#------------------------------------------------------------------------------
#$Date: 2016-03-25 14:28:04 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179897 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/93/7019379.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7019379
loop_
_publ_author_name
'Sun, Ya-Guang'
'Xiong, Gang'
'Guo, Mei-Yan'
'Ding, Fu'
'Wang, Shu-Ju'
'Smet, Philippe F.'
'Poelman, Dirk'
'Gao, En-Jun'
'Verpoort, Francis'
_publ_section_title
;
 Hydrothermal synthesis, crystal structure and properties of Ni(ii)-4f
 complexes based on 1H-benzimidazole-5,6-dicarboxylic acid.
;
_journal_issue                   25
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7670
_journal_page_last               7680
_journal_paper_doi               10.1039/c2dt30277b
_journal_volume                  41
_journal_year                    2012
_chemical_formula_sum            'C18 H22 Eu2 N4 Ni O24 S2'
_chemical_formula_weight         1105.15
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.85(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   22.477(4)
_cell_length_b                   8.7351(17)
_cell_length_c                   15.536(3)
_cell_measurement_reflns_used    3391
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      3.53
_cell_volume                     2973.9(10)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0451
_diffrn_reflns_av_sigmaI/netI    0.0486
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            10227
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.53
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    5.046
_exptl_absorpt_correction_T_max  0.4319
_exptl_absorpt_correction_T_min  0.4319
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    2.468
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2144
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.720
_refine_diff_density_min         -0.967
_refine_diff_density_rms         0.157
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.125
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     232
_refine_ls_number_reflns         3391
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.125
_refine_ls_R_factor_all          0.0540
_refine_ls_R_factor_gt           0.0393
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0190P)²+10.5568P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0627
_refine_ls_wR_factor_ref         0.0662
_reflns_number_gt                2872
_reflns_number_total             3391
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt30277b.txt
_cod_data_source_block           3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7019379
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.247014(11) 0.85806(3) 0.383038(15) 0.01547(8) Uani 1 1 d .
Ni2 Ni 0.0000 0.79611(11) -0.2500 0.0233(2) Uani 1 2 d S
S1 S 0.35183(5) 0.95997(14) 0.58600(8) 0.0178(3) Uani 1 1 d .
O1 O 0.14536(18) 0.9354(5) 0.2799(2) 0.0345(10) Uani 1 1 d .
O2 O 0.21209(16) 0.8170(4) 0.2217(2) 0.0263(9) Uani 1 1 d .
O3 O 0.31100(16) 0.6474(4) 0.3607(2) 0.0260(8) Uani 1 1 d .
O4 O 0.29696(15) 0.6151(4) 0.4955(2) 0.0223(8) Uani 1 1 d .
O5 O 0.31893(18) 0.9702(5) 0.2999(2) 0.0377(10) Uani 1 1 d .
H5A H 0.3513 0.9223 0.2967 0.057 Uiso 1 1 d R
H5B H 0.3112 1.0566 0.2746 0.057 Uiso 1 1 d R
O6 O 0.33534(15) 0.9272(4) 0.4906(2) 0.0254(8) Uani 1 1 d .
O7 O 0.33420(19) 1.1144(4) 0.6033(3) 0.0415(11) Uani 1 1 d .
O8 O 0.41792(15) 0.9413(5) 0.6169(2) 0.0341(10) Uani 1 1 d .
O9 O -0.09334(17) 0.7845(4) -0.2727(2) 0.0330(9) Uani 1 1 d .
H9A H -0.1108 0.8686 -0.2741 0.050 Uiso 1 1 d R
H9B H -0.1062 0.7274 -0.3146 0.050 Uiso 1 1 d R
O10 O 0.0000 1.0368(7) -0.2500 0.0541(18) Uani 1 2 d S
O11 O 0.0000 0.5590(6) -0.2500 0.0461(17) Uani 1 2 d S
O12 O 0.23956(19) 1.1351(5) 0.3914(3) 0.0507(12) Uani 1 1 d .
H12A H 0.2694 1.1866 0.4206 0.076 Uiso 1 1 d R
H12B H 0.2071 1.1805 0.3653 0.076 Uiso 1 1 d R
O13 O 0.32056(18) 0.8539(5) 0.6341(2) 0.0354(10) Uani 1 1 d .
N1 N 0.0009(2) 0.7939(5) -0.1161(3) 0.0277(11) Uani 1 1 d .
N2 N -0.0214(2) 0.6832(5) 0.0009(3) 0.0266(11) Uani 1 1 d .
