#------------------------------------------------------------------------------
#$Date: 2016-03-25 15:43:56 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179933 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/28/7022877.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7022877
loop_
_publ_author_name
'Johnson, Magnus T.'
'Džolić, Zoran'
'Cetina, Mario'
'Lahtinen, Manu'
'Ahlquist, Mårten S G'
'Rissanen, Kari'
'Öhrström, Lars'
'Wendt, Ola F.'
_publ_section_title
;
 Preparation of potentially porous, chiral organometallic materials
 through spontaneous resolution of pincer palladium conformers.
;
_journal_issue                   23
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8484
_journal_page_last               8491
_journal_paper_doi               10.1039/c3dt50190f
_journal_volume                  42
_journal_year                    2013
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C24 H43 Cl P2 Pd'
_chemical_formula_sum            'C24 H43 Cl P2 Pd'
_chemical_formula_weight         535.37
_chemical_melting_point          xxx:xxx
_chemical_name_systematic        ?
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2010-09-24T20:57:39-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 103.6560(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.7371(2)
_cell_length_b                   14.9785(2)
_cell_length_c                   15.6887(2)
_cell_measurement_reflns_used    8343
_cell_measurement_temperature    123.0(1)
_cell_measurement_theta_max      30.999
_cell_measurement_theta_min      0.407
_cell_volume                     2680.17(7)
_computing_cell_refinement       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_collection       'Collect (Hooft, 1998)'
_computing_data_reduction
'HKL Denzo and Scalepack (Otwinowski & Minor 1997)'
_computing_molecular_graphics    'MERCURY (Macrae et al., 2006)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR2002 (Burla, 2003)'
_diffrn_ambient_temperature      123.0(1)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 9
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device       '95mm CCD camera on κ-goniostat'
_diffrn_measurement_device_type  'Bruker-Nonius Kappa Apex II Diffractometer'
_diffrn_measurement_method       'CCD rotation images, thick slices'
_diffrn_radiation_monochromator  'horizonally mounted graphite crystal'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0271
_diffrn_reflns_av_unetI/netI     0.0247
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            20988
_diffrn_reflns_theta_full        25
_diffrn_reflns_theta_max         25
_diffrn_reflns_theta_min         3.68
_diffrn_source                   'Enraf Nonius FR590'
_exptl_absorpt_coefficient_mu    0.919
_exptl_absorpt_correction_T_max  0.7462
_exptl_absorpt_correction_T_min  0.6506
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
Sheldrick, G. M. SADABS 2008/2; University of Göttingen: Göttingen,
Germany, 2008.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.327
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1120
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.30
_refine_diff_density_max         0.337
_refine_diff_density_min         -0.335
_refine_diff_density_rms         0.052
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.996
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     265
_refine_ls_number_reflns         4707
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.996
_refine_ls_R_factor_all          0.0235
_refine_ls_R_factor_gt           0.0195
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0202P)²+2.1122P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0475
_refine_ls_wR_factor_ref         0.0498
_reflns_number_gt                4257
_reflns_number_total             4707
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            c3dt50190f.txt
_cod_data_source_block           4m
_cod_depositor_comments
;
The following automatic conversions were performed:

'_diffrn_radiation_probe' value 'X-ray' changed to 'x-ray' according
to /home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary
named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7022877
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pd1 Pd 0.205405(12) 0.417519(8) 0.719341(8) 0.01227(5) Uani 1 1 d .
Cl1 Cl 0.16830(4) 0.28513(3) 0.79435(3) 0.02162(11) Uani 1 1 d .
P1 P 0.35253(4) 0.35959(3) 0.66134(3) 0.01445(10) Uani 1 1 d .
P2 P 0.06992(4) 0.50682(3) 0.76263(3) 0.01429(10) Uani 1 1 d .
C1 C 0.23000(17) 0.52723(11) 0.65108(11) 0.0157(4) Uani 1 1 d .
C2 C 0.32640(17) 0.53358(12) 0.61188(12) 0.0179(4) Uani 1 1 d .
C3 C 0.33613(19) 0.60588(13) 0.55783(12) 0.0224(4) Uani 1 1 d .
H3 H 0.4002 0.6087 0.5305 0.027 Uiso 1 1 calc R
C4 C 0.2537(2) 0.67325(13) 0.54369(13) 0.0248(4) Uani 1 1 d .
H4 H 0.261 0.722 0.5066 0.03 Uiso 1 1 calc R
C5 C 0.16045(19) 0.66986(12) 0.58355(12) 0.0234(4) Uani 1 1 d .
