#------------------------------------------------------------------------------
#$Date: 2016-03-25 16:23:51 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179967 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/61/7026177.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7026177
loop_
_publ_author_name
'Braddock-Wilking, Janet'
'Gao, Li-Bin'
'Rath, Nigam P.'
_publ_section_title
;
 Luminescent platinum complexes containing phosphorus-linked silole
 ligands.
;
_journal_issue                   39
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9321
_journal_page_last               9328
_journal_paper_doi               10.1039/c0dt00259c
_journal_volume                  39
_journal_year                    2010
_chemical_formula_sum            'C290 H262 Cl30 O13 P8 Pt4 Si4'
_chemical_formula_weight         6158.98
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 98.290(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            1
_cell_length_a                   22.261(4)
_cell_length_b                   14.057(3)
_cell_length_c                   22.741(4)
_cell_measurement_reflns_used    9828
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      25.61
_cell_measurement_theta_min      2.35
_cell_volume                     7042(2)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1008
_diffrn_reflns_av_sigmaI/netI    0.0799
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            157483
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         27.60
_diffrn_reflns_theta_min         2.59
_exptl_absorpt_coefficient_mu    2.386
_exptl_absorpt_correction_T_max  0.7793
_exptl_absorpt_correction_T_min  0.3770
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'sadabs v2008/1'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.452
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             3104
_exptl_crystal_size_max          0.51
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.11
_refine_diff_density_max         2.720
_refine_diff_density_min         -2.059
_refine_diff_density_rms         0.188
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.096
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     835
_refine_ls_number_reflns         16137
_refine_ls_number_restraints     45
_refine_ls_restrained_S_all      1.096
_refine_ls_R_factor_all          0.1358
_refine_ls_R_factor_gt           0.0713
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0740P)²+97.5558P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1692
_refine_ls_wR_factor_ref         0.2223
_reflns_number_gt                10150
_reflns_number_total             16137
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0dt00259c.txt
_cod_data_source_block           w12908
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'no' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7026177
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.849144(15) -0.36658(3) 0.491089(16) 0.03067(12) Uani 1 1 d . . .
P1 P 0.79719(10) -0.46924(17) 0.42188(11) 0.0283(5) Uani 1 1 d . . .
P2 P 0.86052(10) -0.46544(19) 0.57313(11) 0.0335(6) Uani 1 1 d . . .
Si1 Si 0.46320(11) -0.50242(18) 0.38553(11) 0.0276(5) Uani 1 1 d . . .
C1 C 0.8975(4) -0.2667(6) 0.5400(5) 0.036(2) Uani 1 1 d . . .
C2 C 0.9314(5) -0.2048(7) 0.5631(5) 0.041(2) Uani 1 1 d . . .
C3 C 0.9738(5) -0.1354(8) 0.5910(5) 0.045(3) Uani 1 1 d . . .
C4 C 0.9836(5) -0.1235(9) 0.6515(5) 0.050(3) Uani 1 1 d . . .
H4A H 0.9621 -0.1612 0.6762 0.060 Uiso 1 1 calc R . .
C5 C 1.0251(6) -0.0558(11) 0.6764(7) 0.070(4) Uani 1 1 d . . .
H5A H 1.0292 -0.0454 0.7181 0.084 Uiso 1 1 calc R . .
C6 C 1.0595(6) -0.0048(11) 0.6448(7) 0.074(4) Uani 1 1 d . . .
H6A H 1.0880 0.0398 0.6637 0.088 Uiso 1 1 calc R . .
C7 C 1.0530(6) -0.0178(10) 0.5845(7) 0.071(4) Uani 1 1 d . . .
H7A H 1.0767 0.0184 0.5611 0.085 Uiso 1 1 calc R . .
C8 C 1.0110(5) -0.0849(9) 0.5574(6) 0.057(3) Uani 1 1 d . . .
H8A H 1.0078 -0.0960 0.5158 0.069 Uiso 1 1 calc R . .
C9 C 0.8302(4) -0.2677(6) 0.4271(4) 0.030(2) Uani 1 1 d . . .
C10 C 0.8090(4) -0.2091(7) 0.3921(4) 0.034(2) Uani 1 1 d . . .
C11 C 0.7802(5) -0.1427(9) 0.3486(5) 0.046(3) Uani 1 1 d . . .
C12 C 0.7837(7) -0.0455(12) 0.3564(9) 0.096(6) Uani 1 1 d . . .
H12A H 0.8058 -0.0202 0.3918 0.115 Uiso 1 1 calc R . .
C13 C 0.7558(9) 0.0153(14) 0.3137(12) 0.133(10) Uani 1 1 d . . .
H13A H 0.7582 0.0820 0.3203 0.160 Uiso 1 1 calc R . .
C14 C 0.7246(9) -0.0192(19) 0.2619(11) 0.124(10) Uani 1 1 d . . .
H14A H 0.7058 0.0229 0.2321 0.149 Uiso 1 1 calc R . .
C15 C 0.7212(9) -0.109(2) 0.2545(7) 0.111(8) Uani 1 1 d . . .
H15A H 0.6999 -0.1328 0.2183 0.133 Uiso 1 1 calc R . .
C16 C 0.7477(6) -0.1744(12) 0.2976(6) 0.072(4) Uani 1 1 d . . .
H16A H 0.7427 -0.2408 0.2908 0.086 Uiso 1 1 calc R . .
C17 C 0.8186(4) -0.4503(7) 0.3483(4) 0.033(2) Uani 1 1 d . . .
C18 C 0.8799(4) -0.4317(8) 0.3434(4) 0.041(2) Uani 1 1 d . . .
H18A H 0.9088 -0.4255 0.3782 0.049 Uiso 1 1 calc R . .
C19 C 0.8978(5) -0.4224(10) 0.2885(6) 0.056(3) Uani 1 1 d . . .
H19A H 0.9396 -0.4130 0.2857 0.068 Uiso 1 1 calc R . .
C20 C 0.8566(6) -0.4264(10) 0.2373(5) 0.061(3) Uani 1 1 d . . .
H20A H 0.8695 -0.4177 0.1996 0.074 Uiso 1 1 calc R . .
