#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/69/7026923.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7026923
loop_
_publ_author_name
'Andrews, Philip C.'
'Brown, David H.'
'Fraser, Benjamin H.'
'Gorham, Nicole T.'
'Junk, Peter C.'
'Massi, Massimiliano'
'St Pierre, Timothy G.'
'Skelton, Brian W.'
'Woodward, Robert C.'
_publ_section_title
;
 Multifunctional hybrid materials based on transparent poly(methyl
 methacrylate) reinforced by lanthanoid hydroxo clusters.
;
_journal_issue                   46
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11227
_journal_page_last               11234
_journal_paper_doi               10.1039/c0dt00947d
_journal_volume                  39
_journal_year                    2010
_chemical_formula_moiety         'C210 H195 Eu5 O45, 4(C7 H8)'
_chemical_formula_sum            'C238 H227 Eu5 O45'
_chemical_formula_weight         4567
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2010-06-03T12:08:18-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 95.338(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   35.8542(9)
_cell_length_b                   17.7867(4)
_cell_length_c                   32.6504(5)
_cell_measurement_reflns_used    41139
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      34.4527
_cell_measurement_theta_min      3.4535
_cell_volume                     20731.8(8)
_computing_cell_refinement
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.52 (release 06-11-2009 CrysAlis171 .NET)
(compiled Nov 6 2009,16:24:50)
;
_computing_data_collection
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.52 (release 06-11-2009 CrysAlis171 .NET)
(compiled Nov 6 2009,16:24:50)
;
_computing_data_reduction
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.52 (release 06-11-2009 CrysAlis171 .NET)
(compiled Nov 6 2009,16:24:50)
;
_computing_molecular_graphics    'OrtepII (Johnson, C. K. (1976)'
_computing_publication_material  'WinGX Farrugia, L. J. (1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 10.4738
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.954
_diffrn_measurement_device_type  'Oxford Diffraction Gemini, Ruby'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0196682157
_diffrn_orient_matrix_UB_12      0.0034762048
_diffrn_orient_matrix_UB_13      0.000366313
_diffrn_orient_matrix_UB_21      -0.0019213087
_diffrn_orient_matrix_UB_22      -0.0395130842
_diffrn_orient_matrix_UB_23      -0.0020355398
_diffrn_orient_matrix_UB_31      0.0020351749
_diffrn_orient_matrix_UB_32      -0.0037615639
_diffrn_orient_matrix_UB_33      0.0217326655
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0656
_diffrn_reflns_av_unetI/netI     0.0887
_diffrn_reflns_limit_h_max       56
_diffrn_reflns_limit_h_min       -56
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       51
_diffrn_reflns_limit_l_min       -51
_diffrn_reflns_number            192070
_diffrn_reflns_theta_full        33.75
_diffrn_reflns_theta_max         34.56
_diffrn_reflns_theta_min         3.46
_exptl_absorpt_coefficient_mu    1.569
_exptl_absorpt_correction_T_max  0.909
_exptl_absorpt_correction_T_min  0.49
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.52 (release 06-11-2009 CrysAlis171 .NET)
(compiled Nov 6 2009,16:24:50)
Analytical numeric absorption correction using a multifaceted crystal
model based on expressions derived by R.C. Clark & J.S.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.463
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rod
_exptl_crystal_F_000             9320
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.11
_refine_diff_density_max         2.989
_refine_diff_density_min         -2.485
_refine_diff_density_rms         0.126
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.897
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1561
_refine_ls_number_reflns         42124
_refine_ls_number_restraints     565
_refine_ls_restrained_S_all      0.907
_refine_ls_R_factor_all          0.0962
_refine_ls_R_factor_gt           0.044
_refine_ls_shift/su_max          0.019
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0559P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0972
_refine_ls_wR_factor_ref         0.1079
_reflns_number_gt                24086
_reflns_number_total             42124
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            c0dt00947d.txt
_cod_data_source_block           mxm14
_cod_original_sg_symbol_Hall     -C_2yc
_cod_database_code               7026923
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.011894(4) 0.945839(7) 0.330144(3) 0.01803(3) Uani 1 1 d . . .
Eu2 Eu 0.069088(3) 0.943575(7) 0.245114(4) 0.01867(3) Uani 1 1 d . . .
Eu3 Eu 0 1.112234(10) 0.25 0.01878(4) Uani 1 2 d S . .
O1 O 0 0.92109(14) 0.25 0.0184(5) Uani 1 2 d SD . .
H1O H 0 0.8757 0.25 0.022 Uiso 1 1 calc R . .
O2 O 0.04531(5) 1.03048(10) 0.29030(5) 0.0194(4) Uani 1 1 d . B .
H2O H 0.0653 1.0591 0.3071 0.023 Uiso 1 1 calc R . .
O3 O -0.03123(5) 1.03089(10) 0.29651(5) 0.0195(4) Uani 1 1 d . . .
H3O H -0.0458 1.0596 0.316 0.023 Uiso 1 1 calc R . .
C1 C 0.17163(8) 0.90667(19) 0.27523(9) 0.0346(7) Uani 1 1 d . . .
H1 H 0.198 0.8995 0.2796 0.041 Uiso 1 1 calc R . .
C10 C 0.15686(8) 0.97823(19) 0.28349(9) 0.0334(7) Uani 1 1 d D . .
O10 O 0.12197(5) 0.99411(12) 0.28043(6) 0.0314(5) Uani 1 1 d D . .
C11 C 0.18233(8) 1.04008(19) 0.29938(10) 0.0379(8) Uani 1 1 d D . .
C12 C 0.16834(10) 1.0966(2) 0.32288(14) 0.0679(13) Uani 1 1 d D . .
H12 H 0.1428 1.0953 0.3285 0.081 Uiso 1 1 calc R . .
C13 C 0.19111(11) 1.1548(3) 0.33831(15) 0.0803(15) Uani 1 1 d D . .
H13 H 0.1814 1.1918 0.3554 0.096 Uiso 1 1 calc R . .
C14 C 0.22789(10) 1.1592(2) 0.32893(11) 0.0529(10) Uani 1 1 d D . .
O14 O 0.24780(7) 1.22013(17) 0.34474(8) 0.0654(8) Uani 1 1 d D . .
C15 C 0.24216(9) 1.1044(2) 0.30519(10) 0.0445(9) Uani 1 1 d D . .
H15 H 0.2674 1.1073 0.2985 0.053 Uiso 1 1 calc R . .
C16 C 0.21959(9) 1.0449(2) 0.29101(11) 0.0413(8) Uani 1 1 d D . .
H16 H 0.2298 1.0065 0.2752 0.05 Uiso 1 1 calc R . .
C17 C 0.28375(10) 1.2328(2) 0.33138(12) 0.0524(10) Uani 1 1 d . . .
H17A H 0.282 1.2357 0.301 0.063 Uiso 1 1 calc R . .
H17B H 0.3007 1.1908 0.3403 0.063 Uiso 1 1 calc R . .
C18 C 0.29860(12) 1.3038(2) 0.34930(14) 0.0616(12) Uani 1 1 d . . .
H18 H 0.3227 1.319 0.3426 0.074 Uiso 1 1 calc R . .
C19 C 0.28165(14) 1.3478(3) 0.37353(17) 0.0892(17) Uani 1 1 d . . .
H19A H 0.2575 1.3349 0.381 0.107 Uiso 1 1 calc R . .
H19B H 0.2934 1.3928 0.3837 0.107 Uiso 1 1 calc R . .
C20 C 0.14931(8) 0.84579(17) 0.26090(8) 0.0280(6) Uani 1 1 d . . .
O20 O 0.11501(5) 0.85062(11) 0.24757(5) 0.0263(4) Uani 1 1 d . . .
C21 C 0.16529(8) 0.76830(19) 0.26115(9) 0.0329(7) Uani 1 1 d . . .
C22 C 0.14534(9) 0.71156(18) 0.23858(9) 0.0340(7) Uani 1 1 d . . .
H22 H 0.1233 0.7245 0.2216 0.041 Uiso 1 1 calc R . .
C23 C 0.15686(10) 0.6376(2) 0.24034(10) 0.0433(8) Uani 1 1 d . . .
H23 H 0.1429 0.6004 0.2246 0.052 Uiso 1 1 calc R . .
C24 C 0.18865(11) 0.6178(2) 0.26502(11) 0.0483(9) Uani 1 1 d . . .
O24 O 0.20130(8) 0.54537(16) 0.26913(9) 0.0619(8) Uani 1 1 d U A .
C25 C 0.20940(10) 0.6724(2) 0.28707(11) 0.0503(9) Uani 1 1 d U . .
H25 H 0.2316 0.6588 0.3036 0.06 Uiso 1 1 calc R . .
C26 C 0.19797(9) 0.7470(2) 0.28510(10) 0.0426(8) Uani 1 1 d U . .
H26 H 0.2125 0.7841 0.3002 0.051 Uiso 1 1 calc R . .
C27 C 0.17867(18) 0.4847(3) 0.25045(19) 0.1010(17) Uani 1 1 d DU . .
H27A H 0.1765 0.4897 0.2201 0.121 Uiso 0.846(7) 1 calc PRD A 1
H27B H 0.1532 0.4865 0.2598 0.121 Uiso 0.846(7) 1 calc PR A 1
H27C H 0.175 0.4991 0.2211 0.121 Uiso 0.154(7) 1 calc PRD A 2
H27D H 0.154 0.4923 0.2611 0.121 Uiso 0.154(7) 1 calc PR A 2
C28 C 0.1978(3) 0.4090(4) 0.2634(3) 0.112(2) Uani 0.846(7) 1 d PDU A 1
H28 H 0.184 0.3637 0.259 0.134 Uiso 0.846(7) 1 calc PR A 1
C29 C 0.2280(3) 0.4061(5) 0.2779(3) 0.141(3) Uani 0.846(7) 1 d PDU A 1
H29A H 0.2422 0.4509 0.2825 0.211 Uiso 0.846(7) 1 calc PR A 1
H29B H 0.2389 0.3588 0.2855 0.211 Uiso 0.846(7) 1 calc PR A 1
C28' C 0.1825(14) 0.4017(10) 0.2491(11) 0.107(7) Uiso 0.154(7) 1 d PDU A 2
H28' H 0.1821 0.3841 0.2216 0.128 Uiso 0.154(7) 1 calc PR A 2
C29' C 0.1859(7) 0.3488(14) 0.2741(7) 0.048(6) Uiso 0.154(7) 1 d PDU A 2
H29C H 0.1867 0.3585 0.3027 0.072 Uiso 0.154(7) 1 calc PR A 2
H29D H 0.1879 0.2987 0.2644 0.072 Uiso 0.154(7) 1 calc PR A 2
C2 C 0.10445(9) 0.85366(17) 0.35535(9) 0.0301(6) Uani 1 1 d . . .
