#------------------------------------------------------------------------------
#$Date: 2016-03-25 16:33:36 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179976 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/70/7027073.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_7027073
loop_
_publ_author_name
'Chen, Bang-Lin'
'Mok, Kum-Fun'
'Ng, Siu-Choon'
_publ_section_title
;
 Structural diversity in silver(I) and gold(I) complexes with
 2,5-bis(diphenylphosphinomethyl)thiophene
;
_journal_issue                   23
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              4035
_journal_paper_doi               10.1039/a806503i
_journal_year                    1998
_chemical_formula_sum            'C142 H124 Ag2 B2 N2 P6 S3'
_chemical_formula_weight         2377.79
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 127.974(9)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   37.999(4)
_cell_length_b                   14.5278(13)
_cell_length_c                   28.107(3)
_cell_measurement_temperature    293(2)
_cell_volume                     12231(3)
_computing_cell_refinement       'Siemens XSCANS'
_computing_data_collection       'Siemens XSCANS'
_computing_data_reduction        'Siemens SHELXTL'
_computing_molecular_graphics    'Siemens SHELXTL'
_computing_publication_material  'Siemens SHELXTL'
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device       'Siemens P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0249
_diffrn_reflns_av_sigmaI/netI    0.0319
_diffrn_reflns_limit_h_max       45
_diffrn_reflns_limit_h_min       -45
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            31865
_diffrn_reflns_theta_max         25.38
_diffrn_reflns_theta_min         1.84
_exptl_absorpt_coefficient_mu    0.502
_exptl_absorpt_correction_T_max  0.935
_exptl_absorpt_correction_T_min  0.786
_exptl_absorpt_correction_type   Sadabs
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    1.291
_exptl_crystal_density_meas      1.24
_exptl_crystal_density_method    Flotation
_exptl_crystal_description       Prism
_exptl_crystal_F_000             4928
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.23
_refine_diff_density_max         0.571
_refine_diff_density_min         -0.600
_refine_diff_density_rms         0.049
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.057
_refine_ls_goodness_of_fit_obs   1.061
_refine_ls_matrix_type           full
_refine_ls_number_parameters     693
_refine_ls_number_reflns         11175
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.057
_refine_ls_restrained_S_obs      1.061
_refine_ls_R_factor_all          0.0525
_refine_ls_R_factor_obs          0.0365
_refine_ls_shift/esd_max         0.001
_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0386P)²+17.2884P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0979
_refine_ls_wR_factor_obs         0.0869
_reflns_number_observed          8890
_reflns_number_total             11175
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            806503isup1.cif
_cod_data_source_block           mkf26a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0386P)^2^+17.2884P] where P=(Fo^2^+2Fc^2^)/3'
was changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0386P)^2^+17.2884P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        12231.4(21)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7027073
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.589754(7) 0.956893(14) 0.862467(9) 0.04484(8) Uani 1 d .
P2 P 0.61729(2) 0.83190(5) 0.82980(3) 0.0433(2) Uani 1 d .
P3 P 0.60302(2) 1.12174(5) 0.84915(3) 0.0424(2) Uani 1 d .
P4 P 0.57121(3) 0.90930(5) 0.93137(3) 0.0430(2) Uani 1 d .
S5 S 0.47884(2) 1.01622(5) 0.79091(3) 0.0428(2) Uani 1 d .
S6 S 0.5000 0.82105(6) 0.7500 0.0431(2) Uani 1 d S
C1 C 0.65523(9) 0.8674(2) 0.81405(13) 0.0479(7) Uani 1 d .
C2 C 0.64237(12) 0.9381(2) 0.7735(2) 0.0687(10) Uani 1 d .
H2A H 0.61480(12) 0.9662(2) 0.7551(2) 0.082 Uiso 1 calc R
C3 C 0.66968(14) 0.9675(3) 0.7600(2) 0.0784(11) Uani 1 d .
