#------------------------------------------------------------------------------
#$Date: 2016-03-25 14:24:27 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179894 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/90/7019083.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7019083
loop_
_publ_author_name
'McCann, Malachy'
'Curran, Robert'
'Ben-Shoshan, Marcia'
'McKee, Vickie'
'Tahir, Asif Ali'
'Devereux, Michael'
'Kavanagh, Kevin'
'Creaven, Bernadette S.'
'Kellett, Andrew'
_publ_section_title
;
 Silver(i) complexes of 9-anthracenecarboxylic acid and imidazoles:
 synthesis, structure and antimicrobial activity.
;
_journal_issue                   21
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6516
_journal_page_last               6527
_journal_paper_doi               10.1039/c2dt12166b
_journal_volume                  41
_journal_year                    2012
_chemical_formula_sum            'C104 H78 Ag6 N8 O14'
_chemical_formula_weight         2310.96
_chemical_name_systematic        ' ?'
_space_group_IT_number           60
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2n 2ab'
_symmetry_space_group_name_H-M   'P b c n'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   20.6935(8)
_cell_length_b                   18.2786(7)
_cell_length_c                   23.6859(10)
_cell_measurement_reflns_used    9940
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      25.13
_cell_measurement_theta_min      2.27
_cell_volume                     8959.1(6)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0580
_diffrn_reflns_av_sigmaI/netI    0.0328
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            80667
_diffrn_reflns_theta_full        27.00
_diffrn_reflns_theta_max         27.00
_diffrn_reflns_theta_min         1.72
_exptl_absorpt_coefficient_mu    1.358
_exptl_absorpt_correction_T_max  0.8540
_exptl_absorpt_correction_T_min  0.7453
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS v2008/1, Sheldrick, G.M., (2008)'
_exptl_crystal_colour            'Pale yellow'
_exptl_crystal_density_diffrn    1.713
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             4608
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.487
_refine_diff_density_min         -0.788
_refine_diff_density_rms         0.082
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     599
_refine_ls_number_reflns         9793
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.025
_refine_ls_R_factor_all          0.0475
_refine_ls_R_factor_gt           0.0316
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0314P)²+6.8463P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0695
_refine_ls_wR_factor_ref         0.0765
_reflns_number_gt                7518
_reflns_number_total             9793
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt12166b.txt
_cod_data_source_block           Complex_4(agaca)
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      Pbcn
_cod_database_code               7019083
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y+1/2, z+1/2'
'-x, y, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y-1/2, -z-1/2'
'x, -y, z-1/2'
'-x-1/2, y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.318014(12) 0.374879(12) 0.256413(10) 0.03302(7) Uani 1 1 d .
N21 N 0.33669(13) 0.27676(14) 0.21431(11) 0.0354(6) Uani 1 1 d .
C21 C 0.32060(15) 0.20923(16) 0.22901(13) 0.0329(7) Uani 1 1 d .
H21 H 0.2965 0.1970 0.2618 0.040 Uiso 1 1 calc R
N22 N 0.34283(13) 0.16068(14) 0.19156(11) 0.0345(6) Uani 1 1 d .
H22N H 0.3377 0.1129 0.1931 0.041 Uiso 1 1 calc R
C22 C 0.37478(17) 0.19814(18) 0.15057(15) 0.0447(9) Uani 1 1 d .
H22 H 0.3957 0.1783 0.1183 0.054 Uiso 1 1 calc R
C23 C 0.37066(17) 0.27008(18) 0.16526(15) 0.0427(8) Uani 1 1 d .
H23 H 0.3887 0.3096 0.1445 0.051 Uiso 1 1 calc R
N31 N 0.30862(11) 0.47615(13) 0.29644(10) 0.0292(5) Uani 1 1 d .
C31 C 0.32444(15) 0.54174(16) 0.27644(13) 0.0311(7) Uani 1 1 d .
H31 H 0.3407 0.5508 0.2396 0.037 Uiso 1 1 calc R
N32 N 0.31426(12) 0.59298(13) 0.31554(11) 0.0312(6) Uani 1 1 d .
