#------------------------------------------------------------------------------
#$Date: 2016-03-25 16:01:19 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179947 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/42/7024298.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7024298
loop_
_publ_author_name
'Ball, Nicholas D.'
'Kampf, Jeff W.'
'Sanford, Melanie S.'
_publ_section_title
;
 Synthesis and reactivity of palladium(II) fluoride complexes containing
 nitrogen-donor ligands.
;
_journal_issue                   2
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              632
_journal_page_last               640
_journal_paper_doi               10.1039/b914426a
_journal_volume                  39
_journal_year                    2010
_chemical_formula_moiety         'C31 H23 F N P Pd, C H2 Cl2'
_chemical_formula_sum            'C32 H25 Cl2 F N P Pd'
_chemical_formula_weight         650.80
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                96.861(1)
_cell_angle_beta                 98.293(1)
_cell_angle_gamma                104.123(1)
_cell_formula_units_Z            4
_cell_length_a                   8.7399(5)
_cell_length_b                   17.2959(9)
_cell_length_c                   20.3468(11)
_cell_measurement_reflns_used    9709
_cell_measurement_temperature    85(2)
_cell_measurement_theta_max      28.27
_cell_measurement_theta_min      2.42
_cell_volume                     2913.0(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker SMART-APEX'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      85(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0328
_diffrn_reflns_av_sigmaI/netI    0.0167
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            128348
_diffrn_reflns_theta_full        28.33
_diffrn_reflns_theta_max         28.33
_diffrn_reflns_theta_min         1.72
_exptl_absorpt_coefficient_mu    0.904
_exptl_absorpt_correction_T_max  0.9562
_exptl_absorpt_correction_T_min  0.8056
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
Blessing, R. Acta Cryst. (1995) A51 33-38.
Sheldrick, G. SADABS (Version 2008/1) Bruker AXS area
detector absorption and other corrections, University of
Gottingen, Germany 2008.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.484
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1312
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.950
_refine_diff_density_min         -0.859
_refine_diff_density_rms         0.094
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     79
_refine_ls_number_reflns         14487
_refine_ls_number_restraints     45
_refine_ls_restrained_S_all      1.066
_refine_ls_R_factor_all          0.0403
_refine_ls_R_factor_gt           0.0367
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0453P)²+3.3681P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0934
_refine_ls_wR_factor_ref         0.0961
_reflns_number_gt                13303
_reflns_number_total             14487
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b914426a.txt
_cod_data_source_block           nb143
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7024298
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pd1 Pd 0.26443(2) 0.662170(11) 0.297507(8) 0.01770(5) Uani 1 1 d . . .
Pd2 Pd 0.55375(2) 0.176423(11) 0.042141(9) 0.01865(5) Uani 1 1 d . . .
P1 P 0.36887(7) 0.59446(4) 0.37192(3) 0.01811(12) Uani 1 1 d . . .
P2 P 0.50185(7) 0.24006(4) 0.13578(3) 0.01800(12) Uani 1 1 d . . .
F1 F 0.2329(2) 0.74467(10) 0.37049(8) 0.0332(4) Uani 1 1 d . . .
F2 F 0.64706(18) 0.09872(9) 0.09186(8) 0.0259(3) Uani 1 1 d . . .
C1 C 0.0991(3) 0.78365(15) 0.24024(13) 0.0241(5) Uani 1 1 d . . .
H1A H 0.1104 0.8090 0.2854 0.029 Uiso 1 1 calc R . .
C2 C 0.0254(3) 0.81519(17) 0.18778(15) 0.0287(5) Uani 1 1 d . . .
H2A H -0.0112 0.8620 0.1975 0.034 Uiso 1 1 calc R . .
C3 C 0.0060(3) 0.77842(16) 0.12247(14) 0.0276(5) Uani 1 1 d . . .
H3A H -0.0456 0.7990 0.0868 0.033 Uiso 1 1 calc R . .
