#------------------------------------------------------------------------------
#$Date: 2016-03-25 15:27:26 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179920 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/15/7021571.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7021571
loop_
_publ_author_name
'Chen, Yanmei'
'Chen, Wenqian'
'Ju, Zhenghua'
'Gao, Qian'
'Lei, Tao'
'Liu, Wei'
'Li, Yahong'
'Gao, Dandan'
'Li, Wu'
_publ_section_title
;
 Synthesis, structures and luminescent properties of a series of novel
 Sr(II)-Ln(III) (Ln = Eu, Gd, Tb) coordination polymers.
;
_journal_issue                   29
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10495
_journal_page_last               10502
_journal_paper_doi               10.1039/c3dt51184g
_journal_volume                  42
_journal_year                    2013
_chemical_formula_moiety         'C21 H19 Eu N3 O17 Sr, C3 H5 N2, H2 O'
_chemical_formula_sum            'C24 H26 Eu N5 O18 Sr'
_chemical_formula_weight         912.08
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 107.095(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   15.8421(13)
_cell_length_b                   9.9106(8)
_cell_length_c                   20.5688(18)
_cell_measurement_reflns_used    4609
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.639
_cell_measurement_theta_min      2.301
_cell_volume                     3086.7(4)
_computing_cell_refinement       'SAINT (Bruker, 2005)'
_computing_data_collection       'APEX-II (Bruker, 2005)'
_computing_data_reduction        'SAINT (Bruker, 2005)'
_computing_molecular_graphics
'SHELXTL (Sheldrick, 2008) and DIAMOND (Brandenburg, 1999)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker APEXII CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0384
_diffrn_reflns_av_sigmaI/netI    0.0483
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            20844
_diffrn_reflns_theta_full        28.30
_diffrn_reflns_theta_max         28.30
_diffrn_reflns_theta_min         2.30
_exptl_absorpt_coefficient_mu    3.833
_exptl_absorpt_correction_T_max  0.4475
_exptl_absorpt_correction_T_min  0.3644
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 2005)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.963
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       polyhedron
_exptl_crystal_F_000             1800
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.29
_exptl_crystal_size_min          0.25
_refine_diff_density_max         0.615
_refine_diff_density_min         -0.491
_refine_diff_density_rms         0.110
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.996
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     442
_refine_ls_number_reflns         7625
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.996
_refine_ls_R_factor_all          0.0543
_refine_ls_R_factor_gt           0.0294
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0240P)²+0.6449P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0554
_refine_ls_wR_factor_ref         0.0632
_reflns_number_gt                5614
_reflns_number_total             7625
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt51184g.txt
_cod_data_source_block           CCDC899491
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7021571
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.245345(10) 0.362471(15) 0.005973(8) 0.01819(5) Uani 1 1 d .
O1 O 0.28552(14) 0.1881(2) 0.09373(12) 0.0257(5) Uani 1 1 d .
N1 N 0.11967(16) 0.2519(3) 0.03936(13) 0.0208(6) Uani 1 1 d .
C1 C 0.1366(2) 0.1580(3) 0.08816(17) 0.0251(7) Uani 1 1 d .
Sr2 Sr 0.394418(19) 0.12714(3) 0.282733(15) 0.02480(8) Uani 1 1 d .
O2 O 0.25555(15) 0.0722(2) 0.17764(12) 0.0288(5) Uani 1 1 d .
N2 N 0.35245(17) 0.2295(2) -0.03857(13) 0.0215(6) Uani 1 1 d .
C2 C 0.0698(2) 0.0893(4) 0.1046(2) 0.0436(11) Uani 1 1 d .
H2 H 0.0827 0.0241 0.1386 0.052 Uiso 1 1 calc R
O3 O 0.09601(15) 0.4439(2) -0.05179(12) 0.0284(5) Uani 1 1 d .
N3 N 0.25717(16) 0.6156(2) 0.00825(13) 0.0199(6) Uani 1 1 d .
C3 C -0.0165(3) 0.1194(5) 0.0694(3) 0.0580(14) Uani 1 1 d .
H3 H -0.0626 0.0736 0.0790 0.070 Uiso 1 1 calc R
N4 N 0.0679(2) 0.9488(3) 0.67334(16) 0.0391(8) Uani 1 1 d .
H4A H 0.0634 1.0081 0.6420 0.047 Uiso 1 1 calc R
C4 C -0.0337(2) 0.2177(4) 0.0202(2) 0.0479(12) Uani 1 1 d .
H4 H -0.0916 0.2406 -0.0032 0.057 Uiso 1 1 calc R
O4 O -0.04912(15) 0.4085(3) -0.08794(12) 0.0342(6) Uani 1 1 d .