H32N H 0.3212 0.6402 0.3114 0.037 Uiso 1 1 calc R
C32 C 0.29127(15) 0.55980(17) 0.36301(14) 0.0344(7) Uani 1 1 d .
H32 H 0.2800 0.5828 0.3976 0.041 Uiso 1 1 calc R
C33 C 0.28776(15) 0.48755(16) 0.35102(13) 0.0332(7) Uani 1 1 d .
H33 H 0.2732 0.4506 0.3762 0.040 Uiso 1 1 calc R
Ag2 Ag 0.172810(12) 0.405812(14) 0.265499(10) 0.03682(7) Uani 1 1 d .
O1A O 0.19335(10) 0.40052(11) 0.16519(9) 0.0341(5) Uani 1 1 d .
O2A O 0.17089(10) 0.50905(11) 0.20131(8) 0.0325(5) Uani 1 1 d .
C1A C 0.18562(13) 0.46834(16) 0.16071(12) 0.0269(6) Uani 1 1 d .
C2A C 0.19812(14) 0.50382(15) 0.10419(11) 0.0243(6) Uani 1 1 d .
C3A C 0.26261(14) 0.51010(15) 0.08645(12) 0.0254(6) Uani 1 1 d .
C4A C 0.31562(14) 0.48203(16) 0.11831(12) 0.0297(7) Uani 1 1 d .
H4A H 0.3075 0.4575 0.1529 0.036 Uiso 1 1 calc R
C5A C 0.37716(15) 0.48971(17) 0.10012(13) 0.0341(7) Uani 1 1 d .
H5A H 0.4117 0.4706 0.1221 0.041 Uiso 1 1 calc R
C6A C 0.39070(15) 0.52599(18) 0.04867(14) 0.0379(8) Uani 1 1 d .
H6A H 0.4341 0.5310 0.0362 0.046 Uiso 1 1 calc R
C7A C 0.34164(15) 0.55379(18) 0.01702(14) 0.0379(8) Uani 1 1 d .
H7A H 0.3513 0.5778 -0.0175 0.046 Uiso 1 1 calc R
C8A C 0.27599(15) 0.54763(16) 0.03460(12) 0.0296(7) Uani 1 1 d .
C9A C 0.22578(15) 0.57758(16) 0.00341(13) 0.0322(7) Uani 1 1 d .
H9A H 0.2353 0.6030 -0.0306 0.039 Uiso 1 1 calc R
C10A C 0.16163(14) 0.57123(15) 0.02090(12) 0.0280(6) Uani 1 1 d .
C11A C 0.10981(15) 0.60236(16) -0.01039(13) 0.0343(7) Uani 1 1 d .
H11A H 0.1188 0.6283 -0.0442 0.041 Uiso 1 1 calc R
C12A C 0.04797(16) 0.59562(18) 0.00716(15) 0.0394(8) Uani 1 1 d .
H12A H 0.0140 0.6172 -0.0141 0.047 Uiso 1 1 calc R
C13A C 0.03359(15) 0.55631(18) 0.05729(14) 0.0381(8) Uani 1 1 d .
H13A H -0.0101 0.5510 0.0689 0.046 Uiso 1 1 calc R
C14A C 0.08109(14) 0.52634(17) 0.08870(13) 0.0319(7) Uani 1 1 d .
H14A H 0.0703 0.5005 0.1222 0.038 Uiso 1 1 calc R
C15A C 0.14721(14) 0.53288(15) 0.07239(11) 0.0251(6) Uani 1 1 d .
O1B O 0.19310(11) 0.35159(11) 0.34736(8) 0.0333(5) Uani 1 1 d .
O2B O 0.17915(10) 0.24575(10) 0.30164(8) 0.0309(5) Uani 1 1 d .
C1B C 0.18600(13) 0.28327(15) 0.34550(12) 0.0240(6) Uani 1 1 d .
C2B C 0.18308(14) 0.24420(14) 0.40207(11) 0.0233(6) Uani 1 1 d .
