#------------------------------------------------------------------------------
#$Date: 2016-03-25 16:26:56 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179970 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/64/7026431.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7026431
loop_
_publ_author_name
'Watanabe, Chieko'
'Inagawa, Yuichiro'
'Iwamoto, Takeaki'
'Kira, Mitsuo'
_publ_section_title
;
 Synthesis and structures of (dialkylsilylene)bis(phosphine)-nickel,
 palladium, and platinum complexes and
 (η(6)-arene)(dialkylsilylene)nickel complexes.
;
_journal_issue                   39
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9414
_journal_page_last               9420
_journal_paper_doi               10.1039/c0dt00415d
_journal_volume                  39
_journal_year                    2010
_chemical_formula_sum            'C22 H58 P2 Pd Si5'
_chemical_formula_weight         631.47
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                78.740(8)
_cell_angle_beta                 82.334(9)
_cell_angle_gamma                78.477(8)
_cell_formula_units_Z            2
_cell_length_a                   9.596(3)
_cell_length_b                   11.341(3)
_cell_length_c                   16.777(5)
_cell_measurement_reflns_used    5505
_cell_measurement_temperature    173
_cell_measurement_theta_max      27.8764
_cell_measurement_theta_min      3.1052
_cell_volume                     1746.1(9)
_computing_cell_refinement       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_collection       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_reduction        'CrystalClear (Rigaku Corp., 2000)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.994
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0321
_diffrn_reflns_av_sigmaI/netI    0.0342
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            25206
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         3.10
_exptl_absorpt_coefficient_mu    0.804
_exptl_absorpt_correction_T_max  0.9239
_exptl_absorpt_correction_T_min  0.7945
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Jacobson, 1998)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.201
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             672
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.556
_refine_diff_density_min         -0.285
_refine_diff_density_rms         0.064
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.992
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     289
_refine_ls_number_reflns         7987
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.992
_refine_ls_R_factor_all          0.0316
_refine_ls_R_factor_gt           0.0248
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0378P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0640
_refine_ls_wR_factor_ref         0.0664
_reflns_number_gt                6729
_reflns_number_total             7987
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0dt00415d.txt
_cod_data_source_block           (silylene)(Me3P)2Pd_cw07
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        1746.0(9)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7026431
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Si1 Si 0.28282(5) 0.33964(4) 0.76203(3) 0.01754(10) Uani 1 1 d .
C1 C 0.35890(19) 0.21778(15) 0.69453(10) 0.0201(3) Uani 1 1 d .
C2 C 0.3145(2) 0.09645(15) 0.74451(10) 0.0243(4) Uani 1 1 d .
H1 H 0.2188 0.0902 0.7317 0.029 Uiso 1 1 calc R
H2 H 0.3835 0.0253 0.7289 0.029 Uiso 1 1 calc R
C3 C 0.3116(2) 0.09513(15) 0.83676(10) 0.0231(4) Uani 1 1 d .
H3 H 0.4104 0.0746 0.8527 0.028 Uiso 1 1 calc R
H4 H 0.2581 0.0319 0.8679 0.028 Uiso 1 1 calc R
C4 C 0.23821(18) 0.22405(15) 0.85760(10) 0.0194(3) Uani 1 1 d .
Pd1 Pd 0.257091(14) 0.543690(11) 0.740403(8) 0.02076(5) Uani 1 1 d .
P1 P 0.06011(6) 0.68733(5) 0.69714(3) 0.03212(12) Uani 1 1 d .
P2 P 0.41451(5) 0.65878(4) 0.76717(3) 0.02741(11) Uani 1 1 d .
Si2 Si 0.26264(6) 0.26662(5) 0.59818(3) 0.02640(12) Uani 1 1 d .
C5 C 0.0633(2) 0.3032(2) 0.62218(13) 0.0413(5) Uani 1 1 d .