C21 C 0.7952(5) -0.4435(9) 0.2416(5) 0.048(3) Uani 1 1 d . . .
H21A H 0.7663 -0.4472 0.2066 0.057 Uiso 1 1 calc R . .
C22 C 0.7768(4) -0.4549(7) 0.2973(4) 0.035(2) Uani 1 1 d . . .
H22A H 0.7352 -0.4660 0.3001 0.042 Uiso 1 1 calc R . .
C23 C 0.8071(4) -0.5981(7) 0.4304(4) 0.033(2) Uani 1 1 d . . .
C24 C 0.7777(5) -0.6464(7) 0.4716(4) 0.038(2) Uani 1 1 d . B .
H24A H 0.7485 -0.6143 0.4910 0.046 Uiso 1 1 calc R . .
C25 C 0.7911(6) -0.7421(8) 0.4844(6) 0.054(3) Uani 1 1 d . . .
H25A H 0.7715 -0.7746 0.5129 0.064 Uiso 1 1 calc R A 1
C26 C 0.8330(6) -0.7894(9) 0.4557(6) 0.061(3) Uani 1 1 d . B 1
H26A H 0.8419 -0.8544 0.4642 0.073 Uiso 1 1 calc R B 1
C27 C 0.8615(6) -0.7416(10) 0.4149(6) 0.062(4) Uani 1 1 d . . .
H27A H 0.8903 -0.7743 0.3953 0.074 Uiso 1 1 calc R B 1
C28 C 0.8492(5) -0.6474(8) 0.4019(5) 0.049(3) Uani 1 1 d . B .
H28A H 0.8694 -0.6157 0.3734 0.059 Uiso 1 1 calc R . .
C29 C 0.7150(4) -0.4527(6) 0.4123(4) 0.0261(18) Uani 1 1 d . . .
C30 C 0.6924(4) -0.3664(7) 0.4321(4) 0.0295(19) Uani 1 1 d . . .
H30A H 0.7196 -0.3189 0.4495 0.035 Uiso 1 1 calc R . .
C31 C 0.6302(4) -0.3511(7) 0.4259(4) 0.032(2) Uani 1 1 d . . .
H31A H 0.6157 -0.2933 0.4404 0.039 Uiso 1 1 calc R . .
C32 C 0.5881(4) -0.4175(7) 0.3993(4) 0.0281(19) Uani 1 1 d . . .
C33 C 0.6118(4) -0.5027(7) 0.3803(4) 0.032(2) Uani 1 1 d . . .
H33A H 0.5846 -0.5500 0.3626 0.038 Uiso 1 1 calc R . .
C34 C 0.6737(4) -0.5203(7) 0.3865(4) 0.033(2) Uani 1 1 d . . .
H34A H 0.6880 -0.5789 0.3729 0.039 Uiso 1 1 calc R . .
C35 C 0.5213(4) -0.4041(7) 0.3942(4) 0.0267(18) Uani 1 1 d . . .
C36 C 0.4910(4) -0.3216(7) 0.3989(5) 0.035(2) Uani 1 1 d . C .
C37 C 0.4247(4) -0.3306(7) 0.4016(5) 0.041(3) Uani 1 1 d . . .
C38 C 0.4004(4) -0.4181(7) 0.3978(4) 0.032(2) Uani 1 1 d . C .
C39 C 0.4508(5) -0.5539(9) 0.3095(5) 0.049(3) Uani 1 1 d . . .
H39A H 0.4846 -0.5965 0.3044 0.074 Uiso 1 1 calc R . .
H39B H 0.4487 -0.5025 0.2801 0.074 Uiso 1 1 calc R . .
H39C H 0.4127 -0.5898 0.3038 0.074 Uiso 1 1 calc R . .
C40 C 0.4804(4) -0.5989(7) 0.4418(5) 0.038(2) Uani 1 1 d . . .
H40A H 0.5137 -0.6382 0.4315 0.058 Uiso 1 1 calc R . .
H40B H 0.4443 -0.6385 0.4424 0.058 Uiso 1 1 calc R . .
H40C H 0.4923 -0.5706 0.4812 0.058 Uiso 1 1 calc R . .
C41 C 0.5198(4) -0.2239(8) 0.4029(6) 0.049(3) Uani 1 1 d . . .
C42 C 0.5465(6) -0.1892(9) 0.3544(6) 0.066(4) Uani 1 1 d . C .
H42A H 0.5447 -0.2252 0.3188 0.079 Uiso 1 1 calc R . .
C43 C 0.5754(8) -0.1018(11) 0.3598(8) 0.099(6) Uani 1 1 d . . .
H43A H 0.5940 -0.0779 0.3278 0.118 Uiso 1 1 calc R C .
C44 C 0.5775(5) -0.0484(9) 0.4115(8) 0.076(4) Uani 1 1 d . C .
H44A H 0.5974 0.0115 0.4149 0.092 Uiso 1 1 calc R . .
C45 C 0.5497(5) -0.0842(9) 0.4586(8) 0.076(4) Uani 1 1 d . . .
H45A H 0.5506 -0.0476 0.4938 0.092 Uiso 1 1 calc R C .
C46 C 0.5215(5) -0.1709(8) 0.4546(7) 0.057(4) Uani 1 1 d . C .
H46A H 0.5033 -0.1946 0.4870 0.069 Uiso 1 1 calc R . .
C47 C 0.3915(5) -0.2357(6) 0.3994(5) 0.017(2) Uani 0.50 1 d PG C 1
C48 C 0.3862(5) -0.1737(7) 0.3514(4) 0.017(2) Uani 0.50 1 d PG C 1
H48A H 0.4023 -0.1908 0.3163 0.021 Uiso 1 1 calc R C 1
C49 C 0.3574(5) -0.0865(6) 0.3546(5) 0.028(4) Uani 0.50 1 d PG C 1
H49A H 0.3537 -0.0441 0.3217 0.033 Uiso 1 1 calc R C 1
C50 C 0.3339(6) -0.0614(6) 0.4058(6) 0.039(6) Uani 0.50 1 d PG C 1
H50A H 0.3142 -0.0018 0.4080 0.047 Uiso 1 1 calc R C 1
C51 C 0.3392(6) -0.1234(8) 0.4538(5) 0.033(6) Uani 0.50 1 d PG C 1
H51A H 0.3231 -0.1062 0.4889 0.040 Uiso 1 1 calc R C 1
C52 C 0.3680(6) -0.2106(8) 0.4507(4) 0.019(3) Uani 0.50 1 d PG C 1
H52A H 0.3716 -0.2530 0.4835 0.022 Uiso 1 1 calc R C 1
C53 C 0.3359(4) -0.4452(7) 0.4000(4) 0.029(2) Uani 1 1 d . . .
