#------------------------------------------------------------------------------
#$Date: 2016-03-25 14:36:11 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179903 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/99/7019902.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7019902
loop_
_publ_author_name
'Zhu, Qilong'
'Shen, Chaojun'
'Tan, Chunhong'
'Sheng, Tianlu'
'Hu, Shengmin'
'Wu, Xintao'
_publ_section_title
;
 A one-dimensional coordination polymer constructed from planar
 pentanuclear copper(ii) clusters with a flexible tripodal ligand.
;
_journal_issue                   32
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9604
_journal_page_last               9606
_journal_paper_doi               10.1039/c2dt30912b
_journal_volume                  41
_journal_year                    2012
_chemical_formula_sum            'C24 H50 Cl2 Cu5 N6 O40'
_chemical_formula_weight         1451.30
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                93.545(3)
_cell_angle_beta                 93.921(2)
_cell_angle_gamma                114.081(4)
_cell_formula_units_Z            2
_cell_length_a                   12.2174(12)
_cell_length_b                   14.3962(13)
_cell_length_c                   15.2425(9)
_cell_measurement_reflns_used    7753
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.4816
_cell_measurement_theta_min      2.3851
_cell_volume                     2430.0(4)
_computing_cell_refinement       'CrystalClear (Rigaku Inc., 2007)'
_computing_data_collection       'CrystalClear (Rigaku Inc., 2007)'
_computing_data_reduction        'CrystalClear (Rigaku Inc., 2007)'
_computing_molecular_graphics
'ORTEP-3 for Windows (Version 1.06) and DIAMOND (Brandenburg, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 28.5714
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Saturn724+ (2x2 bin mode)'
_diffrn_measurement_method       CCD_Profile_fitting
_diffrn_radiation_monochromator  'Graphite Monochromator'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0306
_diffrn_reflns_av_sigmaI/netI    0.0545
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            21157
_diffrn_reflns_theta_full        27.52
_diffrn_reflns_theta_max         27.52
_diffrn_reflns_theta_min         2.31
_exptl_absorpt_coefficient_mu    2.385
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.5158
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.984
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       chunk
_exptl_crystal_F_000             1470
_exptl_crystal_size_max          0.3000
_exptl_crystal_size_mid          0.1500
_exptl_crystal_size_min          0.0800
_refine_diff_density_max         0.744
_refine_diff_density_min         -1.057
_refine_diff_density_rms         0.110
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.992
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     754
_refine_ls_number_reflns         11011
_refine_ls_number_restraints     380
_refine_ls_restrained_S_all      1.043
_refine_ls_R_factor_all          0.0594
_refine_ls_R_factor_gt           0.0480
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0855P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1363
_refine_ls_wR_factor_ref         0.1462
_reflns_number_gt                8999
_reflns_number_total             11011
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt30912b.txt
_cod_data_source_block           a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7019902
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 0.36676(4) 0.50427(3) -0.33632(3) 0.02942(13) Uani 1 1 d . . .
Cu2 Cu 0.5000 0.5000 0.0000 0.02398(15) Uani 1 2 d S . .
Cu3 Cu 0.49651(4) 0.33424(3) -0.37684(3) 0.03256(13) Uani 1 1 d . . .
Cu4 Cu 0.5000 0.5000 -0.5000 0.02347(14) Uani 1 2 d S . .
Cu5 Cu 0.26369(4) 0.42972(4) -0.12460(3) 0.03931(15) Uani 1 1 d . . .
Cu6 Cu 0.51639(5) 0.65074(4) -0.14165(3) 0.03912(14) Uani 1 1 d . . .
N1 N 0.8136(3) 0.7913(2) -0.3955(2) 0.0370(8) Uani 1 1 d . . .
N2 N 0.9027(3) 0.6795(3) -0.4267(2) 0.0370(8) Uani 1 1 d . . .
N3 N 0.9188(3) 0.8069(3) -0.5189(2) 0.0464(10) Uani 1 1 d . . .