H2 H -0.0405 0.6280 0.0318 0.032 Uiso 1 1 d R
C1 C 0.1610(2) 0.8809(6) 0.2143(3) 0.0214(11) Uani 1 1 d .
C2 C 0.1177(2) 0.8769(6) 0.1254(3) 0.0187(11) Uani 1 1 d .
C3 C 0.3225(2) 0.5773(6) 0.4342(3) 0.0186(11) Uani 1 1 d .
C4 C 0.1298(2) 0.9567(6) 0.0520(3) 0.0171(10) Uani 1 1 d .
C5 C 0.0942(2) 0.9360(6) -0.0318(3) 0.0209(11) Uani 1 1 d .
H5 H 0.1030 0.9871 -0.0799 0.025 Uiso 1 1 calc R
C6 C 0.0442(2) 0.8355(6) -0.0423(3) 0.0205(11) Uani 1 1 d .
C7 C -0.0373(3) 0.7051(7) -0.0861(3) 0.0289(13) Uani 1 1 d .
H7 H -0.0719 0.6619 -0.1220 0.035 Uiso 1 1 calc R
C8 C 0.0310(2) 0.7651(6) 0.0319(3) 0.0226(11) Uani 1 1 d .
C9 C 0.0681(2) 0.7799(6) 0.1157(3) 0.0231(12) Uani 1 1 d .
H9 H 0.0598 0.7266 0.1636 0.028 Uiso 1 1 calc R
H11 H -0.0278 0.5275 -0.2896 0.028 Uiso 0.50 1 d PR
H10 H 0.0342 0.9317 0.2732 0.028 Uiso 0.50 1 d PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O4 Eu1 O6 80.97(12) 7_566 .
O4 Eu1 O13 78.06(13) 7_566 7_566
O6 Eu1 O13 133.85(12) . 7_566
O4 Eu1 O3 124.67(12) 7_566 .
O6 Eu1 O3 82.12(12) . .
O13 Eu1 O3 77.02(14) 7_566 .
O4 Eu1 O12 79.03(13) 7_566 .
O6 Eu1 O12 76.45(14) . .
O13 Eu1 O12 137.14(14) 7_566 .
O3 Eu1 O12 144.97(13) . .
O4 Eu1 O2 137.51(12) 7_566 .
O6 Eu1 O2 140.92(12) . .
O13 Eu1 O2 73.88(12) 7_566 .
O3 Eu1 O2 78.96(11) . .
O12 Eu1 O2 100.84(14) . .
O4 Eu1 O5 145.52(13) 7_566 .
O6 Eu1 O5 74.12(12) . .
O13 Eu1 O5 136.37(13) 7_566 .
O3 Eu1 O5 75.38(13) . .
O12 Eu1 O5 72.29(14) . .
O2 Eu1 O5 68.16(12) . .
O4 Eu1 O1 90.00(12) 7_566 .
O6 Eu1 O1 149.40(13) . .
O13 Eu1 O1 71.16(14) 7_566 .
O3 Eu1 O1 125.94(11) . .
O12 Eu1 O1 73.13(14) . .
O2 Eu1 O1 51.00(11) . .
O5 Eu1 O1 99.38(13) . .
O4 Eu1 O4 75.86(12) 7_566 .
O6 Eu1 O4 66.36(11) . .
O13 Eu1 O4 68.83(12) 7_566 .
O3 Eu1 O4 49.15(10) . .
O12 Eu1 O4 137.63(13) . .
O2 Eu1 O4 120.70(11) . .
O5 Eu1 O4 113.82(12) . .
O1 Eu1 O4 139.47(12) . .
O4 Eu1 C1 114.10(13) 7_566 .
O6 Eu1 C1 154.91(13) . .
O13 Eu1 C1 70.75(13) 7_566 .
O3 Eu1 C1 102.80(13) . .
O12 Eu1 C1 86.56(15) . .
O2 Eu1 C1 25.58(13) . .
O5 Eu1 C1 83.25(13) . .
O1 Eu1 C1 25.42(13) . .
O4 Eu1 C1 134.94(12) . .
O4 Eu1 C3 100.68(13) 7_566 .
O6 Eu1 C3 71.60(13) . .
O13 Eu1 C3 72.59(14) 7_566 .
O3 Eu1 C3 24.35(12) . .
O12 Eu1 C3 147.63(14) . .
O2 Eu1 C3 100.58(12) . .
O5 Eu1 C3 93.75(14) . .