C3B C 0.23941(14) 0.23241(14) 0.43379(12) 0.0245(6) Uani 1 1 d .
C4B C 0.30171(15) 0.25786(15) 0.41721(12) 0.0288(6) Uani 1 1 d .
H4B H 0.3061 0.2852 0.3833 0.035 Uiso 1 1 calc R
C5B C 0.35483(16) 0.24374(16) 0.44894(13) 0.0344(7) Uani 1 1 d .
H5B H 0.3958 0.2613 0.4369 0.041 Uiso 1 1 calc R
C6B C 0.35011(16) 0.20317(18) 0.49979(14) 0.0402(8) Uani 1 1 d .
H6B H 0.3878 0.1937 0.5215 0.048 Uiso 1 1 calc R
C7B C 0.29201(16) 0.17781(17) 0.51739(13) 0.0371(8) Uani 1 1 d .
H7B H 0.2895 0.1501 0.5513 0.045 Uiso 1 1 calc R
C8B C 0.23432(15) 0.19203(15) 0.48588(12) 0.0291(6) Uani 1 1 d .
C9B C 0.17392(15) 0.16823(16) 0.50418(13) 0.0329(7) Uani 1 1 d .
H9B H 0.1710 0.1408 0.5382 0.039 Uiso 1 1 calc R
C10B C 0.11790(14) 0.18347(15) 0.47415(12) 0.0281(6) Uani 1 1 d .
C11B C 0.05558(15) 0.16313(17) 0.49426(14) 0.0363(7) Uani 1 1 d .
H11B H 0.0520 0.1368 0.5287 0.044 Uiso 1 1 calc R
C12B C 0.00146(16) 0.18066(18) 0.46525(13) 0.0371(7) Uani 1 1 d .
H12B H -0.0396 0.1675 0.4800 0.045 Uiso 1 1 calc R
C13B C 0.00542(15) 0.21855(17) 0.41301(13) 0.0338(7) Uani 1 1 d .
H13B H -0.0329 0.2306 0.3930 0.041 Uiso 1 1 calc R
C14B C 0.06405(15) 0.23756(16) 0.39176(13) 0.0298(7) Uani 1 1 d .
H14B H 0.0662 0.2621 0.3564 0.036 Uiso 1 1 calc R
C15B C 0.12250(14) 0.22159(14) 0.42125(12) 0.0255(6) Uani 1 1 d .
Ag3 Ag 0.067640(12) 0.249613(11) 0.235556(10) 0.03105(7) Uani 1 1 d .
O1C O 0.05316(10) 0.36664(11) 0.24346(10) 0.0372(5) Uani 1 1 d .
C1C C 0.0000 0.3978(2) 0.2500 0.0283(9) Uani 1 2 d S
C2C C 0.0000 0.4795(2) 0.2500 0.0302(9) Uani 1 2 d S
C3C C -0.03848(15) 0.51677(15) 0.21093(14) 0.0331(7) Uani 1 1 d .
C4C C -0.07695(15) 0.48066(17) 0.16913(14) 0.0352(7) Uani 1 1 d .
H4C H -0.0741 0.4290 0.1655 0.042 Uiso 1 1 calc R
C5C C -0.11730(16) 0.51826(19) 0.13457(15) 0.0427(8) Uani 1 1 d .
H5C H -0.1435 0.4927 0.1082 0.051 Uiso 1 1 calc R
C6C C -0.12043(18) 0.59607(19) 0.13782(17) 0.0483(9) Uani 1 1 d .
H6C H -0.1497 0.6222 0.1144 0.058 Uiso 1 1 calc R
C7C C -0.08192(18) 0.63276(18) 0.17403(17) 0.0468(9) Uani 1 1 d .
H7C H -0.0831 0.6847 0.1743 0.056 Uiso 1 1 calc R
C8C C -0.03953(16) 0.59571(16) 0.21190(15) 0.0379(8) Uani 1 1 d .