O5 O 0.18160(14) 0.1919(2) -0.08054(12) 0.0287(6) Uani 1 1 d .
C5 C 0.0361(2) 0.2819(3) 0.00589(18) 0.0264(8) Uani 1 1 d .
N5 N 0.1220(2) 0.8040(3) 0.75078(16) 0.0388(8) Uani 1 1 d .
H5 H 0.1593 0.7532 0.7790 0.047 Uiso 1 1 calc R
C6 C 0.2337(2) 0.1364(3) 0.12334(16) 0.0211(7) Uani 1 1 d .
O6 O 0.18941(17) 0.0783(3) -0.17202(13) 0.0428(7) Uani 1 1 d .
O7 O 0.40144(15) 0.4034(2) 0.06146(12) 0.0302(6) Uani 1 1 d .
C7 C 0.0256(2) 0.3872(3) -0.04900(16) 0.0245(8) Uani 1 1 d .
C8 C 0.3227(2) 0.1487(3) -0.09253(17) 0.0235(7) Uani 1 1 d .
O8 O 0.54403(15) 0.3722(3) 0.07150(15) 0.0498(8) Uani 1 1 d .
O9 O 0.25636(15) 0.4678(2) -0.09792(11) 0.0272(5) Uani 1 1 d .
C9 C 0.3786(2) 0.0853(4) -0.1235(2) 0.0349(9) Uani 1 1 d .
H9 H 0.3563 0.0293 -0.1609 0.042 Uiso 1 1 calc R
O10 O 0.25097(16) 0.6476(2) -0.16357(12) 0.0319(6) Uani 1 1 d .
C10 C 0.4688(3) 0.1073(4) -0.0972(2) 0.0491(12) Uani 1 1 d .
H10 H 0.5084 0.0645 -0.1160 0.059 Uiso 1 1 calc R
O11 O 0.24718(15) 0.4740(2) 0.11347(11) 0.0267(5) Uani 1 1 d .
C11 C 0.4985(2) 0.1932(4) -0.0432(2) 0.0448(11) Uani 1 1 d .
H11 H 0.5585 0.2112 -0.0258 0.054 Uiso 1 1 calc R
C12 C 0.4391(2) 0.2532(3) -0.01433(18) 0.0265(8) Uani 1 1 d .
O12 O 0.24394(15) 0.6575(2) 0.17508(12) 0.0315(6) Uani 1 1 d .
C13 C 0.2236(2) 0.1377(3) -0.11790(17) 0.0258(7) Uani 1 1 d .
O13 O 0.45309(17) 0.1568(3) 0.18132(14) 0.0595(9) Uani 1 1 d .
H13A H 0.5039 0.1924 0.1965 0.089 Uiso 1 1 d R
H13B H 0.4082 0.1491 0.1466 0.089 Uiso 1 1 d R
O14 O 0.33111(17) 0.3710(2) 0.24442(14) 0.0444(7) Uani 1 1 d .
H14A H 0.2935 0.4145 0.2584 0.053 Uiso 1 1 d R
H14B H 0.3129 0.4208 0.2094 0.053 Uiso 1 1 d R
C14 C 0.4644(2) 0.3509(3) 0.04439(18) 0.0277(8) Uani 1 1 d .
C15 C 0.2593(2) 0.6821(3) -0.04787(17) 0.0211(7) Uani 1 1 d .
O15 O 0.50840(16) 0.3184(3) 0.33177(14) 0.0436(7) Uani 1 1 d .
H15A H 0.5128 0.3810 0.3047 0.065 Uiso 1 1 d R
H15B H 0.5607 0.3240 0.3584 0.065 Uiso 1 1 d R
O16 O 0.55083(16) 0.0076(3) 0.30762(14) 0.0472(8) Uani 1 1 d .
H16A H 0.5972 0.0367 0.2996 0.057 Uiso 1 1 d R
H16B H 0.5722 0.0241 0.3498 0.057 Uiso 1 1 d R
C16 C 0.2648(2) 0.8207(3) -0.04925(19) 0.0311(8) Uani 1 1 d .
H16 H 0.2645 0.8656 -0.0890 0.037 Uiso 1 1 calc R
C17 C 0.2707(3) 0.8916(3) 0.0098(2) 0.0366(9) Uani 1 1 d .
H17 H 0.2762 0.9851 0.0104 0.044 Uiso 1 1 calc R
O17 O 0.3677(2) -0.1340(3) 0.28292(19) 0.0674(10) Uani 1 1 d .
H17A H 0.3519 -0.1709 0.2439 0.101 Uiso 1 1 d R
H17B H 0.3369 -0.1692 0.3061 0.101 Uiso 1 1 d R
O18 O 0.13279(18) 0.2817(3) 0.72318(14) 0.0519(8) Uani 1 1 d .