N4 N 0.5717(3) 0.2416(2) -0.1278(2) 0.0351(7) Uani 1 1 d . . .
N5 N 0.7500(4) 0.2801(3) -0.0376(2) 0.0479(10) Uani 1 1 d . B .
N6 N 0.7424(3) 0.3887(3) -0.1431(2) 0.0339(7) Uani 1 1 d . . .
C1 C 0.8244(4) 0.7019(3) -0.3783(3) 0.0370(9) Uani 1 1 d . . .
C2 C 0.9506(4) 0.7280(4) -0.4988(3) 0.0452(11) Uani 1 1 d . . .
C3 C 0.8570(4) 0.8453(3) -0.4661(3) 0.0456(11) Uani 1 1 d . . .
C4 C 0.7480(4) 0.8305(3) -0.3353(3) 0.0452(11) Uani 1 1 d . . .
H4A H 0.7914 0.9041 -0.3237 0.054 Uiso 1 1 calc R . .
H4B H 0.7462 0.8012 -0.2795 0.054 Uiso 1 1 calc R . .
C5 C 0.6184(4) 0.8050(3) -0.3735(3) 0.0429(10) Uani 1 1 d . . .
H5A H 0.5801 0.8331 -0.3322 0.051 Uiso 1 1 calc R . .
H5B H 0.6198 0.8364 -0.4282 0.051 Uiso 1 1 calc R . .
C6 C 0.5461(3) 0.6911(3) -0.3911(3) 0.0316(8) Uani 1 1 d . . .
C7 C 0.9285(4) 0.5920(4) -0.4046(3) 0.0447(11) Uani 1 1 d . . .
H7A H 0.9181 0.5824 -0.3428 0.054 Uiso 1 1 calc R . .
H7B H 1.0120 0.6074 -0.4126 0.054 Uiso 1 1 calc R . .
C8 C 0.8482(4) 0.4932(3) -0.4605(3) 0.0390(9) Uani 1 1 d . . .
H8A H 0.8644 0.5005 -0.5217 0.047 Uiso 1 1 calc R . .
H8B H 0.8680 0.4383 -0.4415 0.047 Uiso 1 1 calc R . .
C9 C 0.7160(3) 0.4647(3) -0.4544(2) 0.0291(8) Uani 1 1 d . . .
C10 C 0.9562(5) 0.8543(4) -0.6020(3) 0.0626(16) Uani 1 1 d . . .
H10A H 0.9690 0.9254 -0.5934 0.075 Uiso 1 1 calc R . .
H10B H 1.0330 0.8529 -0.6126 0.075 Uiso 1 1 calc R . .
C11 C 0.8708(4) 0.8057(4) -0.6817(3) 0.0594(15) Uani 1 1 d . . .
H11A H 0.9110 0.7807 -0.7238 0.071 Uiso 1 1 calc R . .
H11B H 0.8526 0.8580 -0.7082 0.071 Uiso 1 1 calc R . .
C12 C 0.7539(4) 0.7190(3) -0.6685(3) 0.0354(9) Uani 1 1 d . . .
C13 C 0.6328(5) 0.2133(4) -0.0627(3) 0.0437(11) Uani 1 1 d . . .
C14 C 0.8124(4) 0.3619(4) -0.0828(3) 0.0455(11) Uani 1 1 d . . .
C15 C 0.6207(3) 0.3327(3) -0.1634(2) 0.0295(8) Uani 1 1 d . . .
C16 C 0.4448(4) 0.1727(3) -0.1551(3) 0.0403(10) Uani 1 1 d . . .
H16A H 0.4371 0.1027 -0.1616 0.048 Uiso 1 1 calc R . .
H16B H 0.4209 0.1885 -0.2122 0.048 Uiso 1 1 calc R . .
C17 C 0.3602(4) 0.1812(3) -0.0893(3) 0.0403(10) Uani 1 1 d . . .