H3A H 0.66043(14) 1.0150(3) 0.7324(2) 0.094 Uiso 1 calc R
C4 C 0.70997(14) 0.9277(3) 0.7868(2) 0.0873(12) Uani 1 d .
H4A H 0.72852(14) 0.9479(3) 0.7778(2) 0.105 Uiso 1 calc R
C5 C 0.72332(14) 0.8579(4) 0.8268(2) 0.104(2) Uani 1 d .
H5A H 0.75102(14) 0.8305(4) 0.8451(2) 0.125 Uiso 1 calc R
C6 C 0.69615(12) 0.8273(3) 0.8406(2) 0.0804(12) Uani 1 d .
H6A H 0.70558(12) 0.7794(3) 0.8679(2) 0.096 Uiso 1 calc R
C7 C 0.64706(10) 0.7440(2) 0.88802(13) 0.0487(7) Uani 1 d .
C8 C 0.64656(12) 0.6511(2) 0.8768(2) 0.0635(9) Uani 1 d .
H8A H 0.63028(12) 0.6302(2) 0.8372(2) 0.076 Uiso 1 calc R
C9 C 0.67003(14) 0.5894(3) 0.9239(2) 0.0823(11) Uani 1 d .
H9A H 0.66939(14) 0.5271(3) 0.9158(2) 0.099 Uiso 1 calc R
C10 C 0.6939(2) 0.6185(3) 0.9815(2) 0.0957(14) Uani 1 d .
H10A H 0.7098(2) 0.5764(3) 1.0130(2) 0.115 Uiso 1 calc R
C11 C 0.6948(2) 0.7092(3) 0.9935(2) 0.102(2) Uani 1 d .
H11A H 0.7112(2) 0.7291(3) 1.0333(2) 0.122 Uiso 1 calc R
C12 C 0.67145(13) 0.7724(3) 0.9469(2) 0.0787(11) Uani 1 d .
H12A H 0.67229(13) 0.8345(3) 0.9556(2) 0.094 Uiso 1 calc R
C13 C 0.57483(10) 0.7689(2) 0.75957(13) 0.0524(7) Uani 1 d .
H13A H 0.56489(10) 0.8079(2) 0.72538(13) 0.063 Uiso 1 calc R
H13B H 0.58868(10) 0.7148(2) 0.75720(13) 0.063 Uiso 1 calc R
C14 C 0.53496(9) 0.7391(2) 0.75451(12) 0.0479(7) Uani 1 d .
C15 C 0.51946(11) 0.6547(2) 0.7523(2) 0.0710(10) Uani 1 d .
H15A H 0.53337(11) 0.6009(2) 0.7538(2) 0.085 Uiso 1 calc R
C16 C 0.58486(10) 0.7911(2) 0.95970(13) 0.0491(7) Uani 1 d .
C17 C 0.56865(12) 0.7198(2) 0.91859(15) 0.0630(9) Uani 1 d .
H17A H 0.55135(12) 0.7329(2) 0.87757(15) 0.076 Uiso 1 calc R
C18 C 0.57787(15) 0.6294(3) 0.9377(2) 0.0829(12) Uani 1 d .
H18A H 0.56685(15) 0.5819(3) 0.9097(2) 0.100 Uiso 1 calc R
C19 C 0.6034(2) 0.6098(3) 0.9983(2) 0.0935(14) Uani 1 d .
H19A H 0.6091(2) 0.5489(3) 1.0112(2) 0.112 Uiso 1 calc R
C20 C 0.6204(2) 0.6794(3) 1.0399(2) 0.0941(15) Uani 1 d .
H20A H 0.6381(2) 0.6659(3) 1.0809(2) 0.113 Uiso 1 calc R
C21 C 0.61109(13) 0.7699(2) 1.02055(15) 0.0715(10) Uani 1 d .