H18A H 0.1396 0.2248 0.7552 0.062 Uiso 1 1 d R
H18B H 0.1529 0.2318 0.6976 0.062 Uiso 1 1 d R
C18 C 0.2685(2) 0.8238(3) 0.06742(19) 0.0301(8) Uani 1 1 d .
H18 H 0.2723 0.8703 0.1074 0.036 Uiso 1 1 calc R
C19 C 0.2603(2) 0.6845(3) 0.06477(17) 0.0213(7) Uani 1 1 d .
C20 C 0.2557(2) 0.5934(3) -0.10808(16) 0.0224(7) Uani 1 1 d .
C21 C 0.2497(2) 0.5998(3) 0.12292(16) 0.0212(7) Uani 1 1 d .
C22 C 0.1412(3) 0.8888(4) 0.70817(19) 0.0346(9) Uani 1 1 d .
H22 H 0.1970 0.9038 0.7035 0.042 Uiso 1 1 calc R
C23 C 0.0338(3) 0.8089(5) 0.7433(2) 0.0533(12) Uani 1 1 d .
H23 H 0.0030 0.7583 0.7669 0.064 Uiso 1 1 calc R
C24 C 0.0005(3) 0.9015(5) 0.6952(3) 0.0547(12) Uani 1 1 d .
H24 H -0.0582 0.9286 0.6795 0.066 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sr Sr -1.5307 3.2498 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O9 Eu1 O7 90.87(8) . .
O9 Eu1 O1 151.97(8) . .
O7 Eu1 O1 76.31(8) . .
O9 Eu1 O5 77.18(8) . .
O7 Eu1 O5 126.97(8) . .
O1 Eu1 O5 90.64(8) . .
O9 Eu1 O3 74.98(8) . .
O7 Eu1 O3 151.09(8) . .
O1 Eu1 O3 126.55(8) . .
O5 Eu1 O3 75.03(8) . .
O9 Eu1 O11 127.68(7) . .
O7 Eu1 O11 76.24(8) . .
O1 Eu1 O11 73.90(7) . .
O5 Eu1 O11 148.85(8) . .
O3 Eu1 O11 92.42(8) . .
O9 Eu1 N3 64.13(8) . .
O7 Eu1 N3 76.42(8) . .
O1 Eu1 N3 133.59(8) . .
O5 Eu1 N3 135.65(8) . .
O3 Eu1 N3 74.72(8) . .
O11 Eu1 N3 63.56(8) . .
O9 Eu1 N2 71.06(8) . .
O7 Eu1 N2 63.79(8) . .
O1 Eu1 N2 80.91(8) . .
O5 Eu1 N2 63.46(8) . .
O3 Eu1 N2 130.71(8) . .
O11 Eu1 N2 136.72(8) . .
N3 Eu1 N2 118.25(8) . .
O9 Eu1 N1 133.49(8) . .
O7 Eu1 N1 135.63(8) . .
O1 Eu1 N1 63.23(8) . .
O5 Eu1 N1 73.12(8) . .
O3 Eu1 N1 63.33(8) . .
O11 Eu1 N1 75.77(8) . .
N3 Eu1 N1 119.06(8) . .
N2 Eu1 N1 122.51(8) . .
C6 O1 Eu1 125.2(2) . .
C5 N1 C1 119.5(3) . .
C5 N1 Eu1 120.2(2) . .
C1 N1 Eu1 120.2(2) . .
N1 C1 C2 121.9(3) . .
N1 C1 C6 114.2(3) . .
C2 C1 C6 124.0(3) . .
O13 Sr2 O4 140.05(8) . 4_666
O13 Sr2 O12 143.98(8) . 2_545
O4 Sr2 O12 75.02(7) 4_666 2_545
O13 Sr2 O15 81.62(10) . .
O4 Sr2 O15 73.05(8) 4_666 .
O12 Sr2 O15 110.03(8) 2_545 .
O13 Sr2 O17 102.36(11) . .
O4 Sr2 O17 82.54(10) 4_666 .
O12 Sr2 O17 87.79(9) 2_545 .
O15 Sr2 O17 144.14(9) . .
O13 Sr2 O14 81.24(9) . .
O4 Sr2 O14 114.82(8) 4_666 .
O12 Sr2 O14 73.20(8) 2_545 .
O15 Sr2 O14 67.06(8) . .
O17 Sr2 O14 148.70(9) . .
O13 Sr2 O2 76.70(8) . .
O4 Sr2 O2 140.34(7) 4_666 .
O12 Sr2 O2 73.55(7) 2_545 .
O15 Sr2 O2 141.24(8) . .