C4 C 0.0630(3) 0.71010(16) 0.10855(13) 0.0237(5) Uani 1 1 d . . .
C5 C 0.0505(3) 0.66654(17) 0.04284(13) 0.0284(5) Uani 1 1 d . . .
H5A H -0.0039 0.6821 0.0049 0.034 Uiso 1 1 calc R . .
C6 C 0.1155(3) 0.60331(17) 0.03410(13) 0.0269(5) Uani 1 1 d . . .
H6A H 0.1058 0.5756 -0.0101 0.032 Uiso 1 1 calc R . .
C7 C 0.1987(3) 0.57686(15) 0.08981(12) 0.0219(5) Uani 1 1 d . . .
C8 C 0.2777(3) 0.51543(16) 0.08196(13) 0.0259(5) Uani 1 1 d . . .
H8A H 0.2757 0.4881 0.0383 0.031 Uiso 1 1 calc R . .
C9 C 0.3578(3) 0.49529(16) 0.13782(13) 0.0260(5) Uani 1 1 d . . .
H9A H 0.4149 0.4555 0.1321 0.031 Uiso 1 1 calc R . .
C10 C 0.3573(3) 0.53224(15) 0.20351(12) 0.0224(5) Uani 1 1 d . . .
H10A H 0.4098 0.5150 0.2411 0.027 Uiso 1 1 calc R . .
C11 C 0.2820(3) 0.59293(14) 0.21415(11) 0.0178(4) Uani 1 1 d . . .
C12 C 0.2055(3) 0.61563(14) 0.15566(12) 0.0190(4) Uani 1 1 d . . .
C13 C 0.1377(3) 0.68256(14) 0.16371(12) 0.0191(4) Uani 1 1 d . . .
C14 C 0.3250(3) 0.62099(17) 0.45531(12) 0.0242(5) Uani 1 1 d . . .
C15 C 0.3850(4) 0.70178(19) 0.48592(14) 0.0351(6) Uani 1 1 d . . .
H15A H 0.4476 0.7398 0.4637 0.042 Uiso 1 1 calc R . .
C16 C 0.3530(5) 0.7263(2) 0.54873(15) 0.0444(8) Uani 1 1 d . . .
H16A H 0.3941 0.7812 0.5695 0.053 Uiso 1 1 calc R . .
C17 C 0.2616(4) 0.6712(3) 0.58136(15) 0.0451(9) Uani 1 1 d . . .
H17A H 0.2392 0.6886 0.6242 0.054 Uiso 1 1 calc R . .
C18 C 0.2030(4) 0.5914(2) 0.55198(14) 0.0398(8) Uani 1 1 d . . .
H18A H 0.1415 0.5537 0.5747 0.048 Uiso 1 1 calc R . .
C19 C 0.2344(3) 0.56586(19) 0.48830(13) 0.0287(6) Uani 1 1 d . . .
H19A H 0.1935 0.5109 0.4678 0.034 Uiso 1 1 calc R . .
C20 C 0.5865(3) 0.61752(15) 0.38833(13) 0.0226(5) Uani 1 1 d . . .
C21 C 0.6721(3) 0.64465(16) 0.33914(14) 0.0263(5) Uani 1 1 d . . .
H21A H 0.6163 0.6481 0.2964 0.032 Uiso 1 1 calc R . .
C22 C 0.8391(3) 0.66672(17) 0.35234(16) 0.0324(6) Uani 1 1 d . . .
H22A H 0.8971 0.6855 0.3187 0.039 Uiso 1 1 calc R . .
C23 C 0.9208(3) 0.66133(19) 0.41460(19) 0.0394(7) Uani 1 1 d . . .
H23A H 1.0347 0.6767 0.4237 0.047 Uiso 1 1 calc R . .
C24 C 0.8372(4) 0.6338(2) 0.46310(19) 0.0426(8) Uani 1 1 d . . .
