#------------------------------------------------------------------------------
#$Date: 2016-03-25 15:07:06 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179913 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/08/7020865.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7020865
loop_
_publ_author_name
'Zeng, Cheng-Hui'
'Zhao, Fu-Li'
'Yang, Yang-Yi'
'Xie, Ming-Yuan'
'Ding, Xue-Mei'
'Hou, De-Jian'
'Ng, Seik Weng'
_publ_section_title
;
 Unusual method for phenolic hydroxyl bridged lanthanide CPs: Syntheses,
 characterization, one and two photon luminescence.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2052
_journal_page_last               2061
_journal_paper_doi               10.1039/c2dt32233a
_journal_volume                  42
_journal_year                    2013
_chemical_formula_moiety         'C16 H15 Eu O7'
_chemical_formula_sum            'C16 H15 Eu O7'
_chemical_formula_weight         471.24
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 91.970(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.6908(7)
_cell_length_b                   8.6945(3)
_cell_length_c                   10.8897(4)
_cell_measurement_reflns_used    3621
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.5015
_cell_measurement_theta_min      2.3377
_cell_volume                     1579.36(10)
_computing_cell_refinement       'CrysAlis PRO (Agilent, 2011)'
_computing_data_collection       'CrysAlis PRO (Agilent, 2011)'
_computing_data_reduction        'CrysAlis PRO (Agilent, 2011)'
_computing_molecular_graphics    'X-Seed (Barbour, 2001)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 10.4041
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type
'Agilent Technologies SuperNova Dual diffractometer with Atlas detector'
_diffrn_measurement_method       'ω scan'
_diffrn_radiation_monochromator  Mirror
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0341
_diffrn_reflns_av_sigmaI/netI    0.0385
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            10361
_diffrn_reflns_theta_full        27.56
_diffrn_reflns_theta_max         27.56
_diffrn_reflns_theta_min         2.44
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    4.007
_exptl_absorpt_correction_T_max  0.8248
_exptl_absorpt_correction_T_min  0.5848
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'CrysAlis PRO (Agilent, 2011)'
_exptl_crystal_colour            baby-pink
_exptl_crystal_density_diffrn    1.982
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             920
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.05
_refine_diff_density_max         4.058
_refine_diff_density_min         -1.546
_refine_diff_density_rms         0.187
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     207
_refine_ls_number_reflns         3651
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.068
_refine_ls_R_factor_all          0.0430
_refine_ls_R_factor_gt           0.0348
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0430P)²+7.8434P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0856
_refine_ls_wR_factor_ref         0.0913
_reflns_number_gt                3164
_reflns_number_total             3651
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            c2dt32233a.txt
_cod_data_source_block           3
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7020865
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.462538(13) 0.56661(2) 0.157886(19) 0.00830(9) Uani 1 1 d .
O1 O 0.5614(2) 0.5475(4) 0.3213(3) 0.0135(7) Uani 1 1 d .
O2 O 0.53823(19) 0.7942(4) 0.2942(3) 0.0114(6) Uani 1 1 d .
O3 O 0.5686(2) 0.9374(3) 0.5256(3) 0.0092(6) Uani 1 1 d .
O4 O 0.3721(2) 0.6653(4) 0.3173(3) 0.0154(7) Uani 1 1 d .
O5 O 0.3190(2) 0.5340(4) 0.1638(3) 0.0144(7) Uani 1 1 d .
O6 O 0.1683(2) 0.4706(4) 0.1481(3) 0.0163(7) Uani 1 1 d .
H6 H 0.2164 0.4661 0.1278 0.024 Uiso 1 1 calc R
O7 O 0.4233(2) 0.7893(4) 0.0495(3) 0.0171(7) Uani 1 1 d .
H7A H 0.4167 0.8738 0.0867 0.026 Uiso 1 1 d R
H7B H 0.4070 0.8023 -0.0245 0.026 Uiso 1 1 d R
C1 C 0.5761(3) 0.6869(5) 0.3507(4) 0.010 Uani 1 1 d .
C2 C 0.6389(3) 0.7190(5) 0.4470(4) 0.0105(9) Uani 1 1 d .
C3 C 0.6340(3) 0.8458(5) 0.5270(4) 0.010 Uani 1 1 d .
C4 C 0.6998(3) 0.8802(5) 0.6057(4) 0.0112(9) Uani 1 1 d .
H4 H 0.6962 0.9630 0.6622 0.013 Uiso 1 1 calc R
C5 C 0.7701(3) 0.7950(6) 0.6025(4) 0.0146(10) Uani 1 1 d .
C6 C 0.7732(3) 0.6680(5) 0.5256(4) 0.0141(9) Uani 1 1 d .
