 0.9601(7) 0.9587(7) 0.1904(5) 0.0283(19) Uani 1 1 d .
O26 O 0.7171(7) 0.9148(6) 0.1804(4) 0.0234(18) Uani 1 1 d .
O27 O 0.7610(6) 0.7449(6) 0.0875(4) 0.0193(17) Uani 1 1 d .
O28 O 0.4893(7) 0.9119(7) 0.1666(5) 0.029(2) Uani 1 1 d .
O29 O 0.5066(7) 0.7301(7) 0.0670(4) 0.0249(18) Uani 1 1 d .
O30 O 0.4517(7) 0.7927(7) 0.4311(5) 0.032(2) Uani 1 1 d .
O31 O 0.3267(7) 0.7974(7) 0.2922(5) 0.035(2) Uani 1 1 d .
O32 O 0.6871(6) 0.5080(6) 0.2228(4) 0.0167(16) Uani 1 1 d .
O33 O 0.5555(6) 0.5081(6) 0.0708(4) 0.0170(17) Uani 1 1 d .
Na1 Na 0.4876(4) 0.1352(4) 0.4199(3) 0.0369(12) Uani 1 1 d .
Na2 Na 0.0023(4) 0.3046(4) 0.3887(3) 0.0388(13) Uani 1 1 d .
Na3 Na 0.1725(5) 0.1777(5) 0.4388(3) 0.0439(14) Uani 1 1 d .
Na4 Na 0.1658(5) -0.0340(6) 0.2169(4) 0.073(2) Uani 1 1 d .
O1W O 0.3200(8) -0.0447(7) 0.4279(5) 0.038(2) Uani 1 1 d .
O2W O 0.0955(7) 0.2054(7) 0.3099(5) 0.033(2) Uani 1 1 d .
O3W O -0.0227(8) 0.1472(7) 0.4599(6) 0.045(2) Uani 1 1 d .
O4W O 0.2049(8) 0.3912(8) 0.4857(5) 0.044(2) Uani 1 1 d .
O5W O 0.3821(7) 0.2537(7) 0.4281(5) 0.035(2) Uani 1 1 d .
O6W O 0.6553(8) 0.0911(7) 0.4169(5) 0.042(2) Uani 1 1 d .
O7W O 0.3901(8) 0.0511(8) 0.2644(5) 0.044(2) Uani 1 1 d .
O8W O -0.1835(8) 0.1651(8) 0.2789(7) 0.064(3) Uani 1 1 d .
O9W O 0.1298(8) -0.0179(7) 0.3499(5) 0.047(3) Uani 1 1 d .
O10W O -0.2743(11) 0.3810(11) 0.0680(6) 0.079(4) Uani 1 1 d .
O11W O 0.0870(9) 0.4802(10) 0.3379(7) 0.073(3) Uani 1 1 d .
O12W O -0.1179(10) 0.3558(10) 0.4716(7) 0.079(4) Uani 1 1 d .
O13W O -0.0708(11) 0.4293(14) 0.0966(9) 0.130(6) Uani 1 1 d .
O14W O 0.177(2) -0.207(2) 0.1467(15) 0.062(7) Uani 0.50 1 d P
O15W O 0.131(3) -0.236(3) 0.1840(17) 0.101(12) Uani 0.50 1 d P
O16W O -0.505(2) -0.1124(19) -0.0584(12) 0.071(7) Uani 0.50 1 d P
O17W O -0.066(4) 0.272(3) 0.141(3) 0.119(16) Uani 0.50 1 d P
O18W O 0.764(2) 1.001(2) 0.0343(14) 0.103(9) Uani 0.50 1 d P
O19W O -0.665(3) -0.136(2) 0.0111(15) 0.152(16) Uani 0.50 1 d P
O20W O -0.051(2) -0.397(2) 0.0553(16) 0.101(8) Uani 0.50 1 d PU
O21W O -0.043(3) 0.216(4) 0.151(2) 0.139(18) Uani 0.50 1 d P
O22W O -0.008(3) -0.133(3) 0.0187(17) 0.125(10) Uani 0.50 1 d PU
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Mo1 O5 105.6(4) . .
