#------------------------------------------------------------------------------
#$Date: 2016-03-25 14:30:52 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179899 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/95/7019536.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7019536
loop_
_publ_author_name
'Béziau, Antoine'
'Baudron, Stéphane A'
'Hosseini, Mir Wais'
_publ_section_title
;
 Heterometallic coordination polymers incorporating dipyrrin based
 heteroleptic copper and cobalt complexes: to Ag-π or not?
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7227
_journal_page_last               7234
_journal_paper_doi               10.1039/c2dt30549f
_journal_volume                  41
_journal_year                    2012
_chemical_formula_moiety
'C86 H64 Ag2 Co2 N18 O4, C6 H6, 2(C F3 O3 S), 4(C2 H3 N)'
_chemical_formula_sum            'C102 H82 Ag2 Co2 F6 N22 O10 S2'
_chemical_formula_weight         2287.62
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                92.645(2)
_cell_angle_beta                 101.045(2)
_cell_angle_gamma                103.095(3)
_cell_formula_units_Z            1
_cell_length_a                   12.4775(9)
_cell_length_b                   14.1836(10)
_cell_length_c                   14.2334(11)
_cell_measurement_reflns_used    8163
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.10
_cell_measurement_theta_min      2.52
_cell_volume                     2397.4(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.975
_diffrn_measured_fraction_theta_max 0.975
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0368
_diffrn_reflns_av_sigmaI/netI    0.0519
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            27655
_diffrn_reflns_theta_full        27.69
_diffrn_reflns_theta_max         27.69
_diffrn_reflns_theta_min         1.98
_exptl_absorpt_coefficient_mu    0.871
_exptl_absorpt_correction_T_max  0.9660
_exptl_absorpt_correction_T_min  0.8450
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.584
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1162
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.04
_refine_diff_density_max         3.362
_refine_diff_density_min         -1.338
_refine_diff_density_rms         0.163
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.117
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     661
_refine_ls_number_reflns         10945
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.117
_refine_ls_R_factor_all          0.1116
_refine_ls_R_factor_gt           0.0885
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1056P)²+18.9687P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2398
_refine_ls_wR_factor_ref         0.2539
_reflns_number_gt                8311
_reflns_number_total             10945
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt30549f.txt
_cod_data_source_block           compound8
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      'P-1 '
_cod_database_code               7019536
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.1135(6) 0.2033(5) 1.1083(5) 0.0249(13) Uani 1 1 d .
H1 H 0.0554 0.2306 1.0803 0.030 Uiso 1 1 calc R
C2 C 0.1223(6) 0.1661(5) 1.1992(5) 0.0288(14) Uani 1 1 d .
H2 H 0.0729 0.1650 1.2407 0.035 Uiso 1 1 calc R
C3 C 0.2179(6) 0.1321(5) 1.2140(5) 0.0268(14) Uani 1 1 d .
H3 H 0.2449 0.1018 1.2670 0.032 Uiso 1 1 calc R
C4 C 0.2683(5) 0.1519(5) 1.1330(4) 0.0221(12) Uani 1 1 d .
C5 C 0.3731(6) 0.1405(5) 1.1195(5) 0.0246(13) Uani 1 1 d .
C6 C 0.4212(6) 0.1725(5) 1.0432(5) 0.0255(13) Uani 1 1 d .
C7 C 0.5346(6) 0.1802(5) 1.0336(5) 0.0301(15) Uani 1 1 d .
H7 H 0.5889 0.1568 1.0737 0.036 Uiso 1 1 calc R
C8 C 0.5479(6) 0.2286(5) 0.9537(5) 0.0309(15) Uani 1 1 d .
H8 H 0.6129 0.2444 0.9292 0.037 Uiso 1 1 calc R
C9 C 0.4443(6) 0.2499(5) 0.9162(5) 0.0279(14) Uani 1 1 d .
H9 H 0.4304 0.2826 0.8617 0.034 Uiso 1 1 calc R
C10 C 0.4412(6) 0.0939(5) 1.1924(5) 0.0287(14) Uani 1 1 d .