H6A H 0.8206 0.6077 0.5243 0.017 Uiso 1 1 calc R
C7 C 0.7080(3) 0.6285(5) 0.4511(4) 0.0118(9) Uani 1 1 d .
H7 H 0.7100 0.5384 0.4019 0.014 Uiso 1 1 calc R
C8 C 0.8424(3) 0.8449(6) 0.6796(5) 0.0185(10) Uani 1 1 d .
H8A H 0.8728 0.9216 0.6345 0.028 Uiso 1 1 calc R
H8B H 0.8766 0.7556 0.6979 0.028 Uiso 1 1 calc R
H8C H 0.8248 0.8900 0.7566 0.028 Uiso 1 1 calc R
C9 C 0.3098(3) 0.6113(5) 0.2615(4) 0.0120(9) Uani 1 1 d .
C10 C 0.2285(3) 0.6373(5) 0.3051(4) 0.0133(9) Uani 1 1 d .
C11 C 0.1622(3) 0.5646(5) 0.2454(5) 0.0138(10) Uani 1 1 d .
C12 C 0.0855(3) 0.5852(6) 0.2913(5) 0.0177(10) Uani 1 1 d .
H12 H 0.0409 0.5363 0.2513 0.021 Uiso 1 1 calc R
C13 C 0.0734(3) 0.6754(6) 0.3940(5) 0.0194(11) Uani 1 1 d .
C14 C 0.1393(3) 0.7459(6) 0.4521(5) 0.0182(11) Uani 1 1 d .
H14 H 0.1318 0.8073 0.5230 0.022 Uiso 1 1 calc R
C15 C 0.2153(3) 0.7278(6) 0.4080(5) 0.0174(10) Uani 1 1 d .
H15 H 0.2593 0.7779 0.4486 0.021 Uiso 1 1 calc R
C16 C -0.0091(3) 0.6960(7) 0.4431(5) 0.0267(13) Uani 1 1 d .
H16A H -0.0315 0.7942 0.4141 0.040 Uiso 1 1 calc R
H16B H -0.0057 0.6956 0.5331 0.040 Uiso 1 1 calc R
H16C H -0.0437 0.6117 0.4140 0.040 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 Eu1 O3 67.29(13) 4_575 2_645
O3 Eu1 O7 84.59(11) 4_575 .
O3 Eu1 O7 85.22(11) 2_645 .
O3 Eu1 O1 86.52(12) 4_575 .
O3 Eu1 O1 136.98(11) 2_645 .
O7 Eu1 O1 127.20(11) . .
O3 Eu1 O5 142.48(11) 4_575 .
O3 Eu1 O5 76.95(11) 2_645 .
O7 Eu1 O5 81.42(12) . .
O1 Eu1 O5 129.19(12) . .
O3 Eu1 O2 97.39(10) 4_575 2_645
O3 Eu1 O2 73.24(11) 2_645 2_645
O7 Eu1 O2 155.46(12) . 2_645
O1 Eu1 O2 77.33(11) . 2_645
O5 Eu1 O2 82.35(11) . 2_645
O3 Eu1 O4 158.59(11) 4_575 .
O3 Eu1 O4 129.73(11) 2_645 .
O7 Eu1 O4 84.32(12) . .
O1 Eu1 O4 85.69(12) . .
O5 Eu1 O4 52.89(11) . .
O2 Eu1 O4 100.29(11) 2_645 .
O3 Eu1 O2 89.99(10) 4_575 .
O3 Eu1 O2 153.04(10) 2_645 .
O7 Eu1 O2 78.07(11) . .
O1 Eu1 O2 49.96(10) . .
O5 Eu1 O2 120.47(10) . .
O2 Eu1 O2 126.25(4) 2_645 .
O4 Eu1 O2 69.81(10) . .
O3 Eu1 C9 163.68(12) 4_575 .
O3 Eu1 C9 103.20(13) 2_645 .
O7 Eu1 C9 81.31(13) . .
O1 Eu1 C9 108.59(13) . .
O5 Eu1 C9 26.36(13) . .
O2 Eu1 C9 92.10(12) 2_645 .
O4 Eu1 C9 26.55(13) . .
O2 Eu1 C9 95.08(12) . .
