#------------------------------------------------------------------------------
#$Date: 2016-03-25 16:03:25 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179949 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/44/7024491.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7024491
loop_
_publ_author_name
'Wang, Siegfried M. J.'
'Zhao, Liang'
'Mak, Thomas C. W.'
_publ_section_title
;
 Coordination networks constructed with the multinuclear silver-ethynide
 supramolecular synthon 4-nitrophenyl-C[triple bond]C subset Ag(n) (n = 3,
 4, 5).
;
_journal_issue                   8
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2108
_journal_page_last               2121
_journal_paper_doi               10.1039/b917789b
_journal_volume                  39
_journal_year                    2010
_chemical_formula_moiety
'4(Ag C8 H4 N O2), 12(Ag C2 F3 O2), 4(C8 H4 N2), (H2 O)'
_chemical_formula_sum            'C88 H34 Ag16 F36 N12 O33'
_chemical_formula_weight         4197.19
_chemical_name_common            'Compound 10'
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 101.4790(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   23.0077(11)
_cell_length_b                   17.0544(8)
_cell_length_c                   28.6284(14)
_cell_measurement_reflns_used    935
_cell_measurement_temperature    293(2)
_cell_volume                     11008.6(9)
_computing_cell_refinement       'BrukerAXS APEX 2.1.4 Suite'
_computing_data_collection       'BrukerAXS APEX 2.1.4 Suite'
_computing_data_reduction        'BrukerAXS APEX 2.1.4 Suite'
_computing_molecular_graphics    'BrukerAXS APEX 2.1.4 Suite'
_computing_publication_material  'BrukerAXS APEX 2.1.4 Suite'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device_type  'BrukerAXS Kappa APEX2 CCD'
_diffrn_measurement_method       'Phi scan and Omega scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0450
_diffrn_reflns_av_sigmaI/netI    0.0154
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            384259
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.40
_exptl_absorpt_coefficient_mu    2.920
_exptl_absorpt_correction_T_max  0.4458
_exptl_absorpt_correction_T_min  0.3735
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    2.532
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Needle
_exptl_crystal_F_000             7944
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.39
_exptl_crystal_size_min          0.33
_refine_ls_extinction_coef       0.000004(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.094
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1695
_refine_ls_number_reflns         19401
_refine_ls_number_restraints     11
_refine_ls_restrained_S_all      1.094
_refine_ls_R_factor_all          0.0532
_refine_ls_R_factor_gt           0.0383
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0194P)²+105.0305P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0795
_refine_ls_wR_factor_ref         0.0934
_reflns_number_gt                15948
_reflns_number_total             19401
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b917789b.txt
_cod_data_source_block           729726
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7024491
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.25781(2) 0.71502(3) 0.101140(18) 0.03397(12) Uani 1 1 d . . .
Ag2 Ag 0.194677(19) 0.83898(3) 0.135816(17) 0.02890(11) Uani 1 1 d . . .
Ag3 Ag 0.19342(2) 0.78808(3) 0.014908(18) 0.03275(12) Uani 1 1 d . . .
Ag4 Ag 0.18929(2) 0.81572(3) 0.26069(2) 0.04006(13) Uani 1 1 d . . .
Ag5 Ag 0.18601(2) 0.79883(3) 0.390847(19) 0.03604(12) Uani 1 1 d . . .
Ag6 Ag 0.25945(2) 0.71289(3) 0.20571(2) 0.03812(13) Uani 1 1 d . . .
Ag7 Ag 0.25955(2) 0.91104(3) 0.33382(2) 0.03856(13) Uani 1 1 d . . .
Ag8 Ag 0.05357(2) 0.87535(3) 0.17941(2) 0.04211(14) Uani 1 1 d . . .
Ag9 Ag 0.28006(2) 0.90871(3) 0.22423(2) 0.04171(14) Uani 1 1 d . . .
Ag10 Ag 0.25986(3) 0.64037(4) -0.02168(2) 0.04879(16) Uani 1 1 d . . .
Ag11 Ag 0.05035(2) 0.77210(4) -0.07497(2) 0.04448(14) Uani 1 1 d . . .
Ag12 Ag 0.27104(2) 0.81842(3) -0.05456(2) 0.04025(13) Uani 1 1 d . . .
Ag13 Ag 0.29933(3) 1.10970(4) 0.19326(3) 0.0677(2) Uani 1 1 d . . .
Ag14 Ag 0.27481(3) 0.99650(4) -0.02173(3) 0.06124(18) Uani 1 1 d . A .
Ag15 Ag 0.25724(3) 0.71131(4) 0.34040(2) 0.05806(18) Uani 1 1 d . . .
Ag16 Ag 0.28555(5) 0.89076(5) 0.07814(4) 0.0430(2) Uani 0.80 1 d P . .
Ag17 Ag 0.2828(2) 0.9259(7) 0.1030(4) 0.222(7) Uani 0.20 1 d P . .
C1 C 0.2852(3) 0.7681(4) 0.0272(2) 0.0308(14) Uani 1 1 d . . .
C2 C 0.3392(3) 0.7671(4) 0.0328(2) 0.0297(14) Uani 1 1 d . . .
C3 C 0.40252(12) 0.7613(2) 0.04017(17) 0.0334(15) Uani 1 1 d G . .
C4 C 0.42914(16) 0.6882(2) 0.04874(17) 0.0373(16) Uani 1 1 d G . .
H4 H 0.4060 0.6440 0.0505 0.045 Uiso 1 1 calc R A .
C5 C 0.49036(17) 0.6811(2) 0.05472(17) 0.0396(16) Uani 1 1 d G A .
H5 H 0.5082 0.6321 0.0604 0.048 Uiso 1 1 calc R . .
C6 C 0.52496(12) 0.7471(3) 0.05213(18) 0.0409(17) Uani 1 1 d G . .
C7 C 0.49835(17) 0.8203(2) 0.04356(19) 0.051(2) Uani 1 1 d G A .
H7 H 0.5215 0.8645 0.0418 0.061 Uiso 1 1 calc R . .
C8 C 0.43713(18) 0.82740(19) 0.03758(18) 0.0432(18) Uani 1 1 d G . .
H8 H 0.4193 0.8763 0.0318 0.052 Uiso 1 1 calc R A .
C9 C 0.2879(3) 0.8199(4) 0.1540(2) 0.0290(14) Uani 1 1 d . . .
C10 C 0.3409(3) 0.8371(4) 0.1628(2) 0.0284(13) Uani 1 1 d . . .
C11 C 0.40420(12) 0.8460(2) 0.17179(16) 0.0286(13) Uani 1 1 d G . .
C12 C 0.43887(17) 0.78126(19) 0.16625(16) 0.0354(15) Uani 1 1 d G A .
H12 H 0.4210 0.7332 0.1573 0.043 Uiso 1 1 calc R . .
C13 C 0.50022(16) 0.7884(2) 0.17402(18) 0.0451(18) Uani 1 1 d G A .
H13 H 0.5234 0.7450 0.1703 0.054 Uiso 1 1 calc R . .
C14 C 0.52691(12) 0.8603(3) 0.18734(17) 0.0399(17) Uani 1 1 d G A .
C15 C 0.49224(17) 0.9250(2) 0.19288(18) 0.0440(18) Uani 1 1 d G A .
H15 H 0.5101 0.9731 0.2018 0.053 Uiso 1 1 calc R . .
C16 C 0.43088(16) 0.9179(2) 0.18511(17) 0.0398(17) Uani 1 1 d G A .
H16 H 0.4077 0.9612 0.1888 0.048 Uiso 1 1 calc R . .
C17 C 0.2820(3) 0.7985(4) 0.2757(2) 0.0284(13) Uani 1 1 d . . .
C18 C 0.3336(3) 0.7791(4) 0.2820(2) 0.0313(14) Uani 1 1 d . . .
C19 C 0.39595(13) 0.7619(3) 0.28960(17) 0.0345(15) Uani 1 1 d G . .
C20 C 0.43654(18) 0.8231(2) 0.29917(19) 0.0458(18) Uani 1 1 d G . .
H20 H 0.4233 0.8741 0.3018 0.055 Uiso 1 1 calc R . .
C21 C 0.49690(17) 0.8079(3) 0.3048(2) 0.054(2) Uani 1 1 d G . .
H21 H 0.5241 0.8488 0.3112 0.065 Uiso 1 1 calc R . .
C22 C 0.51667(14) 0.7316(3) 0.3009(2) 0.052(2) Uani 1 1 d G . .
C23 C 0.4761(2) 0.6705(2) 0.2913(2) 0.059(2) Uani 1 1 d G . .
H23 H 0.4893 0.6195 0.2887 0.071 Uiso 1 1 calc R . .
C24 C 0.41572(18) 0.6857(2) 0.28569(19) 0.050(2) Uani 1 1 d G . .
H24 H 0.3886 0.6448 0.2793 0.060 Uiso 1 1 calc R . .
C25 C 0.2800(3) 0.8028(4) 0.4029(2) 0.0291(14) Uani 1 1 d . . .
C26 C 0.3325(3) 0.8215(4) 0.4119(2) 0.0293(14) Uani 1 1 d . . .
C27 C 0.39435(13) 0.8400(2) 0.42161(17) 0.0334(15) Uani 1 1 d G . .
C28 C 0.43618(17) 0.78155(19) 0.42053(17) 0.0378(16) Uani 1 1 d G . .
H28 H 0.4240 0.7303 0.4132 0.045 Uiso 1 1 calc R . .
C29 C 0.49627(16) 0.7998(2) 0.43042(18) 0.0441(18) Uani 1 1 d G . .
H29 H 0.5243 0.7607 0.4297 0.053 Uiso 1 1 calc R . .
C30 C 0.51451(13) 0.8765(3) 0.44140(18) 0.0448(18) Uani 1 1 d G . .
C31 C 0.47267(19) 0.9349(2) 0.4425(2) 0.055(2) Uani 1 1 d G . .
H31 H 0.4849 0.9862 0.4498 0.066 Uiso 1 1 calc R . .
C32 C 0.41259(17) 0.9166(2) 0.43259(19) 0.0482(19) Uani 1 1 d G . .
H32 H 0.3846 0.9557 0.4333 0.058 Uiso 1 1 calc R . .
