#------------------------------------------------------------------------------
#$Date: 2016-03-25 16:51:56 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179993 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/87/7028768.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7028768
loop_
_publ_author_name
'Hu, Xiao-Hui'
'Liang, Yan'
'Li, Chen'
'Yi, Xiao-Yi'
_publ_section_title
;
 Multi-nuclear silver(i) and copper(i) complexes: a novel bonding mode for
 bispyridylpyrrolides.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2458
_journal_page_last               2464
_journal_paper_doi               10.1039/c3dt52794h
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C36 H36 Cu N6 Na O2'
_chemical_formula_weight         671.24
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           43
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'F 2 -2d'
_symmetry_space_group_name_H-M   'F d d 2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   11.6882(3)
_cell_length_b                   30.6434(8)
_cell_length_c                   18.0484(5)
_cell_measurement_reflns_used    7123
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.55
_cell_measurement_theta_min      2.66
_cell_volume                     6464.3(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0137
_diffrn_reflns_av_unetI/netI     0.0319
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -38
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            7241
_diffrn_reflns_theta_full        27.55
_diffrn_reflns_theta_max         27.55
_diffrn_reflns_theta_min         2.18
_exptl_absorpt_coefficient_mu    0.732
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6596
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.379
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2800
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.1
_refine_diff_density_max         0.209
_refine_diff_density_min         -0.215
_refine_diff_density_rms         0.046
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.023(9)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.049
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     210
_refine_ls_number_reflns         2976
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.049
_refine_ls_R_factor_all          0.0180
_refine_ls_R_factor_gt           0.0178
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0242P)²+3.9959P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0530
_refine_ls_wR_factor_ref         0.0532
_reflns_number_gt                2949
_reflns_number_total             2976
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt52794h.txt
_cod_data_source_block           complex_4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/usr/data/users/saulius/automatic-downloads/current/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_sg_symbol_H-M      'Fdd2 '
_cod_database_code               7028768
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x+1/4, y+1/4, z+1/4'
'x+3/4, -y+3/4, z+1/4'
'x, y+1/2, z+1/2'
'-x, -y+1/2, z+1/2'
'-x+1/4, y+3/4, z+3/4'
'x+3/4, -y+5/4, z+3/4'
'x+1/2, y, z+1/2'
'-x+1/2, -y, z+1/2'
'-x+3/4, y+1/4, z+3/4'
'x+5/4, -y+3/4, z+3/4'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z'
'-x+3/4, y+3/4, z+1/4'
'x+5/4, -y+5/4, z+1/4'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cu1 Cu -0.2500 -0.2500 0.221725(15) 0.01557(6) Uani 1 2 d S
Na1 Na -0.2500 -0.2500 0.06145(5) 0.01707(18) Uani 1 2 d S
O1 O -0.37965(9) -0.26146(4) -0.03788(7) 0.0268(2) Uani 1 1 d .
N1 N -0.09464(10) -0.25736(4) 0.16953(7) 0.0136(2) Uani 1 1 d .
N2 N -0.17698(9) -0.19514(4) 0.25938(6) 0.0155(2) Uani 1 1 d .
N3 N -0.18803(10) -0.32503(4) 0.08111(7) 0.0172(2) Uani 1 1 d .
C1 C -0.22580(14) -0.16267(5) 0.29811(8) 0.0212(3) Uani 1 1 d .
H1A H -0.3009 -0.1663 0.3140 0.025 Uiso 1 1 calc R
C2 C -0.17097(15) -0.12442(5) 0.31559(9) 0.0261(3) Uani 1 1 d .
H2A H -0.2081 -0.1027 0.3425 0.031 Uiso 1 1 calc R
C3 C -0.05876(15) -0.11888(5) 0.29210(10) 0.0284(3) Uani 1 1 d .
H3A H -0.0193 -0.0933 0.3031 0.034 Uiso 1 1 calc R
C4 C -0.00673(13) -0.15165(6) 0.25227(10) 0.0247(3) Uani 1 1 d .
H4A H 0.0684 -0.1484 0.2363 0.030 Uiso 1 1 calc R
C5 C -0.06722(11) -0.18988(5) 0.23590(7) 0.0159(3) Uani 1 1 d .
C6 C -0.02040(11) -0.22595(5) 0.19450(8) 0.0158(3) Uani 1 1 d .
C7 C 0.09299(12) -0.23756(6) 0.17873(9) 0.0214(3) Uani 1 1 d .