O1 Mo1 O3 102.0(3) . .
O5 Mo1 O3 97.5(3) . .
O1 Mo1 O4 100.2(3) . .
O5 Mo1 O4 90.9(3) . .
O3 Mo1 O4 153.1(3) . .
O1 Mo1 O2 94.0(3) . .
O5 Mo1 O2 157.4(3) . .
O3 Mo1 O2 89.1(3) . .
O4 Mo1 O2 74.3(3) . .
O1 Mo1 O6 167.0(3) . .
O5 Mo1 O6 87.4(3) . .
O3 Mo1 O6 75.8(3) . .
O4 Mo1 O6 79.2(3) . .
O2 Mo1 O6 73.3(2) . .
O7 Mo2 O10 104.5(4) . .
O7 Mo2 O8 100.2(3) . .
O10 Mo2 O8 97.7(3) . .
O7 Mo2 O9 101.8(3) . .
O10 Mo2 O9 93.2(3) . .
O8 Mo2 O9 152.1(3) . .
O7 Mo2 O2 90.8(3) . .
O10 Mo2 O2 161.2(3) . .
O8 Mo2 O2 90.1(3) . .
O9 Mo2 O2 72.7(3) . .
O7 Mo2 O6 162.2(3) . .
O10 Mo2 O6 93.1(3) . .
O8 Mo2 O6 74.6(3) . .
O9 Mo2 O6 79.3(3) . .
O2 Mo2 O6 72.4(2) . .
O11 Mo3 O13 104.2(3) . .
O11 Mo3 O12 102.5(3) . .
O13 Mo3 O12 98.3(3) . .
O11 Mo3 O8 97.1(3) . .
O13 Mo3 O8 93.0(3) . .
O12 Mo3 O8 154.1(3) . .
O11 Mo3 O3 94.9(3) . .
O13 Mo3 O3 159.5(3) . .
O12 Mo3 O3 84.8(3) . .
O8 Mo3 O3 76.8(3) . .
O11 Mo3 O6 166.7(3) . .
O13 Mo3 O6 86.5(3) . .
O12 Mo3 O6 83.4(3) . .
O8 Mo3 O6 74.1(3) . .
O3 Mo3 O6 73.6(3) . .
O14 Mo4 O15 104.1(4) . .
O14 Mo4 O16 96.9(4) . .
O15 Mo4 O16 99.3(3) . .
O14 Mo4 O12 98.7(4) . .
O15 Mo4 O12 93.9(3) . .
O16 Mo4 O12 156.5(3) . .
O14 Mo4 O32 163.6(3) . .
O15 Mo4 O32 91.2(3) . .
O16 Mo4 O32 74.4(3) . .
O12 Mo4 O32 86.1(3) . .
O14 Mo4 O5 85.9(3) . .
O15 Mo4 O5 169.2(3) . .
O16 Mo4 O5 83.2(3) . .
O12 Mo4 O5 80.4(3) . .
O32 Mo4 O5 79.4(3) . .
O18 Mo5 O19 103.3(4) . .
O18 Mo5 O16 97.0(4) . .
O19 Mo5 O16 98.7(4) . .
O18 Mo5 O20 99.1(4) . .
O19 Mo5 O20 95.6(4) . .
O16 Mo5 O20 155.3(3) . .
O18 Mo5 O21 86.8(3) . .
O19 Mo5 O21 169.3(3) . .
O16 Mo5 O21 82.9(3) . .
O20 Mo5 O21 79.4(3) . .
O18 Mo5 O32 163.5(3) . .
O19 Mo5 O32 91.5(3) . .
O16 Mo5 O32 73.3(3) . .
O20 Mo5 O32 86.5(3) . .
O21 Mo5 O32 78.9(2) . .
O22 Mo6 O21 104.5(3) . .
O22 Mo6 O17 102.3(3) . .
O21 Mo6 O17 98.1(3) . .
O22 Mo6 O4 101.0(3) . .
O21 Mo6 O4 90.1(3) . .
O17 Mo6 O4 152.4(3) . .