O1 Eu1 C3 138.99(13) . .
O4 Eu1 C3 24.86(11) . .
C1 Eu1 C3 121.49(13) . .
O4 Eu1 Eu1 42.18(8) 7_566 7_566
O6 Eu1 Eu1 68.45(9) . 7_566
O13 Eu1 Eu1 68.39(9) 7_566 7_566
O3 Eu1 Eu1 82.67(8) . 7_566
O12 Eu1 Eu1 113.75(11) . 7_566
O2 Eu1 Eu1 140.82(9) . 7_566
O5 Eu1 Eu1 138.68(9) . 7_566
O1 Eu1 Eu1 121.76(9) . 7_566
O4 Eu1 Eu1 33.68(7) . 7_566
C1 Eu1 Eu1 136.27(10) . 7_566
C3 Eu1 Eu1 58.52(9) . 7_566
O9 Ni2 O9 174.3(2) . 2_554
O9 Ni2 O11 87.16(11) . .
O9 Ni2 O11 87.16(11) 2_554 .
O9 Ni2 N1 87.30(16) . .
O9 Ni2 N1 92.65(16) 2_554 .
O11 Ni2 N1 89.47(13) . .
O9 Ni2 N1 92.65(16) . 2_554
O9 Ni2 N1 87.30(16) 2_554 2_554
O11 Ni2 N1 89.47(13) . 2_554
N1 Ni2 N1 178.9(3) . 2_554
O9 Ni2 O10 92.84(11) . .
O9 Ni2 O10 92.84(11) 2_554 .
O11 Ni2 O10 180.0 . .
N1 Ni2 O10 90.53(13) . .
N1 Ni2 O10 90.53(13) 2_554 .
O7 S1 O13 108.2(3) . .
O7 S1 O8 110.0(2) . .
O13 S1 O8 109.2(2) . .
O7 S1 O6 110.5(2) . .
O13 S1 O6 110.4(2) . .
O8 S1 O6 108.5(2) . .
C1 O1 Eu1 92.0(3) . .
C1 O2 Eu1 96.1(3) . .
C3 O3 Eu1 104.3(3) . .
C3 O4 Eu1 170.2(3) . 7_566
C3 O4 Eu1 85.1(3) . .
Eu1 O4 Eu1 104.14(12) 7_566 .
Eu1 O5 H5A 120.0 . .
Eu1 O5 H5B 120.0 . .
H5A O5 H5B 120.0 . .
S1 O6 Eu1 137.9(2) . .
Ni2 O9 H9A 114.8 . .
Ni2 O9 H9B 109.5 . .
H9A O9 H9B 115.8 . .
Ni2 O11 H11 109.6 . .
Eu1 O12 H12A 120.0 . .
Eu1 O12 H12B 120.0 . .
H12A O12 H12B 120.0 . .
S1 O13 Eu1 143.5(2) . 7_566
C7 N1 C6 104.8(4) . .
C7 N1 Ni2 119.9(4) . .
C6 N1 Ni2 132.7(4) . .
C7 N2 C8 107.2(4) . .
C7 N2 H2 126.4 . .
C8 N2 H2 126.4 . .
O1 C1 O2 120.9(5) . .
O1 C1 C2 121.2(5) . .
O2 C1 C2 117.7(4) . .
O1 C1 Eu1 62.5(3) . .
O2 C1 Eu1 58.3(2) . .
C2 C1 Eu1 174.5(4) . .
C9 C2 C4 120.7(4) . .
C9 C2 C1 117.1(4) . .
C4 C2 C1 121.9(4) . .
O4 C3 O3 121.1(5) . .
O4 C3 C4 120.9(4) . 4_545
O3 C3 C4 117.9(4) . 4_545
O4 C3 Eu1 70.0(3) . .
O3 C3 Eu1 51.3(2) . .
C4 C3 Eu1 166.0(3) 4_545 .
C5 C4 C2 121.4(4) . .
C5 C4 C3 118.6(4) . 4
C2 C4 C3 119.7(4) . 4
C4 C5 C6 118.2(4) . .
C4 C5 H5 120.9 . .
C6 C5 H5 120.9 . .
N1 C6 C8 109.3(4) . .
N1 C6 C5 131.3(5) . .
C8 C6 C5 119.3(4) . .
N1 C7 N2 113.3(5) . .
N1 C7 H7 123.4 . .
N2 C7 H7 123.4 . .
N2 C8 C9 131.9(5) . .