H17A H 0.3817 0.1628 -0.0326 0.048 Uiso 1 1 calc R . .
H17B H 0.2782 0.1336 -0.1098 0.048 Uiso 1 1 calc R . .
C18 C 0.3669(3) 0.2886(3) -0.0783(2) 0.0298(8) Uani 1 1 d . . .
C19 C 0.8147(6) 0.2612(6) 0.0405(3) 0.076(2) Uani 1 1 d . . .
H19A H 0.8054 0.1909 0.0335 0.092 Uiso 0.50 1 calc PR A 1
H19B H 0.9000 0.3048 0.0418 0.092 Uiso 0.50 1 calc PR A 1
H19C H 0.7720 0.1909 0.0527 0.092 Uiso 0.50 1 d PR A 2
H19D H 0.8928 0.2669 0.0242 0.092 Uiso 0.50 1 d PR A 2
C20A C 0.7762(10) 0.2786(9) 0.1212(7) 0.044(2) Uani 0.50 1 d P B 1
H20A H 0.8423 0.2954 0.1670 0.053 Uiso 0.50 1 calc PR B 1
H20B H 0.7115 0.2157 0.1339 0.053 Uiso 0.50 1 calc PR B 1
C20B C 0.8347(10) 0.3280(9) 0.1182(8) 0.046(2) Uani 0.50 1 d P B 2
H20C H 0.9106 0.3871 0.1178 0.055 Uiso 0.50 1 calc PR B 2
H20D H 0.8410 0.2931 0.1694 0.055 Uiso 0.50 1 calc PR B 2
C21 C 0.7311(6) 0.3651(6) 0.1264(3) 0.0607(17) Uani 1 1 d . . .
C22 C 0.8026(4) 0.4837(3) -0.1845(3) 0.0420(10) Uani 1 1 d . . .
H22A H 0.7537 0.4819 -0.2380 0.050 Uiso 1 1 calc R . .
H22B H 0.8794 0.4875 -0.2012 0.050 Uiso 1 1 calc R . .
C23 C 0.8242(4) 0.5792(3) -0.1244(3) 0.0397(10) Uani 1 1 d . . .
H23A H 0.8675 0.6394 -0.1540 0.048 Uiso 1 1 calc R . .
H23B H 0.8735 0.5818 -0.0708 0.048 Uiso 1 1 calc R . .
C24 C 0.7060(3) 0.5796(3) -0.1007(3) 0.0309(8) Uani 1 1 d . . .
O1 O 0.7700(3) 0.6482(2) -0.32381(19) 0.0431(7) Uani 1 1 d . . .
O1W O 0.0139(3) 0.4210(3) -0.2975(2) 0.0574(9) Uani 1 1 d . . .
O2 O 1.0151(3) 0.7034(3) -0.5422(2) 0.0621(10) Uani 1 1 d . . .
O2W O 0.3193(5) 0.0145(3) -0.4250(4) 0.0961(16) Uani 1 1 d . . .
O3 O 0.8409(3) 0.9205(2) -0.4815(2) 0.0608(10) Uani 1 1 d . . .
O3W O 0.2568(5) 0.7290(4) -0.3670(5) 0.119(2) Uani 1 1 d U . .
O4 O 0.4788(3) 0.6471(2) -0.33307(19) 0.0391(7) Uani 1 1 d . . .
O4W O 0.6901(5) 0.1747(4) -0.4734(4) 0.1053(17) Uani 1 1 d . . .
O5 O 0.5607(2) 0.64843(19) -0.46101(18) 0.0310(6) Uani 1 1 d . . .
O5W O 0.6147(12) 0.0888(9) 0.2884(8) 0.167(4) Uani 0.65 1 d PU . .
O6 O 0.6644(3) 0.3968(2) -0.40445(19) 0.0372(6) Uani 1 1 d . . .