H5 H 0.0265 0.2274 0.6436 0.062 Uiso 1 1 calc R
H6 H 0.0191 0.3445 0.5723 0.062 Uiso 1 1 calc R
H7 H 0.0405 0.3569 0.6632 0.062 Uiso 1 1 calc R
C6 C 0.2897(3) 0.1378(2) 0.53860(13) 0.0439(6) Uani 1 1 d .
H8 H 0.2120 0.1511 0.5036 0.066 Uiso 1 1 calc R
H9 H 0.2897 0.0602 0.5765 0.066 Uiso 1 1 calc R
H10 H 0.3813 0.1350 0.5047 0.066 Uiso 1 1 calc R
C7 C 0.3189(3) 0.40678(19) 0.53295(12) 0.0396(5) Uani 1 1 d .
H11 H 0.2652 0.4309 0.4848 0.059 Uiso 1 1 calc R
H12 H 0.4214 0.3892 0.5154 0.059 Uiso 1 1 calc R
H13 H 0.2996 0.4735 0.5645 0.059 Uiso 1 1 calc R
Si3 Si 0.56073(6) 0.19999(5) 0.66804(3) 0.02834(12) Uani 1 1 d .
C8 C 0.6262(3) 0.1506(3) 0.56715(16) 0.0650(8) Uani 1 1 d .
H14 H 0.7304 0.1434 0.5581 0.097 Uiso 1 1 calc R
H15 H 0.5823 0.2113 0.5234 0.097 Uiso 1 1 calc R
H16 H 0.6002 0.0713 0.5673 0.097 Uiso 1 1 calc R
C9 C 0.6309(2) 0.3440(2) 0.66571(16) 0.0464(6) Uani 1 1 d .
H17 H 0.5795 0.4110 0.6283 0.070 Uiso 1 1 calc R
H18 H 0.7331 0.3317 0.6469 0.070 Uiso 1 1 calc R
H19 H 0.6167 0.3645 0.7207 0.070 Uiso 1 1 calc R
C10 C 0.6582(2) 0.0732(2) 0.74182(15) 0.0434(5) Uani 1 1 d .
H20 H 0.7608 0.0610 0.7240 0.065 Uiso 1 1 calc R
H21 H 0.6225 -0.0025 0.7434 0.065 Uiso 1 1 calc R
H22 H 0.6422 0.0950 0.7964 0.065 Uiso 1 1 calc R
Si4 Si 0.32479(6) 0.25863(5) 0.94380(3) 0.02517(11) Uani 1 1 d .
C11 C 0.5189(2) 0.2669(2) 0.91363(13) 0.0364(5) Uani 1 1 d .
H23 H 0.5559 0.2996 0.9549 0.055 Uiso 1 1 calc R
H24 H 0.5291 0.3205 0.8606 0.055 Uiso 1 1 calc R
H25 H 0.5729 0.1848 0.9097 0.055 Uiso 1 1 calc R
C12 C 0.3293(2) 0.1327(2) 1.03566(12) 0.0408(5) Uani 1 1 d .
H26 H 0.2379 0.1436 1.0696 0.061 Uiso 1 1 calc R
H27 H 0.4067 0.1355 1.0675 0.061 Uiso 1 1 calc R
H28 H 0.3457 0.0535 1.0176 0.061 Uiso 1 1 calc R
C13 C 0.2340(2) 0.40832(19) 0.97419(13) 0.0398(5) Uani 1 1 d .
H29 H 0.2299 0.4727 0.9257 0.060 Uiso 1 1 calc R
H30 H 0.2880 0.4286 1.0138 0.060 Uiso 1 1 calc R
H31 H 0.1368 0.4018 0.9989 0.060 Uiso 1 1 calc R
Si5 Si 0.03754(6) 0.23162(5) 0.88510(3) 0.02726(12) Uani 1 1 d .
C14 C -0.0351(2) 0.1271(2) 0.83349(14) 0.0460(6) Uani 1 1 d .
H32 H -0.0341 0.1594 0.7748 0.069 Uiso 1 1 calc R
H33 H -0.1334 0.1219 0.8567 0.069 Uiso 1 1 calc R
H34 H 0.0243 0.0455 0.8420 0.069 Uiso 1 1 calc R
C15 C -0.0683(2) 0.3894(2) 0.85919(15) 0.0457(6) Uani 1 1 d .