N2 C8 C6 105.3(4) . .
C9 C8 C6 122.8(5) . .
C2 C9 C8 117.4(5) . .
C2 C9 H9 121.3 . .
C8 C9 H9 121.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O4 2.328(3) 7_566
Eu1 O6 2.371(3) .
Eu1 O13 2.372(4) 7_566
Eu1 O3 2.408(4) .
Eu1 O12 2.432(4) .
Eu1 O2 2.480(3) .
Eu1 O5 2.484(4) .
Eu1 O1 2.572(4) .
Eu1 O4 2.819(3) .
Eu1 C1 2.897(5) .
Eu1 C3 2.988(5) .
Eu1 Eu1 4.0709(8) 7_566
Ni2 O9 2.051(4) .
Ni2 O9 2.051(4) 2_554
Ni2 O11 2.072(6) .
Ni2 N1 2.075(4) .
Ni2 N1 2.075(4) 2_554
Ni2 O10 2.102(6) .
S1 O7 1.448(4) .
S1 O13 1.465(4) .
S1 O8 1.465(4) .
S1 O6 1.474(3) .
O1 C1 1.245(6) .
O2 C1 1.258(6) .
O3 C3 1.271(6) .
O4 C3 1.261(6) .
O4 Eu1 2.328(3) 7_566
O5 H5A 0.8499 .
O5 H5B 0.8500 .
O9 H9A 0.8306 .
O9 H9B 0.8199 .
O11 H11 0.8205 .
O12 H12A 0.8497 .
O12 H12B 0.8502 .
O13 Eu1 2.372(4) 7_566
N1 C7 1.316(7) .
N1 C6 1.378(6) .
N2 C7 1.333(6) .
N2 C8 1.372(6) .
N2 H2 0.8602 .
C1 C2 1.503(6) .
C2 C9 1.383(7) .
C2 C4 1.413(6) .
C3 C4 1.484(7) 4_545
C4 C5 1.380(6) .
C4 C3 1.484(7) 4
C5 C6 1.406(7) .
C5 H5 0.9300 .
C6 C8 1.395(7) .
C7 H7 0.9300 .
C8 C9 1.387(7) .
C9 H9 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O4 Eu1 O1 C1 -162.0(3) 7_566 .
O6 Eu1 O1 C1 125.9(3) . .
O13 Eu1 O1 C1 -84.6(3) 7_566 .
O3 Eu1 O1 C1 -27.4(4) . .
O12 Eu1 O1 C1 119.5(3) . .
O2 Eu1 O1 C1 -0.4(3) . .
O5 Eu1 O1 C1 51.3(3) . .
O4 Eu1 O1 C1 -94.1(3) . .
C3 Eu1 O1 C1 -55.6(4) . .
Eu1 Eu1 O1 C1 -132.6(3) 7_566 .
O4 Eu1 O2 C1 28.3(4) 7_566 .
O6 Eu1 O2 C1 -139.0(3) . .
O13 Eu1 O2 C1 79.0(3) 7_566 .
O3 Eu1 O2 C1 158.5(3) . .
O12 Eu1 O2 C1 -57.2(3) . .
O5 Eu1 O2 C1 -123.0(3) . .
O1 Eu1 O2 C1 0.4(3) . .
O4 Eu1 O2 C1 131.5(3) . .
C3 Eu1 O2 C1 147.2(3) . .
Eu1 Eu1 O2 C1 94.9(3) 7_566 .
O4 Eu1 O3 C3 -11.1(4) 7_566 .
O6 Eu1 O3 C3 62.2(3) . .
O13 Eu1 O3 C3 -76.4(3) 7_566 .
O12 Eu1 O3 C3 114.6(3) . .
O2 Eu1 O3 C3 -152.2(3) . .
O5 Eu1 O3 C3 137.7(3) . .
O1 Eu1 O3 C3 -131.2(3) . .
O4 Eu1 O3 C3 -3.3(3) . .
C1 Eu1 O3 C3 -142.9(3) . .
Eu1 Eu1 O3 C3 -7.0(3) 7_566 .
O4 Eu1 O4 C3 176.6(3) 7_566 .
O6 Eu1 O4 C3 -97.2(3) . .
O13 Eu1 O4 C3 94.2(3) 7_566 .
O3 Eu1 O4 C3 3.2(3) . .
O12 Eu1 O4 C3 -127.9(3) . .
O2 Eu1 O4 C3 39.3(3) . .
O5 Eu1 O4 C3 -38.5(3) . .
