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#$Date: 2016-03-25 16:20:24 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179964 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/58/7025890.cif $
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#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7025890
loop_
_publ_author_name
'Wang, Jiao'
'Pan, Yingli'
'Chen, Jiangfang'
'Gu, Jiansheng'
'Zhang, Yong'
'Jia, Dingxian'
_publ_section_title
;
 Investigating metal size effects in the Ln/As/Se/amine (Ln = lanthanide
 excluding Pm, amine = en, dien, en+trien) systems: solvothermal syntheses
 and characterizations of lanthanide selenidoarsenates.
;
_journal_issue                   30
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7066
_journal_page_last               7072
_journal_paper_doi               10.1039/c0dt00040j
_journal_volume                  39
_journal_year                    2010
_chemical_formula_moiety         'C8 H26 As Ce N6 Se4'
_chemical_formula_sum            'C8 H26 As Ce N6 Se4'
_chemical_formula_weight         737.24
_chemical_name_systematic
;
?
;
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      61
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   8.8021(9)
_cell_length_b                   16.5022(14)
_cell_length_c                   26.691(3)
_cell_measurement_reflns_used    12052
_cell_measurement_temperature    223(2)
_cell_measurement_theta_max      25.3
_cell_measurement_theta_min      3.0
_cell_volume                     3877.0(7)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      223(2)
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0736
_diffrn_reflns_av_sigmaI/netI    0.0365
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            36022
_diffrn_reflns_theta_full        25.35
_diffrn_reflns_theta_max         25.35
_diffrn_reflns_theta_min         3.03
_exptl_absorpt_coefficient_mu    11.408
_exptl_absorpt_correction_T_max  0.3414
_exptl_absorpt_correction_T_min  0.2087
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    2.522
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2736
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.887
_refine_diff_density_min         -0.790
_refine_diff_density_rms         0.192
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.168
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     176
_refine_ls_number_reflns         3548
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.169
_refine_ls_R_factor_all          0.0569
_refine_ls_R_factor_gt           0.0500
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0079P)²+44.1402P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0827
_refine_ls_wR_factor_ref         0.0848
_reflns_number_gt                3247
_reflns_number_total             3548
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0dt00040j.txt
_cod_data_source_block           complex_2b
_cod_database_code               7025890
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, z'
'x, -y+1/2, z+1/2'
'-x+1/2, -y, z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, -z'
'-x, y-1/2, -z-1/2'
'x-1/2, y, -z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ce1 Ce 0.04323(5) 0.24176(3) 0.617129(17) 0.01677(13) Uani 1 1 d .
Se1 Se 0.33301(9) 0.16434(5) 0.56517(3) 0.0219(2) Uani 1 1 d .
Se2 Se 0.34300(10) 0.33706(5) 0.65043(3) 0.0250(2) Uani 1 1 d .
Se4 Se 0.56887(10) 0.15082(6) 0.68409(3) 0.0256(2) Uani 1 1 d .
Se3 Se 0.69549(9) 0.28156(6) 0.57455(3) 0.0251(2) Uani 1 1 d .
As1 As 0.49117(9) 0.23340(5) 0.61948(3) 0.01809(19) Uani 1 1 d .
N1 N -0.0820(9) 0.0933(4) 0.6309(3) 0.0270(17) Uani 1 1 d .
H1 H -0.1863 0.1013 0.6335 0.032 Uiso 1 1 calc R
N2 N -0.0333(8) 0.1625(5) 0.5320(3) 0.0271(17) Uani 1 1 d .
H2A H -0.0928 0.1960 0.5126 0.033 Uiso 1 1 calc R
H2B H 0.0537 0.1514 0.5142 0.033 Uiso 1 1 calc R
N3 N 0.1670(8) 0.1504(4) 0.6889(3) 0.0284(17) Uani 1 1 d .
H3A H 0.2707 0.1570 0.6877 0.034 Uiso 1 1 calc R
H3B H 0.1346 0.1697 0.7194 0.034 Uiso 1 1 calc R
N4 N -0.0325(9) 0.3973(4) 0.6320(2) 0.0289(18) Uani 1 1 d D
N5 N -0.1059(9) 0.2759(4) 0.7048(3) 0.0307(18) Uani 1 1 d D
N6 N 0.0939(9) 0.3430(4) 0.5406(3) 0.0314(18) Uani 1 1 d D
C1 C -0.0579(12) 0.0420(5) 0.5868(3) 0.034(2) Uani 1 1 d .