H2 H 0.1243 0.8232 0.3673 0.036 Uiso 1 1 calc R . .
C30 C 0.10207(8) 0.92916(17) 0.36997(8) 0.0276(6) Uani 1 1 d . . .
O30 O 0.07278(6) 0.96771(11) 0.36556(5) 0.0258(4) Uani 1 1 d . . .
C31 C 0.13563(8) 0.96411(17) 0.39296(9) 0.0314(7) Uani 1 1 d . . .
C32 C 0.13140(9) 1.02757(18) 0.41712(9) 0.0345(7) Uani 1 1 d . . .
H32 H 0.107 1.0469 0.4192 0.041 Uiso 1 1 calc R . .
C33 C 0.16163(10) 1.0632(2) 0.43809(11) 0.0458(9) Uani 1 1 d . . .
H33 H 0.158 1.1055 0.455 0.055 Uiso 1 1 calc R . .
C34 C 0.19725(11) 1.0364(2) 0.43412(12) 0.0538(10) Uani 1 1 d . . .
O34 O 0.22971(8) 1.06589(17) 0.45408(10) 0.0738(10) Uani 1 1 d . . .
C35 C 0.20247(10) 0.9750(2) 0.40944(12) 0.0550(11) Uani 1 1 d . . .
H35 H 0.2271 0.9574 0.4065 0.066 Uiso 1 1 calc R . .
C36 C 0.17217(9) 0.9391(2) 0.38907(11) 0.0424(8) Uani 1 1 d . . .
H36 H 0.1761 0.8969 0.3722 0.051 Uiso 1 1 calc R . .
C37 C 0.22853(13) 1.1371(3) 0.47524(15) 0.0773(15) Uani 1 1 d . . .
H37A H 0.2515 1.1427 0.4943 0.093 Uiso 1 1 calc R . .
H37B H 0.2067 1.1378 0.4917 0.093 Uiso 1 1 calc R . .
C38 C 0.22569(13) 1.2015(3) 0.44574(16) 0.0728(14) Uani 1 1 d . . .
H38 H 0.2411 1.2008 0.4236 0.087 Uiso 1 1 calc R . .
C39 C 0.20319(13) 1.2591(3) 0.44864(16) 0.0744(14) Uani 1 1 d . . .
H39A H 0.1874 1.2614 0.4705 0.089 Uiso 1 1 calc R . .
H39B H 0.2026 1.2984 0.4289 0.089 Uiso 1 1 calc R . .
C40 C 0.08001(8) 0.82207(15) 0.32517(8) 0.0235(6) Uani 1 1 d . . .
O40 O 0.05452(5) 0.86110(10) 0.30326(5) 0.0219(4) Uani 1 1 d . . .
C41 C 0.08095(8) 0.74033(16) 0.31470(8) 0.0277(6) Uani 1 1 d . . .
C42 C 0.06205(8) 0.71508(17) 0.27814(9) 0.0301(6) Uani 1 1 d . . .
H42 H 0.0493 0.7505 0.2601 0.036 Uiso 1 1 calc R . .
C43 C 0.06126(9) 0.63973(18) 0.26736(10) 0.0374(8) Uani 1 1 d . . .
H43 H 0.0483 0.6241 0.2421 0.045 Uiso 1 1 calc R . .
C44 C 0.07944(10) 0.58723(19) 0.29352(11) 0.0437(9) Uani 1 1 d . . .
O44 O 0.07984(8) 0.51165(14) 0.28555(9) 0.0632(8) Uani 1 1 d . B .
C45 C 0.09892(11) 0.61151(19) 0.33016(11) 0.0475(9) Uani 1 1 d . . .
H45 H 0.1117 0.576 0.3481 0.057 Uiso 1 1 calc R . .
C46 C 0.09969(10) 0.68669(18) 0.34048(10) 0.0410(8) Uani 1 1 d . . .
H46 H 0.1131 0.7024 0.3655 0.049 Uiso 1 1 calc R . .
C47 C 0.05966(17) 0.4846(2) 0.25009(16) 0.0857(16) Uani 1 1 d DU . .
H47A H 0.0698 0.5064 0.2255 0.103 Uiso 0.5890(17) 1 calc PR B 1
H47B H 0.0331 0.4999 0.2499 0.103 Uiso 0.5890(17) 1 calc PR B 1
H47C H 0.064 0.5181 0.2267 0.103 Uiso 0.4110(17) 1 d PR B 2
H47D H 0.0323 0.4845 0.2533 0.103 Uiso 0.4110(17) 1 d PR B 2
C48 C 0.0623(4) 0.4004(6) 0.2488(6) 0.1060(19) Uani 0.5890(17) 1 d PDU B 1
H48 H 0.0523 0.3776 0.2239 0.127 Uiso 0.5890(17) 1 calc PR B 1
C49 C 0.0765(3) 0.3546(5) 0.2770(3) 0.096(3) Uani 0.5890(17) 1 d PDU B 1
H49A H 0.0871 0.3736 0.3027 0.115 Uiso 0.5890(17) 1 calc PR B 1
H49B H 0.0764 0.302 0.272 0.115 Uiso 0.5890(17) 1 calc PR B 1
C48' C 0.0595(6) 0.4021(8) 0.2491(9) 0.1060(19) Uani 0.4110(17) 1 d PDU B 2
H48' H 0.0828 0.3768 0.2541 0.127 Uiso 0.4110(17) 1 calc PR B 2
C49' C 0.0305(5) 0.3630(8) 0.2421(6) 0.143(5) Uani 0.4110(17) 1 d PDU B 2
H49C H 0.0068 0.3866 0.2369 0.172 Uiso 0.4110(17) 1 calc PR B 2
H49D H 0.0323 0.3097 0.2418 0.172 Uiso 0.4110(17) 1 calc PR B 2
C3 C -0.01296(9) 0.91057(17) 0.43863(8) 0.0300(7) Uani 1 1 d . . .
H3 H -0.0191 0.9019 0.4659 0.036 Uiso 1 1 calc R . .
C50 C -0.02510(7) 0.97839(16) 0.41952(8) 0.0238(6) Uani 1 1 d . . .
O50 O -0.01740(5) 0.99774(11) 0.38389(5) 0.0249(4) Uani 1 1 d . . .
C51 C -0.04932(8) 1.03144(17) 0.44076(8) 0.0282(6) Uani 1 1 d . . .
C52 C -0.06705(9) 1.0894(2) 0.41805(9) 0.0375(8) Uani 1 1 d . . .
H52 H -0.0627 1.0954 0.39 0.045 Uiso 1 1 calc R . .
C53 C -0.09097(11) 1.1388(2) 0.43558(11) 0.0512(10) Uani 1 1 d . . .
H53 H -0.103 1.1777 0.4194 0.061 Uiso 1 1 calc R . .
C54 C -0.09732(10) 1.1318(2) 0.47654(10) 0.0470(9) Uani 1 1 d . . .
O54 O -0.12124(9) 1.18594(19) 0.49092(8) 0.0722(9) Uani 1 1 d . . .
C55 C -0.08035(10) 1.0745(2) 0.49962(10) 0.0407(8) Uani 1 1 d . . .
H55 H -0.0848 1.0691 0.5277 0.049 Uiso 1 1 calc R . .
C56 C -0.05663(9) 1.02456(19) 0.48206(9) 0.0337(7) Uani 1 1 d . . .
H56 H -0.0452 0.9851 0.4983 0.04 Uiso 1 1 calc R . .
C57 C -0.12443(12) 1.1885(3) 0.53362(12) 0.0628(12) Uani 1 1 d . B .
H57A H -0.0993 1.1912 0.5489 0.075 Uiso 1 1 calc R . .
H57B H -0.1373 1.1429 0.5425 0.075 Uiso 1 1 calc R . .
C58 C -0.14690(17) 1.2579(4) 0.54166(17) 0.1015(19) Uani 1 1 d DU . .
H58 H -0.1406 1.302 0.5275 0.122 Uiso 0.5890(17) 1 calc PR B 1
H58' H -0.1721 1.2436 0.5331 0.122 Uiso 0.4110(17) 1 d PR B 2
C59 C -0.1727(2) 1.2648(6) 0.5645(2) 0.083(3) Uani 0.5890(17) 1 d PDU B 1
H59A H -0.179 1.3131 0.5741 0.099 Uiso 0.5890(17) 1 calc PR B 1
H59B H -0.186 1.2217 0.5723 0.099 Uiso 0.5890(17) 1 calc PR B 1
C59' C -0.1504(5) 1.3162(8) 0.5497(5) 0.101(4) Uani 0.4110(17) 1 d PDU B 2
H59C H -0.1691 1.3301 0.5671 0.121 Uiso 0.4110(17) 1 calc PR B 2
H59D H -0.1348 1.3535 0.5395 0.121 Uiso 0.4110(17) 1 calc PR B 2
C60 C 0.00742(8) 0.85527(16) 0.42021(8) 0.0260(6) Uani 1 1 d . . .
O60 O 0.01587(6) 0.85817(11) 0.38325(5) 0.0274(4) Uani 1 1 d . . .
C61 C 0.02033(10) 0.78636(18) 0.44379(9) 0.0347(7) Uani 1 1 d U . .
C62 C 0.03360(10) 0.72611(18) 0.42308(10) 0.0398(8) Uani 1 1 d U . .
H62 H 0.0352 0.73 0.3943 0.048 Uiso 1 1 calc R . .
C63 C 0.04462(12) 0.6600(2) 0.44301(12) 0.0524(10) Uani 1 1 d U . .
H63 H 0.0533 0.6187 0.428 0.063 Uiso 1 1 calc R . .
C64 C 0.04279(16) 0.6548(2) 0.48494(13) 0.0743(14) Uani 1 1 d U . .
C65 C 0.03208(17) 0.7160(2) 0.50668(12) 0.0800(16) Uani 1 1 d U . .
H65 H 0.0327 0.7136 0.5358 0.096 Uiso 1 1 calc R . .
C66 C 0.02056(14) 0.7805(2) 0.48644(10) 0.0580(11) Uani 1 1 d U . .
H66 H 0.0126 0.822 0.5017 0.07 Uiso 1 1 calc R . .
O64 O 0.05135(13) 0.59102(18) 0.50764(11) 0.1030(13) Uani 1 1 d U . .
C67 C 0.05817(18) 0.5255(3) 0.48735(18) 0.0926(16) Uani 1 1 d U . .