O22 Mo6 O24 95.6(3) . .
O21 Mo6 O24 155.9(3) . .
O17 Mo6 O24 90.2(3) . .
O4 Mo6 O24 72.9(3) . .
O22 Mo6 O23 167.7(3) . .
O21 Mo6 O23 87.8(3) . .
O17 Mo6 O23 75.6(3) . .
O4 Mo6 O23 78.5(3) . .
O24 Mo6 O23 72.3(2) . .
O22 Mo6 Na3 38.6(3) . 2_666
O21 Mo6 Na3 67.6(3) . 2_666
O17 Mo6 Na3 117.5(2) . 2_666
O4 Mo6 Na3 90.0(2) . 2_666
O24 Mo6 Na3 127.8(2) . 2_666
O23 Mo6 Na3 152.86(18) . 2_666
O25 Mo7 O27 105.3(3) . .
O25 Mo7 O20 101.2(3) . .
O27 Mo7 O20 99.1(3) . .
O25 Mo7 O26 98.0(3) . .
O27 Mo7 O26 93.3(3) . .
O20 Mo7 O26 153.4(3) . .
O25 Mo7 O17 94.3(3) . .
O27 Mo7 O17 158.9(3) . .
O20 Mo7 O17 84.3(3) . .
O26 Mo7 O17 76.1(3) . .
O25 Mo7 O23 166.2(3) . .
O27 Mo7 O23 86.2(3) . .
O20 Mo7 O23 84.0(3) . .
O26 Mo7 O23 73.4(3) . .
O17 Mo7 O23 73.4(3) . .
O28 Mo8 O29 104.6(4) . .
O28 Mo8 O26 100.9(3) . .
O29 Mo8 O26 98.0(3) . .
O28 Mo8 O9 101.5(3) . .
O29 Mo8 O9 93.2(3) . .
O26 Mo8 O9 151.4(3) . .
O28 Mo8 O24 90.7(3) . .
O29 Mo8 O24 161.9(3) . .
O26 Mo8 O24 88.5(3) . .
O9 Mo8 O24 73.9(3) . .
O28 Mo8 O23 161.5(3) . .
O29 Mo8 O23 93.8(3) . .
O26 Mo8 O23 73.7(3) . .
O9 Mo8 O23 79.4(3) . .
O24 Mo8 O23 71.7(2) . .
O30 Mo9 O31 102.3(4) . .
O30 Mo9 O2 103.9(3) . .
O31 Mo9 O2 103.4(3) . .
O30 Mo9 O24 104.0(3) . .
O31 Mo9 O24 103.0(4) . .
O2 Mo9 O24 136.0(3) . .
O30 Mo9 O4 87.2(3) . .
O31 Mo9 O4 170.4(3) . .
O2 Mo9 O4 75.2(3) . .
O24 Mo9 O4 72.9(3) . .
O30 Mo9 O9 173.9(3) . .
O31 Mo9 O9 83.9(3) . .
O2 Mo9 O9 74.0(3) . .
O24 Mo9 O9 74.6(3) . .
O4 Mo9 O9 86.7(3) . .
O6 Ge1 O33 110.0(3) . .
O6 Ge1 O32 108.3(3) . .
O33 Ge1 O32 110.7(3) . .
O6 Ge1 O23 108.1(3) . .
O33 Ge1 O23 109.2(3) . .
O32 Ge1 O23 110.5(3) . .
O33 Cu1 O33 81.0(3) . 2_665
O33 Cu1 O13 176.1(3) . 2_665
O33 Cu1 O13 95.8(3) 2_665 2_665
O33 Cu1 O27 95.1(3) . .
O33 Cu1 O27 175.1(3) 2_665 .
O13 Cu1 O27 88.2(3) 2_665 .
O33 Cu1 O10 89.5(3) . 2_665
O33 Cu1 O10 90.1(3) 2_665 2_665
O13 Cu1 O10 88.2(3) 2_665 2_665
O27 Cu1 O10 92.8(3) . 2_665
O33 Cu1 Cu1 40.78(19) . 2_665
O33 Cu1 Cu1 40.2(2) 2_665 2_665
O13 Cu1 Cu1 136.0(2) 2_665 2_665
O27 Cu1 Cu1 135.8(2) . 2_665
O10 Cu1 Cu1 89.76(19) 2_665 2_665
Mo9 O2 Mo1 103.6(3) . .