H21A H 0.62258(13) 0.8172(2) 1.04880(15) 0.086 Uiso 1 calc R
C22 C 0.59624(10) 0.9793(2) 0.99877(12) 0.0452(6) Uani 1 d .
C23 C 0.57869(12) 0.9902(3) 1.0288(2) 0.0692(9) Uani 1 d .
H23A H 0.55107(12) 0.9644(3) 1.0130(2) 0.083 Uiso 1 calc R
C24 C 0.60139(15) 1.0389(3) 1.0824(2) 0.0799(11) Uani 1 d .
H24A H 0.58879(15) 1.0461(3) 1.1020(2) 0.096 Uiso 1 calc R
C25 C 0.64178(14) 1.0762(3) 1.1065(2) 0.0761(11) Uani 1 d .
H25A H 0.65713(14) 1.1082(3) 1.1428(2) 0.091 Uiso 1 calc R
C26 C 0.65985(15) 1.0666(3) 1.0775(2) 0.0959(14) Uani 1 d .
H26A H 0.68777(15) 1.0915(3) 1.0940(2) 0.115 Uiso 1 calc R
C27 C 0.63660(12) 1.0199(3) 1.0233(2) 0.0785(11) Uani 1 d .
H27A H 0.64867(12) 1.0158(3) 1.0029(2) 0.094 Uiso 1 calc R
C28 C 0.51056(9) 0.9113(2) 0.89341(13) 0.0497(7) Uani 1 d .
H28A H 0.49670(9) 0.8591(2) 0.86623(13) 0.060 Uiso 1 calc R
H28B H 0.50605(9) 0.9042(2) 0.92363(13) 0.060 Uiso 1 calc R
C29 C 0.48776(9) 0.9973(2) 0.85847(12) 0.0438(6) Uani 1 d .
C30 C 0.47217(11) 1.0695(2) 0.87089(14) 0.0587(8) Uani 1 d .
H30A H 0.47415(11) 1.0728(2) 0.90551(14) 0.070 Uiso 1 calc R
C31 C 0.60240(9) 1.2068(2) 0.89624(12) 0.0446(6) Uani 1 d .
C32 C 0.62553(12) 1.2897(2) 0.9127(2) 0.0688(10) Uani 1 d .
H32A H 0.64358(12) 1.3019(2) 0.9015(2) 0.083 Uiso 1 calc R
C33 C 0.62180(14) 1.3542(3) 0.9457(2) 0.0822(12) Uani 1 d .
H33A H 0.63735(14) 1.4095(3) 0.9567(2) 0.099 Uiso 1 calc R
C34 C 0.59540(14) 1.3368(3) 0.9621(2) 0.0781(11) Uani 1 d .
H34A H 0.59314(14) 1.3802(3) 0.9843(2) 0.094 Uiso 1 calc R
C35 C 0.57220(14) 1.2562(3) 0.9462(2) 0.0789(11) Uani 1 d .
H35A H 0.55417(14) 1.2449(3) 0.9575(2) 0.095 Uiso 1 calc R
C36 C 0.57565(11) 1.1910(2) 0.9129(2) 0.0589(8) Uani 1 d .
H36A H 0.55973(11) 1.1363(2) 0.9019(2) 0.071 Uiso 1 calc R
C37 C 0.65756(10) 1.1355(2) 0.86749(13) 0.0476(7) Uani 1 d .
C38 C 0.66540(12) 1.1648(3) 0.82863(15) 0.0671(9) Uani 1 d .
H38A H 0.64132(12) 1.1804(3) 0.78935(15) 0.081 Uiso 1 calc R
C39 C 0.70788(14) 1.1717(3) 0.8460(2) 0.0798(11) Uani 1 d .
H39A H 0.71201(14) 1.1908(3) 0.8181(2) 0.096 Uiso 1 calc R
C40 C 0.74361(13) 1.1511(3) 0.9027(2) 0.0878(13) Uani 1 d .