C33 C 0.2002(3) 0.5347(5) 0.0904(3) 0.0470(19) Uani 1 1 d . . .
C34 C 0.1968(2) 0.4495(2) 0.0891(2) 0.0438(18) Uani 1 1 d G . .
C35 C 0.24815(16) 0.4064(3) 0.0896(2) 0.056(2) Uani 1 1 d G . .
H35 H 0.2838 0.4321 0.0896 0.068 Uiso 1 1 calc R . .
C36 C 0.24621(17) 0.3249(3) 0.0900(2) 0.060(2) Uani 1 1 d G . .
H36 H 0.2806 0.2961 0.0903 0.073 Uiso 1 1 calc R . .
C37 C 0.1929(2) 0.2866(2) 0.0899(2) 0.052(2) Uani 1 1 d G . .
H37 H 0.1916 0.2321 0.0902 0.062 Uiso 1 1 calc R . .
C38 C 0.14149(16) 0.3297(3) 0.08941(18) 0.0424(17) Uani 1 1 d G . .
C39 C 0.14343(16) 0.4112(3) 0.08900(18) 0.0427(17) Uani 1 1 d G . .
H39 H 0.1090 0.4400 0.0887 0.051 Uiso 1 1 calc R . .
C40 C 0.0869(3) 0.2897(5) 0.0889(3) 0.0450(18) Uani 1 1 d . . .
C41 C 0.2350(4) 0.5465(5) 0.2806(3) 0.059(2) Uani 1 1 d . . .
C42 C 0.2057(2) 0.4804(2) 0.25536(18) 0.0472(19) Uani 1 1 d G . .
C43 C 0.23742(15) 0.4146(3) 0.24641(18) 0.0432(18) Uani 1 1 d G . .
H43 H 0.2786 0.4145 0.2546 0.052 Uiso 1 1 calc R . .
C44 C 0.20752(19) 0.3488(2) 0.22526(18) 0.0412(17) Uani 1 1 d G . .
C45 C 0.14594(19) 0.3489(3) 0.21307(18) 0.053(2) Uani 1 1 d G . .
H45 H 0.1259 0.3049 0.1989 0.064 Uiso 1 1 calc R . .
C46 C 0.11427(15) 0.4147(4) 0.2220(2) 0.066(3) Uani 1 1 d G . .
H46 H 0.0731 0.4148 0.2139 0.079 Uiso 1 1 calc R . .
C47 C 0.1442(2) 0.4805(3) 0.24318(19) 0.062(3) Uani 1 1 d G . .
H47 H 0.1230 0.5245 0.2492 0.075 Uiso 1 1 calc R . .
C48 C 0.2389(3) 0.2794(5) 0.2177(3) 0.0475(19) Uani 1 1 d . . .
C49 C 0.2245(4) 1.1202(6) 0.3187(3) 0.059(2) Uani 1 1 d . . .
C50 C 0.21403(19) 1.2007(2) 0.32877(18) 0.0476(19) Uani 1 1 d G . .
C51 C 0.15664(16) 1.2298(3) 0.32331(17) 0.0424(18) Uani 1 1 d G . .
H51 H 0.1244 1.1972 0.3123 0.051 Uiso 1 1 calc R . .
C52 C 0.14740(13) 1.3076(3) 0.33431(17) 0.0379(16) Uani 1 1 d G . .
C53 C 0.19556(18) 1.3563(2) 0.35076(18) 0.0448(18) Uani 1 1 d G . .
H53 H 0.1894 1.4084 0.3581 0.054 Uiso 1 1 calc R . .
C54 C 0.25295(15) 1.3272(3) 0.35621(19) 0.054(2) Uani 1 1 d G . .
H54 H 0.2852 1.3598 0.3672 0.065 Uiso 1 1 calc R . .
C55 C 0.26219(14) 1.2494(3) 0.3452(2) 0.054(2) Uani 1 1 d G . .
H55 H 0.3006 1.2299 0.3489 0.065 Uiso 1 1 calc R . .
C56 C 0.0880(3) 1.3358(4) 0.3291(2) 0.0350(15) Uani 1 1 d . . .
C57 C 0.2340(4) 1.1819(5) -0.0227(4) 0.063(2) Uani 1 1 d . . .
C58 C 0.20863(18) 1.2559(2) -0.03734(19) 0.0423(17) Uani 1 1 d G . .
C59 C 0.24426(14) 1.3199(3) -0.0426(2) 0.048(2) Uani 1 1 d G . .
H59 H 0.2853 1.3148 -0.0356 0.058 Uiso 1 1 calc R . .
C60 C 0.21851(19) 1.3913(2) -0.0584(2) 0.050(2) Uani 1 1 d G . .
C61 C 0.1571(2) 1.3987(2) -0.0690(2) 0.052(2) Uani 1 1 d G . .
H61 H 0.1399 1.4465 -0.0796 0.062 Uiso 1 1 calc R . .
C62 C 0.12150(14) 1.3348(3) -0.0637(2) 0.053(2) Uani 1 1 d G . .
H62 H 0.0804 1.3399 -0.0707 0.063 Uiso 1 1 calc R . .
C63 C 0.14725(18) 1.2634(2) -0.0479(2) 0.0471(19) Uani 1 1 d G . .
H63 H 0.1234 1.2207 -0.0443 0.056 Uiso 1 1 calc R . .
C64 C 0.2542(4) 1.4547(5) -0.0674(4) 0.063(2) Uani 1 1 d . . .
C65 C 0.1657(3) 0.9984(4) 0.1882(2) 0.0282(13) Uani 1 1 d . . .
C66 C 0.1225(3) 1.0675(4) 0.1850(3) 0.0420(17) Uani 1 1 d . . .
C67 C 0.1547(3) 0.9017(4) -0.0838(2) 0.0370(16) Uani 1 1 d . . .
C68 C 0.1062(3) 0.9599(4) -0.1072(3) 0.0437(18) Uani 1 1 d . . .
C69 C 0.1162(3) 0.9275(4) 0.3093(3) 0.0360(15) Uani 1 1 d . . .
C70 C 0.0606(3) 0.9764(5) 0.3122(3) 0.0419(17) Uani 1 1 d . . .
C71 C 0.3431(3) 0.5919(4) 0.1651(2) 0.0359(15) Uani 1 1 d . . .
C72 C 0.3845(4) 0.5190(5) 0.1722(3) 0.059(2) Uani 1 1 d . . .
C73 C 0.1251(3) 0.6932(4) 0.1819(2) 0.0330(15) Uani 1 1 d . . .
C74 C 0.0680(3) 0.6554(4) 0.1531(3) 0.0417(17) Uani 1 1 d . . .
C75 C 0.3632(3) 1.0125(4) 0.2975(3) 0.0363(16) Uani 1 1 d . . .
C76 C 0.4061(5) 1.0789(7) 0.3151(4) 0.074(3) Uani 1 1 d . . .
C77 C 0.0795(3) 0.8155(4) 0.0551(3) 0.0369(16) Uani 1 1 d . . .
C78 C 0.0115(3) 0.8254(6) 0.0417(3) 0.053(2) Uani 1 1 d . . .
C79 C 0.0957(3) 0.7219(4) 0.3144(2) 0.0376(16) Uani 1 1 d . . .
C80 C 0.0328(4) 0.6999(5) 0.2883(3) 0.055(2) Uani 1 1 d . . .
C81 C 0.1768(3) 0.9844(4) 0.0507(3) 0.0410(17) Uani 1 1 d . A .
C82 C 0.1213(4) 1.0348(5) 0.0360(3) 0.052(2) Uani 1 1 d . . .
C83 C 0.3494(4) 1.0348(6) 0.0898(4) 0.062(2) Uani 1 1 d D . .
C84 C 0.3851(7) 1.1150(9) 0.0758(7) 0.138(7) Uani 1 1 d D . .
C85 C 0.1283(3) 0.6064(4) -0.0313(2) 0.0376(16) Uani 1 1 d . B .
C86 C 0.0706(3) 0.5707(5) -0.0212(3) 0.0472(19) Uani 1 1 d . . .
F1 F 0.06883(19) 1.0508(3) 0.1614(2) 0.0700(15) Uani 1 1 d . . .
F2 F 0.1410(2) 1.1294(3) 0.1643(2) 0.0758(16) Uani 1 1 d . . .
F3 F 0.1173(2) 1.0903(4) 0.2283(2) 0.0820(18) Uani 1 1 d . . .
F4 F 0.1196(2) 1.0329(3) -0.09264(18) 0.0602(12) Uani 1 1 d . . .
F5 F 0.0533(2) 0.9445(3) -0.0983(2) 0.0762(16) Uani 1 1 d . . .
F6 F 0.1018(3) 0.9597(3) -0.15408(17) 0.0833(18) Uani 1 1 d . . .
F7 F 0.02184(18) 0.9811(3) 0.27175(17) 0.0558(12) Uani 1 1 d . . .
F8 F 0.0756(2) 1.0500(3) 0.3250(2) 0.0806(18) Uani 1 1 d . . .
F9 F 0.0326(2) 0.9473(4) 0.3439(2) 0.088(2) Uani 1 1 d . . .
F10 F 0.4279(2) 0.5267(3) 0.20940(19) 0.0745(16) Uani 1 1 d . . .
F11 F 0.3541(3) 0.4551(3) 0.1808(3) 0.102(2) Uani 1 1 d . . .
F12 F 0.4061(4) 0.5011(5) 0.1352(2) 0.128(3) Uani 1 1 d . . .
F13 F 0.01911(19) 0.6950(3) 0.15446(19) 0.0653(14) Uani 1 1 d . . .
F14 F 0.0600(2) 0.5837(3) 0.1676(2) 0.0741(16) Uani 1 1 d . . .
F15 F 0.0712(2) 0.6511(3) 0.10727(17) 0.0693(14) Uani 1 1 d . . .
F16 F 0.4511(3) 1.0823(6) 0.2963(4) 0.153(4) Uani 1 1 d . . .
F17 F 0.3813(4) 1.1478(4) 0.3026(4) 0.159(4) Uani 1 1 d . . .
F18 F 0.4228(7) 1.0817(8) 0.3581(3) 0.288(10) Uani 1 1 d . . .
