#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/44/7024488.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7024488
loop_
_publ_author_name
'Wang, Siegfried M. J.'
'Zhao, Liang'
'Mak, Thomas C. W.'
_publ_section_title
;
 Coordination networks constructed with the multinuclear silver-ethynide
 supramolecular synthon 4-nitrophenyl-C[triple bond]C subset Ag(n) (n = 3,
 4, 5).
;
_journal_issue                   8
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2108
_journal_page_last               2121
_journal_paper_doi               10.1039/b917789b
_journal_volume                  39
_journal_year                    2010
_chemical_formula_moiety         '(Ag C8 H4 N O2), 2(Ag2 C5 F6 O4), 4.5(H2 O)'
_chemical_formula_sum            'C18 H13 Ag5 F12 N O14.5'
_chemical_formula_weight         1242.64
_chemical_name_common            'Compound 11'
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.313(10)
_cell_angle_beta                 100.425(9)
_cell_angle_gamma                101.915(11)
_cell_formula_units_Z            2
_cell_length_a                   11.269(6)
_cell_length_b                   11.597(6)
_cell_length_c                   11.940(6)
_cell_measurement_reflns_used    562
_cell_measurement_temperature    296(2)
_cell_volume                     1434.4(13)
_computing_cell_refinement       'BrukerAXS APEX2 Suite 2.1.4'
_computing_data_collection       'BrukerAXS APEX2 Suite 2.1.4'
_computing_data_reduction        'BrukerAXS APEX2 Suite 2.1.4'
_computing_molecular_graphics    'BrukerAXS APEX2 Suite 2.1.4'
_computing_publication_material  'BrukerAXS APEX2 Suite 2.1.4'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'BrukerAXS Kappa APEX2 CCD'
_diffrn_measurement_method       'Phi scan and Omega scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0284
_diffrn_reflns_av_sigmaI/netI    0.0146
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            45714
_diffrn_reflns_theta_full        26.01
_diffrn_reflns_theta_max         26.01
_diffrn_reflns_theta_min         2.94
_exptl_absorpt_coefficient_mu    3.503
_exptl_absorpt_correction_T_max  0.5266
_exptl_absorpt_correction_T_min  0.3736
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    2.877
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Plate
_exptl_crystal_F_000             1174
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.31
_exptl_crystal_size_min          0.21
_refine_diff_density_max         1.442
_refine_diff_density_min         -1.288
_refine_diff_density_rms         0.085
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     448
_refine_ls_number_reflns         5606
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.055
_refine_ls_R_factor_all          0.0270
_refine_ls_R_factor_gt           0.0245
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0181P)²+4.0055P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0553
_refine_ls_wR_factor_ref         0.0568
_reflns_number_gt                5198
_reflns_number_total             5606
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b917789b.txt
_cod_data_source_block           729722
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        1434.5(12)
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'C18 H13 Ag5 F12 N O14.50'
_cod_database_code               7024488
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.87003(3) 0.91125(3) 0.35934(3) 0.04311(8) Uani 1 1 d .
Ag2 Ag 0.61565(3) 0.62322(2) 0.47308(3) 0.03595(8) Uani 1 1 d .
Ag3 Ag 0.87634(2) 0.79289(3) 0.57980(2) 0.03029(7) Uani 1 1 d .
Ag4 Ag 0.69205(3) 0.79073(4) 0.73702(3) 0.05234(10) Uani 1 1 d .
Ag5 Ag 0.67226(3) 0.88744(3) 0.50874(3) 0.04033(8) Uani 1 1 d .
C1 C 0.7529(3) 0.7377(3) 0.4058(3) 0.0252(6) Uani 1 1 d .
C2 C 0.7387(3) 0.7021(3) 0.2980(3) 0.0283(7) Uani 1 1 d .
