#------------------------------------------------------------------------------
#$Date: 2016-03-25 16:03:25 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179949 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/44/7024484.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7024484
loop_
_publ_author_name
'Wang, Siegfried M. J.'
'Zhao, Liang'
'Mak, Thomas C. W.'
_publ_section_title
;
 Coordination networks constructed with the multinuclear silver-ethynide
 supramolecular synthon 4-nitrophenyl-C[triple bond]C subset Ag(n) (n = 3,
 4, 5).
;
_journal_issue                   8
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2108
_journal_page_last               2121
_journal_paper_doi               10.1039/b917789b
_journal_volume                  39
_journal_year                    2010
_chemical_formula_moiety         'C18 H7 Ag5 F12 N2 O10'
_chemical_formula_sum            'C18 H7 Ag5 F12 N2 O10'
_chemical_formula_weight         1178.61
_chemical_name_common            'Compound 1'
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                100.291(8)
_cell_angle_beta                 91.633(10)
_cell_angle_gamma                100.111(8)
_cell_formula_units_Z            2
_cell_length_a                   10.549(5)
_cell_length_b                   11.224(5)
_cell_length_c                   12.845(6)
_cell_measurement_reflns_used    285
_cell_measurement_temperature    296(2)
_cell_volume                     1470.4(12)
_computing_cell_refinement       'BrukerAXS APEX2 Suite 2.1.4'
_computing_data_collection       'BrukerAXS APEX2 Suite 2.1.4'
_computing_data_reduction        'BrukerAXS APEX2 Suite 2.1.4'
_computing_molecular_graphics    'BrukerAXS APEX2 Suite 2.1.4'
_computing_publication_material  'BrukerAXS APEX2 Suite 2.1.4'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'BrukerAXS Kappa APEX2 CCD'
_diffrn_measurement_method       'Phi scan and Omega scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0297
_diffrn_reflns_av_sigmaI/netI    0.0106
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            77417
_diffrn_reflns_theta_full        26.01
_diffrn_reflns_theta_max         26.01
_diffrn_reflns_theta_min         1.61
_exptl_absorpt_coefficient_mu    3.400
_exptl_absorpt_correction_T_max  0.3433
_exptl_absorpt_correction_T_min  0.2812
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    2.662
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1104
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.45
_exptl_crystal_size_min          0.40
_refine_diff_density_max         0.675
_refine_diff_density_min         -0.650
_refine_diff_density_rms         0.069
_refine_ls_extinction_coef       0.0172(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     470
_refine_ls_number_reflns         5775
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.039
_refine_ls_R_factor_all          0.0275
_refine_ls_R_factor_gt           0.0246
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0253P)²+2.6027P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0598
_refine_ls_wR_factor_ref         0.0620
_reflns_number_gt                5306
_reflns_number_total             5775
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b917789b.txt
_cod_data_source_block           729718
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        1470.4(11)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7024484
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.51654(3) 1.07211(3) 0.91700(2) 0.06318(11) Uani 1 1 d . . .
Ag2 Ag 0.34561(3) 0.96225(3) 0.67786(2) 0.06151(10) Uani 1 1 d . A .
Ag3 Ag 0.31557(3) 0.87405(3) 0.31805(2) 0.05663(10) Uani 1 1 d . A .
Ag4 Ag 0.12608(3) 0.96945(3) 0.50644(3) 0.05955(10) Uani 1 1 d . . .
Ag5 Ag 0.40994(3) 1.08644(2) 0.50150(2) 0.04570(9) Uani 1 1 d . . .
C1 C 0.3316(3) 0.8910(3) 0.5047(3) 0.0384(7) Uani 1 1 d . . .
C2 C 0.3031(3) 0.7802(3) 0.4878(3) 0.0380(7) Uani 1 1 d . . .
C3 C 0.2633(2) 0.64948(13) 0.47480(19) 0.0401(7) Uani 1 1 d G . .
C4 C 0.1503(2) 0.59222(18) 0.41470(19) 0.0509(9) Uani 1 1 d G . .
