#------------------------------------------------------------------------------
#$Date: 2016-03-25 16:45:25 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179988 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/82/7028263.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7028263
loop_
_publ_author_name
'Chaubey, Bimba'
'Mobin, Shaikh M.'
'Balakrishna, Maravanji S.'
_publ_section_title
;
 P-Cl bond-induced lactamization of 2(2'-hydroxyl)phenyloxazoline to form
 a cyclic phosphinite,
 3-(2-chloroethyl)-2-phenyl-2H-benzo[e][1,3,2]oxaza-phosphinin-4(3H)-one:
 synthesis, structural studies and transition metal complexes.
;
_journal_issue                   2
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              584
_journal_page_last               591
_journal_paper_doi               10.1039/c3dt52223g
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C24 H21 Cl2 N2 O4 P Pd'
_chemical_formula_weight         609.70
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 95.0960(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   16.9050(2)
_cell_length_b                   15.6580(2)
_cell_length_c                   17.4771(2)
_cell_measurement_reflns_used    13976
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      32.6200
_cell_measurement_theta_min      3.4594
_cell_volume                     4607.88(10)
_computing_cell_refinement       'CrysAlis RED, Oxford Diffraction Ltd.,'
_computing_data_collection       'CrysAlis CCD, Oxford Diffraction Ltd.,'
_computing_data_reduction        'CrysAlis RED, Oxford Diffraction Ltd.,'
_computing_molecular_graphics    Ortep3
_computing_publication_material  Shelx97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 15.9948
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'OXFORD DIFFRACTION XCALIBUR-S'
_diffrn_measurement_method       ω/q-scan
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0263
_diffrn_reflns_av_sigmaI/netI    0.0236
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            16661
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.50
_exptl_absorpt_coefficient_mu    1.143
_exptl_absorpt_correction_T_max  0.7953
_exptl_absorpt_correction_T_min  0.7041
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.31.7 (release 18-10-2006 CrysAlis171 .NET)
(compiled Oct 18 2006,16:28:17)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.758
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2448
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.21
_refine_diff_density_max         0.374
_refine_diff_density_min         -0.456
_refine_diff_density_rms         0.064
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.095
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     309
_refine_ls_number_reflns         4060
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.095
_refine_ls_R_factor_all          0.0266
_refine_ls_R_factor_gt           0.0221
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0358P)²+0.1109P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0595
_refine_ls_wR_factor_ref         0.0604
_reflns_number_gt                3532
_reflns_number_total             4060
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt52223g.txt
_cod_data_source_block           msb057
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/automatic-downloads/current/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7028263
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pd2 Pd 0.7500 -0.2500 0.5000 0.01766(8) Uani 1 2 d S
Pd1 Pd 1.0000 0.017823(14) 0.2500 0.01363(8) Uani 1 2 d S
Cl1 Cl 0.91234(3) 0.12356(3) 0.28663(3) 0.02103(13) Uani 1 1 d .
Cl2 Cl 0.65672(3) 0.01540(4) 0.41656(3) 0.02699(15) Uani 1 1 d .
P1 P 0.91380(3) -0.07690(3) 0.29023(3) 0.01505(13) Uani 1 1 d .
O1 O 0.94606(9) -0.17263(9) 0.30761(8) 0.0178(3) Uani 1 1 d .
O2 O 0.90257(10) -0.05375(11) 0.50664(9) 0.0252(4) Uani 1 1 d .
O3 O 0.77581(10) -0.28827(11) 0.39712(9) 0.0264(4) Uani 1 1 d .
O4 O 0.97744(9) -0.34137(10) 0.55619(9) 0.0257(4) Uani 1 1 d .
N1 N 0.87853(10) -0.05582(12) 0.37649(10) 0.0161(4) Uani 1 1 d .
N2 N 0.85958(11) -0.27681(12) 0.54400(10) 0.0197(4) Uani 1 1 d .
C1 C 1.00094(13) -0.18216(14) 0.37190(13) 0.0182(5) Uani 1 1 d .
C2 C 1.06189(15) -0.24003(14) 0.36748(14) 0.0237(5) Uani 1 1 d .