H1A H -0.1122 -0.0101 0.5910 0.041 Uiso 1 1 calc R
H1B H 0.0518 0.0302 0.5828 0.041 Uiso 1 1 calc R
C2 C -0.1166(11) 0.0855(5) 0.5408(4) 0.032(2) Uani 1 1 d .
H2C H -0.1052 0.0498 0.5112 0.039 Uiso 1 1 calc R
H2D H -0.2261 0.0972 0.5452 0.039 Uiso 1 1 calc R
C3 C -0.0331(10) 0.0533(5) 0.6788(3) 0.029(2) Uani 1 1 d .
H3C H -0.0894 0.0772 0.7073 0.035 Uiso 1 1 calc R
H3D H -0.0575 -0.0053 0.6773 0.035 Uiso 1 1 calc R
C4 C 0.1340(11) 0.0641(5) 0.6867(4) 0.031(2) Uani 1 1 d .
H4A H 0.1653 0.0377 0.7184 0.037 Uiso 1 1 calc R
H4B H 0.1911 0.0388 0.6589 0.037 Uiso 1 1 calc R
C5A C -0.146(2) 0.4197(12) 0.6703(6) 0.036(3) Uani 0.45 1 d PD
C5B C -0.064(2) 0.4145(9) 0.6856(4) 0.036(3) Uani 0.55 1 d PD
C6A C -0.114(3) 0.3649(6) 0.7141(8) 0.036(3) Uani 0.47 1 d PD
C6B C -0.1730(19) 0.3574(6) 0.7107(8) 0.036(3) Uani 0.53 1 d PD
C7A C 0.047(2) 0.4601(9) 0.6015(6) 0.036(3) Uani 0.48 1 d PD
C7B C -0.024(2) 0.4512(10) 0.5879(5) 0.036(3) Uani 0.52 1 d PD
C8A C 0.040(2) 0.4267(7) 0.5484(7) 0.036(3) Uani 0.56 1 d PD
C8B C 0.095(3) 0.4322(7) 0.5491(10) 0.036(3) Uani 0.44 1 d PD
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ce Ce -0.2871 2.4523 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
N3 Ce1 N6 146.3(2) .
N3 Ce1 N4 122.4(2) .
N6 Ce1 N4 63.7(2) .
N3 Ce1 N2 115.5(2) .
N6 Ce1 N2 72.7(2) .
N4 Ce1 N2 121.7(2) .
N3 Ce1 N1 63.8(2) .
N6 Ce1 N1 137.3(2) .
N4 Ce1 N1 138.0(2) .
N2 Ce1 N1 64.9(2) .
N3 Ce1 N5 72.5(2) .
N6 Ce1 N5 127.1(2) .
N4 Ce1 N5 63.74(19) .
N2 Ce1 N5 134.2(2) .
N1 Ce1 N5 82.8(2) .
N3 Ce1 Se1 76.01(16) .
N6 Ce1 Se1 77.51(16) .
N4 Ce1 Se1 130.57(16) .
N2 Ce1 Se1 68.81(15) .
N1 Ce1 Se1 91.28(16) .
N5 Ce1 Se1 147.25(16) .
N3 Ce1 Se2 75.03(16) .
N6 Ce1 Se2 76.57(18) .
N4 Ce1 Se2 72.14(17) .
N2 Ce1 Se2 132.56(15) .
N1 Ce1 Se2 137.90(16) .
N5 Ce1 Se2 93.25(16) .
Se1 Ce1 Se2 69.89(2) .
N3 Ce1 Se3 136.98(16) 1_455
N6 Ce1 Se3 76.68(18) 1_455
N4 Ce1 Se3 68.48(17) 1_455
N2 Ce1 Se3 65.18(16) 1_455
N1 Ce1 Se3 81.43(16) 1_455
N5 Ce1 Se3 79.08(16) 1_455
Se1 Ce1 Se3 132.01(3) 1_455
Se2 Ce1 Se3 139.13(3) 1_455
As1 Se1 Ce1 90.66(3) .
As1 Se2 Ce1 90.13(3) .
As1 Se3 Ce1 118.16(4) 1_655
Se4 As1 Se3 111.24(5) .
Se4 As1 Se2 109.82(5) .
Se3 As1 Se2 111.87(5) .
Se4 As1 Se1 110.92(5) .
Se3 As1 Se1 108.31(5) .
Se2 As1 Se1 104.48(4) .
C1 N1 C3 112.8(7) .
C1 N1 Ce1 110.7(5) .
C3 N1 Ce1 113.4(5) .
C1 N1 H1 106.5 .
C3 N1 H1 106.5 .
Ce1 N1 H1 106.5 .