C11 C 0.5001(7) 0.1442(6) 1.2799(5) 0.0396(19) Uani 1 1 d .
H11 H 0.4932 0.2062 1.2974 0.048 Uiso 1 1 calc R
C12 C 0.5685(9) 0.0994(7) 1.3395(7) 0.053(3) Uani 1 1 d .
H12 H 0.6094 0.1343 1.3970 0.064 Uiso 1 1 calc R
C13 C 0.5223(8) -0.0373(7) 1.2379(6) 0.046(2) Uani 1 1 d .
H13 H 0.5279 -0.1003 1.2232 0.055 Uiso 1 1 calc R
C14 C 0.4540(7) 0.0015(6) 1.1722(6) 0.0363(17) Uani 1 1 d .
H14 H 0.4163 -0.0341 1.1142 0.044 Uiso 1 1 calc R
C15 C -0.0277(6) 0.1191(5) 0.8710(5) 0.0272(14) Uani 1 1 d .
H15 H -0.0182 0.0585 0.8879 0.033 Uiso 1 1 calc R
C16 C -0.1283(6) 0.1364(6) 0.8167(5) 0.0340(16) Uani 1 1 d .
H16 H -0.1947 0.0900 0.7915 0.041 Uiso 1 1 calc R
C17 C -0.1094(6) 0.2324(6) 0.8088(5) 0.0316(15) Uani 1 1 d .
H17 H -0.1605 0.2650 0.7774 0.038 Uiso 1 1 calc R
C18 C 0.0034(5) 0.2752(5) 0.8573(4) 0.0217(12) Uani 1 1 d .
C19 C -0.0617(5) 0.6263(5) 0.1308(4) 0.0210(12) Uani 1 1 d .
C20 C 0.1714(5) 0.4099(5) 0.9199(4) 0.0212(12) Uani 1 1 d .
C21 C 0.2301(6) 0.5086(5) 0.9461(4) 0.0244(13) Uani 1 1 d .
H21 H 0.2048 0.5632 0.9277 0.029 Uiso 1 1 calc R
C22 C 0.3330(6) 0.5077(5) 1.0047(5) 0.0245(13) Uani 1 1 d .
H22 H 0.3900 0.5615 1.0329 0.029 Uiso 1 1 calc R
C23 C 0.3333(5) 0.4098(5) 1.0126(4) 0.0231(13) Uani 1 1 d .
H23 H 0.3921 0.3887 1.0491 0.028 Uiso 1 1 calc R
C24 C 0.0011(5) 0.5543(5) 0.1717(4) 0.0219(12) Uani 1 1 d .
C25 C 0.0898(7) 0.5348(6) 0.1340(5) 0.0321(16) Uani 1 1 d .
H25 H 0.1110 0.5660 0.0821 0.039 Uiso 1 1 calc R
C26 C 0.1454(7) 0.4688(6) 0.1748(5) 0.0370(17) Uani 1 1 d .
H26 H 0.2042 0.4559 0.1489 0.044 Uiso 1 1 calc R
C27 C 0.0343(6) 0.4400(5) 0.2854(5) 0.0268(14) Uani 1 1 d .
H27 H 0.0153 0.4078 0.3375 0.032 Uiso 1 1 calc R
C28 C -0.0276(6) 0.5047(5) 0.2484(5) 0.0270(14) Uani 1 1 d .
H28 H -0.0874 0.5146 0.2746 0.032 Uiso 1 1 calc R
C29 C 0.1764(6) -0.2097(5) 0.9497(6) 0.0332(16) Uani 1 1 d .
H29 H 0.1698 -0.2323 1.0091 0.040 Uiso 1 1 calc R
C30 C 0.1838(6) -0.1126(5) 0.9403(5) 0.0293(14) Uani 1 1 d .
H30 H 0.1820 -0.0713 0.9923 0.035 Uiso 1 1 calc R
C31 C 0.1940(5) -0.0766(5) 0.8527(5) 0.0235(13) Uani 1 1 d .