H2 H 1.0665 -0.2726 0.3222 0.028 Uiso 1 1 calc R
C3 C 1.11640(15) -0.24927(15) 0.43128(15) 0.0277(6) Uani 1 1 d .
H3 H 1.1591 -0.2885 0.4294 0.033 Uiso 1 1 calc R
C4 C 1.10958(15) -0.20231(15) 0.49758(14) 0.0268(6) Uani 1 1 d .
H4 H 1.1481 -0.2085 0.5402 0.032 Uiso 1 1 calc R
C5 C 1.04684(14) -0.14648(15) 0.50177(13) 0.0239(5) Uani 1 1 d .
H5 H 1.0413 -0.1157 0.5478 0.029 Uiso 1 1 calc R
C6 C 0.99123(13) -0.13525(14) 0.43788(13) 0.0192(5) Uani 1 1 d .
C7 C 0.92211(14) -0.07811(14) 0.44500(13) 0.0194(5) Uani 1 1 d .
C8 C 0.80788(13) -0.00063(14) 0.38242(13) 0.0189(5) Uani 1 1 d .
H8A H 0.7916 0.0252 0.3318 0.023 Uiso 1 1 calc R
H8B H 0.8213 0.0461 0.4194 0.023 Uiso 1 1 calc R
C9 C 0.74025(13) -0.05310(15) 0.40886(14) 0.0218(5) Uani 1 1 d .
H9A H 0.7565 -0.0795 0.4593 0.026 Uiso 1 1 calc R
H9B H 0.7260 -0.0993 0.3715 0.026 Uiso 1 1 calc R
C10 C 0.82856(13) -0.09446(14) 0.22431(12) 0.0179(5) Uani 1 1 d .
C11 C 0.77479(13) -0.15993(14) 0.23796(13) 0.0212(5) Uani 1 1 d .
H11 H 0.7832 -0.1949 0.2824 0.025 Uiso 1 1 calc R
C12 C 0.70988(14) -0.17271(16) 0.18605(14) 0.0271(6) Uani 1 1 d .
H12 H 0.6734 -0.2172 0.1946 0.033 Uiso 1 1 calc R
C13 C 0.69699(15) -0.12145(16) 0.12142(14) 0.0277(6) Uani 1 1 d .
H13 H 0.6513 -0.1301 0.0865 0.033 Uiso 1 1 calc R
C14 C 0.75058(15) -0.05797(16) 0.10787(14) 0.0291(6) Uani 1 1 d .
H14 H 0.7420 -0.0235 0.0631 0.035 Uiso 1 1 calc R
C15 C 0.81673(14) -0.04406(15) 0.15896(13) 0.0221(5) Uani 1 1 d .
H15 H 0.8536 -0.0004 0.1494 0.026 Uiso 1 1 calc R
C16 C 0.83374(14) -0.34112(14) 0.38429(13) 0.0217(5) Uani 1 1 d .
C17 C 0.83137(15) -0.37726(16) 0.30978(14) 0.0262(6) Uani 1 1 d .
H17 H 0.7895 -0.3622 0.2724 0.031 Uiso 1 1 calc R
C18 C 0.88869(16) -0.43382(17) 0.29065(14) 0.0307(6) Uani 1 1 d .
H18 H 0.8857 -0.4573 0.2403 0.037 Uiso 1 1 calc R
C19 C 0.95074(15) -0.45708(16) 0.34375(15) 0.0295(6) Uani 1 1 d .
H19 H 0.9897 -0.4967 0.3302 0.035 Uiso 1 1 calc R
C20 C 0.95542(14) -0.42248(15) 0.41596(14) 0.0252(5) Uani 1 1 d .
H20 H 0.9980 -0.4384 0.4523 0.030 Uiso 1 1 calc R
C21 C 0.89820(13) -0.36364(14) 0.43728(13) 0.0205(5) Uani 1 1 d .
C22 C 0.90862(13) -0.32562(14) 0.51306(13) 0.0194(5) Uani 1 1 d .
C23 C 0.89681(15) -0.24613(15) 0.61882(14) 0.0261(6) Uani 1 1 d .