F19 F -0.0137(2) 0.7537(4) 0.0305(3) 0.105(2) Uani 1 1 d . . .
F20 F -0.0048(2) 0.8606(4) 0.0010(2) 0.0860(19) Uani 1 1 d . . .
F21 F -0.0120(2) 0.8559(6) 0.0728(2) 0.146(4) Uani 1 1 d . . .
F22 F 0.0083(3) 0.7577(4) 0.2618(2) 0.100(2) Uani 1 1 d . . .
F23 F 0.0325(3) 0.6389(4) 0.2596(2) 0.105(2) Uani 1 1 d . . .
F24 F -0.0018(2) 0.6817(4) 0.3180(2) 0.093(2) Uani 1 1 d . . .
F25 F 0.0841(7) 0.9989(10) 0.0001(5) 0.077(6) Uani 0.50(2) 1 d P A 1
F26 F 0.1285(9) 1.1011(10) 0.0219(12) 0.092(9) Uani 0.50(2) 1 d P A 1
F27 F 0.0900(8) 1.0427(14) 0.0679(5) 0.081(8) Uani 0.50(2) 1 d P A 1
F28 F 0.3527(5) 1.1761(7) 0.0885(4) 0.179(4) Uiso 1 1 d . . .
F29 F 0.3956(5) 1.1159(6) 0.0346(3) 0.160(4) Uani 1 1 d . . .
F30 F 0.4388(4) 1.1122(6) 0.1055(3) 0.163(4) Uani 1 1 d . . .
F31 F 0.0364(10) 0.552(2) -0.0597(5) 0.115(16) Uani 0.51(5) 1 d P B 1
F32 F 0.0786(6) 0.5125(15) 0.0067(12) 0.102(14) Uani 0.51(5) 1 d P B 1
F33 F 0.0419(11) 0.6231(10) -0.0003(11) 0.090(11) Uani 0.51(5) 1 d P B 1
F37 F 0.1299(16) 1.1016(16) 0.0627(12) 0.165(15) Uani 0.50(2) 1 d P A 2
F38 F 0.0752(8) 1.0059(13) 0.0408(19) 0.19(2) Uani 0.50(2) 1 d P A 2
F39 F 0.1222(13) 1.072(2) -0.0041(9) 0.137(14) Uani 0.50(2) 1 d P A 2
F40 F 0.0712(9) 0.567(2) 0.0246(5) 0.106(15) Uani 0.49(5) 1 d P B 2
F41 F 0.0214(6) 0.6041(15) -0.0397(13) 0.099(15) Uani 0.49(5) 1 d P B 2
F42 F 0.0622(10) 0.4971(11) -0.0344(14) 0.103(14) Uani 0.49(5) 1 d P B 2
N1 N 0.5886(3) 0.7388(5) 0.0573(3) 0.060(2) Uani 1 1 d . . .
N2 N 0.5910(3) 0.8675(5) 0.1958(3) 0.060(2) Uani 1 1 d . . .
N3 N 0.5792(3) 0.7172(6) 0.3057(3) 0.077(3) Uani 1 1 d . . .
N4 N 0.5767(3) 0.8963(5) 0.4525(3) 0.063(2) Uani 1 1 d . . .
N5 N 0.2058(3) 0.6022(4) 0.0927(2) 0.0428(14) Uani 1 1 d . . .
N6 N 0.0429(3) 0.2590(4) 0.0887(2) 0.0513(17) Uani 1 1 d . . .
N7 N 0.2556(4) 0.5985(5) 0.3018(3) 0.071(2) Uani 1 1 d . . .
N8 N 0.2615(3) 0.2221(4) 0.2112(3) 0.068(2) Uani 1 1 d . . .
N9 N 0.2338(3) 1.0562(5) 0.3127(3) 0.076(2) Uani 1 1 d . . .
N10 N 0.0406(2) 1.3585(4) 0.3253(2) 0.0389(14) Uani 1 1 d . . .
N11 N 0.2518(4) 1.1214(5) -0.0138(5) 0.112(4) Uani 1 1 d . . .
N12 N 0.2824(4) 1.5063(5) -0.0747(4) 0.089(3) Uani 1 1 d . . .
O1 O 0.6080(3) 0.6736(5) 0.0529(3) 0.090(2) Uani 1 1 d . . .
O2 O 0.6191(3) 0.7965(5) 0.0642(3) 0.103(3) Uani 1 1 d . . .
O3 O 0.6185(3) 0.8136(5) 0.1839(4) 0.114(3) Uani 1 1 d . . .
O4 O 0.6129(3) 0.9298(6) 0.2116(3) 0.095(3) Uani 1 1 d . . .
O5 O 0.5938(3) 0.6486(5) 0.3021(3) 0.093(3) Uani 1 1 d . . .
O6 O 0.6134(3) 0.7716(6) 0.3145(4) 0.132(4) Uani 1 1 d . . .
O7 O 0.6122(3) 0.8488(5) 0.4442(3) 0.093(3) Uani 1 1 d . . .
O8 O 0.5894(3) 0.9618(4) 0.4705(3) 0.081(2) Uani 1 1 d . . .
O9 O 0.14380(19) 0.9325(3) 0.17918(18) 0.0366(11) Uani 1 1 d . . .
O10 O 0.21912(19) 1.0148(3) 0.20111(18) 0.0383(11) Uani 1 1 d . . .
O11 O 0.1385(2) 0.8424(3) -0.06485(18) 0.0435(12) Uani 1 1 d . . .
O12 O 0.2058(2) 0.9201(3) -0.08754(18) 0.0424(12) Uani 1 1 d . A .
O13 O 0.11319(19) 0.8900(3) 0.27125(17) 0.0394(11) Uani 1 1 d . . .
O14 O 0.1566(2) 0.9314(3) 0.34477(18) 0.0443(12) Uani 1 1 d . . .
O15 O 0.3391(2) 0.6255(3) 0.12635(17) 0.0391(11) Uani 1 1 d . . .
O16 O 0.3193(2) 0.6060(3) 0.19888(18) 0.0488(13) Uani 1 1 d . . .
O17 O 0.1693(2) 0.6502(3) 0.18804(17) 0.0382(11) Uani 1 1 d . . .
O18 O 0.1212(2) 0.7631(3) 0.19340(18) 0.0412(12) Uani 1 1 d . . .
O19 O 0.3523(2) 0.9690(3) 0.32860(18) 0.0436(12) Uani 1 1 d . . .
O20 O 0.3459(2) 1.0100(3) 0.25325(17) 0.0377(11) Uani 1 1 d . . .
O21 O 0.10210(19) 0.8324(3) 0.09609(18) 0.0451(13) Uani 1 1 d . . .
O22 O 0.1020(2) 0.7914(4) 0.02183(18) 0.0501(14) Uani 1 1 d . . .
O23 O 0.1370(2) 0.6997(3) 0.2964(2) 0.0534(14) Uani 1 1 d . . .
O24 O 0.0971(2) 0.7615(3) 0.35122(17) 0.0449(12) Uani 1 1 d . . .
O25 O 0.1959(3) 0.9516(3) 0.0188(3) 0.0720(19) Uani 1 1 d . . .
O26 O 0.1965(3) 0.9796(4) 0.0919(3) 0.086(2) Uani 1 1 d . . .
O27 O 0.3502(3) 0.9855(5) 0.0597(3) 0.086(2) Uani 1 1 d . . .
O28 O 0.3264(4) 1.0388(6) 0.1262(3) 0.115(3) Uani 1 1 d . . .
O29 O 0.1739(2) 0.5687(3) -0.0172(2) 0.0529(14) Uani 1 1 d . . .
O30 O 0.1234(2) 0.6693(3) -0.0528(2) 0.0604(16) Uani 1 1 d . . .
O1W O 0.3122(2) 0.5547(3) 0.0362(2) 0.0531(14) Uani 1 1 d . . .
H1W H 0.3206 0.5775 0.0651 0.080 Uiso 1 1 d R B .
H2W H 0.3437 0.5248 0.0339 0.080 Uiso 1 1 d R . .
O31 O 0.3326(6) 1.0046(7) -0.0753(7) 0.109(6) Uani 0.590(11) 1 d PD A 1
O32 O 0.3553(6) 0.8768(8) -0.0749(6) 0.059(4) Uani 0.590(11) 1 d PD A 1
C87 C 0.3642(10) 0.9469(8) -0.0790(10) 0.052(7) Uani 0.590(11) 1 d PD A 1
C88 C 0.4224(9) 0.9672(13) -0.0921(8) 0.070(7) Uani 0.590(11) 1 d PD A 1
F34 F 0.4686(5) 0.9539(9) -0.0586(5) 0.125(6) Uani 0.590(11) 1 d PD A 1
F35 F 0.4273(6) 1.0378(7) -0.1080(4) 0.088(4) Uani 0.590(11) 1 d PD A 1
F36 F 0.4327(5) 0.9206(7) -0.1292(4) 0.100(4) Uani 0.590(11) 1 d PD A 1
O33 O 0.3415(5) 0.9085(8) -0.0500(5) 0.038(3) Uani 0.410(11) 1 d PD A 2
O34 O 0.3568(6) 0.8727(8) -0.1217(5) 0.050(4) Uani 0.410(11) 1 d PD A 2
C89 C 0.3606(12) 0.915(2) -0.0866(7) 0.036(6) Uani 0.410(11) 1 d PD A 2
C90 C 0.393(2) 0.987(3) -0.095(3) 0.19(3) Uani 0.410(11) 1 d PD A 2
F43 F 0.3649(14) 1.0511(11) -0.0986(12) 0.204(17) Uani 0.410(11) 1 d PD A 2
F44 F 0.4334(11) 0.9867(17) -0.1184(10) 0.139(11) Uani 0.410(11) 1 d PD A 2
F45 F 0.4322(13) 1.0028(17) -0.0455(9) 0.181(14) Uani 0.410(11) 1 d PD A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N5 Ag1 C9 143.0(2) . .
N5 Ag1 O15 81.7(2) . .
C9 Ag1 O15 100.21(19) . .
N5 Ag1 C1 115.9(2) . .
C9 Ag1 C1 100.3(2) . .