C32 C 0.1987(6) -0.1414(5) 0.7785(5) 0.0318(15) Uani 1 1 d .
H32 H 0.2071 -0.1200 0.7190 0.038 Uiso 1 1 calc R
C33 C 0.1910(7) -0.2373(5) 0.7938(6) 0.0366(17) Uani 1 1 d .
H33 H 0.1947 -0.2796 0.7432 0.044 Uiso 1 1 calc R
C34 C 0.1998(5) 0.0297(4) 0.8434(4) 0.0210(12) Uani 1 1 d .
C35 C 0.2143(6) 0.0700(5) 0.7588(5) 0.0268(14) Uani 1 1 d .
H35 H 0.2208 0.0294 0.7081 0.032 Uiso 1 1 calc R
C36 C 0.2196(5) 0.1667(5) 0.7445(4) 0.0227(13) Uani 1 1 d .
C37 C 0.2270(6) 0.2021(5) 0.6483(4) 0.0256(14) Uani 1 1 d .
C38 C 0.2690(6) 0.1558(5) 0.5816(5) 0.0290(15) Uani 1 1 d .
H38 H 0.2961 0.1010 0.5955 0.035 Uiso 1 1 calc R
C39 C 0.2697(7) 0.1932(5) 0.4931(5) 0.0319(16) Uani 1 1 d .
H39 H 0.2987 0.1619 0.4485 0.038 Uiso 1 1 calc R
C40 C 0.1908(7) 0.3148(5) 0.5336(5) 0.0318(15) Uani 1 1 d .
H40 H 0.1638 0.3692 0.5177 0.038 Uiso 1 1 calc R
C41 C 0.1865(6) 0.2839(5) 0.6237(5) 0.0303(15) Uani 1 1 d .
H41 H 0.1574 0.3167 0.6671 0.036 Uiso 1 1 calc R
C42 C 0.4761(7) 0.3950(7) 0.2458(6) 0.0397(18) Uani 1 1 d .
C43 C 0.5801(9) 0.4252(12) 0.2103(8) 0.081(4) Uani 1 1 d .
H43A H 0.5778 0.3819 0.1557 0.121 Uiso 1 1 calc R
H43B H 0.6432 0.4232 0.2601 0.121 Uiso 1 1 calc R
H43C H 0.5875 0.4902 0.1918 0.121 Uiso 1 1 calc R
N1 N 0.1980(4) 0.1945(4) 1.0680(3) 0.0195(10) Uani 1 1 d .
N2 N 0.3684(5) 0.2171(4) 0.9691(4) 0.0225(11) Uani 1 1 d .
N3 N 0.5816(8) 0.0091(6) 1.3219(6) 0.055(2) Uani 1 1 d .
N4 N 0.0509(4) 0.2016(4) 0.8943(4) 0.0220(11) Uani 1 1 d .
N5 N 0.2394(4) 0.3504(4) 0.9618(4) 0.0197(10) Uani 1 1 d .
N6 N 0.1192(5) 0.4219(4) 0.2502(4) 0.0285(12) Uani 1 1 d .
N7 N 0.1783(6) -0.2738(4) 0.8782(5) 0.0359(14) Uani 1 1 d .
N8 N 0.2316(5) 0.2713(4) 0.4678(4) 0.0280(12) Uani 1 1 d .
N9 N 0.3976(6) 0.3728(5) 0.2712(5) 0.0441(17) Uani 1 1 d .
O1 O 0.1876(4) 0.0758(3) 0.9194(3) 0.0252(10) Uani 1 1 d .
O2 O 0.2211(4) 0.2342(3) 0.8086(3) 0.0242(9) Uani 1 1 d .
Co1 Co 0.21074(7) 0.21309(6) 0.93794(6) 0.0185(2) Uani 1 1 d .
Ag1 Ag 0.23108(5) 0.32974(5) 0.32404(4) 0.03688(19) Uani 1 1 d .
C44 C 0.8548(10) 0.3383(8) 0.5084(7) 0.060(3) Uani 1 1 d .
O3 O 0.7933(6) 0.4438(6) 0.3826(5) 0.063(2) Uani 1 1 d .
