#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/84/7028403.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7028403
loop_
_publ_author_name
'Hashemi, Lida'
'Morsali, Ali'
'Joo, Sang Woo'
_publ_section_title
;
 Mechanochemical solid state anion-exchange of lead(II) coordination
 polymers via an intermediate coordination polymer; new precursors for the
 preparation of PbBr2/Pb3O2Br2, PbBr(OH) and PbO nanoparticles.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1489
_journal_page_last               1492
_journal_paper_doi               10.1039/c3dt51533h
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C28 H28 Br2.16 N9.84 O5.5 Pb2'
_chemical_formula_weight         1177.72
_chemical_name_systematic
;

?

;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.475(1)
_cell_angle_beta                 89.987(1)
_cell_angle_gamma                117.915(1)
_cell_formula_units_Z            4
_cell_length_a                   8.3995(1)
_cell_length_b                   17.9496(3)
_cell_length_c                   27.9998(5)
_cell_measurement_reflns_used    9976
_cell_measurement_temperature    180(2)
_cell_measurement_theta_max      28.99
_cell_measurement_theta_min      2.68
_cell_volume                     3578.05(11)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      180(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0402
_diffrn_reflns_av_sigmaI/netI    0.0495
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            46625
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.71
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    11.868
_exptl_absorpt_correction_T_max  0.2691
_exptl_absorpt_correction_T_min  0.1554
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Bruker SADABS'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.186
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2195
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.15
_refine_diff_density_max         2.778
_refine_diff_density_min         -3.300
_refine_diff_density_rms         0.151
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     630
_refine_ls_number_reflns         14031
_refine_ls_number_restraints     14
_refine_ls_restrained_S_all      1.021
_refine_ls_R_factor_all          0.0651
_refine_ls_R_factor_gt           0.0346
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0222P)²+26.6600P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0787
_refine_ls_wR_factor_ref         0.0926
_reflns_number_gt                8664
_reflns_number_total             14031
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt51533h.txt
_cod_data_source_block           sk13
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/automatic-downloads/current/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/usr/data/users/saulius/automatic-downloads/current/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_cell_volume        3578.0(1)
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'C28 H28 Br2.16 N9.84 O5.50 Pb2'
_cod_database_code               7028403
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Pb1 Pb 0.61645(11) 0.63252(5) 0.74916(3) 0.0236(2) Uani 1 1 d D .
Pb2 Pb 0.38244(11) 0.36623(5) 0.75026(3) 0.0228(2) Uani 1 1 d D .
Pb3 Pb 0.64882(11) 0.13249(5) 0.74916(3) 0.0237(2) Uani 1 1 d D .
Pb4 Pb 0.35013(11) -0.13384(5) 0.75029(3) 0.0230(2) Uani 1 1 d D .
Br1 Br 0.3158(3) 0.51555(13) 0.79384(8) 0.03445(11) Uani 1 1 d . .
Br2 Br 0.6881(3) 0.48391(13) 0.70726(8) 0.03445(11) Uani 1 1 d . .
Br3 Br 0.7191(3) 0.01522(14) 0.79272(8) 0.03445(11) Uani 1 1 d . .
Br4 Br 0.2833(3) -0.01644(14) 0.70621(8) 0.03445(11) Uani 1 1 d . .
Br5 Br 0.470(3) 0.7595(16) 0.7926(11) 0.03445(11) Uani 0.088(8) 1 d PD 1
Br6 Br 0.474(5) 0.2233(17) 0.6953(14) 0.03445(11) Uani 0.069(8) 1 d PD 1
Br7 Br 1.050(3) 0.2581(16) 0.7909(11) 0.03445(11) Uani 0.088(8) 1 d PD 1
Br8 Br -0.026(3) -0.2742(16) 0.6934(11) 0.03445(11) Uani 0.083(8) 1 d PD 1
N1 N 0.827(3) 0.6558(12) 0.8279(7) 0.0342(7) Uani 1 1 d . .
C1 C 0.773(3) 0.6585(14) 0.8729(6) 0.037(3) Uani 1 1 d . .
H1A H 0.6625 0.6600 0.8775 0.045 Uiso 1 1 calc R .
C2 C 0.866(3) 0.6593(15) 0.9114(8) 0.041(5) Uani 1 1 d . .
H2A H 0.8213 0.6608 0.9426 0.049 Uiso 1 1 calc R .
C3 C 1.039(3) 0.6577(13) 0.9055(7) 0.0287(12) Uani 1 1 d D .
C4 C 1.096(3) 0.6572(13) 0.8580(8) 0.036(5) Uani 1 1 d . .
H4A H 1.2078 0.6578 0.8518 0.043 Uiso 1 1 calc R .
C5 C 0.987(3) 0.6558(15) 0.8212(7) 0.037(3) Uani 1 1 d . .
H5A H 1.0255 0.6549 0.7892 0.045 Uiso 1 1 calc R .
C6 C 1.152(3) 0.6575(13) 0.9467(7) 0.032(4) Uani 1 1 d D .
C7 C 1.332(3) 0.6711(15) 0.9406(7) 0.045(6) Uani 1 1 d . .
H7A H 1.3864 0.6681 0.9705 0.067 Uiso 1 1 calc R .
H7B H 1.4062 0.7291 0.9354 0.067 Uiso 1 1 calc R .
H7C H 1.3267 0.6256 0.9117 0.067 Uiso 1 1 calc R .
N2 N 1.373(2) 0.5753(10) 1.1666(6) 0.0342(7) Uani 1 1 d . .
C8 C 1.211(3) 0.5716(13) 1.1738(7) 0.037(3) Uani 1 1 d . .
H8A H 1.1685 0.5661 1.2049 0.045 Uiso 1 1 calc R .
C9 C 1.098(3) 0.5757(12) 1.1366(7) 0.032(4) Uani 1 1 d . .
H9A H 0.9820 0.5705 1.1423 0.039 Uiso 1 1 calc R .
C10 C 1.166(3) 0.5878(12) 1.0917(6) 0.024(3) Uani 1 1 d D .
C11 C 1.329(3) 0.5811(11) 1.0844(7) 0.032(4) Uani 1 1 d . .