H5 H 0.1047 0.717 0.5746 0.028 Uiso 1 1 calc R
C6 C 0.14781(18) 0.59742(12) 0.63690(12) 0.0178(4) Uani 1 1 d .
C7 C 0.41901(17) 0.46195(12) 0.62988(13) 0.0198(4) Uani 1 1 d .
H7A H 0.4856 0.4809 0.6779 0.024 Uiso 1 1 calc R
H7B H 0.4488 0.451 0.5768 0.024 Uiso 1 1 calc R
C8 C 0.04395(18) 0.59324(12) 0.67750(13) 0.0209(4) Uani 1 1 d .
H8A H -0.0278 0.579 0.632 0.025 Uiso 1 1 calc R
H8B H 0.0326 0.6518 0.7036 0.025 Uiso 1 1 calc R
C9 C 0.29619(17) 0.29736(12) 0.55673(12) 0.0188(4) Uani 1 1 d .
C10 C 0.2112(2) 0.22467(14) 0.57138(14) 0.0286(5) Uani 1 1 d .
H10A H 0.173 0.1976 0.515 0.043 Uiso 1 1 calc R
H10B H 0.1516 0.2511 0.5981 0.043 Uiso 1 1 calc R
H10C H 0.2545 0.1787 0.6105 0.043 Uiso 1 1 calc R
C11 C 0.3916(2) 0.25658(14) 0.51673(13) 0.0287(5) Uani 1 1 d .
H11A H 0.4328 0.2096 0.5555 0.043 Uiso 1 1 calc R
H11B H 0.4474 0.3031 0.5099 0.043 Uiso 1 1 calc R
H11C H 0.3554 0.231 0.4592 0.043 Uiso 1 1 calc R
C12 C 0.2258(2) 0.36421(14) 0.49086(13) 0.0305(5) Uani 1 1 d .
H12A H 0.2787 0.41 0.4775 0.046 Uiso 1 1 calc R
H12B H 0.1661 0.3926 0.5161 0.046 Uiso 1 1 calc R
H12C H 0.1876 0.3328 0.4368 0.046 Uiso 1 1 calc R
C13 C 0.47547(18) 0.30036(13) 0.73831(13) 0.0233(4) Uani 1 1 d .
C14 C 0.4943(2) 0.35090(15) 0.82585(13) 0.0311(5) Uani 1 1 d .
H14A H 0.4221 0.349 0.8469 0.047 Uiso 1 1 calc R
H14B H 0.5148 0.4131 0.8172 0.047 Uiso 1 1 calc R
H14C H 0.5581 0.3227 0.8692 0.047 Uiso 1 1 calc R
C15 C 0.4417(2) 0.20341(14) 0.75261(15) 0.0320(5) Uani 1 1 d .
H15A H 0.5022 0.1764 0.7994 0.048 Uiso 1 1 calc R
H15B H 0.435 0.1695 0.6982 0.048 Uiso 1 1 calc R
H15C H 0.3664 0.2024 0.7694 0.048 Uiso 1 1 calc R
C16 C 0.59029(19) 0.30197(16) 0.70774(15) 0.0326(5) Uani 1 1 d .
H16A H 0.6115 0.3639 0.6985 0.049 Uiso 1 1 calc R
H16B H 0.58 0.2687 0.6526 0.049 Uiso 1 1 calc R
H16C H 0.6528 0.2743 0.7525 0.049 Uiso 1 1 calc R
C17 C -0.07932(17) 0.45959(12) 0.75795(12) 0.0193(4) Uani 1 1 d .
C18 C -0.17511(18) 0.53179(13) 0.74818(14) 0.0259(4) Uani 1 1 d .
H18A H -0.252 0.5031 0.7403 0.039 Uiso 1 1 calc R
H18B H -0.1743 0.5691 0.697 0.039 Uiso 1 1 calc R
H18C H -0.16 0.569 0.801 0.039 Uiso 1 1 calc R
C19 C -0.07955(19) 0.40208(13) 0.83892(14) 0.0260(5) Uani 1 1 d .
H19A H -0.1544 0.3703 0.8302 0.039 Uiso 1 1 calc R
H19B H -0.0691 0.4405 0.8908 0.039 Uiso 1 1 calc R
H19C H -0.0153 0.3588 0.8475 0.039 Uiso 1 1 calc R
C20 C -0.10656(19) 0.39971(14) 0.67595(14) 0.0264(5) Uani 1 1 d .