H35 H -0.0261 0.4471 0.8808 0.069 Uiso 1 1 calc R
H36 H -0.1672 0.3907 0.8834 0.069 Uiso 1 1 calc R
H37 H -0.0669 0.4130 0.7997 0.069 Uiso 1 1 calc R
C16 C -0.0141(2) 0.1789(2) 0.99662(13) 0.0449(6) Uani 1 1 d .
H38 H -0.1163 0.1751 1.0052 0.067 Uiso 1 1 calc R
H39 H 0.0057 0.2366 1.0284 0.067 Uiso 1 1 calc R
H40 H 0.0413 0.0977 1.0144 0.067 Uiso 1 1 calc R
C17 C -0.0668(3) 0.6435(3) 0.64088(17) 0.0596(7) Uani 1 1 d .
H41 H -0.1456 0.7122 0.6296 0.089 Uiso 1 1 calc R
H42 H -0.1046 0.5732 0.6737 0.089 Uiso 1 1 calc R
H43 H -0.0181 0.6216 0.5892 0.089 Uiso 1 1 calc R
C18 C 0.0851(3) 0.8347(2) 0.63484(18) 0.0699(9) Uani 1 1 d .
H44 H 0.1392 0.8755 0.6633 0.105 Uiso 1 1 calc R
H45 H -0.0084 0.8861 0.6257 0.105 Uiso 1 1 calc R
H46 H 0.1378 0.8215 0.5822 0.105 Uiso 1 1 calc R
C19 C -0.0617(2) 0.7413(2) 0.78095(15) 0.0483(6) Uani 1 1 d .
H47 H -0.1433 0.7994 0.7589 0.072 Uiso 1 1 calc R
H48 H -0.0115 0.7818 0.8119 0.072 Uiso 1 1 calc R
H49 H -0.0957 0.6718 0.8171 0.072 Uiso 1 1 calc R
C20 C 0.5753(3) 0.5880(2) 0.81806(18) 0.0532(7) Uani 1 1 d .
H50 H 0.6257 0.6517 0.8252 0.080 Uiso 1 1 calc R
H51 H 0.6379 0.5331 0.7847 0.080 Uiso 1 1 calc R
H52 H 0.5483 0.5414 0.8716 0.080 Uiso 1 1 calc R
C21 C 0.3370(3) 0.7696(2) 0.83373(15) 0.0441(6) Uani 1 1 d .
H53 H 0.2568 0.8264 0.8091 0.066 Uiso 1 1 calc R
H54 H 0.4097 0.8153 0.8408 0.066 Uiso 1 1 calc R
H55 H 0.3027 0.7267 0.8870 0.066 Uiso 1 1 calc R
C22 C 0.4922(3) 0.7556(2) 0.67892(15) 0.0467(6) Uani 1 1 d .