Mo9 O2 Mo2 105.0(3) . .
Mo1 O2 Mo2 108.9(3) . .
Mo1 O3 Mo3 114.5(3) . .
Mo1 O4 Mo6 150.1(4) . .
Mo1 O4 Mo9 103.8(3) . .
Mo6 O4 Mo9 105.9(3) . .
Mo1 O5 Mo4 140.9(4) . .
Ge1 O6 Mo3 121.6(3) . .
Ge1 O6 Mo2 121.4(4) . .
Mo3 O6 Mo2 92.0(2) . .
Ge1 O6 Mo1 120.0(3) . .
Mo3 O6 Mo1 93.0(3) . .
Mo2 O6 Mo1 102.3(2) . .
Mo2 O8 Mo3 116.6(4) . .
Mo2 O9 Mo8 148.0(4) . .
Mo2 O9 Mo9 106.1(3) . .
Mo8 O9 Mo9 105.6(3) . .
Mo2 O10 Cu1 127.6(4) . 2_665
Mo3 O11 Na4 144.7(4) . .
Mo3 O12 Mo4 154.4(4) . .
Mo3 O13 Cu1 143.5(4) . 2_665
Mo4 O14 Na1 151.3(4) . .
Mo4 O16 Mo5 115.4(3) . .
Mo6 O17 Mo7 115.5(4) . .
Mo7 O20 Mo5 155.7(4) . .
Mo6 O21 Mo5 141.0(4) . .
Mo6 O22 Na3 115.3(4) . 2_666
Ge1 O23 Mo7 120.2(3) . .
Ge1 O23 Mo8 122.2(3) . .
Mo7 O23 Mo8 93.5(2) . .
Ge1 O23 Mo6 119.1(3) . .
Mo7 O23 Mo6 92.2(2) . .
Mo8 O23 Mo6 103.2(3) . .
Mo9 O24 Mo6 105.5(3) . .
Mo9 O24 Mo8 103.3(3) . .
Mo6 O24 Mo8 109.4(3) . .
Mo7 O25 Na4 124.2(4) . 1_665
Mo8 O26 Mo7 116.1(3) . .
Mo7 O27 Cu1 144.9(4) . .
Mo9 O30 Na1 172.7(5) . 2_666
Ge1 O32 Mo4 129.2(4) . .
Ge1 O32 Mo5 127.0(3) . .
Mo4 O32 Mo5 95.0(3) . .
Ge1 O33 Cu1 125.1(4) . .
Ge1 O33 Cu1 124.0(4) . 2_665
Cu1 O33 Cu1 99.0(3) . 2_665
O1W Na1 O6W 105.8(3) . .
O1W Na1 O5W 95.6(3) . .
O6W Na1 O5W 158.3(4) . .
O1W Na1 O30 88.3(3) . 2_666
O6W Na1 O30 92.1(3) . 2_666
O5W Na1 O30 85.4(3) . 2_666
O1W Na1 O14 160.8(3) . .
O6W Na1 O14 76.9(3) . .
O5W Na1 O14 83.9(3) . .
O30 Na1 O14 110.8(3) 2_666 .
O1W Na1 O7W 85.8(3) . .
O6W Na1 O7W 95.7(3) . .
O5W Na1 O7W 88.8(3) . .
O30 Na1 O7W 171.3(4) 2_666 .
O14 Na1 O7W 75.0(3) . .
O12W Na2 O2W 166.2(4) . .
O12W Na2 O11W 101.1(4) . .
O2W Na2 O11W 92.3(4) . .
O12W Na2 O8W 90.8(4) . .
O2W Na2 O8W 83.5(3) . .
O11W Na2 O8W 101.3(4) . .
O12W Na2 O4W 103.3(4) . .
O2W Na2 O4W 80.0(3) . .
O11W Na2 O4W 88.0(4) . .