C54 C 0.2869(4) -0.3854(7) 0.3795(4) 0.032(2) Uani 1 1 d . C .
H54A H 0.2946 -0.3269 0.3611 0.038 Uiso 1 1 calc R . .
C55 C 0.2270(4) -0.4097(7) 0.3855(4) 0.034(2) Uani 1 1 d . . .
H55A H 0.1947 -0.3674 0.3719 0.041 Uiso 1 1 calc R C .
C56 C 0.2149(4) -0.4963(7) 0.4116(4) 0.032(2) Uani 1 1 d . . .
C57 C 0.2626(4) -0.5582(7) 0.4288(4) 0.033(2) Uani 1 1 d . . .
H57A H 0.2547 -0.6184 0.4451 0.040 Uiso 1 1 calc R C .
C58 C 0.3218(4) -0.5336(7) 0.4228(4) 0.033(2) Uani 1 1 d . C .
H58A H 0.3535 -0.5779 0.4343 0.040 Uiso 1 1 calc R . .
C59 C 0.9094(4) -0.5685(8) 0.5698(5) 0.044(3) Uani 1 1 d . . .
C60 C 0.9396(4) -0.5782(8) 0.5205(5) 0.043(3) Uani 1 1 d . . .
H60A H 0.9312 -0.5348 0.4884 0.052 Uiso 1 1 calc R . .
C61 C 0.9814(5) -0.6500(9) 0.5178(7) 0.062(4) Uani 1 1 d . . .
H61A H 1.0032 -0.6540 0.4848 0.075 Uiso 1 1 calc R . .
C62 C 0.9914(6) -0.7157(10) 0.5631(9) 0.080(5) Uani 1 1 d . . .
H62A H 1.0194 -0.7662 0.5607 0.096 Uiso 1 1 calc R . .
C63 C 0.9621(6) -0.7094(11) 0.6106(8) 0.081(5) Uani 1 1 d . . .
H63A H 0.9693 -0.7556 0.6413 0.097 Uiso 1 1 calc R . .
C64 C 0.9214(5) -0.6356(10) 0.6152(6) 0.065(4) Uani 1 1 d . . .
H64A H 0.9016 -0.6308 0.6495 0.078 Uiso 1 1 calc R . .
C65 C 0.8953(5) -0.4125(9) 0.6427(5) 0.048(3) Uani 1 1 d . . .
C66 C 0.9583(6) -0.4064(11) 0.6541(7) 0.076(4) Uani 1 1 d . . .
H66A H 0.9822 -0.4317 0.6264 0.091 Uiso 1 1 calc R . .
C67 C 0.9857(8) -0.3641(14) 0.7052(9) 0.105(7) Uani 1 1 d . . .
H67A H 1.0287 -0.3603 0.7129 0.126 Uiso 1 1 calc R . .
C68 C 0.9512(10) -0.3266(14) 0.7458(7) 0.108(8) Uani 1 1 d . . .
H68A H 0.9703 -0.2976 0.7814 0.129 Uiso 1 1 calc R . .
C69 C 0.8895(8) -0.3319(12) 0.7341(6) 0.078(5) Uani 1 1 d . . .
H69A H 0.8659 -0.3061 0.7619 0.094 Uiso 1 1 calc R . .
C70 C 0.8606(6) -0.3738(9) 0.6828(5) 0.057(3) Uani 1 1 d . . .
H70A H 0.8176 -0.3762 0.6751 0.069 Uiso 1 1 calc R . .
C1S C 0.7785(5) -1.1263(7) 0.5343(4) 0.060(3) Uani 1 1 d D D 1
H1S H 0.8056 -1.1676 0.5137 0.072 Uiso 1 1 calc R D 1
Cl1 Cl 0.70815(17) -1.1157(3) 0.48850(18) 0.0906(15) Uani 1 1 d D D 1
Cl2 Cl 0.81440(18) -1.0159(3) 0.5496(2) 0.0840(12) Uani 1 1 d D D 1
Cl3 Cl 0.7681(2) -1.1812(3) 0.60139(18) 0.0862(12) Uani 1 1 d D D 1
C2S C 0.1834(5) -0.1883(10) 0.2569(5) 0.093(5) Uani 1 1 d D E 1
H2S H 0.1667 -0.1310 0.2342 0.111 Uiso 1 1 calc R E 1
Cl4 Cl 0.13434(19) -0.2806(4) 0.2408(2) 0.1028(16) Uani 1 1 d D E 1
Cl5 Cl 0.1879(3) -0.1652(3) 0.3320(2) 0.1151(19) Uani 1 1 d D E 1
Cl6 Cl 0.2556(2) -0.2146(3) 0.2372(3) 0.1025(15) Uani 1 1 d D E 1
C3S C 0.5458(7) -0.3948(19) 0.1631(8) 0.094(13) Uani 0.50 1 d PD . .