H67A H 0.0822 0.5283 0.4747 0.111 Uiso 1 1 calc R . .
H67B H 0.0377 0.5144 0.4657 0.111 Uiso 1 1 calc R . .
C68 C 0.05997(16) 0.4656(3) 0.52205(19) 0.0910(16) Uani 1 1 d DU . .
H68 H 0.0743 0.4755 0.5475 0.109 Uiso 1 1 calc R . .
C69 C 0.04308(15) 0.4051(3) 0.5171(2) 0.0937(17) Uani 1 1 d DU . .
H69A H 0.0287 0.3947 0.4918 0.112 Uiso 1 1 calc R . .
H69B H 0.0445 0.369 0.5386 0.112 Uiso 1 1 calc R . .
C4 C 0.0863(2) 1.2018(4) 0.3005(2) 0.0357(19) Uani 0.4110(17) 1 d P B 1
H4 H 0.11 1.2135 0.3147 0.043 Uiso 0.4110(17) 1 calc PR B 1
C70 C 0.0551(2) 1.1915(4) 0.32294(18) 0.0312(17) Uani 0.4110(17) 1 d PD B 1
O70 O 0.0212(3) 1.1790(5) 0.3091(2) 0.0261(5) Uani 0.4110(17) 1 d PD B 1
C71 C 0.0608(2) 1.1916(4) 0.3695(2) 0.030(2) Uani 0.4110(17) 1 d PD B 1
C72 C 0.0375(2) 1.1471(4) 0.39103(17) 0.0297(16) Uani 0.4110(17) 1 d PD B 1
H72 H 0.0175 1.1203 0.3764 0.036 Uiso 0.4110(17) 1 calc PR B 1
C73 C 0.0427(2) 1.1413(4) 0.4330(2) 0.0340(17) Uani 0.4110(17) 1 d PD B 1
H73 H 0.026 1.1113 0.4469 0.041 Uiso 0.4110(17) 1 calc PR B 1
C74 C 0.0721(2) 1.1781(4) 0.45581(19) 0.0326(18) Uani 0.4110(17) 1 d PD B 1
O74 O 0.07473(17) 1.1665(3) 0.49740(13) 0.0446(15) Uani 0.4110(17) 1 d PD B 1
C75 C 0.0948(3) 1.2238(5) 0.4350(2) 0.037(2) Uani 0.4110(17) 1 d PD B 1
H75 H 0.1144 1.2512 0.4498 0.045 Uiso 0.4110(17) 1 calc PR B 1
C76 C 0.0892(3) 1.2304(5) 0.3921(2) 0.039(2) Uani 0.4110(17) 1 d PD B 1
H76 H 0.1053 1.262 0.3782 0.047 Uiso 0.4110(17) 1 calc PR B 1
C77 C 0.0855(3) 1.2256(5) 0.5242(3) 0.045(2) Uani 0.4110(17) 1 d PD B 1
H77A H 0.072 1.2211 0.5491 0.054 Uiso 0.4110(17) 1 calc PR B 1
H77B H 0.0781 1.2738 0.5106 0.054 Uiso 0.4110(17) 1 calc PR B 1
C78 C 0.1273(3) 1.2272(7) 0.5368(3) 0.053(3) Uani 0.4110(17) 1 d PD B 1
H78 H 0.1398 1.1803 0.5407 0.064 Uiso 0.4110(17) 1 calc PR B 1
C79 C 0.1469(4) 1.2867(8) 0.5427(3) 0.075(4) Uani 0.4110(17) 1 d PD B 1
H79A H 0.1354 1.3347 0.5391 0.09 Uiso 0.4110(17) 1 calc PR B 1
H79B H 0.173 1.2831 0.5506 0.09 Uiso 0.4110(17) 1 calc PR B 1
C80 C 0.08304(18) 1.1948(3) 0.25684(18) 0.0243(14) Uani 0.4110(17) 1 d PD B 1
O80 O 0.0532(2) 1.1787(4) 0.2348(2) 0.0280(7) Uani 0.4110(17) 1 d PD B 1
C81 C 0.11654(18) 1.2110(4) 0.2345(2) 0.0308(16) Uani 0.4110(17) 1 d PD B 1
C82 C 0.1122(3) 1.2215(7) 0.1923(2) 0.048(3) Uani 0.4110(17) 1 d PD B 1
H82 H 0.0877 1.2181 0.1785 0.058 Uiso 0.4110(17) 1 calc PR B 1
C83 C 0.1417(2) 1.2365(5) 0.1691(2) 0.042(2) Uani 0.4110(17) 1 d PD B 1
H83 H 0.1375 1.2449 0.1404 0.051 Uiso 0.4110(17) 1 calc PR B 1
C84 C 0.1771(2) 1.2389(7) 0.1888(2) 0.046(3) Uani 0.4110(17) 1 d PD B 1
O84 O 0.2073(2) 1.2593(5) 0.1688(3) 0.068(3) Uani 0.4110(17) 1 d PD B 1
C85 C 0.1826(2) 1.2263(7) 0.2307(2) 0.074(4) Uani 0.4110(17) 1 d PD B 1
H85 H 0.2073 1.2264 0.2441 0.089 Uiso 0.4110(17) 1 calc PR B 1
C86 C 0.1531(2) 1.2139(6) 0.2527(2) 0.063(3) Uani 0.4110(17) 1 d PD B 1
H86 H 0.1576 1.2069 0.2816 0.076 Uiso 0.4110(17) 1 calc PR B 1
C87 C 0.2037(3) 1.2778(6) 0.1266(3) 0.051(3) Uani 0.4110(17) 1 d PD B 1
H87A H 0.1844 1.317 0.1206 0.062 Uiso 0.4110(17) 1 calc PR B 1
H87B H 0.1968 1.2329 0.1096 0.062 Uiso 0.4110(17) 1 calc PR B 1
C88 C 0.2403(3) 1.3053(8) 0.1186(4) 0.068(4) Uani 0.4110(17) 1 d PD B 1
H88 H 0.2473 1.3542 0.1281 0.081 Uiso 0.4110(17) 1 calc PR B 1
C89 C 0.2635(3) 1.2683(8) 0.0997(4) 0.090(4) Uani 0.4110(17) 1 d PD B 1
H89A H 0.2573 1.2192 0.0898 0.108 Uiso 0.4110(17) 1 calc PR B 1
H89B H 0.2871 1.2896 0.0954 0.108 Uiso 0.4110(17) 1 calc PR B 1
C5 C 0.09324(8) 0.86496(16) 0.14587(8) 0.0245(6) Uani 1 1 d . . .
H5 H 0.1039 0.838 0.1247 0.029 Uiso 1 1 calc R . .
C90 C 0.10827(8) 0.93753(16) 0.15638(8) 0.0261(6) Uani 1 1 d . . .
O90 O 0.10113(5) 0.97420(11) 0.18757(6) 0.0266(4) Uani 1 1 d . . .
C91 C 0.13539(8) 0.97294(17) 0.13031(8) 0.0267(6) Uani 1 1 d . . .
C92 C 0.13527(9) 0.95923(18) 0.08856(9) 0.0323(7) Uani 1 1 d . . .
H92 H 0.1184 0.9232 0.0759 0.039 Uiso 1 1 calc R . .
C93 C 0.15950(9) 0.9976(2) 0.06487(10) 0.0422(8) Uani 1 1 d . . .
H93 H 0.1589 0.9884 0.0362 0.051 Uiso 1 1 calc R . .
C94 C 0.18424(11) 1.0488(2) 0.08368(11) 0.0480(9) Uani 1 1 d . . .
O94 O 0.20897(8) 1.09143(19) 0.06383(8) 0.0699(9) Uani 1 1 d . . .
C95 C 0.18521(11) 1.0624(2) 0.12558(12) 0.0486(9) Uani 1 1 d . . .
H95 H 0.2028 1.0969 0.1384 0.058 Uiso 1 1 calc R . .
C96 C 0.16043(9) 1.02541(19) 0.14852(10) 0.0359(7) Uani 1 1 d . . .
H96 H 0.1605 1.036 0.1771 0.043 Uiso 1 1 calc R . .
C97 C 0.20896(13) 1.0817(3) 0.02029(13) 0.0832(16) Uani 1 1 d . . .
H97A H 0.184 1.0919 0.0058 0.1 Uiso 1 1 calc R . .
H97B H 0.2171 1.0305 0.0133 0.1 Uiso 1 1 calc R . .
C98 C 0.23873(17) 1.1435(4) 0.00978(16) 0.124(2) Uani 1 1 d DU . .
H98 H 0.2369 1.1921 0.0215 0.149 Uiso 1 1 calc R . .
C99 C 0.26389(15) 1.1323(4) -0.01249(16) 0.115(2) Uani 1 1 d DU . .
H99A H 0.2665 1.0842 -0.0247 0.138 Uiso 1 1 calc R . .
H99B H 0.2808 1.1716 -0.0176 0.138 Uiso 1 1 calc R . .
C100 C 0.06416(7) 0.83075(15) 0.16422(7) 0.0207(5) Uani 1 1 d . . .
O100 O 0.04375(5) 0.86590(10) 0.18921(5) 0.0210(4) Uani 1 1 d . . .
C101 C 0.05471(8) 0.75093(17) 0.15608(8) 0.0285(6) Uani 1 1 d . . .
C102 C 0.02222(9) 0.72083(17) 0.16966(9) 0.0307(7) Uani 1 1 d . . .
H102 H 0.0064 0.7524 0.184 0.037 Uiso 1 1 calc R . .
C103 C 0.01211(10) 0.64590(17) 0.16295(10) 0.0384(8) Uani 1 1 d . . .
H103 H -0.01 0.6266 0.173 0.046 Uiso 1 1 calc R . .
C104 C 0.03445(12) 0.60016(19) 0.14171(10) 0.0469(9) Uani 1 1 d . . .
O104 O 0.02616(10) 0.52647(14) 0.13202(9) 0.0679(9) Uani 1 1 d . B .
C105 C 0.06754(14) 0.6279(2) 0.12899(13) 0.0634(12) Uani 1 1 d . . .
H105 H 0.0836 0.5955 0.1155 0.076 Uiso 1 1 calc R . .
C106 C 0.07758(11) 0.70255(18) 0.13573(11) 0.0441(9) Uani 1 1 d . . .
H106 H 0.1002 0.721 0.1264 0.053 Uiso 1 1 calc R . .
C107 C -0.00677(14) 0.4951(2) 0.14504(16) 0.0694(13) Uani 1 1 d DU . .