O4 O 0.7537(6) 0.4708(5) 0.5403(5) 0.0558(17) Uani 1 1 d .
O5 O 0.6487(6) 0.3281(5) 0.4343(5) 0.0603(19) Uani 1 1 d .
F1 F 0.9575(6) 0.3968(7) 0.5333(6) 0.091(2) Uani 1 1 d .
F2 F 0.8572(9) 0.2663(7) 0.4446(6) 0.109(3) Uani 1 1 d .
F3 F 0.8350(10) 0.2955(7) 0.5859(6) 0.117(3) Uani 1 1 d .
S1 S 0.75048(18) 0.40192(15) 0.46166(14) 0.0389(5) Uani 1 1 d .
C45 C 0.6298(11) 0.0786(10) 0.5939(10) 0.073(3) Uani 1 1 d .
C46 C 0.5804(15) 0.1610(10) 0.5912(12) 0.098(5) Uani 1 1 d .
H46A H 0.6072 0.2024 0.5449 0.147 Uiso 1 1 calc R
H46B H 0.6011 0.1967 0.6536 0.147 Uiso 1 1 calc R
H46C H 0.5000 0.1390 0.5734 0.147 Uiso 1 1 calc R
N10 N 0.6680(12) 0.0111(11) 0.5898(10) 0.101(4) Uani 1 1 d .
C47 C 0.4671(19) 0.6248(11) 0.3248(15) 0.111(7) Uani 1 1 d .
C48 C 0.4994(11) 0.5902(12) 0.4180(15) 0.115(7) Uani 1 1 d .
H48A H 0.5246 0.6443 0.4664 0.172 Uiso 1 1 calc R
H48B H 0.5591 0.5581 0.4167 0.172 Uiso 1 1 calc R
H48C H 0.4358 0.5454 0.4324 0.172 Uiso 1 1 calc R
N11 N 0.439(3) 0.6547(14) 0.2557(17) 0.216(14) Uani 1 1 d .
C50 C 1.0356(10) 0.0081(10) 0.4136(9) 0.073(3) Uani 1 1 d .
H50 H 1.0602 0.0141 0.3559 0.087 Uiso 1 1 calc R
C51 C 0.9847(10) 0.0796(9) 0.4469(10) 0.070(3) Uani 1 1 d .
H51 H 0.9746 0.1310 0.4107 0.084 Uiso 1 1 calc R
C52 C 0.9502(10) 0.0718(9) 0.5342(11) 0.076(4) Uani 1 1 d .
H52 H 0.9182 0.1187 0.5577 0.091 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C1 C2 111.6(6) . .
N1 C1 H1 124.2 . .
C2 C1 H1 124.2 . .
C3 C2 C1 106.4(6) . .
C3 C2 H2 126.8 . .
C1 C2 H2 126.8 . .
C2 C3 C4 107.1(6) . .
C2 C3 H3 126.4 . .
C4 C3 H3 126.4 . .
C5 C4 N1 123.3(6) . .
C5 C4 C3 128.6(6) . .
N1 C4 C3 107.9(6) . .
C6 C5 C4 124.5(6) . .
C6 C5 C10 116.2(6) . .
C4 C5 C10 119.3(6) . .
C5 C6 N2 123.3(6) . .
C5 C6 C7 127.6(6) . .
N2 C6 C7 108.4(6) . .
C8 C7 C6 106.7(6) . .
C8 C7 H7 126.7 . .
C6 C7 H7 126.7 . .
C7 C8 C9 106.8(6) . .
C7 C8 H8 126.6 . .
C9 C8 H8 126.6 . .
N2 C9 C8 111.2(6) . .
N2 C9 H9 124.4 . .
C8 C9 H9 124.4 . .
C14 C10 C11 117.9(7) . .
C14 C10 C5 120.7(6) . .
C11 C10 C5 121.3(6) . .
C12 C11 C10 117.7(7) . .
C12 C11 H11 121.2 . .
C10 C11 H11 121.2 . .