O15 Ag1 C1 99.91(18) . .
N5 Ag1 Ag2 111.92(16) . .
C9 Ag1 Ag2 47.05(15) . .
O15 Ag1 Ag2 141.58(12) . .
C1 Ag1 Ag2 104.96(14) . .
N5 Ag1 Ag3 96.03(16) . .
C9 Ag1 Ag3 104.84(15) . .
O15 Ag1 Ag3 139.69(12) . .
C1 Ag1 Ag3 45.04(14) . .
Ag2 Ag1 Ag3 76.603(19) . .
N5 Ag1 Ag6 89.85(16) . .
C9 Ag1 Ag6 54.67(16) . .
O15 Ag1 Ag6 80.67(11) . .
C1 Ag1 Ag6 154.12(15) . .
Ag2 Ag1 Ag6 64.277(18) . .
Ag3 Ag1 Ag6 139.64(2) . .
N5 Ag1 Ag16 155.80(17) . .
C9 Ag1 Ag16 50.84(16) . .
O15 Ag1 Ag16 119.08(12) . .
C1 Ag1 Ag16 51.96(14) . .
Ag2 Ag1 Ag16 60.51(2) . .
Ag3 Ag1 Ag16 60.31(2) . .
Ag6 Ag1 Ag16 104.93(3) . .
C9 Ag2 O21 160.0(2) . .
C9 Ag2 O9 122.24(20) . .
O21 Ag2 O9 77.63(17) . .
C9 Ag2 Ag17 53.5(2) . .
O21 Ag2 Ag17 122.6(2) . .
O9 Ag2 Ag17 105.9(3) . .
C9 Ag2 Ag1 54.15(17) . .
O21 Ag2 Ag1 106.77(13) . .
O9 Ag2 Ag1 169.70(12) . .
Ag17 Ag2 Ag1 79.9(3) . .
C9 Ag2 Ag16 53.82(17) . .
O21 Ag2 Ag16 115.59(14) . .
O9 Ag2 Ag16 122.29(11) . .
Ag17 Ag2 Ag16 18.0(3) . .
Ag1 Ag2 Ag16 64.76(2) . .
C9 Ag2 Ag6 53.56(17) . .
O21 Ag2 Ag6 125.86(15) . .
O9 Ag2 Ag6 109.84(12) . .
Ag17 Ag2 Ag6 107.08(11) . .
Ag1 Ag2 Ag6 59.952(17) . .
Ag16 Ag2 Ag6 104.89(3) . .
C9 Ag2 Ag9 54.36(16) . .
O21 Ag2 Ag9 145.65(13) . .
O9 Ag2 Ag9 68.18(11) . .
Ag17 Ag2 Ag9 72.0(3) . .
Ag1 Ag2 Ag9 106.45(2) . .
Ag16 Ag2 Ag9 86.55(2) . .
Ag6 Ag2 Ag9 66.229(17) . .
C1 Ag3 O22 163.4(2) . .
C1 Ag3 O11 120.8(2) . .
O22 Ag3 O11 75.74(18) . .
C1 Ag3 Ag1 57.32(18) . .
O22 Ag3 Ag1 106.05(14) . .
O11 Ag3 Ag1 175.28(12) . .
C1 Ag3 Ag12 54.66(18) . .
O22 Ag3 Ag12 141.78(14) . .
O11 Ag3 Ag12 66.10(11) . .
Ag1 Ag3 Ag12 111.83(2) . .
C1 Ag3 Ag16 55.70(17) . .
O22 Ag3 Ag16 120.42(15) . .
O11 Ag3 Ag16 118.94(11) . .
Ag1 Ag3 Ag16 64.15(3) . .
Ag12 Ag3 Ag16 81.84(3) . .
C1 Ag3 Ag10 53.27(17) . .
O22 Ag3 Ag10 125.82(16) . .
O11 Ag3 Ag10 100.10(12) . .
Ag1 Ag3 Ag10 75.281(18) . .
Ag12 Ag3 Ag10 62.097(17) . .
Ag16 Ag3 Ag10 108.82(2) . .
C17 Ag4 O13 147.2(2) . .
C17 Ag4 O18 125.6(2) . .
O13 Ag4 O18 85.22(17) . .
C17 Ag4 Ag7 62.11(17) . .
O13 Ag4 Ag7 85.58(12) . .
O18 Ag4 Ag7 167.46(11) . .
C17 Ag4 Ag9 52.65(17) . .
O13 Ag4 Ag9 111.71(13) . .
O18 Ag4 Ag9 108.01(13) . .
Ag7 Ag4 Ag9 67.796(19) . .
C17 Ag4 Ag6 53.38(17) . .
O13 Ag4 Ag6 156.02(12) . .
O18 Ag4 Ag6 72.36(12) . .
Ag7 Ag4 Ag6 115.12(2) . .
Ag9 Ag4 Ag6 69.018(18) . .
C17 Ag4 Ag15 54.77(17) . .
O13 Ag4 Ag15 121.79(13) . .
O18 Ag4 Ag15 122.32(11) . .
Ag7 Ag4 Ag15 69.97(2) . .
Ag9 Ag4 Ag15 106.34(2) . .
Ag6 Ag4 Ag15 78.75(2) . .
C25 Ag5 O24 153.6(2) . .
C25 Ag5 O30 127.2(2) . 4_576
O24 Ag5 O30 78.24(19) . 4_576
C25 Ag5 Ag15 54.73(17) . .
O24 Ag5 Ag15 99.01(13) . .
O30 Ag5 Ag15 160.26(15) 4_576 .
C25 Ag5 Ag10 56.57(17) . 4_576
O24 Ag5 Ag10 148.97(13) . 4_576
O30 Ag5 Ag10 70.83(14) 4_576 4_576
Ag15 Ag5 Ag10 109.20(2) . 4_576
C25 Ag5 Ag12 53.14(17) . 4_576
O24 Ag5 Ag12 120.75(15) . 4_576
O30 Ag5 Ag12 102.33(16) 4_576 4_576
Ag15 Ag5 Ag12 61.96(2) . 4_576
Ag10 Ag5 Ag12 65.387(19) 4_576 4_576
C25 Ag5 Ag7 55.98(17) . .
O24 Ag5 Ag7 115.84(13) . .
O30 Ag5 Ag7 130.34(14) 4_576 .
Ag15 Ag5 Ag7 68.64(2) . .
Ag10 Ag5 Ag7 87.07(2) 4_576 .
Ag12 Ag5 Ag7 107.86(2) 4_576 .
O17 Ag6 O16 98.11(18) . .
O17 Ag6 C17 119.49(19) . .
O16 Ag6 C17 120.37(19) . .
O17 Ag6 C9 122.45(19) . .
O16 Ag6 C9 107.03(19) . .
C17 Ag6 C9 90.6(2) . .
O17 Ag6 Ag1 87.38(12) . .
O16 Ag6 Ag1 79.28(12) . .
C17 Ag6 Ag1 140.42(15) . .
C9 Ag6 Ag1 49.83(14) . .
O17 Ag6 Ag4 80.36(11) . .
O16 Ag6 Ag4 152.51(13) . .
C17 Ag6 Ag4 43.77(14) . .
C9 Ag6 Ag4 96.50(14) . .
Ag1 Ag6 Ag4 127.75(2) . .
O17 Ag6 Ag2 83.33(12) . .
O16 Ag6 Ag2 134.99(13) . .
C17 Ag6 Ag2 96.34(15) . .
C9 Ag6 Ag2 42.88(14) . .
Ag1 Ag6 Ag2 55.771(16) . .
Ag4 Ag6 Ag2 72.366(19) . .
O19 Ag7 O14 147.30(17) . .
O19 Ag7 N9 75.8(2) . .
O14 Ag7 N9 73.4(2) . .
O19 Ag7 C17 88.38(18) . .
O14 Ag7 C17 119.39(17) . .
N9 Ag7 C17 127.4(2) . .
O19 Ag7 C25 107.71(18) . .
O14 Ag7 C25 92.00(18) . .
N9 Ag7 C25 146.1(2) . .
C17 Ag7 C25 86.41(19) . .
O19 Ag7 Ag4 124.65(13) . .
O14 Ag7 Ag4 76.01(11) . .
N9 Ag7 Ag4 107.5(2) . .
C17 Ag7 Ag4 44.60(13) . .
C25 Ag7 Ag4 97.96(13) . .
O19 Ag7 Ag5 148.08(12) . .
O14 Ag7 Ag5 53.42(12) . .
N9 Ag7 Ag5 124.74(18) . .
C17 Ag7 Ag5 94.36(14) . .
C25 Ag7 Ag5 41.03(13) . .
Ag4 Ag7 Ag5 75.91(2) . .
O19 Ag7 Ag9 69.04(12) . .
O14 Ag7 Ag9 116.65(12) . .
N9 Ag7 Ag9 81.8(2) . .
C17 Ag7 Ag9 46.05(14) . .
C25 Ag7 Ag9 131.59(14) . .
Ag4 Ag7 Ag9 57.450(18) . .
Ag5 Ag7 Ag9 132.35(2) . .
N10 Ag8 O9 162.2(2) 2_545 .
N10 Ag8 O18 120.2(2) 2_545 .
O9 Ag8 O18 77.67(16) . .
O10 Ag9 O20 80.59(16) . .
O10 Ag9 C17 137.09(19) . .
O20 Ag9 C17 115.57(19) . .
O10 Ag9 C9 111.97(19) . .
O20 Ag9 C9 125.16(19) . .
C17 Ag9 C9 91.3(2) . .
O10 Ag9 Ag4 95.16(12) . .
O20 Ag9 Ag4 136.08(12) . .
C17 Ag9 Ag4 44.78(14) . .
C9 Ag9 Ag4 97.16(15) . .
O10 Ag9 Ag2 79.45(12) . .
O20 Ag9 Ag2 146.10(12) . .
C17 Ag9 Ag2 97.62(15) . .
C9 Ag9 Ag2 42.70(14) . .
Ag4 Ag9 Ag2 73.026(18) . .
O10 Ag9 Ag7 94.04(13) . .
O20 Ag9 Ag7 81.78(12) . .
C17 Ag9 Ag7 53.41(15) . .
C9 Ag9 Ag7 144.16(15) . .