H40A H 0.77238(13) 1.1580(3) 0.9147(2) 0.105 Uiso 1 calc R
C41 C 0.73682(14) 1.1202(5) 0.9420(2) 0.139(3) Uani 1 d .
H41A H 0.76113(14) 1.1046(5) 0.9812(2) 0.167 Uiso 1 calc R
C42 C 0.69378(13) 1.1116(4) 0.9242(2) 0.113(2) Uani 1 d .
H42A H 0.68965(13) 1.0891(4) 0.9515(2) 0.136 Uiso 1 calc R
C43 C 0.56301(10) 1.1776(2) 0.77483(12) 0.0503(7) Uani 1 d .
H43A H 0.53717(10) 1.1968(2) 0.77164(12) 0.060 Uiso 1 calc R
H43B H 0.57690(10) 1.2328(2) 0.77382(12) 0.060 Uiso 1 calc R
C44 C 0.54706(9) 1.1209(2) 0.72056(12) 0.0442(6) Uani 1 d .
C45 C 0.54743(11) 1.1395(2) 0.67348(14) 0.0595(8) Uani 1 d .
H45A H 0.55944(11) 1.1931(2) 0.67070(14) 0.071 Uiso 1 calc R
B7 B 0.65403(13) 1.4519(3) 0.7336(2) 0.0543(9) Uani 1 d .
C46 C 0.60496(11) 1.4417(2) 0.7188(2) 0.0583(8) Uani 1 d .
C47 C 0.56601(13) 1.4392(3) 0.6591(2) 0.0828(11) Uani 1 d .
H47A H 0.56855(13) 1.4463(3) 0.6285(2) 0.099 Uiso 1 calc R
C48 C 0.52399(15) 1.4269(3) 0.6431(2) 0.1006(14) Uani 1 d .
H48A H 0.49921(15) 1.4252(3) 0.6026(2) 0.121 Uiso 1 calc R
C49 C 0.5187(2) 1.4172(3) 0.6870(3) 0.0926(14) Uani 1 d .
H49A H 0.4905(2) 1.4082(3) 0.6765(3) 0.111 Uiso 1 calc R
C50 C 0.5555(2) 1.4209(2) 0.7462(2) 0.0784(11) Uani 1 d .
H50A H 0.5523(2) 1.4153(2) 0.7764(2) 0.094 Uiso 1 calc R
C51 C 0.59782(12) 1.4332(2) 0.7616(2) 0.0630(9) Uani 1 d .
H51A H 0.62234(12) 1.4358(2) 0.8022(2) 0.076 Uiso 1 calc R
C52 C 0.65027(11) 1.5310(2) 0.68918(15) 0.0605(8) Uani 1 d .
C53 C 0.6310(2) 1.6165(3) 0.6832(2) 0.0901(12) Uani 1 d .
H53A H 0.6186(2) 1.6259(3) 0.7029(2) 0.108 Uiso 1 calc R
C54 C 0.6295(2) 1.6874(3) 0.6493(2) 0.113(2) Uani 1 d .
H54A H 0.6169(2) 1.7435(3) 0.6472(2) 0.135 Uiso 1 calc R
C55 C 0.6465(2) 1.6755(4) 0.6188(2) 0.114(2) Uani 1 d .
H55A H 0.6453(2) 1.7229(4) 0.5957(2) 0.137 Uiso 1 calc R
C56 C 0.6651(2) 1.5936(3) 0.6228(2) 0.100(2) Uani 1 d .
H56A H 0.6767(2) 1.5849(3) 0.6020(2) 0.120 Uiso 1 calc R
C57 C 0.66720(13) 1.5218(3) 0.6577(2) 0.0719(10) Uani 1 d .
H57A H 0.68032(13) 1.4664(3) 0.6597(2) 0.086 Uiso 1 calc R
C58 C 0.69243(11) 1.4812(2) 0.80433(15) 0.0578(8) Uani 1 d .
C59 C 0.71454(12) 1.5648(3) 0.8233(2) 0.0750(10) Uani 1 d .