O3 Eu1 C3 88.77(11) 4_575 2_645
O3 Eu1 C3 22.29(11) 2_645 2_645
O7 Eu1 C3 93.04(12) . 2_645
O1 Eu1 C3 138.69(11) . 2_645
O5 Eu1 C3 57.62(11) . 2_645
O2 Eu1 C3 62.64(12) 2_645 2_645
O4 Eu1 C3 110.06(11) . 2_645
O2 Eu1 C3 171.10(11) . 2_645
C9 Eu1 C3 83.82(13) . 2_645
O3 Eu1 Eu1 33.76(8) 4_575 3_665
O3 Eu1 Eu1 33.53(8) 2_645 3_665
O7 Eu1 Eu1 83.88(8) . 3_665
O1 Eu1 Eu1 113.83(9) . 3_665
O5 Eu1 Eu1 109.81(8) . 3_665
O2 Eu1 Eu1 84.45(8) 2_645 3_665
O4 Eu1 Eu1 160.48(8) . 3_665
O2 Eu1 Eu1 122.46(7) . 3_665
C9 Eu1 Eu1 135.42(10) . 3_665
C3 Eu1 Eu1 55.23(8) 2_645 3_665
C1 O1 Eu1 104.1(3) . .
C1 O2 Eu1 128.1(3) . 2_655
C1 O2 Eu1 86.9(3) . .
Eu1 O2 Eu1 144.28(14) 2_655 .
C3 O3 Eu1 128.1(3) . 4_576
C3 O3 Eu1 116.7(3) . 2_655
Eu1 O3 Eu1 112.71(13) 4_576 2_655
C9 O4 Eu1 92.6(3) . .
C9 O5 Eu1 96.2(3) . .
C11 O6 H6 109.5 . .
Eu1 O7 H7A 120.8 . .
Eu1 O7 H7B 131.4 . .
H7A O7 H7B 107.2 . .
O2 C1 O1 119.1(4) . .
O2 C1 C2 122.0(4) . .
O1 C1 C2 118.8(4) . .
C7 C2 C3 119.2(4) . .
C7 C2 C1 118.6(4) . .
C3 C2 C1 122.0(4) . .
O3 C3 C4 119.8(4) . .
O3 C3 C2 121.2(4) . .
C4 C3 C2 118.9(4) . .
O3 C3 Eu1 40.99(19) . 2_655
C4 C3 Eu1 128.9(3) . 2_655
C2 C3 Eu1 96.9(3) . 2_655
C5 C4 C3 121.0(4) . .
C5 C4 H4 119.5 . .
C3 C4 H4 119.5 . .
C6 C5 C4 119.2(5) . .
C6 C5 C8 121.3(4) . .
C4 C5 C8 119.5(4) . .
C7 C6 C5 120.6(4) . .
C7 C6 H6A 119.7 . .
C5 C6 H6A 119.7 . .
C6 C7 C2 120.9(4) . .
C6 C7 H7 119.6 . .
C2 C7 H7 119.6 . .
C5 C8 H8A 109.5 . .
C5 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C5 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
O5 C9 O4 118.2(4) . .
O5 C9 C10 119.4(4) . .
O4 C9 C10 122.4(4) . .
O5 C9 Eu1 57.4(2) . .
O4 C9 Eu1 60.9(2) . .
C10 C9 Eu1 175.5(3) . .
C15 C10 C11 118.7(5) . .
C15 C10 C9 121.3(5) . .
C11 C10 C9 119.9(4) . .
O6 C11 C12 116.9(5) . .
O6 C11 C10 123.8(4) . .
C12 C11 C10 119.3(5) . .
C13 C12 C11 121.3(5) . .
C13 C12 H12 119.3 . .
C11 C12 H12 119.3 . .
C12 C13 C14 118.8(5) . .
C12 C13 C16 120.9(5) . .
C14 C13 C16 120.3(5) . .
C15 C14 C13 120.9(5) . .
C15 C14 H14 119.6 . .
C13 C14 H14 119.6 . .
C14 C15 C10 121.1(5) . .
C14 C15 H15 119.5 . .
C10 C15 H15 119.5 . .
C13 C16 H16A 109.5 . .
C13 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C13 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O3 2.321(3) 4_575
Eu1 O3 2.335(3) 2_645
Eu1 O7 2.349(3) .
Eu1 O1 2.391(3) .
Eu1 O5 2.415(4) .
Eu1 O2 2.425(3) 2_645
Eu1 O4 2.492(3) .
Eu1 O2 2.754(3) .
Eu1 C9 2.850(5) .
Eu1 C3 3.180(5) 2_645
Eu1 Eu1 3.8763(4) 3_665
O1 C1 1.275(5) .
O2 C1 1.274(5) .
O2 Eu1 2.425(3) 2_655
O3 C3 1.350(5) .
O3 Eu1 2.321(3) 4_576
O3 Eu1 2.335(3) 2_655
O4 C9 1.275(6) .
O5 C9 1.273(6) .
O6 C11 1.345(6) .