O1 Eu1 O4 C3 103.8(3) . .
C1 Eu1 O4 C3 66.5(3) . .
Eu1 Eu1 O4 C3 176.6(3) 7_566 .
O4 Eu1 O4 Eu1 0.0 7_566 7_566
O6 Eu1 O4 Eu1 86.19(14) . 7_566
O13 Eu1 O4 Eu1 -82.46(15) 7_566 7_566
O3 Eu1 O4 Eu1 -173.4(2) . 7_566
O12 Eu1 O4 Eu1 55.4(2) . 7_566
O2 Eu1 O4 Eu1 -137.28(12) . 7_566
O5 Eu1 O4 Eu1 144.89(13) . 7_566
O1 Eu1 O4 Eu1 -72.87(19) . 7_566
C1 Eu1 O4 Eu1 -110.09(18) . 7_566
C3 Eu1 O4 Eu1 -176.6(3) . 7_566
O7 S1 O6 Eu1 -79.7(4) . .
O13 S1 O6 Eu1 40.0(4) . .
O8 S1 O6 Eu1 159.6(3) . .
O4 Eu1 O6 S1 3.1(3) 7_566 .
O13 Eu1 O6 S1 -60.5(4) 7_566 .
O3 Eu1 O6 S1 -124.0(3) . .
O12 Eu1 O6 S1 83.9(3) . .
O2 Eu1 O6 S1 174.5(3) . .
O5 Eu1 O6 S1 159.1(4) . .
O1 Eu1 O6 S1 77.6(4) . .
O4 Eu1 O6 S1 -75.3(3) . .
C1 Eu1 O6 S1 132.6(3) . .
C3 Eu1 O6 S1 -101.4(3) . .
Eu1 Eu1 O6 S1 -38.8(3) 7_566 .
O7 S1 O13 Eu1 122.4(4) . 7_566
O8 S1 O13 Eu1 -117.9(4) . 7_566
O6 S1 O13 Eu1 1.4(5) . 7_566
O9 Ni2 N1 C7 39.6(4) . .
O9 Ni2 N1 C7 -134.7(4) 2_554 .
O11 Ni2 N1 C7 -47.6(4) . .
N1 Ni2 N1 C7 -47.6(4) 2_554 .
O10 Ni2 N1 C7 132.4(4) . .
O9 Ni2 N1 C6 -161.3(5) . .
O9 Ni2 N1 C6 24.4(5) 2_554 .
O11 Ni2 N1 C6 111.5(5) . .
N1 Ni2 N1 C6 111.5(5) 2_554 .
O10 Ni2 N1 C6 -68.5(5) . .
Eu1 O1 C1 O2 0.8(5) . .
Eu1 O1 C1 C2 175.4(4) . .
Eu1 O2 C1 O1 -0.8(5) . .
Eu1 O2 C1 C2 -175.6(4) . .
O4 Eu1 C1 O1 19.8(3) 7_566 .
O6 Eu1 C1 O1 -103.6(4) . .
O13 Eu1 C1 O1 86.4(3) 7_566 .
O3 Eu1 C1 O1 157.6(3) . .
O12 Eu1 C1 O1 -56.6(3) . .
O2 Eu1 C1 O1 179.2(5) . .
O5 Eu1 C1 O1 -129.1(3) . .
O4 Eu1 C1 O1 113.7(3) . .
C3 Eu1 C1 O1 140.6(3) . .
Eu1 Eu1 C1 O1 64.8(4) 7_566 .
O4 Eu1 C1 O2 -159.4(3) 7_566 .
O6 Eu1 C1 O2 77.2(4) . .
O13 Eu1 C1 O2 -92.8(3) 7_566 .
O3 Eu1 C1 O2 -21.7(3) . .
O12 Eu1 C1 O2 124.2(3) . .
O5 Eu1 C1 O2 51.6(3) . .
O1 Eu1 C1 O2 -179.2(5) . .
O4 Eu1 C1 O2 -65.5(4) . .
C3 Eu1 C1 O2 -38.6(3) . .
Eu1 Eu1 C1 O2 -114.4(3) 7_566 .
O4 Eu1 C1 C2 -114(4) 7_566 .
O6 Eu1 C1 C2 122(4) . .
O13 Eu1 C1 C2 -48(4) 7_566 .
O3 Eu1 C1 C2 24(4) . .
O12 Eu1 C1 C2 169(4) . .
O2 Eu1 C1 C2 45(4) . .