O17 Sr2 O2 72.71(9) . .
O14 Sr2 O2 78.07(7) . .
O13 Sr2 O16 70.36(9) . .
O4 Sr2 O16 73.63(8) 4_666 .
O12 Sr2 O16 144.77(8) 2_545 .
O15 Sr2 O16 75.46(8) . .
O17 Sr2 O16 72.64(9) . .
O14 Sr2 O16 135.64(9) . .
O2 Sr2 O16 124.72(8) . .
O13 Sr2 C21 160.73(8) . 2_545
O4 Sr2 C21 59.21(7) 4_666 2_545
O12 Sr2 C21 18.14(7) 2_545 2_545
O15 Sr2 C21 109.91(8) . 2_545
O17 Sr2 C21 77.62(9) . 2_545
O14 Sr2 C21 89.05(8) . 2_545
O2 Sr2 C21 85.05(7) . 2_545
O16 Sr2 C21 126.64(8) . 2_545
O13 Sr2 H13A 16.4 . .
O4 Sr2 H13A 125.2 4_666 .
O12 Sr2 H13A 153.4 2_545 .
O15 Sr2 H13A 66.6 . .
O17 Sr2 H13A 110.3 . .
O14 Sr2 H13A 81.7 . .
O2 Sr2 H13A 92.8 . .
O16 Sr2 H13A 61.6 . .
C21 Sr2 H13A 170.8 2_545 .
O13 Sr2 H13B 16.5 . .
O4 Sr2 H13B 156.1 4_666 .
O12 Sr2 H13B 128.9 2_545 .
O15 Sr2 H13B 94.5 . .
O17 Sr2 H13B 97.7 . .
O14 Sr2 H13B 76.8 . .
O2 Sr2 H13B 60.3 . .
O16 Sr2 H13B 83.6 . .
C21 Sr2 H13B 144.4 2_545 .
H13A Sr2 H13B 32.6 . .
O13 Sr2 H16B 83.9 . .
O4 Sr2 H16B 58.1 4_666 .
O12 Sr2 H16B 132.1 2_545 .
O15 Sr2 H16B 67.1 . .
O17 Sr2 H16B 77.8 . .
O14 Sr2 H16B 133.3 . .
O2 Sr2 H16B 139.9 . .
O16 Sr2 H16B 16.6 . .
C21 Sr2 H16B 114.5 2_545 .
H13A Sr2 H16B 72.6 . .
H13B Sr2 H16B 98.5 . .
C6 O2 Sr2 125.0(2) . .
C12 N2 C8 119.2(3) . .
C12 N2 Eu1 120.0(2) . .
C8 N2 Eu1 120.2(2) . .
C3 C2 C1 118.5(4) . .
C3 C2 H2 120.7 . .
C1 C2 H2 120.7 . .
C7 O3 Eu1 124.7(2) . .
C19 N3 C15 119.7(3) . .
C19 N3 Eu1 120.6(2) . .
C15 N3 Eu1 119.7(2) . .
C4 C3 C2 119.5(4) . .
C4 C3 H3 120.2 . .
C2 C3 H3 120.2 . .
C22 N4 C24 108.5(3) . .
C22 N4 H4A 125.7 . .
C24 N4 H4A 125.7 . .
C3 C4 C5 119.1(3) . .
C3 C4 H4 120.5 . .
C5 C4 H4 120.5 . .
C7 O4 Sr2 128.5(2) . 4_565
C13 O5 Eu1 123.6(2) . .
N1 C5 C4 121.5(3) . .
N1 C5 C7 114.5(3) . .
C4 C5 C7 124.0(3) . .
C22 N5 C23 109.5(3) . .
C22 N5 H5 125.3 . .
C23 N5 H5 125.3 . .
O2 C6 O1 126.2(3) . .
O2 C6 C1 118.6(3) . .
O1 C6 C1 115.2(3) . .
C14 O7 Eu1 125.3(2) . .
O4 C7 O3 125.7(3) . .
O4 C7 C5 118.4(3) . .
O3 C7 C5 115.9(3) . .
N2 C8 C9 122.5(3) . .
N2 C8 C13 114.1(3) . .
C9 C8 C13 123.4(3) . .
C20 O9 Eu1 124.8(2) . .
C8 C9 C10 118.3(3) . .
C8 C9 H9 120.8 . .
C10 C9 H9 120.8 . .
C11 C10 C9 118.8(4) . .
C11 C10 H10 120.6 . .
C9 C10 H10 120.6 . .
C21 O11 Eu1 125.0(2) . .
C10 C11 C12 120.0(4) . .
C10 C11 H11 120.0 . .
C12 C11 H11 120.0 . .
N2 C12 C11 121.2(3) . .