O6W O 0.5215(6) 0.9302(3) -0.1312(4) 0.118(2) Uani 1 1 d U . .
O7W O 0.8529(6) 0.8767(5) -0.0815(4) 0.138(2) Uani 1 1 d . . .
O7 O 0.6673(2) 0.51088(19) -0.49948(17) 0.0285(5) Uani 1 1 d . . .
O8W O 0.0211(6) 0.1485(6) -0.0776(5) 0.156(3) Uani 1 1 d U . .
O8 O 0.6705(3) 0.7418(2) -0.6439(2) 0.0442(7) Uani 1 1 d . . .
O9 O 0.7492(3) 0.6304(2) -0.6813(2) 0.0449(8) Uani 1 1 d . . .
O10 O 0.5838(4) 0.1331(3) -0.0297(2) 0.0682(11) Uani 1 1 d . . .
O11 O 0.9202(3) 0.4101(3) -0.0694(3) 0.0671(11) Uani 1 1 d . . .
O12 O 0.5595(3) 0.3617(2) -0.21246(18) 0.0362(6) Uani 1 1 d . . .
O13 O 0.2894(2) 0.3060(2) -0.1224(2) 0.0402(7) Uani 1 1 d . . .
O14 O 0.4542(2) 0.35285(19) -0.02568(17) 0.0295(6) Uani 1 1 d . . .
O15 O 0.7828(3) 0.4591(4) 0.1208(2) 0.0628(11) Uani 1 1 d . . .
O16 O 0.6199(4) 0.3148(3) 0.1334(2) 0.0596(10) Uani 1 1 d . . .
O17 O 0.6634(3) 0.6291(2) -0.1459(2) 0.0418(7) Uani 1 1 d . . .
O18 O 0.6579(2) 0.52723(19) -0.03905(17) 0.0295(6) Uani 1 1 d . . .
O19 O 0.4949(2) 0.46460(19) -0.35531(17) 0.0294(6) Uani 1 1 d . . .
H19 H 0.5631 0.5065 -0.3301 0.033(12) Uiso 1 1 d R . .
O20 O 0.4219(2) 0.5065(2) -0.15460(19) 0.0361(6) Uani 1 1 d . . .
H20 H 0.4609 0.4718 -0.1694 0.042(13) Uiso 1 1 d R . .
O21 O 0.2417(3) 0.5520(2) -0.3189(2) 0.0420(7) Uani 1 1 d . . .
O22 O 0.5061(3) 0.2027(2) -0.3947(2) 0.0556(9) Uani 1 1 d . . .
O23 O 0.6159(4) 0.7954(2) -0.1424(2) 0.0620(10) Uani 1 1 d . . .
O24 O 0.0952(3) 0.3444(3) -0.1115(3) 0.0686(11) Uani 1 1 d . . .
Cl1 Cl 0.90365(16) 0.09458(12) 0.23202(13) 0.0809(5) Uani 1 1 d . . .
O1A O 0.7914(6) 0.0628(5) 0.1885(6) 0.165(3) Uani 1 1 d . . .
O1B O 0.9041(7) 0.0866(6) 0.3236(5) 0.170(3) Uani 1 1 d U . .
O1C O 0.9802(6) 0.1895(4) 0.2139(5) 0.142(3) Uani 1 1 d U . .
O1D O 0.9521(9) 0.0265(6) 0.2038(6) 0.185(4) Uani 1 1 d . . .