H23A H 0.8608 -0.2534 0.6600 0.031 Uiso 1 1 calc R
H23B H 0.9125 -0.1854 0.6161 0.031 Uiso 1 1 calc R
C24 C 0.96878(15) -0.30372(16) 0.63145(14) 0.0298(6) Uani 1 1 d .
H24A H 1.0166 -0.2704 0.6495 0.036 Uiso 1 1 calc R
H24B H 0.9601 -0.3486 0.6698 0.036 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 Pd2 O3 180.0 7_646 .
O3 Pd2 N2 90.83(7) 7_646 7_646
O3 Pd2 N2 89.17(7) . 7_646
O3 Pd2 N2 89.17(7) 7_646 .
O3 Pd2 N2 90.83(7) . .
N2 Pd2 N2 180.00(10) 7_646 .
P1 Pd1 P1 96.89(3) . 2_755
P1 Pd1 Cl1 86.40(2) . .
P1 Pd1 Cl1 176.35(2) 2_755 .
P1 Pd1 Cl1 176.35(2) . 2_755
P1 Pd1 Cl1 86.40(2) 2_755 2_755
Cl1 Pd1 Cl1 90.35(3) . 2_755
O1 P1 N1 98.76(8) . .
O1 P1 C10 102.61(9) . .
N1 P1 C10 105.98(10) . .
O1 P1 Pd1 117.16(6) . .
N1 P1 Pd1 116.06(7) . .
C10 P1 Pd1 114.24(8) . .
C1 O1 P1 116.01(13) . .
C16 O3 Pd2 124.89(14) . .
C22 O4 C24 106.17(17) . .
C7 N1 C8 116.93(18) . .
C7 N1 P1 120.83(15) . .
C8 N1 P1 121.45(14) . .
C22 N2 C23 109.02(19) . .
C22 N2 Pd2 125.35(15) . .
C23 N2 Pd2 125.60(15) . .
C2 C1 C6 122.5(2) . .
C2 C1 O1 118.0(2) . .
C6 C1 O1 119.41(19) . .
C1 C2 C3 118.0(2) . .
C1 C2 H2 121.0 . .
C3 C2 H2 121.0 . .
C4 C3 C2 121.2(2) . .
C4 C3 H3 119.4 . .
C2 C3 H3 119.4 . .
C5 C4 C3 120.1(2) . .
C5 C4 H4 120.0 . .
C3 C4 H4 120.0 . .
C4 C5 C6 120.0(2) . .
C4 C5 H5 120.0 . .
C6 C5 H5 120.0 . .
C1 C6 C5 118.3(2) . .
C1 C6 C7 122.7(2) . .
C5 C6 C7 119.0(2) . .
O2 C7 N1 121.2(2) . .
O2 C7 C6 122.7(2) . .
N1 C7 C6 116.0(2) . .
N1 C8 C9 109.85(18) . .
N1 C8 H8A 109.7 . .
C9 C8 H8A 109.7 . .
N1 C8 H8B 109.7 . .
C9 C8 H8B 109.7 . .
H8A C8 H8B 108.2 . .
C8 C9 Cl2 108.69(16) . .
C8 C9 H9A 110.0 . .
Cl2 C9 H9A 110.0 . .
C8 C9 H9B 110.0 . .
Cl2 C9 H9B 110.0 . .
H9A C9 H9B 108.3 . .
C15 C10 C11 120.4(2) . .
C15 C10 P1 119.52(17) . .
C11 C10 P1 120.03(17) . .
C12 C11 C10 119.0(2) . .
C12 C11 H11 120.5 . .
C10 C11 H11 120.5 . .
C11 C12 C13 120.8(2) . .
C11 C12 H12 119.6 . .
C13 C12 H12 119.6 . .
C14 C13 C12 119.9(2) . .
C14 C13 H13 120.0 . .
C12 C13 H13 120.0 . .
C13 C14 C15 120.5(2) . .
C13 C14 H14 119.7 . .
C15 C14 H14 119.7 . .
C14 C15 C10 119.4(2) . .
C14 C15 H15 120.3 . .
C10 C15 H15 120.3 . .
O3 C16 C21 126.0(2) . .
O3 C16 C17 116.5(2) . .
C21 C16 C17 117.4(2) . .
C18 C17 C16 121.1(2) . .