H24A H 0.8937 0.6297 0.5055 0.051 Uiso 1 1 calc R . .
C25 C 0.6705(3) 0.61190(19) 0.45054(16) 0.0342(6) Uani 1 1 d . . .
H25A H 0.6136 0.5930 0.4844 0.041 Uiso 1 1 calc R . .
C26 C 0.2933(3) 0.48514(15) 0.35464(12) 0.0205(4) Uani 1 1 d . . .
C27 C 0.3856(3) 0.43264(16) 0.37146(12) 0.0238(5) Uani 1 1 d . . .
H27A H 0.4956 0.4536 0.3914 0.029 Uiso 1 1 calc R . .
C28 C 0.3169(4) 0.34972(17) 0.35910(14) 0.0289(5) Uani 1 1 d . . .
H28A H 0.3804 0.3141 0.3702 0.035 Uiso 1 1 calc R . .
C29 C 0.1561(4) 0.31878(17) 0.33066(14) 0.0306(6) Uani 1 1 d . . .
H29A H 0.1094 0.2621 0.3227 0.037 Uiso 1 1 calc R . .
C30 C 0.0631(3) 0.37052(18) 0.31375(14) 0.0302(6) Uani 1 1 d . . .
H30A H -0.0471 0.3493 0.2942 0.036 Uiso 1 1 calc R . .
C31 C 0.1314(3) 0.45318(16) 0.32543(13) 0.0251(5) Uani 1 1 d . . .
H31A H 0.0678 0.4885 0.3135 0.030 Uiso 1 1 calc R . .
C32 C 0.6496(3) 0.05274(15) -0.05332(14) 0.0244(5) Uani 1 1 d . . .
H32A H 0.6797 0.0301 -0.0147 0.029 Uiso 1 1 calc R . .
C33 C 0.6689(3) 0.01809(16) -0.11641(14) 0.0274(5) Uani 1 1 d . . .
H33A H 0.7141 -0.0266 -0.1203 0.033 Uiso 1 1 calc R . .
C34 C 0.6219(3) 0.04929(16) -0.17264(14) 0.0282(5) Uani 1 1 d . . .
H34A H 0.6339 0.0261 -0.2157 0.034 Uiso 1 1 calc R . .
C35 C 0.5559(3) 0.11581(16) -0.16624(13) 0.0238(5) Uani 1 1 d . . .
C36 C 0.4974(3) 0.15176(18) -0.22137(14) 0.0299(6) Uani 1 1 d . . .
H36A H 0.5025 0.1307 -0.2661 0.036 Uiso 1 1 calc R . .
C37 C 0.4347(3) 0.21565(17) -0.21003(13) 0.0288(5) Uani 1 1 d . . .
H37A H 0.3951 0.2378 -0.2474 0.035 Uiso 1 1 calc R . .
C38 C 0.4263(3) 0.25075(16) -0.14349(13) 0.0239(5) Uani 1 1 d . . .
C39 C 0.3679(3) 0.31886(16) -0.13048(13) 0.0255(5) Uani 1 1 d . . .
H39A H 0.3326 0.3444 -0.1664 0.031 Uiso 1 1 calc R . .
C40 C 0.3623(3) 0.34817(16) -0.06519(13) 0.0248(5) Uani 1 1 d . . .
H40A H 0.3247 0.3948 -0.0565 0.030 Uiso 1 1 calc R . .
C41 C 0.4107(3) 0.31103(15) -0.01117(13) 0.0229(5) Uani 1 1 d . . .
H41A H 0.4027 0.3323 0.0331 0.027 Uiso 1 1 calc R . .
C42 C 0.4700(3) 0.24400(14) -0.02087(12) 0.0188(4) Uani 1 1 d . . .
C43 C 0.4787(3) 0.21568(15) -0.08838(12) 0.0211(5) Uani 1 1 d . . .