H59A H 0.70774(12) 1.6086(3) 0.7946(2) 0.090 Uiso 1 calc R
C60 C 0.74687(15) 1.5852(3) 0.8846(2) 0.0991(15) Uani 1 d .
H60A H 0.76136(15) 1.6418(3) 0.8961(2) 0.119 Uiso 1 calc R
C61 C 0.7573(2) 1.5216(4) 0.9280(2) 0.103(2) Uani 1 d .
H61A H 0.7778(2) 1.5360(4) 0.9688(2) 0.124 Uiso 1 calc R
C62 C 0.73757(15) 1.4382(4) 0.9106(2) 0.0927(13) Uani 1 d .
H62A H 0.74544(15) 1.3939(4) 0.9395(2) 0.111 Uiso 1 calc R
C63 C 0.70603(12) 1.4182(3) 0.8507(2) 0.0719(10) Uani 1 d .
H63A H 0.69300(12) 1.3601(3) 0.8401(2) 0.086 Uiso 1 calc R
C64 C 0.66887(11) 1.3516(2) 0.72219(13) 0.0544(8) Uani 1 d .
C65 C 0.63915(13) 1.2815(2) 0.68582(15) 0.0642(9) Uani 1 d .
H65A H 0.60904(13) 1.2895(2) 0.66771(15) 0.077 Uiso 1 calc R
C66 C 0.6526(2) 1.1999(3) 0.6754(2) 0.0845(12) Uani 1 d .
H66A H 0.6316(2) 1.1549(3) 0.6509(2) 0.101 Uiso 1 calc R
C67 C 0.6961(2) 1.1855(3) 0.7007(2) 0.0918(14) Uani 1 d .
H67A H 0.7051(2) 1.1310(3) 0.6936(2) 0.110 Uiso 1 calc R
C68 C 0.7269(2) 1.2527(3) 0.7370(2) 0.0861(12) Uani 1 d .
H68A H 0.7568(2) 1.2438(3) 0.7545(2) 0.103 Uiso 1 calc R
C69 C 0.71325(13) 1.3336(3) 0.7474(2) 0.0695(9) Uani 1 d .
H69A H 0.73468(13) 1.3779(3) 0.7723(2) 0.083 Uiso 1 calc R
N70 N 0.5002(2) 0.8038(4) 0.9995(2) 0.140(2) Uiso 1 d .
C71 C 0.4968(2) 0.7290(5) 0.9881(3) 0.121(2) Uiso 1 d .
C72 C 0.4910(3) 0.6300(6) 0.9714(4) 0.174(3) Uiso 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P3 Ag1 P4 123.24(2) . .
P3 Ag1 P2 117.52(3) . .
P4 Ag1 P2 116.94(3) . .
C7 P2 C1 105.66(13) . .
C7 P2 C13 105.29(14) . .
C1 P2 C13 100.47(13) . .
C7 P2 Ag1 110.13(9) . .
C1 P2 Ag1 116.72(10) . .
C13 P2 Ag1 117.28(9) . .
C37 P3 C31 104.02(13) . .
C37 P3 C43 105.90(14) . .
C31 P3 C43 98.82(13) . .
C37 P3 Ag1 111.12(10) . .
C31 P3 Ag1 116.33(9) . .
C43 P3 Ag1 118.93(9) . .
C22 P4 C16 104.19(13) . .
C22 P4 C28 105.02(14) . .
C16 P4 C28 100.65(14) . .
C22 P4 Ag1 115.51(10) . .
C16 P4 Ag1 116.86(10) . .
C28 P4 Ag1 112.88(9) . .
C44 S5 C29 92.82(14) 2_656 .
C14 S6 C14 93.0(2) 2_656 .
C6 C1 C2 118.2(3) . .
C6 C1 P2 123.2(3) . .
C2 C1 P2 118.6(2) . .