C18 C17 H17 119.4 . .
C16 C17 H17 119.4 . .
C17 C18 C19 120.9(2) . .
C17 C18 H18 119.5 . .
C19 C18 H18 119.5 . .
C20 C19 C18 119.4(2) . .
C20 C19 H19 120.3 . .
C18 C19 H19 120.3 . .
C19 C20 C21 121.2(2) . .
C19 C20 H20 119.4 . .
C21 C20 H20 119.4 . .
C20 C21 C16 119.9(2) . .
C20 C21 C22 118.7(2) . .
C16 C21 C22 121.4(2) . .
N2 C22 O4 115.5(2) . .
N2 C22 C21 126.9(2) . .
O4 C22 C21 117.6(2) . .
N2 C23 C24 102.04(19) . .
N2 C23 H23A 111.4 . .
C24 C23 H23A 111.4 . .
N2 C23 H23B 111.4 . .
C24 C23 H23B 111.4 . .
H23A C23 H23B 109.2 . .
O4 C24 C23 104.62(18) . .
O4 C24 H24A 110.8 . .
C23 C24 H24A 110.8 . .
O4 C24 H24B 110.8 . .
C23 C24 H24B 110.8 . .
H24A C24 H24B 108.9 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pd2 O3 1.9803(15) 7_646
Pd2 O3 1.9803(15) .
Pd2 N2 1.9864(18) 7_646
Pd2 N2 1.9864(18) .
Pd1 P1 2.2359(6) .
Pd1 P1 2.2359(6) 2_755
Pd1 Cl1 2.3484(5) .
Pd1 Cl1 2.3484(5) 2_755
Cl2 C9 1.788(2) .
P1 O1 1.6147(15) .
P1 N1 1.7021(19) .
P1 C10 1.784(2) .
O1 C1 1.400(3) .
O2 C7 1.216(3) .
O3 C16 1.317(3) .
O4 C22 1.352(3) .
O4 C24 1.461(3) .
N1 C7 1.393(3) .
N1 C8 1.485(3) .
N2 C22 1.282(3) .
N2 C23 1.480(3) .
C1 C2 1.379(3) .
C1 C6 1.389(3) .
C2 C3 1.390(4) .
C2 H2 0.9500 .
C3 C4 1.386(4) .
C3 H3 0.9500 .
C4 C5 1.381(3) .
C4 H4 0.9500 .
C5 C6 1.405(3) .
C5 H5 0.9500 .
C6 C7 1.486(3) .
C8 C9 1.513(3) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C10 C15 1.388(3) .
C10 C11 1.405(3) .
C11 C12 1.375(3) .
C11 H11 0.9500 .
C12 C13 1.387(3) .
C12 H12 0.9500 .
C13 C14 1.379(4) .
C13 H13 0.9500 .
C14 C15 1.385(3) .
C14 H14 0.9500 .
C15 H15 0.9500 .
C16 C21 1.411(3) .
C16 C17 1.417(3) .
C17 C18 1.376(4) .
C17 H17 0.9500 .
C18 C19 1.386(4) .
C18 H18 0.9500 .
C19 C20 1.369(3) .
C19 H19 0.9500 .
C20 C21 1.410(3) .
C20 H20 0.9500 .
C21 C22 1.448(3) .
C23 C24 1.515(3) .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C24 H24A 0.9900 .
C24 H24B 0.9900 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
P1 Pd1 P1 O1 20.02(6) 2_755
Cl1 Pd1 P1 O1 -161.57(7) .
Cl1 Pd1 P1 O1 -134.3(3) 2_755
P1 Pd1 P1 N1 136.21(7) 2_755
Cl1 Pd1 P1 N1 -45.38(7) .
Cl1 Pd1 P1 N1 -18.1(3) 2_755
P1 Pd1 P1 C10 -99.99(8) 2_755
Cl1 Pd1 P1 C10 78.43(8) .
Cl1 Pd1 P1 C10 105.7(3) 2_755
N1 P1 O1 C1 -55.92(16) .
C10 P1 O1 C1 -164.59(15) .
Pd1 P1 O1 C1 69.43(15) .
