#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/46/7024600.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7024600
loop_
_publ_author_name
'Kizaki, Tetsuro'
'Matsumoto, Takahiro'
'Ogo, Seiji'
_publ_section_title
;
 Dissolved N(2) sensing by pH-dependent Ru complexes.
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1339
_journal_page_last               1344
_journal_paper_doi               10.1039/b918940h
_journal_volume                  39
_journal_year                    2010
_chemical_formula_sum            'C15 H37 F6 N6 O2 P Ru'
_chemical_formula_weight         579.53
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                85.549(9)
_cell_angle_beta                 76.427(8)
_cell_angle_gamma                82.05(1)
_cell_formula_units_Z            2
_cell_length_a                   8.024(2)
_cell_length_b                   10.482(3)
_cell_length_c                   14.330(4)
_cell_measurement_reflns_used    3352
_cell_measurement_temperature    123.2
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.5
_cell_volume                     1159.1(5)
_computing_cell_refinement       CRYSTALCLEAR
_computing_data_collection       CRYSTALCLEAR
_computing_data_reduction        'teXsan Ver. 2.0'
_computing_publication_material  'teXsan Ver. 2.0'
_computing_structure_refinement  'teXsan Ver. 2.0'
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 28.57
_diffrn_measured_fraction_theta_full 0.9853
_diffrn_measured_fraction_theta_max 0.9853
_diffrn_measurement_device_type  'Rigaku/MSC Saturn CCD'
_diffrn_measurement_method       ω
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.026
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            5227
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.818
_exptl_absorpt_correction_T_max  0.947
_exptl_absorpt_correction_T_min  0.891
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Jacobson, 1998)'
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.660
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             596.00
_exptl_crystal_size_max          0.150
_exptl_crystal_size_mid          0.080
_exptl_crystal_size_min          0.080
_refine_diff_density_max         2.12
_refine_diff_density_min         -0.92
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.004
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     280
_refine_ls_number_reflns         5227
_refine_ls_R_factor_gt           0.0608
_refine_ls_shift/su_max          0.0004
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²) + (0.12900(Max(Fo²,0) + 2Fc²)/3)²]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1857