H56 H 0.5492 0.7043 0.6413 0.070 Uiso 1 1 calc R
H57 H 0.5535 0.8024 0.6974 0.070 Uiso 1 1 calc R
H58 H 0.4155 0.8121 0.6508 0.070 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C4 Si1 C1 94.83(8)
C4 Si1 Pd1 131.60(5)
C1 Si1 Pd1 133.56(6)
C2 C1 Si2 109.63(12)
C2 C1 Si3 111.69(12)
Si2 C1 Si3 110.63(8)
C2 C1 Si1 104.98(11)
Si2 C1 Si1 106.20(9)
Si3 C1 Si1 113.42(9)
C3 C2 C1 110.05(14)
C3 C2 H1 109.7
C1 C2 H1 109.7
C3 C2 H2 109.7
C1 C2 H2 109.7
H1 C2 H2 108.2
C2 C3 C4 109.92(14)
C2 C3 H3 109.7
C4 C3 H3 109.7
C2 C3 H4 109.7
C4 C3 H4 109.7
H3 C3 H4 108.2
C3 C4 Si4 110.02(12)
C3 C4 Si5 110.93(12)
Si4 C4 Si5 110.96(8)
C3 C4 Si1 105.28(11)
Si4 C4 Si1 106.64(9)
Si5 C4 Si1 112.77(9)
Si1 Pd1 P2 127.19(2)
Si1 Pd1 P1 128.07(2)
P2 Pd1 P1 104.55(3)
C19 P1 C17 99.84(13)
C19 P1 C18 99.38(13)
C17 P1 C18 100.89(14)
C19 P1 Pd1 113.49(8)
C17 P1 Pd1 119.42(9)
C18 P1 Pd1 120.20(9)
C21 P2 C20 98.90(12)
C21 P2 C22 101.56(11)
C20 P2 C22 99.99(12)
C21 P2 Pd1 114.82(8)
C20 P2 Pd1 121.85(8)
C22 P2 Pd1 116.36(8)
C7 Si2 C5 107.01(11)
C7 Si2 C6 111.08(10)
C5 Si2 C6 103.91(11)
C7 Si2 C1 111.62(9)
C5 Si2 C1 111.88(9)
C6 Si2 C1 111.02(9)
Si2 C5 H5 109.5
Si2 C5 H6 109.5
H5 C5 H6 109.5
Si2 C5 H7 109.5
H5 C5 H7 109.5
H6 C5 H7 109.5
Si2 C6 H8 109.5
Si2 C6 H9 109.5
H8 C6 H9 109.5
Si2 C6 H10 109.5
H8 C6 H10 109.5
H9 C6 H10 109.5
Si2 C7 H11 109.5
Si2 C7 H12 109.5
H11 C7 H12 109.5
Si2 C7 H13 109.5
H11 C7 H13 109.5
H12 C7 H13 109.5
C8 Si3 C9 106.26(13)
C8 Si3 C10 102.31(12)
C9 Si3 C10 108.83(12)
C8 Si3 C1 114.46(11)
C9 Si3 C1 113.11(9)
C10 Si3 C1 111.17(9)
Si3 C8 H14 109.5
Si3 C8 H15 109.5
H14 C8 H15 109.5
Si3 C8 H16 109.5
H14 C8 H16 109.5
H15 C8 H16 109.5
Si3 C9 H17 109.5
Si3 C9 H18 109.5
H17 C9 H18 109.5
Si3 C9 H19 109.5
H17 C9 H19 109.5
H18 C9 H19 109.5
Si3 C10 H20 109.5
Si3 C10 H21 109.5
H20 C10 H21 109.5
Si3 C10 H22 109.5
H20 C10 H22 109.5
H21 C10 H22 109.5
C13 Si4 C11 107.81(10)
C13 Si4 C12 110.17(10)
C11 Si4 C12 103.28(10)
C13 Si4 C4 111.36(9)
C11 Si4 C4 111.43(9)
C12 Si4 C4 112.42(9)
Si4 C11 H23 109.5
Si4 C11 H24 109.5
H23 C11 H24 109.5
Si4 C11 H25 109.5
H23 C11 H25 109.5
H24 C11 H25 109.5
Si4 C12 H26 109.5
Si4 C12 H27 109.5
H26 C12 H27 109.5
Si4 C12 H28 109.5
H26 C12 H28 109.5
H27 C12 H28 109.5