C2 N2 Ce1 113.7(5) .
C2 N2 H2A 108.8 .
Ce1 N2 H2A 108.8 .
C2 N2 H2B 108.8 .
Ce1 N2 H2B 108.8 .
H2A N2 H2B 107.7 .
C4 N3 Ce1 116.3(5) .
C4 N3 H3A 108.2 .
Ce1 N3 H3A 108.2 .
C4 N3 H3B 108.2 .
Ce1 N3 H3B 108.2 .
H3A N3 H3B 107.4 .
C5A N4 C7B 115.8(10) .
C5A N4 C5B 32.5(10) .
C7B N4 C5B 131.5(10) .
C5A N4 C7A 121.5(12) .
C7B N4 C7A 28.9(10) .
C5B N4 C7A 118.8(10) .
C5A N4 Ce1 120.7(9) .
C7B N4 Ce1 116.5(8) .
C5B N4 Ce1 111.9(7) .
C7A N4 Ce1 117.8(8) .
C6B N5 C6A 20.9(12) .
C6B N5 Ce1 118.1(8) .
C6A N5 Ce1 111.6(9) .
C8A N6 C8B 19.2(12) .
C8A N6 Ce1 115.0(8) .
C8B N6 Ce1 120.1(10) .
N1 C1 C2 109.1(7) .
N1 C1 H1A 109.9 .
C2 C1 H1A 109.9 .
N1 C1 H1B 109.9 .
C2 C1 H1B 109.9 .
H1A C1 H1B 108.3 .
N2 C2 C1 111.5(7) .
N2 C2 H2C 109.3 .
C1 C2 H2C 109.3 .
N2 C2 H2D 109.3 .
C1 C2 H2D 109.3 .
H2C C2 H2D 108.0 .
C4 C3 N1 110.5(7) .
C4 C3 H3C 109.6 .
N1 C3 H3C 109.6 .
C4 C3 H3D 109.6 .
N1 C3 H3D 109.6 .
H3C C3 H3D 108.1 .
N3 C4 C3 108.6(7) .
N3 C4 H4A 110.0 .
C3 C4 H4A 110.0 .
N3 C4 H4B 110.0 .
C3 C4 H4B 110.0 .
H4A C4 H4B 108.4 .
N4 C5A C6A 105.3(14) .
N4 C5B C6B 115.5(14) .
N5 C6A C5A 118.2(15) .
N5 C6B C5B 105.6(11) .
N4 C7A C8A 103.6(12) .
N4 C7B C8B 117.2(15) .
N6 C8A C7A 117.2(14) .
N6 C8B C7B 107.9(13) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ce1 N3 2.670(7) .
Ce1 N6 2.676(7) .
Ce1 N4 2.682(7) .
Ce1 N2 2.708(7) .
Ce1 N1 2.711(7) .
Ce1 N5 2.741(7) .
Ce1 Se1 3.1720(10) .
Ce1 Se2 3.1978(10) .
Ce1 Se3 3.3304(10) 1_455
Se1 As1 2.3104(12) .
Se2 As1 2.3044(12) .
Se4 As1 2.3021(12) .
Se3 As1 2.3030(12) .
Se3 Ce1 3.3304(10) 1_655
N1 C1 1.467(11) .
N1 C3 1.501(11) .
N1 H1 0.9300 .
N2 C2 1.486(11) .
N2 H2A 0.9200 .
N2 H2B 0.9200 .
N3 C4 1.455(11) .
N3 H3A 0.9200 .
N3 H3B 0.9200 .
N4 C5A 1.473(9) .
N4 C7B 1.478(9) .
N4 C5B 1.484(9) .
N4 C7A 1.495(9) .
N5 C6B 1.478(9) .
N5 C6A 1.491(9) .
N6 C8A 1.477(9) .
N6 C8B 1.490(10) .
C1 C2 1.512(13) .
C1 H1A 0.9900 .
C1 H1B 0.9900 .
C2 H2C 0.9900 .
C2 H2D 0.9900 .
C3 C4 1.497(13) .
C3 H3C 0.9900 .
C3 H3D 0.9900 .
C4 H4A 0.9900 .
C4 H4B 0.9900 .
C5A C6A 1.502(10) .
C5B C6B 1.500(10) .
C7A C8A 1.520(10) .
C7B C8B 1.505(10) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N3 H3B Se4 0.92 2.66 3.498(7) 152.2 8_557
N3 H3A Se4 0.92 2.63 3.540(8) 171.0 .
N2 H2B Se3 0.92 2.90 3.605(7) 134.8 6_566
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
N3 Ce1 Se1 As1 -64.70(16) .