C9C C 0.0000 0.6321(2) 0.2500 0.0435(12) Uani 1 2 d S
H9C H 0.0000 0.6841 0.2500 0.052 Uiso 1 2 calc SR
O1D O 0.05248(10) 0.13288(10) 0.23794(9) 0.0338(5) Uani 1 1 d .
C1D C 0.0000 0.1034(2) 0.2500 0.0241(8) Uani 1 2 d S
C2D C 0.0000 0.0207(2) 0.2500 0.0224(8) Uani 1 2 d S
C3D C -0.01833(13) -0.01659(14) 0.20080(11) 0.0222(6) Uani 1 1 d .
C4D C -0.03733(13) 0.02107(15) 0.15056(12) 0.0258(6) Uani 1 1 d .
H4D H -0.0377 0.0730 0.1501 0.031 Uiso 1 1 calc R
C5D C -0.05473(14) -0.01634(16) 0.10379(12) 0.0296(7) Uani 1 1 d .
H5D H -0.0679 0.0093 0.0709 0.036 Uiso 1 1 calc R
C6D C -0.05334(15) -0.09423(17) 0.10388(13) 0.0321(7) Uani 1 1 d .
H6D H -0.0650 -0.1202 0.0707 0.039 Uiso 1 1 calc R
C7D C -0.03565(15) -0.13145(16) 0.15041(13) 0.0311(7) Uani 1 1 d .
H7D H -0.0351 -0.1834 0.1493 0.037 Uiso 1 1 calc R
C8D C -0.01783(13) -0.09533(15) 0.20107(12) 0.0245(6) Uani 1 1 d .
C9D C 0.0000 -0.1325(2) 0.2500 0.0269(9) Uani 1 2 d S
H9D H 0.0000 -0.1844 0.2500 0.032 Uiso 1 2 calc SR
O41 O 0.13626(10) 0.26392(11) 0.15108(9) 0.0364(5) Uani 1 1 d .
H41 H 0.1683 0.3006 0.1534 0.044 Uiso 1 1 d .
C41 C 0.18100(18) 0.2046(2) 0.14033(17) 0.0554(10) Uani 1 1 d .
H41A H 0.2035 0.1919 0.1754 0.083 Uiso 1 1 calc R
H41B H 0.2126 0.2199 0.1119 0.083 Uiso 1 1 calc R
H41C H 0.1572 0.1619 0.1265 0.083 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N21 Ag1 N31 174.33(10) . .
N21 Ag1 Ag2 111.93(7) . .
N31 Ag1 Ag2 73.35(7) . .
C21 N21 C23 105.7(3) . .
C21 N21 Ag1 128.9(2) . .
C23 N21 Ag1 125.4(2) . .
N21 C21 N22 111.0(3) . .
C21 N22 C22 107.9(3) . .
N22 C22 C23 105.9(3) . .
C22 C23 N21 109.7(3) . .
C31 N31 C33 105.9(2) . .
C31 N31 Ag1 127.9(2) . .
C33 N31 Ag1 126.1(2) . .
N31 C31 N32 110.3(3) . .
C31 N32 C32 108.4(3) . .
C33 C32 N32 106.2(3) . .
C32 C33 N31 109.1(3) . .
O1B Ag2 O1A 143.97(7) . .
O1B Ag2 O2A 154.09(7) . .
O1A Ag2 O2A 54.34(7) . .
O1B Ag2 Ag1 78.07(6) . .
O1A Ag2 Ag1 75.58(5) . .
O2A Ag2 Ag1 96.64(5) . .
C1A O1A Ag2 91.21(17) . .
C1A O2A Ag2 90.86(17) . .
O2A C1A O1A 123.6(3) . .
O2A C1A C2A 117.8(3) . .
O1A C1A C2A 118.5(3) . .
C15A C2A C3A 121.6(3) . .
C15A C2A C1A 120.7(2) . .
C3A C2A C1A 117.6(2) . .
C2A C3A C4A 122.9(3) . .
C2A C3A C8A 118.6(3) . .
C4A C3A C8A 118.5(3) . .
C5A C4A C3A 121.2(3) . .
C4A C5A C6A 120.6(3) . .