C3 C2 C1 121.0(3) . .
C4 C3 C2 120.1(4) . .
C3 C4 C5 119.9(4) . .
C4 C5 C6 120.6(4) . .
C1 C6 C5 120.2(4) . .
C12 C7 C8 118.3(3) . .
C12 C7 P2 117.3(2) . .
C8 C7 P2 124.5(2) . .
C9 C8 C7 120.4(3) . .
C10 C9 C8 120.6(4) . .
C9 C10 C11 120.0(4) . .
C10 C11 C12 120.4(4) . .
C7 C12 C11 120.4(4) . .
C14 C13 P2 114.3(2) . .
C15 C14 C13 131.1(3) . .
C15 C14 S6 109.2(2) . .
C13 C14 S6 119.7(2) . .
C14 C15 C15 114.3(2) . 2_656
C17 C16 C21 118.6(3) . .
C17 C16 P4 118.6(2) . .
C21 C16 P4 122.8(2) . .
C18 C17 C16 120.7(3) . .
C19 C18 C17 119.8(4) . .
C20 C19 C18 120.4(3) . .
C19 C20 C21 119.7(3) . .
C20 C21 C16 120.8(3) . .
C27 C22 C23 117.3(3) . .
C27 C22 P4 118.1(2) . .
C23 C22 P4 124.5(2) . .
C22 C23 C24 121.1(3) . .
C25 C24 C23 120.3(4) . .
C24 C25 C26 119.7(4) . .
C25 C26 C27 119.7(4) . .
C22 C27 C26 121.8(3) . .
C29 C28 P4 113.9(2) . .
C30 C29 C28 130.4(3) . .
C30 C29 S5 109.8(2) . .
C28 C29 S5 119.8(2) . .
C29 C30 C45 114.0(3) . 2_656
C36 C31 C32 118.6(3) . .
C36 C31 P3 118.5(2) . .
C32 C31 P3 122.8(2) . .
C33 C32 C31 120.3(3) . .
C34 C33 C32 120.0(3) . .
C33 C34 C35 120.8(3) . .
C34 C35 C36 119.6(4) . .
C31 C36 C35 120.7(3) . .
C42 C37 C38 117.1(3) . .
C42 C37 P3 117.4(2) . .
C38 C37 P3 125.5(2) . .
C37 C38 C39 121.8(3) . .
C40 C39 C38 120.9(3) . .
C39 C40 C41 118.6(4) . .
C40 C41 C42 120.5(4) . .
C37 C42 C41 121.1(4) . .
C44 C43 P3 116.5(2) . .
C45 C44 C43 130.1(3) . .
C45 C44 S5 109.8(2) . 2_656
C43 C44 S5 120.1(2) . 2_656
C44 C45 C30 113.6(3) . 2_656
C52 B7 C58 109.7(3) . .
C52 B7 C46 108.4(3) . .
C58 B7 C46 110.7(3) . .
C52 B7 C64 110.4(3) . .
C58 B7 C64 107.8(3) . .
C46 B7 C64 109.7(3) . .
C51 C46 C47 114.1(3) . .
C51 C46 B7 125.5(3) . .
C47 C46 B7 120.3(3) . .
C48 C47 C46 123.7(4) . .
C49 C48 C47 120.0(4) . .
C50 C49 C48 119.1(4) . .
C49 C50 C51 120.0(4) . .
C46 C51 C50 123.0(4) . .
C57 C52 C53 115.1(3) . .
C57 C52 B7 124.3(3) . .
C53 C52 B7 120.5(3) . .
C54 C53 C52 122.7(4) . .
C55 C54 C53 120.3(5) . .
C56 C55 C54 119.1(4) . .
C55 C56 C57 120.9(4) . .
C52 C57 C56 121.8(4) . .
C59 C58 C63 115.1(3) . .
C59 C58 B7 124.8(3) . .
C63 C58 B7 120.0(3) . .
C58 C59 C60 121.7(4) . .