H20A H -0.0482 0.3518 0.6828 0.04 Uiso 1 1 calc R
H20B H -0.104 0.4355 0.6242 0.04 Uiso 1 1 calc R
H20C H -0.1848 0.3736 0.6687 0.04 Uiso 1 1 calc R
C21 C 0.13470(18) 0.56514(12) 0.86870(12) 0.0200(4) Uani 1 1 d .
C22 C 0.04807(19) 0.62585(13) 0.90000(13) 0.0264(5) Uani 1 1 d .
H22A H -0.0133 0.5894 0.9157 0.04 Uiso 1 1 calc R
H22B H 0.0124 0.6673 0.8529 0.04 Uiso 1 1 calc R
H22C H 0.0896 0.6597 0.9514 0.04 Uiso 1 1 calc R
C23 C 0.1856(2) 0.49540(14) 0.93909(13) 0.0271(5) Uani 1 1 d .
H23A H 0.2275 0.5257 0.9927 0.041 Uiso 1 1 calc R
H23B H 0.2401 0.4565 0.9178 0.041 Uiso 1 1 calc R
H23C H 0.1218 0.4594 0.9517 0.041 Uiso 1 1 calc R
C24 C 0.23619(19) 0.62238(14) 0.85316(14) 0.0275(5) Uani 1 1 d .
H24A H 0.2789 0.6483 0.9089 0.041 Uiso 1 1 calc R
H24B H 0.205 0.6703 0.8117 0.041 Uiso 1 1 calc R
H24C H 0.2895 0.585 0.8289 0.041 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C1 Pd1 P2 83.03(5)
C1 Pd1 P1 83.26(5)
P2 Pd1 P1 166.154(17)
C1 Pd1 Cl1 177.13(5)
P2 Pd1 Cl1 96.763(16)
P1 Pd1 Cl1 97.028(16)
C7 P1 C9 105.36(9)
C7 P1 C13 104.88(9)
C9 P1 C13 112.92(9)
C7 P1 Pd1 101.37(6)
C9 P1 Pd1 113.10(6)
C13 P1 Pd1 117.34(6)
C8 P2 C21 106.30(9)
C8 P2 C17 104.18(9)
C21 P2 C17 112.96(9)
C8 P2 Pd1 101.73(6)
C21 P2 Pd1 111.68(6)
C17 P2 Pd1 118.29(6)
C6 C1 C2 118.04(16)
C6 C1 Pd1 120.85(13)
C2 C1 Pd1 121.01(13)
C3 C2 C1 120.34(18)
C3 C2 C7 120.49(17)
C1 C2 C7 119.16(16)
C4 C3 C2 120.68(18)
C4 C3 H3 119.7
C2 C3 H3 119.7
C3 C4 C5 120.00(18)
C3 C4 H4 120
C5 C4 H4 120
C4 C5 C6 120.37(19)
C4 C5 H5 119.8
C6 C5 H5 119.8
C5 C6 C1 120.51(18)
C5 C6 C8 119.77(17)
C1 C6 C8 119.70(16)
C2 C7 P1 108.12(13)
C2 C7 H7A 110.1
P1 C7 H7A 110.1
C2 C7 H7B 110.1
P1 C7 H7B 110.1
H7A C7 H7B 108.4
C6 C8 P2 109.02(13)
C6 C8 H8A 109.9
P2 C8 H8A 109.9
C6 C8 H8B 109.9
P2 C8 H8B 109.9
H8A C8 H8B 108.3
C10 C9 C11 110.06(16)
C10 C9 C12 107.41(17)
C11 C9 C12 108.28(16)
C10 C9 P1 109.34(13)
C11 C9 P1 114.66(14)
C12 C9 P1 106.80(12)
C9 C10 H10A 109.5
C9 C10 H10B 109.5
H10A C10 H10B 109.5
C9 C10 H10C 109.5
H10A C10 H10C 109.5
H10B C10 H10C 109.5
C9 C11 H11A 109.5
C9 C11 H11B 109.5
H11A C11 H11B 109.5
C9 C11 H11C 109.5
H11A C11 H11C 109.5
H11B C11 H11C 109.5
C9 C12 H12A 109.5
C9 C12 H12B 109.5
H12A C12 H12B 109.5
C9 C12 H12C 109.5
H12A C12 H12C 109.5
H12B C12 H12C 109.5
C16 C13 C15 109.67(17)