H7A H 0.1584 -0.2216 0.1897 0.026 Uiso 1 1 calc R
C8 C 0.08790(11) -0.27784(5) 0.14334(9) 0.0205(3) Uani 1 1 d .
H8A H 0.1496 -0.2941 0.1261 0.025 Uiso 1 1 calc R
C9 C -0.02854(11) -0.28924(5) 0.13863(8) 0.0154(3) Uani 1 1 d .
C10 C -0.07966(11) -0.32847(5) 0.10686(7) 0.0153(3) Uani 1 1 d .
C11 C -0.01967(13) -0.36780(5) 0.10292(9) 0.0218(3) Uani 1 1 d .
H11A H 0.0550 -0.3695 0.1205 0.026 Uiso 1 1 calc R
C12 C -0.07169(14) -0.40415(5) 0.07286(9) 0.0262(3) Uani 1 1 d .
H12A H -0.0323 -0.4304 0.0696 0.031 Uiso 1 1 calc R
C13 C -0.18346(14) -0.40102(5) 0.04759(9) 0.0248(3) Uani 1 1 d .
H13A H -0.2211 -0.4251 0.0278 0.030 Uiso 1 1 calc R
C14 C -0.23680(12) -0.36100(5) 0.05285(10) 0.0222(3) Uani 1 1 d .
H14A H -0.3116 -0.3588 0.0357 0.027 Uiso 1 1 calc R
C15 C -0.40549(17) -0.22530(6) -0.08456(10) 0.0369(4) Uani 1 1 d .
H15A H -0.3955 -0.2330 -0.1363 0.044 Uiso 1 1 calc R
H15B H -0.3564 -0.2007 -0.0731 0.044 Uiso 1 1 calc R
C16 C -0.5287(2) -0.21457(7) -0.06842(11) 0.0441(5) Uani 1 1 d .
H16A H -0.5364 -0.1978 -0.0231 0.053 Uiso 1 1 calc R
H16B H -0.5637 -0.1987 -0.1090 0.053 Uiso 1 1 calc R
C17 C -0.57920(18) -0.25933(8) -0.06035(15) 0.0507(6) Uani 1 1 d .
H17A H -0.5980 -0.2718 -0.1082 0.061 Uiso 1 1 calc R
H17B H -0.6474 -0.2587 -0.0298 0.061 Uiso 1 1 calc R
C18 C -0.48356(13) -0.28465(6) -0.02294(13) 0.0303(4) Uani 1 1 d .
H18A H -0.4968 -0.2864 0.0300 0.036 Uiso 1 1 calc R
H18B H -0.4794 -0.3140 -0.0427 0.036 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Cu1 N2 140.35(7) . 14_445
N2 Cu1 N1 116.04(5) . 14_445
N2 Cu1 N1 82.61(5) 14_445 14_445
N2 Cu1 N1 82.61(5) . .
N2 Cu1 N1 116.04(5) 14_445 .
N1 Cu1 N1 125.52(7) 14_445 .
N2 Cu1 Na1 109.82(4) . .
N2 Cu1 Na1 109.82(4) 14_445 .
N1 Cu1 Na1 62.76(3) 14_445 .
N1 Cu1 Na1 62.76(3) . .
O1 Na1 O1 81.89(6) . 14_445
O1 Na1 N3 93.43(4) . 14_445
O1 Na1 N3 99.21(4) 14_445 14_445
O1 Na1 N3 99.21(4) . .
O1 Na1 N3 93.43(4) 14_445 .
N3 Na1 N3 163.26(7) 14_445 .
O1 Na1 N1 166.37(4) . .
O1 Na1 N1 97.46(4) 14_445 .
N3 Na1 N1 100.09(4) 14_445 .
N3 Na1 N1 67.19(4) . .
O1 Na1 N1 97.46(4) . 14_445
O1 Na1 N1 166.37(4) 14_445 14_445
N3 Na1 N1 67.19(4) 14_445 14_445
N3 Na1 N1 100.09(4) . 14_445
N1 Na1 N1 86.34(6) . 14_445
O1 Na1 Cu1 139.05(3) . .
O1 Na1 Cu1 139.05(3) 14_445 .
N3 Na1 Cu1 81.63(3) 14_445 .
N3 Na1 Cu1 81.63(3) . .
N1 Na1 Cu1 43.17(3) . .
N1 Na1 Cu1 43.17(3) 14_445 .
C15 O1 C18 108.51(13) . .
C15 O1 Na1 117.84(10) . .
C18 O1 Na1 118.19(11) . .
C9 N1 C6 106.16(11) . .
C9 N1 Cu1 139.92(10) . .