H11A H 1.3637 0.5721 1.0520 0.039 Uiso 1 1 calc R .
C12 C 1.428(3) 0.5875(11) 1.1228(6) 0.037(3) Uani 1 1 d . .
H12A H 1.5511 0.6021 1.1194 0.045 Uiso 1 1 calc R .
N3 N 1.060(2) 0.6321(11) 0.9825(6) 0.036(5) Uani 1 1 d D .
N4 N 1.160(2) 0.6251(12) 1.0197(5) 0.039(5) Uani 1 1 d D .
C13 C 1.067(3) 0.5975(13) 1.0515(7) 0.032(4) Uani 1 1 d D .
C14 C 0.873(3) 0.5698(12) 1.0528(8) 0.038(6) Uani 1 1 d . .
H14A H 0.8257 0.5812 1.0250 0.057 Uiso 1 1 calc R .
H14B H 0.8572 0.6028 1.0843 0.057 Uiso 1 1 calc R .
H14C H 0.8065 0.5068 1.0500 0.057 Uiso 1 1 calc R .
N5 N 0.167(3) 0.3432(12) 0.6739(7) 0.0342(7) Uani 1 1 d . .
C15 C 0.011(3) 0.3438(15) 0.6784(9) 0.040(3) Uani 1 1 d . .
H15A H -0.0294 0.3467 0.7101 0.048 Uiso 1 1 calc R .
C16 C -0.097(3) 0.3403(14) 0.6397(7) 0.032(4) Uani 1 1 d . .
H16A H -0.2099 0.3384 0.6450 0.039 Uiso 1 1 calc R .
C17 C -0.041(3) 0.3396(13) 0.5944(7) 0.0287(12) Uani 1 1 d . .
C18 C 0.112(3) 0.3388(14) 0.5881(7) 0.032(4) Uani 1 1 d . .
H18A H 0.1535 0.3374 0.5565 0.039 Uiso 1 1 calc R .
C19 C 0.218(3) 0.3400(14) 0.6292(8) 0.040(3) Uani 1 1 d . .
H19A H 0.3286 0.3384 0.6238 0.048 Uiso 1 1 calc R .
C20 C -0.143(3) 0.3442(11) 0.5526(8) 0.031(4) Uani 1 1 d . .
C21 C -0.348(3) 0.3207(14) 0.5565(8) 0.045(6) Uani 1 1 d . .
H21A H -0.3988 0.3266 0.5271 0.067 Uiso 1 1 calc R .
H21B H -0.3537 0.3609 0.5865 0.067 Uiso 1 1 calc R .
H21C H -0.4173 0.2601 0.5583 0.067 Uiso 1 1 calc R .
N6 N -0.355(2) 0.4277(10) 0.3307(6) 0.0342(7) Uani 1 1 d . .
C22 C -0.414(2) 0.4270(10) 0.3747(7) 0.033(3) Uani 1 1 d . .
H22A H -0.5093 0.4407 0.3824 0.040 Uiso 1 1 calc R .
C23 C -0.331(3) 0.4049(11) 0.4111(7) 0.033(4) Uani 1 1 d . .
H23A H -0.3922 0.3845 0.4375 0.039 Uiso 1 1 calc R .
C24 C -0.164(3) 0.4150(13) 0.4054(7) 0.0287(12) Uani 1 1 d . .
C25 C -0.102(3) 0.4239(12) 0.3609(7) 0.033(4) Uani 1 1 d . .
H25A H 0.0117 0.4259 0.3551 0.039 Uiso 1 1 calc R .
C26 C -0.198(2) 0.4298(12) 0.3256(8) 0.033(3) Uani 1 1 d . .
H26A H -0.1509 0.4359 0.2951 0.040 Uiso 1 1 calc R .
N7 N -0.058(2) 0.3652(11) 0.5171(6) 0.035(5) Uani 1 1 d D .
N8 N -0.159(2) 0.3723(10) 0.4802(6) 0.034(5) Uani 1 1 d D .
C27 C -0.064(3) 0.4038(11) 0.4446(7) 0.026(4) Uani 1 1 d . .
C28 C 0.132(3) 0.4251(14) 0.4425(7) 0.035(6) Uani 1 1 d . .
H28A H 0.1773 0.4158 0.4715 0.053 Uiso 1 1 calc R .
H28B H 0.2057 0.4866 0.4426 0.053 Uiso 1 1 calc R .
H28C H 0.1405 0.3867 0.4120 0.053 Uiso 1 1 calc R .
N9 N 0.209(2) -0.0743(11) 0.8314(6) 0.0342(7) Uani 1 1 d . .
C29 C 0.060(3) -0.0720(14) 0.8253(7) 0.039(4) Uani 1 1 d . .
H29A H 0.0226 -0.0681 0.7944 0.047 Uiso 1 1 calc R .
C30 C -0.048(3) -0.0754(12) 0.8632(7) 0.032(3) Uani 1 1 d . .
H30A H -0.1526 -0.0690 0.8581 0.039 Uiso 1 1 calc R .
C31 C -0.011(3) -0.0876(12) 0.9084(7) 0.0287(12) Uani 1 1 d . .
C32 C 0.144(2) -0.0959(11) 0.9128(7) 0.032(3) Uani 1 1 d . .
H32A H 0.1731 -0.1084 0.9416 0.039 Uiso 1 1 calc R .
C33 C 0.250(2) -0.0869(12) 0.8778(6) 0.039(4) Uani 1 1 d . .
H33A H 0.3599 -0.0888 0.8833 0.047 Uiso 1 1 calc R .
C34 C -0.127(3) -0.0969(13) 0.9476(7) 0.0296(10) Uani 1 1 d . .
C35 C -0.276(3) -0.0705(14) 0.9460(7) 0.038(4) Uani 1 1 d . .
H35A H -0.3435 -0.0808 0.9743 0.057 Uiso 1 1 calc R .
H35B H -0.3600 -0.1057 0.9149 0.057 Uiso 1 1 calc R .
H35C H -0.2204 -0.0080 0.9476 0.057 Uiso 1 1 calc R .
N10 N -0.484(3) -0.1571(12) 1.1729(7) 0.0342(7) Uani 1 1 d . .
