#------------------------------------------------------------------------------
#$Date: 2016-03-25 16:51:56 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179993 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/87/7028769.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7028769
loop_
_publ_author_name
'Hu, Xiao-Hui'
'Liang, Yan'
'Li, Chen'
'Yi, Xiao-Yi'
_publ_section_title
;
 Multi-nuclear silver(i) and copper(i) complexes: a novel bonding mode for
 bispyridylpyrrolides.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2458
_journal_page_last               2464
_journal_paper_doi               10.1039/c3dt52794h
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C30 H18 Ag2 Br4 F6 N6 O6 S2'
_chemical_formula_weight         1272.00
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                110.57(3)
_cell_angle_beta                 98.30(3)
_cell_angle_gamma                96.19(3)
_cell_formula_units_Z            2
_cell_length_a                   7.8073(16)
_cell_length_b                   15.310(3)
_cell_length_c                   16.630(3)
_cell_measurement_reflns_used    7027
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.63
_cell_measurement_theta_min      2.52
_cell_volume                     1814.4(8)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.958
_diffrn_measured_fraction_theta_max 0.958
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0211
_diffrn_reflns_av_unetI/netI     0.0321
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            15452
_diffrn_reflns_theta_full        27.65
_diffrn_reflns_theta_max         27.65
_diffrn_reflns_theta_min         1.44
_exptl_absorpt_coefficient_mu    5.684
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.5111
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            'slightly yellow'
_exptl_crystal_density_diffrn    2.328
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       layer
_exptl_crystal_F_000             1216
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.888
_refine_diff_density_min         -0.559
_refine_diff_density_rms         0.109
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     505
_refine_ls_number_reflns         8113
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.059
_refine_ls_R_factor_all          0.0355
_refine_ls_R_factor_gt           0.0266
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0280P)²+1.9851P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0585
_refine_ls_wR_factor_ref         0.0679
_reflns_number_gt                6909
_reflns_number_total             8113
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt52794h.txt
_cod_data_source_block           complex_5
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/automatic-downloads/current/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_cell_volume        1814.4(6)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7028769
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.51379(3) 0.212947(16) -0.025930(15) 0.01677(6) Uani 1 1 d .
Br1 Br 0.60686(4) 0.44200(2) 0.07428(2) 0.02023(8) Uani 1 1 d .
Br2 Br 0.53977(5) -0.31650(2) 0.16514(2) 0.02178(8) Uani 1 1 d .
S1 S 0.98560(10) 0.23794(5) -0.02888(5) 0.01450(15) Uani 1 1 d .
F1 F 0.9195(3) 0.40074(13) -0.03169(14) 0.0275(5) Uani 1 1 d .
F2 F 1.1032(3) 0.41074(14) 0.08262(14) 0.0338(5) Uani 1 1 d .
F3 F 1.1839(3) 0.38038(14) -0.04099(15) 0.0328(5) Uani 1 1 d .
O1 O 0.8533(3) 0.23666(16) 0.02314(15) 0.0206(5) Uani 1 1 d .
O2 O 1.1440(3) 0.20736(17) -0.00276(17) 0.0290(6) Uani 1 1 d .
O3 O 0.9190(3) 0.20087(15) -0.12237(14) 0.0175(5) Uani 1 1 d .
N1 N 0.4454(3) 0.10189(17) 0.19971(17) 0.0144(5) Uani 1 1 d .
H1A H 0.4798 0.1309 0.2554 0.017 Uiso 1 1 calc R
N2 N 0.4956(3) 0.29005(17) 0.11670(17) 0.0135(5) Uani 1 1 d .
N3 N 0.4720(3) -0.14190(17) 0.16964(16) 0.0129(5) Uani 1 1 d .
C1 C 0.5207(4) 0.3844(2) 0.1477(2) 0.0150(6) Uani 1 1 d .
C2 C 0.4925(4) 0.4420(2) 0.2274(2) 0.0204(7) Uani 1 1 d .
H2A H 0.5126 0.5076 0.2448 0.025 Uiso 1 1 calc R
C3 C 0.4331(5) 0.3983(2) 0.2803(2) 0.0222(7) Uani 1 1 d .
H3A H 0.4103 0.4341 0.3345 0.027 Uiso 1 1 calc R
C4 C 0.4078(4) 0.3006(2) 0.2520(2) 0.0193(7) Uani 1 1 d .