H4 H 0.1048 0.6377 0.3785 0.061 Uiso 1 1 calc R . .
C5 C 0.1051(2) 0.46701(18) 0.4088(2) 0.0579(10) Uani 1 1 d G . .
H5 H 0.0295 0.4287 0.3686 0.069 Uiso 1 1 calc R . .
C6 C 0.1730(2) 0.39907(13) 0.4629(2) 0.0492(8) Uani 1 1 d G . .
C7 C 0.2861(2) 0.45632(17) 0.5231(2) 0.0553(9) Uani 1 1 d G . .
H7 H 0.3315 0.4109 0.5593 0.066 Uiso 1 1 calc R . .
C8 C 0.33119(19) 0.58153(18) 0.52898(19) 0.0528(9) Uani 1 1 d G . .
H8 H 0.4068 0.6198 0.5692 0.063 Uiso 1 1 calc R . .
C9 C 0.4253(3) 1.2483(3) 0.7322(3) 0.0482(8) Uani 1 1 d . . .
C10 C 0.4117(7) 1.3636(5) 0.8101(4) 0.0947(18) Uani 1 1 d D . .
C11 C 0.3693(4) 1.1461(4) 0.2771(3) 0.0510(8) Uani 1 1 d . A .
C12 C 0.3469(8) 1.2290(6) 0.1982(5) 0.097(2) Uani 1 1 d . . .
C13 C 0.2989(4) 0.8324(4) 0.8912(3) 0.0508(8) Uani 1 1 d . B .
C14 C 0.1841(5) 0.7421(5) 0.8286(4) 0.0813(16) Uani 1 1 d . . .
C15 C 0.0242(4) 1.0809(5) 0.7150(4) 0.0651(11) Uani 1 1 d . . .
C16 C 0.0293(6) 1.1226(9) 0.8353(5) 0.121(3) Uani 1 1 d D . .
C17 C 0.2357(5) 0.6163(4) 0.1362(4) 0.0710(12) Uani 1 1 d . . .
C18 C 0.2026(8) 0.5027(6) 0.0567(5) 0.126(3) Uani 1 1 d . . .
H18A H 0.1258 0.5046 0.0157 0.188 Uiso 1 1 calc R . .
H18B H 0.1882 0.4331 0.0916 0.188 Uiso 1 1 calc R . .
H18C H 0.2723 0.4960 0.0108 0.188 Uiso 1 1 calc R . .
F1 F 0.3000(6) 1.3911(5) 0.8008(4) 0.179(3) Uani 1 1 d D . .
F2 F 0.4396(7) 1.3611(5) 0.9076(3) 0.187(3) Uani 1 1 d D . .
F3 F 0.4889(7) 1.4585(4) 0.7922(5) 0.203(3) Uani 1 1 d D . .
F4 F 0.279(2) 1.3043(17) 0.2280(13) 0.144(8) Uani 0.625(18) 1 d P A 1
F5 F 0.3152(19) 1.1671(15) 0.1026(8) 0.155(9) Uani 0.625(18) 1 d P A 1
F6 F 0.4710(12) 1.2958(9) 0.1869(12) 0.146(5) Uani 0.625(18) 1 d P A 1
F7 F 0.154(2) 0.764(2) 0.7390(17) 0.136(11) Uani 0.46(3) 1 d P B 1
F8 F 0.216(3) 0.6271(12) 0.805(2) 0.152(9) Uani 0.46(3) 1 d P B 1
F9 F 0.0876(16) 0.726(3) 0.8822(16) 0.144(12) Uani 0.46(3) 1 d P B 1
F10 F 0.1286(5) 1.1107(8) 0.8848(3) 0.210(3) Uani 1 1 d D . .
F11 F -0.0738(6) 1.0822(8) 0.8762(3) 0.214(3) Uani 1 1 d D . .
F12 F 0.0286(7) 1.2444(7) 0.8593(4) 0.206(3) Uani 1 1 d D . .