C36 C -0.543(3) -0.1589(17) 1.1276(9) 0.049(6) Uani 1 1 d . .
H36A H -0.6542 -0.1587 1.1223 0.059 Uiso 1 1 calc R .
C37 C -0.439(3) -0.1610(14) 1.0877(8) 0.032(3) Uani 1 1 d . .
H37A H -0.4825 -0.1628 1.0559 0.039 Uiso 1 1 calc R .
C38 C -0.275(3) -0.1605(13) 1.0942(7) 0.0287(12) Uani 1 1 d . .
C39 C -0.216(3) -0.1571(13) 1.1414(7) 0.032(3) Uani 1 1 d . .
H39A H -0.1051 -0.1571 1.1474 0.039 Uiso 1 1 calc R .
C40 C -0.321(3) -0.1538(14) 1.1804(8) 0.035(5) Uani 1 1 d . .
H40A H -0.2767 -0.1491 1.2128 0.041 Uiso 1 1 calc R .
N11 N -0.090(2) -0.1244(11) 0.9814(5) 0.034(3) Uani 1 1 d D .
N12 N -0.208(2) -0.1308(11) 1.0184(5) 0.034(3) Uani 1 1 d D .
C41 C -0.168(3) -0.1541(12) 1.0544(7) 0.0296(10) Uani 1 1 d . .
C42 C 0.000(3) -0.1691(14) 1.0610(7) 0.038(4) Uani 1 1 d . .
H42A H 0.0641 -0.1630 1.0318 0.057 Uiso 1 1 calc R .
H42B H -0.0423 -0.2282 1.0645 0.057 Uiso 1 1 calc R .
H42C H 0.0827 -0.1253 1.0909 0.057 Uiso 1 1 calc R .
N13 N 0.518(3) -0.1555(12) 0.6729(7) 0.0342(7) Uani 1 1 d . .
C43 C 0.462(3) -0.1591(14) 0.6286(8) 0.036(4) Uani 1 1 d . .
H43A H 0.3476 -0.1616 0.6240 0.044 Uiso 1 1 calc R .
C44 C 0.551(3) -0.1596(16) 0.5888(8) 0.045(5) Uani 1 1 d . .
H44A H 0.5016 -0.1607 0.5579 0.054 Uiso 1 1 calc R .
C45 C 0.717(3) -0.1584(12) 0.5941(7) 0.029(3) Uani 1 1 d D .
C46 C 0.774(3) -0.1605(14) 0.6403(8) 0.035(4) Uani 1 1 d . .
H46A H 0.8825 -0.1636 0.6455 0.042 Uiso 1 1 calc R .
C47 C 0.674(3) -0.1582(15) 0.6773(8) 0.036(4) Uani 1 1 d . .
H47A H 0.7156 -0.1586 0.7087 0.044 Uiso 1 1 calc R .
C48 C 0.836(3) -0.1582(12) 0.5522(7) 0.0296(10) Uani 1 1 d D .
C49 C 0.978(3) -0.1821(15) 0.5554(8) 0.051(6) Uani 1 1 d . .
H49A H 1.0381 -0.1783 0.5254 0.077 Uiso 1 1 calc R .
H49B H 0.9237 -0.2424 0.5579 0.077 Uiso 1 1 calc R .
H49C H 1.0670 -0.1418 0.5848 0.077 Uiso 1 1 calc R .
N14 N 1.222(2) -0.0732(11) 0.3318(6) 0.0342(7) Uani 1 1 d . .
C50 C 1.064(3) -0.0702(12) 0.3266(7) 0.033(4) Uani 1 1 d . .
H50A H 1.0329 -0.0631 0.2961 0.040 Uiso 1 1 calc R .
C51 C 0.945(3) -0.0767(11) 0.3616(7) 0.030(3) Uani 1 1 d . .
H51A H 0.8359 -0.0750 0.3554 0.036 Uiso 1 1 calc R .
C52 C 0.994(3) -0.0858(12) 0.4061(7) 0.027(3) Uani 1 1 d D .
C53 C 1.165(2) -0.0794(9) 0.4135(7) 0.030(3) Uani 1 1 d . .
H53A H 1.2091 -0.0793 0.4447 0.036 Uiso 1 1 calc R .
C54 C 1.271(2) -0.0731(10) 0.3743(6) 0.033(4) Uani 1 1 d . .
H54A H 1.3873 -0.0685 0.3802 0.040 Uiso 1 1 calc R .
N15 N 0.791(2) -0.1365(10) 0.5166(6) 0.035(4) Uani 1 1 d D .
N16 N 0.904(2) -0.1283(10) 0.4790(6) 0.033(4) Uani 1 1 d D .
C55 C 0.868(3) -0.0962(13) 0.4454(7) 0.0296(10) Uani 1 1 d D .
C56 C 0.726(3) -0.0744(13) 0.4424(8) 0.039(5) Uani 1 1 d . .
H56A H 0.6562 -0.0858 0.4703 0.058 Uiso 1 1 calc R .
H56B H 0.6451 -0.1105 0.4109 0.058 Uiso 1 1 calc R .
H56C H 0.7786 -0.0121 0.4440 0.058 Uiso 1 1 calc R .