Cl2 Cl 0.23465(16) 0.87918(12) 0.24559(12) 0.0805(6) Uani 0.178(4) 1 d PDU C 1
O2A O 0.258(2) 0.8746(17) 0.1581(8) 0.088(6) Uani 0.178(4) 1 d PDU C 1
O2B O 0.3394(15) 0.9540(14) 0.2990(14) 0.111(7) Uani 0.178(4) 1 d PDU C 1
O2C O 0.1410(14) 0.9147(15) 0.2517(14) 0.073(5) Uani 0.178(4) 1 d PDU C 1
O2D O 0.202(2) 0.7856(11) 0.2823(15) 0.106(7) Uani 0.178(4) 1 d PDU C 1
Cl2A Cl 0.23465(16) 0.87918(12) 0.24559(12) 0.0805(6) Uani 0.82 1 d PDU C 2
O2E O 0.1673(8) 0.7744(4) 0.2311(6) 0.162(3) Uani 0.822(4) 1 d PDU C 2
O2F O 0.2212(8) 0.9231(6) 0.3230(5) 0.153(3) Uani 0.822(4) 1 d PDU C 2
O2G O 0.3613(5) 0.9020(6) 0.2427(6) 0.140(3) Uani 0.822(4) 1 d PDU C 2
O2H O 0.2084(10) 0.9261(8) 0.1714(6) 0.209(4) Uani 0.822(4) 1 d PDU C 2
O9W O 0.811(2) 0.0383(18) -0.0032(16) 0.171(9) Uani 0.35 1 d P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O19 Cu1 O9 95.66(12) . 2_664
O19 Cu1 O21 176.85(11) . .
O9 Cu1 O21 87.45(13) 2_664 .
O19 Cu1 O4 89.69(11) . .
O9 Cu1 O4 169.76(13) 2_664 .
O21 Cu1 O4 87.30(12) . .
O18 Cu2 O18 180.0 . 2_665
O18 Cu2 O14 90.61(11) . 2_665
O18 Cu2 O14 89.39(11) 2_665 2_665
O18 Cu2 O14 89.39(11) . .
O18 Cu2 O14 90.61(11) 2_665 .
O14 Cu2 O14 180.00(15) 2_665 .
O19 Cu3 O8 95.10(12) . 2_664
O19 Cu3 O22 176.92(14) . .
O8 Cu3 O22 86.93(14) 2_664 .
O19 Cu3 O6 91.05(11) . .
O8 Cu3 O6 173.56(13) 2_664 .
O22 Cu3 O6 87.01(13) . .
O7 Cu4 O7 180.00(15) 2_664 .
O7 Cu4 O5 89.06(11) 2_664 .
O7 Cu4 O5 90.94(11) . .
O7 Cu4 O5 90.94(11) 2_664 2_664
O7 Cu4 O5 89.06(11) . 2_664
O5 Cu4 O5 180.00(17) . 2_664
O7 Cu4 O19 91.12(10) 2_664 2_664
O7 Cu4 O19 88.88(10) . 2_664
O5 Cu4 O19 90.02(10) . 2_664
O5 Cu4 O19 89.98(10) 2_664 2_664
O7 Cu4 O19 88.88(10) 2_664 .
O7 Cu4 O19 91.12(10) . .
O5 Cu4 O19 89.98(10) . .
O5 Cu4 O19 90.02(10) 2_664 .
O19 Cu4 O19 180.00(14) 2_664 .
O20 Cu5 O15 95.49(14) . 2_665
O20 Cu5 O13 92.54(12) . .
O15 Cu5 O13 171.92(14) 2_665 .
O20 Cu5 O24 171.91(16) . .
O15 Cu5 O24 85.73(17) 2_665 .
O13 Cu5 O24 86.43(15) . .
O20 Cu6 O16 94.68(15) . 2_665
O20 Cu6 O23 173.47(13) . .
O16 Cu6 O23 87.73(17) 2_665 .
O20 Cu6 O17 90.47(12) . .
O16 Cu6 O17 174.69(15) 2_665 .
O23 Cu6 O17 87.30(15) . .
C3 N1 C1 124.3(4) . .
C3 N1 C4 117.4(4) . .
C1 N1 C4 118.2(3) . .
C2 N2 C1 124.2(4) . .
C2 N2 C7 117.9(4) . .
C1 N2 C7 117.6(3) . .
C3 N3 C2 124.1(4) . .
C3 N3 C10 118.1(5) . .