F13 F 0.390(4) 1.220(4) 0.1186(19) 0.197(19) Uani 0.375(18) 1 d P A 2
F14 F 0.349(4) 1.341(3) 0.240(3) 0.177(17) Uani 0.375(18) 1 d P A 2
F15 F 0.2058(19) 1.211(3) 0.184(3) 0.223(18) Uani 0.375(18) 1 d P A 2
F16 F 0.142(2) 0.651(2) 0.8676(16) 0.149(10) Uani 0.54(3) 1 d P B 2
F17 F 0.0821(12) 0.8031(19) 0.827(2) 0.150(7) Uani 0.54(3) 1 d P B 2
F18 F 0.200(2) 0.714(2) 0.7327(11) 0.142(10) Uani 0.54(3) 1 d P B 2
N1 N 0.1202(4) 0.2737(3) 0.4645(3) 0.0657(9) Uani 1 1 d . . .
N2 N 0.2624(4) 0.7018(4) 0.1968(3) 0.0741(10) Uani 1 1 d . . .
O1 O 0.1692(4) 0.2219(3) 0.5251(4) 0.0996(13) Uani 1 1 d . . .
O2 O 0.0254(5) 0.2259(4) 0.4125(5) 0.148(2) Uani 1 1 d . . .
O3 O 0.4264(3) 1.2580(2) 0.6393(2) 0.0577(7) Uani 1 1 d . . .
O4 O 0.4338(3) 1.1574(3) 0.7716(2) 0.0669(8) Uani 1 1 d . . .
O5 O 0.3723(4) 1.0386(3) 0.2379(2) 0.0748(9) Uani 1 1 d . . .
O6 O 0.3815(4) 1.1969(3) 0.3709(2) 0.0782(10) Uani 1 1 d . . .
O7 O 0.3495(3) 0.9172(3) 0.8475(2) 0.0599(7) Uani 1 1 d . . .
O8 O 0.3273(3) 0.8103(3) 0.9775(2) 0.0683(8) Uani 1 1 d . . .
O9 O 0.1172(3) 1.0399(3) 0.6801(2) 0.0634(7) Uani 1 1 d . . .
O10 O -0.0737(3) 1.0949(4) 0.6664(3) 0.0872(11) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O8 Ag1 O7 162.77(10) 2_677 .
O8 Ag1 O4 117.28(11) 2_677 .
O7 Ag1 O4 79.38(10) . .
O8 Ag1 O5 105.45(13) 2_677 2_676
O7 Ag1 O5 80.62(12) . 2_676
O4 Ag1 O5 80.41(11) . 2_676
O8 Ag1 Ag1 85.19(8) 2_677 2_677
O7 Ag1 Ag1 77.58(7) . 2_677
O4 Ag1 Ag1 152.48(8) . 2_677
O5 Ag1 Ag1 110.21(8) 2_676 2_677
C1 Ag2 O4 129.50(11) . .
C1 Ag2 O7 147.29(11) . .
O4 Ag2 O7 81.26(10) . .
C1 Ag2 Ag5 48.99(8) . .
O4 Ag2 Ag5 80.69(8) . .
O7 Ag2 Ag5 160.33(7) . .
C1 Ag2 Ag4 51.11(8) . .
O4 Ag2 Ag4 112.10(7) . .
O7 Ag2 Ag4 135.13(8) . .
Ag5 Ag2 Ag4 60.29(3) . .
N2 Ag3 O5 110.23(14) . .
N2 Ag3 C1 127.18(13) . .
O5 Ag3 C1 122.39(11) . .
N2 Ag3 C2 99.43(13) . .
O5 Ag3 C2 149.84(11) . .
C1 Ag3 C2 27.75(10) . .
N2 Ag3 Ag5 171.36(11) . .
O5 Ag3 Ag5 76.19(9) . .
C1 Ag3 Ag5 46.21(7) . .
C2 Ag3 Ag5 73.76(8) . .
N2 Ag3 Ag4 124.48(11) . .