H10A H -0.0289 0.5271 0.1373 0.083 Uiso 0.4110(17) 1 calc PR B 1
H10B H -0.0045 0.4861 0.1751 0.083 Uiso 0.4110(17) 1 calc PR B 1
H10F H -0.0292 0.519 0.1302 0.083 Uiso 0.5890(17) 1 d PR B 2
H10G H -0.0083 0.5004 0.1752 0.083 Uiso 0.5890(17) 1 d PR B 2
C108 C -0.0083(6) 0.4233(7) 0.1214(6) 0.092(4) Uani 0.4110(17) 1 d PDU B 1
H108 H -0.011 0.4339 0.0927 0.111 Uiso 0.4110(17) 1 calc PR B 1
C109 C -0.0073(5) 0.3579(7) 0.1266(6) 0.123(4) Uani 0.4110(17) 1 d PDU B 1
H10C H -0.0047 0.3381 0.1537 0.147 Uiso 0.4110(17) 1 calc PR B 1
H10D H -0.0091 0.3249 0.1036 0.147 Uiso 0.4110(17) 1 calc PR B 1
C10A C -0.0135(4) 0.4140(5) 0.1316(4) 0.079(3) Uani 0.5890(17) 1 d PDU B 2
H10E H -0.0295 0.3814 0.145 0.095 Uiso 0.5890(17) 1 calc PR B 2
C10B C 0.0044(2) 0.3913(4) 0.1000(2) 0.066(2) Uani 0.5890(17) 1 d PDU B 2
H10H H 0.0202 0.4252 0.0872 0.079 Uiso 0.5890(17) 1 calc PR B 2
H10I H 0.0013 0.3413 0.0901 0.079 Uiso 0.5890(17) 1 calc PR B 2
C6 C -0.03075(14) 1.2078(3) 0.34295(14) 0.0275(10) Uani 0.5890(17) 1 d P B 2
H6 H -0.0391 1.2196 0.369 0.033 Uiso 0.5890(17) 1 calc PR B 2
C110 C 0.00792(13) 1.1963(2) 0.34058(13) 0.0229(10) Uani 0.5890(17) 1 d PD B 2
O110 O 0.02318(19) 1.1839(4) 0.30749(18) 0.0261(5) Uani 0.5890(17) 1 d PD B 2
C111 C 0.03479(14) 1.2011(3) 0.37839(13) 0.0258(10) Uani 0.5890(17) 1 d PD B 2
C112 C 0.02461(14) 1.1937(3) 0.41844(13) 0.0287(11) Uani 0.5890(17) 1 d PD B 2
H112 H -0.001 1.1864 0.4228 0.034 Uiso 0.5890(17) 1 calc PR B 2
C113 C 0.05153(15) 1.1970(3) 0.45204(15) 0.0305(12) Uani 0.5890(17) 1 d PD B 2
H113 H 0.0442 1.1912 0.4791 0.037 Uiso 0.5890(17) 1 calc PR B 2
C114 C 0.08845(17) 1.2085(4) 0.44640(17) 0.0280(14) Uani 0.5890(17) 1 d PD B 2
O114 O 0.11673(10) 1.2143(2) 0.47764(10) 0.0382(9) Uani 0.5890(17) 1 d PD B 2
C115 C 0.09894(15) 1.2163(4) 0.40648(17) 0.0309(13) Uani 0.5890(17) 1 d PD B 2
H115 H 0.1244 1.2256 0.4022 0.037 Uiso 0.5890(17) 1 calc PR B 2
C116 C 0.07256(15) 1.2105(4) 0.37338(16) 0.0267(13) Uani 0.5890(17) 1 d PD B 2
H116 H 0.0803 1.2129 0.3464 0.032 Uiso 0.5890(17) 1 calc PR B 2
C117 C 0.10633(18) 1.2246(4) 0.51869(16) 0.0373(14) Uani 0.5890(17) 1 d PD B 2
H11A H 0.0932 1.1794 0.5278 0.045 Uiso 0.5890(17) 1 calc PR B 2
H11B H 0.0895 1.2685 0.5199 0.045 Uiso 0.5890(17) 1 calc PR B 2
C118 C 0.1423(2) 1.2373(5) 0.5456(2) 0.046(2) Uani 0.5890(17) 1 d PD B 2
H118 H 0.1594 1.1966 0.5497 0.055 Uiso 0.5890(17) 1 calc PR B 2
C119 C 0.1511(2) 1.3002(4) 0.5632(2) 0.057(2) Uani 0.5890(17) 1 d PD B 2
H11C H 0.1345 1.3418 0.5596 0.069 Uiso 0.5890(17) 1 calc PR B 2
H11D H 0.1741 1.3052 0.5798 0.069 Uiso 0.5890(17) 1 calc PR B 2
C120 C -0.05789(13) 1.2027(3) 0.30843(13) 0.0245(10) Uani 0.5890(17) 1 d PD B 2
O120 O -0.05123(16) 1.1828(3) 0.27221(15) 0.0280(7) Uani 0.5890(17) 1 d PD B 2
C121 C -0.09845(15) 1.2161(4) 0.31427(17) 0.0269(13) Uani 0.5890(17) 1 d PD B 2
C122 C -0.12605(13) 1.1853(3) 0.28625(17) 0.0310(12) Uani 0.5890(17) 1 d PD B 2
H122 H -0.1188 1.1594 0.2628 0.037 Uiso 0.5890(17) 1 calc PR B 2
C123 C -0.16371(14) 1.1916(3) 0.29195(16) 0.0388(13) Uani 0.5890(17) 1 d PD B 2
H123 H -0.1822 1.1703 0.2726 0.047 Uiso 0.5890(17) 1 calc PR B 2
C124 C -0.17417(16) 1.2295(4) 0.32622(18) 0.0358(16) Uani 0.5890(17) 1 d PD B 2
O124 O -0.21253(13) 1.2285(3) 0.33083(14) 0.0336(11) Uani 0.5890(17) 1 d PD B 2
C125 C -0.14746(15) 1.2649(3) 0.35290(16) 0.0383(13) Uani 0.5890(17) 1 d PD B 2
H125 H -0.1549 1.2937 0.3753 0.046 Uiso 0.5890(17) 1 calc PR B 2
C126 C -0.11005(14) 1.2582(3) 0.34695(15) 0.0344(12) Uani 0.5890(17) 1 d PD B 2
H126 H -0.0918 1.2826 0.3654 0.041 Uiso 0.5890(17) 1 calc PR B 2
C127 C -0.22348(19) 1.2518(4) 0.37011(18) 0.0456(16) Uani 0.5890(17) 1 d PD B 2
H12A H -0.2038 1.2374 0.392 0.055 Uiso 0.5890(17) 1 calc PR B 2
H12B H -0.2469 1.2257 0.3756 0.055 Uiso 0.5890(17) 1 calc PR B 2
C128 C -0.2294(3) 1.3343(4) 0.3713(2) 0.057(2) Uani 0.5890(17) 1 d PD B 2
H128 H -0.2348 1.3543 0.397 0.068 Uiso 0.5890(17) 1 calc PR B 2
C129 C -0.22831(17) 1.3819(4) 0.34207(18) 0.0488(16) Uani 0.5890(17) 1 d PD B 2
H12C H -0.2231 1.3656 0.3155 0.059 Uiso 0.5890(17) 1 calc PR B 2
H12D H -0.2327 1.4337 0.347 0.059 Uiso 0.5890(17) 1 calc PR B 2
C211 C 0.18267(18) 0.4808(4) 0.40074(17) 0.111(2) Uani 1 1 d D . .
C212 C 0.15641(17) 0.4392(4) 0.37457(18) 0.100(2) Uani 1 1 d D . .
H212 H 0.1596 0.4312 0.3463 0.12 Uiso 1 1 calc R . .
C213 C 0.1268(2) 0.4118(4) 0.3921(2) 0.133(3) Uani 1 1 d D . .
H213 H 0.1068 0.3926 0.374 0.16 Uiso 1 1 calc R . .
C214 C 0.1227(2) 0.4086(5) 0.4325(2) 0.164(4) Uani 1 1 d D . .
H214 H 0.1019 0.3846 0.4431 0.197 Uiso 1 1 calc R . .
C215 C 0.1503(2) 0.4424(4) 0.4573(2) 0.117(2) Uani 1 1 d D . .
H215 H 0.1494 0.4388 0.4862 0.14 Uiso 1 1 calc R . .
C216 C 0.1795(2) 0.4816(4) 0.44266(18) 0.130(3) Uani 1 1 d D . .
H216 H 0.1969 0.5083 0.4609 0.156 Uiso 1 1 calc R . .
C217 C 0.2112(3) 0.5277(6) 0.3837(3) 0.229(6) Uani 1 1 d D . .
H21A H 0.2027 0.5411 0.3553 0.344 Uiso 1 1 calc R . .
H21B H 0.2348 0.4996 0.3843 0.344 Uiso 1 1 calc RD . .
H21C H 0.2151 0.5735 0.4002 0.344 Uiso 1 1 calc R . .
C311 C 0.13617(18) 0.5307(4) 0.6252(2) 0.133(2) Uani 1 1 d DU . .
C312 C 0.1665(2) 0.4785(5) 0.6326(2) 0.166(2) Uani 1 1 d DU . .
H312 H 0.1699 0.4532 0.6583 0.199 Uiso 1 1 calc R . .
C313 C 0.1906(2) 0.4644(5) 0.6036(2) 0.156(2) Uani 1 1 d DU . .
H313 H 0.2113 0.4313 0.6086 0.187 Uiso 1 1 calc R . .
C314 C 0.1830(2) 0.5012(5) 0.5663(2) 0.150(2) Uani 1 1 d DU . .
H314 H 0.1985 0.4904 0.545 0.18 Uiso 1 1 calc R . .
C315 C 0.1548(2) 0.5518(5) 0.5582(2) 0.150(2) Uani 1 1 d DU . .
H315 H 0.1513 0.5764 0.5323 0.18 Uiso 1 1 calc R . .
C316 C 0.1307(2) 0.5670(5) 0.5893(2) 0.152(2) Uani 1 1 d DU . .
H316 H 0.1109 0.6024 0.5846 0.182 Uiso 1 1 calc R . .
C317 C 0.1124(2) 0.5461(4) 0.6606(2) 0.152(3) Uani 1 1 d DU . .
H31A H 0.1034 0.4984 0.671 0.228 Uiso 1 1 calc R . .
H31B H 0.091 0.5777 0.6509 0.228 Uiso 1 1 calc RD . .