C61 C60 C59 120.2(4) . .
C62 C61 C60 119.1(4) . .
C61 C62 C63 120.6(5) . .
C62 C63 C58 123.1(4) . .
C65 C64 C69 114.7(3) . .
C65 C64 B7 124.4(3) . .
C69 C64 B7 120.9(3) . .
C64 C65 C66 122.7(4) . .
C67 C66 C65 120.7(4) . .
C66 C67 C68 118.9(4) . .
C67 C68 C69 120.1(4) . .
C68 C69 C64 122.9(4) . .
N70 C71 C72 178.2(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 P3 2.5221(8) .
Ag1 P4 2.5307(8) .
Ag1 P2 2.5333(7) .
P2 C7 1.820(3) .
P2 C1 1.824(3) .
P2 C13 1.849(3) .
P3 C37 1.813(3) .
P3 C31 1.822(3) .
P3 C43 1.851(3) .
P4 C22 1.819(3) .
P4 C16 1.829(3) .
P4 C28 1.851(3) .
S5 C44 1.731(3) 2_656
S5 C29 1.733(3) .
S6 C14 1.729(3) 2_656
S6 C14 1.729(3) .
C1 C6 1.373(4) .
C1 C2 1.381(4) .
C2 C3 1.374(5) .
C3 C4 1.352(6) .
C4 C5 1.359(6) .
C5 C6 1.381(5) .
C7 C12 1.372(4) .
C7 C8 1.383(4) .
C8 C9 1.378(5) .
C9 C10 1.349(6) .
C10 C11 1.355(6) .
C11 C12 1.385(5) .
C13 C14 1.496(4) .
C14 C15 1.346(4) .
C15 C15 1.403(7) 2_656
C16 C17 1.382(4) .
C16 C21 1.384(4) .
C17 C18 1.381(5) .
C18 C19 1.374(5) .
C19 C20 1.369(6) .
C20 C21 1.383(5) .
C22 C27 1.369(5) .
C22 C23 1.371(4) .
C23 C24 1.384(5) .
C24 C25 1.352(5) .
C25 C26 1.360(6) .
C26 C27 1.380(5) .
C28 C29 1.492(4) .
C29 C30 1.352(4) .
C30 C45 1.415(4) 2_656
C31 C36 1.376(4) .
C31 C32 1.391(4) .
C32 C33 1.385(5) .
C33 C34 1.360(5) .
C34 C35 1.364(5) .
C35 C36 1.392(4) .
C37 C42 1.363(5) .
C37 C38 1.365(4) .
C38 C39 1.373(5) .
C39 C40 1.345(5) .
C40 C41 1.358(6) .
C41 C42 1.390(6) .
C43 C44 1.495(4) .
C44 C45 1.359(4) .
C44 S5 1.731(3) 2_656
C45 C30 1.415(4) 2_656
B7 C52 1.637(5) .
B7 C58 1.641(5) .
B7 C46 1.648(5) .
B7 C64 1.663(5) .
C46 C51 1.393(5) .
C46 C47 1.396(5) .
C47 C48 1.378(6) .
C48 C49 1.372(6) .
C49 C50 1.365(6) .
C50 C51 1.398(5) .
C52 C57 1.385(5) .
C52 C53 1.399(5) .
C53 C54 1.382(6) .
C54 C55 1.363(7) .
C55 C56 1.353(7) .
C56 C57 1.400(5) .
C58 C59 1.384(5) .
C58 C63 1.404(5) .
C59 C60 1.399(6) .
C60 C61 1.381(7) .
C61 C62 1.349(7) .
C62 C63 1.369(5) .
C64 C65 1.391(4) .
C64 C69 1.394(5) .
C65 C66 1.392(5) .
C66 C67 1.355(6) .
C67 C68 1.375(6) .
C68 C69 1.387(5) .
N70 C71 1.118(7) .
C71 C72 1.487(9) .