N2 C12 C14 114.4(3) . .
C11 C12 C14 124.4(3) . .
C21 O12 Sr2 121.2(2) . 2
O6 C13 O5 125.2(3) . .
O6 C13 C8 118.9(3) . .
O5 C13 C8 115.9(3) . .
Sr2 O13 H13A 106.4 . .
Sr2 O13 H13B 105.2 . .
H13A O13 H13B 144.5 . .
Sr2 O14 H14A 127.1 . .
Sr2 O14 H14B 141.9 . .
H14A O14 H14B 83.9 . .
O8 C14 O7 126.0(3) . .
O8 C14 C12 117.8(3) . .
O7 C14 C12 116.2(3) . .
N3 C15 C16 121.8(3) . .
N3 C15 C20 114.7(3) . .
C16 C15 C20 123.5(3) . .
Sr2 O15 H15A 117.3 . .
Sr2 O15 H15B 136.9 . .
H15A O15 H15B 97.0 . .
Sr2 O16 H16A 128.5 . .
Sr2 O16 H16B 100.4 . .
H16A O16 H16B 91.5 . .
C15 C16 C17 118.5(3) . .
C15 C16 H16 120.7 . .
C17 C16 H16 120.7 . .
C18 C17 C16 119.8(3) . .
C18 C17 H17 120.1 . .
C16 C17 H17 120.1 . .
Sr2 O17 H17A 115.2 . .
Sr2 O17 H17B 121.7 . .
H17A O17 H17B 107.2 . .
H18A O18 H18B 96.3 . .
C17 C18 C19 118.7(3) . .
C17 C18 H18 120.7 . .
C19 C18 H18 120.7 . .
N3 C19 C18 121.5(3) . .
N3 C19 C21 114.9(3) . .
C18 C19 C21 123.6(3) . .
O10 C20 O9 125.0(3) . .
O10 C20 C15 118.7(3) . .
O9 C20 C15 116.3(3) . .
O12 C21 O11 125.5(3) . .
O12 C21 C19 118.8(3) . .
O11 C21 C19 115.7(3) . .
O12 C21 Sr2 40.67(16) . 2
O11 C21 Sr2 99.8(2) . 2
C19 C21 Sr2 130.9(2) . 2
N5 C22 N4 108.2(3) . .
N5 C22 H22 125.9 . .
N4 C22 H22 125.9 . .
C24 C23 N5 106.0(4) . .
C24 C23 H23 127.0 . .
N5 C23 H23 127.0 . .
C23 C24 N4 107.7(4) . .
C23 C24 H24 126.2 . .
N4 C24 H24 126.2 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O9 2.430(2) .
Eu1 O7 2.434(2) .
Eu1 O1 2.444(2) .
Eu1 O5 2.447(2) .
Eu1 O3 2.451(2) .
Eu1 O11 2.465(2) .
Eu1 N3 2.515(2) .
Eu1 N2 2.524(3) .
Eu1 N1 2.538(3) .
O1 C6 1.266(4) .
N1 C5 1.334(4) .
N1 C1 1.337(4) .
C1 C2 1.381(5) .
C1 C6 1.510(4) .
Sr2 O13 2.538(3) .
Sr2 O4 2.569(2) 4_666
Sr2 O12 2.601(2) 2_545
Sr2 O15 2.607(2) .
Sr2 O17 2.623(3) .
Sr2 O14 2.647(2) .
Sr2 O2 2.648(2) .
Sr2 O16 2.657(2) .
Sr2 C21 3.415(3) 2_545
Sr2 H13A 2.8953 .
Sr2 H13B 2.8802 .
Sr2 H16B 2.9318 .
O2 C6 1.242(4) .
N2 C12 1.336(4) .
N2 C8 1.337(4) .
C2 C3 1.378(5) .
C2 H2 0.9300 .
O3 C7 1.265(4) .
N3 C19 1.336(4) .
N3 C15 1.338(4) .
C3 C4 1.374(5) .
C3 H3 0.9300 .
N4 C22 1.314(4) .
N4 C24 1.357(5) .
N4 H4A 0.8600 .
C4 C5 1.380(5) .
C4 H4 0.9300 .
O4 C7 1.237(4) .
O4 Sr2 2.569(2) 4_565
O5 C13 1.274(4) .
C5 C7 1.510(5) .
N5 C22 1.313(5) .
N5 C23 1.360(5) .
N5 H5 0.8600 .
O6 C13 1.235(4) .
O7 C14 1.263(4) .
C8 C9 1.384(5) .
C8 C13 1.505(5) .
O8 C14 1.238(4) .
O9 C20 1.262(4) .
C9 C10 1.389(5) .
C9 H9 0.9300 .