H4A H 0.3696 0.2704 0.2875 0.023 Uiso 1 1 calc R
C5 C 0.4398(4) 0.2476(2) 0.1700(2) 0.0141(6) Uani 1 1 d .
C6 C 0.4161(4) 0.1450(2) 0.1401(2) 0.0139(6) Uani 1 1 d .
C7 C 0.3593(4) 0.0744(2) 0.0583(2) 0.0159(6) Uani 1 1 d .
H7A H 0.3283 0.0828 0.0058 0.019 Uiso 1 1 calc R
C8 C 0.3568(4) -0.0132(2) 0.0692(2) 0.0148(6) Uani 1 1 d .
H8A H 0.3239 -0.0729 0.0250 0.018 Uiso 1 1 calc R
C9 C 0.4112(4) 0.0054(2) 0.1563(2) 0.0137(6) Uani 1 1 d .
C10 C 0.4257(4) -0.0561(2) 0.2069(2) 0.0136(6) Uani 1 1 d .
C11 C 0.3878(4) -0.0260(2) 0.2907(2) 0.0142(6) Uani 1 1 d .
H11A H 0.3558 0.0332 0.3147 0.017 Uiso 1 1 calc R
C12 C 0.3979(4) -0.0840(2) 0.3384(2) 0.0171(6) Uani 1 1 d .
H12A H 0.3740 -0.0642 0.3946 0.020 Uiso 1 1 calc R
C13 C 0.4438(4) -0.1715(2) 0.3012(2) 0.0173(6) Uani 1 1 d .
H13A H 0.4510 -0.2126 0.3310 0.021 Uiso 1 1 calc R
C14 C 0.4787(4) -0.1958(2) 0.2178(2) 0.0143(6) Uani 1 1 d .
C71 C 1.0509(4) 0.3641(2) -0.0032(2) 0.0193(7) Uani 1 1 d .
Ag3 Ag 0.02388(3) 0.208909(16) 0.467736(15) 0.01772(6) Uani 1 1 d .
Br5 Br 0.14690(4) 0.44724(2) 0.56351(2) 0.02074(8) Uani 1 1 d .
Br6 Br 0.04377(5) -0.32163(2) 0.66370(2) 0.02724(9) Uani 1 1 d .
N21 N 0.0315(3) 0.10908(17) 0.70559(17) 0.0144(5) Uani 1 1 d .
H21A H -0.0128 0.1320 0.7515 0.017 Uiso 1 1 calc R
N22 N 0.0443(3) -0.13663(17) 0.67873(16) 0.0123(5) Uani 1 1 d .
N23 N 0.0785(3) 0.29471(17) 0.61320(16) 0.0131(5) Uani 1 1 d .
C29 C 0.0446(4) -0.1916(2) 0.7260(2) 0.0155(6) Uani 1 1 d .
C30 C 0.0454(4) -0.1618(2) 0.8144(2) 0.0209(7) Uani 1 1 d .
H30A H 0.0420 -0.2041 0.8431 0.025 Uiso 1 1 calc R
C31 C 0.0514(4) -0.0664(2) 0.8582(2) 0.0211(7) Uani 1 1 d .
H31A H 0.0481 -0.0429 0.9176 0.025 Uiso 1 1 calc R
C32 C 0.0623(4) -0.0057(2) 0.8136(2) 0.0208(7) Uani 1 1 d .
H32A H 0.0722 0.0593 0.8433 0.025 Uiso 1 1 calc R
C33 C 0.0583(4) -0.0423(2) 0.7237(2) 0.0132(6) Uani 1 1 d .
C34 C 0.0751(4) 0.0209(2) 0.6754(2) 0.0133(6) Uani 1 1 d .
C35 C 0.1448(4) 0.0108(2) 0.6013(2) 0.0149(6) Uani 1 1 d .
H35A H 0.1860 -0.0421 0.5676 0.018 Uiso 1 1 calc R
C36 C 0.1418(4) 0.0957(2) 0.5867(2) 0.0146(6) Uani 1 1 d .
H36A H 0.1816 0.1091 0.5415 0.018 Uiso 1 1 calc R
C37 C 0.0693(4) 0.1560(2) 0.6512(2) 0.0132(6) Uani 1 1 d .