N6 Ce1 Se1 As1 94.29(17) .
N4 Ce1 Se1 As1 56.2(2) .
N2 Ce1 Se1 As1 170.35(17) .
N1 Ce1 Se1 As1 -127.24(16) .
N5 Ce1 Se1 As1 -48.5(3) .
Se2 Ce1 Se1 As1 14.21(3) .
Se3 Ce1 Se1 As1 153.15(4) 1_455
N3 Ce1 Se2 As1 66.04(17) .
N6 Ce1 Se2 As1 -95.67(16) .
N4 Ce1 Se2 As1 -161.99(14) .
N2 Ce1 Se2 As1 -45.1(2) .
N1 Ce1 Se2 As1 54.1(2) .
N5 Ce1 Se2 As1 136.95(15) .
Se1 Ce1 Se2 As1 -14.25(3) .
Se3 Ce1 Se2 As1 -146.01(4) 1_455
Ce1 Se3 As1 Se4 -6.46(6) 1_655
Ce1 Se3 As1 Se2 116.77(5) 1_655
Ce1 Se3 As1 Se1 -128.61(4) 1_655
Ce1 Se2 As1 Se4 -99.89(4) .
Ce1 Se2 As1 Se3 136.09(4) .
Ce1 Se2 As1 Se1 19.13(4) .
Ce1 Se1 As1 Se4 98.97(4) .
Ce1 Se1 As1 Se3 -138.68(4) .
Ce1 Se1 As1 Se2 -19.30(4) .
N3 Ce1 N1 C1 -114.5(6) .
N6 Ce1 N1 C1 32.1(7) .
N4 Ce1 N1 C1 135.3(6) .
N2 Ce1 N1 C1 25.1(6) .
N5 Ce1 N1 C1 171.6(6) .
Se1 Ce1 N1 C1 -40.8(6) .
Se2 Ce1 N1 C1 -101.5(6) .
Se3 Ce1 N1 C1 91.6(6) 1_455
N3 Ce1 N1 C3 13.5(5) .
N6 Ce1 N1 C3 160.0(5) .
N4 Ce1 N1 C3 -96.7(6) .
N2 Ce1 N1 C3 153.0(6) .
N5 Ce1 N1 C3 -60.5(5) .
Se1 Ce1 N1 C3 87.2(5) .
Se2 Ce1 N1 C3 26.4(6) .
Se3 Ce1 N1 C3 -140.5(5) 1_455
N3 Ce1 N2 C2 46.4(6) .
N6 Ce1 N2 C2 -168.8(6) .
N4 Ce1 N2 C2 -126.3(6) .
N1 Ce1 N2 C2 6.2(5) .
N5 Ce1 N2 C2 -43.5(7) .
Se1 Ce1 N2 C2 108.2(6) .
Se2 Ce1 N2 C2 139.3(5) .
Se3 Ce1 N2 C2 -85.8(6) 1_455
N6 Ce1 N3 C4 -119.6(6) .
N4 Ce1 N3 C4 150.1(6) .
N2 Ce1 N3 C4 -22.6(7) .
N1 Ce1 N3 C4 18.1(6) .
N5 Ce1 N3 C4 108.6(6) .
Se1 Ce1 N3 C4 -80.5(6) .
Se2 Ce1 N3 C4 -153.0(6) .
Se3 Ce1 N3 C4 57.6(7) 1_455
N3 Ce1 N4 C5A -60.8(12) .
N6 Ce1 N4 C5A 157.4(12) .
N2 Ce1 N4 C5A 111.4(12) .
N1 Ce1 N4 C5A 24.8(13) .
N5 Ce1 N4 C5A -16.0(12) .
Se1 Ce1 N4 C5A -160.3(11) .
Se2 Ce1 N4 C5A -119.1(12) .
Se3 Ce1 N4 C5A 72.1(12) 1_455
N3 Ce1 N4 C7B 149.7(10) .
N6 Ce1 N4 C7B 7.9(10) .
N2 Ce1 N4 C7B -38.1(11) .
N1 Ce1 N4 C7B -124.7(10) .
N5 Ce1 N4 C7B -165.6(11) .
Se1 Ce1 N4 C7B 50.1(11) .
Se2 Ce1 N4 C7B 91.4(10) .
Se3 Ce1 N4 C7B -77.4(10) 1_455
N3 Ce1 N4 C5B -25.7(10) .
N6 Ce1 N4 C5B -167.5(9) .
N2 Ce1 N4 C5B 146.5(9) .