O10 C20 1.244(4) .
C10 C11 1.369(5) .
C10 H10 0.9300 .
O11 C21 1.261(4) .
C11 C12 1.385(5) .
C11 H11 0.9300 .
C12 C14 1.507(5) .
O12 C21 1.243(4) .
O12 Sr2 2.601(2) 2
O13 H13A 0.8500 .
O13 H13B 0.8500 .
O14 H14A 0.8500 .
O14 H14B 0.8500 .
C15 C16 1.377(4) .
C15 C20 1.506(5) .
O15 H15A 0.8502 .
O15 H15B 0.8500 .
O16 H16A 0.8500 .
O16 H16B 0.8502 .
C16 C17 1.382(5) .
C16 H16 0.9300 .
C17 C18 1.372(5) .
C17 H17 0.9300 .
O17 H17A 0.8500 .
O17 H17B 0.8500 .
O18 H18A 0.8500 .
O18 H18B 0.8500 .
C18 C19 1.386(4) .
C18 H18 0.9300 .
C19 C21 1.510(4) .
C21 Sr2 3.415(3) 2
C22 H22 0.9300 .
C23 C24 1.340(6) .
C23 H23 0.9300 .
C24 H24 0.9300 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N4 H4A O8 0.86 1.83 2.685(4) 174.9 4_576
N5 H5 O10 0.86 1.89 2.750(4) 173.6 1_556
O13 H13A O18 0.85 1.97 2.789(4) 161.7 4_665
O13 H13B O1 0.85 1.97 2.753(3) 153.3 .
O14 H14A O2 0.85 2.32 3.119(4) 156.6 2
O14 H14A O17 0.85 2.49 3.032(4) 122.5 2
O14 H14B O11 0.85 2.01 2.821(3) 158.7 .
O14 H14B O12 0.85 2.60 3.293(3) 140.0 .
O15 H15B O5 0.85 1.96 2.808(3) 171.6 4_666
O15 H15B O6 0.85 2.50 3.067(4) 125.3 4_666
O16 H16A O18 0.85 2.56 3.223(4) 135.9 4_665
O16 H16B O3 0.85 1.97 2.809(4) 167.9 4_666
O17 H17A O12 0.85 2.53 3.237(4) 141.3 1_545
O17 H17B O14 0.85 2.59 3.032(4) 113.8 2_545
O18 H18A O6 0.85 2.07 2.894(4) 164.1 1_556
O18 H18B O10 0.85 2.03 2.826(3) 155.2 2_545
C18 H18 O2 0.93 2.53 3.394(4) 155.2 1_565
C22 H22 O9 0.93 2.57 3.249(4) 130.2 2
C23 H23 O17 0.93 2.58 3.444(5) 155.5 4_566
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O9 Eu1 O1 C6 -144.4(2) . .
O7 Eu1 O1 C6 150.7(3) . .
O5 Eu1 O1 C6 -81.3(2) . .
O3 Eu1 O1 C6 -9.5(3) . .
O11 Eu1 O1 C6 71.3(2) . .
N3 Eu1 O1 C6 95.1(3) . .
N2 Eu1 O1 C6 -144.2(3) . .
N1 Eu1 O1 C6 -10.6(2) . .
O9 Eu1 N1 C5 -22.7(3) . .
O7 Eu1 N1 C5 158.6(2) . .
O1 Eu1 N1 C5 -174.9(3) . .
O5 Eu1 N1 C5 -75.3(2) . .
O3 Eu1 N1 C5 6.1(2) . .
O11 Eu1 N1 C5 106.2(2) . .
N3 Eu1 N1 C5 58.0(3) . .
N2 Eu1 N1 C5 -117.0(2) . .
O9 Eu1 N1 C1 153.8(2) . .
O7 Eu1 N1 C1 -24.9(3) . .
O1 Eu1 N1 C1 1.6(2) . .
O5 Eu1 N1 C1 101.2(2) . .
O3 Eu1 N1 C1 -177.4(3) . .
O11 Eu1 N1 C1 -77.3(2) . .
N3 Eu1 N1 C1 -125.5(2) . .
N2 Eu1 N1 C1 59.5(3) . .
C5 N1 C1 C2 0.8(5) . .
Eu1 N1 C1 C2 -175.7(3) . .
C5 N1 C1 C6 -178.4(3) . .
Eu1 N1 C1 C6 5.1(4) . .
O13 Sr2 O2 C6 -41.9(3) . .
O4 Sr2 O2 C6 156.5(2) 4_666 .
O12 Sr2 O2 C6 117.6(3) 2_545 .
O15 Sr2 O2 C6 15.9(3) . .
O17 Sr2 O2 C6 -149.6(3) . .