H3S H 0.5382 -0.4599 0.1460 0.112 Uiso 0.50 1 calc PR F 1
Cl7 Cl 0.6105(5) -0.3300(5) 0.1349(3) 0.093(3) Uani 0.50 1 d PD G 1
Cl8 Cl 0.5795(6) -0.3946(10) 0.2450(3) 0.155(6) Uani 0.50 1 d PD G 1
Cl9 Cl 0.4771(5) -0.3170(7) 0.1537(8) 0.159(6) Uani 0.50 1 d PD G 1
O1 O 0.6172(11) -0.5135(16) 0.2131(8) 0.092(7) Uani 0.50 1 d PU H 2
O2 O 0.1045(6) -0.1046(9) 0.3405(7) 0.087(5) Uani 0.75 1 d PU I 2
O3 O 0.3396(13) -0.2939(13) 0.1211(10) 0.107(6) Uani 0.50 1 d PU J 2
C47' C 0.3897(7) -0.2607(12) 0.4393(9) 0.060(7) Uani 0.50 1 d PG C 2
C48' C 0.3772(8) -0.1727(15) 0.4125(9) 0.096(13) Uani 0.50 1 d PG C 2
H48' H 0.3876 -0.1607 0.3741 0.116 Uiso 0.50 1 calc PR C 2
C49' C 0.3493(9) -0.1021(12) 0.4418(12) 0.075(14) Uani 0.50 1 d PG C 2
H49' H 0.3408 -0.0419 0.4235 0.090 Uiso 0.50 1 calc PR C 2
C50' C 0.3341(8) -0.1197(14) 0.4980(12) 0.13(2) Uani 0.50 1 d PG C 2
H50' H 0.3150 -0.0715 0.5181 0.151 Uiso 0.50 1 calc PR C 2
C51' C 0.3466(8) -0.2077(16) 0.5248(9) 0.088(10) Uani 0.50 1 d PG C 2
H51' H 0.3362 -0.2197 0.5632 0.105 Uiso 0.50 1 calc PR C 2
C52' C 0.3745(8) -0.2782(11) 0.4954(9) 0.084(10) Uani 0.50 1 d PG C 2
H52' H 0.3831 -0.3384 0.5137 0.101 Uiso 0.50 1 calc PR C 2
O4 O 0.3038(14) -0.2433(13) 0.2132(10) 0.107(6) Uani 0.50 1 d PU K 2
O5 O 0.2369(12) -0.1445(17) 0.3453(14) 0.125(8) Uani 0.50 1 d PU L 2
O6 O 0.4041(11) -0.2812(16) 0.2375(13) 0.125(8) Uani 0.50 1 d PU . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Pt1 C9 87.6(4) . .
C1 Pt1 P2 89.2(3) . .
C9 Pt1 P2 170.5(3) . .
C1 Pt1 P1 171.1(3) . .
C9 Pt1 P1 84.6(3) . .
P2 Pt1 P1 99.19(9) . .
C17 P1 C29 105.2(4) . .
C17 P1 C23 101.4(4) . .
C29 P1 C23 104.0(4) . .
C17 P1 Pt1 111.2(3) . .
C29 P1 Pt1 113.3(3) . .
C23 P1 Pt1 120.2(3) . .
C65 P2 C59 100.4(5) . .
C65 P2 C56 103.9(5) . 3_646
C59 P2 C56 110.0(5) . 3_646
C65 P2 Pt1 116.1(4) . .
C59 P2 Pt1 116.2(4) . .
C56 P2 Pt1 109.3(3) 3_646 .
C39 Si1 C40 110.1(5) . .
C39 Si1 C35 113.0(5) . .
C40 Si1 C35 113.1(4) . .
C39 Si1 C38 111.7(5) . .
C40 Si1 C38 116.0(4) . .
C35 Si1 C38 92.0(4) . .
C2 C1 Pt1 170.9(10) . .
C1 C2 C3 177.0(10) . .
C4 C3 C8 117.8(11) . .
C4 C3 C2 121.6(11) . .
C8 C3 C2 120.3(11) . .
C3 C4 C5 119.5(12) . .
C3 C4 H4A 120.2 . .
C5 C4 H4A 120.2 . .
C6 C5 C4 123.2(14) . .
C6 C5 H5A 118.4 . .
C4 C5 H5A 118.4 . .
C5 C6 C7 118.9(13) . .
C5 C6 H6A 120.6 . .
C7 C6 H6A 120.6 . .
C6 C7 C8 119.8(14) . .
C6 C7 H7A 120.1 . .
C8 C7 H7A 120.1 . .
C3 C8 C7 120.5(13) . .
C3 C8 H8A 119.7 . .
C7 C8 H8A 119.7 . .
C10 C9 Pt1 168.5(8) . .
C9 C10 C11 176.1(11) . .
C16 C11 C12 116.7(13) . .
C16 C11 C10 120.4(12) . .
C12 C11 C10 122.8(12) . .
C13 C12 C11 121.0(18) . .
C13 C12 H12A 119.5 . .
C11 C12 H12A 119.5 . .
C14 C13 C12 121(2) . .
C14 C13 H13A 119.6 . .
C12 C13 H13A 119.6 . .
C15 C14 C13 118.6(16) . .
C15 C14 H14A 120.7 . .
C13 C14 H14A 120.7 . .
C14 C15 C16 123(2) . .
C14 C15 H15A 118.6 . .
C16 C15 H15A 118.6 . .
C11 C16 C15 120.0(18) . .
C11 C16 H16A 120.0 . .
C15 C16 H16A 120.0 . .
C22 C17 C18 119.1(9) . .
C22 C17 P1 122.0(7) . .
C18 C17 P1 118.9(7) . .
C19 C18 C17 120.1(9) . .
C19 C18 H18A 120.0 . .
C17 C18 H18A 120.0 . .
C18 C19 C20 121.4(10) . .
C18 C19 H19A 119.3 . .
C20 C19 H19A 119.3 . .
C19 C20 C21 119.1(11) . .
C19 C20 H20A 120.5 . .
C21 C20 H20A 120.5 . .
C22 C21 C20 120.0(10) . .
C22 C21 H21A 120.0 . .
C20 C21 H21A 120.0 . .
C17 C22 C21 120.4(9) . .
C17 C22 H22A 119.8 . .
C21 C22 H22A 119.8 . .
C24 C23 C28 118.8(9) . .
C24 C23 P1 119.4(7) . .
C28 C23 P1 121.3(8) . .
C23 C24 C25 120.1(10) . .
C23 C24 H24A 120.0 . .
C25 C24 H24A 119.9 . .
C26 C25 C24 120.1(12) . .
C26 C25 H25A 119.9 . .
C24 C25 H25A 119.9 . .
C27 C26 C25 119.6(11) . .
C27 C26 H26A 120.2 . .
C25 C26 H26A 120.2 . .
C26 C27 C28 121.2(11) . .