N17 N 0.506(3) 0.7721(12) 0.8085(8) 0.0182(18) Uani 0.912(8) 1 d P 2
O1 O 0.572(2) 0.7386(9) 0.8306(6) 0.038(3) Uani 0.912(8) 1 d P 2
O2 O 0.478(3) 0.7479(13) 0.7585(6) 0.052(4) Uani 0.912(8) 1 d P 2
O3 O 0.443(3) 0.8194(11) 0.8313(6) 0.053(4) Uani 0.912(8) 1 d P 2
N18 N 0.525(3) 0.2341(11) 0.6955(8) 0.0182(18) Uani 0.931(8) 1 d P 2
O4 O 0.528(3) 0.2515(11) 0.7360(6) 0.043(3) Uani 0.931(8) 1 d P 2
O5 O 0.429(2) 0.2568(10) 0.6695(5) 0.043(3) Uani 0.931(8) 1 d P 2
O6 O 0.552(2) 0.1773(10) 0.6688(5) 0.043(3) Uani 0.931(8) 1 d P 2
N19 N 1.041(3) 0.2715(12) 0.8086(8) 0.0182(18) Uani 0.912(8) 1 d P 2
O7 O 1.023(3) 0.2490(14) 0.7600(7) 0.054(4) Uani 0.912(8) 1 d P 2
O8 O 0.910(2) 0.2406(9) 0.8299(5) 0.036(3) Uani 0.912(8) 1 d P 2
O9 O 1.196(2) 0.3192(10) 0.8318(6) 0.053(4) Uani 0.912(8) 1 d P 2
N20 N -0.057(3) -0.2652(12) 0.6972(8) 0.0182(18) Uani 0.917(8) 1 d P 2
O10 O -0.021(2) -0.2479(12) 0.7375(6) 0.045(3) Uani 0.917(8) 1 d P 2
O11 O 0.089(2) -0.2413(10) 0.6690(6) 0.045(3) Uani 0.917(8) 1 d P 2
O12 O -0.196(2) -0.3236(10) 0.6685(5) 0.045(3) Uani 0.917(8) 1 d P 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Pb1 O1 70.8(5) . .
N1 Pb1 N6 167.6(5) . 2_566
O1 Pb1 N6 112.5(5) . 2_566
N1 Pb1 Br1 85.0(4) . .
O1 Pb1 Br1 73.5(3) . .
N6 Pb1 Br1 84.7(3) 2_566 .
N1 Pb1 Br2 82.4(4) . .
O1 Pb1 Br2 148.5(3) . .
N6 Pb1 Br2 90.5(3) 2_566 .
Br1 Pb1 Br2 88.23(6) . .
N1 Pb1 Br5 101.1(7) . .
O1 Pb1 Br5 30.9(6) . .
N6 Pb1 Br5 84.3(6) 2_566 .
Br1 Pb1 Br5 82.1(5) . .
Br2 Pb1 Br5 169.3(6) . .
N5 Pb2 N2 168.6(5) . 2_767
N5 Pb2 O5 73.4(5) . .
N2 Pb2 O5 114.2(5) 2_767 .
N5 Pb2 Br2 87.5(4) . .
N2 Pb2 Br2 86.5(3) 2_767 .
O5 Pb2 Br2 74.7(4) . .
N5 Pb2 Br1 82.4(4) . .
N2 Pb2 Br1 87.7(3) 2_767 .
O5 Pb2 Br1 150.8(3) . .
Br2 Pb2 Br1 88.36(6) . .
N5 Pb2 Br7 87.6(6) . 1_455
N2 Pb2 Br7 97.5(6) 2_767 1_455
O5 Pb2 Br7 108.4(6) . 1_455
Br2 Pb2 Br7 173.1(5) . 1_455
Br1 Pb2 Br7 86.2(5) . 1_455
N5 Pb2 Br6 94.3(9) . .
N2 Pb2 Br6 94.8(8) 2_767 .
O5 Pb2 Br6 23.2(8) . .
Br2 Pb2 Br6 85.1(6) . .
Br1 Pb2 Br6 172.8(7) . .
Br7 Pb2 Br6 100.1(8) 1_455 .
N10 Pb3 N14 168.7(5) 2_557 2_756
N10 Pb3 O8 71.8(5) 2_557 .
N14 Pb3 O8 113.9(5) 2_756 .
N10 Pb3 Br3 86.7(4) 2_557 .
N14 Pb3 Br3 85.6(4) 2_756 .
O8 Pb3 Br3 74.3(3) . .
N10 Pb3 Br4 83.1(4) 2_557 .
N14 Pb3 Br4 88.3(4) 2_756 .
O8 Pb3 Br4 150.0(3) . .
Br3 Pb3 Br4 88.41(6) . .
N10 Pb3 Br7 102.2(7) 2_557 .
N14 Pb3 Br7 85.0(6) 2_756 .
O8 Pb3 Br7 31.0(6) . .
Br3 Pb3 Br7 81.8(5) . .
Br4 Pb3 Br7 168.5(5) . .
N13 Pb4 O11 72.4(6) . .
N13 Pb4 N9 167.9(5) . .
O11 Pb4 N9 112.4(5) . .
N13 Pb4 Br4 85.7(4) . .
O11 Pb4 Br4 73.9(4) . .
N9 Pb4 Br4 85.1(4) . .
N13 Pb4 Br3 81.8(4) . .
O11 Pb4 Br3 149.3(3) . .
N9 Pb4 Br3 90.1(4) . .
Br4 Pb4 Br3 88.19(6) . .
N13 Pb4 Br5 89.0(7) . 1_545
O11 Pb4 Br5 109.8(7) . 1_545
N9 Pb4 Br5 99.3(6) . 1_545
Br4 Pb4 Br5 172.3(5) . 1_545
Br3 Pb4 Br5 85.5(5) . 1_545
N13 Pb4 Br8 93.2(8) . .
O11 Pb4 Br8 22.7(7) . .
N9 Pb4 Br8 93.6(7) . .
Br4 Pb4 Br8 84.0(6) . .
Br3 Pb4 Br8 171.0(6) . .
Br5 Pb4 Br8 102.0(8) 1_545 .
Pb1 Br1 Pb2 91.75(7) . .
Pb2 Br2 Pb1 91.64(7) . .
Pb3 Br3 Pb4 91.49(7) . .
Pb4 Br4 Pb3 91.91(7) . .
Pb4 Br5 Pb1 134.2(10) 1_565 .
Pb2 Br7 Pb3 135.6(10) 1_655 .
C1 N1 C5 119(2) . .
C1 N1 Pb1 122.4(16) . .
C5 N1 Pb1 118.5(14) . .
C2 C1 N1 124(2) . .
C1 C2 C3 120(2) . .
C4 C3 C2 116.2(19) . .
C4 C3 C6 120(2) . .
C2 C3 C6 123.5(19) . .
C5 C4 C3 119(2) . .
N1 C5 C4 123(2) . .
N3 C6 C7 127.0(17) . .
N3 C6 C3 112.4(19) . .
C7 C6 C3 119.9(19) . .
C12 N2 C8 115.3(17) . .
C12 N2 Pb2 121.3(12) . 2_767
C8 N2 Pb2 117.0(12) . 2_767
N2 C8 C9 123.2(18) . .