C38 C 0.0416(4) 0.2531(2) 0.6705(2) 0.0144(6) Uani 1 1 d .
C39 C -0.0149(5) 0.3039(2) 0.7467(2) 0.0208(7) Uani 1 1 d .
H39A H -0.0462 0.2739 0.7836 0.025 Uiso 1 1 calc R
C40 C -0.0244(5) 0.3985(2) 0.7673(2) 0.0262(8) Uani 1 1 d .
H40A H -0.0654 0.4321 0.8171 0.031 Uiso 1 1 calc R
C41 C 0.0275(5) 0.4430(2) 0.7132(2) 0.0229(7) Uani 1 1 d .
H41A H 0.0294 0.5076 0.7271 0.027 Uiso 1 1 calc R
C42 C 0.0759(4) 0.3877(2) 0.6383(2) 0.0161(6) Uani 1 1 d .
S3 S 0.55197(10) 0.20988(6) 0.46348(5) 0.01635(16) Uani 1 1 d .
F7 F 0.7302(3) 0.38287(15) 0.52436(16) 0.0395(6) Uani 1 1 d .
F8 F 0.5299(3) 0.36130(15) 0.59567(13) 0.0359(5) Uani 1 1 d .
F9 F 0.4600(3) 0.37094(15) 0.46897(14) 0.0335(5) Uani 1 1 d .
O7 O 0.3716(3) 0.17443(18) 0.45905(18) 0.0345(6) Uani 1 1 d .
O8 O 0.5992(3) 0.19889(16) 0.38031(14) 0.0211(5) Uani 1 1 d .
O9 O 0.6799(4) 0.18729(18) 0.52129(16) 0.0315(6) Uani 1 1 d .
C73 C 0.5682(4) 0.3375(2) 0.5159(2) 0.0231(7) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N3 Ag1 N2 177.30(9) 2_655 .
O2 S1 O1 115.42(15) . .
O2 S1 O3 114.61(15) . .
O1 S1 O3 114.50(14) . .
O2 S1 C71 104.50(15) . .
O1 S1 C71 102.38(14) . .
O3 S1 C71 103.13(14) . .
C9 N1 C6 109.3(2) . .
C9 N1 H1A 125.3 . .
C6 N1 H1A 125.3 . .
C1 N2 C5 116.5(3) . .
C1 N2 Ag1 117.88(19) . .
C5 N2 Ag1 125.1(2) . .
C14 N3 C10 116.2(3) . .
C14 N3 Ag1 116.9(2) . 2_655
C10 N3 Ag1 125.8(2) . 2_655
N2 C1 C2 126.0(3) . .
N2 C1 Br1 115.8(2) . .
C2 C1 Br1 118.2(2) . .
C1 C2 C3 117.0(3) . .
C1 C2 H2A 121.5 . .
C3 C2 H2A 121.5 . .
C2 C3 C4 119.3(3) . .
C2 C3 H3A 120.3 . .
C4 C3 H3A 120.3 . .
C3 C4 C5 119.8(3) . .
C3 C4 H4A 120.1 . .
C5 C4 H4A 120.1 . .
N2 C5 C4 121.3(3) . .
N2 C5 C6 118.4(3) . .
C4 C5 C6 120.3(3) . .
N1 C6 C7 107.5(3) . .
N1 C6 C5 120.0(3) . .
C7 C6 C5 132.4(3) . .
C6 C7 C8 107.3(3) . .
C6 C7 H7A 126.3 . .
C8 C7 H7A 126.3 . .
C9 C8 C7 107.8(3) . .
C9 C8 H8A 126.1 . .
C7 C8 H8A 126.1 . .
C8 C9 N1 108.0(3) . .
C8 C9 C10 132.5(3) . .
N1 C9 C10 119.3(3) . .
N3 C10 C11 121.7(3) . .
N3 C10 C9 118.8(3) . .
C11 C10 C9 119.5(3) . .
C12 C11 C10 120.0(3) . .
C12 C11 H11A 120.0 . .
C10 C11 H11A 120.0 . .
C13 C12 C11 118.9(3) . .
C13 C12 H12A 120.5 . .
C11 C12 H12A 120.5 . .
C12 C13 C14 117.3(3) . .
C12 C13 H13A 121.4 . .
C14 C13 H13A 121.4 . .
N3 C14 C13 125.9(3) . .
N3 C14 Br2 116.3(2) . .