_reflns_number_gt                4527
_reflns_number_total             5227
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            b918940h.txt
_cod_data_source_block           '_RuC14H32N4OHN2_3_090625'
_cod_original_cell_volume        1159.0(6)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C15 H37 F6 N6 O2 P Ru '
_cod_database_code               7024600
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
-x,-y,-z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
Ru(1) Ru 0.72257(4) 0.31315(3) 0.27459(2) 0.0221(1) Uani 1.00 1 d
P(1) P 1.2173(2) -0.1774(1) 0.25056(9) 0.0290(3) Uani 1.00 1 d
F(1) F 1.0286(6) -0.2037(4) 0.3057(4) 0.092(2) Uani 1.00 1 d
F(2) F 1.1421(8) -0.0611(4) 0.1905(3) 0.091(2) Uani 1.00 1 d
F(3) F 1.2107(5) -0.0776(3) 0.3314(2) 0.0522(10) Uani 1.00 1 d
F(4) F 1.4048(6) -0.1526(5) 0.2005(4) 0.104(2) Uani 1.00 1 d
F(5) F 1.2220(5) -0.2771(3) 0.1722(2) 0.0513(10) Uani 1.00 1 d
F(6) F 1.2878(8) -0.2932(4) 0.3140(3) 0.090(2) Uani 1.00 1 d
O(1) O 0.9688(4) 0.2385(3) 0.2042(2) 0.0274(8) Uani 1.00 1 d
O(2) O 1.2365(4) 0.2795(3) 0.0625(2) 0.0347(9) Uani 1.00 1 d
N(1) N 0.5047(5) 0.3874(4) 0.3423(3) 0.033(1) Uani 1.00 1 d
N(2) N 0.3767(5) 0.4307(5) 0.3865(3) 0.042(1) Uani 1.00 1 d
N(3) N 0.8492(5) 0.4699(4) 0.2988(3) 0.034(1) Uani 1.00 1 d
N(4) N 0.6972(5) 0.4229(4) 0.1447(3) 0.0272(9) Uani 1.00 1 d
N(5) N 0.6152(6) 0.1504(4) 0.2421(3) 0.035(1) Uani 1.00 1 d
N(6) N 0.7638(5) 0.1947(4) 0.3985(3) 0.0289(9) Uani 1.00 1 d
C(1) C 0.7350(8) 0.5772(6) 0.3525(5) 0.055(2) Uani 1.00 1 d
C(2) C 0.9224(9) 0.5225(6) 0.1993(5) 0.057(2) Uani 1.00 1 d
C(3) C 0.799(1) 0.5350(6) 0.1366(4) 0.059(2) Uani 1.00 1 d
C(4) C 0.5245(7) 0.4811(5) 0.1369(3) 0.042(1) Uani 1.00 1 d
C(5) C 0.7736(7) 0.3377(5) 0.0611(3) 0.034(1) Uani 1.00 1 d
C(6) C 0.6863(8) 0.2161(5) 0.0653(4) 0.043(1) Uani 1.00 1 d
C(7) C 0.7053(7) 0.1099(5) 0.1456(4) 0.045(1) Uani 1.00 1 d
C(8) C 0.4277(7) 0.1693(5) 0.2467(4) 0.041(1) Uani 1.00 1 d
C(9) C 0.6440(10) 0.0432(6) 0.3168(5) 0.059(2) Uani 1.00 1 d
C(10) C 0.7803(9) 0.0598(6) 0.3676(4) 0.053(2) Uani 1.00 1 d
C(11) C 0.6199(9) 0.2092(7) 0.4852(4) 0.058(2) Uani 1.00 1 d
C(12) C 0.9223(8) 0.2116(6) 0.4283(4) 0.052(2) Uani 1.00 1 d
C(13) C 0.935(1) 0.3558(7) 0.4448(5) 0.067(2) Uani 1.00 1 d
C(14) C 0.9939(8) 0.4323(6) 0.3447(5) 0.050(2) Uani 1.00 1 d
C(15) C 1.2639(7) 0.1720(5) 0.0039(4) 0.040(1) Uani 1.00 1 d
H(1) H 0.9978 0.1455 0.2088 0.0343 Uiso 1.00 1 calc
H(2) H 0.6956 0.5492 0.4175 0.0656 Uiso 1.00 1 calc
H(3) H 0.6389 0.6025 0.3242 0.0656 Uiso 1.00 1 calc
H(4) H 0.7979 0.6484 0.3496 0.0656 Uiso 1.00 1 calc