C3 C 0.7093(2) 0.64891(19) 0.17159(13) 0.0273(7) Uani 1 1 d G
C4 C 0.7605(2) 0.5557(2) 0.12049(17) 0.0329(8) Uani 1 1 d G
H4 H 0.8178 0.5299 0.1684 0.040 Uiso 1 1 calc R
C5 C 0.7259(2) 0.50105(19) -0.00220(17) 0.0339(8) Uani 1 1 d G
H5 H 0.7602 0.4387 -0.0364 0.041 Uiso 1 1 calc R
C6 C 0.6403(2) 0.5396(2) -0.07380(13) 0.0301(7) Uani 1 1 d G
C7 C 0.5891(2) 0.6328(2) -0.02271(16) 0.0328(7) Uani 1 1 d G
H7 H 0.5318 0.6586 -0.0706 0.039 Uiso 1 1 calc R
C8 C 0.6236(2) 0.68749(18) 0.09999(17) 0.0326(7) Uani 1 1 d G
H8 H 0.5894 0.7499 0.1342 0.039 Uiso 1 1 calc R
C9 C 0.9337(3) 0.7384(3) 0.8145(3) 0.0301(7) Uani 1 1 d .
C10 C 1.0243(3) 0.7239(3) 0.9208(3) 0.0321(7) Uani 1 1 d .
C11 C 1.0388(3) 0.8254(3) 1.0374(3) 0.0285(7) Uani 1 1 d .
C12 C 1.1085(3) 0.8127(3) 1.1547(3) 0.0318(7) Uani 1 1 d .
C13 C 1.1476(3) 0.9346(3) 1.2588(3) 0.0291(7) Uani 1 1 d .
C14 C 0.4181(3) 0.6878(3) 0.5992(3) 0.0268(7) Uani 1 1 d .
C15 C 0.2953(3) 0.6738(3) 0.6402(3) 0.0289(7) Uani 1 1 d .
C16 C 0.1707(3) 0.6263(3) 0.5462(3) 0.0307(7) Uani 1 1 d .
C17 C 0.1469(3) 0.7001(3) 0.4579(3) 0.0284(7) Uani 1 1 d .
C18 C 0.1696(3) 0.8417(3) 0.5116(3) 0.0264(7) Uani 1 1 d .
F1 F 1.1380(2) 0.7289(3) 0.8984(2) 0.0565(7) Uani 1 1 d .
F2 F 0.9840(3) 0.6136(2) 0.9375(2) 0.0518(6) Uani 1 1 d .
F3 F 0.9246(2) 0.8335(3) 1.0478(2) 0.0535(7) Uani 1 1 d .
F4 F 1.0983(3) 0.9330(2) 1.0255(2) 0.0522(6) Uani 1 1 d .
F5 F 1.2103(2) 0.7750(2) 1.1359(2) 0.0548(7) Uani 1 1 d .
F6 F 1.0343(3) 0.7241(2) 1.1832(2) 0.0626(8) Uani 1 1 d .
F7 F 0.2949(2) 0.5926(2) 0.7058(2) 0.0457(6) Uani 1 1 d .
F8 F 0.2920(2) 0.7813(2) 0.71451(19) 0.0409(5) Uani 1 1 d .
F9 F 0.1622(2) 0.50960(18) 0.4831(2) 0.0450(6) Uani 1 1 d .
F10 F 0.07950(19) 0.6229(2) 0.6050(2) 0.0428(5) Uani 1 1 d .
F11 F 0.2209(2) 0.6789(2) 0.3823(2) 0.0438(5) Uani 1 1 d .
F12 F 0.0271(2) 0.6494(2) 0.3942(2) 0.0444(5) Uani 1 1 d .
N1 N 0.5985(3) 0.4785(3) -0.1992(3) 0.0384(7) Uani 1 1 d .
O1 O 0.5405(3) 0.5270(3) -0.2620(2) 0.0520(8) Uani 1 1 d .
O2 O 0.6197(4) 0.3802(3) -0.2359(3) 0.0666(10) Uani 1 1 d .
O3 O 0.9832(2) 0.8043(3) 0.7588(2) 0.0381(6) Uani 1 1 d .
O4 O 0.8227(2) 0.6874(3) 0.7996(3) 0.0469(7) Uani 1 1 d .
O5 O 1.2586(2) 0.9953(2) 1.2814(2) 0.0396(6) Uani 1 1 d .
O6 O 1.0660(2) 0.9609(3) 1.3085(2) 0.0425(6) Uani 1 1 d .