O5 Ag3 Ag4 104.36(8) . .
C1 Ag3 Ag4 47.97(8) . .
C2 Ag3 Ag4 60.48(7) . .
Ag5 Ag3 Ag4 57.14(2) . .
O10 Ag4 O9 162.97(11) 2_576 .
O10 Ag4 C1 95.59(11) 2_576 .
O9 Ag4 C1 100.89(11) . .
O10 Ag4 Ag4 79.64(8) 2_576 2_576
O9 Ag4 Ag4 83.54(7) . 2_576
C1 Ag4 Ag4 172.85(7) . 2_576
O10 Ag4 Ag5 100.58(10) 2_576 .
O9 Ag4 Ag5 94.05(8) . .
C1 Ag4 Ag5 45.61(7) . .
Ag4 Ag4 Ag5 140.25(3) 2_576 .
O10 Ag4 Ag2 139.66(8) 2_576 .
O9 Ag4 Ag2 56.83(8) . .
C1 Ag4 Ag2 44.10(8) . .
Ag4 Ag4 Ag2 140.22(3) 2_576 .
Ag5 Ag4 Ag2 55.48(2) . .
O10 Ag4 Ag3 52.30(8) 2_576 .
O9 Ag4 Ag3 144.73(7) . .
C1 Ag4 Ag3 45.25(8) . .
Ag4 Ag4 Ag3 131.25(3) 2_576 .
Ag5 Ag4 Ag3 56.65(2) . .
Ag2 Ag4 Ag3 88.52(4) . .
C1 Ag5 O6 128.73(12) . .
C1 Ag5 O3 128.38(11) . .
O6 Ag5 O3 93.84(11) . .
C1 Ag5 C1 107.17(9) . 2_676
O6 Ag5 C1 96.74(13) . 2_676
O3 Ag5 C1 92.72(10) . 2_676
C1 Ag5 Ag2 49.13(9) . .
O6 Ag5 Ag2 157.94(11) . .
O3 Ag5 Ag2 80.16(7) . .
C1 Ag5 Ag2 104.69(7) 2_676 .
C1 Ag5 Ag5 61.24(9) . 2_676
O6 Ag5 Ag5 125.32(10) . 2_676
O3 Ag5 Ag5 120.70(7) . 2_676
C1 Ag5 Ag5 45.94(7) 2_676 2_676
Ag2 Ag5 Ag5 74.96(2) . 2_676
C1 Ag5 Ag3 50.67(9) . .
O6 Ag5 Ag3 80.72(8) . .
O3 Ag5 Ag3 164.88(8) . .
C1 Ag5 Ag3 101.89(7) 2_676 .
Ag2 Ag5 Ag3 99.59(3) . .
Ag5 Ag5 Ag3 73.28(3) 2_676 .
C1 Ag5 Ag4 53.20(8) . .
O6 Ag5 Ag4 96.56(10) . .
O3 Ag5 Ag4 100.73(8) . .
C1 Ag5 Ag4 160.36(7) 2_676 .
Ag2 Ag5 Ag4 64.228(16) . .
Ag5 Ag5 Ag4 114.43(3) 2_676 .
Ag3 Ag5 Ag4 66.204(18) . .
C2 C1 Ag5 166.3(3) . .
C2 C1 Ag2 109.7(3) . .
Ag5 C1 Ag2 81.88(11) . .
C2 C1 Ag3 86.0(2) . .
Ag5 C1 Ag3 83.12(11) . .
Ag2 C1 Ag3 163.75(15) . .
C2 C1 Ag4 106.5(2) . .
Ag5 C1 Ag4 81.19(10) . .
Ag2 C1 Ag4 84.79(11) . .
Ag3 C1 Ag4 86.78(11) . .
C2 C1 Ag5 98.9(2) . 2_676
Ag5 C1 Ag5 72.83(9) . 2_676
Ag2 C1 Ag5 92.14(11) . 2_676
Ag3 C1 Ag5 89.36(10) . 2_676
Ag4 C1 Ag5 154.00(13) . 2_676
C1 C2 C3 175.5(3) . .