Ag4 Ag9 Ag7 54.755(18) . .
Ag2 Ag9 Ag7 126.67(2) . .
O29 Ag10 O1W 87.52(18) . .
O29 Ag10 C25 123.58(19) . 4_575
O1W Ag10 C25 133.97(19) . 4_575
O29 Ag10 C1 120.6(2) . .
O1W Ag10 C1 96.5(2) . .
C25 Ag10 C1 94.6(2) 4_575 .
O29 Ag10 Ag5 83.06(12) . 4_575
O1W Ag10 Ag5 162.29(14) . 4_575
C25 Ag10 Ag5 45.28(14) 4_575 4_575
C1 Ag10 Ag5 101.20(14) . 4_575
O29 Ag10 Ag12 128.80(14) . .
O1W Ag10 Ag12 137.35(14) . .
C25 Ag10 Ag12 48.49(15) 4_575 .
C1 Ag10 Ag12 48.67(14) . .
Ag5 Ag10 Ag12 58.607(18) 4_575 .
O29 Ag10 Ag3 86.00(15) . .
O1W Ag10 Ag3 117.71(14) . .
C25 Ag10 Ag3 99.15(15) 4_575 .
C1 Ag10 Ag3 40.43(14) . .
Ag5 Ag10 Ag3 76.65(2) 4_575 .
Ag12 Ag10 Ag3 55.015(17) . .
N6 Ag11 O11 162.9(2) 3_565 .
N6 Ag11 O30 118.7(2) 3_565 .
O11 Ag11 O30 78.38(19) . .
O33 Ag12 O32 25.0(4) . .
O33 Ag12 O12 85.1(3) . .
O32 Ag12 O12 94.6(3) . .
O33 Ag12 C25 119.0(4) . 4_575
O32 Ag12 C25 94.6(4) . 4_575
O12 Ag12 C25 122.32(19) . 4_575
O33 Ag12 C1 103.3(4) . .
O32 Ag12 C1 115.2(4) . .
O12 Ag12 C1 126.20(19) . .
C25 Ag12 C1 99.9(2) 4_575 .
O33 Ag12 Ag3 127.6(4) . .
O32 Ag12 Ag3 150.9(4) . .
O12 Ag12 Ag3 88.65(12) . .
C25 Ag12 Ag3 108.03(15) 4_575 .
C1 Ag12 Ag3 44.23(15) . .
O33 Ag12 Ag15 96.1(4) . 4_575
O32 Ag12 Ag15 75.6(4) . 4_575
O12 Ag12 Ag15 77.98(12) . 4_575
C25 Ag12 Ag15 49.98(15) 4_575 4_575
C1 Ag12 Ag15 149.75(15) . 4_575
Ag3 Ag12 Ag15 133.08(3) . 4_575
O33 Ag12 Ag5 152.0(4) . 4_575
O32 Ag12 Ag5 129.4(4) . 4_575
O12 Ag12 Ag5 89.11(12) . 4_575
C25 Ag12 Ag5 44.36(14) 4_575 4_575
C1 Ag12 Ag5 102.25(15) . 4_575
Ag3 Ag12 Ag5 79.43(2) . 4_575
Ag15 Ag12 Ag5 55.90(2) 4_575 4_575
O33 Ag12 Ag14 49.0(4) . .
O32 Ag12 Ag14 72.1(4) . .
O12 Ag12 Ag14 52.72(13) . .
C25 Ag12 Ag14 164.26(15) 4_575 .
C1 Ag12 Ag14 93.53(15) . .
Ag3 Ag12 Ag14 87.32(2) . .
Ag15 Ag12 Ag14 116.68(3) 4_575 .
Ag5 Ag12 Ag14 140.01(3) 4_575 .
O33 Ag12 Ag10 137.7(3) . .
O32 Ag12 Ag10 126.3(3) . .
O12 Ag12 Ag10 136.94(12) . .
C25 Ag12 Ag10 50.24(15) 4_575 .
C1 Ag12 Ag10 52.52(15) . .
Ag3 Ag12 Ag10 62.888(19) . .
Ag15 Ag12 Ag10 97.78(2) 4_575 .
Ag5 Ag12 Ag10 56.005(17) 4_575 .
Ag14 Ag12 Ag10 144.94(3) . .
N8 Ag13 O28 141.5(3) 1_565 .
N8 Ag13 O10 102.1(2) 1_565 .
O28 Ag13 O10 93.3(2) . .
N8 Ag13 O20 124.5(3) 1_565 .
O28 Ag13 O20 93.5(3) . .
O10 Ag13 O20 73.81(15) . .
N8 Ag13 O5 100.6(3) 1_565 2_655
O28 Ag13 O5 77.0(3) . 2_655
O10 Ag13 O5 153.5(2) . 2_655
O20 Ag13 O5 82.1(2) . 2_655
N11 Ag14 O31 101.4(4) . .
N11 Ag14 O33 144.8(4) . .
O31 Ag14 O33 45.3(4) . .
N11 Ag14 O25 92.1(3) . .
O31 Ag14 O25 160.3(4) . .
O33 Ag14 O25 123.0(3) . .
N11 Ag14 O12 116.0(3) . .
O31 Ag14 O12 83.8(4) . .
O33 Ag14 O12 77.2(3) . .
O25 Ag14 O12 77.4(2) . .
N11 Ag14 Ag12 163.0(3) . .
O31 Ag14 Ag12 80.8(3) . .
O33 Ag14 Ag12 44.2(3) . .
O25 Ag14 Ag12 82.13(14) . .
O12 Ag14 Ag12 47.19(11) . .
N11 Ag14 Ag16 114.1(4) . .
O31 Ag14 Ag16 132.0(4) . .
O33 Ag14 Ag16 90.4(3) . .
O25 Ag14 Ag16 50.66(17) . .
O12 Ag14 Ag16 106.46(11) . .
Ag12 Ag14 Ag16 74.37(2) . .
N7 Ag15 C25 159.1(3) . .
N7 Ag15 C17 97.5(2) . .
C25 Ag15 C17 96.8(2) . .
N7 Ag15 Ag5 139.6(2) . .
C25 Ag15 Ag5 47.40(15) . .
C17 Ag15 Ag5 107.63(14) . .
N7 Ag15 Ag12 109.9(2) . 4_576
C25 Ag15 Ag12 52.19(16) . 4_576
C17 Ag15 Ag12 147.02(14) . 4_576
Ag5 Ag15 Ag12 62.136(19) . 4_576
N7 Ag15 Ag4 100.2(2) . .
C25 Ag15 Ag4 100.64(15) . .
C17 Ag15 Ag4 43.01(14) . .
Ag5 Ag15 Ag4 79.13(2) . .
Ag12 Ag15 Ag4 141.24(3) 4_576 .
Ag17 Ag16 O27 82.6(4) . .
Ag17 Ag16 C9 68.9(4) . .
O27 Ag16 C9 129.4(2) . .
Ag17 Ag16 C1 164.0(4) . .
O27 Ag16 C1 111.7(3) . .
C9 Ag16 C1 95.7(2) . .
Ag17 Ag16 C10 67.9(4) . .
O27 Ag16 C10 103.5(2) . .
C9 Ag16 C10 27.39(19) . .
C1 Ag16 C10 100.66(19) . .
Ag17 Ag16 Ag2 67.5(4) . .
O27 Ag16 Ag2 149.8(2) . .
C9 Ag16 Ag2 43.91(14) . .
C1 Ag16 Ag2 98.50(15) . .
C10 Ag16 Ag2 70.28(13) . .
Ag17 Ag16 Ag3 132.1(4) . .
O27 Ag16 Ag3 131.6(2) . .
C9 Ag16 Ag3 97.57(15) . .
C1 Ag16 Ag3 42.83(14) . .
C10 Ag16 Ag3 119.49(14) . .
Ag2 Ag16 Ag3 71.58(3) . .
Ag17 Ag16 Ag1 113.5(4) . .
O27 Ag16 Ag1 150.51(18) . .
C9 Ag16 Ag1 47.54(15) . .
C1 Ag16 Ag1 50.45(15) . .
C10 Ag16 Ag1 64.20(14) . .
Ag2 Ag16 Ag1 54.73(2) . .
Ag3 Ag16 Ag1 55.54(2) . .
Ag17 Ag16 Ag14 107.3(4) . .
O27 Ag16 Ag14 51.23(18) . .
C9 Ag16 Ag14 175.43(14) . .
C1 Ag16 Ag14 87.83(15) . .
C10 Ag16 Ag14 154.44(14) . .
Ag2 Ag16 Ag14 132.70(4) . .
Ag3 Ag16 Ag14 82.99(3) . .
Ag1 Ag16 Ag14 134.84(3) . .
Ag16 Ag17 O26 110.9(6) . .
Ag16 Ag17 O28 133.3(6) . .
O26 Ag17 O28 91.4(6) . .
Ag16 Ag17 C9 88.7(6) . .
O26 Ag17 C9 110.8(4) . .
O28 Ag17 C9 121.9(6) . .
Ag16 Ag17 O27 74.4(5) . .
O26 Ag17 O27 114.6(4) . .
O28 Ag17 O27 58.9(4) . .
C9 Ag17 O27 134.6(4) . .
Ag16 Ag17 C10 91.4(5) . .
O26 Ag17 C10 136.1(5) . .
O28 Ag17 C10 100.1(5) . .
C9 Ag17 C10 29.6(2) . .
O27 Ag17 C10 107.6(3) . .
Ag16 Ag17 C83 103.0(6) . .
O26 Ag17 C83 103.8(5) . .
O28 Ag17 C83 30.4(3) . .
C9 Ag17 C83 136.5(4) . .
O27 Ag17 C83 28.6(3) . .
C10 Ag17 C83 107.4(4) . .
Ag16 Ag17 Ag2 94.5(5) . .
O26 Ag17 Ag2 64.5(3) . .
O28 Ag17 Ag2 132.2(7) . .
C9 Ag17 Ag2 47.76(18) . .
O27 Ag17 Ag2 167.9(7) . .
C10 Ag17 Ag2 76.9(2) . .
C83 Ag17 Ag2 161.8(7) . .
C2 C1 Ag3 171.2(6) . .