C10 C9 C8 117.4(19) . .
C9 C10 C11 116.0(17) . .
C9 C10 C13 122.3(19) . .
C11 C10 C13 121.4(18) . .
C12 C11 C10 119.2(19) . .
C11 C12 N2 126(2) . .
C6 N3 N4 113.3(17) . .
C13 N4 N3 111.5(17) . .
N4 C13 C14 128.2(18) . .
N4 C13 C10 113.7(19) . .
C14 C13 C10 118.1(19) . .
C15 N5 C19 116(2) . .
C15 N5 Pb2 122.8(16) . .
C19 N5 Pb2 121.1(15) . .
N5 C15 C16 124(2) . .
C17 C16 C15 120(2) . .
C18 C17 C16 118(2) . .
C18 C17 C20 119.3(19) . .
C16 C17 C20 122(2) . .
C17 C18 C19 120(2) . .
N5 C19 C18 122(2) . .
N7 C20 C17 116.4(19) . .
N7 C20 C21 126.2(19) . .
C17 C20 C21 117.4(18) . .
C26 N6 C22 118.6(17) . .
C26 N6 Pb1 122.3(13) . 2_566
C22 N6 Pb1 115.6(11) . 2_566
N6 C22 C23 119.1(17) . .
C24 C23 C22 116.7(18) . .
C23 C24 C25 118(2) . .
C23 C24 C27 118.8(19) . .
C25 C24 C27 122(2) . .
C26 C25 C24 121(2) . .
N6 C26 C25 123(2) . .
C20 N7 N8 113.4(17) . .
C27 N8 N7 114.4(16) . .
N8 C27 C24 116.6(18) . .
N8 C27 C28 123.2(17) . .
C24 C27 C28 120.2(17) . .
C29 N9 C33 116.7(18) . .
C29 N9 Pb4 120.6(14) . .
C33 N9 Pb4 116.3(12) . .
N9 C29 C30 121.0(19) . .
C29 C30 C31 123(2) . .
C32 C31 C30 114.5(19) . .
C32 C31 C34 120.6(18) . .
C30 C31 C34 124.8(19) . .
C33 C32 C31 121.2(18) . .
C32 C33 N9 123.0(18) . .
N11 C34 C31 115.4(18) . .
N11 C34 C35 125.8(18) . .
C31 C34 C35 118.8(18) . .
C36 N10 C40 119(2) . .
C36 N10 Pb3 121.6(16) . 2_557
C40 N10 Pb3 118.5(15) . 2_557
N10 C36 C37 120(2) . .
C38 C37 C36 121(2) . .
C37 C38 C39 117(2) . .
C37 C38 C41 119(2) . .
C39 C38 C41 124(2) . .
C38 C39 C40 120(2) . .
N10 C40 C39 122(2) . .
C34 N11 N12 112.0(16) . .
C41 N12 N11 113.6(16) . .
N12 C41 C38 118.1(19) . .
N12 C41 C42 125.6(17) . .
C38 C41 C42 116.1(18) . .
C43 N13 C47 115(2) . .
C43 N13 Pb4 122.7(16) . .
C47 N13 Pb4 121.8(16) . .
N13 C43 C44 126(2) . .
C43 C44 C45 118(2) . .
C44 C45 C46 116.8(19) . .
C44 C45 C48 124(2) . .
C46 C45 C48 119(2) . .
C47 C46 C45 119(2) . .
N13 C47 C46 124(2) . .
N15 C48 C49 127.0(18) . .
N15 C48 C45 111.7(18) . .
C49 C48 C45 121.2(19) . .
C54 N14 C50 116.0(18) . .
C54 N14 Pb3 120.4(13) . 2_756
C50 N14 Pb3 120.3(13) . 2_756
N14 C50 C51 126(2) . .
C52 C51 C50 116.2(19) . .
C51 C52 C53 117.6(17) . .
C51 C52 C55 119.3(19) . .
C53 C52 C55 123.0(18) . .
C52 C53 C54 119.5(18) . .
N14 C54 C53 124.0(18) . .
C48 N15 N16 114.5(17) . .
C55 N16 N15 113.7(16) . .
N16 C55 C56 127.3(18) . .
N16 C55 C52 112.8(17) . .
C56 C55 C52 119.9(18) . .
O1 N17 O3 121(2) . .
O1 N17 O2 119.8(18) . .
O3 N17 O2 118.2(19) . .
N17 O1 Pb1 98.3(12) . .
O4 N18 O6 129(2) . .
O4 N18 O5 116.8(19) . .
O6 N18 O5 111.1(18) . .
N18 O5 Pb2 96.4(11) . .
O8 N19 O9 121(2) . .
O8 N19 O7 120.0(19) . .
O9 N19 O7 118.3(19) . .
N19 O8 Pb3 99.5(13) . .
O10 N20 O12 132(2) . .
O10 N20 O11 116(2) . .
O12 N20 O11 107.6(18) . .
N20 O11 Pb4 94.6(11) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pb1 N1 2.645(19) .
Pb1 O1 2.734(15) .
Pb1 N6 2.753(16) 2_566
Pb1 Br1 2.949(2) .
Pb1 Br2 2.965(2) .
Pb1 Br5 3.07(2) .
Pb2 N5 2.622(19) .
Pb2 N2 2.741(16) 2_767
Pb2 O5 2.759(14) .
Pb2 Br2 2.949(2) .
Pb2 Br1 2.959(2) .
Pb2 Br7 2.98(3) 1_455
Pb2 Br6 3.07(2) .
Pb3 N10 2.639(19) 2_557
Pb3 N14 2.708(17) 2_756
Pb3 O8 2.741(15) .
Pb3 Br3 2.952(2) .
Pb3 Br4 2.954(2) .
Pb3 Br7 3.06(2) .
Pb4 N13 2.632(19) .
Pb4 O11 2.750(16) .
Pb4 N9 2.773(16) .
Pb4 Br4 2.947(2) .
Pb4 Br3 2.971(2) .
Pb4 Br5 3.01(2) 1_545
Pb4 Br8 3.07(2) .
Br5 Pb4 3.01(2) 1_565
Br7 Pb2 2.98(2) 1_655
N1 C1 1.33(2) .