Si4 C13 H29 109.5
Si4 C13 H30 109.5
H29 C13 H30 109.5
Si4 C13 H31 109.5
H29 C13 H31 109.5
H30 C13 H31 109.5
C15 Si5 C14 108.02(12)
C15 Si5 C16 105.73(11)
C14 Si5 C16 103.31(11)
C15 Si5 C4 113.16(9)
C14 Si5 C4 112.01(9)
C16 Si5 C4 113.90(9)
Si5 C14 H32 109.5
Si5 C14 H33 109.5
H32 C14 H33 109.5
Si5 C14 H34 109.5
H32 C14 H34 109.5
H33 C14 H34 109.5
Si5 C15 H35 109.5
Si5 C15 H36 109.5
H35 C15 H36 109.5
Si5 C15 H37 109.5
H35 C15 H37 109.5
H36 C15 H37 109.5
Si5 C16 H38 109.5
Si5 C16 H39 109.5
H38 C16 H39 109.5
Si5 C16 H40 109.5
H38 C16 H40 109.5
H39 C16 H40 109.5
P1 C17 H41 109.5
P1 C17 H42 109.5
H41 C17 H42 109.5
P1 C17 H43 109.5
H41 C17 H43 109.5
H42 C17 H43 109.5
P1 C18 H44 109.5
P1 C18 H45 109.5
H44 C18 H45 109.5
P1 C18 H46 109.5
H44 C18 H46 109.5
H45 C18 H46 109.5
P1 C19 H47 109.5
P1 C19 H48 109.5
H47 C19 H48 109.5
P1 C19 H49 109.5
H47 C19 H49 109.5
H48 C19 H49 109.5
P2 C20 H50 109.5
P2 C20 H51 109.5
H50 C20 H51 109.5
P2 C20 H52 109.5
H50 C20 H52 109.5
H51 C20 H52 109.5
P2 C21 H53 109.5
P2 C21 H54 109.5
H53 C21 H54 109.5
P2 C21 H55 109.5
H53 C21 H55 109.5
H54 C21 H55 109.5
P2 C22 H56 109.5
P2 C22 H57 109.5
H56 C22 H57 109.5
P2 C22 H58 109.5
H56 C22 H58 109.5
H57 C22 H58 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Si1 C4 1.9216(17)
Si1 C1 1.9268(17)
Si1 Pd1 2.2395(8)
C1 C2 1.570(2)
C1 Si2 1.9019(18)
C1 Si3 1.9075(19)
C2 C3 1.541(2)
C2 H1 0.9900
C2 H2 0.9900
C3 C4 1.574(2)
C3 H3 0.9900
C3 H4 0.9900
C4 Si4 1.8994(18)
C4 Si5 1.9080(19)
Pd1 P2 2.3205(7)
Pd1 P1 2.3297(7)
P1 C19 1.825(2)
P1 C17 1.831(3)
P1 C18 1.832(2)
P2 C21 1.826(2)
P2 C20 1.828(2)
P2 C22 1.831(2)
Si2 C7 1.877(2)
Si2 C5 1.880(2)
Si2 C6 1.885(2)
C5 H5 0.9800
C5 H6 0.9800
C5 H7 0.9800
C6 H8 0.9800
C6 H9 0.9800
C6 H10 0.9800
C7 H11 0.9800
C7 H12 0.9800
C7 H13 0.9800
Si3 C8 1.876(2)
Si3 C9 1.879(2)
Si3 C10 1.885(2)
C8 H14 0.9800
C8 H15 0.9800
C8 H16 0.9800
C9 H17 0.9800
C9 H18 0.9800
C9 H19 0.9800
C10 H20 0.9800
C10 H21 0.9800
C10 H22 0.9800
Si4 C13 1.879(2)
Si4 C11 1.880(2)
Si4 C12 1.884(2)
C11 H23 0.9800
C11 H24 0.9800
C11 H25 0.9800
C12 H26 0.9800
C12 H27 0.9800
C12 H28 0.9800
C13 H29 0.9800
C13 H30 0.9800
C13 H31 0.9800
Si5 C15 1.874(2)
Si5 C14 1.880(2)
Si5 C16 1.881(2)
C14 H32 0.9800