C7A C6A C5A 120.1(3) . .
C6A C7A C8A 121.4(3) . .
C9A C8A C7A 121.8(3) . .
C9A C8A C3A 120.0(3) . .
C7A C8A C3A 118.2(3) . .
C8A C9A C10A 121.4(3) . .
C9A C10A C11A 122.0(3) . .
C9A C10A C15A 119.3(3) . .
C11A C10A C15A 118.7(3) . .
C12A C11A C10A 121.1(3) . .
C11A C12A C13A 120.1(3) . .
C14A C13A C12A 121.0(3) . .
C13A C14A C15A 121.0(3) . .
C2A C15A C14A 123.0(3) . .
C2A C15A C10A 119.0(3) . .
C14A C15A C10A 118.0(3) . .
C1B O1B Ag2 113.00(18) . .
C1B O2B Ag3 123.03(18) . .
O2B C1B O1B 125.8(3) . .
O2B C1B C2B 118.0(2) . .
O1B C1B C2B 116.1(2) . .
C15B C2B C3B 121.8(3) . .
C15B C2B C1B 117.5(2) . .
C3B C2B C1B 120.7(2) . .
C2B C3B C4B 123.6(3) . .
C2B C3B C8B 118.4(3) . .
C4B C3B C8B 118.0(3) . .
C5B C4B C3B 121.2(3) . .
C4B C5B C6B 121.0(3) . .
C7B C6B C5B 120.1(3) . .
C6B C7B C8B 121.2(3) . .
C9B C8B C7B 122.0(3) . .
C9B C8B C3B 119.5(3) . .
C7B C8B C3B 118.6(3) . .
C10B C9B C8B 121.8(3) . .
C9B C10B C11B 122.2(3) . .
C9B C10B C15B 119.3(3) . .
C11B C10B C15B 118.6(3) . .
C12B C11B C10B 121.2(3) . .
C11B C12B C13B 120.7(3) . .
C14B C13B C12B 119.9(3) . .
C13B C14B C15B 121.6(3) . .
C2B C15B C14B 122.8(3) . .
C2B C15B C10B 119.1(3) . .
C14B C15B C10B 118.0(3) . .
O1D Ag3 O1C 162.45(8) . .
O1D Ag3 O41 102.11(7) . .
O1C Ag3 O41 92.58(8) . .
O1D Ag3 O2B 94.62(7) . .
O1C Ag3 O2B 95.22(7) . .
O41 Ag3 O2B 88.95(7) . .
O1D Ag3 Ag3 81.52(6) . 3
O1C Ag3 Ag3 81.10(6) . 3
O41 Ag3 Ag3 138.73(5) . 3
O2B Ag3 Ag3 132.10(4) . 3
C1C O1C Ag3 125.6(2) . .
O1C C1C O1C 125.7(4) 3 .
O1C C1C C2C 117.13(19) 3 .
O1C C1C C2C 117.13(19) . .
C3C C2C C3C 121.7(4) 3 .
C3C C2C C1C 119.14(19) 3 .
C3C C2C C1C 119.14(19) . .
C2C C3C C4C 123.4(3) . .
C2C C3C C8C 119.0(3) . .
C4C C3C C8C 117.6(3) . .
C5C C4C C3C 121.8(3) . .
C4C C5C C6C 120.1(4) . .
C7C C6C C5C 120.2(3) . .
C6C C7C C8C 121.8(3) . .
C9C C8C C7C 122.9(3) . .
C9C C8C C3C 118.8(3) . .
C7C C8C C3C 118.3(3) . .
C8C C9C C8C 122.7(4) . 3
C1D O1D Ag3 124.1(2) . .
O1D C1D O1D 128.7(4) . 3
O1D C1D C2D 115.66(18) . .
O1D C1D C2D 115.66(18) 3 .
C3D C2D C3D 121.9(3) . 3
C3D C2D C1D 119.06(17) . .
C3D C2D C1D 119.06(17) 3 .
C2D C3D C4D 122.2(3) . .
C2D C3D C8D 118.7(3) . .