C2 C1 Ag12 94.0(5) . .
Ag3 C1 Ag12 81.1(2) . .
C2 C1 Ag1 107.7(5) . .
Ag3 C1 Ag1 77.6(2) . .
Ag12 C1 Ag1 158.2(3) . .
C2 C1 Ag16 92.8(4) . .
Ag3 C1 Ag16 81.5(2) . .
Ag12 C1 Ag16 104.1(2) . .
Ag1 C1 Ag16 77.59(18) . .
C2 C1 Ag10 99.9(5) . .
Ag3 C1 Ag10 86.3(2) . .
Ag12 C1 Ag10 78.81(18) . .
Ag1 C1 Ag10 94.9(2) . .
Ag16 C1 Ag10 166.8(3) . .
C1 C2 C3 176.8(7) . .
C4 C3 C8 120.0 . .
C4 C3 C2 119.1(4) . .
C8 C3 C2 120.9(4) . .
C5 C4 C3 120.0 . .
C5 C4 H4 120.0 . .
C3 C4 H4 120.0 . .
C6 C5 C4 120.0 . .
C6 C5 H5 120.0 . .
C4 C5 H5 120.0 . .
C7 C6 C5 120.0 . .
C7 C6 N1 120.5(5) . .
C5 C6 N1 119.5(5) . .
C6 C7 C8 120.0 . .
C6 C7 H7 120.0 . .
C8 C7 H7 120.0 . .
C7 C8 C3 120.0 . .
C7 C8 H8 120.0 . .
C3 C8 H8 120.0 . .
C10 C9 Ag2 157.4(5) . .
C10 C9 Ag17 82.3(5) . .
Ag2 C9 Ag17 78.7(2) . .
C10 C9 Ag1 117.6(5) . .
Ag2 C9 Ag1 78.8(2) . .
Ag17 C9 Ag1 102.5(4) . .
C10 C9 Ag16 84.8(4) . .
Ag2 C9 Ag16 82.3(2) . .
Ag17 C9 Ag16 22.4(4) . .
Ag1 C9 Ag16 81.61(19) . .
C10 C9 Ag6 114.6(5) . .
Ag2 C9 Ag6 83.6(2) . .
Ag17 C9 Ag6 162.2(3) . .
Ag1 C9 Ag6 75.51(19) . .
Ag16 C9 Ag6 155.0(3) . .
C10 C9 Ag9 85.5(4) . .
Ag2 C9 Ag9 82.9(2) . .
Ag17 C9 Ag9 91.8(4) . .
Ag1 C9 Ag9 154.0(3) . .
Ag16 C9 Ag9 114.1(2) . .
Ag6 C9 Ag9 84.28(19) . .
C9 C10 C11 172.2(6) . .
C9 C10 Ag17 68.1(4) . .
C11 C10 Ag17 116.7(4) . .
C9 C10 Ag16 67.8(4) . .
C11 C10 Ag16 114.3(4) . .
Ag17 C10 Ag16 20.7(4) . .
C12 C11 C16 120.0 . .
C12 C11 C10 118.7(3) . .
C16 C11 C10 121.3(3) . .
C13 C12 C11 120.0 . .
C13 C12 H12 120.0 . .
C11 C12 H12 120.0 . .
C12 C13 C14 120.0 . .
C12 C13 H13 120.0 . .
C14 C13 H13 120.0 . .
C13 C14 C15 120.0 . .
C13 C14 N2 120.0(5) . .
C15 C14 N2 120.0(5) . .
C16 C15 C14 120.0 . .
C16 C15 H15 120.0 . .
C14 C15 H15 120.0 . .
C15 C16 C11 120.0 . .
C15 C16 H16 120.0 . .
C11 C16 H16 120.0 . .
C18 C17 Ag4 171.6(6) . .
C18 C17 Ag9 101.8(5) . .
Ag4 C17 Ag9 82.6(2) . .
C18 C17 Ag6 90.0(4) . .
Ag4 C17 Ag6 82.8(2) . .
Ag9 C17 Ag6 89.4(2) . .
C18 C17 Ag15 95.0(5) . .
Ag4 C17 Ag15 82.2(2) . .
Ag9 C17 Ag15 159.7(3) . .
Ag6 C17 Ag15 101.9(2) . .
C18 C17 Ag7 114.3(5) . .
Ag4 C17 Ag7 73.29(18) . .
Ag9 C17 Ag7 80.54(19) . .
Ag6 C17 Ag7 155.1(3) . .
Ag15 C17 Ag7 82.27(18) . .
C17 C18 C19 175.9(7) . .
C20 C19 C24 120.0 . .
C20 C19 C18 119.2(4) . .
C24 C19 C18 120.7(4) . .
C19 C20 C21 120.0 . .
C19 C20 H20 120.0 . .
C21 C20 H20 120.0 . .
C22 C21 C20 120.0 . .
C22 C21 H21 120.0 . .
C20 C21 H21 120.0 . .
C21 C22 C23 120.0 . .
C21 C22 N3 119.3(6) . .
C23 C22 N3 120.7(6) . .
C24 C23 C22 120.0 . .
C24 C23 H23 120.0 . .
C22 C23 H23 120.0 . .
C23 C24 C19 120.0 . .
C23 C24 H24 120.0 . .
C19 C24 H24 120.0 . .
C26 C25 Ag5 166.4(6) . .
C26 C25 Ag15 113.1(5) . .
Ag5 C25 Ag15 77.9(2) . .
C26 C25 Ag12 107.1(5) . 4_576
Ag5 C25 Ag12 82.5(2) . 4_576
Ag15 C25 Ag12 77.82(19) . 4_576
C26 C25 Ag10 93.5(4) . 4_576
Ag5 C25 Ag10 78.14(19) . 4_576
Ag15 C25 Ag10 149.9(3) . 4_576
Ag12 C25 Ag10 81.27(19) 4_576 4_576
C26 C25 Ag7 89.8(4) . .
Ag5 C25 Ag7 83.0(2) . .
Ag15 C25 Ag7 85.1(2) . .
Ag12 C25 Ag7 159.6(3) 4_576 .
Ag10 C25 Ag7 109.6(2) 4_576 .
C25 C26 C27 177.4(7) . .
C28 C27 C32 120.0 . .
C28 C27 C26 120.3(4) . .
C32 C27 C26 119.7(4) . .
C29 C28 C27 120.0 . .
C29 C28 H28 120.0 . .
C27 C28 H28 120.0 . .
C28 C29 C30 120.0 . .
C28 C29 H29 120.0 . .
C30 C29 H29 120.0 . .
C31 C30 C29 120.0 . .
C31 C30 N4 119.2(5) . .
C29 C30 N4 120.8(5) . .
C30 C31 C32 120.0 . .
C30 C31 H31 120.0 . .
C32 C31 H31 120.0 . .
C31 C32 C27 120.0 . .
C31 C32 H32 120.0 . .
C27 C32 H32 120.0 . .
N5 C33 C34 176.6(8) . .
C35 C34 C39 120.0 . .
C35 C34 C33 119.1(4) . .
C39 C34 C33 120.8(4) . .
C36 C35 C34 120.0 . .
C36 C35 H35 120.0 . .
C34 C35 H35 120.0 . .
C35 C36 C37 120.0 . .
C35 C36 H36 120.0 . .
C37 C36 H36 120.0 . .
C38 C37 C36 120.0 . .
C38 C37 H37 120.0 . .
C36 C37 H37 120.0 . .
C37 C38 C39 120.0 . .
C37 C38 C40 119.5(4) . .
C39 C38 C40 120.5(4) . .
C38 C39 C34 120.0 . .
C38 C39 H39 120.0 . .
C34 C39 H39 120.0 . .
N6 C40 C38 178.7(9) . .
N7 C41 C42 176.2(10) . .
C43 C42 C47 120.0 . .
C43 C42 C41 121.1(5) . .
C47 C42 C41 118.7(5) . .
C44 C43 C42 120.0 . .
C44 C43 H43 120.0 . .
C42 C43 H43 120.0 . .
C43 C44 C45 120.0 . .
C43 C44 C48 121.0(4) . .
C45 C44 C48 119.0(4) . .
C46 C45 C44 120.0 . .
C46 C45 H45 120.0 . .
C44 C45 H45 120.0 . .
C45 C46 C47 120.0 . .
C45 C46 H46 120.0 . .
C47 C46 H46 120.0 . .
C46 C47 C42 120.0 . .
C46 C47 H47 120.0 . .
C42 C47 H47 120.0 . .
N8 C48 C44 176.8(8) . .
N9 C49 C50 177.2(11) . .
C51 C50 C55 120.0 . .
C51 C50 C49 120.9(4) . .
C55 C50 C49 119.1(4) . .
C50 C51 C52 120.0 . .
C50 C51 H51 120.0 . .
C52 C51 H51 120.0 . .
C51 C52 C53 120.0 . .
C51 C52 C56 119.0(4) . .
C53 C52 C56 121.0(4) . .
C54 C53 C52 120.0 . .
C54 C53 H53 120.0 . .
C52 C53 H53 120.0 . .
C55 C54 C53 120.0 . .
C55 C54 H54 120.0 . .
C53 C54 H54 120.0 . .
C54 C55 C50 120.0 . .
C54 C55 H55 120.0 . .
C50 C55 H55 120.0 . .
N10 C56 C52 179.6(8) . .
N11 C57 C58 175.4(12) . .
C59 C58 C63 120.0 . .
C59 C58 C57 120.8(4) . .
C63 C58 C57 119.1(4) . .
C58 C59 C60 120.0 . .
C58 C59 H59 120.0 . .
C60 C59 H59 120.0 . .
C61 C60 C59 120.0 . .
C61 C60 C64 119.5(5) . .
C59 C60 C64 120.3(5) . .
C60 C61 C62 120.0 . .
C60 C61 H61 120.0 . .
C62 C61 H61 120.0 . .
C63 C62 C61 120.0 . .
C63 C62 H62 120.0 . .
C61 C62 H62 120.0 . .
C62 C63 C58 120.0 . .
C62 C63 H63 120.0 . .
C58 C63 H63 120.0 . .
N12 C64 C60 179.3(12) . .
O9 C65 O10 127.1(6) . .