O5 Eu1 C1 C2 97(4) . .
O1 Eu1 C1 C2 -134(4) . .
O4 Eu1 C1 C2 -20(4) . .
C3 Eu1 C1 C2 7(4) . .
Eu1 Eu1 C1 C2 -69(4) 7_566 .
O1 C1 C2 C9 -68.3(7) . .
O2 C1 C2 C9 106.5(6) . .
Eu1 C1 C2 C9 63(4) . .
O1 C1 C2 C4 117.7(6) . .
O2 C1 C2 C4 -67.5(7) . .
Eu1 C1 C2 C4 -110(4) . .
Eu1 O4 C3 O3 155.0(15) 7_566 .
Eu1 O4 C3 O3 -5.4(4) . .
Eu1 O4 C3 C4 -29(2) 7_566 4_545
Eu1 O4 C3 C4 170.3(4) . 4_545
Eu1 O4 C3 Eu1 160.4(18) 7_566 .
Eu1 O3 C3 O4 6.5(5) . .
Eu1 O3 C3 C4 -169.3(3) . 4_545
O4 Eu1 C3 O4 -3.3(3) 7_566 .
O6 Eu1 C3 O4 73.3(3) . .
O13 Eu1 C3 O4 -77.1(3) 7_566 .
O3 Eu1 C3 O4 -174.1(5) . .
O12 Eu1 C3 O4 83.0(4) . .
O2 Eu1 C3 O4 -146.3(2) . .
O5 Eu1 C3 O4 145.2(3) . .
O1 Eu1 C3 O4 -105.9(3) . .
C1 Eu1 C3 O4 -130.4(3) . .
Eu1 Eu1 C3 O4 -2.2(2) 7_566 .
O4 Eu1 C3 O3 170.7(3) 7_566 .
O6 Eu1 C3 O3 -112.6(3) . .
O13 Eu1 C3 O3 97.0(3) 7_566 .
O12 Eu1 C3 O3 -102.9(4) . .
O2 Eu1 C3 O3 27.7(3) . .
O5 Eu1 C3 O3 -40.7(3) . .
O1 Eu1 C3 O3 68.2(4) . .
O4 Eu1 C3 O3 174.1(5) . .
C1 Eu1 C3 O3 43.7(3) . .
Eu1 Eu1 C3 O3 171.9(3) 7_566 .
O4 Eu1 C3 C4 -146.4(13) 7_566 4_545
O6 Eu1 C3 C4 -69.8(13) . 4_545
O13 Eu1 C3 C4 139.8(13) 7_566 4_545
O3 Eu1 C3 C4 42.8(12) . 4_545
O12 Eu1 C3 C4 -60.1(14) . 4_545
O2 Eu1 C3 C4 70.6(13) . 4_545
O5 Eu1 C3 C4 2.1(13) . 4_545
O1 Eu1 C3 C4 111.0(13) . 4_545
O4 Eu1 C3 C4 -143.1(15) . 4_545
C1 Eu1 C3 C4 86.5(13) . 4_545
Eu1 Eu1 C3 C4 -145.3(14) 7_566 4_545
C9 C2 C4 C5 -2.7(8) . .
C1 C2 C4 C5 171.1(5) . .
C9 C2 C4 C3 170.9(5) . 4
C1 C2 C4 C3 -15.4(7) . 4
C2 C4 C5 C6 1.5(8) . .
C3 C4 C5 C6 -172.1(5) 4 .
C7 N1 C6 C8 1.3(6) . .
Ni2 N1 C6 C8 -160.0(4) . .
C7 N1 C6 C5 -175.6(6) . .
Ni2 N1 C6 C5 23.1(9) . .
C4 C5 C6 N1 179.0(5) . .
C4 C5 C6 C8 2.4(8) . .
C6 N1 C7 N2 -1.3(7) . .
Ni2 N1 C7 N2 162.9(4) . .
C8 N2 C7 N1 0.8(7) . .
C7 N2 C8 C9 -177.7(6) . .
C7 N2 C8 C6 0.1(6) . .
N1 C6 C8 N2 -0.9(6) . .
C5 C6 C8 N2 176.4(5) . .
N1 C6 C8 C9 177.2(5) . .
C5 C6 C8 C9 -5.5(8) . .
C4 C2 C9 C8 -0.2(8) . .
C1 C2 C9 C8 -174.3(5) . .
N2 C8 C9 C2 -178.2(5) . .
C6 C8 C9 C2 4.3(8) . .