O14 Sr2 O2 C6 41.8(3) . .
O16 Sr2 O2 C6 -96.2(3) . .
C21 Sr2 O2 C6 131.9(3) 2_545 .
O9 Eu1 N2 C12 95.8(2) . .
O7 Eu1 N2 C12 -4.9(2) . .
O1 Eu1 N2 C12 -84.1(2) . .
O5 Eu1 N2 C12 -179.4(3) . .
O3 Eu1 N2 C12 144.8(2) . .
O11 Eu1 N2 C12 -29.5(3) . .
N3 Eu1 N2 C12 50.9(3) . .
N1 Eu1 N2 C12 -134.1(2) . .
O9 Eu1 N2 C8 -75.1(2) . .
O7 Eu1 N2 C8 -175.9(3) . .
O1 Eu1 N2 C8 105.0(2) . .
O5 Eu1 N2 C8 9.7(2) . .
O3 Eu1 N2 C8 -26.1(3) . .
O11 Eu1 N2 C8 159.6(2) . .
N3 Eu1 N2 C8 -120.0(2) . .
N1 Eu1 N2 C8 55.0(3) . .
N1 C1 C2 C3 -0.1(6) . .
C6 C1 C2 C3 179.0(4) . .
O9 Eu1 O3 C7 147.6(3) . .
O7 Eu1 O3 C7 -149.3(2) . .
O1 Eu1 O3 C7 -12.2(3) . .
O5 Eu1 O3 C7 67.2(3) . .
O11 Eu1 O3 C7 -83.9(3) . .
N3 Eu1 O3 C7 -145.6(3) . .
N2 Eu1 O3 C7 100.0(3) . .
N1 Eu1 O3 C7 -11.1(2) . .
O9 Eu1 N3 C19 -177.6(2) . .
O7 Eu1 N3 C19 -79.9(2) . .
O1 Eu1 N3 C19 -24.4(3) . .
O5 Eu1 N3 C19 150.4(2) . .
O3 Eu1 N3 C19 101.9(2) . .
O11 Eu1 N3 C19 1.3(2) . .
N2 Eu1 N3 C19 -129.7(2) . .
N1 Eu1 N3 C19 55.1(2) . .
O9 Eu1 N3 C15 3.1(2) . .
O7 Eu1 N3 C15 100.8(2) . .
O1 Eu1 N3 C15 156.4(2) . .
O5 Eu1 N3 C15 -28.8(3) . .
O3 Eu1 N3 C15 -77.3(2) . .
O11 Eu1 N3 C15 -178.0(3) . .
N2 Eu1 N3 C15 51.0(2) . .
N1 Eu1 N3 C15 -124.2(2) . .
C1 C2 C3 C4 -1.1(7) . .
C2 C3 C4 C5 1.5(7) . .
O9 Eu1 O5 C13 59.5(3) . .
O7 Eu1 O5 C13 -21.7(3) . .
O1 Eu1 O5 C13 -95.0(3) . .
O3 Eu1 O5 C13 137.2(3) . .
O11 Eu1 O5 C13 -153.8(2) . .
N3 Eu1 O5 C13 88.8(3) . .
N2 Eu1 O5 C13 -15.5(2) . .
N1 Eu1 O5 C13 -156.7(3) . .
C1 N1 C5 C4 -0.4(5) . .
Eu1 N1 C5 C4 176.1(3) . .
C1 N1 C5 C7 -178.7(3) . .
Eu1 N1 C5 C7 -2.2(4) . .
C3 C4 C5 N1 -0.8(7) . .
C3 C4 C5 C7 177.3(4) . .
Sr2 O2 C6 O1 36.6(5) . .
Sr2 O2 C6 C1 -142.7(2) . .
Eu1 O1 C6 O2 -162.3(2) . .
Eu1 O1 C6 C1 17.0(4) . .
N1 C1 C6 O2 165.7(3) . .
C2 C1 C6 O2 -13.5(5) . .
N1 C1 C6 O1 -13.7(4) . .
C2 C1 C6 O1 167.2(3) . .
O9 Eu1 O7 C14 -65.2(3) . .
O1 Eu1 O7 C14 89.7(3) . .
O5 Eu1 O7 C14 9.4(3) . .
O3 Eu1 O7 C14 -124.6(3) . .
O11 Eu1 O7 C14 166.1(3) . .
N3 Eu1 O7 C14 -128.3(3) . .
N2 Eu1 O7 C14 3.2(3) . .
N1 Eu1 O7 C14 113.9(3) . .
Sr2 O4 C7 O3 61.2(4) 4_565 .
Sr2 O4 C7 C5 -116.9(3) 4_565 .
Eu1 O3 C7 O4 -163.9(2) . .