N1 Ce1 N4 C5B 59.8(10) .
N5 Ce1 N4 C5B 19.0(9) .
Se1 Ce1 N4 C5B -125.3(9) .
Se2 Ce1 N4 C5B -84.0(9) .
Se3 Ce1 N4 C5B 107.1(9) 1_455
N3 Ce1 N4 C7A 117.2(10) .
N6 Ce1 N4 C7A -24.6(10) .
N2 Ce1 N4 C7A -70.6(11) .
N1 Ce1 N4 C7A -157.2(10) .
N5 Ce1 N4 C7A 162.0(11) .
Se1 Ce1 N4 C7A 17.6(11) .
Se2 Ce1 N4 C7A 58.9(10) .
Se3 Ce1 N4 C7A -109.9(10) 1_455
N3 Ce1 N5 C6B 151.8(11) .
N6 Ce1 N5 C6B 3.0(11) .
N4 Ce1 N5 C6B 10.3(10) .
N2 Ce1 N5 C6B -99.4(10) .
N1 Ce1 N5 C6B -143.5(10) .
Se1 Ce1 N5 C6B 135.3(10) .
Se2 Ce1 N5 C6B 78.6(10) .
Se3 Ce1 N5 C6B -60.9(10) 1_455
N3 Ce1 N5 C6A 129.8(11) .
N6 Ce1 N5 C6A -19.0(11) .
N4 Ce1 N5 C6A -11.7(10) .
N2 Ce1 N5 C6A -121.4(10) .
N1 Ce1 N5 C6A -165.5(11) .
Se1 Ce1 N5 C6A 113.3(10) .
Se2 Ce1 N5 C6A 56.6(11) .
Se3 Ce1 N5 C6A -82.9(11) 1_455
N3 Ce1 N6 C8A -114.4(10) .
N4 Ce1 N6 C8A -4.7(10) .
N2 Ce1 N6 C8A 135.4(10) .
N1 Ce1 N6 C8A 128.7(10) .
N5 Ce1 N6 C8A 2.6(11) .
Se1 Ce1 N6 C8A -153.2(10) .
Se2 Ce1 N6 C8A -81.2(10) .
Se3 Ce1 N6 C8A 67.6(10) 1_455
N3 Ce1 N6 C8B -93.5(13) .
N4 Ce1 N6 C8B 16.2(12) .
N2 Ce1 N6 C8B 156.3(13) .
N1 Ce1 N6 C8B 149.6(12) .
N5 Ce1 N6 C8B 23.5(13) .
Se1 Ce1 N6 C8B -132.3(13) .
Se2 Ce1 N6 C8B -60.3(12) .
Se3 Ce1 N6 C8B 88.5(13) 1_455
C3 N1 C1 C2 177.5(7) .
Ce1 N1 C1 C2 -54.3(9) .
Ce1 N2 C2 C1 -36.6(9) .
N1 C1 C2 N2 61.8(10) .
C1 N1 C3 C4 83.7(9) .
Ce1 N1 C3 C4 -43.2(8) .
Ce1 N3 C4 C3 -47.3(9) .
N1 C3 C4 N3 59.4(10) .
C7B N4 C5A C6A -171.0(15) .
C5B N4 C5A C6A -43.4(15) .
C7A N4 C5A C6A -138.6(16) .
Ce1 N4 C5A C6A 39(2) .
C5A N4 C5B C6B 63(2) .
C7B N4 C5B C6B 135.3(16) .
C7A N4 C5B C6B 167.3(15) .
Ce1 N4 C5B C6B -50.2(16) .
C6B N5 C6A C5A -72(4) .
Ce1 N5 C6A C5A 40(2) .
N4 C5A C6A N5 -52(2) .
C6A N5 C6B C5B 40(3) .
Ce1 N5 C6B C5B -36.4(18) .
N4 C5B C6B N5 57(2) .
C5A N4 C7A C8A -134.8(16) .
C7B N4 C7A C8A -47.8(17) .
C5B N4 C7A C8A -172.4(13) .
Ce1 N4 C7A C8A 47.3(16) .
C5A N4 C7B C8B 177.3(18) .
C5B N4 C7B C8B 142.7(17) .
C7A N4 C7B C8B 68(3) .
Ce1 N4 C7B C8B -32(2) .
C8B N6 C8A C7A -76(5) .
Ce1 N6 C8A C7A 33.9(18) .
N4 C7A C8A N6 -52(2) .
C8A N6 C8B C7B 43(3) .
Ce1 N6 C8B C7B -36(2) .
N4 C7B C8B N6 44(3) .