O6 H6 0.8400 .
O7 H7A 0.8481 .
O7 H7B 0.8497 .
C1 C2 1.483(6) .
C2 C7 1.395(7) .
C2 C3 1.409(6) .
C3 C4 1.402(7) .
C3 Eu1 3.180(5) 2_655
C4 C5 1.389(7) .
C4 H4 0.9500 .
C5 C6 1.388(7) .
C5 C8 1.510(7) .
C6 C7 1.379(7) .
C6 H6A 0.9500 .
C7 H7 0.9500 .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C9 C10 1.471(7) .
C10 C15 1.393(7) .
C10 C11 1.413(7) .
C11 C12 1.403(7) .
C12 C13 1.386(7) .
C12 H12 0.9500 .
C13 C14 1.392(8) .
C13 C16 1.504(7) .
C14 C15 1.381(7) .
C14 H14 0.9500 .
C15 H15 0.9500 .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O6 H6 O5 0.84 1.84 2.575(5) 145.0 .
O7 H7A O1 0.85 1.84 2.657(5) 160.6 2_655
O7 H7B O4 0.85 1.82 2.671(5) 178.7 4_575
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O3 Eu1 O1 C1 92.4(3) 4_575 .
O3 Eu1 O1 C1 143.2(3) 2_645 .
O7 Eu1 O1 C1 11.9(3) . .
O5 Eu1 O1 C1 -100.3(3) . .
O2 Eu1 O1 C1 -169.2(3) 2_645 .
O4 Eu1 O1 C1 -67.7(3) . .
O2 Eu1 O1 C1 -0.5(3) . .
C9 Eu1 O1 C1 -81.3(3) . .
C3 Eu1 O1 C1 176.5(3) 2_645 .
Eu1 Eu1 O1 C1 112.7(3) 3_665 .
O3 Eu1 O2 C1 -84.9(3) 4_575 .
O3 Eu1 O2 C1 -116.5(3) 2_645 .
O7 Eu1 O2 C1 -169.4(3) . .
O1 Eu1 O2 C1 0.5(2) . .
O5 Eu1 O2 C1 118.1(3) . .
O2 Eu1 O2 C1 14.2(2) 2_645 .
O4 Eu1 O2 C1 102.3(3) . .
C9 Eu1 O2 C1 110.6(3) . .
C3 Eu1 O2 C1 -166.9(6) 2_645 .
Eu1 Eu1 O2 C1 -94.7(2) 3_665 .
O3 Eu1 O2 Eu1 105.7(2) 4_575 2_655
O3 Eu1 O2 Eu1 74.1(3) 2_645 2_655
O7 Eu1 O2 Eu1 21.2(2) . 2_655
O1 Eu1 O2 Eu1 -168.8(3) . 2_655
O5 Eu1 O2 Eu1 -51.2(3) . 2_655
O2 Eu1 O2 Eu1 -155.1(3) 2_645 2_655
O4 Eu1 O2 Eu1 -67.0(2) . 2_655
C9 Eu1 O2 Eu1 -58.7(2) . 2_655
C3 Eu1 O2 Eu1 23.8(8) 2_645 2_655
Eu1 Eu1 O2 Eu1 96.0(2) 3_665 2_655
O3 Eu1 O4 C9 141.0(3) 4_575 .
O3 Eu1 O4 C9 3.0(3) 2_645 .
O7 Eu1 O4 C9 81.9(3) . .
O1 Eu1 O4 C9 -150.0(3) . .
O5 Eu1 O4 C9 -1.6(3) . .
O2 Eu1 O4 C9 -73.7(3) 2_645 .
O2 Eu1 O4 C9 161.3(3) . .
C3 Eu1 O4 C9 -9.3(3) 2_645 .
Eu1 Eu1 O4 C9 28.9(4) 3_665 .
O3 Eu1 O5 C9 -157.1(3) 4_575 .
O3 Eu1 O5 C9 -174.8(3) 2_645 .
O7 Eu1 O5 C9 -87.7(3) . .
O1 Eu1 O5 C9 44.0(3) . .
O2 Eu1 O5 C9 110.8(3) 2_645 .
O4 Eu1 O5 C9 1.6(3) . .
O2 Eu1 O5 C9 -17.1(3) . .
C3 Eu1 O5 C9 173.1(3) 2_645 .
Eu1 Eu1 O5 C9 -168.0(3) 3_665 .
Eu1 O2 C1 O1 171.2(3) 2_655 .
Eu1 O2 C1 O1 -0.9(4) . .
Eu1 O2 C1 C2 -10.8(6) 2_655 .
Eu1 O2 C1 C2 177.1(4) . .