C44 C 0.5431(3) 0.14796(15) -0.10132(12) 0.0217(5) Uani 1 1 d . . .
C45 C 0.5310(3) 0.19027(15) 0.20884(12) 0.0218(5) Uani 1 1 d . . .
C46 C 0.6796(3) 0.17474(17) 0.22808(13) 0.0280(5) Uani 1 1 d . . .
H46A H 0.7634 0.1909 0.2036 0.034 Uiso 1 1 calc R . .
C47 C 0.7046(4) 0.13588(18) 0.28281(14) 0.0320(6) Uani 1 1 d . . .
H47A H 0.8060 0.1261 0.2960 0.038 Uiso 1 1 calc R . .
C48 C 0.5821(4) 0.11119(17) 0.31855(14) 0.0345(6) Uani 1 1 d . . .
H48A H 0.5989 0.0832 0.3552 0.041 Uiso 1 1 calc R . .
C49 C 0.4351(4) 0.12753(18) 0.30053(14) 0.0319(6) Uani 1 1 d . . .
H49A H 0.3521 0.1118 0.3256 0.038 Uiso 1 1 calc R . .
C50 C 0.4093(3) 0.16702(16) 0.24568(13) 0.0257(5) Uani 1 1 d . . .
H50A H 0.3087 0.1781 0.2334 0.031 Uiso 1 1 calc R . .
C51 C 0.2935(3) 0.24394(15) 0.12686(12) 0.0201(4) Uani 1 1 d . . .
C52 C 0.1806(3) 0.18140(15) 0.08175(14) 0.0243(5) Uani 1 1 d . . .
H52A H 0.2143 0.1403 0.0572 0.029 Uiso 1 1 calc R . .
C53 C 0.0193(3) 0.17983(16) 0.07311(14) 0.0267(5) Uani 1 1 d . . .
H53A H -0.0582 0.1362 0.0443 0.032 Uiso 1 1 calc R . .
C54 C -0.0287(3) 0.24223(17) 0.10659(14) 0.0269(5) Uani 1 1 d . . .
H54A H -0.1387 0.2420 0.0995 0.032 Uiso 1 1 calc R . .
C55 C 0.0810(3) 0.30343(17) 0.14928(13) 0.0268(5) Uani 1 1 d . . .
H55A H 0.0470 0.3461 0.1714 0.032 Uiso 1 1 calc R . .
C56 C 0.2434(3) 0.30479(16) 0.16126(13) 0.0234(5) Uani 1 1 d . . .
H56A H 0.3186 0.3469 0.1926 0.028 Uiso 1 1 calc R . .
C57 C 0.6249(3) 0.34303(14) 0.16708(12) 0.0190(4) Uani 1 1 d . . .
C58 C 0.7135(3) 0.38609(15) 0.12477(12) 0.0218(5) Uani 1 1 d . . .
H58A H 0.7100 0.3614 0.0801 0.026 Uiso 1 1 calc R . .
C59 C 0.8069(3) 0.46508(16) 0.14801(14) 0.0251(5) Uani 1 1 d . . .
H59A H 0.8675 0.4939 0.1192 0.030 Uiso 1 1 calc R . .
C60 C 0.8114(3) 0.50174(15) 0.21312(13) 0.0249(5) Uani 1 1 d . . .
H60A H 0.8735 0.5559 0.2286 0.030 Uiso 1 1 calc R . .
C61 C 0.7250(3) 0.45900(15) 0.25564(13) 0.0225(5) Uani 1 1 d . . .
H61A H 0.7288 0.4839 0.3003 0.027 Uiso 1 1 calc R . .
C62 C 0.6331(3) 0.37991(15) 0.23311(12) 0.0209(4) Uani 1 1 d . . .
H62A H 0.5755 0.3508 0.2626 0.025 Uiso 1 1 calc R . .
N1 N 0.1534(2) 0.71906(12) 0.22803(10) 0.0191(4) Uani 1 1 d . . .