H31C H 0.1276 0.572 0.6828 0.228 Uiso 1 1 calc RD . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
1 0 0 0.0678
-1 0 0 0.0173
-1 -1 0 0.0449
-1 1 0 0.0209
-44 -1 26 0.0958
0 0 -1 0.9596
9 19 28 0.1673
-10 -24 14 0.1037
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O50 Eu1 O60 72.75(7) . .
O50 Eu1 O3 76.92(6) . .
O60 Eu1 O3 140.23(7) . .
O50 Eu1 O40 152.33(6) . .
O60 Eu1 O40 81.55(6) . .
O3 Eu1 O40 130.69(6) . .
O50 Eu1 O2 116.58(6) . .
O60 Eu1 O2 146.18(7) . .
O3 Eu1 O2 71.46(6) . .
O40 Eu1 O2 79.95(6) . .
O50 Eu1 O30 91.51(6) . .
O60 Eu1 O30 76.12(7) . .
O3 Eu1 O30 130.25(6) . .
O40 Eu1 O30 72.15(6) . .
O2 Eu1 O30 71.36(6) . .
O50 Eu1 O100 90.62(6) . 2
O60 Eu1 O100 78.35(6) . 2
O3 Eu1 O100 76.85(6) . 2
O40 Eu1 O100 94.13(6) . 2
O2 Eu1 O100 130.95(6) . 2
O30 Eu1 O100 152.47(6) . 2
O50 Eu1 O1 140.46(5) . .
O60 Eu1 O1 128.17(7) . .
O3 Eu1 O1 66.96(6) . .
O40 Eu1 O1 65.10(5) . .
O2 Eu1 O1 66.97(6) . .
O30 Eu1 O1 123.88(5) . .
O100 Eu1 O1 66.53(5) 2 .
O10 Eu2 O20 73.39(7) . .
O10 Eu2 O2 76.07(6) . .
O20 Eu2 O2 137.86(6) . .
O10 Eu2 O90 82.51(7) . .
O20 Eu2 O90 78.23(7) . .
O2 Eu2 O90 125.50(6) . .
O10 Eu2 O100 147.11(6) . .
O20 Eu2 O100 80.43(6) . .
O2 Eu2 O100 136.24(6) . .
O90 Eu2 O100 72.82(6) . .
O10 Eu2 O3 115.22(7) . 2
O20 Eu2 O3 147.09(6) . 2
O2 Eu2 O3 73.20(6) . 2
O90 Eu2 O3 71.98(6) . 2
O100 Eu2 O3 77.74(6) . 2
O10 Eu2 O40 93.97(7) . .
O20 Eu2 O40 75.74(6) . .
O2 Eu2 O40 78.17(6) . .
O90 Eu2 O40 153.63(6) . .
O100 Eu2 O40 98.58(6) . .
O3 Eu2 O40 131.66(6) 2 .
O10 Eu2 O1 142.57(5) . .
O20 Eu2 O1 125.37(7) . .
O2 Eu2 O1 69.51(6) . .
O90 Eu2 O1 129.80(5) . .
O100 Eu2 O1 69.70(5) . .
O3 Eu2 O1 68.43(6) 2 .
O40 Eu2 O1 65.35(5) . .
O70 Eu3 O70 118.8(5) . 2
O70 Eu3 O80 73.1(3) . .
O70 Eu3 O80 77.0(3) 2 .
O70 Eu3 O80 77.0(3) . 2
O70 Eu3 O80 73.1(3) 2 2
O80 Eu3 O80 119.2(3) . 2
O70 Eu3 O110 3.1(4) . .
O70 Eu3 O110 116.59(12) 2 .
O80 Eu3 O110 70.2(2) . .
O80 Eu3 O110 77.9(2) 2 .
O70 Eu3 O110 116.59(12) . 2
O70 Eu3 O110 3.1(4) 2 2
O80 Eu3 O110 77.9(2) . 2
O80 Eu3 O110 70.2(2) 2 2
O110 Eu3 O110 114.5(3) . 2
O70 Eu3 O120 77.5(3) . 2
O70 Eu3 O120 71.4(3) 2 2
O80 Eu3 O120 5.7(3) . 2
O80 Eu3 O120 117.63(13) 2 2
O110 Eu3 O120 74.5(2) . 2
O110 Eu3 O120 72.5(2) 2 2
O70 Eu3 O120 71.4(3) . .
O70 Eu3 O120 77.5(3) 2 .
O80 Eu3 O120 117.63(12) . .
O80 Eu3 O120 5.7(3) 2 .
O110 Eu3 O120 72.5(2) . .
O110 Eu3 O120 74.5(2) 2 .
O120 Eu3 O120 116.7(3) 2 .
O70 Eu3 O3 133.1(2) . 2
O70 Eu3 O3 85.4(2) 2 2
O80 Eu3 O3 74.76(19) . 2
O80 Eu3 O3 149.57(17) 2 2
O110 Eu3 O3 131.88(18) . 2
O110 Eu3 O3 88.47(17) 2 2
O120 Eu3 O3 73.34(14) 2 2
O120 Eu3 O3 155.27(13) . 2
O70 Eu3 O3 85.4(2) . .
O70 Eu3 O3 133.1(2) 2 .
O80 Eu3 O3 149.57(17) . .
O80 Eu3 O3 74.76(19) 2 .
O110 Eu3 O3 88.47(17) . .
O110 Eu3 O3 131.88(18) 2 .
O120 Eu3 O3 155.27(13) 2 .
O120 Eu3 O3 73.34(14) . .
O3 Eu3 O3 107.38(8) 2 .
O70 Eu3 O2 152.7(2) . 2
O70 Eu3 O2 73.2(2) 2 2
O80 Eu3 O2 134.01(19) . 2
O80 Eu3 O2 84.36(17) 2 2
O110 Eu3 O2 155.50(17) . 2
O110 Eu3 O2 74.21(18) 2 2
O120 Eu3 O2 129.32(13) 2 2
O120 Eu3 O2 89.13(13) . 2
O3 Eu3 O2 68.69(6) 2 2
O3 Eu3 O2 70.45(6) . 2
O70 Eu3 O2 73.2(2) . .
O70 Eu3 O2 152.7(2) 2 .
O80 Eu3 O2 84.36(17) . .
O80 Eu3 O2 134.01(19) 2 .
O110 Eu3 O2 74.21(18) . .
O110 Eu3 O2 155.50(17) 2 .
O120 Eu3 O2 89.13(13) 2 .
O120 Eu3 O2 129.32(13) . .
O3 Eu3 O2 70.45(6) 2 .
O3 Eu3 O2 68.69(6) . .
O2 Eu3 O2 107.78(8) 2 .
Eu2 O1 Eu2 161.80(11) . 2
Eu2 O1 Eu1 88.855(18) . 2
Eu2 O1 Eu1 88.133(18) 2 2
Eu2 O1 Eu1 88.133(18) . .
Eu2 O1 Eu1 88.855(18) 2 .
Eu1 O1 Eu1 160.87(10) 2 .
Eu2 O1 H1O 99.10 . .
Eu2 O1 H1O 99.10 2 .
Eu1 O1 H1O 99.57 2 .
Eu1 O1 H1O 99.57 . .
Eu2 O2 Eu1 99.04(7) . .
Eu2 O2 Eu3 108.18(6) . .
Eu1 O2 Eu3 108.89(7) . .
Eu2 O2 H2O 113.2 . .
Eu1 O2 H2O 113.2 . .
Eu3 O2 H2O 113.2 . .
Eu1 O3 Eu2 99.22(7) . 2
Eu1 O3 Eu3 110.52(7) . .
Eu2 O3 Eu3 107.39(6) 2 .
Eu1 O3 H3O 112.9 . .
Eu2 O3 H3O 112.9 2 .
Eu3 O3 H3O 112.9 . .
C20 C1 C10 123.1(3) . .
C20 C1 H1 118.4 . .
C10 C1 H1 118.4 . .
O10 C10 C1 124.5(3) . .
O10 C10 C11 115.3(3) . .
C1 C10 C11 120.1(3) . .
C10 O10 Eu2 134.91(18) . .
C12 C11 C16 117.9(3) . .
C12 C11 C10 119.1(3) . .
C16 C11 C10 123.1(3) . .
C13 C12 C11 120.8(3) . .
C13 C12 H12 119.6 . .
C11 C12 H12 119.6 . .
C14 C13 C12 120.3(4) . .
C14 C13 H13 119.9 . .
C12 C13 H13 119.9 . .
O14 C14 C15 124.4(3) . .
O14 C14 C13 115.8(3) . .
C15 C14 C13 119.8(3) . .
C14 O14 C17 117.8(3) . .
C14 C15 C16 119.6(3) . .
C14 C15 H15 120.2 . .
C16 C15 H15 120.2 . .
C15 C16 C11 121.6(3) . .
C15 C16 H16 119.2 . .
C11 C16 H16 119.2 . .
O14 C17 C18 108.7(3) . .
O14 C17 H17A 110 . .
C18 C17 H17A 110 . .
O14 C17 H17B 110 . .
C18 C17 H17B 110 . .
H17A C17 H17B 108.3 . .
C19 C18 C17 125.8(4) . .
C19 C18 H18 117.1 . .
C17 C18 H18 117.1 . .
C18 C19 H19A 120 . .
C18 C19 H19B 120 . .
H19A C19 H19B 120 . .
O20 C20 C1 124.6(3) . .
O20 C20 C21 115.1(3) . .
C1 C20 C21 120.3(3) . .
C20 O20 Eu2 135.99(18) . .
C26 C21 C22 117.3(3) . .
C26 C21 C20 123.6(3) . .
C22 C21 C20 118.9(3) . .
C23 C22 C21 121.8(3) . .
C23 C22 H22 119.1 . .
C21 C22 H22 119.1 . .
C22 C23 C24 119.8(3) . .
C22 C23 H23 120.1 . .
C24 C23 H23 120.1 . .
O24 C24 C23 123.1(4) . .
O24 C24 C25 116.9(3) . .
C23 C24 C25 120.0(3) . .
C24 O24 C27 119.5(3) . .
C24 C25 C26 120.3(3) . .
C24 C25 H25 119.8 . .
C26 C25 H25 119.8 . .
C25 C26 C21 120.8(3) . .
C25 C26 H26 119.6 . .
C21 C26 H26 119.6 . .
O24 C27 C28' 134.7(18) . .
O24 C27 C28 108.3(5) . .
O24 C27 H27A 110 . .
C28 C27 H27A 110 . .
O24 C27 H27B 110 . .
C28 C27 H27B 110 . .
H27A C27 H27B 108.4 . .
O24 C27 H27C 103.5 . .
C28' C27 H27C 103.5 . .
C28 C27 H27C 120.2 . .