N3 C12 C11 125.6(8) . .
N3 C12 H12 117.2 . .
C11 C12 H12 117.2 . .
N3 C13 C14 124.4(8) . .
N3 C13 H13 117.8 . .
C14 C13 H13 117.8 . .
C13 C14 C10 119.6(7) . .
C13 C14 H14 120.2 . .
C10 C14 H14 120.2 . .
N4 C15 C16 110.5(6) . .
N4 C15 H15 124.7 . .
C16 C15 H15 124.7 . .
C17 C16 C15 106.9(6) . .
C17 C16 H16 126.5 . .
C15 C16 H16 126.5 . .
C16 C17 C18 107.5(6) . .
C16 C17 H17 126.2 . .
C18 C17 H17 126.2 . .
N4 C18 C19 123.2(6) . 2_566
N4 C18 C17 108.1(6) . .
C19 C18 C17 128.7(6) 2_566 .
C20 C19 C18 125.1(6) 2_566 2_566
C20 C19 C24 117.4(6) 2_566 .
C18 C19 C24 117.5(6) 2_566 .
C19 C20 N5 123.1(6) 2_566 .
C19 C20 C21 128.1(6) 2_566 .
N5 C20 C21 108.6(5) . .
C22 C21 C20 106.6(6) . .
C22 C21 H21 126.7 . .
C20 C21 H21 126.7 . .
C21 C22 C23 106.2(6) . .
C21 C22 H22 126.9 . .
C23 C22 H22 126.9 . .
N5 C23 C22 112.0(6) . .
N5 C23 H23 124.0 . .
C22 C23 H23 124.0 . .
C28 C24 C25 117.9(6) . .
C28 C24 C19 120.8(6) . .
C25 C24 C19 121.3(6) . .
C26 C25 C24 119.0(6) . .
C26 C25 H25 120.5 . .
C24 C25 H25 120.5 . .
N6 C26 C25 123.3(7) . .
N6 C26 H26 118.4 . .
C25 C26 H26 118.4 . .
N6 C27 C28 123.2(6) . .
N6 C27 H27 118.4 . .
C28 C27 H27 118.4 . .
C24 C28 C27 118.9(6) . .
C24 C28 H28 120.5 . .
C27 C28 H28 120.5 . .
N7 C29 C30 123.8(7) . .
N7 C29 H29 118.1 . .
C30 C29 H29 118.1 . .
C29 C30 C31 119.6(7) . .
C29 C30 H30 120.2 . .
C31 C30 H30 120.2 . .
C32 C31 C30 117.4(6) . .
C32 C31 C34 123.9(6) . .
C30 C31 C34 118.7(6) . .
C33 C32 C31 119.5(7) . .
C33 C32 H32 120.3 . .
C31 C32 H32 120.3 . .
N7 C33 C32 123.6(7) . .
N7 C33 H33 118.2 . .
C32 C33 H33 118.2 . .
O1 C34 C35 125.2(6) . .
O1 C34 C31 113.8(5) . .
C35 C34 C31 121.0(6) . .
C34 C35 C36 124.4(6) . .
C34 C35 H35 117.8 . .
C36 C35 H35 117.8 . .
O2 C36 C35 126.1(6) . .
O2 C36 C37 113.4(6) . .
C35 C36 C37 120.6(6) . .
C38 C37 C41 118.7(6) . .
C38 C37 C36 122.6(6) . .
C41 C37 C36 118.7(6) . .
C37 C38 C39 118.2(7) . .
C37 C38 H38 120.9 . .
C39 C38 H38 120.9 . .
N8 C39 C38 124.4(7) . .
N8 C39 H39 117.8 . .
C38 C39 H39 117.8 . .
N8 C40 C41 124.0(7) . .
N8 C40 H40 118.0 . .
C41 C40 H40 118.0 . .
C40 C41 C37 118.5(7) . .
C40 C41 H41 120.8 . .
C37 C41 H41 120.8 . .
N9 C42 C43 179.0(10) . .
C42 C43 H43A 109.5 . .
C42 C43 H43B 109.5 . .