Eu1 O3 C7 C5 14.3(4) . .
N1 C5 C7 O4 171.1(3) . .
C4 C5 C7 O4 -7.2(5) . .
N1 C5 C7 O3 -7.2(4) . .
C4 C5 C7 O3 174.5(4) . .
C12 N2 C8 C9 1.7(5) . .
Eu1 N2 C8 C9 172.7(3) . .
C12 N2 C8 C13 -176.0(3) . .
Eu1 N2 C8 C13 -5.0(4) . .
O7 Eu1 O9 C20 -80.4(2) . .
O1 Eu1 O9 C20 -142.0(2) . .
O5 Eu1 O9 C20 151.8(3) . .
O3 Eu1 O9 C20 74.1(2) . .
O11 Eu1 O9 C20 -7.1(3) . .
N3 Eu1 O9 C20 -5.9(2) . .
N2 Eu1 O9 C20 -142.2(3) . .
N1 Eu1 O9 C20 100.6(3) . .
N2 C8 C9 C10 -0.2(6) . .
C13 C8 C9 C10 177.3(4) . .
C8 C9 C10 C11 -1.6(6) . .
O9 Eu1 O11 C21 3.8(3) . .
O7 Eu1 O11 C21 84.0(2) . .
O1 Eu1 O11 C21 163.5(3) . .
O5 Eu1 O11 C21 -133.6(2) . .
O3 Eu1 O11 C21 -69.0(2) . .
N3 Eu1 O11 C21 2.6(2) . .
N2 Eu1 O11 C21 106.6(2) . .
N1 Eu1 O11 C21 -130.7(3) . .
C9 C10 C11 C12 1.9(7) . .
C8 N2 C12 C11 -1.5(5) . .
Eu1 N2 C12 C11 -172.5(3) . .
C8 N2 C12 C14 177.2(3) . .
Eu1 N2 C12 C14 6.2(4) . .
C10 C11 C12 N2 -0.4(6) . .
C10 C11 C12 C14 -178.9(4) . .
Eu1 O5 C13 O6 -161.1(3) . .
Eu1 O5 C13 C8 18.9(4) . .
N2 C8 C13 O6 171.7(3) . .
C9 C8 C13 O6 -6.0(5) . .
N2 C8 C13 O5 -8.4(4) . .
C9 C8 C13 O5 174.0(3) . .
Eu1 O7 C14 O8 178.9(3) . .
Eu1 O7 C14 C12 -1.3(4) . .
N2 C12 C14 O8 176.5(3) . .
C11 C12 C14 O8 -4.9(6) . .
N2 C12 C14 O7 -3.3(5) . .
C11 C12 C14 O7 175.3(4) . .
C19 N3 C15 C16 0.0(5) . .
Eu1 N3 C15 C16 179.3(2) . .
C19 N3 C15 C20 179.8(3) . .
Eu1 N3 C15 C20 -1.0(3) . .
N3 C15 C16 C17 1.9(5) . .
C20 C15 C16 C17 -177.9(3) . .
C15 C16 C17 C18 -1.9(5) . .
C16 C17 C18 C19 0.1(5) . .
C15 N3 C19 C18 -1.9(4) . .
Eu1 N3 C19 C18 178.8(2) . .
C15 N3 C19 C21 175.1(3) . .
Eu1 N3 C19 C21 -4.2(3) . .
C17 C18 C19 N3 1.9(5) . .
C17 C18 C19 C21 -174.9(3) . .
Eu1 O9 C20 O10 -171.2(2) . .
Eu1 O9 C20 C15 7.6(4) . .
N3 C15 C20 O10 174.9(3) . .
C16 C15 C20 O10 -5.4(5) . .
N3 C15 C20 O9 -4.0(4) . .
C16 C15 C20 O9 175.7(3) . .
Sr2 O12 C21 O11 -59.3(4) 2 .
Sr2 O12 C21 C19 120.4(3) 2 .
Eu1 O11 C21 O12 174.2(2) . .
Eu1 O11 C21 C19 -5.5(4) . .
Eu1 O11 C21 Sr2 139.58(14) . 2
N3 C19 C21 O12 -173.6(3) . .
C18 C19 C21 O12 3.3(5) . .
N3 C19 C21 O11 6.1(4) . .
C18 C19 C21 O11 -176.9(3) . .
N3 C19 C21 Sr2 -125.6(3) . 2
C18 C19 C21 Sr2 51.3(4) . 2
C23 N5 C22 N4 0.1(5) . .
C24 N4 C22 N5 0.7(5) . .
C22 N5 C23 C24 -0.9(5) . .
N5 C23 C24 N4 1.3(5) . .
C22 N4 C24 C23 -1.2(5) . .