C14 H33 0.9800
C14 H34 0.9800
C15 H35 0.9800
C15 H36 0.9800
C15 H37 0.9800
C16 H38 0.9800
C16 H39 0.9800
C16 H40 0.9800
C17 H41 0.9800
C17 H42 0.9800
C17 H43 0.9800
C18 H44 0.9800
C18 H45 0.9800
C18 H46 0.9800
C19 H47 0.9800
C19 H48 0.9800
C19 H49 0.9800
C20 H50 0.9800
C20 H51 0.9800
C20 H52 0.9800
C21 H53 0.9800
C21 H54 0.9800
C21 H55 0.9800
C22 H56 0.9800
C22 H57 0.9800
C22 H58 0.9800
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C4 Si1 C1 C2 12.05(12)
Pd1 Si1 C1 C2 -168.97(8)
C4 Si1 C1 Si2 128.15(9)
Pd1 Si1 C1 Si2 -52.87(11)
C4 Si1 C1 Si3 -110.15(9)
Pd1 Si1 C1 Si3 68.83(11)
Si2 C1 C2 C3 -146.36(13)
Si3 C1 C2 C3 90.65(15)
Si1 C1 C2 C3 -32.66(17)
C1 C2 C3 C4 43.2(2)
C2 C3 C4 Si4 -145.97(13)
C2 C3 C4 Si5 90.87(15)
C2 C3 C4 Si1 -31.41(17)
C1 Si1 C4 C3 10.45(12)
Pd1 Si1 C4 C3 -168.57(8)
C1 Si1 C4 Si4 127.33(9)
Pd1 Si1 C4 Si4 -51.68(11)
C1 Si1 C4 Si5 -110.64(9)
Pd1 Si1 C4 Si5 70.35(11)
C4 Si1 Pd1 P2 84.91(8)
C1 Si1 Pd1 P2 -93.73(8)
C4 Si1 Pd1 P1 -89.31(8)
C1 Si1 Pd1 P1 92.05(8)
Si1 Pd1 P1 C19 94.33(9)
P2 Pd1 P1 C19 -80.91(9)
Si1 Pd1 P1 C17 -22.98(12)
P2 Pd1 P1 C17 161.78(11)
Si1 Pd1 P1 C18 -148.37(13)
P2 Pd1 P1 C18 36.39(13)
Si1 Pd1 P2 C21 -124.12(9)
P1 Pd1 P2 C21 51.17(9)
Si1 Pd1 P2 C20 -4.91(12)
P1 Pd1 P2 C20 170.39(11)
Si1 Pd1 P2 C22 117.48(9)
P1 Pd1 P2 C22 -67.22(9)
C2 C1 Si2 C7 -176.94(12)
Si3 C1 Si2 C7 -53.33(12)
Si1 C1 Si2 C7 70.15(11)
C2 C1 Si2 C5 63.18(14)
Si3 C1 Si2 C5 -173.21(10)
Si1 C1 Si2 C5 -49.74(12)
C2 C1 Si2 C6 -52.41(14)
Si3 C1 Si2 C6 71.20(12)
Si1 C1 Si2 C6 -165.33(10)
C2 C1 Si3 C8 91.40(16)
Si2 C1 Si3 C8 -31.02(15)
Si1 C1 Si3 C8 -150.22(13)
C2 C1 Si3 C9 -146.70(14)
Si2 C1 Si3 C9 90.88(12)
Si1 C1 Si3 C9 -28.32(14)
C2 C1 Si3 C10 -23.90(15)
Si2 C1 Si3 C10 -146.32(10)
Si1 C1 Si3 C10 94.48(12)
C3 C4 Si4 C13 -177.09(12)
Si5 C4 Si4 C13 -53.95(12)
Si1 C4 Si4 C13 69.22(11)
C3 C4 Si4 C11 62.49(14)
Si5 C4 Si4 C11 -174.36(9)
Si1 C4 Si4 C11 -51.20(11)
C3 C4 Si4 C12 -52.91(14)
Si5 C4 Si4 C12 70.24(11)
Si1 C4 Si4 C12 -166.59(9)
C3 C4 Si5 C15 -150.67(13)
Si4 C4 Si5 C15 86.71(12)
Si1 C4 Si5 C15 -32.86(13)
C3 C4 Si5 C14 -28.27(15)
Si4 C4 Si5 C14 -150.89(10)
Si1 C4 Si5 C14 89.54(12)
C3 C4 Si5 C16 88.52(14)
Si4 C4 Si5 C16 -34.10(13)
Si1 C4 Si5 C16 -153.67(10)