C6 N1 Cu1 109.32(9) . .
C9 N1 Na1 98.44(8) . .
C6 N1 Na1 127.58(9) . .
Cu1 N1 Na1 74.07(4) . .
C1 N2 C5 118.35(13) . .
C1 N2 Cu1 128.09(10) . .
C5 N2 Cu1 113.28(9) . .
C14 N3 C10 117.66(13) . .
C14 N3 Na1 126.41(10) . .
C10 N3 Na1 113.69(9) . .
N2 C1 C2 123.63(15) . .
N2 C1 H1A 118.2 . .
C2 C1 H1A 118.2 . .
C1 C2 C3 118.38(15) . .
C1 C2 H2A 120.8 . .
C3 C2 H2A 120.8 . .
C4 C3 C2 119.17(15) . .
C4 C3 H3A 120.4 . .
C2 C3 H3A 120.4 . .
C3 C4 C5 119.84(14) . .
C3 C4 H4A 120.1 . .
C5 C4 H4A 120.1 . .
N2 C5 C4 120.63(13) . .
N2 C5 C6 115.37(12) . .
C4 C5 C6 124.00(13) . .
N1 C6 C7 110.69(13) . .
N1 C6 C5 117.90(12) . .
C7 C6 C5 131.20(13) . .
C8 C7 C6 106.15(13) . .
C8 C7 H7A 126.9 . .
C6 C7 H7A 126.9 . .
C7 C8 C9 106.81(12) . .
C7 C8 H8A 126.6 . .
C9 C8 H8A 126.6 . .
N1 C9 C8 110.20(12) . .
N1 C9 C10 121.21(12) . .
C8 C9 C10 128.59(13) . .
N3 C10 C11 121.32(13) . .
N3 C10 C9 116.99(12) . .
C11 C10 C9 121.70(12) . .
C12 C11 C10 119.71(14) . .
C12 C11 H11A 120.1 . .
C10 C11 H11A 120.1 . .
C11 C12 C13 119.24(14) . .
C11 C12 H12A 120.4 . .
C13 C12 H12A 120.4 . .
C14 C13 C12 117.68(15) . .
C14 C13 H13A 121.2 . .
C12 C13 H13A 121.2 . .
N3 C14 C13 124.38(14) . .
N3 C14 H14A 117.8 . .
C13 C14 H14A 117.8 . .
O1 C15 C16 104.97(14) . .
O1 C15 H15A 110.8 . .
C16 C15 H15A 110.8 . .
O1 C15 H15B 110.8 . .
C16 C15 H15B 110.8 . .
H15A C15 H15B 108.8 . .
C17 C16 C15 101.25(16) . .
C17 C16 H16A 111.5 . .
C15 C16 H16A 111.5 . .
C17 C16 H16B 111.5 . .
C15 C16 H16B 111.5 . .
H16A C16 H16B 109.3 . .
C16 C17 C18 102.77(15) . .
C16 C17 H17A 111.2 . .
C18 C17 H17A 111.2 . .
C16 C17 H17B 111.2 . .
C18 C17 H17B 111.2 . .
H17A C17 H17B 109.1 . .
O1 C18 C17 106.66(16) . .
O1 C18 H18A 110.4 . .
C17 C18 H18A 110.4 . .
O1 C18 H18B 110.4 . .
C17 C18 H18B 110.4 . .
H18A C18 H18B 108.6 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu1 N2 2.0041(12) .
Cu1 N2 2.0041(12) 14_445
Cu1 N1 2.0581(12) 14_445
Cu1 N1 2.0581(12) .
Cu1 Na1 2.8927(9) .
Na1 O1 2.3736(13) .
Na1 O1 2.3736(13) 14_445
Na1 N3 2.4365(12) 14_445
Na1 N3 2.4365(12) .
Na1 N1 2.6745(13) .
Na1 N1 2.6745(13) 14_445
O1 C15 1.424(2) .
O1 C18 1.4328(19) .
N1 C9 1.3646(17) .
N1 C6 1.3720(17) .
N2 C1 1.3433(19) .
N2 C5 1.3607(17) .
N3 C14 1.3417(19) .
N3 C10 1.3534(17) .
C1 C2 1.372(2) .
C1 H1A 0.9300 .
C2 C3 1.389(2) .
C2 H2A 0.9300 .
C3 C4 1.377(2) .
C3 H3A 0.9300 .
C4 C5 1.400(2) .
C4 H4A 0.9300 .
C5 C6 1.442(2) .
C6 C7 1.4015(19) .
C7 C8 1.391(2) .