H27B C27 H27C 104.3 . .
O24 C27 H27D 103.5 . .
C28' C27 H27D 103.5 . .
C28 C27 H27D 114.2 . .
H27C C27 H27D 105.3 . .
C29 C28 C27 122.1(9) . .
C29 C28 H28 118.9 . .
C27 C28 H28 118.9 . .
C28 C29 H29A 120 . .
C28 C29 H29B 120 . .
H29A C29 H29B 120 . .
C29' C28' C27 138(3) . .
C29' C28' H28' 111.2 . .
C27 C28' H28' 111.2 . .
C28' C29' H29C 120 . .
C28' C29' H29D 120 . .
H29C C29' H29D 120 . .
C40 C2 C30 124.6(3) . .
C40 C2 H2 117.7 . .
C30 C2 H2 117.7 . .
O30 C30 C2 123.5(3) . .
O30 C30 C31 117.3(3) . .
C2 C30 C31 119.2(3) . .
C30 O30 Eu1 132.94(18) . .
C32 C31 C36 117.4(3) . .
C32 C31 C30 119.8(3) . .
C36 C31 C30 122.6(3) . .
C33 C32 C31 122.0(3) . .
C33 C32 H32 119 . .
C31 C32 H32 119 . .
C34 C33 C32 119.0(3) . .
C34 C33 H33 120.5 . .
C32 C33 H33 120.5 . .
C33 C34 C35 120.3(3) . .
C33 C34 O34 124.8(3) . .
C35 C34 O34 114.9(3) . .
C34 O34 C37 119.8(3) . .
C36 C35 C34 120.3(3) . .
C36 C35 H35 119.8 . .
C34 C35 H35 119.8 . .
C35 C36 C31 120.8(3) . .
C35 C36 H36 119.6 . .
C31 C36 H36 119.6 . .
O34 C37 C38 111.6(4) . .
O34 C37 H37A 109.3 . .
C38 C37 H37A 109.3 . .
O34 C37 H37B 109.3 . .
C38 C37 H37B 109.3 . .
H37A C37 H37B 108 . .
C39 C38 C37 123.9(5) . .
C39 C38 H38 118.1 . .
C37 C38 H38 118.1 . .
C38 C39 H39A 120 . .
C38 C39 H39B 120 . .
H39A C39 H39B 120 . .
O40 C40 C2 122.8(3) . .
O40 C40 C41 114.9(2) . .
C2 C40 C41 122.3(2) . .
C40 O40 Eu1 125.24(15) . .
C40 O40 Eu2 122.96(17) . .
Eu1 O40 Eu2 95.50(6) . .
C42 C41 C46 117.6(3) . .
C42 C41 C40 119.4(2) . .
C46 C41 C40 123.0(2) . .
C43 C42 C41 121.8(3) . .
C43 C42 H42 119.1 . .
C41 C42 H42 119.1 . .
C42 C43 C44 119.8(3) . .
C42 C43 H43 120.1 . .
C44 C43 H43 120.1 . .
O44 C44 C43 123.8(3) . .
O44 C44 C45 117.0(3) . .
C43 C44 C45 119.2(3) . .
C44 O44 C47 118.9(3) . .
C46 C45 C44 120.4(3) . .
C46 C45 H45 119.8 . .
C44 C45 H45 119.8 . .
C45 C46 C41 121.0(3) . .
C45 C46 H46 119.5 . .
C41 C46 H46 119.5 . .
O44 C47 C48' 111.3(10) . .
O44 C47 C48 109.8(7) . .
O44 C47 H47A 109.7 . .
C48' C47 H47A 111.9 . .
C48 C47 H47A 109.7 . .
O44 C47 H47B 109.7 . .
C48' C47 H47B 105.8 . .
C48 C47 H47B 109.7 . .
H47A C47 H47B 108.2 . .
O44 C47 H47C 109 . .
C48' C47 H47C 125.7 . .
C48 C47 H47C 124.2 . .
O44 C47 H47D 110.7 . .
C48' C47 H47D 89.9 . .
C48 C47 H47D 93.8 . .
H47C C47 H47D 108.1 . .
C49 C48 C47 128.9(13) . .
C49 C48 H48 115.5 . .
C47 C48 H48 115.5 . .
C48 C49 H49A 120 . .
C48 C49 H49B 120 . .
H49A C49 H49B 120 . .
C49' C48' C47 124.0(17) . .
C49' C48' H48' 118 . .
C47 C48' H48' 118 . .
C48' C49' H49C 120 . .
C48' C49' H49D 120 . .
H49C C49' H49D 120 . .
C60 C3 C50 124.5(2) . .
C60 C3 H3 117.8 . .
C50 C3 H3 117.8 . .
O50 C50 C3 123.7(3) . .
O50 C50 C51 116.1(3) . .
C3 C50 C51 120.2(2) . .
C50 O50 Eu1 137.64(18) . .
C52 C51 C56 117.4(3) . .
C52 C51 C50 118.5(2) . .
C56 C51 C50 124.0(3) . .
C53 C52 C51 121.3(3) . .
C53 C52 H52 119.3 . .
C51 C52 H52 119.3 . .
C54 C53 C52 120.3(3) . .
C54 C53 H53 119.8 . .
C52 C53 H53 119.8 . .
C55 C54 C53 119.5(3) . .
C55 C54 O54 125.4(3) . .
C53 C54 O54 115.0(3) . .
C54 O54 C57 117.6(3) . .
C54 C55 C56 120.3(3) . .
C54 C55 H55 119.9 . .
C56 C55 H55 119.9 . .
C55 C56 C51 121.1(3) . .
C55 C56 H56 119.4 . .
C51 C56 H56 119.4 . .
O54 C57 C58 107.0(4) . .
O54 C57 H57A 110.3 . .
C58 C57 H57A 110.3 . .
O54 C57 H57B 110.3 . .
C58 C57 H57B 110.3 . .
H57A C57 H57B 108.6 . .
C59 C58 C57 128.4(7) . .
C59 C58 H58 115.8 . .
C57 C58 H58 115.8 . .
C59' C58 H58' 101.5 . .
C57 C58 H58' 103.7 . .
C58 C59 H59A 120 . .
C58 C59 H59B 120 . .
H59A C59 H59B 120 . .
C58 C59' H59C 120 . .
C58 C59' H59D 120 . .
H59C C59' H59D 120 . .
O60 C60 C3 124.1(3) . .
O60 C60 C61 115.5(3) . .
C3 C60 C61 120.3(2) . .
C60 O60 Eu1 136.94(18) . .
C62 C61 C66 117.5(3) . .
C62 C61 C60 119.3(3) . .
C66 C61 C60 123.2(3) . .
C61 C62 C63 121.9(3) . .
C61 C62 H62 119.1 . .
C63 C62 H62 119.1 . .
C64 C63 C62 119.1(4) . .
C64 C63 H63 120.5 . .
C62 C63 H63 120.5 . .
O64 C64 C65 115.8(4) . .
O64 C64 C63 124.2(4) . .
C65 C64 C63 120.0(4) . .
C66 C65 C64 120.1(4) . .
C66 C65 H65 120 . .
C64 C65 H65 120 . .
C65 C66 C61 121.2(4) . .
C65 C66 H66 119.4 . .
C61 C66 H66 119.4 . .
C67 O64 C64 118.8(4) . .
O64 C67 C68 103.2(4) . .
O64 C67 H67A 111.1 . .
C68 C67 H67A 111.1 . .
O64 C67 H67B 111.1 . .
C68 C67 H67B 111.1 . .
H67A C67 H67B 109.1 . .
C69 C68 C67 121.0(6) . .
C69 C68 H68 119.5 . .
C67 C68 H68 119.5 . .
C68 C69 H69A 120 . .
C68 C69 H69B 120 . .
H69A C69 H69B 120 . .
C70 C4 C80 120.9(7) . .
C70 C4 H4 119.6 . .
C80 C4 H4 119.6 . .
O70 C70 C4 128.1(7) . .
O70 C70 C71 113.1(7) . .
C4 C70 C71 118.8(6) . .
C70 O70 Eu3 127.5(7) . .
C76 C71 C72 117.4(6) . .
C76 C71 C70 124.1(7) . .
C72 C71 C70 118.4(6) . .
C73 C72 C71 121.1(6) . .
C73 C72 H72 119.5 . .
C71 C72 H72 119.5 . .
C72 C73 C74 121.7(7) . .
C72 C73 H73 119.1 . .
C74 C73 H73 119.1 . .
O74 C74 C75 126.1(7) . .
O74 C74 C73 116.1(7) . .
C75 C74 C73 117.8(6) . .
C74 O74 C77 119.8(6) . .
C74 C75 C76 120.5(8) . .
C74 C75 H75 119.8 . .
C76 C75 H75 119.8 . .
C71 C76 C75 121.5(7) . .
C71 C76 H76 119.3 . .
C75 C76 H76 119.3 . .
O74 C77 C78 113.2(8) . .
O74 C77 H77A 108.9 . .
C78 C77 H77A 108.9 . .
O74 C77 H77B 108.9 . .
C78 C77 H77B 108.9 . .
H77A C77 H77B 107.8 . .
C79 C78 C77 124.9(12) . .
C79 C78 H78 117.5 . .
C77 C78 H78 117.5 . .
C78 C79 H79A 120 . .
C78 C79 H79B 120 . .
H79A C79 H79B 120 . .
O80 C80 C4 125.1(7) . .
O80 C80 C81 116.3(6) . .
C4 C80 C81 118.5(6) . .
C80 O80 Eu3 131.1(5) . .
C82 C81 C86 115.6(7) . .
C82 C81 C80 119.5(6) . .
C86 C81 C80 124.8(6) . .
C83 C82 C81 123.4(8) . .
C83 C82 H82 118.3 . .
C81 C82 H82 118.3 . .
C84 C83 C82 118.2(7) . .
C84 C83 H83 120.9 . .
C82 C83 H83 120.9 . .
O84 C84 C83 121.7(7) . .
O84 C84 C85 118.2(7) . .
C83 C84 C85 119.9(8) . .
C84 O84 C87 121.7(8) . .
C86 C85 C84 120.5(8) . .
C86 C85 H85 119.7 . .
C84 C85 H85 119.7 . .
C85 C86 C81 122.3(7) . .
C85 C86 H86 118.9 . .
C81 C86 H86 118.9 . .
O84 C87 C88 104.7(8) . .
O84 C87 H87A 110.8 . .
C88 C87 H87A 110.8 . .
O84 C87 H87B 110.8 . .
C88 C87 H87B 110.8 . .
H87A C87 H87B 108.9 . .