N7 N 0.5903(2) 0.11637(12) -0.04611(11) 0.0207(4) Uani 1 1 d . . .
Cl1 Cl 0.89240(10) -0.04121(4) 0.07508(4) 0.03935(17) Uani 1 1 d D . .
Cl2 Cl 1.00774(9) 0.04482(5) 0.21228(4) 0.03954(17) Uani 1 1 d D . .
C63 C 0.8369(3) -0.00348(18) 0.15009(15) 0.0316(6) Uani 1 1 d D . .
H63A H 0.7735 0.0355 0.1406 0.038 Uiso 1 1 calc R . .
H63B H 0.7686 -0.0486 0.1671 0.038 Uiso 1 1 calc R . .
Cl3 Cl 0.6921(8) 0.04000(14) 0.62580(17) 0.1031(17) Uani 0.50 1 d PDU A 1
Cl4 Cl 0.5204(9) 0.0657(4) 0.4962(3) 0.105(2) Uani 0.50 1 d PDU . 1
C64 C 0.6842(13) 0.0932(5) 0.5589(4) 0.077(2) Uani 0.50 1 d PDU A 1
H64A H 0.6979 0.1504 0.5779 0.093 Uiso 0.50 1 calc PR A 1
H64B H 0.7787 0.0912 0.5377 0.093 Uiso 0.50 1 calc PR A 1
Cl5 Cl 0.140(4) 0.133(2) 0.520(2) 0.25(3) Uani 0.25 1 d PDU B 2
Cl6 Cl 0.4289(8) 0.0780(3) 0.5686(3) 0.098(2) Uani 0.25 1 d PDU B 2
C65 C 0.304(2) 0.1397(13) 0.5838(13) 0.140(9) Uani 0.25 1 d PDU B 2
H65A H 0.3701 0.1964 0.5934 0.168 Uiso 0.25 1 calc PR B 2
H65B H 0.2617 0.1276 0.6251 0.168 Uiso 0.25 1 calc PR B 2
Cl7 Cl 0.2941(14) 0.1225(6) 0.4885(5) 0.161(4) Uani 0.25 1 d PDU C 3
Cl8 Cl -0.0258(13) 0.1592(6) 0.4506(5) 0.154(3) Uani 0.25 1 d PDU C 3
C66 C 0.127(3) 0.151(2) 0.5106(9) 0.165(10) Uani 0.25 1 d PDU C 3
H66A H 0.0783 0.1120 0.5385 0.197 Uiso 0.25 1 calc PR C 3
H66B H 0.1681 0.2041 0.5403 0.197 Uiso 0.25 1 calc PR C 3
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
C11 Pd1 F1 169.77(8) .
C11 Pd1 N1 82.52(9) .
F1 Pd1 N1 87.36(7) .
C11 Pd1 P1 96.97(7) .
F1 Pd1 P1 93.23(5) .
N1 Pd1 P1 176.20(6) .
C42 Pd2 F2 170.46(8) .
C42 Pd2 N7 82.57(9) .
F2 Pd2 N7 87.91(7) .
C42 Pd2 P2 96.08(7) .
F2 Pd2 P2 93.46(5) .
N7 Pd2 P2 177.32(6) .
C26 P1 C20 107.02(11) .
C26 P1 C14 103.43(12) .
C20 P1 C14 102.23(12) .
C26 P1 Pd1 116.10(8) .
C20 P1 Pd1 115.30(8) .
C14 P1 Pd1 111.25(8) .
C45 P2 C51 104.15(11) .
C45 P2 C57 102.19(11) .
C51 P2 C57 106.64(11) .
C45 P2 Pd2 113.53(8) .
C51 P2 Pd2 112.23(8) .
C57 P2 Pd2 116.85(8) .
N1 C1 C2 121.3(2) .
C3 C2 C1 119.9(2) .
C2 C3 C4 119.6(2) .