C7 H7A 0.9300 .
C8 C9 1.4076(17) .
C8 H8A 0.9300 .
C9 C10 1.4599(19) .
C10 C11 1.396(2) .
C11 C12 1.380(2) .
C11 H11A 0.9300 .
C12 C13 1.387(2) .
C12 H12A 0.9300 .
C13 C14 1.379(2) .
C13 H13A 0.9300 .
C14 H14A 0.9300 .
C15 C16 1.506(3) .
C15 H15A 0.9700 .
C15 H15B 0.9700 .
C16 C17 1.500(3) .
C16 H16A 0.9700 .
C16 H16B 0.9700 .
C17 C18 1.519(3) .
C17 H17A 0.9700 .
C17 H17B 0.9700 .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N2 Cu1 Na1 O1 -129.97(6) . .
N2 Cu1 Na1 O1 50.03(6) 14_445 .
N1 Cu1 Na1 O1 -20.13(6) 14_445 .
N1 Cu1 Na1 O1 159.87(6) . .
N2 Cu1 Na1 O1 50.03(6) . 14_445
N2 Cu1 Na1 O1 -129.97(6) 14_445 14_445
N1 Cu1 Na1 O1 159.87(6) 14_445 14_445
N1 Cu1 Na1 O1 -20.13(6) . 14_445
N2 Cu1 Na1 N3 -44.40(4) . 14_445
N2 Cu1 Na1 N3 135.60(4) 14_445 14_445
N1 Cu1 Na1 N3 65.43(5) 14_445 14_445
N1 Cu1 Na1 N3 -114.57(5) . 14_445
N2 Cu1 Na1 N3 135.60(4) . .
N2 Cu1 Na1 N3 -44.40(4) 14_445 .
N1 Cu1 Na1 N3 -114.57(5) 14_445 .
N1 Cu1 Na1 N3 65.43(5) . .
N2 Cu1 Na1 N1 70.16(5) . .
N2 Cu1 Na1 N1 -109.84(5) 14_445 .
N1 Cu1 Na1 N1 180.0 14_445 .
N2 Cu1 Na1 N1 -109.84(5) . 14_445
N2 Cu1 Na1 N1 70.16(5) 14_445 14_445
N1 Cu1 Na1 N1 180.0 . 14_445
O1 Na1 O1 C15 -65.67(11) 14_445 .
N3 Na1 O1 C15 33.16(13) 14_445 .
N3 Na1 O1 C15 -157.86(12) . .
N1 Na1 O1 C15 -153.92(18) . .
N1 Na1 O1 C15 100.59(12) 14_445 .
Cu1 Na1 O1 C15 114.33(11) . .
O1 Na1 O1 C18 160.67(14) 14_445 .
N3 Na1 O1 C18 -100.50(12) 14_445 .
N3 Na1 O1 C18 68.49(12) . .
N1 Na1 O1 C18 72.4(2) . .
N1 Na1 O1 C18 -33.07(12) 14_445 .
Cu1 Na1 O1 C18 -19.33(14) . .
N2 Cu1 N1 C9 159.02(15) . .
N2 Cu1 N1 C9 15.82(16) 14_445 .
N1 Cu1 N1 C9 -84.14(14) 14_445 .
Na1 Cu1 N1 C9 -84.14(14) . .
N2 Cu1 N1 C6 8.05(9) . .
N2 Cu1 N1 C6 -135.15(9) 14_445 .
N1 Cu1 N1 C6 124.89(10) 14_445 .
Na1 Cu1 N1 C6 124.89(10) . .
N2 Cu1 N1 Na1 -116.83(4) . .
N2 Cu1 N1 Na1 99.96(4) 14_445 .
N1 Cu1 N1 Na1 0.0 14_445 .
O1 Na1 N1 C9 32.9(2) . .
O1 Na1 N1 C9 -53.51(9) 14_445 .
N3 Na1 N1 C9 -154.31(9) 14_445 .
N3 Na1 N1 C9 37.09(8) . .
N1 Na1 N1 C9 139.64(10) 14_445 .
Cu1 Na1 N1 C9 139.64(10) . .
O1 Na1 N1 C6 150.84(18) . .
O1 Na1 N1 C6 64.47(11) 14_445 .
N3 Na1 N1 C6 -36.33(12) 14_445 .
N3 Na1 N1 C6 155.06(12) . .
N1 Na1 N1 C6 -102.38(12) 14_445 .
Cu1 Na1 N1 C6 -102.38(12) . .
O1 Na1 N1 Cu1 -106.77(19) . .