H(5) H 0.9539 0.6044 0.2039 0.0683 Uiso 1.00 1 calc
H(6) H 1.0204 0.4668 0.1715 0.0683 Uiso 1.00 1 calc
H(7) H 0.7210 0.6109 0.1521 0.0707 Uiso 1.00 1 calc
H(8) H 0.8632 0.5437 0.0719 0.0707 Uiso 1.00 1 calc
H(9) H 0.5312 0.5277 0.0768 0.0506 Uiso 1.00 1 calc
H(10) H 0.4770 0.5377 0.1876 0.0506 Uiso 1.00 1 calc
H(11) H 0.4525 0.4149 0.1409 0.0506 Uiso 1.00 1 calc
H(12) H 0.7637 0.3862 0.0034 0.0415 Uiso 1.00 1 calc
H(13) H 0.8925 0.3123 0.0602 0.0415 Uiso 1.00 1 calc
H(14) H 0.5664 0.2433 0.0722 0.0512 Uiso 1.00 1 calc
H(15) H 0.7314 0.1770 0.0054 0.0512 Uiso 1.00 1 calc
H(16) H 0.6593 0.0362 0.1323 0.0541 Uiso 1.00 1 calc
H(17) H 0.8246 0.0879 0.1444 0.0541 Uiso 1.00 1 calc
H(18) H 0.4033 0.2335 0.1995 0.0490 Uiso 1.00 1 calc
H(19) H 0.3671 0.1963 0.3087 0.0490 Uiso 1.00 1 calc
H(20) H 0.3920 0.0906 0.2349 0.0490 Uiso 1.00 1 calc
H(21) H 0.6752 -0.0352 0.2856 0.0714 Uiso 1.00 1 calc
H(22) H 0.5399 0.0397 0.3629 0.0714 Uiso 1.00 1 calc
H(23) H 0.7720 0.0020 0.4224 0.0619 Uiso 1.00 1 calc
H(24) H 0.8910 0.0404 0.3253 0.0619 Uiso 1.00 1 calc
H(25) H 0.5147 0.1995 0.4690 0.0691 Uiso 1.00 1 calc
H(26) H 0.6417 0.1455 0.5332 0.0691 Uiso 1.00 1 calc
H(27) H 0.6123 0.2926 0.5092 0.0691 Uiso 1.00 1 calc
H(28) H 0.9250 0.1625 0.4864 0.0624 Uiso 1.00 1 calc
H(29) H 1.0190 0.1812 0.3795 0.0624 Uiso 1.00 1 calc
H(30) H 0.8259 0.3952 0.4778 0.0808 Uiso 1.00 1 calc
H(31) H 1.0179 0.3584 0.4824 0.0808 Uiso 1.00 1 calc
H(32) H 1.0392 0.5075 0.3554 0.0595 Uiso 1.00 1 calc
H(33) H 1.0809 0.3785 0.3035 0.0595 Uiso 1.00 1 calc
H(34) H 1.1428 0.2745 0.1084 0.0416 Uiso 1.00 1 calc
H(35) H 1.2991 0.0884 0.0392 0.0343 Uiso 1.00 1 calc
H(36) H 1.1645 0.1759 -0.0209 0.0343 Uiso 1.00 1 calc
H(37) H 1.3695 0.1834 -0.0455 0.0343 Uiso 1.00 1 calc
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.003 0.002
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
H H 0.000 0.000
;International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.2)
;
F F 0.017 0.010
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
N N 0.006 0.003
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
O O 0.011 0.006
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
P P 0.102 0.094
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
Ru Ru -1.259 0.836
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
O(1) Ru(1) N(1) 176.6(1) yes
O(1) Ru(1) N(3) 83.8(1) yes
O(1) Ru(1) N(4) 88.5(1) yes
O(1) Ru(1) N(5) 91.6(1) yes
O(1) Ru(1) N(6) 87.5(1) yes
N(1) Ru(1) N(3) 93.1(2) yes
N(1) Ru(1) N(4) 92.3(2) yes
N(1) Ru(1) N(5) 91.6(2) yes
N(1) Ru(1) N(6) 91.8(2) yes
N(3) Ru(1) N(4) 83.9(2) yes