C3 C4 C13 117.2(2) .
C3 C4 C5 125.0(2) .
C13 C4 C5 117.7(2) .
C6 C5 C4 120.8(2) .
C5 C6 C7 122.0(2) .
C8 C7 C12 118.0(2) .
C8 C7 C6 123.3(2) .
C12 C7 C6 118.7(2) .
C9 C8 C7 119.5(2) .
C8 C9 C10 121.7(2) .
C11 C10 C9 121.2(2) .
C10 C11 C12 116.5(2) .
C10 C11 Pd1 132.79(18) .
C12 C11 Pd1 110.69(16) .
C7 C12 C11 123.0(2) .
C7 C12 C13 118.3(2) .
C11 C12 C13 118.6(2) .
N1 C13 C4 122.2(2) .
N1 C13 C12 115.5(2) .
C4 C13 C12 122.3(2) .
C19 C14 C15 119.6(3) .
C19 C14 P1 123.4(2) .
C15 C14 P1 117.0(2) .
C16 C15 C14 119.9(3) .
C17 C16 C15 120.4(3) .
C18 C17 C16 120.3(3) .
C17 C18 C19 119.9(3) .
C14 C19 C18 120.0(3) .
C21 C20 C25 119.0(2) .
C21 C20 P1 119.67(19) .
C25 C20 P1 121.2(2) .
C22 C21 C20 120.3(3) .
C23 C22 C21 120.0(3) .
C24 C23 C22 120.1(3) .
C23 C24 C25 120.4(3) .
C24 C25 C20 120.2(3) .
C27 C26 C31 119.2(2) .
C27 C26 P1 123.59(19) .
C31 C26 P1 117.19(19) .
C28 C27 C26 120.1(2) .
C29 C28 C27 120.3(3) .
C28 C29 C30 120.1(3) .
C31 C30 C29 119.8(3) .
C30 C31 C26 120.5(2) .
N7 C32 C33 121.7(3) .
C34 C33 C32 119.4(2) .
C33 C34 C35 119.8(2) .
C44 C35 C34 117.4(2) .
C44 C35 C36 117.7(2) .
C34 C35 C36 124.9(2) .
C37 C36 C35 120.4(2) .
C36 C37 C38 122.2(3) .
C39 C38 C43 118.1(2) .
C39 C38 C37 123.1(2) .
C43 C38 C37 118.9(2) .
C40 C39 C38 119.3(2) .
C39 C40 C41 121.8(2) .
C42 C41 C40 121.5(2) .
C41 C42 C43 116.0(2) .
C41 C42 Pd2 133.27(18) .
C43 C42 Pd2 110.67(17) .
C38 C43 C42 123.3(2) .
C38 C43 C44 118.1(2) .
C42 C43 C44 118.6(2) .
N7 C44 C35 122.1(2) .
N7 C44 C43 115.3(2) .
C35 C44 C43 122.6(2) .
C50 C45 C46 119.4(2) .
C50 C45 P2 121.81(19) .
C46 C45 P2 118.8(2) .
C47 C46 C45 120.1(3) .
C46 C47 C48 120.4(3) .
C47 C48 C49 119.9(3) .
C48 C49 C50 120.0(3) .
C49 C50 C45 120.1(3) .
C56 C51 C52 119.7(2) .
C56 C51 P2 123.75(19) .
C52 C51 P2 116.58(18) .
C53 C52 C51 119.7(2) .
C52 C53 C54 119.9(2) .
C55 C54 C53 120.2(2) .
C54 C55 C56 121.1(2) .
C51 C56 C55 119.2(2) .
C58 C57 C62 119.2(2) .
C58 C57 P2 119.76(18) .
C62 C57 P2 121.09(18) .
C59 C58 C57 120.2(2) .
C60 C59 C58 120.2(2) .
C61 C60 C59 119.9(2) .
C62 C61 C60 120.3(2) .