O3 Pd2 O3 C16 110(100) 7_646
N2 Pd2 O3 C16 -157.45(19) 7_646
N2 Pd2 O3 C16 22.55(19) .
O1 P1 N1 C7 43.44(18) .
C10 P1 N1 C7 149.33(17) .
Pd1 P1 N1 C7 -82.68(17) .
O1 P1 N1 C8 -147.07(16) .
C10 P1 N1 C8 -41.17(19) .
Pd1 P1 N1 C8 86.81(16) .
O3 Pd2 N2 C22 161.8(2) 7_646
O3 Pd2 N2 C22 -18.2(2) .
N2 Pd2 N2 C22 -31(100) 7_646
O3 Pd2 N2 C23 -16.06(18) 7_646
O3 Pd2 N2 C23 163.94(18) .
N2 Pd2 N2 C23 152(100) 7_646
P1 O1 C1 C2 -143.13(17) .
P1 O1 C1 C6 38.5(3) .
C6 C1 C2 C3 -1.8(3) .
O1 C1 C2 C3 179.9(2) .
C1 C2 C3 C4 0.4(4) .
C2 C3 C4 C5 1.4(4) .
C3 C4 C5 C6 -2.0(4) .
C2 C1 C6 C5 1.2(3) .
O1 C1 C6 C5 179.55(19) .
C2 C1 C6 C7 -175.0(2) .
O1 C1 C6 C7 3.4(3) .
C4 C5 C6 C1 0.7(3) .
C4 C5 C6 C7 177.0(2) .
C8 N1 C7 O2 0.5(3) .
P1 N1 C7 O2 170.42(18) .
C8 N1 C7 C6 178.39(18) .
P1 N1 C7 C6 -11.7(3) .
C1 C6 C7 O2 161.3(2) .
C5 C6 C7 O2 -14.8(3) .
C1 C6 C7 N1 -16.5(3) .
C5 C6 C7 N1 167.3(2) .
C7 N1 C8 C9 -76.5(2) .
P1 N1 C8 C9 113.64(19) .
N1 C8 C9 Cl2 179.27(15) .
O1 P1 C10 C15 -134.64(18) .
N1 P1 C10 C15 122.27(19) .
Pd1 P1 C10 C15 -6.8(2) .
O1 P1 C10 C11 44.2(2) .
N1 P1 C10 C11 -58.9(2) .
Pd1 P1 C10 C11 172.02(16) .
C15 C10 C11 C12 -0.7(3) .
P1 C10 C11 C12 -179.48(18) .
C10 C11 C12 C13 -0.6(4) .
C11 C12 C13 C14 1.4(4) .
C12 C13 C14 C15 -1.0(4) .
C13 C14 C15 C10 -0.3(4) .
C11 C10 C15 C14 1.1(3) .
P1 C10 C15 C14 179.89(19) .
Pd2 O3 C16 C21 -16.1(3) .
Pd2 O3 C16 C17 165.07(16) .
O3 C16 C17 C18 -179.4(2) .
C21 C16 C17 C18 1.7(4) .
C16 C17 C18 C19 -0.2(4) .
C17 C18 C19 C20 -0.7(4) .
C18 C19 C20 C21 0.0(4) .
C19 C20 C21 C16 1.5(4) .
C19 C20 C21 C22 -176.7(2) .
O3 C16 C21 C20 178.9(2) .
C17 C16 C21 C20 -2.3(3) .
O3 C16 C21 C22 -3.0(4) .
C17 C16 C21 C22 175.8(2) .
C23 N2 C22 O4 4.0(3) .
Pd2 N2 C22 O4 -174.10(14) .
C23 N2 C22 C21 -174.9(2) .
Pd2 N2 C22 C21 7.0(3) .
C24 O4 C22 N2 6.9(3) .
C24 O4 C22 C21 -174.1(2) .
C20 C21 C22 N2 -173.8(2) .
C16 C21 C22 N2 8.0(4) .
C20 C21 C22 O4 7.3(3) .
C16 C21 C22 O4 -170.9(2) .
C22 N2 C23 C24 -12.5(3) .
Pd2 N2 C23 C24 165.58(16) .
C22 O4 C24 C23 -14.3(2) .
N2 C23 C24 O4 15.8(2) .