C2 N3 C10 117.8(4) . .
C15 N4 C13 123.2(4) . .
C15 N4 C16 118.9(4) . .
C13 N4 C16 117.7(4) . .
C14 N5 C13 123.3(4) . .
C14 N5 C19 118.0(5) . .
C13 N5 C19 118.6(5) . .
C15 N6 C14 123.4(4) . .
C15 N6 C22 119.1(4) . .
C14 N6 C22 117.5(4) . .
O1 C1 N2 122.5(4) . .
O1 C1 N1 122.4(4) . .
N2 C1 N1 115.0(3) . .
O2 C2 N2 122.5(5) . .
O2 C2 N3 122.1(4) . .
N2 C2 N3 115.4(4) . .
O3 C3 N3 122.2(4) . .
O3 C3 N1 122.6(5) . .
N3 C3 N1 115.2(4) . .
N1 C4 C5 112.7(4) . .
C6 C5 C4 111.1(4) . .
O5 C6 O4 126.2(3) . .
O5 C6 C5 116.8(3) . .
O4 C6 C5 117.0(3) . .
N2 C7 C8 113.1(4) . .
C9 C8 C7 112.8(3) . .
O6 C9 O7 126.1(3) . .
O6 C9 C8 116.7(3) . .
O7 C9 C8 117.2(3) . .
C11 C10 N3 115.6(4) . .
C10 C11 C12 116.6(4) . .
O9 C12 O8 126.1(3) . .
O9 C12 C11 116.6(4) . .
O8 C12 C11 117.2(4) . .
O10 C13 N5 122.6(5) . .
O10 C13 N4 121.1(5) . .
N5 C13 N4 116.3(4) . .
O11 C14 N5 122.8(5) . .
O11 C14 N6 121.8(5) . .
N5 C14 N6 115.4(4) . .
O12 C15 N4 121.7(4) . .
O12 C15 N6 122.0(4) . .
N4 C15 N6 116.3(4) . .
N4 C16 C17 112.7(3) . .
C16 C17 C18 111.1(3) . .
O13 C18 O14 126.5(4) . .
O13 C18 C17 117.4(4) . .
O14 C18 C17 116.1(4) . .
C20A C19 C20B 32.3(5) . .
C20A C19 N5 114.8(6) . .
C20B C19 N5 116.0(6) . .
C19 C20A C21 115.1(8) . .
C19 C20B C21 112.4(8) . .
O15 C21 O16 126.2(4) . .
O15 C21 C20A 132.3(7) . .
O16 C21 C20A 101.4(7) . .
O15 C21 C20B 103.3(7) . .
O16 C21 C20B 130.4(7) . .
C20A C21 C20B 29.0(5) . .
N6 C22 C23 113.1(3) . .
C22 C23 C24 110.9(3) . .
O17 C24 O18 126.2(4) . .
O17 C24 C23 116.8(3) . .
O18 C24 C23 116.9(4) . .
C6 O4 Cu1 128.4(2) . .
C6 O5 Cu4 129.0(2) . .
C9 O6 Cu3 131.4(3) . .
C9 O7 Cu4 127.7(2) . .
C12 O8 Cu3 135.5(3) . 2_664
C12 O9 Cu1 134.6(3) . 2_664
C18 O13 Cu5 130.2(3) . .
C18 O14 Cu2 128.3(3) . .
C21 O15 Cu5 135.6(3) . 2_665
C21 O16 Cu6 134.8(3) . 2_665
C24 O17 Cu6 131.9(2) . .
C24 O18 Cu2 127.5(3) . .
Cu3 O19 Cu1 131.49(14) . .
Cu3 O19 Cu4 95.67(11) . .
Cu1 O19 Cu4 93.95(11) . .
Cu5 O20 Cu6 130.06(15) . .
O1C Cl1 O1A 112.8(4) . .
O1C Cl1 O1D 107.3(5) . .
O1A Cl1 O1D 107.8(6) . .