O9 C65 C66 117.0(5) . .
O10 C65 C66 115.9(6) . .
F1 C66 F2 107.2(6) . .
F1 C66 F3 107.0(6) . .
F2 C66 F3 106.3(6) . .
F1 C66 C65 113.3(6) . .
F2 C66 C65 112.3(6) . .
F3 C66 C65 110.3(6) . .
O11 C67 O12 128.1(6) . .
O11 C67 C68 117.3(6) . .
O12 C67 C68 114.6(6) . .
F5 C68 F6 107.9(7) . .
F5 C68 F4 106.9(6) . .
F6 C68 F4 106.5(6) . .
F5 C68 C67 113.8(6) . .
F6 C68 C67 109.9(6) . .
F4 C68 C67 111.4(6) . .
O14 C69 O13 130.1(6) . .
O14 C69 C70 115.0(6) . .
O13 C69 C70 114.9(6) . .
F9 C70 F7 107.0(6) . .
F9 C70 F8 107.6(7) . .
F7 C70 F8 106.0(6) . .
F9 C70 C69 111.1(6) . .
F7 C70 C69 114.1(6) . .
F8 C70 C69 110.6(6) . .
O16 C71 O15 130.6(6) . .
O16 C71 C72 114.3(6) . .
O15 C71 C72 115.0(6) . .
F12 C72 F10 109.6(8) . .
F12 C72 F11 104.9(9) . .
F10 C72 F11 105.8(7) . .
F12 C72 C71 114.0(7) . .
F10 C72 C71 111.9(7) . .
F11 C72 C71 110.1(7) . .
O17 C73 O18 129.1(6) . .
O17 C73 C74 114.5(6) . .
O18 C73 C74 116.3(6) . .
F14 C74 F13 107.1(6) . .
F14 C74 F15 107.3(6) . .
F13 C74 F15 105.7(6) . .
F14 C74 C73 112.3(6) . .
F13 C74 C73 114.2(6) . .
F15 C74 C73 109.9(6) . .
O19 C75 O20 130.3(6) . .
O19 C75 C76 115.0(7) . .
O20 C75 C76 114.6(7) . .
F18 C76 F16 108.1(12) . .
F18 C76 F17 105.8(13) . .
F16 C76 F17 100.9(10) . .
F18 C76 C75 114.8(9) . .
F16 C76 C75 115.2(9) . .
F17 C76 C75 110.8(9) . .
O21 C77 O22 130.8(6) . .
O21 C77 C78 115.5(7) . .
O22 C77 C78 113.7(6) . .
F21 C78 F20 111.1(8) . .
F21 C78 F19 108.5(8) . .
F20 C78 F19 99.9(7) . .
F21 C78 C77 115.5(7) . .
F20 C78 C77 111.8(6) . .
F19 C78 C77 108.9(7) . .
O23 C79 O24 129.1(7) . .
O23 C79 C80 116.9(7) . .
O24 C79 C80 114.0(7) . .
F22 C80 F24 107.9(8) . .
F22 C80 F23 106.4(7) . .
F24 C80 F23 106.8(7) . .
F22 C80 C79 110.8(7) . .
F24 C80 C79 112.1(6) . .
F23 C80 C79 112.4(8) . .
O26 C81 O25 126.2(8) . .
O26 C81 C82 116.6(8) . .
O25 C81 C82 117.2(8) . .
F38 C82 F26 126.6(14) . .
F38 C82 F27 47.7(19) . .
F26 C82 F27 105.7(14) . .
F38 C82 F39 118(2) . .
F26 C82 F39 40.7(14) . .
F27 C82 F39 133.2(15) . .
F38 C82 F25 57(2) . .
F26 C82 F25 106.0(16) . .
F27 C82 F25 103.4(12) . .
F39 C82 F25 70.6(17) . .
F38 C82 F37 108(2) . .
F26 C82 F37 53.0(14) . .
F27 C82 F37 63.3(16) . .
F39 C82 F37 93.7(18) . .
F25 C82 F37 143.8(12) . .
F38 C82 C81 116.6(11) . .
F26 C82 C81 116.8(11) . .
F27 C82 C81 115.0(10) . .
F39 C82 C81 110.5(13) . .
F25 C82 C81 108.9(9) . .
F37 C82 C81 107.2(12) . .
O27 C83 O28 134.2(11) . .
O27 C83 C84 108.4(10) . .
O28 C83 C84 117.3(11) . .
O27 C83 Ag17 71.7(7) . .
O28 C83 Ag17 62.7(7) . .
C84 C83 Ag17 171.2(8) . .
F29 C84 F30 105.8(14) . .
F29 C84 F28 117.3(17) . .
F30 C84 F28 109.6(13) . .
F29 C84 C83 115.5(12) . .
F30 C84 C83 104.4(12) . .
F28 C84 C83 103.6(12) . .
O30 C85 O29 127.4(7) . .
O30 C85 C86 116.3(7) . .
O29 C85 C86 116.2(6) . .
F31 C86 F32 110.3(16) . .
F31 C86 F41 53.3(13) . .
F32 C86 F41 128.0(11) . .
F31 C86 F40 138.2(12) . .
F32 C86 F40 49.9(12) . .
F41 C86 F40 105.7(16) . .
F31 C86 F42 58.7(13) . .
F32 C86 F42 55.1(12) . .
F41 C86 F42 103.8(14) . .
F40 C86 F42 102.3(15) . .
F31 C86 F33 106.4(16) . .
F32 C86 F33 105.6(15) . .
F41 C86 F33 53.7(12) . .
F40 C86 F33 59.3(12) . .
F42 C86 F33 135.9(11) . .
F31 C86 C85 110.0(9) . .
F32 C86 C85 114.1(9) . .
F41 C86 C85 117.9(9) . .
F40 C86 C85 111.8(10) . .
F42 C86 C85 114.0(9) . .
F33 C86 C85 110.1(9) . .
O2 N1 O1 123.5(8) . .
O2 N1 C6 118.8(8) . .
O1 N1 C6 117.7(7) . .
O3 N2 O4 124.5(7) . .
O3 N2 C14 117.6(8) . .
O4 N2 C14 117.8(7) . .
O6 N3 O5 124.9(8) . .
O6 N3 C22 119.1(9) . .
O5 N3 C22 116.0(9) . .
O7 N4 O8 125.0(8) . .
O7 N4 C30 118.6(8) . .
O8 N4 C30 116.3(8) . .
C33 N5 Ag1 154.8(6) . .
C40 N6 Ag11 163.8(7) . 3_565
C41 N7 Ag15 156.7(9) . .
C48 N8 Ag13 175.2(8) . 1_545
C49 N9 Ag7 158.0(9) . .
C56 N10 Ag8 167.6(6) . 2
C57 N11 Ag14 160.9(12) . .
N3 O5 Ag13 121.7(7) . 2_645
C65 O9 Ag8 135.7(4) . .
C65 O9 Ag2 118.7(4) . .
Ag8 O9 Ag2 104.38(17) . .
C65 O10 Ag9 114.7(4) . .
C65 O10 Ag13 145.4(4) . .
Ag9 O10 Ag13 96.69(15) . .
C67 O11 Ag11 134.3(4) . .
C67 O11 Ag3 123.3(4) . .
Ag11 O11 Ag3 100.86(17) . .
C67 O12 Ag12 108.5(4) . .
C67 O12 Ag14 121.6(4) . .
Ag12 O12 Ag14 80.09(15) . .
C69 O13 Ag4 119.9(4) . .
C69 O14 Ag7 118.1(4) . .
C71 O15 Ag1 118.5(4) . .
C71 O16 Ag6 126.0(5) . .
C73 O17 Ag6 115.8(4) . .
C73 O18 Ag4 120.0(4) . .
C73 O18 Ag8 141.4(4) . .
Ag4 O18 Ag8 97.54(17) . .
C75 O19 Ag7 127.8(4) . .
C75 O20 Ag9 116.0(4) . .
C75 O20 Ag13 132.7(4) . .
Ag9 O20 Ag13 95.69(16) . .
C77 O21 Ag2 133.7(5) . .
C77 O22 Ag3 130.1(4) . .
C79 O24 Ag5 116.9(4) . .
C81 O25 Ag14 128.2(5) . .
C81 O26 Ag17 109.7(7) . .
C83 O27 Ag16 102.6(7) . .
C83 O27 Ag17 79.7(7) . .
Ag16 O27 Ag17 23.0(4) . .
C83 O28 Ag17 86.9(7) . .
C83 O28 Ag13 152.6(8) . .
Ag17 O28 Ag13 119.6(5) . .
C85 O29 Ag10 112.5(5) . .
C85 O30 Ag11 138.7(5) . .
C85 O30 Ag5 121.3(5) . 4_575
Ag11 O30 Ag5 97.80(19) . 4_575
Ag10 O1W H1W 111.4 . .
Ag10 O1W H2W 127.4 . .
H1W O1W H2W 106.5 . .
C87 O31 Ag14 116.8(14) . .
C87 O32 Ag12 126.9(14) . .
O32 C87 O31 131(2) . .
O32 C87 C88 115.2(16) . .
O31 C87 C88 114.0(17) . .
F35 C88 F34 107.8(14) . .
F35 C88 F36 102.9(17) . .
F34 C88 F36 103.1(19) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N5 2.254(6) .
Ag1 C9 2.357(6) .
Ag1 O15 2.410(4) .
Ag1 C1 2.495(7) .
Ag1 Ag2 2.8528(7) .
Ag1 Ag3 2.8958(7) .
Ag1 Ag6 2.9867(8) .
Ag1 Ag16 3.1607(12) .
Ag2 C9 2.129(6) .
Ag2 O21 2.209(4) .
Ag2 O9 2.456(4) .
Ag2 Ag17 2.819(5) .
Ag2 Ag16 3.0415(13) .
Ag2 Ag6 3.1085(7) .
Ag2 Ag9 3.1145(7) .
Ag3 C1 2.098(6) .
Ag3 O22 2.152(5) .
Ag3 O11 2.554(5) .
Ag3 Ag12 2.9708(7) .
Ag3 Ag16 3.0512(11) .
Ag3 Ag10 3.2275(9) .
Ag4 C17 2.111(6) .
Ag4 O13 2.230(4) .