C26 C27 H27A 119.4 . .
C28 C27 H27A 119.4 . .
C27 C28 C23 120.2(12) . .
C27 C28 H28A 119.9 . .
C23 C28 H28A 119.9 . .
C34 C29 C30 118.5(8) . .
C34 C29 P1 123.6(7) . .
C30 C29 P1 117.9(7) . .
C31 C30 C29 119.8(8) . .
C31 C30 H30A 120.1 . .
C29 C30 H30A 120.1 . .
C30 C31 C32 122.5(9) . .
C30 C31 H31A 118.8 . .
C32 C31 H31A 118.8 . .
C31 C32 C33 116.4(8) . .
C31 C32 C35 123.4(8) . .
C33 C32 C35 120.1(8) . .
C34 C33 C32 122.3(9) . .
C34 C33 H33A 118.8 . .
C32 C33 H33A 118.8 . .
C33 C34 C29 120.5(9) . .
C33 C34 H34A 119.8 . .
C29 C34 H34A 119.8 . .
C36 C35 C32 127.3(9) . .
C36 C35 Si1 107.2(6) . .
C32 C35 Si1 125.4(7) . .
C35 C36 C37 116.0(8) . .
C35 C36 C41 124.9(8) . .
C37 C36 C41 119.2(8) . .
C38 C37 C36 117.8(8) . .
C38 C37 C47 127.8(8) . .
C36 C37 C47 113.8(8) . .
C38 C37 C47' 112.3(11) . .
C36 C37 C47' 122.5(10) . .
C47 C37 C47' 36.7(9) . .
C37 C38 C53 127.7(9) . .
C37 C38 Si1 106.7(6) . .
C53 C38 Si1 125.6(7) . .
Si1 C39 H39A 109.5 . .
Si1 C39 H39B 109.5 . .
H39A C39 H39B 109.5 . .
Si1 C39 H39C 109.5 . .
H39A C39 H39C 109.5 . .
H39B C39 H39C 109.5 . .
Si1 C40 H40A 109.5 . .
Si1 C40 H40B 109.5 . .
H40A C40 H40B 109.5 . .
Si1 C40 H40C 109.5 . .
H40A C40 H40C 109.5 . .
H40B C40 H40C 109.5 . .
C46 C41 C42 120.8(11) . .
C46 C41 C36 119.8(11) . .
C42 C41 C36 119.3(11) . .
C43 C42 C41 118.6(15) . .
C43 C42 H42A 120.7 . .
C41 C42 H42A 120.7 . .
C42 C43 C44 120.9(17) . .
C42 C43 H43A 119.5 . .
C44 C43 H43A 119.5 . .
C43 C44 C45 119.2(13) . .
C43 C44 H44A 120.4 . .
C45 C44 H44A 120.4 . .
C46 C45 C44 121.1(15) . .
C46 C45 H45A 119.5 . .
C44 C45 H45A 119.5 . .
C45 C46 C41 119.4(14) . .
C45 C46 H46A 120.3 . .
C41 C46 H46A 120.3 . .
C48 C47 C52 120.0 . .
C48 C47 C37 124.2(8) . .
C52 C47 C37 115.8(8) . .
C49 C48 C47 120.0 . .
C49 C48 H48A 120.0 . .
C47 C48 H48A 120.0 . .
C48 C49 C50 120.0 . .
C48 C49 H49A 120.0 . .
C50 C49 H49A 120.0 . .
C51 C50 C49 120.0 . .
C51 C50 H50A 120.0 . .
C49 C50 H50A 120.0 . .
C50 C51 C52 120.0 . .
C50 C51 H51A 120.0 . .
C52 C51 H51A 120.0 . .
C51 C52 C47 120.0 . .
C51 C52 H52A 120.0 . .
C47 C52 H52A 120.0 . .
C58 C53 C54 116.8(8) . .
C58 C53 C38 120.5(8) . .
C54 C53 C38 122.7(9) . .
C53 C54 C55 121.8(9) . .
C53 C54 H54A 119.1 . .
C55 C54 H54A 119.1 . .
C56 C55 C54 119.8(8) . .
C56 C55 H55A 120.1 . .
C54 C55 H55A 120.1 . .
C57 C56 C55 118.8(8) . .
C57 C56 P2 116.5(8) . 3_646
C55 C56 P2 124.8(7) . 3_646
C56 C57 C58 121.0(9) . .
C56 C57 H57A 119.5 . .
C58 C57 H57A 119.5 . .
C57 C58 C53 121.6(8) . .
C57 C58 H58A 119.2 . .
C53 C58 H58A 119.2 . .
C60 C59 C64 117.8(11) . .
C60 C59 P2 118.2(8) . .
C64 C59 P2 123.9(10) . .
C61 C60 C59 121.0(12) . .
C61 C60 H60A 119.5 . .
C59 C60 H60A 119.5 . .
C62 C61 C60 119.5(14) . .
C62 C61 H61A 120.2 . .
C60 C61 H61A 120.2 . .
C63 C62 C61 120.8(13) . .
C63 C62 H62A 119.6 . .
C61 C62 H62A 119.6 . .
C62 C63 C64 120.5(13) . .
C62 C63 H63A 119.7 . .
C64 C63 H63A 119.7 . .
C63 C64 C59 120.3(13) . .
C63 C64 H64A 119.9 . .
C59 C64 H64A 119.9 . .
C70 C65 C66 119.7(12) . .
C70 C65 P2 121.7(9) . .
C66 C65 P2 118.6(11) . .
C67 C66 C65 119.9(18) . .
C67 C66 H66A 120.1 . .
C65 C66 H66A 120.1 . .
C66 C67 C68 120.6(16) . .
C66 C67 H67A 119.7 . .
C68 C67 H67A 119.7 . .
C69 C68 C67 119.2(13) . .
C69 C68 H68A 120.4 . .
C67 C68 H68A 120.4 . .
C68 C69 C70 121.5(17) . .
C68 C69 H69A 119.3 . .
C70 C69 H69A 119.3 . .
C69 C70 C65 119.1(13) . .
C69 C70 H70A 120.4 . .
C65 C70 H70A 120.4 . .
Cl3 C1S Cl2 109.3(6) . .