N1 C5 1.36(3) .
C1 C2 1.32(3) .
C2 C3 1.47(3) .
C3 C4 1.41(3) .
C3 C6 1.50(2) .
C4 C5 1.37(3) .
C6 N3 1.31(2) .
C6 C7 1.43(3) .
N2 C12 1.34(2) .
N2 C8 1.35(2) .
N2 Pb2 2.741(16) 2_767
C8 C9 1.45(3) .
C9 C10 1.41(2) .
C10 C11 1.43(3) .
C10 C13 1.496(19) .
C11 C12 1.31(2) .
N3 N4 1.404(11) .
N4 C13 1.23(2) .
C13 C14 1.46(3) .
N5 C15 1.32(3) .
N5 C19 1.32(3) .
C15 C16 1.38(3) .
C16 C17 1.35(3) .
C17 C18 1.30(3) .
C17 C20 1.49(2) .
C18 C19 1.45(3) .
C20 N7 1.26(2) .
C20 C21 1.58(3) .
N6 C26 1.30(2) .
N6 C22 1.33(2) .
N6 Pb1 2.753(16) 2_566
C22 C23 1.47(2) .
C23 C24 1.35(3) .
C24 C25 1.37(3) .
C24 C27 1.49(2) .
C25 C26 1.34(2) .
N7 N8 1.407(11) .
N8 C27 1.34(2) .
C27 C28 1.51(2) .
N9 C29 1.29(2) .
N9 C33 1.44(2) .
C29 C30 1.39(3) .
C30 C31 1.40(2) .
C31 C32 1.39(3) .
C31 C34 1.46(2) .
C32 C33 1.32(2) .
C34 N11 1.27(2) .
C34 C35 1.54(3) .
N10 C36 1.35(3) .
N10 C40 1.35(3) .
N10 Pb3 2.639(19) 2_557
C36 C37 1.42(3) .
C37 C38 1.38(3) .
C38 C39 1.39(3) .
C38 C41 1.42(2) .
C39 C40 1.41(3) .
N11 N12 1.420(11) .
N12 C41 1.28(2) .
C41 C42 1.58(3) .
N13 C43 1.30(3) .
N13 C47 1.34(3) .
C43 C44 1.34(3) .
C44 C45 1.39(3) .
C45 C46 1.40(3) .
C45 C48 1.54(2) .
C46 C47 1.34(3) .
C48 N15 1.27(2) .
C48 C49 1.45(3) .
N14 C54 1.26(2) .
N14 C50 1.36(2) .
N14 Pb3 2.708(17) 2_756
C50 C51 1.39(2) .
C51 C52 1.38(3) .
C52 C53 1.39(3) .
C52 C55 1.51(2) .
C53 C54 1.41(2) .
N15 N16 1.406(11) .
N16 C55 1.32(2) .
C55 C56 1.43(3) .
N17 O1 1.25(2) .
N17 O3 1.25(2) .
N17 O2 1.34(3) .
N18 O4 1.09(2) .
N18 O6 1.22(2) .
N18 O5 1.35(3) .
N19 O8 1.21(2) .
N19 O9 1.24(2) .
N19 O7 1.31(3) .
N20 O10 1.09(2) .
N20 O12 1.24(2) .
N20 O11 1.41(3) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 Pb1 Br1 Pb2 -83.6(4) . .
O1 Pb1 Br1 Pb2 -155.1(3) . .
N6 Pb1 Br1 Pb2 89.5(3) 2_566 .
Br2 Pb1 Br1 Pb2 -1.12(8) . .
Br5 Pb1 Br1 Pb2 174.5(5) . .
N5 Pb2 Br1 Pb1 -86.5(4) . .
N2 Pb2 Br1 Pb1 87.7(3) 2_767 .
O5 Pb2 Br1 Pb1 -52.5(8) . .
Br2 Pb2 Br1 Pb1 1.12(8) . .
Br7 Pb2 Br1 Pb1 -174.6(5) 1_455 .
Br6 Pb2 Br1 Pb1 -23(6) . .
N5 Pb2 Br2 Pb1 81.4(4) . .
N2 Pb2 Br2 Pb1 -89.0(3) 2_767 .
O5 Pb2 Br2 Pb1 154.8(4) . .
Br1 Pb2 Br2 Pb1 -1.12(8) . .
Br7 Pb2 Br2 Pb1 37(4) 1_455 .
Br6 Pb2 Br2 Pb1 175.9(8) . .
N1 Pb1 Br2 Pb2 86.3(4) . .
O1 Pb1 Br2 Pb2 54.7(6) . .
N6 Pb1 Br2 Pb2 -83.6(3) 2_566 .
Br1 Pb1 Br2 Pb2 1.12(8) . .
Br5 Pb1 Br2 Pb2 -23(3) . .
N10 Pb3 Br3 Pb4 82.7(4) 2_557 .
N14 Pb3 Br3 Pb4 -89.0(4) 2_756 .
O8 Pb3 Br3 Pb4 154.7(3) . .
Br4 Pb3 Br3 Pb4 -0.53(9) . .
Br7 Pb3 Br3 Pb4 -174.5(5) . .
N13 Pb4 Br3 Pb3 86.4(4) . .
O11 Pb4 Br3 Pb3 54.0(7) . .
N9 Pb4 Br3 Pb3 -84.6(3) . .
Br4 Pb4 Br3 Pb3 0.53(9) . .
Br5 Pb4 Br3 Pb3 176.1(5) 1_545 .
Br8 Pb4 Br3 Pb3 30(3) . .
N13 Pb4 Br4 Pb3 -82.4(4) . .
O11 Pb4 Br4 Pb3 -155.3(4) . .
N9 Pb4 Br4 Pb3 89.8(3) . .
Br3 Pb4 Br4 Pb3 -0.53(9) . .
Br5 Pb4 Br4 Pb3 -35(4) 1_545 .
Br8 Pb4 Br4 Pb3 -176.1(6) . .
N10 Pb3 Br4 Pb4 -86.4(4) 2_557 .
N14 Pb3 Br4 Pb4 86.2(4) 2_756 .
O8 Pb3 Br4 Pb4 -53.3(7) . .