H43A C43 H43B 109.5 . .
C42 C43 H43C 109.5 . .
H43A C43 H43C 109.5 . .
H43B C43 H43C 109.5 . .
C1 N1 C4 106.9(5) . .
C1 N1 Co1 127.2(4) . .
C4 N1 Co1 125.1(4) . .
C9 N2 C6 106.9(6) . .
C9 N2 Co1 126.7(5) . .
C6 N2 Co1 125.7(5) . .
C13 N3 C12 114.8(7) . .
C15 N4 C18 107.0(5) . .
C15 N4 Co1 125.9(5) . .
C18 N4 Co1 125.0(4) . .
C23 N5 C20 106.5(5) . .
C23 N5 Co1 126.8(4) . .
C20 N5 Co1 126.4(4) . .
C27 N6 C26 117.6(6) . .
C27 N6 Ag1 121.8(4) . .
C26 N6 Ag1 120.2(5) . .
C29 N7 C33 116.1(6) . .
C40 N8 C39 116.4(6) . .
C40 N8 Ag1 119.6(5) . .
C39 N8 Ag1 124.1(5) . .
C42 N9 Ag1 178.6(8) . .
C34 O1 Co1 124.3(4) . .
C36 O2 Co1 124.0(4) . .
N5 Co1 O1 177.2(2) . .
N5 Co1 O2 86.8(2) . .
O1 Co1 O2 95.00(19) . .
N5 Co1 N1 92.1(2) . .
O1 Co1 N1 86.2(2) . .
O2 Co1 N1 178.4(2) . .
N5 Co1 N2 91.7(2) . .
O1 Co1 N2 86.2(2) . .
O2 Co1 N2 90.0(2) . .
N1 Co1 N2 91.1(2) . .
N5 Co1 N4 91.9(2) . .
O1 Co1 N4 90.4(2) . .
O2 Co1 N4 85.6(2) . .
N1 Co1 N4 93.4(2) . .
N2 Co1 N4 174.2(2) . .
N8 Ag1 N6 127.9(2) . .
N8 Ag1 N9 119.4(2) . .
N6 Ag1 N9 106.0(2) . .
F3 C44 F1 106.3(9) . .
F3 C44 F2 105.2(10) . .
F1 C44 F2 108.5(10) . .
F3 C44 S1 112.6(9) . .
F1 C44 S1 112.4(8) . .
F2 C44 S1 111.4(7) . .
O5 S1 O3 114.4(4) . .
O5 S1 O4 115.1(4) . .
O3 S1 O4 114.9(4) . .
O5 S1 C44 104.6(5) . .
O3 S1 C44 101.4(5) . .
O4 S1 C44 104.2(5) . .
N10 C45 C46 175.7(16) . .
C45 C46 H46A 109.5 . .
C45 C46 H46B 109.5 . .
H46A C46 H46B 109.5 . .
C45 C46 H46C 109.5 . .
H46A C46 H46C 109.5 . .
H46B C46 H46C 109.5 . .
N11 C47 C48 176(2) . .
C47 C48 H48A 109.5 . .
C47 C48 H48B 109.5 . .
H48A C48 H48B 109.5 . .
C47 C48 H48C 109.5 . .
H48A C48 H48C 109.5 . .
H48B C48 H48C 109.5 . .
C52 C50 C51 121.6(12) 2_756 .
C52 C50 H50 119.2 2_756 .
C51 C50 H50 119.2 . .
C52 C51 C50 119.3(12) . .
C52 C51 H51 120.3 . .
C50 C51 H51 120.3 . .
C51 C52 C50 119.1(13) . 2_756
C51 C52 H52 120.5 . .
C50 C52 H52 120.5 2_756 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.319(8) .
C1 C2 1.414(9) .
C1 H1 0.9300 .
C2 C3 1.369(10) .
C2 H2 0.9300 .
C3 C4 1.425(9) .
C3 H3 0.9300 .
C4 C5 1.400(9) .
C4 N1 1.404(8) .
C5 C6 1.385(10) .
C5 C10 1.489(9) .