Cl3 C1S Cl1 109.5(6) . .
Cl2 C1S Cl1 112.5(6) . .
Cl3 C1S H1S 108.5 . .
Cl2 C1S H1S 108.5 . .
Cl1 C1S H1S 108.5 . .
Cl4 C2S Cl5 107.5(8) . .
Cl4 C2S Cl6 111.4(7) . .
Cl5 C2S Cl6 111.4(7) . .
Cl4 C2S H2S 108.8 . .
Cl5 C2S H2S 108.8 . .
Cl6 C2S H2S 108.8 . .
Cl9 C3S Cl7 109.3(12) . .
Cl9 C3S Cl8 108.2(13) . .
Cl7 C3S Cl8 96.8(11) . .
Cl9 C3S H3S 113.7 . .
Cl7 C3S H3S 113.7 . .
Cl8 C3S H3S 113.7 . .
C48' C47' C52' 120.0 . .
C48' C47' C37 113.6(14) . .
C52' C47' C37 126.3(14) . .
C49' C48' C47' 120.0 . .
C49' C48' H48' 120.0 . .
C47' C48' H48' 120.0 . .
C48' C49' C50' 120.0 . .
C48' C49' H49' 120.0 . .
C50' C49' H49' 120.0 . .
C51' C50' C49' 120.0 . .
C51' C50' H50' 120.0 . .
C49' C50' H50' 120.0 . .
C52' C51' C50' 120.0 . .
C52' C51' H51' 120.0 . .
C50' C51' H51' 120.0 . .
C51' C52' C47' 120.0 . .
C51' C52' H52' 120.0 . .
C47' C52' H52' 120.0 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C1 2.006(10) .
Pt1 C9 2.013(9) .
Pt1 P2 2.311(3) .
Pt1 P1 2.318(2) .
P1 C17 1.825(10) .
P1 C29 1.826(8) .
P1 C23 1.832(10) .
P2 C65 1.818(11) .
P2 C59 1.820(11) .
P2 C56 1.844(9) 3_646
Si1 C39 1.859(11) .
Si1 C40 1.867(10) .
Si1 C35 1.883(9) .
Si1 C38 1.884(9) .
C1 C2 1.219(14) .
C2 C3 1.441(15) .
C3 C4 1.372(16) .
C3 C8 1.399(17) .
C4 C5 1.389(17) .
C4 H4A 0.9500 .
C5 C6 1.33(2) .
C5 H5A 0.9500 .
C6 C7 1.37(2) .
C6 H6A 0.9500 .
C7 C8 1.407(17) .
C7 H7A 0.9500 .
C8 H8A 0.9500 .
C9 C10 1.194(13) .
C10 C11 1.441(14) .
C11 C16 1.351(18) .
C11 C12 1.38(2) .
C12 C13 1.37(2) .
C12 H12A 0.9500 .
C13 C14 1.37(3) .
C13 H13A 0.9500 .
C14 C15 1.27(3) .
C14 H14A 0.9500 .
C15 C16 1.41(2) .
C15 H15A 0.9500 .
C16 H16A 0.9500 .
C17 C22 1.380(13) .
C17 C18 1.410(13) .
C18 C19 1.371(15) .
C18 H18A 0.9500 .
C19 C20 1.375(17) .
C19 H19A 0.9500 .
C20 C21 1.405(16) .
C20 H20A 0.9500 .
C21 C22 1.396(14) .
C21 H21A 0.9500 .
C22 H22A 0.9500 .
C23 C24 1.393(14) .
C23 C28 1.398(14) .
C24 C25 1.400(15) .
C24 H24A 0.9500 .
C25 C26 1.383(17) .
C25 H25A 0.9500 .
C26 C27 1.373(19) .
C26 H26A 0.9500 .
C27 C28 1.377(17) .
C27 H27A 0.9500 .
C28 H28A 0.9500 .
C29 C34 1.391(12) .
C29 C30 1.412(12) .
C30 C31 1.388(12) .
C30 H30A 0.9500 .
C31 C32 1.397(13) .
C31 H31A 0.9500 .
C32 C33 1.402(13) .
C32 C35 1.487(12) .
C33 C34 1.387(12) .
C33 H33A 0.9500 .
C34 H34A 0.9500 .
C35 C36 1.353(13) .
C36 C37 1.492(13) .
C36 C41 1.512(14) .
C37 C38 1.340(14) .
C37 C47 1.522(11) .
C37 C47' 1.580(18) .
C38 C53 1.495(12) .
C39 H39A 0.9800 .
C39 H39B 0.9800 .
C39 H39C 0.9800 .
C40 H40A 0.9800 .
C40 H40B 0.9800 .
C40 H40C 0.9800 .
C41 C46 1.389(18) .
C41 C42 1.414(18) .
C42 C43 1.384(19) .
C42 H42A 0.9500 .
C43 C44 1.39(2) .
C43 H43A 0.9500 .
C44 C45 1.41(2) .
C44 H44A 0.9500 .
C45 C46 1.368(16) .
C45 H45A 0.9500 .
C46 H46A 0.9500 .
C47 C48 1.3900 .
C47 C52 1.3900 .
C48 C49 1.3900 .
C48 H48A 0.9500 .
C49 C50 1.3900 .
C49 H49A 0.9500 .
C50 C51 1.3900 .
C50 H50A 0.9500 .
C51 C52 1.3900 .
C51 H51A 0.9500 .
C52 H52A 0.9500 .
C53 C58 1.399(13) .
C53 C54 1.401(12) .
C54 C55 1.403(12) .
C54 H54A 0.9500 .
C55 C56 1.397(14) .
C55 H55A 0.9500 .
C56 C57 1.384(13) .
C56 P2 1.844(9) 3_646
C57 C58 1.387(13) .
C57 H57A 0.9500 .
C58 H58A 0.9500 .
C59 C60 1.393(15) .
C59 C64 1.396(16) .
C60 C61 1.381(14) .
C60 H60A 0.9500 .
C61 C62 1.38(2) .
C61 H61A 0.9500 .
C62 C63 1.34(2) .
C62 H62A 0.9500 .
C63 C64 1.39(2) .