N(3) Ru(1) N(5) 175.2(1) yes
N(3) Ru(1) N(6) 96.8(2) yes
N(4) Ru(1) N(5) 95.1(2) yes
N(4) Ru(1) N(6) 175.8(1) yes
N(5) Ru(1) N(6) 83.9(2) yes
F(1) P(1) F(2) 91.1(3) yes
F(1) P(1) F(3) 87.6(2) yes
F(1) P(1) F(4) 177.6(4) yes
F(1) P(1) F(5) 91.7(2) yes
F(1) P(1) F(6) 87.4(3) yes
F(2) P(1) F(3) 87.7(2) yes
F(2) P(1) F(4) 90.7(3) yes
F(2) P(1) F(5) 92.8(2) yes
F(2) P(1) F(6) 178.1(3) yes
F(3) P(1) F(4) 90.9(2) yes
F(3) P(1) F(5) 179.1(2) yes
F(3) P(1) F(6) 91.1(2) yes
F(4) P(1) F(5) 89.8(2) yes
F(4) P(1) F(6) 90.9(3) yes
F(5) P(1) F(6) 88.4(2) yes
Ru(1) N(1) N(2) 176.9(4) yes
Ru(1) N(3) C(1) 115.5(3) yes
Ru(1) N(3) C(2) 103.7(3) yes
Ru(1) N(3) C(14) 114.5(3) yes
C(1) N(3) C(2) 107.5(5) yes
C(1) N(3) C(14) 108.0(4) yes
C(2) N(3) C(14) 107.1(5) yes
Ru(1) N(4) C(3) 107.3(3) yes
Ru(1) N(4) C(4) 117.9(3) yes
Ru(1) N(4) C(5) 108.2(3) yes
C(3) N(4) C(4) 104.8(5) yes
C(3) N(4) C(5) 109.5(4) yes
C(4) N(4) C(5) 108.9(4) yes
Ru(1) N(5) C(7) 109.0(3) yes
Ru(1) N(5) C(8) 116.1(3) yes
Ru(1) N(5) C(9) 107.0(3) yes
C(7) N(5) C(8) 108.3(4) yes
C(7) N(5) C(9) 110.2(5) yes
C(8) N(5) C(9) 106.1(5) yes
Ru(1) N(6) C(10) 104.3(3) yes
Ru(1) N(6) C(11) 115.1(3) yes
Ru(1) N(6) C(12) 114.1(3) yes
C(10) N(6) C(11) 107.7(5) yes
C(10) N(6) C(12) 108.3(5) yes
C(11) N(6) C(12) 107.0(5) yes
N(3) C(2) C(3) 113.0(5) yes
N(4) C(3) C(2) 114.8(5) yes
N(4) C(5) C(6) 113.9(4) yes
C(5) C(6) C(7) 119.1(5) yes
N(5) C(7) C(6) 113.2(4) yes
N(5) C(9) C(10) 114.5(5) yes
N(6) C(10) C(9) 111.4(5) yes
N(6) C(12) C(13) 113.1(5) yes
C(12) C(13) C(14) 110.4(5) yes
N(3) C(14) C(13) 111.4(5) yes
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Ru(1) O(1) 2.072(3) yes
Ru(1) N(1) 1.884(4) yes
Ru(1) N(3) 2.138(4) yes
Ru(1) N(4) 2.148(4) yes
Ru(1) N(5) 2.142(4) yes
Ru(1) N(6) 2.151(4) yes
P(1) F(1) 1.585(4) yes
P(1) F(2) 1.572(4) yes
P(1) F(3) 1.608(3) yes
P(1) F(4) 1.555(4) yes
P(1) F(5) 1.583(3) yes
P(1) F(6) 1.581(4) yes
O(2) C(15) 1.420(6) yes
N(1) N(2) 1.128(6) yes
N(3) C(1) 1.488(7) yes
N(3) C(2) 1.502(7) yes
N(3) C(14) 1.458(7) yes
N(4) C(3) 1.506(7) yes
N(4) C(4) 1.460(6) yes
N(4) C(5) 1.510(6) yes
N(5) C(7) 1.467(7) yes
N(5) C(8) 1.477(7) yes
N(5) C(9) 1.523(8) yes
N(6) C(10) 1.494(7) yes
N(6) C(11) 1.485(7) yes
N(6) C(12) 1.470(7) yes
C(2) C(3) 1.469(9) yes
C(5) C(6) 1.528(8) yes
C(6) C(7) 1.557(8) yes
C(9) C(10) 1.484(9) yes
C(12) C(13) 1.569(9) yes
C(13) C(14) 1.591(10) yes
loop_
_geom_contact_atom_site_label_1
_geom_contact_atom_site_label_2
_geom_contact_distance
_geom_contact_site_symmetry_2
F(1) C(10) 3.226(8) .
F(1) C(1) 3.433(8) 1_545
F(2) O(1) 3.255(5) .
F(2) C(10) 3.535(8) .