C61 C62 C57 120.3(2) .
C1 N1 C13 119.7(2) .
C1 N1 Pd1 127.68(17) .
C13 N1 Pd1 112.60(15) .
C32 N7 C44 119.6(2) .
C32 N7 Pd2 127.57(18) .
C44 N7 Pd2 112.81(16) .
Cl2 C63 Cl1 111.06(15) .
C64 Cl4 Cl4 92.8(5) 2_656
Cl4 C64 Cl3 120.1(6) .
Cl6 C65 Cl5 117.5(10) .
Cl8 C66 Cl7 121.5(12) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pd1 C11 2.004(2) .
Pd1 F1 2.0301(15) .
Pd1 N1 2.0762(19) .
Pd1 P1 2.2458(6) .
Pd2 C42 2.012(2) .
Pd2 F2 2.0290(15) .
Pd2 N7 2.070(2) .
Pd2 P2 2.2448(6) .
P1 C26 1.816(3) .
P1 C20 1.818(2) .
P1 C14 1.823(3) .
P2 C45 1.822(3) .
P2 C51 1.822(2) .
P2 C57 1.825(2) .
C1 N1 1.327(3) .
C1 C2 1.402(4) .
C2 C3 1.371(4) .
C3 C4 1.404(4) .
C4 C13 1.408(3) .
C4 C5 1.430(4) .
C5 C6 1.355(4) .
C6 C7 1.440(3) .
C7 C8 1.407(4) .
C7 C12 1.411(3) .
C8 C9 1.373(4) .
C9 C10 1.412(3) .
C10 C11 1.381(3) .
C11 C12 1.424(3) .
C12 C13 1.427(3) .
C13 N1 1.356(3) .
C14 C19 1.387(4) .
C14 C15 1.398(4) .
C15 C16 1.386(4) .
C16 C17 1.386(6) .
C17 C18 1.376(5) .
C18 C19 1.405(4) .
C20 C21 1.392(4) .
C20 C25 1.395(4) .
C21 C22 1.392(4) .
C22 C23 1.387(5) .
C23 C24 1.373(5) .
C24 C25 1.390(4) .
C26 C27 1.395(3) .
C26 C31 1.399(3) .
C27 C28 1.389(4) .
C28 C29 1.386(4) .
C29 C30 1.388(4) .
C30 C31 1.385(4) .
C32 N7 1.328(3) .
C32 C33 1.401(4) .
C33 C34 1.374(4) .
C34 C35 1.408(4) .
C35 C44 1.402(3) .
C35 C36 1.436(4) .
C36 C37 1.358(4) .
C37 C38 1.436(4) .
C38 C39 1.406(4) .
C38 C43 1.409(4) .
C39 C40 1.376(4) .
C40 C41 1.402(4) .
C41 C42 1.386(3) .
C42 C43 1.421(3) .
C43 C44 1.431(3) .
C44 N7 1.362(3) .
C45 C50 1.396(4) .
C45 C46 1.400(4) .
C46 C47 1.386(4) .
C47 C48 1.390(5) .
C48 C49 1.390(4) .
C49 C50 1.395(4) .
C51 C56 1.388(3) .
C51 C52 1.402(3) .
C52 C53 1.389(3) .
C53 C54 1.390(4) .
C54 C55 1.356(4) .
C55 C56 1.399(3) .
C57 C58 1.400(3) .
C57 C62 1.401(3) .
C58 C59 1.395(3) .
C59 C60 1.389(4) .
C60 C61 1.391(4) .
C61 C62 1.391(3) .
Cl1 C63 1.767(3) .
Cl2 C63 1.767(3) .
Cl3 C64 1.734(7) .
Cl4 C64 1.702(8) .
Cl4 Cl4 2.240(13) 2_656
Cl5 C65 1.757(10) .
Cl6 C65 1.737(10) .
Cl7 C66 1.751(10) .
Cl8 C66 1.720(10) .