Eu1 O1 C1 O2 1.0(5) . .
Eu1 O1 C1 C2 -177.0(3) . .
O2 C1 C2 C7 -140.1(5) . .
O1 C1 C2 C7 37.9(6) . .
O2 C1 C2 C3 34.3(6) . .
O1 C1 C2 C3 -147.7(4) . .
Eu1 O3 C3 C4 -82.9(5) 4_576 .
Eu1 O3 C3 C4 116.3(4) 2_655 .
Eu1 O3 C3 C2 99.8(4) 4_576 .
Eu1 O3 C3 C2 -61.0(5) 2_655 .
Eu1 O3 C3 Eu1 160.8(4) 4_576 2_655
C7 C2 C3 O3 179.5(4) . .
C1 C2 C3 O3 5.1(7) . .
C7 C2 C3 C4 2.1(6) . .
C1 C2 C3 C4 -172.3(4) . .
C7 C2 C3 Eu1 144.1(4) . 2_655
C1 C2 C3 Eu1 -30.2(4) . 2_655
O3 C3 C4 C5 -175.0(4) . .
C2 C3 C4 C5 2.4(7) . .
Eu1 C3 C4 C5 -126.0(4) 2_655 .
C3 C4 C5 C6 -4.2(7) . .
C3 C4 C5 C8 174.0(4) . .
C4 C5 C6 C7 1.5(7) . .
C8 C5 C6 C7 -176.7(4) . .
C5 C6 C7 C2 3.0(7) . .
C3 C2 C7 C6 -4.8(7) . .
C1 C2 C7 C6 169.8(4) . .
Eu1 O5 C9 O4 -2.9(5) . .
Eu1 O5 C9 C10 176.3(4) . .
Eu1 O4 C9 O5 2.8(4) . .
Eu1 O4 C9 C10 -176.3(4) . .
O3 Eu1 C9 O5 57.7(6) 4_575 .
O3 Eu1 C9 O5 5.2(3) 2_645 .
O7 Eu1 C9 O5 88.2(3) . .
O1 Eu1 C9 O5 -145.4(3) . .
O2 Eu1 C9 O5 -68.0(3) 2_645 .
O4 Eu1 C9 O5 -177.1(5) . .
O2 Eu1 C9 O5 165.3(3) . .
C3 Eu1 C9 O5 -5.8(3) 2_645 .
Eu1 Eu1 C9 O5 16.2(3) 3_665 .
O3 Eu1 C9 O4 -125.2(4) 4_575 .
O3 Eu1 C9 O4 -177.7(3) 2_645 .
O7 Eu1 C9 O4 -94.7(3) . .
O1 Eu1 C9 O4 31.7(3) . .
O5 Eu1 C9 O4 177.1(5) . .
O2 Eu1 C9 O4 109.1(3) 2_645 .
O2 Eu1 C9 O4 -17.6(3) . .
C3 Eu1 C9 O4 171.3(3) 2_645 .
Eu1 Eu1 C9 O4 -166.7(2) 3_665 .
O3 Eu1 C9 C10 12(5) 4_575 .
O3 Eu1 C9 C10 -41(4) 2_645 .
O7 Eu1 C9 C10 42(4) . .
O1 Eu1 C9 C10 169(4) . .
O5 Eu1 C9 C10 -46(4) . .
O2 Eu1 C9 C10 -114(4) 2_645 .
O4 Eu1 C9 C10 137(4) . .
O2 Eu1 C9 C10 119(4) . .
C3 Eu1 C9 C10 -52(4) 2_645 .
Eu1 Eu1 C9 C10 -30(4) 3_665 .
O5 C9 C10 C15 -176.7(4) . .
O4 C9 C10 C15 2.4(7) . .
Eu1 C9 C10 C15 -133(4) . .
O5 C9 C10 C11 6.0(7) . .
O4 C9 C10 C11 -174.9(4) . .
Eu1 C9 C10 C11 50(4) . .
C15 C10 C11 O6 -177.6(4) . .
C9 C10 C11 O6 -0.2(7) . .
C15 C10 C11 C12 -0.1(7) . .
C9 C10 C11 C12 177.3(4) . .
O6 C11 C12 C13 177.7(4) . .
C10 C11 C12 C13 0.0(7) . .
C11 C12 C13 C14 -0.2(8) . .
C11 C12 C13 C16 -179.6(5) . .
C12 C13 C14 C15 0.6(8) . .
C16 C13 C14 C15 179.9(5) . .
C13 C14 C15 C10 -0.7(8) . .
C11 C10 C15 C14 0.5(7) . .
C9 C10 C15 C14 -176.9(5) . .