O1 Na1 N1 Cu1 166.85(4) 14_445 .
N3 Na1 N1 Cu1 66.05(4) 14_445 .
N3 Na1 N1 Cu1 -102.56(4) . .
N1 Na1 N1 Cu1 0.0 14_445 .
N2 Cu1 N2 C1 -65.15(12) 14_445 .
N1 Cu1 N2 C1 46.28(13) 14_445 .
N1 Cu1 N2 C1 172.34(13) . .
Na1 Cu1 N2 C1 114.85(12) . .
N2 Cu1 N2 C5 121.04(9) 14_445 .
N1 Cu1 N2 C5 -127.53(9) 14_445 .
N1 Cu1 N2 C5 -1.47(9) . .
Na1 Cu1 N2 C5 -58.96(9) . .
O1 Na1 N3 C14 -12.68(13) . .
O1 Na1 N3 C14 -95.01(13) 14_445 .
N3 Na1 N3 C14 125.87(13) 14_445 .
N1 Na1 N3 C14 168.33(14) . .
N1 Na1 N3 C14 86.67(13) 14_445 .
Cu1 Na1 N3 C14 125.87(13) . .
O1 Na1 N3 C10 149.78(9) . .
O1 Na1 N3 C10 67.45(9) 14_445 .
N3 Na1 N3 C10 -71.66(9) 14_445 .
N1 Na1 N3 C10 -29.21(8) . .
N1 Na1 N3 C10 -110.86(9) 14_445 .
Cu1 Na1 N3 C10 -71.66(9) . .
C5 N2 C1 C2 -0.2(2) . .
Cu1 N2 C1 C2 -173.75(11) . .
N2 C1 C2 C3 -0.1(2) . .
C1 C2 C3 C4 0.1(2) . .
C2 C3 C4 C5 0.1(2) . .
C1 N2 C5 C4 0.45(19) . .
Cu1 N2 C5 C4 174.92(11) . .
C1 N2 C5 C6 -179.83(13) . .
Cu1 N2 C5 C6 -5.36(14) . .
C3 C4 C5 N2 -0.4(2) . .
C3 C4 C5 C6 179.88(15) . .
C9 N1 C6 C7 0.70(16) . .
Cu1 N1 C6 C7 161.72(10) . .
Na1 N1 C6 C7 -113.86(13) . .
C9 N1 C6 C5 -174.58(12) . .
Cu1 N1 C6 C5 -13.57(15) . .
Na1 N1 C6 C5 70.86(15) . .
N2 C5 C6 N1 13.19(18) . .
C4 C5 C6 N1 -167.10(14) . .
N2 C5 C6 C7 -160.94(15) . .
C4 C5 C6 C7 18.8(3) . .
N1 C6 C7 C8 -0.55(18) . .
C5 C6 C7 C8 173.90(15) . .
C6 C7 C8 C9 0.18(18) . .
C6 N1 C9 C8 -0.58(15) . .
Cu1 N1 C9 C8 -152.10(12) . .
Na1 N1 C9 C8 132.64(11) . .
C6 N1 C9 C10 179.22(13) . .
Cu1 N1 C9 C10 27.7(2) . .
Na1 N1 C9 C10 -47.56(13) . .
C7 C8 C9 N1 0.25(17) . .
C7 C8 C9 C10 -179.54(15) . .
C14 N3 C10 C11 1.2(2) . .
Na1 N3 C10 C11 -162.87(12) . .
C14 N3 C10 C9 -178.95(13) . .
Na1 N3 C10 C9 16.94(14) . .
N1 C9 C10 N3 26.75(19) . .
C8 C9 C10 N3 -153.49(14) . .
N1 C9 C10 C11 -153.43(14) . .
C8 C9 C10 C11 26.3(2) . .
N3 C10 C11 C12 -0.6(2) . .
C9 C10 C11 C12 179.58(14) . .
C10 C11 C12 C13 -0.6(2) . .
C11 C12 C13 C14 1.0(2) . .
C10 N3 C14 C13 -0.7(2) . .
Na1 N3 C14 C13 161.10(13) . .
C12 C13 C14 N3 -0.4(3) . .
C18 O1 C15 C16 26.4(2) . .
Na1 O1 C15 C16 -111.39(13) . .
O1 C15 C16 C17 -39.1(2) . .
C15 C16 C17 C18 36.1(2) . .
C15 O1 C18 C17 -2.8(2) . .
Na1 O1 C18 C17 134.75(15) . .
C16 C17 C18 O1 -21.7(2) . .