Br3 Pb3 Br4 Pb4 0.53(9) . .
Br7 Pb3 Br4 Pb4 32(3) . .
N1 Pb1 Br5 Pb4 150.1(12) . 1_565
O1 Pb1 Br5 Pb4 162(2) . 1_565
N6 Pb1 Br5 Pb4 -41.2(12) 2_566 1_565
Br1 Pb1 Br5 Pb4 -126.6(13) . 1_565
Br2 Pb1 Br5 Pb4 -102(3) . 1_565
N10 Pb3 Br7 Pb2 -147.9(12) 2_557 1_655
N14 Pb3 Br7 Pb2 41.0(12) 2_756 1_655
O8 Pb3 Br7 Pb2 -160(2) . 1_655
Br3 Pb3 Br7 Pb2 127.2(12) . 1_655
Br4 Pb3 Br7 Pb2 95(3) . 1_655
O1 Pb1 N1 C1 38.5(17) . .
N6 Pb1 N1 C1 -70(3) 2_566 .
Br1 Pb1 N1 C1 -35.8(17) . .
Br2 Pb1 N1 C1 -124.7(17) . .
Br5 Pb1 N1 C1 45.1(18) . .
O1 Pb1 N1 C5 -148.4(19) . .
N6 Pb1 N1 C5 104(3) 2_566 .
Br1 Pb1 N1 C5 137.3(18) . .
Br2 Pb1 N1 C5 48.4(17) . .
Br5 Pb1 N1 C5 -141.8(18) . .
C5 N1 C1 C2 -2(4) . .
Pb1 N1 C1 C2 171.4(18) . .
N1 C1 C2 C3 1(4) . .
C1 C2 C3 C4 1(3) . .
C1 C2 C3 C6 -179(2) . .
C2 C3 C4 C5 -2(3) . .
C6 C3 C4 C5 178.8(19) . .
C1 N1 C5 C4 1(4) . .
Pb1 N1 C5 C4 -172.3(17) . .
C3 C4 C5 N1 1(4) . .
C4 C3 C6 N3 -161.0(19) . .
C2 C3 C6 N3 20(3) . .
C4 C3 C6 C7 10(3) . .
C2 C3 C6 C7 -169(2) . .
C12 N2 C8 C9 3(3) . .
Pb2 N2 C8 C9 155.4(15) 2_767 .
N2 C8 C9 C10 -3(3) . .
C8 C9 C10 C11 9(3) . .
C8 C9 C10 C13 -176.9(17) . .
C9 C10 C11 C12 -18(3) . .
C13 C10 C11 C12 168.7(18) . .
C10 C11 C12 N2 20(3) . .
C8 N2 C12 C11 -12(3) . .
Pb2 N2 C12 C11 -163.3(15) 2_767 .
C7 C6 N3 N4 5(3) . .
C3 C6 N3 N4 175.5(15) . .
C6 N3 N4 C13 -177.1(19) . .
N3 N4 C13 C14 3(3) . .
N3 N4 C13 C10 179.3(16) . .
C9 C10 C13 N4 166.0(18) . .
C11 C10 C13 N4 -21(3) . .
C9 C10 C13 C14 -17(3) . .
C11 C10 C13 C14 156.2(18) . .
N2 Pb2 N5 C15 -78(3) 2_767 .
O5 Pb2 N5 C15 149(2) . .
Br2 Pb2 N5 C15 -136.3(19) . .
Br1 Pb2 N5 C15 -47.7(18) . .
Br7 Pb2 N5 C15 38.8(19) 1_455 .
Br6 Pb2 N5 C15 138.8(19) . .
N2 Pb2 N5 C19 94(3) 2_767 .
O5 Pb2 N5 C19 -38.6(16) . .
Br2 Pb2 N5 C19 36.1(17) . .
Br1 Pb2 N5 C19 124.8(17) . .
Br7 Pb2 N5 C19 -148.7(17) 1_455 .
Br6 Pb2 N5 C19 -48.8(18) . .
C19 N5 C15 C16 1(4) . .
Pb2 N5 C15 C16 173.5(17) . .
N5 C15 C16 C17 -3(4) . .
C15 C16 C17 C18 3(3) . .
C15 C16 C17 C20 -174.3(19) . .
C16 C17 C18 C19 -1(3) . .
C20 C17 C18 C19 176.1(18) . .
C15 N5 C19 C18 1(3) . .
Pb2 N5 C19 C18 -171.8(15) . .
C17 C18 C19 N5 -1(4) . .
C18 C17 C20 N7 -14(3) . .
C16 C17 C20 N7 163(2) . .
C18 C17 C20 C21 164.6(19) . .
C16 C17 C20 C21 -18(3) . .
C26 N6 C22 C23 -16(3) . .
Pb1 N6 C22 C23 143.2(13) 2_566 .
N6 C22 C23 C24 21(3) . .
C22 C23 C24 C25 -15(3) . .
C22 C23 C24 C27 172.8(15) . .
C23 C24 C25 C26 5(3) . .
C27 C24 C25 C26 177.0(18) . .
C22 N6 C26 C25 6(3) . .
Pb1 N6 C26 C25 -152.2(16) 2_566 .
C24 C25 C26 N6 0(3) . .
C17 C20 N7 N8 -177.2(15) . .
C21 C20 N7 N8 4(3) . .
C20 N7 N8 C27 173.2(17) . .
N7 N8 C27 C24 -178.4(16) . .
N7 N8 C27 C28 3(3) . .
C23 C24 C27 N8 9(3) . .
C25 C24 C27 N8 -162.5(18) . .
C23 C24 C27 C28 -172.7(18) . .
C25 C24 C27 C28 16(3) . .
N13 Pb4 N9 C29 88(3) . .
O11 Pb4 N9 C29 -22.6(18) . .
Br4 Pb4 N9 C29 47.8(16) . .
Br3 Pb4 N9 C29 136.0(16) . .
Br5 Pb4 N9 C29 -138.6(17) 1_545 .
Br8 Pb4 N9 C29 -35.9(17) . .
N13 Pb4 N9 C33 -121(3) . .
O11 Pb4 N9 C33 128.3(12) . .
Br4 Pb4 N9 C33 -161.3(13) . .