Ag4 O18 2.402(5) .
Ag4 Ag7 2.8797(8) .
Ag4 Ag9 2.9722(8) .
Ag4 Ag6 3.0282(7) .
Ag4 Ag15 3.0662(10) .
Ag5 C25 2.122(6) .
Ag5 O24 2.226(5) .
Ag5 O30 2.430(5) 4_576
Ag5 Ag15 2.8181(9) .
Ag5 Ag10 2.9221(8) 4_576
Ag5 Ag12 3.0086(8) 4_576
Ag5 Ag7 3.2077(8) .
Ag6 O17 2.300(4) .
Ag6 O16 2.317(5) .
Ag6 C17 2.450(6) .
Ag6 C9 2.517(7) .
Ag7 O19 2.384(5) .
Ag7 O14 2.474(5) .
Ag7 N9 2.589(9) .
Ag7 C17 2.658(6) .
Ag7 C25 2.679(6) .
Ag7 Ag9 3.2646(9) .
Ag8 N10 2.163(5) 2_545
Ag8 O9 2.294(4) .
Ag8 O18 2.449(5) .
Ag9 O10 2.304(4) .
Ag9 O20 2.339(4) .
Ag9 C17 2.383(6) .
Ag9 C9 2.551(6) .
Ag10 O29 2.350(5) .
Ag10 O1W 2.353(5) .
Ag10 C25 2.492(6) 4_575
Ag10 C1 2.592(6) .
Ag10 Ag5 2.9222(8) 4_575
Ag10 Ag12 3.2044(8) .
Ag11 N6 2.169(6) 3_565
Ag11 O11 2.324(5) .
Ag11 O30 2.424(5) .
Ag12 O33 2.218(12) .
Ag12 O32 2.352(14) .
Ag12 O12 2.365(5) .
Ag12 C25 2.428(6) 4_575
Ag12 C1 2.453(6) .
Ag12 Ag15 3.0038(8) 4_575
Ag12 Ag5 3.0086(8) 4_575
Ag12 Ag14 3.1753(9) .
Ag13 N8 2.207(8) 1_565
Ag13 O28 2.452(9) .
Ag13 O10 2.498(4) .
Ag13 O20 2.502(5) .
Ag13 O5 2.525(6) 2_655
Ag14 N11 2.217(9) .
Ag14 O31 2.225(14) .
Ag14 O33 2.399(15) .
Ag14 O25 2.462(6) .
Ag14 O12 2.565(5) .
Ag14 Ag16 3.3478(14) .
Ag15 N7 2.215(8) .
Ag15 C25 2.353(6) .
Ag15 C17 2.528(6) .
Ag15 Ag12 3.0038(8) 4_576
Ag16 Ag17 0.943(15) .
Ag16 O27 2.327(8) .
Ag16 C9 2.477(6) .
Ag16 C1 2.549(6) .
Ag16 C10 2.666(6) .
Ag17 O26 2.151(10) .
Ag17 O28 2.211(15) .
Ag17 C9 2.312(8) .
Ag17 O27 2.396(10) .
Ag17 C10 2.470(8) .
Ag17 C83 2.483(12) .
C1 C2 1.221(9) .
C2 C3 1.434(7) .
C3 C4 1.3900 .
C3 C8 1.3900 .
C4 C5 1.3900 .
C4 H4 0.9300 .
C5 C6 1.3900 .
C5 H5 0.9300 .
C6 C7 1.3900 .
C6 N1 1.448(7) .
C7 C8 1.3900 .
C7 H7 0.9300 .
C8 H8 0.9300 .
C9 C10 1.231(9) .
C10 C11 1.435(7) .
C11 C12 1.3900 .
C11 C16 1.3900 .
C12 C13 1.3900 .
C12 H12 0.9300 .
C13 C14 1.3900 .
C13 H13 0.9300 .
C14 C15 1.3900 .
C14 N2 1.451(7) .
C15 C16 1.3900 .
C15 H15 0.9300 .
C16 H16 0.9300 .
C17 C18 1.212(9) .
C18 C19 1.437(7) .
C19 C20 1.3900 .
C19 C24 1.3900 .
C20 C21 1.3900 .
C20 H20 0.9300 .
C21 C22 1.3900 .
C21 H21 0.9300 .
C22 C23 1.3900 .
C22 N3 1.439(8) .
C23 C24 1.3900 .
C23 H23 0.9300 .
C24 H24 0.9300 .
C25 C26 1.226(9) .
C25 Ag12 2.428(6) 4_576
C25 Ag10 2.492(6) 4_576
C26 C27 1.430(7) .
C27 C28 1.3900 .
C27 C32 1.3900 .
C28 C29 1.3900 .
C28 H28 0.9300 .
C29 C30 1.3900 .
C29 H29 0.9300 .
C30 C31 1.3900 .
C30 N4 1.444(7) .
C31 C32 1.3900 .
C31 H31 0.9300 .
C32 H32 0.9300 .
C33 N5 1.159(10) .
C33 C34 1.455(9) .
C34 C35 1.3900 .
C34 C39 1.3900 .
C35 C36 1.3900 .
C35 H35 0.9300 .
C36 C37 1.3900 .
C36 H36 0.9300 .
C37 C38 1.3900 .
C37 H37 0.9300 .
C38 C39 1.3900 .
C38 C40 1.427(8) .
C39 H39 0.9300 .
C40 N6 1.139(9) .
C41 N7 1.124(12) .
C41 C42 1.433(11) .
C42 C43 1.3900 .
C42 C47 1.3900 .
C43 C44 1.3900 .
C43 H43 0.9300 .
C44 C45 1.3900 .
C44 C48 1.426(9) .
C45 C46 1.3900 .
C45 H45 0.9300 .
C46 C47 1.3900 .
C46 H46 0.9300 .
C47 H47 0.9300 .
C48 N8 1.139(10) .
C49 N9 1.133(12) .
C49 C50 1.432(11) .
C50 C51 1.3900 .
C50 C55 1.3900 .
C51 C52 1.3900 .
C51 H51 0.9300 .
C52 C53 1.3900 .
C52 C56 1.429(7) .
C53 C54 1.3900 .
C53 H53 0.9300 .
C54 C55 1.3900 .
C54 H54 0.9300 .
C55 H55 0.9300 .
C56 N10 1.142(8) .
C57 N11 1.121(11) .
C57 C58 1.419(9) .
C58 C59 1.3900 .
C58 C63 1.3900 .
C59 C60 1.3900 .
C59 H59 0.9300 .
C60 C61 1.3900 .
C60 C64 1.412(9) .
C61 C62 1.3900 .
C61 H61 0.9300 .
C62 C63 1.3900 .
C62 H62 0.9300 .
C63 H63 0.9300 .
C64 N12 1.138(11) .
C65 O9 1.238(7) .
C65 O10 1.243(7) .
C65 C66 1.531(9) .
C66 F1 1.315(8) .
C66 F2 1.321(9) .
C66 F3 1.327(9) .
C67 O11 1.240(8) .
C67 O12 1.241(8) .
C67 C68 1.542(9) .
C68 F5 1.318(9) .
C68 F6 1.326(9) .
C68 F4 1.331(9) .
C69 O14 1.236(8) .
C69 O13 1.252(8) .
C69 C70 1.543(9) .
C70 F9 1.310(9) .
C70 F7 1.316(8) .
C70 F8 1.334(9) .
C71 O16 1.225(8) .
C71 O15 1.237(8) .
C71 C72 1.555(10) .
C72 F12 1.292(10) .
C72 F10 1.312(10) .
C72 F11 1.345(11) .
C73 O17 1.237(8) .
C73 O18 1.245(8) .
C73 C74 1.546(9) .
C74 F14 1.315(8) .
C74 F13 1.319(9) .
C74 F15 1.332(9) .
C75 O19 1.224(9) .
C75 O20 1.250(8) .
C75 C76 1.521(11) .
C76 F18 1.216(12) .
C76 F16 1.260(13) .
C76 F17 1.323(14) .
C77 O21 1.220(8) .
C77 O22 1.241(9) .
C77 C78 1.544(9) .
C78 F21 1.244(10) .
C78 F20 1.297(9) .
C78 F19 1.364(11) .
C79 O23 1.229(9) .
C79 O24 1.246(8) .
C79 C80 1.537(10) .
C80 F22 1.302(10) .
C80 F24 1.313(10) .
C80 F23 1.325(11) .
C81 O26 1.180(10) .
C81 O25 1.223(9) .
C81 C82 1.528(10) .
C82 F38 1.202(17) .
C82 F26 1.224(18) .
C82 F27 1.278(16) .
C82 F39 1.31(2) .
C82 F25 1.346(15) .
C82 F37 1.36(2) .
C83 O27 1.208(11) .
C83 O28 1.258(12) .
C83 C84 1.686(15) .
C84 F29 1.247(18) .
C84 F30 1.354(16) .
C84 F28 1.373(17) .
C85 O30 1.229(9) .
C85 O29 1.230(9) .
C85 C86 1.541(10) .
C86 F31 1.259(15) .
C86 F32 1.263(15) .
C86 F41 1.283(15) .
C86 F40 1.308(16) .
C86 F42 1.314(15) .
C86 F33 1.322(15) .
N1 O2 1.203(10) .
N1 O1 1.213(10) .
N2 O3 1.204(10) .
N2 O4 1.224(10) .
N3 O6 1.210(12) .
N3 O5 1.228(11) .
N4 O7 1.207(11) .
N4 O8 1.241(10) .
N6 Ag11 2.169(6) 3_565
N8 Ag13 2.207(8) 1_545
N10 Ag8 2.163(5) 2
O5 Ag13 2.525(6) 2_645
O30 Ag5 2.429(5) 4_575
O1W H1W 0.8998 .
O1W H2W 0.8993 .
O31 C87 1.241(16) .
O32 C87 1.224(14) .
C87 C88 1.501(10) .
C88 F35 1.30(3) .
C88 F34 1.30(2) .
C88 F36 1.39(3) .
O33 C89 1.22(2) .
O34 C89 1.222(18) .
C89 C90 1.502(10) .
C90 F44 1.23(8) .
C90 F43 1.26(6) .
C90 F45 1.55(7) .