C63 H63A 0.9500 .
C64 H64A 0.9500 .
C65 C70 1.387(18) .
C65 C66 1.391(17) .
C66 C67 1.37(2) .
C66 H66A 0.9500 .
C67 C68 1.39(3) .
C67 H67A 0.9500 .
C68 C69 1.36(3) .
C68 H68A 0.9500 .
C69 C70 1.381(16) .
C69 H69A 0.9500 .
C70 H70A 0.9500 .
C1S Cl3 1.754(10) .
C1S Cl2 1.758(10) .
C1S Cl1 1.758(9) .
C1S H1S 1.0000 .
C2S Cl4 1.702(12) .
C2S Cl5 1.727(11) .
C2S Cl6 1.767(11) .
C2S H2S 1.0000 .
C3S Cl9 1.867(16) .
C3S Cl7 1.893(18) .
C3S Cl8 1.905(19) .
C3S H3S 1.0000 .
C47' C48' 1.3900 .
C47' C52' 1.3900 .
C48' C49' 1.3900 .
C48' H48' 0.9500 .
C49' C50' 1.3900 .
C49' H49' 0.9500 .
C50' C51' 1.3900 .
C50' H50' 0.9500 .
C51' C52' 1.3900 .
C51' H51' 0.9500 .
C52' H52' 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C1 Pt1 P1 C17 13.9(16) . .
C9 Pt1 P1 C17 43.3(4) . .
P2 Pt1 P1 C17 -145.4(3) . .
C1 Pt1 P1 C29 -104.3(16) . .
C9 Pt1 P1 C29 -74.8(4) . .
P2 Pt1 P1 C29 96.4(3) . .
C1 Pt1 P1 C23 132.0(16) . .
C9 Pt1 P1 C23 161.5(5) . .
P2 Pt1 P1 C23 -27.3(4) . .
C1 Pt1 P2 C65 7.4(5) . .
C9 Pt1 P2 C65 -62.6(16) . .
P1 Pt1 P2 C65 -175.7(5) . .
C1 Pt1 P2 C59 -110.3(5) . .
C9 Pt1 P2 C59 180(22) . .
P1 Pt1 P2 C59 66.6(4) . .
C1 Pt1 P2 C56 124.6(4) . 3_646
C9 Pt1 P2 C56 54.5(16) . 3_646
P1 Pt1 P2 C56 -58.6(3) . 3_646
C9 Pt1 C1 C2 -56(5) . .
P2 Pt1 C1 C2 132(5) . .
P1 Pt1 C1 C2 -27(6) . .
Pt1 C1 C2 C3 -76(26) . .
C1 C2 C3 C4 -84(24) . .
C1 C2 C3 C8 89(24) . .
C8 C3 C4 C5 6.4(17) . .
C2 C3 C4 C5 179.8(11) . .
C3 C4 C5 C6 -4(2) . .
C4 C5 C6 C7 1(2) . .
C5 C6 C7 C8 -1(2) . .
C4 C3 C8 C7 -5.8(17) . .
C2 C3 C8 C7 -179.3(11) . .
C6 C7 C8 C3 3(2) . .
C1 Pt1 C9 C10 -106(4) . .
P2 Pt1 C9 C10 -36(5) . .
P1 Pt1 C9 C10 78(4) . .
Pt1 C9 C10 C11 -53(19) . .
C9 C10 C11 C16 -31(17) . .
C9 C10 C11 C12 149(16) . .
C16 C11 C12 C13 -1(2) . .
C10 C11 C12 C13 179.8(16) . .
C11 C12 C13 C14 -1(3) . .
C12 C13 C14 C15 1(4) . .
C13 C14 C15 C16 1(3) . .
C12 C11 C16 C15 2(2) . .
C10 C11 C16 C15 -178.1(13) . .
C14 C15 C16 C11 -2(3) . .
C29 P1 C17 C22 -18.5(10) . .
C23 P1 C17 C22 89.6(9) . .
Pt1 P1 C17 C22 -141.5(8) . .
C29 P1 C17 C18 162.4(8) . .
C23 P1 C17 C18 -89.5(9) . .
Pt1 P1 C17 C18 39.4(9) . .
C22 C17 C18 C19 -2.8(16) . .
P1 C17 C18 C19 176.4(9) . .
C17 C18 C19 C20 3(2) . .
C18 C19 C20 C21 -2(2) . .
C19 C20 C21 C22 1(2) . .
C18 C17 C22 C21 1.5(16) . .
P1 C17 C22 C21 -177.7(8) . .
C20 C21 C22 C17 -0.5(18) . .
C17 P1 C23 C24 -159.6(8) . .
C29 P1 C23 C24 -50.6(9) . .
Pt1 P1 C23 C24 77.5(8) . .
C17 P1 C23 C28 28.3(9) . .
C29 P1 C23 C28 137.3(8) . .
Pt1 P1 C23 C28 -94.7(8) . .
C28 C23 C24 C25 0.9(15) . .
P1 C23 C24 C25 -171.4(8) . .
C23 C24 C25 C26 -0.9(17) . .
C24 C25 C26 C27 0.4(19) . .
C25 C26 C27 C28 0(2) . .
C26 C27 C28 C23 0(2) . .
C24 C23 C28 C27 -0.6(16) . .
P1 C23 C28 C27 171.6(10) . .
C17 P1 C29 C34 76.4(9) . .
C23 P1 C29 C34 -29.8(9) . .
Pt1 P1 C29 C34 -162.0(7) . .
C17 P1 C29 C30 -103.3(7) . .
C23 P1 C29 C30 150.5(7) . .
Pt1 P1 C29 C30 18.3(8) . .
C34 C29 C30 C31 0.6(13) . .
P1 C29 C30 C31 -179.6(7) . .
C29 C30 C31 C32 -1.6(14) . .
C30 C31 C32 C33 1.7(13) . .
C30 C31 C32 C35 177.8(8) . .
C31 C32 C33 C34 -1.0(13) . .
C35 C32 C33 C34 -177.2(8) . .
C32 C33 C34 C29 0.1(14) . .
C30 C29 C34 C33 0.1(14) . .
P1 C29 C34 C33 -179.6(7) . .