O7 O 0.4308(2) 0.5933(2) 0.5311(2) 0.0315(5) Uani 1 1 d .
O8 O 0.4933(2) 0.7904(2) 0.6418(3) 0.0421(6) Uani 1 1 d .
O9 O 0.0819(2) 0.8767(2) 0.5467(2) 0.0338(5) Uani 1 1 d .
O10 O 0.2724(2) 0.9049(2) 0.5142(3) 0.0403(6) Uani 1 1 d .
O1W O 0.7809(3) 0.9832(3) 0.1819(3) 0.0496(7) Uani 1 1 d .
H9 H 0.7147 1.0050 0.2045 0.074 Uiso 1 1 d R
H10 H 0.8393 1.0560 0.2080 0.074 Uiso 1 1 d R
O2W O 0.6415(4) 0.8964(4) 0.9229(3) 0.0738(10) Uani 1 1 d .
H11 H 0.7129 0.8806 0.9545 0.111 Uiso 1 1 d R
H12 H 0.6737 0.9684 0.9102 0.111 Uiso 1 1 d R
O3W O 0.5298(3) 0.9708(3) 0.2210(3) 0.0653(9) Uani 1 1 d .
H13 H 0.4936 0.9289 0.1440 0.098 Uiso 1 1 d R
H14 H 0.5011 1.0333 0.2572 0.098 Uiso 1 1 d R
O4W O 0.4743(3) 0.8750(4) 0.4077(4) 0.0782(12) Uani 1 1 d .
H15 H 0.4166 0.9077 0.3741 0.117 Uiso 1 1 d R
H16 H 0.4462 0.7984 0.3562 0.117 Uiso 1 1 d R
O5W O 0.4197(7) 0.8447(8) 0.9870(7) 0.078(2) Uani 0.50 1 d P
H17 H 0.4819 0.8621 0.9510 0.116 Uiso 0.50 1 d PR
H18 H 0.3772 0.7648 0.9552 0.116 Uiso 0.50 1 d PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O9 Ag1 O6 84.19(9) 2_676 1_554
O9 Ag1 C1 131.15(10) 2_676 .
O6 Ag1 C1 135.11(11) 1_554 .
O9 Ag1 C2 153.76(10) 2_676 .
O6 Ag1 C2 122.05(11) 1_554 .
C1 Ag1 C2 29.23(11) . .
O9 Ag1 O1W 80.29(10) 2_676 .
O6 Ag1 O1W 85.81(10) 1_554 .
C1 Ag1 O1W 121.96(11) . .
C2 Ag1 O1W 99.74(11) . .
O9 Ag1 Ag5 85.67(6) 2_676 .
O6 Ag1 Ag5 161.13(7) 1_554 .
C1 Ag1 Ag5 47.53(8) . .
C2 Ag1 Ag5 69.25(8) . .
O1W Ag1 Ag5 108.09(7) . .
O9 Ag1 Ag3 103.37(7) 2_676 .
O6 Ag1 Ag3 114.62(7) 1_554 .
C1 Ag1 Ag3 41.20(8) . .
C2 Ag1 Ag3 67.92(8) . .
O1W Ag1 Ag3 159.40(7) . .
Ag5 Ag1 Ag3 52.78(2) . .
C1 Ag2 O7 148.48(11) . .
C1 Ag2 O7 133.06(10) . 2_666
O7 Ag2 O7 76.79(9) . 2_666
C1 Ag2 Ag5 51.61(9) . .
O7 Ag2 Ag5 99.85(6) . .
O7 Ag2 Ag5 173.04(6) 2_666 .
C1 Ag2 Ag3 45.07(9) . .
O7 Ag2 Ag3 135.76(7) . .
O7 Ag2 Ag3 121.36(6) 2_666 .
Ag5 Ag2 Ag3 56.988(19) . .
C1 Ag2 Ag4 97.32(9) . .
O7 Ag2 Ag4 76.87(7) . .
O7 Ag2 Ag4 109.47(6) 2_666 .
Ag5 Ag2 Ag4 63.66(2) . .
Ag3 Ag2 Ag4 59.296(17) . .
C1 Ag3 O3 166.27(11) . .