C16 C13 C14 108.66(18)
C15 C13 C14 108.83(17)
C16 C13 P1 113.03(14)
C15 C13 P1 110.87(14)
C14 C13 P1 105.61(13)
C13 C14 H14A 109.5
C13 C14 H14B 109.5
H14A C14 H14B 109.5
C13 C14 H14C 109.5
H14A C14 H14C 109.5
H14B C14 H14C 109.5
C13 C15 H15A 109.5
C13 C15 H15B 109.5
H15A C15 H15B 109.5
C13 C15 H15C 109.5
H15A C15 H15C 109.5
H15B C15 H15C 109.5
C13 C16 H16A 109.5
C13 C16 H16B 109.5
H16A C16 H16B 109.5
C13 C16 H16C 109.5
H16A C16 H16C 109.5
H16B C16 H16C 109.5
C19 C17 C20 108.91(16)
C19 C17 C18 109.41(16)
C20 C17 C18 108.85(17)
C19 C17 P2 111.32(14)
C20 C17 P2 105.10(13)
C18 C17 P2 113.08(13)
C17 C18 H18A 109.5
C17 C18 H18B 109.5
H18A C18 H18B 109.5
C17 C18 H18C 109.5
H18A C18 H18C 109.5
H18B C18 H18C 109.5
C17 C19 H19A 109.5
C17 C19 H19B 109.5
H19A C19 H19B 109.5
C17 C19 H19C 109.5
H19A C19 H19C 109.5
H19B C19 H19C 109.5
C17 C20 H20A 109.5
C17 C20 H20B 109.5
H20A C20 H20B 109.5
C17 C20 H20C 109.5
H20A C20 H20C 109.5
H20B C20 H20C 109.5
C22 C21 C23 110.44(16)
C22 C21 C24 108.61(16)
C23 C21 C24 108.04(17)
C22 C21 P2 113.65(14)
C23 C21 P2 109.21(13)
C24 C21 P2 106.68(13)
C21 C22 H22A 109.5
C21 C22 H22B 109.5
H22A C22 H22B 109.5
C21 C22 H22C 109.5
H22A C22 H22C 109.5
H22B C22 H22C 109.5
C21 C23 H23A 109.5
C21 C23 H23B 109.5
H23A C23 H23B 109.5
C21 C23 H23C 109.5
H23A C23 H23C 109.5
H23B C23 H23C 109.5
C21 C24 H24A 109.5
C21 C24 H24B 109.5
H24A C24 H24B 109.5
C21 C24 H24C 109.5
H24A C24 H24C 109.5
H24B C24 H24C 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Pd1 C1 2.0191(17)
Pd1 P2 2.2998(5)
Pd1 P1 2.3032(5)
Pd1 Cl1 2.3976(4)
P1 C7 1.8398(18)
P1 C9 1.8674(18)
P1 C13 1.872(2)
P2 C8 1.8330(18)
P2 C21 1.8743(19)
P2 C17 1.875(2)
C1 C6 1.409(3)
C1 C2 1.413(3)
C2 C3 1.397(3)
C2 C7 1.506(3)
C3 C4 1.379(3)
C3 H3 0.95
C4 C5 1.384(3)
C4 H4 0.95
C5 C6 1.400(3)
C5 H5 0.95
C6 C8 1.504(3)
C7 H7A 0.99
C7 H7B 0.99
C8 H8A 0.99
C8 H8B 0.99
C9 C10 1.530(3)
C9 C11 1.533(3)
C9 C12 1.533(3)
C10 H10A 0.98
C10 H10B 0.98
C10 H10C 0.98
C11 H11A 0.98
C11 H11B 0.98
C11 H11C 0.98
C12 H12A 0.98
C12 H12B 0.98
C12 H12C 0.98
C13 C16 1.534(3)
C13 C15 1.536(3)
C13 C14 1.538(3)
C14 H14A 0.98
C14 H14B 0.98
C14 H14C 0.98
C15 H15A 0.98
C15 H15B 0.98
C15 H15C 0.98
C16 H16A 0.98
C16 H16B 0.98
C16 H16C 0.98
C17 C19 1.535(3)
C17 C20 1.539(3)
C17 C18 1.541(3)
C18 H18A 0.98
C18 H18B 0.98
C18 H18C 0.98