F(2) C(15) 3.535(7) .
F(3) C(8) 3.311(6) 1_655
F(3) C(11) 3.355(7) 2_756
F(3) C(10) 3.488(8) .
F(3) C(12) 3.594(7) 2_756
F(4) C(15) 3.460(7) 2_855
F(4) C(8) 3.526(7) 1_655
F(5) C(4) 3.239(6) 1_645
F(5) C(6) 3.340(6) 2_755
F(5) C(2) 3.343(7) 1_545
F(5) C(5) 3.442(6) 2_755
F(6) N(2) 3.045(6) 1_645
F(6) C(11) 3.342(8) 2_756
F(6) C(13) 3.557(9) 2_756
F(6) N(1) 3.592(6) 1_645
O(1) O(2) 2.645(4) .
O(1) C(15) 3.317(6) .
O(2) C(3) 3.373(7) 2_765
O(2) C(8) 3.405(7) 1_655
O(2) C(6) 3.587(7) 1_655
N(2) C(14) 3.262(7) 1_455
C(3) C(15) 3.582(8) 2_765
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
O(1) H(1) F(2) 1_555 0.971 2.314 3.255(5) 163.078 no
O(2) H(34) O(1) 1_555 0.880 1.773 2.645(4) 170.677 no
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_publ_flag
Ru(1) N(3) C(2) C(3) 44.6(6) yes
Ru(1) N(3) C(14) C(13) -57.1(5) yes
Ru(1) N(4) C(3) C(2) 15.8(7) yes
Ru(1) N(4) C(5) C(6) 59.7(5) yes
Ru(1) N(5) C(7) C(6) -61.2(5) yes
Ru(1) N(5) C(9) C(10) -19.2(7) yes
Ru(1) N(6) C(10) C(9) -45.6(6) yes
Ru(1) N(6) C(12) C(13) 54.0(6) yes
O(1) Ru(1) N(1) N(2) -52(8) yes
O(1) Ru(1) N(3) C(1) 179.2(4) yes
O(1) Ru(1) N(3) C(2) 61.9(4) yes
O(1) Ru(1) N(3) C(14) -54.4(4) yes
O(1) Ru(1) N(4) C(3) -76.6(4) yes
O(1) Ru(1) N(4) C(4) 165.5(4) yes
O(1) Ru(1) N(4) C(5) 41.5(3) yes
O(1) Ru(1) N(5) C(7) -37.0(3) yes
O(1) Ru(1) N(5) C(8) -159.6(4) yes
O(1) Ru(1) N(5) C(9) 82.1(4) yes
O(1) Ru(1) N(6) C(10) -64.6(4) yes
O(1) Ru(1) N(6) C(11) 177.6(4) yes
O(1) Ru(1) N(6) C(12) 53.3(4) yes
N(1) Ru(1) N(3) C(1) -1.9(4) yes
N(1) Ru(1) N(3) C(2) -119.2(4) yes
N(1) Ru(1) N(3) C(14) 124.5(4) yes
N(1) Ru(1) N(4) C(3) 100.2(4) yes
N(1) Ru(1) N(4) C(4) -17.8(4) yes
N(1) Ru(1) N(4) C(5) -141.8(3) yes
N(1) Ru(1) N(5) C(7) 144.0(4) yes
N(1) Ru(1) N(5) C(8) 21.4(4) yes
N(1) Ru(1) N(5) C(9) -96.9(4) yes
N(1) Ru(1) N(6) C(10) 118.6(4) yes
N(1) Ru(1) N(6) C(11) 0.9(4) yes
N(1) Ru(1) N(6) C(12) -123.4(4) yes
N(2) N(1) Ru(1) N(3) -71(7) yes
N(2) N(1) Ru(1) N(4) -155(7) yes
N(2) N(1) Ru(1) N(5) 109(7) yes