C1 Ag3 O9 103.49(11) . 1_655
O3 Ag3 O9 85.18(10) . 1_655
C1 Ag3 Ag5 53.31(9) . .
O3 Ag3 Ag5 131.19(7) . .
O9 Ag3 Ag5 120.06(7) 1_655 .
C1 Ag3 Ag2 47.19(8) . .
O3 Ag3 Ag2 121.09(7) . .
O9 Ag3 Ag2 147.04(6) 1_655 .
Ag5 Ag3 Ag2 59.35(4) . .
C1 Ag3 Ag4 101.51(9) . .
O3 Ag3 Ag4 73.45(8) . .
O9 Ag3 Ag4 150.84(6) 1_655 .
Ag5 Ag3 Ag4 65.55(3) . .
Ag2 Ag3 Ag4 61.96(3) . .
C1 Ag3 Ag1 47.88(9) . .
O3 Ag3 Ag1 145.16(7) . .
O9 Ag3 Ag1 64.62(6) 1_655 .
Ag5 Ag3 Ag1 60.977(19) . .
Ag2 Ag3 Ag1 93.49(2) . .
Ag4 Ag3 Ag1 126.32(2) . .
O4 Ag4 O8 149.17(10) . .
O4 Ag4 O2W 103.06(13) . .
O8 Ag4 O2W 85.59(12) . .
O4 Ag4 O5 128.74(10) . 2_777
O8 Ag4 O5 81.41(9) . 2_777
O2W Ag4 O5 82.17(11) . 2_777
O4 Ag4 Ag3 74.66(8) . .
O8 Ag4 Ag3 113.65(8) . .
O2W Ag4 Ag3 146.82(9) . .
O5 Ag4 Ag3 74.86(6) 2_777 .
O4 Ag4 Ag2 94.43(9) . .
O8 Ag4 Ag2 68.81(7) . .
O2W Ag4 Ag2 152.24(10) . .
O5 Ag4 Ag2 103.55(7) 2_777 .
Ag3 Ag4 Ag2 58.75(3) . .
O4 Ag4 Ag5 128.12(8) . .
O8 Ag4 Ag5 63.66(8) . .
O2W Ag4 Ag5 123.35(10) . .
O5 Ag4 Ag5 48.82(6) 2_777 .
Ag3 Ag4 Ag5 54.02(2) . .
Ag2 Ag4 Ag5 54.82(4) . .
O4W Ag5 C1 111.28(14) . .
O4W Ag5 O5 118.16(13) . 2_777
C1 Ag5 O5 127.98(11) . 2_777
O4W Ag5 O10 85.38(13) . 2_676
C1 Ag5 O10 118.47(10) . 2_676
O5 Ag5 O10 81.65(10) 2_777 2_676
O4W Ag5 Ag3 155.06(12) . .
C1 Ag5 Ag3 47.96(8) . .
O5 Ag5 Ag3 80.05(7) 2_777 .
O10 Ag5 Ag3 115.60(6) 2_676 .
O4W Ag5 Ag2 92.50(12) . .
C1 Ag5 Ag2 48.79(8) . .
O5 Ag5 Ag2 112.22(7) 2_777 .
O10 Ag5 Ag2 165.00(7) 2_676 .
Ag3 Ag5 Ag2 63.66(2) . .
O4W Ag5 Ag1 113.85(10) . .
C1 Ag5 Ag1 50.28(8) . .
O5 Ag5 Ag1 116.42(7) 2_777 .
O10 Ag5 Ag1 68.54(6) 2_676 .
Ag3 Ag5 Ag1 66.24(3) . .
Ag2 Ag5 Ag1 99.048(16) . .
O4W Ag5 Ag4 116.19(9) . .
C1 Ag5 Ag4 93.74(9) . .
O5 Ag5 Ag4 50.80(7) 2_777 .
O10 Ag5 Ag4 132.40(7) 2_676 .
Ag3 Ag5 Ag4 60.438(17) . .
Ag2 Ag5 Ag4 61.53(2) . .
Ag1 Ag5 Ag4 126.48(2) . .
C2 C1 Ag3 148.2(3) . .