O8W Na2 O4W 161.3(4) . .
O12W Na2 O3W 86.0(4) . .
O2W Na2 O3W 81.8(3) . .
O11W Na2 O3W 164.0(4) . .
O8W Na2 O3W 92.8(4) . .
O4W Na2 O3W 76.3(3) . .
O12W Na2 Na3 125.1(3) . .
O2W Na2 Na3 47.6(2) . .
O11W Na2 Na3 120.1(3) . .
O8W Na2 Na3 112.6(3) . .
O4W Na2 Na3 49.2(2) . .
O3W Na2 Na3 46.0(2) . .
O3W Na3 O5W 167.8(4) . .
O3W Na3 O9W 104.9(4) . .
O5W Na3 O9W 86.8(3) . .
O3W Na3 O22 100.3(3) . 2_666
O5W Na3 O22 84.5(3) . 2_666
O9W Na3 O22 82.0(3) . 2_666
O3W Na3 O2W 83.4(3) . .
O5W Na3 O2W 94.7(3) . .
O9W Na3 O2W 83.4(3) . .
O22 Na3 O2W 165.4(3) 2_666 .
O3W Na3 O4W 76.9(3) . .
O5W Na3 O4W 90.9(3) . .
O9W Na3 O4W 161.2(4) . .
O22 Na3 O4W 116.4(3) 2_666 .
O2W Na3 O4W 78.2(3) . .
O3W Na3 Na2 48.6(2) . .
O5W Na3 Na2 122.4(3) . .
O9W Na3 Na2 119.9(3) . .
O22 Na3 Na2 143.7(3) 2_666 .
O2W Na3 Na2 47.0(2) . .
O4W Na3 Na2 47.4(2) . .
O3W Na3 Mo6 90.9(3) . 2_666
O5W Na3 Mo6 88.7(2) . 2_666
O9W Na3 Mo6 107.9(3) . 2_666
O22 Na3 Mo6 26.02(17) 2_666 2_666
O2W Na3 Mo6 168.4(3) . 2_666
O4W Na3 Mo6 90.7(2) . 2_666
Na2 Na3 Mo6 122.33(18) . 2_666
O3W Na3 Na4 116.7(3) . .
O5W Na3 Na4 72.2(2) . .
O9W Na3 Na4 29.4(2) . .
O22 Na3 Na4 105.5(2) 2_666 .
O2W Na3 Na4 60.7(2) . .
O4W Na3 Na4 133.0(3) . .
Na2 Na3 Na4 105.86(18) . .
Mo6 Na3 Na4 130.80(16) 2_666 .
O15W Na4 O14W 23.2(7) . .
O15W Na4 O11 139.3(8) . .
O14W Na4 O11 117.1(7) . .
O15W Na4 O9W 98.2(7) . .
O14W Na4 O9W 119.8(7) . .
O11 Na4 O9W 122.5(4) . .
O15W Na4 O7W 93.0(7) . .
O14W Na4 O7W 82.8(7) . .
O11 Na4 O7W 83.4(3) . .
O9W Na4 O7W 95.9(4) . .
O15W Na4 O25 107.7(8) . 1_445
O14W Na4 O25 117.5(7) . 1_445
O11 Na4 O25 82.8(3) . 1_445
O9W Na4 O25 78.5(3) . 1_445
O7W Na4 O25 159.1(4) . 1_445
O15W Na4 Na3 128.0(7) . .
O14W Na4 Na3 147.9(7) . .
O11 Na4 Na3 92.6(3) . .
O9W Na4 Na3 30.1(2) . .
O7W Na4 Na3 89.3(3) . .
O25 Na4 Na3 75.7(2) 1_445 .
Na2 O2W Na3 85.4(3) . .
Na3 O3W Na2 85.3(3) . .
Na2 O4W Na3 83.5(3) . .
Na1 O5W Na3 124.0(4) . .
Na4 O7W Na1 117.3(4) . .
Na4 O9W Na3 120.5(4) . .
O15W O14W Na4 77(3) . .
O14W O15W Na4 80(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Mo1 O1 1.719(8) .