N(2) N(1) Ru(1) N(6) 25(7) yes
N(3) Ru(1) N(4) C(3) 7.3(4) yes
N(3) Ru(1) N(4) C(4) -110.6(4) yes
N(3) Ru(1) N(4) C(5) 125.4(3) yes
N(3) Ru(1) N(5) C(7) -26(1) yes
N(3) Ru(1) N(5) C(8) -148(1) yes
N(3) Ru(1) N(5) C(9) 93(1) yes
N(3) Ru(1) N(6) C(10) -148.1(4) yes
N(3) Ru(1) N(6) C(11) 94.2(4) yes
N(3) Ru(1) N(6) C(12) -30.1(4) yes
N(3) C(2) C(3) N(4) -42.4(8) yes
N(3) C(14) C(13) C(12) 79.6(7) yes
N(4) Ru(1) N(3) C(1) 90.1(4) yes
N(4) Ru(1) N(3) C(2) -27.2(4) yes
N(4) Ru(1) N(3) C(14) -143.5(4) yes
N(4) Ru(1) N(5) C(7) 51.6(4) yes
N(4) Ru(1) N(5) C(8) -71.0(4) yes
N(4) Ru(1) N(5) C(9) 170.7(4) yes
N(4) Ru(1) N(6) C(10) -48(1) yes
N(4) Ru(1) N(6) C(11) -166(1) yes
N(4) Ru(1) N(6) C(12) 69(1) yes
N(4) C(5) C(6) C(7) -67.4(6) yes
N(5) Ru(1) N(3) C(1) 168(1) yes
N(5) Ru(1) N(3) C(2) 50(1) yes
N(5) Ru(1) N(3) C(14) -65(1) yes
N(5) Ru(1) N(4) C(3) -168.0(4) yes
N(5) Ru(1) N(4) C(4) 74.1(4) yes
N(5) Ru(1) N(4) C(5) -49.9(3) yes
N(5) Ru(1) N(6) C(10) 27.2(4) yes
N(5) Ru(1) N(6) C(11) -90.6(4) yes
N(5) Ru(1) N(6) C(12) 145.2(4) yes
N(5) C(7) C(6) C(5) 68.3(6) yes
N(5) C(9) C(10) N(6) 45.3(8) yes
N(6) Ru(1) N(3) C(1) -94.1(4) yes
N(6) Ru(1) N(3) C(2) 148.6(4) yes
N(6) Ru(1) N(3) C(14) 32.4(4) yes
N(6) Ru(1) N(4) C(3) -92(1) yes
N(6) Ru(1) N(4) C(4) 149(1) yes
N(6) Ru(1) N(4) C(5) 25(1) yes
N(6) Ru(1) N(5) C(7) -124.4(4) yes
N(6) Ru(1) N(5) C(8) 113.0(4) yes
N(6) Ru(1) N(5) C(9) -5.2(4) yes
N(6) C(12) C(13) C(14) -78.2(7) yes
C(1) N(3) C(2) C(3) -78.2(6) yes
C(1) N(3) C(14) C(13) 73.1(6) yes
C(2) N(3) C(14) C(13) -171.4(5) yes
C(2) C(3) N(4) C(4) 141.9(6) yes
C(2) C(3) N(4) C(5) -101.4(6) yes
C(3) N(4) C(5) C(6) 176.4(5) yes
C(3) C(2) N(3) C(14) 166.0(5) yes
C(4) N(4) C(5) C(6) -69.5(5) yes
C(6) C(7) N(5) C(8) 66.0(5) yes
C(6) C(7) N(5) C(9) -178.3(5) yes
C(7) N(5) C(9) C(10) 99.2(6) yes
C(8) N(5) C(9) C(10) -143.8(6) yes
C(9) C(10) N(6) C(11) 77.2(6) yes
C(9) C(10) N(6) C(12) -167.5(5) yes
C(10) N(6) C(12) C(13) 169.7(5) yes
C(11) N(6) C(12) C(13) -74.6(6) yes
C(11) N(6) C(12) C(13) -74.6(6) yes