C2 C1 Ag2 113.7(2) . .
Ag3 C1 Ag2 87.74(12) . .
C2 C1 Ag5 126.4(3) . .
Ag3 C1 Ag5 78.74(11) . .
Ag2 C1 Ag5 79.60(11) . .
C2 C1 Ag1 75.8(2) . .
Ag3 C1 Ag1 90.92(11) . .
Ag2 C1 Ag1 161.65(16) . .
Ag5 C1 Ag1 82.19(11) . .
C1 C2 C3 173.1(3) . .
C1 C2 Ag1 75.0(2) . .
C3 C2 Ag1 111.6(2) . .
C4 C3 C8 120.0 . .
C4 C3 C2 120.89(19) . .
C8 C3 C2 119.03(19) . .
C3 C4 C5 120.0 . .
C3 C4 H4 120.0 . .
C5 C4 H4 120.0 . .
C6 C5 C4 120.0 . .
C6 C5 H5 120.0 . .
C4 C5 H5 120.0 . .
C7 C6 C5 120.0 . .
C7 C6 N1 119.7(2) . .
C5 C6 N1 120.2(2) . .
C6 C7 C8 120.0 . .
C6 C7 H7 120.0 . .
C8 C7 H7 120.0 . .
C7 C8 C3 120.0 . .
C7 C8 H8 120.0 . .
C3 C8 H8 120.0 . .
O4 C9 O3 129.1(3) . .
O4 C9 C10 115.7(3) . .
O3 C9 C10 115.2(3) . .
F2 C10 F1 106.7(3) . .
F2 C10 C11 108.6(3) . .
F1 C10 C11 108.6(3) . .
F2 C10 C9 110.8(3) . .
F1 C10 C9 110.1(3) . .
C11 C10 C9 111.8(3) . .
F3 C11 F4 107.1(3) . .
F3 C11 C12 107.8(3) . .
F4 C11 C12 107.7(3) . .
F3 C11 C10 107.9(3) . .
F4 C11 C10 107.5(3) . .
C12 C11 C10 118.3(3) . .
F6 C12 F5 107.6(3) . .
F6 C12 C11 108.3(3) . .
F5 C12 C11 108.1(3) . .
F6 C12 C13 109.7(3) . .
F5 C12 C13 110.0(3) . .
C11 C12 C13 113.0(3) . .
O6 C13 O5 127.5(3) . .
O6 C13 C12 116.9(3) . .
O5 C13 C12 115.7(3) . .
O8 C14 O7 128.2(3) . .
O8 C14 C15 115.6(3) . .
O7 C14 C15 116.1(3) . .
F8 C15 F7 106.1(3) . .
F8 C15 C16 106.5(3) . .
F7 C15 C16 106.2(3) . .
F8 C15 C14 111.1(3) . .
F7 C15 C14 107.0(3) . .
C16 C15 C14 119.1(3) . .
F10 C16 F9 108.2(3) . .
F10 C16 C15 107.0(3) . .
F9 C16 C15 107.9(3) . .
F10 C16 C17 108.1(3) . .
F9 C16 C17 108.1(3) . .
C15 C16 C17 117.3(3) . .
F11 C17 F12 107.4(3) . .
F11 C17 C16 106.8(3) . .
F12 C17 C16 106.2(3) . .
F11 C17 C18 109.2(3) . .
F12 C17 C18 109.9(3) . .
C16 C17 C18 116.9(3) . .
O10 C18 O9 128.2(3) . .
O10 C18 C17 115.6(3) . .
O9 C18 C17 116.2(3) . .
O2 N1 O1 123.9(3) . .
O2 N1 C6 117.8(3) . .
O1 N1 C6 118.2(3) . .
C9 O3 Ag3 118.3(2) . .
C9 O4 Ag4 114.3(2) . .
C13 O5 Ag5 109.5(2) . 2_777
C13 O5 Ag4 120.0(2) . 2_777
Ag5 O5 Ag4 80.38(8) 2_777 2_777
C13 O6 Ag1 153.1(3) . 1_556
C14 O7 Ag2 113.7(2) . .
C14 O7 Ag2 133.1(2) . 2_666
Ag2 O7 Ag2 103.21(9) . 2_666
C14 O8 Ag4 115.1(2) . .