C4D C3D C8D 119.2(2) . .
C5D C4D C3D 120.8(3) . .
C4D C5D C6D 120.0(3) . .
C7D C6D C5D 120.8(3) . .
C6D C7D C8D 121.9(3) . .
C9D C8D C7D 123.1(3) . .
C9D C8D C3D 119.5(3) . .
C7D C8D C3D 117.4(3) . .
C8D C9D C8D 121.7(4) 3 .
C41 O41 Ag3 115.5(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N21 2.088(2) .
Ag1 N31 2.089(2) .
Ag1 Ag2 3.0651(4) .
N21 C21 1.325(4) .
N21 C23 1.363(4) .
C21 N22 1.336(4) .
N22 C22 1.360(4) .
C22 C23 1.363(4) .
N31 C31 1.330(4) .
N31 C33 1.379(4) .
C31 N32 1.334(4) .
N32 C32 1.363(4) .
C32 C33 1.353(4) .
Ag2 O1B 2.218(2) .
Ag2 O1A 2.416(2) .
Ag2 O2A 2.424(2) .
O1A C1A 1.254(3) .
O2A C1A 1.254(3) .
C1A C2A 1.510(4) .
C2A C15A 1.400(4) .
C2A C3A 1.404(4) .
C3A C4A 1.427(4) .
C3A C8A 1.434(4) .
C4A C5A 1.352(4) .
C5A C6A 1.415(4) .
C6A C7A 1.360(5) .
C7A C8A 1.425(4) .
C8A C9A 1.387(4) .
C9A C10A 1.396(4) .
C10A C11A 1.422(4) .
C10A C15A 1.438(4) .
C11A C12A 1.351(4) .
C12A C13A 1.419(5) .
C13A C14A 1.349(4) .
C14A C15A 1.427(4) .
O1B C1B 1.258(3) .
O2B C1B 1.253(3) .
O2B Ag3 2.789(2) .
C1B C2B 1.520(4) .
C2B C15B 1.396(4) .
C2B C3B 1.403(4) .
C3B C4B 1.426(4) .
C3B C8B 1.442(4) .
C4B C5B 1.357(4) .
C5B C6B 1.418(4) .
C6B C7B 1.354(5) .
C7B C8B 1.432(4) .
C8B C9B 1.393(4) .
C9B C10B 1.388(4) .
C10B C11B 1.424(4) .
C10B C15B 1.437(4) .
C11B C12B 1.352(4) .
C12B C13B 1.420(4) .
C13B C14B 1.359(4) .
C14B C15B 1.427(4) .
Ag3 O1D 2.1574(19) .
Ag3 O1C 2.1681(19) .
Ag3 O41 2.467(2) .
Ag3 Ag3 2.8818(5) 3
O1C C1C 1.248(3) .
C1C O1C 1.248(3) 3
C1C C2C 1.494(5) .
C2C C3C 1.398(4) 3
C2C C3C 1.398(4) .
C3C C4C 1.432(5) .
C3C C8C 1.443(4) .
C4C C5C 1.356(5) .
C5C C6C 1.426(5) .
C6C C7C 1.349(5) .
C7C C8C 1.426(5) .
C8C C9C 1.388(4) .
C9C C8C 1.388(4) 3
O1D C1D 1.246(3) .
C1D O1D 1.246(3) 3
C1D C2D 1.512(5) .
C2D C3D 1.402(3) .
C2D C3D 1.402(3) 3
C3D C4D 1.430(4) .
C3D C8D 1.439(4) .
C4D C5D 1.351(4) .
C5D C6D 1.424(4) .
C6D C7D 1.346(4) .
C7D C8D 1.418(4) .
C8D C9D 1.393(3) .
C9D C8D 1.393(3) 3
O41 C41 1.448(4) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N22 H22N O2A 0.88 1.92 2.796(3) 176.3 8_655
N32 H32N O2B 0.88 1.94 2.815(3) 170.4 8_665
O41 H41 O1A 0.94 1.92 2.782(3) 150.9 .