Mo1 O5 1.780(7) .
Mo1 O3 1.875(7) .
Mo1 O4 1.969(7) .
Mo1 O2 2.206(7) .
Mo1 O6 2.369(7) .
Mo2 O7 1.715(7) .
Mo2 O10 1.729(8) .
Mo2 O8 1.890(7) .
Mo2 O9 1.966(7) .
Mo2 O2 2.293(7) .
Mo2 O6 2.331(7) .
Mo3 O11 1.731(7) .
Mo3 O13 1.778(7) .
Mo3 O12 1.893(7) .
Mo3 O8 1.998(7) .
Mo3 O3 2.124(7) .
Mo3 O6 2.269(7) .
Mo4 O14 1.720(8) .
Mo4 O15 1.733(8) .
Mo4 O16 1.929(7) .
Mo4 O12 1.990(7) .
Mo4 O32 2.211(7) .
Mo4 O5 2.238(7) .
Mo5 O18 1.713(7) .
Mo5 O19 1.713(8) .
Mo5 O16 1.953(7) .
Mo5 O20 1.998(7) .
Mo5 O21 2.241(7) .
Mo5 O32 2.240(7) .
Mo6 O22 1.717(7) .
Mo6 O21 1.761(7) .
Mo6 O17 1.832(8) .
Mo6 O4 1.984(7) .
Mo6 O24 2.189(7) .
Mo6 O23 2.368(7) .
Mo6 Na3 3.537(6) 2_666
Mo7 O25 1.710(7) .
Mo7 O27 1.768(7) .
Mo7 O20 1.860(7) .
Mo7 O26 1.996(7) .
Mo7 O17 2.105(7) .
Mo7 O23 2.256(7) .
Mo8 O28 1.714(7) .
Mo8 O29 1.720(7) .
Mo8 O26 1.916(7) .
Mo8 O9 1.972(7) .
Mo8 O24 2.295(8) .
Mo8 O23 2.302(7) .
Mo9 O30 1.717(8) .
Mo9 O31 1.737(7) .
Mo9 O2 1.950(7) .
Mo9 O24 1.990(8) .
Mo9 O4 2.183(7) .
Mo9 O9 2.248(7) .
Ge1 O6 1.749(7) .
Ge1 O33 1.748(7) .
Ge1 O32 1.760(7) .
Ge1 O23 1.781(6) .
Cu1 O33 1.951(7) .
Cu1 O33 1.973(7) 2_665
Cu1 O13 1.980(7) 2_665
Cu1 O27 1.993(7) .
Cu1 O10 2.412(7) 2_665
Cu1 Cu1 2.983(3) 2_665
O10 Cu1 2.412(7) 2_665
O11 Na4 2.390(10) .
O13 Cu1 1.980(7) 2_665
O14 Na1 2.532(10) .
O22 Na3 2.444(9) 2_666
O25 Na4 2.497(10) 1_665
O30 Na1 2.435(9) 2_666
O33 Cu1 1.973(7) 2_665
Na1 O1W 2.384(10) .
Na1 O6W 2.400(10) .
Na1 O5W 2.402(9) .
Na1 O30 2.435(9) 2_666
Na1 O7W 2.570(10) .
Na2 O12W 2.418(12) .
Na2 O2W 2.426(9) .
Na2 O11W 2.430(11) .
Na2 O8W 2.430(10) .
Na2 O4W 2.450(9) .
Na2 O3W 2.490(10) .
Na2 Na3 3.307(7) .
Na3 O3W 2.389(10) .
Na3 O5W 2.410(10) .
Na3 O9W 2.444(10) .
Na3 O22 2.444(9) 2_666
Na3 O2W 2.448(10) .
Na3 O4W 2.518(10) .
Na3 Mo6 3.537(6) 2_666
Na3 Na4 4.197(9) .
Na4 O15W 2.35(4) .
Na4 O14W 2.37(2) .
Na4 O9W 2.389(12) .
Na4 O7W 2.450(11) .
Na4 O25 2.497(10) 1_445
O14W O15W 0.95(3) .
O17W O21W 0.92(5) .