C6 N2 1.390(8) .
C6 C7 1.428(9) .
C7 C8 1.373(11) .
C7 H7 0.9300 .
C8 C9 1.404(10) .
C8 H8 0.9300 .
C9 N2 1.336(9) .
C9 H9 0.9300 .
C10 C14 1.380(11) .
C10 C11 1.389(10) .
C11 C12 1.367(11) .
C11 H11 0.9300 .
C12 N3 1.346(12) .
C12 H12 0.9300 .
C13 N3 1.333(11) .
C13 C14 1.362(11) .
C13 H13 0.9300 .
C14 H14 0.9300 .
C15 N4 1.326(8) .
C15 C16 1.421(10) .
C15 H15 0.9300 .
C16 C17 1.341(11) .
C16 H16 0.9300 .
C17 C18 1.423(9) .
C17 H17 0.9300 .
C18 N4 1.390(8) .
C18 C19 1.408(9) 2_566
C19 C20 1.388(9) 2_566
C19 C18 1.408(9) 2_566
C19 C24 1.497(9) .
C20 C19 1.388(9) 2_566
C20 N5 1.402(8) .
C20 C21 1.421(9) .
C21 C22 1.393(9) .
C21 H21 0.9300 .
C22 C23 1.400(9) .
C22 H22 0.9300 .
C23 N5 1.334(8) .
C23 H23 0.9300 .
C24 C28 1.386(9) .
C24 C25 1.393(9) .
C25 C26 1.373(11) .
C25 H25 0.9300 .
C26 N6 1.342(9) .
C26 H26 0.9300 .
C27 N6 1.325(9) .
C27 C28 1.388(10) .
C27 H27 0.9300 .
C28 H28 0.9300 .
C29 N7 1.340(10) .
C29 C30 1.374(10) .
C29 H29 0.9300 .
C30 C31 1.387(9) .
C30 H30 0.9300 .
C31 C32 1.386(10) .
C31 C34 1.505(9) .
C32 C33 1.373(10) .
C32 H32 0.9300 .
C33 N7 1.353(10) .
C33 H33 0.9300 .
C34 O1 1.290(8) .
C34 C35 1.382(9) .
C35 C36 1.385(10) .
C35 H35 0.9300 .
C36 O2 1.286(8) .
C36 C37 1.492(9) .
C37 C38 1.377(10) .
C37 C41 1.399(10) .
C38 C39 1.390(9) .
C38 H38 0.9300 .
C39 N8 1.339(10) .
C39 H39 0.9300 .
C40 N8 1.337(9) .
C40 C41 1.382(10) .
C40 H40 0.9300 .
C41 H41 0.9300 .
C42 N9 1.093(11) .
C42 C43 1.464(13) .
C43 H43A 0.9600 .
C43 H43B 0.9600 .
C43 H43C 0.9600 .
N1 Co1 1.914(5) .
N2 Co1 1.919(6) .
N4 Co1 1.938(5) .
N5 Co1 1.900(5) .
N6 Ag1 2.270(6) .
N8 Ag1 2.242(6) .
N9 Ag1 2.308(7) .
O1 Co1 1.900(5) .
O2 Co1 1.903(4) .
C44 F3 1.321(13) .
C44 F1 1.331(14) .
C44 F2 1.344(12) .
C44 S1 1.792(12) .
O3 S1 1.432(6) .
O4 S1 1.440(7) .
O5 S1 1.425(7) .
C45 N10 1.166(18) .
C45 C46 1.44(2) .
C46 H46A 0.9600 .
C46 H46B 0.9600 .
C46 H46C 0.9600 .
C47 N11 1.11(3) .
C47 C48 1.45(3) .
C48 H48A 0.9600 .
C48 H48B 0.9600 .
C48 H48C 0.9600 .
C50 C52 1.409(18) 2_756
C50 C51 1.422(19) .
C50 H50 0.9300 .
C51 C52 1.392(19) .
C51 H51 0.9300 .
C52 C50 1.409(18) 2_756
C52 H52 0.9300 .