C31 C32 C35 C36 18.3(14) . .
C33 C32 C35 C36 -165.7(9) . .
C31 C32 C35 Si1 -156.5(7) . .
C33 C32 C35 Si1 19.5(12) . .
C39 Si1 C35 C36 108.9(7) . .
C40 Si1 C35 C36 -125.2(7) . .
C38 Si1 C35 C36 -5.7(7) . .
C39 Si1 C35 C32 -75.4(8) . .
C40 Si1 C35 C32 50.5(9) . .
C38 Si1 C35 C32 170.0(8) . .
C32 C35 C36 C37 -170.5(9) . .
Si1 C35 C36 C37 5.1(11) . .
C32 C35 C36 C41 8.3(16) . .
Si1 C35 C36 C41 -176.1(9) . .
C35 C36 C37 C38 -1.3(15) . .
C41 C36 C37 C38 179.8(10) . .
C35 C36 C37 C47 -173.0(9) . .
C41 C36 C37 C47 8.1(14) . .
C35 C36 C37 C47' 146.3(13) . .
C41 C36 C37 C47' -32.5(17) . .
C36 C37 C38 C53 179.3(9) . .
C47 C37 C38 C53 -10.3(18) . .
C47' C37 C38 C53 28.5(16) . .
C36 C37 C38 Si1 -3.2(12) . .
C47 C37 C38 Si1 167.1(10) . .
C47' C37 C38 Si1 -154.0(9) . .
C39 Si1 C38 C37 -110.7(8) . .
C40 Si1 C38 C37 122.0(8) . .
C35 Si1 C38 C37 5.0(8) . .
C39 Si1 C38 C53 66.8(9) . .
C40 Si1 C38 C53 -60.5(9) . .
C35 Si1 C38 C53 -177.5(8) . .
C35 C36 C41 C46 -114.1(12) . .
C37 C36 C41 C46 64.7(13) . .
C35 C36 C41 C42 63.6(14) . .
C37 C36 C41 C42 -117.6(12) . .
C46 C41 C42 C43 0.9(18) . .
C36 C41 C42 C43 -176.7(11) . .
C41 C42 C43 C44 -1(2) . .
C42 C43 C44 C45 0(2) . .
C43 C44 C45 C46 0.8(19) . .
C44 C45 C46 C41 -0.7(17) . .
C42 C41 C46 C45 -0.2(15) . .
C36 C41 C46 C45 177.4(9) . .
C38 C37 C47 C48 -107.2(13) . .
C36 C37 C47 C48 63.4(12) . .
C47' C37 C47 C48 176.4(17) . .
C38 C37 C47 C52 75.6(14) . .
C36 C37 C47 C52 -113.7(10) . .
C47' C37 C47 C52 -0.7(12) . .
C52 C47 C48 C49 0.0 . .
C37 C47 C48 C49 -177.0(10) . .
C47 C48 C49 C50 0.0 . .
C48 C49 C50 C51 0.0 . .
C49 C50 C51 C52 0.0 . .
C50 C51 C52 C47 0.0 . .
C48 C47 C52 C51 0.0 . .
C37 C47 C52 C51 177.3(9) . .
C37 C38 C53 C58 -150.0(11) . .
Si1 C38 C53 C58 33.0(12) . .
C37 C38 C53 C54 30.4(15) . .
Si1 C38 C53 C54 -146.6(8) . .
C58 C53 C54 C55 4.6(14) . .
C38 C53 C54 C55 -175.8(9) . .
C53 C54 C55 C56 -1.1(14) . .
C54 C55 C56 C57 -2.6(14) . .
C54 C55 C56 P2 175.9(7) . 3_646
C55 C56 C57 C58 2.7(14) . .
P2 C56 C57 C58 -176.0(7) 3_646 .
C56 C57 C58 C53 1.0(15) . .
C54 C53 C58 C57 -4.6(14) . .
C38 C53 C58 C57 175.8(9) . .
C65 P2 C59 C60 -122.1(9) . .
C56 P2 C59 C60 128.8(8) 3_646 .
Pt1 P2 C59 C60 4.0(10) . .
C65 P2 C59 C64 53.9(11) . .
C56 P2 C59 C64 -55.2(11) 3_646 .
Pt1 P2 C59 C64 180.0(9) . .
C64 C59 C60 C61 -2.1(17) . .
P2 C59 C60 C61 174.1(9) . .
C59 C60 C61 C62 3.1(18) . .
C60 C61 C62 C63 -2(2) . .
C61 C62 C63 C64 -1(2) . .
C62 C63 C64 C59 2(2) . .
C60 C59 C64 C63 -0.2(19) . .
P2 C59 C64 C63 -176.2(11) . .
C59 P2 C65 C70 -139.5(10) . .
C56 P2 C65 C70 -25.7(11) 3_646 .
Pt1 P2 C65 C70 94.3(10) . .
C59 P2 C65 C66 43.9(11) . .
C56 P2 C65 C66 157.7(10) 3_646 .
Pt1 P2 C65 C66 -82.2(10) . .
C70 C65 C66 C67 1(2) . .
P2 C65 C66 C67 177.8(12) . .
C65 C66 C67 C68 0(2) . .
C66 C67 C68 C69 0(3) . .
C67 C68 C69 C70 0(3) . .
C68 C69 C70 C65 1(2) . .
C66 C65 C70 C69 -1.5(19) . .
P2 C65 C70 C69 -178.0(10) . .
C38 C37 C47' C48' -133.5(10) . .
C36 C37 C47' C48' 77.3(14) . .
C47 C37 C47' C48' -9.6(11) . .
C38 C37 C47' C52' 50.0(15) . .
C36 C37 C47' C52' -99.2(15) . .
C47 C37 C47' C52' 173.9(19) . .
C52' C47' C48' C49' 0.0 . .
C37 C47' C48' C49' -176.8(12) . .
C47' C48' C49' C50' 0.0 . .
C48' C49' C50' C51' 0.0 . .
C49' C50' C51' C52' 0.0 . .
C50' C51' C52' C47' 0.0 . .
C48' C47' C52' C51' 0.0 . .
C37 C47' C52' C51' 176.3(14) . .