C89 C88 C87 124.1(13) . .
C89 C88 H88 118 . .
C87 C88 H88 118 . .
C88 C89 H89A 120 . .
C88 C89 H89B 120 . .
H89A C89 H89B 120 . .
C100 C5 C90 125.0(2) . .
C100 C5 H5 117.5 . .
C90 C5 H5 117.5 . .
O90 C90 C5 124.3(3) . .
O90 C90 C91 115.9(3) . .
C5 C90 C91 119.8(2) . .
C90 O90 Eu2 132.71(18) . .
C92 C91 C96 118.8(3) . .
C92 C91 C90 123.1(3) . .
C96 C91 C90 118.0(3) . .
C91 C92 C93 121.0(3) . .
C91 C92 H92 119.5 . .
C93 C92 H92 119.5 . .
C94 C93 C92 119.1(3) . .
C94 C93 H93 120.5 . .
C92 C93 H93 120.5 . .
O94 C94 C93 124.9(3) . .
O94 C94 C95 114.3(4) . .
C93 C94 C95 120.8(3) . .
C94 O94 C97 117.5(4) . .
C96 C95 C94 119.6(4) . .
C96 C95 H95 120.2 . .
C94 C95 H95 120.2 . .
C95 C96 C91 120.7(3) . .
C95 C96 H96 119.7 . .
C91 C96 H96 119.7 . .
O94 C97 C98 101.1(4) . .
O94 C97 H97A 111.6 . .
C98 C97 H97A 111.6 . .
O94 C97 H97B 111.6 . .
C98 C97 H97B 111.6 . .
H97A C97 H97B 109.4 . .
C99 C98 C97 124.1(7) . .
C99 C98 H98 118 . .
C97 C98 H98 118 . .
C98 C99 H99A 120 . .
C98 C99 H99B 120 . .
H99A C99 H99B 120 . .
O100 C100 C5 123.1(2) . .
O100 C100 C101 116.1(2) . .
C5 C100 C101 120.8(2) . .
C100 O100 Eu2 123.83(15) . .
C100 O100 Eu1 126.81(15) . 2
Eu2 O100 Eu1 95.87(6) . 2
C102 C101 C106 117.4(3) . .
C102 C101 C100 119.8(3) . .
C106 C101 C100 122.8(3) . .
C101 C102 C103 122.1(3) . .
C101 C102 H102 119 . .
C103 C102 H102 119 . .
C104 C103 C102 119.4(3) . .
C104 C103 H103 120.3 . .
C102 C103 H103 120.3 . .
C103 C104 O104 123.9(4) . .
C103 C104 C105 119.8(3) . .
O104 C104 C105 116.3(3) . .
C104 O104 C107 118.6(3) . .
C104 C105 C106 120.7(4) . .
C104 C105 H105 119.7 . .
C106 C105 H105 119.7 . .
C105 C106 C101 120.6(4) . .
C105 C106 H106 119.7 . .
C101 C106 H106 119.7 . .
O104 C107 C108 100.1(9) . .
O104 C107 C10A 113.7(6) . .
O104 C107 H10A 111.8 . .
C108 C107 H10A 111.8 . .
C10A C107 H10A 111.8 . .
O104 C107 H10B 111.8 . .
C108 C107 H10B 111.8 . .
C10A C107 H10B 97.4 . .
H10A C107 H10B 109.5 . .
O104 C107 H10F 110.2 . .
C108 C107 H10F 97.1 . .
C10A C107 H10F 99.5 . .
O104 C107 H10G 112.8 . .
C108 C107 H10G 126.2 . .
C10A C107 H10G 110.8 . .
H10F C107 H10G 109 . .
C109 C108 C107 140.7(19) . .
C109 C108 H108 109.7 . .
C107 C108 H108 109.7 . .
C108 C109 H10C 120 . .
C108 C109 H10D 120 . .
H10C C109 H10D 120 . .
C10B C10A C107 116.0(9) . .
C10B C10A H10E 122 . .
C107 C10A H10E 122 . .
C10A C10B H10H 120 . .
C10A C10B H10I 120 . .
H10H C10B H10I 120 . .
C110 C6 C120 123.4(4) . .
C110 C6 H6 118.3 . .
C120 C6 H6 118.3 . .
O110 C110 C6 125.0(5) . .
O110 C110 C111 114.5(5) . .
C6 C110 C111 120.5(4) . .
C110 O110 Eu3 128.4(5) . .
C116 C111 C112 117.7(4) . .
C116 C111 C110 118.0(4) . .
C112 C111 C110 124.2(4) . .
C113 C112 C111 120.7(4) . .
C113 C112 H112 119.6 . .
C111 C112 H112 119.6 . .
C114 C113 C112 120.5(5) . .
C114 C113 H113 119.7 . .
C112 C113 H113 119.7 . .
C113 C114 O114 124.6(5) . .
C113 C114 C115 119.2(5) . .
O114 C114 C115 116.2(5) . .
C114 O114 C117 117.7(4) . .
C116 C115 C114 120.1(5) . .
C116 C115 H115 119.9 . .
C114 C115 H115 119.9 . .
C115 C116 C111 121.6(5) . .
C115 C116 H116 119.2 . .
C111 C116 H116 119.2 . .
O114 C117 C118 106.3(5) . .
O114 C117 H11A 110.5 . .
C118 C117 H11A 110.5 . .
O114 C117 H11B 110.5 . .
C118 C117 H11B 110.5 . .
H11A C117 H11B 108.7 . .
C119 C118 C117 123.4(8) . .
C119 C118 H118 118.3 . .
C117 C118 H118 118.3 . .
C118 C119 H11C 120 . .
C118 C119 H11D 120 . .
H11C C119 H11D 120 . .
O120 C120 C6 125.3(5) . .
O120 C120 C121 115.3(5) . .
C6 C120 C121 119.2(4) . .
C120 O120 Eu3 129.8(4) . .
C122 C121 C126 117.9(5) . .
C122 C121 C120 119.3(5) . .
C126 C121 C120 122.8(5) . .
C123 C122 C121 121.4(5) . .
C123 C122 H122 119.3 . .
C121 C122 H122 119.3 . .
C122 C123 C124 119.2(5) . .
C122 C123 H123 120.4 . .
C124 C123 H123 120.4 . .
C125 C124 C123 120.3(5) . .
C125 C124 O124 124.6(5) . .
C123 C124 O124 115.0(5) . .
C124 O124 C127 116.5(5) . .
C126 C125 C124 119.8(5) . .
C126 C125 H125 120.1 . .
C124 C125 H125 120.1 . .
C125 C126 C121 121.1(5) . .
C125 C126 H126 119.5 . .
C121 C126 H126 119.5 . .
O124 C127 C128 111.1(6) . .
O124 C127 H12A 109.4 . .
C128 C127 H12A 109.4 . .
O124 C127 H12B 109.4 . .
C128 C127 H12B 109.4 . .
H12A C127 H12B 108 . .
C129 C128 C127 128.5(7) . .
C129 C128 H128 115.8 . .
C127 C128 H128 115.8 . .
C128 C129 H12C 120 . .
C128 C129 H12D 120 . .
H12C C129 H12D 120 . .
C216 C211 C212 119.3(5) . .
C216 C211 C217 119.6(7) . .
C212 C211 C217 121.0(6) . .
C213 C212 C211 116.1(6) . .
C213 C212 H212 122 . .
C211 C212 H212 122 . .
C212 C213 C214 126.7(7) . .
C212 C213 H213 116.6 . .
C214 C213 H213 116.6 . .
C213 C214 C215 115.1(7) . .
C213 C214 H214 122.4 . .
C215 C214 H214 122.4 . .
C214 C215 C216 123.5(6) . .
C214 C215 H215 118.3 . .
C216 C215 H215 118.3 . .
C215 C216 C211 118.2(6) . .
C215 C216 H216 120.9 . .
C211 C216 H216 120.9 . .
C211 C217 H21A 109.5 . .
C211 C217 H21B 109.5 . .
H21A C217 H21B 109.5 . .
C211 C217 H21C 109.5 . .
H21A C217 H21C 109.5 . .
H21B C217 H21C 109.5 . .
C316 C311 C312 120.5(6) . .
C316 C311 C317 122.2(7) . .
C312 C311 C317 117.2(6) . .
C313 C312 C311 121.4(7) . .
C313 C312 H312 119.3 . .
C311 C312 H312 119.3 . .
C312 C313 C314 115.9(7) . .
C312 C313 H313 122.1 . .
C314 C313 H313 122.1 . .
C315 C314 C313 124.5(7) . .
C315 C314 H314 117.8 . .
C313 C314 H314 117.8 . .
C314 C315 C316 118.4(7) . .
C314 C315 H315 120.8 . .
C316 C315 H315 120.8 . .
C311 C316 C315 119.2(7) . .
C311 C316 H316 120.4 . .
C315 C316 H316 120.4 . .
C311 C317 H31A 109.5 . .
C311 C317 H31B 109.5 . .
H31A C317 H31B 109.5 . .
C311 C317 H31C 109.5 . .
H31A C317 H31C 109.5 . .
H31B C317 H31C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O50 2.3190(18) .
Eu1 O60 2.3265(18) .
Eu1 O3 2.3599(17) .
Eu1 O40 2.3721(18) .
Eu1 O2 2.3843(17) .
Eu1 O30 2.4050(19) .
Eu1 O100 2.4832(18) 2
Eu1 O1 2.6487(4) .
Eu2 O10 2.3078(18) .
Eu2 O20 2.3294(19) .
Eu2 O2 2.3509(17) .
Eu2 O90 2.3555(19) .
Eu2 O100 2.3994(17) .
Eu2 O3 2.3997(18) 2
Eu2 O40 2.4928(18) .
Eu2 O1 2.5288(4) .
Eu3 O70 2.331(8) .
Eu3 O70 2.331(8) 2
Eu3 O80 2.335(8) .
Eu3 O80 2.335(8) 2
Eu3 O110 2.355(6) .
Eu3 O110 2.355(6) 2
Eu3 O120 2.393(5) 2
Eu3 O120 2.393(5) .
Eu3 O3 2.4433(17) 2
Eu3 O3 2.4433(17) .
Eu3 O2 2.4674(17) 2
Eu3 O2 2.4674(17) .
O1 Eu2 2.5288(4) 2
O1 Eu1 2.6487(4) 2
O1 H1O 0.807 .
O2 H2O 1 .
O3 Eu2 2.3997(18) 2
O3 H3O 1 .
C1 C20 1.401(4) .
C1 C10 1.414(5) .
C1 H1 0.95 .
C10 O10 1.277(3) .