C19 H19A 0.98
C19 H19B 0.98
C19 H19C 0.98
C20 H20A 0.98
C20 H20B 0.98
C20 H20C 0.98
C21 C22 1.529(3)
C21 C23 1.535(3)
C21 C24 1.533(3)
C22 H22A 0.98
C22 H22B 0.98
C22 H22C 0.98
C23 H23A 0.98
C23 H23B 0.98
C23 H23C 0.98
C24 H24A 0.98
C24 H24B 0.98
C24 H24C 0.98
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C1 Pd1 P1 C7 19.07(8)
P2 Pd1 P1 C7 11.07(11)
Cl1 Pd1 P1 C7 -163.81(7)
C1 Pd1 P1 C9 -93.23(8)
P2 Pd1 P1 C9 -101.23(10)
Cl1 Pd1 P1 C9 83.89(7)
C1 Pd1 P1 C13 132.57(9)
P2 Pd1 P1 C13 124.58(10)
Cl1 Pd1 P1 C13 -50.31(8)
C1 Pd1 P2 C8 19.43(9)
P1 Pd1 P2 C8 27.43(11)
Cl1 Pd1 P2 C8 -157.68(7)
C1 Pd1 P2 C21 -93.58(8)
P1 Pd1 P2 C21 -85.58(10)
Cl1 Pd1 P2 C21 89.30(7)
C1 Pd1 P2 C17 132.74(9)
P1 Pd1 P2 C17 140.74(9)
Cl1 Pd1 P2 C17 -44.37(7)
P2 Pd1 C1 C6 -15.59(14)
P1 Pd1 C1 C6 166.33(15)
P2 Pd1 C1 C2 168.12(15)
P1 Pd1 C1 C2 -9.96(14)
C6 C1 C2 C3 -2.6(3)
Pd1 C1 C2 C3 173.76(14)
C6 C1 C2 C7 176.75(16)
Pd1 C1 C2 C7 -6.9(2)
C1 C2 C3 C4 1.7(3)
C7 C2 C3 C4 -177.67(18)
C2 C3 C4 C5 0.3(3)
C3 C4 C5 C6 -1.3(3)
C4 C5 C6 C1 0.3(3)
C4 C5 C6 C8 -178.08(18)
C2 C1 C6 C5 1.7(3)
Pd1 C1 C6 C5 -174.75(14)
C2 C1 C6 C8 -179.98(17)
Pd1 C1 C6 C8 3.6(2)
C3 C2 C7 P1 -156.65(15)
C1 C2 C7 P1 24.0(2)
C9 P1 C7 C2 91.15(14)
C13 P1 C7 C2 -149.45(13)
Pd1 P1 C7 C2 -26.90(13)
C5 C6 C8 P2 -166.68(15)
C1 C6 C8 P2 14.9(2)
C21 P2 C8 C6 94.15(14)
C17 P2 C8 C6 -146.31(13)
Pd1 P2 C8 C6 -22.83(14)
C7 P1 C9 C10 -164.86(14)
C13 P1 C9 C10 81.24(16)
Pd1 P1 C9 C10 -55.02(15)
C7 P1 C9 C11 71.01(16)
C13 P1 C9 C11 -42.90(17)
Pd1 P1 C9 C11 -179.15(12)
C7 P1 C9 C12 -48.93(16)
C13 P1 C9 C12 -162.84(14)
Pd1 P1 C9 C12 60.90(14)
C7 P1 C13 C16 -42.37(17)
C9 P1 C13 C16 71.83(17)
Pd1 P1 C13 C16 -153.90(13)
C7 P1 C13 C15 -165.98(14)
C9 P1 C13 C15 -51.78(17)
Pd1 P1 C13 C15 82.49(14)
C7 P1 C13 C14 76.31(15)
C9 P1 C13 C14 -169.50(13)
Pd1 P1 C13 C14 -35.22(16)
C8 P2 C17 C19 -166.31(13)
C21 P2 C17 C19 -51.39(15)
Pd1 P2 C17 C19 81.73(14)
C8 P2 C17 C20 75.94(14)
C21 P2 C17 C20 -169.13(12)
Pd1 P2 C17 C20 -36.01(14)
C8 P2 C17 C18 -42.66(16)
C21 P2 C17 C18 72.26(16)
Pd1 P2 C17 C18 -154.62(12)
C8 P2 C21 C22 69.54(15)
C17 P2 C21 C22 -44.10(16)
Pd1 P2 C21 C22 179.66(12)
C8 P2 C21 C23 -166.66(14)
C17 P2 C21 C23 79.70(15)
Pd1 P2 C21 C23 -56.53(14)
C8 P2 C21 C24 -50.12(16)
C17 P2 C21 C24 -163.76(13)
Pd1 P2 C21 C24 60.00(14)