Br3 Pb4 N9 C33 -73.1(12) . .
Br5 Pb4 N9 C33 12.3(14) 1_545 .
Br8 Pb4 N9 C33 115.0(14) . .
C33 N9 C29 C30 4(3) . .
Pb4 N9 C29 C30 155.3(15) . .
N9 C29 C30 C31 -5(3) . .
C29 C30 C31 C32 0(3) . .
C29 C30 C31 C34 -176.0(19) . .
C30 C31 C32 C33 4(3) . .
C34 C31 C32 C33 -179.4(18) . .
C31 C32 C33 N9 -5(3) . .
C29 N9 C33 C32 0(3) . .
Pb4 N9 C33 C32 -152.1(15) . .
C32 C31 C34 N11 -9(3) . .
C30 C31 C34 N11 166.7(18) . .
C32 C31 C34 C35 168.8(18) . .
C30 C31 C34 C35 -15(3) . .
C40 N10 C36 C37 3(4) . .
Pb3 N10 C36 C37 171.9(17) 2_557 .
N10 C36 C37 C38 -1(4) . .
C36 C37 C38 C39 -1(3) . .
C36 C37 C38 C41 -174(2) . .
C37 C38 C39 C40 0(3) . .
C41 C38 C39 C40 173(2) . .
C36 N10 C40 C39 -4(4) . .
Pb3 N10 C40 C39 -173.3(15) 2_557 .
C38 C39 C40 N10 3(3) . .
C31 C34 N11 N12 179.3(16) . .
C35 C34 N11 N12 1(3) . .
C34 N11 N12 C41 -176.7(19) . .
N11 N12 C41 C38 178.5(16) . .
N11 N12 C41 C42 4(3) . .
C37 C38 C41 N12 14(3) . .
C39 C38 C41 N12 -159(2) . .
C37 C38 C41 C42 -170.6(18) . .
C39 C38 C41 C42 16(3) . .
O11 Pb4 N13 C43 37.8(18) . .
N9 Pb4 N13 C43 -77(3) . .
Br4 Pb4 N13 C43 -36.7(18) . .
Br3 Pb4 N13 C43 -125.5(18) . .
Br5 Pb4 N13 C43 148.9(19) 1_545 .
Br8 Pb4 N13 C43 47.0(19) . .
O11 Pb4 N13 C47 -146(2) . .
N9 Pb4 N13 C47 99(3) . .
Br4 Pb4 N13 C47 139.2(19) . .
Br3 Pb4 N13 C47 50.4(18) . .
Br5 Pb4 N13 C47 -35.2(19) 1_545 .
Br8 Pb4 N13 C47 -137.1(19) . .
C47 N13 C43 C44 -5(4) . .
Pb4 N13 C43 C44 171.6(19) . .
N13 C43 C44 C45 2(4) . .
C43 C44 C45 C46 3(3) . .
C43 C44 C45 C48 -180(2) . .
C44 C45 C46 C47 -4(3) . .
C48 C45 C46 C47 178(2) . .
C43 N13 C47 C46 3(4) . .
Pb4 N13 C47 C46 -173.2(18) . .
C45 C46 C47 N13 1(4) . .
C44 C45 C48 N15 17(3) . .
C46 C45 C48 N15 -165.3(18) . .
C44 C45 C48 C49 -162(2) . .
C46 C45 C48 C49 16(3) . .
C54 N14 C50 C51 -7(3) . .
Pb3 N14 C50 C51 152.1(16) 2_756 .
N14 C50 C51 C52 1(3) . .
C50 C51 C52 C53 6(3) . .
C50 C51 C52 C55 -178.1(16) . .
C51 C52 C53 C54 -6(2) . .
C55 C52 C53 C54 177.7(16) . .
C50 N14 C54 C53 7(3) . .
Pb3 N14 C54 C53 -152.5(13) 2_756 .
C52 C53 C54 N14 0(3) . .
C49 C48 N15 N16 -6(3) . .
C45 C48 N15 N16 175.2(14) . .
C48 N15 N16 C55 -172.6(18) . .
N15 N16 C55 C56 -4(3) . .
N15 N16 C55 C52 178.5(15) . .
C51 C52 C55 N16 162.1(16) . .
C53 C52 C55 N16 -22(3) . .
C51 C52 C55 C56 -16(3) . .
C53 C52 C55 C56 159.9(18) . .
O3 N17 O1 Pb1 171.9(17) . .
O2 N17 O1 Pb1 1(2) . .
N1 Pb1 O1 N17 160.6(13) . .
N6 Pb1 O1 N17 -32.1(13) 2_566 .
Br1 Pb1 O1 N17 -109.0(12) . .
Br2 Pb1 O1 N17 -166.0(10) . .
Br5 Pb1 O1 N17 -6.6(16) . .
O4 N18 O5 Pb2 12(2) . .
O6 N18 O5 Pb2 173.5(14) . .
N5 Pb2 O5 N18 -169.1(12) . .
N2 Pb2 O5 N18 19.9(13) 2_767 .
Br2 Pb2 O5 N18 98.9(11) . .
Br1 Pb2 O5 N18 155.5(8) . .
Br7 Pb2 O5 N18 -87.5(12) 1_455 .
Br6 Pb2 O5 N18 -15.5(17) . .
O9 N19 O8 Pb3 -173.2(17) . .
O7 N19 O8 Pb3 1(2) . .
N10 Pb3 O8 N19 -162.0(13) 2_557 .
N14 Pb3 O8 N19 28.4(14) 2_756 .
Br3 Pb3 O8 N19 106.2(12) . .
Br4 Pb3 O8 N19 163.2(10) . .
Br7 Pb3 O8 N19 5.8(15) . .
O10 N20 O11 Pb4 -12(2) . .
O12 N20 O11 Pb4 -172.7(14) . .
N13 Pb4 O11 N20 168.8(12) . .
N9 Pb4 O11 N20 -23.1(12) . .
Br4 Pb4 O11 N20 -100.7(11) . .
Br3 Pb4 O11 N20 -157.3(8) . .
Br5 Pb4 O11 N20 86.5(12) 1_545 .
Br8 Pb4 O11 N20 13.2(16) . .