C10 C11 1.492(4) .
C11 C12 1.386(5) .
C11 C16 1.391(4) .
C12 C13 1.384(5) .
C12 H12 0.95 .
C13 C14 1.383(5) .
C13 H13 0.95 .
C14 O14 1.372(4) .
C14 C15 1.373(5) .
O14 C17 1.417(4) .
C15 C16 1.385(4) .
C15 H15 0.95 .
C16 H16 0.95 .
C17 C18 1.471(5) .
C17 H17A 0.99 .
C17 H17B 0.99 .
C18 C19 1.303(6) .
C18 H18 0.95 .
C19 H19A 0.95 .
C19 H19B 0.95 .
C20 O20 1.269(3) .
C20 C21 1.492(4) .
C21 C26 1.399(4) .
C21 C22 1.406(4) .
C22 C23 1.378(5) .
C22 H22 0.95 .
C23 C24 1.379(5) .
C23 H23 0.95 .
C24 O24 1.368(4) .
C24 C25 1.385(6) .
O24 C27 1.450(7) .
C25 C26 1.389(5) .
C25 H25 0.95 .
C26 H26 0.95 .
C27 C28' 1.483(17) .
C27 C28 1.551(8) .
C27 H27A 0.99 .
C27 H27B 0.99 .
C27 H27C 0.99 .
C27 H27D 0.99 .
C28 C29 1.143(10) .
C28 H28 0.95 .
C29 H29A 0.95 .
C29 H29B 0.95 .
C28' C29' 1.243(18) .
C28' H28' 0.95 .
C29' H29C 0.95 .
C29' H29D 0.95 .
C2 C40 1.376(4) .
C2 C30 1.430(4) .
C2 H2 0.95 .
C30 O30 1.251(3) .
C30 C31 1.493(4) .
C31 C32 1.393(4) .
C31 C36 1.400(4) .
C32 C33 1.381(4) .
C32 H32 0.95 .
C33 C34 1.380(5) .
C33 H33 0.95 .
C34 C35 1.380(5) .
C34 O34 1.383(4) .
O34 C37 1.445(5) .
C35 C36 1.377(5) .
C35 H35 0.95 .
C36 H36 0.95 .
C37 C38 1.495(7) .
C37 H37A 0.99 .
C37 H37B 0.99 .
C38 C39 1.312(7) .
C38 H38 0.95 .
C39 H39A 0.95 .
C39 H39B 0.95 .
C40 O40 1.307(3) .
C40 C41 1.495(4) .
C41 C42 1.391(4) .
C41 C46 1.402(4) .
C42 C43 1.385(4) .
C42 H42 0.95 .
C43 C44 1.387(5) .
C43 H43 0.95 .
C44 O44 1.370(4) .
C44 C45 1.396(5) .
O44 C47 1.392(5) .
C45 C46 1.379(5) .
C45 H45 0.95 .
C46 H46 0.95 .
C47 C48' 1.468(14) .
C47 C48 1.501(11) .
C47 H47A 0.99 .
C47 H47B 0.99 .
C47 H47C 0.9923 .
C47 H47D 0.9948 .
C48 C49 1.299(14) .
C48 H48 0.95 .
C49 H49A 0.95 .
C49 H49B 0.95 .
C48' C49' 1.254(17) .
C48' H48' 0.95 .
C49' H49C 0.95 .
C49' H49D 0.95 .
C3 C60 1.395(4) .
C3 C50 1.408(4) .
C3 H3 0.95 .
C50 O50 1.268(3) .
C50 C51 1.496(4) .
C51 C52 1.389(4) .
C51 C56 1.403(4) .
C52 C53 1.388(5) .
C52 H52 0.95 .
C53 C54 1.383(5) .
C53 H53 0.95 .
C54 C55 1.375(5) .
C54 O54 1.399(4) .
O54 C57 1.410(5) .
C55 C56 1.390(5) .
C55 H55 0.95 .
C56 H56 0.95 .
C57 C58 1.510(7) .
C57 H57A 0.99 .
C57 H57B 0.99 .
C58 C59' 1.079(12) .
C58 C59 1.246(9) .
C58 H58 0.95 .
C58 H58' 0.9556 .
C59 H59A 0.95 .
C59 H59B 0.95 .
C59' H59C 0.95 .
C59' H59D 0.95 .
C60 O60 1.272(3) .
C60 C61 1.498(4) .
C61 C62 1.375(5) .
C61 C66 1.396(4) .
C62 C63 1.384(5) .
C62 H62 0.95 .
C63 C64 1.380(6) .
C63 H63 0.95 .
C64 O64 1.373(4) .
C64 C65 1.374(6) .
C65 C66 1.368(5) .
C65 H65 0.95 .
C66 H66 0.95 .
O64 C67 1.373(6) .
C67 C68 1.553(7) .
C67 H67A 0.99 .
C67 H67B 0.99 .
C68 C69 1.238(4) .
C68 H68 0.95 .
C69 H69A 0.95 .
C69 H69B 0.95 .
C4 C70 1.408(11) .
C4 C80 1.425(9) .
C4 H4 0.95 .
C70 O70 1.277(10) .
C70 C71 1.514(8) .
C71 C76 1.385(9) .
C71 C72 1.390(9) .
C72 C73 1.369(8) .
C72 H72 0.95 .
C73 C74 1.394(9) .
C73 H73 0.95 .
C74 O74 1.368(7) .
C74 C75 1.376(9) .
O74 C77 1.398(9) .
C75 C76 1.401(9) .
C75 H75 0.95 .
C76 H76 0.95 .
C77 C78 1.516(12) .
C77 H77A 0.99 .
C77 H77B 0.99 .
C78 C79 1.275(11) .
C78 H78 0.95 .
C79 H79A 0.95 .
C79 H79B 0.95 .
C80 O80 1.267(9) .
C80 C81 1.490(8) .
C81 C82 1.386(9) .
C81 C86 1.389(9) .
C82 C83 1.379(10) .
C82 H82 0.95 .
C83 C84 1.371(9) .
C83 H83 0.95 .
C84 O84 1.365(10) .
C84 C85 1.380(9) .
O84 C87 1.410(10) .
C85 C86 1.350(10) .
C85 H85 0.95 .
C86 H86 0.95 .
C87 C88 1.445(12) .
C87 H87A 0.99 .
C87 H87B 0.99 .
C88 C89 1.265(11) .
C88 H88 0.95 .
C89 H89A 0.95 .
C89 H89B 0.95 .
C5 C100 1.390(4) .
C5 C90 1.428(4) .
C5 H5 0.95 .
C90 O90 1.256(3) .
C90 C91 1.490(4) .
C91 C92 1.385(4) .
C91 C96 1.390(4) .
C92 C93 1.394(4) .
C92 H92 0.95 .
C93 C94 1.376(5) .
C93 H93 0.95 .
C94 O94 1.374(4) .
C94 C95 1.387(5) .
O94 C97 1.432(5) .
C95 C96 1.381(5) .
C95 H95 0.95 .
C96 H96 0.95 .
C97 C98 1.592(7) .
C97 H97A 0.99 .
C97 H97B 0.99 .
C98 C99 1.227(4) .
C98 H98 0.95 .
C99 H99A 0.95 .
C99 H99B 0.95 .
C100 O100 1.305(3) .
C100 C101 1.478(4) .
O100 Eu1 2.4832(18) 2
C101 C102 1.391(4) .
C101 C106 1.399(4) .
C102 C103 1.393(4) .
C102 H102 0.95 .
C103 C104 1.374(5) .
C103 H103 0.95 .
C104 O104 1.374(4) .
C104 C105 1.384(6) .
O104 C107 1.406(6) .
C105 C106 1.388(5) .
C105 H105 0.95 .
C106 H106 0.95 .
C107 C108 1.491(13) .
C107 C10A 1.522(9) .
C107 H10A 0.99 .
C107 H10B 0.99 .
C107 H10F 0.9956 .
C107 H10G 0.9946 .
C108 C109 1.175(14) .
C108 H108 0.95 .
C109 H10C 0.95 .
C109 H10D 0.95 .
C10A C10B 1.326(12) .
C10A H10E 0.95 .
C10B H10H 0.95 .
C10B H10I 0.95 .
C6 C110 1.411(7) .
C6 C120 1.422(6) .
C6 H6 0.95 .
C110 O110 1.275(7) .
C110 C111 1.496(6) .
C111 C116 1.389(7) .
C111 C112 1.396(6) .
C112 C113 1.394(6) .
C112 H112 0.95 .
C113 C114 1.368(7) .
C113 H113 0.95 .
C114 O114 1.374(6) .
C114 C115 1.397(7) .
O114 C117 1.436(6) .
C115 C116 1.372(7) .
C115 H115 0.95 .
C116 H116 0.95 .
C117 C118 1.509(8) .
C117 H11A 0.99 .
C117 H11B 0.99 .
C118 C119 1.284(9) .
C118 H118 0.95 .
C119 H11C 0.95 .
C119 H11D 0.95 .
C120 O120 1.278(6) .
C120 C121 1.503(7) .
C121 C122 1.396(7) .
C121 C126 1.398(7) .
C122 C123 1.385(6) .
C122 H122 0.95 .
C123 C124 1.387(7) .
C123 H123 0.95 .
C124 C125 1.385(8) .
C124 O124 1.397(7) .
O124 C127 1.437(7) .
C125 C126 1.378(7) .
C125 H125 0.95 .
C126 H126 0.95 .
C127 C128 1.484(9) .
C127 H12A 0.99 .
C127 H12B 0.99 .
C128 C129 1.279(8) .
C128 H128 0.95 .
C129 H12C 0.95 .
C129 H12D 0.95 .
C211 C216 1.384(6) .
C211 C212 1.420(6) .
C211 C217 1.467(7) .
C212 C213 1.342(7) .
C212 H212 0.95 .
C213 C214 1.345(7) .
C213 H213 0.95 .
C214 C215 1.358(7) .
C214 H214 0.95 .
C215 C216 1.380(7) .
C215 H215 0.95 .
C216 H216 0.95 .
C217 H21A 0.98 .
C217 H21B 0.98 .
C217 H21C 0.98 .
C311 C316 1.339(7) .
C311 C312 1.432(7) .
C311 C317 1.522(7) .
C312 C313 1.366(7) .
C312 H312 0.95 .
C313 C314 1.386(7) .
C313 H313 0.95 .
C314 C315 1.362(7) .
C314 H314 0.95 .
C315 C316 1.418(7) .
C315 H315 0.95 .
C316 H316 0.95 .
C317 H31A 0.98 .
C317 H31B 0.98 .
C317 H31C 0.98 .