C1 C2 Ag3 66.3(2) . .
C3 C2 Ag3 117.2(2) . .
C4 C3 C8 120.0 . .
C4 C3 C2 119.54(18) . .
C8 C3 C2 120.24(18) . .
C5 C4 C3 120.0 . .
C5 C4 H4 120.0 . .
C3 C4 H4 120.0 . .
C6 C5 C4 120.0 . .
C6 C5 H5 120.0 . .
C4 C5 H5 120.0 . .
C5 C6 C7 120.0 . .
C5 C6 N1 119.6(2) . .
C7 C6 N1 120.1(2) . .
C6 C7 C8 120.0 . .
C6 C7 H7 120.0 . .
C8 C7 H7 120.0 . .
C7 C8 C3 120.0 . .
C7 C8 H8 120.0 . .
C3 C8 H8 120.0 . .
O3 C9 O4 128.7(4) . .
O3 C9 C10 115.7(4) . .
O4 C9 C10 115.6(4) . .
F1 C10 F3 104.1(6) . .
F1 C10 F2 109.7(6) . .
F3 C10 F2 103.8(6) . .
F1 C10 C9 112.1(5) . .
F3 C10 C9 111.5(5) . .
F2 C10 C9 114.8(5) . .
O5 C11 O6 129.2(4) . .
O5 C11 C12 115.5(4) . .
O6 C11 C12 115.3(4) . .
F13 C12 F4 123.0(12) . .
F13 C12 F14 112(2) . .
F4 C12 F14 36.4(19) . .
F13 C12 F5 42(2) . .
F4 C12 F5 114.0(13) . .
F14 C12 F5 132.7(17) . .
F13 C12 F6 60(2) . .
F4 C12 F6 107.0(12) . .
F14 C12 F6 72.4(17) . .
F5 C12 F6 102.1(10) . .
F13 C12 F15 110(2) . .
F4 C12 F15 53.0(13) . .
F14 C12 F15 89.2(18) . .
F5 C12 F15 73.5(15) . .
F6 C12 F15 150.6(10) . .
F13 C12 C11 121.9(11) . .
F4 C12 C11 115.1(8) . .
F14 C12 C11 114.2(15) . .
F5 C12 C11 112.5(9) . .
F6 C12 C11 104.7(7) . .
F15 C12 C11 103.7(10) . .
O8 C13 O7 129.0(4) . .
O8 C13 C14 115.0(4) . .
O7 C13 C14 116.0(3) . .
F16 C14 F18 112.1(12) . .
F16 C14 F9 51.7(9) . .
F18 C14 F9 132.9(11) . .
F16 C14 F7 128.3(10) . .
F18 C14 F7 37.4(11) . .
F9 C14 F7 111.5(13) . .
F16 C14 F17 104.1(11) . .
F18 C14 F17 101.8(10) . .
F9 C14 F17 55.2(10) . .
F7 C14 F17 65.5(11) . .
F16 C14 F8 53.1(9) . .
F18 C14 F8 68.7(11) . .
F9 C14 F8 103.6(11) . .
F7 C14 F8 103.2(12) . .
F17 C14 F8 142.5(8) . .
F16 C14 C13 115.9(6) . .
F18 C14 C13 113.5(9) . .
F9 C14 C13 112.8(8) . .
F7 C14 C13 115.4(9) . .
F17 C14 C13 107.9(7) . .
F8 C14 C13 109.1(8) . .
O9 C15 O10 129.0(4) . .
O9 C15 C16 115.7(4) . .
O10 C15 C16 115.2(4) . .
F10 C16 F11 113.0(8) . .
F10 C16 F12 103.9(7) . .
F11 C16 F12 99.5(7) . .
F10 C16 C15 115.7(6) . .
F11 C16 C15 113.2(6) . .
F12 C16 C15 109.8(7) . .
N2 C17 C18 179.0(7) . .