O1C Cl1 O1B 111.6(5) . .
O1A Cl1 O1B 114.0(5) . .
O1D Cl1 O1B 102.6(5) . .
O2A Cl2 O2D 113.7(8) . .
O2A Cl2 O2C 108.6(8) . .
O2D Cl2 O2C 109.8(8) . .
O2A Cl2 O2B 110.2(8) . .
O2D Cl2 O2B 108.0(8) . .
O2C Cl2 O2B 106.2(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu1 O19 1.906(3) .
Cu1 O9 1.928(3) 2_664
Cu1 O21 1.941(3) .
Cu1 O4 1.945(3) .
Cu2 O18 1.949(2) .
Cu2 O18 1.949(2) 2_665
Cu2 O14 1.963(2) 2_665
Cu2 O14 1.963(2) .
Cu3 O19 1.893(3) .
Cu3 O8 1.942(3) 2_664
Cu3 O22 1.949(3) .
Cu3 O6 1.962(3) .
Cu4 O7 1.984(2) 2_664
Cu4 O7 1.984(2) .
Cu4 O5 1.990(2) .
Cu4 O5 1.990(2) 2_664
Cu4 O19 2.293(3) 2_664
Cu4 O19 2.293(3) .
Cu5 O20 1.900(3) .
Cu5 O15 1.903(4) 2_665
Cu5 O13 1.932(3) .
Cu5 O24 1.952(3) .
Cu6 O20 1.909(3) .
Cu6 O16 1.931(4) 2_665
Cu6 O23 1.937(3) .
Cu6 O17 1.949(3) .
N1 C3 1.374(5) .
N1 C1 1.386(6) .
N1 C4 1.485(5) .
N2 C2 1.373(5) .
N2 C1 1.372(5) .
N2 C7 1.469(6) .
N3 C3 1.376(6) .
N3 C2 1.386(7) .
N3 C10 1.486(5) .
N4 C15 1.366(5) .
N4 C13 1.380(6) .
N4 C16 1.472(5) .
N5 C14 1.372(6) .
N5 C13 1.369(7) .
N5 C19 1.485(6) .
N6 C15 1.373(5) .
N6 C14 1.389(5) .
N6 C22 1.470(5) .
C1 O1 1.210(5) .
C2 O2 1.205(6) .
C3 O3 1.209(6) .
C4 C5 1.535(7) .
C5 C6 1.508(5) .
C6 O5 1.256(4) .
C6 O4 1.267(4) .
C7 C8 1.520(6) .
C8 C9 1.507(5) .
C9 O6 1.260(4) .
C9 O7 1.262(5) .
C10 C11 1.476(7) .
C11 C12 1.502(5) .
C12 O9 1.255(5) .
C12 O8 1.264(5) .
C13 O10 1.223(6) .
C14 O11 1.208(6) .
C15 O12 1.228(5) .
C16 C17 1.523(6) .
C17 C18 1.512(5) .
C18 O13 1.241(5) .
C18 O14 1.274(5) .
C19 C20A 1.391(11) .
C19 C20B 1.419(12) .
C20A C21 1.554(12) .
C20B C21 1.571(11) .
C21 O15 1.250(7) .
C21 O16 1.268(7) .
C22 C23 1.521(6) .
C23 C24 1.514(5) .
C24 O17 1.252(5) .
C24 O18 1.263(4) .
O8 Cu3 1.942(3) 2_664
O9 Cu1 1.928(3) 2_664
O15 Cu5 1.903(4) 2_665
O16 Cu6 1.931(4) 2_665
Cl1 O1C 1.362(5) .
Cl1 O1A 1.362(6) .
Cl1 O1D 1.397(7) .
Cl1 O1B 1.407(7) .
Cl2 O2A 1.386(8) .
Cl2 O2D 1.405(8) .
Cl2 O2C 1.438(8) .
Cl2 O2B 1.444(9) .