C18 O9 Ag1 113.9(2) . 2_676
C18 O9 Ag3 140.6(2) . 1_455
Ag1 O9 Ag3 104.63(9) 2_676 1_455
C18 O10 Ag5 128.9(2) . 2_676
Ag1 O1W H9 100.1 . .
Ag1 O1W H10 93.2 . .
H9 O1W H10 101.7 . .
Ag4 O2W H11 80.5 . .
Ag4 O2W H12 87.7 . .
H11 O2W H12 99.3 . .
H13 O3W H14 119.1 . .
Ag5 O4W H15 152.4 . .
Ag5 O4W H16 105.6 . .
H15 O4W H16 97.4 . .
H17 O5W H18 109.8 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 O9 2.338(3) 2_676
Ag1 O6 2.389(3) 1_554
Ag1 C1 2.412(3) .
Ag1 C2 2.421(3) .
Ag1 O1W 2.578(3) .
Ag1 Ag5 3.1071(12) .
Ag1 Ag3 3.2522(13) .
Ag2 C1 2.220(3) .
Ag2 O7 2.298(3) .
Ag2 O7 2.443(3) 2_666
Ag2 Ag5 2.9029(16) .
Ag2 Ag3 3.0240(13) .
Ag2 Ag4 3.1221(14) .
Ag3 C1 2.143(3) .
Ag3 O3 2.214(3) .
Ag3 O9 2.462(3) 1_655
Ag3 Ag5 2.8295(11) .
Ag3 Ag4 3.0415(12) .
Ag4 O4 2.222(3) .
Ag4 O8 2.320(3) .
Ag4 O2W 2.480(4) .
Ag4 O5 2.502(3) 2_777
Ag4 Ag5 3.1830(14) .
Ag5 O4W 2.294(3) .
Ag5 C1 2.313(3) .
Ag5 O5 2.430(3) 2_777
Ag5 O10 2.455(3) 2_676
C1 C2 1.219(5) .
C2 C3 1.430(4) .
C3 C4 1.3900 .
C3 C8 1.3900 .
C4 C5 1.3900 .
C4 H4 0.9300 .
C5 C6 1.3900 .
C5 H5 0.9300 .
C6 C7 1.3900 .
C6 N1 1.431(3) .
C7 C8 1.3900 .
C7 H7 0.9300 .
C8 H8 0.9300 .
C9 O4 1.229(4) .
C9 O3 1.244(4) .
C9 C10 1.545(5) .
C10 F2 1.342(4) .
C10 F1 1.348(4) .
C10 C11 1.542(5) .
C11 F3 1.335(4) .
C11 F4 1.343(4) .
C11 C12 1.534(5) .
C12 F6 1.339(4) .
C12 F5 1.345(4) .
C12 C13 1.554(5) .
C13 O6 1.231(4) .
C13 O5 1.247(4) .
C14 O8 1.234(4) .
C14 O7 1.245(4) .
C14 C15 1.540(5) .
C15 F8 1.352(4) .
C15 F7 1.366(4) .
C15 C16 1.529(5) .
C16 F10 1.345(4) .
C16 F9 1.351(4) .
C16 C17 1.535(5) .
C17 F11 1.348(4) .
C17 F12 1.351(4) .
C17 C18 1.556(5) .
C18 O10 1.227(4) .
C18 O9 1.244(4) .
N1 O2 1.205(4) .
N1 O1 1.220(4) .
O5 Ag5 2.430(3) 2_777
O5 Ag4 2.502(3) 2_777
O6 Ag1 2.389(3) 1_556
O7 Ag2 2.443(3) 2_666
O9 Ag1 2.338(3) 2_676
O9 Ag3 2.462(3) 1_455
O10 Ag5 2.456(3) 2_676
O1W H9 0.9000 .
O1W H10 0.9000 .
O2W H11 0.8994 .
O2W H12 0.8999 .
O3W H13 0.9000 .
O3W H14 0.9000 .
O4W H15 0.8995 .
O4W H16 0.9002 .
O5W H17 0.9001 .
O5W H18 0.9000 .