C17 C18 H18A 109.5 . .
C17 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C17 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
O2 N1 O1 121.6(4) . .
O2 N1 C6 119.5(4) . .
O1 N1 C6 118.7(3) . .
C17 N2 Ag3 179.7(5) . .
C9 O3 Ag5 122.3(2) . .
C9 O4 Ag2 119.4(2) . .
C9 O4 Ag1 148.7(3) . .
Ag2 O4 Ag1 91.84(10) . .
C11 O5 Ag3 125.5(3) . .
C11 O5 Ag1 135.9(3) . 2_676
Ag3 O5 Ag1 96.88(11) . 2_676
C11 O6 Ag5 120.4(3) . .
C13 O7 Ag1 126.3(2) . .
C13 O7 Ag2 136.7(2) . .
Ag1 O7 Ag2 96.24(10) . .
C13 O8 Ag1 121.9(3) . 2_677
C15 O9 Ag4 121.3(3) . .
C15 O10 Ag4 126.2(3) . 2_576
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 O8 2.182(3) 2_677
Ag1 O7 2.282(3) .
Ag1 O4 2.450(3) .
Ag1 O5 2.576(3) 2_676
Ag1 Ag1 2.8923(11) 2_677
Ag2 C1 2.216(3) .
Ag2 O4 2.321(3) .
Ag2 O7 2.324(3) .
Ag2 Ag5 2.9016(10) .
Ag2 Ag4 3.1713(11) .
Ag3 N2 2.230(4) .
Ag3 O5 2.271(3) .
Ag3 C1 2.370(3) .
Ag3 C2 2.582(3) .
Ag3 Ag5 3.0417(10) .
Ag3 Ag4 3.3317(11) .
Ag4 O10 2.230(3) 2_576
Ag4 O9 2.240(3) .
Ag4 C1 2.478(3) .
Ag4 Ag4 2.8687(13) 2_576
Ag4 Ag5 3.0587(13) .
Ag5 C1 2.212(3) .
Ag5 O6 2.299(3) .
Ag5 O3 2.349(3) .
Ag5 C1 2.698(3) 2_676
Ag5 Ag5 2.9409(11) 2_676
C1 C2 1.205(4) .
C1 Ag5 2.698(3) 2_676
C2 C3 1.432(3) .
C3 C4 1.3900 .
C3 C8 1.3900 .
C4 C5 1.3900 .
C4 H4 0.9300 .
C5 C6 1.3900 .
C5 H5 0.9300 .
C6 C7 1.3900 .
C6 N1 1.424(3) .
C7 C8 1.3900 .
C7 H7 0.9300 .
C8 H8 0.9300 .
C9 O3 1.218(5) .
C9 O4 1.233(4) .
C9 C10 1.519(6) .
C10 F1 1.277(7) .
C10 F3 1.282(8) .
C10 F2 1.285(7) .
C11 O5 1.228(5) .
C11 O6 1.230(5) .
C11 C12 1.532(6) .
C12 F13 1.126(14) .
C12 F4 1.218(13) .
C12 F14 1.27(3) .
C12 F5 1.300(12) .
C12 F6 1.415(13) .
C12 F15 1.47(2) .
C13 O8 1.219(4) .
C13 O7 1.240(4) .
C13 C14 1.536(6) .
C14 F16 1.236(11) .
C14 F18 1.241(14) .
C14 F9 1.250(13) .
C14 F7 1.263(14) .
C14 F17 1.374(13) .
C14 F8 1.376(13) .
C15 O9 1.218(5) .
C15 O10 1.239(5) .
C15 C16 1.529(8) .
C16 F10 1.249(7) .
C16 F11 1.268(8) .
C16 F12 1.349(10) .
C17 N2 1.110(6) .
C17 C18 1.466(7) .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
N1 O2 1.174(5) .
N1 O1 1.206(5) .
O5 Ag1 2.576(3) 2_676
O8 Ag1 2.182(3) 2_677
O10 Ag4 2.230(3) 2_576