C13 C14 Br2 117.8(2) . .
F1 C71 F2 108.6(3) . .
F1 C71 F3 107.1(3) . .
F2 C71 F3 107.4(3) . .
F1 C71 S1 111.3(2) . .
F2 C71 S1 111.0(2) . .
F3 C71 S1 111.4(2) . .
N22 Ag3 N23 173.72(9) 2_556 .
C34 N21 C37 109.7(2) . .
C34 N21 H21A 125.2 . .
C37 N21 H21A 125.2 . .
C29 N22 C33 116.5(3) . .
C29 N22 Ag3 117.4(2) . 2_556
C33 N22 Ag3 125.23(19) . 2_556
C42 N23 C38 116.8(3) . .
C42 N23 Ag3 117.3(2) . .
C38 N23 Ag3 120.4(2) . .
N22 C29 C30 125.9(3) . .
N22 C29 Br6 115.9(2) . .
C30 C29 Br6 118.2(2) . .
C31 C30 C29 116.8(3) . .
C31 C30 H30A 121.6 . .
C29 C30 H30A 121.6 . .
C30 C31 C32 119.7(3) . .
C30 C31 H31A 120.2 . .
C32 C31 H31A 120.2 . .
C31 C32 C33 119.6(3) . .
C31 C32 H32A 120.2 . .
C33 C32 H32A 120.2 . .
N22 C33 C32 121.4(3) . .
N22 C33 C34 118.0(3) . .
C32 C33 C34 120.5(3) . .
N21 C34 C35 108.1(3) . .
N21 C34 C33 121.2(3) . .
C35 C34 C33 130.5(3) . .
C34 C35 C36 107.2(3) . .
C34 C35 H35A 126.4 . .
C36 C35 H35A 126.4 . .
C37 C36 C35 108.1(3) . .
C37 C36 H36A 125.9 . .
C35 C36 H36A 125.9 . .
N21 C37 C36 107.0(3) . .
N21 C37 C38 120.9(3) . .
C36 C37 C38 132.0(3) . .
N23 C38 C39 120.6(3) . .
N23 C38 C37 118.0(3) . .
C39 C38 C37 121.4(3) . .
C40 C39 C38 120.1(3) . .
C40 C39 H39A 119.9 . .
C38 C39 H39A 119.9 . .
C39 C40 C41 119.4(3) . .
C39 C40 H40A 120.3 . .
C41 C40 H40A 120.3 . .
C42 C41 C40 116.9(3) . .
C42 C41 H41A 121.5 . .
C40 C41 H41A 121.5 . .
N23 C42 C41 125.8(3) . .
N23 C42 Br5 116.7(2) . .
C41 C42 Br5 117.6(2) . .
O7 S3 O9 115.93(17) . .
O7 S3 O8 115.06(16) . .
O9 S3 O8 113.71(15) . .
O7 S3 C73 103.36(16) . .
O9 S3 C73 103.57(16) . .
O8 S3 C73 102.86(15) . .
F9 C73 F8 108.3(3) . .
F9 C73 F7 106.4(3) . .
F8 C73 F7 107.7(3) . .
F9 C73 S3 111.4(2) . .
F8 C73 S3 111.2(2) . .
F7 C73 S3 111.5(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N3 2.276(3) 2_655
Ag1 N2 2.282(3) .
Br1 C1 1.894(3) .
Br2 C14 1.893(3) .
S1 O2 1.432(2) .
S1 O1 1.443(2) .
S1 O3 1.447(2) .
S1 C71 1.821(3) .
F1 C71 1.328(4) .
F2 C71 1.329(4) .
F3 C71 1.333(4) .
N1 C9 1.373(4) .
N1 C6 1.377(4) .
N1 H1A 0.8600 .
N2 C1 1.333(4) .
N2 C5 1.362(4) .
N3 C14 1.336(4) .
N3 C10 1.355(4) .
N3 Ag1 2.276(3) 2_655
C1 C2 1.374(4) .
C2 C3 1.380(4) .
C2 H2A 0.9300 .
C3 C4 1.383(4) .
C3 H3A 0.9300 .
C4 C5 1.394(4) .
C4 H4A 0.9300 .
C5 C6 1.453(4) .
C6 C7 1.380(4) .
C7 C8 1.413(4) .
C7 H7A 0.9300 .
C8 C9 1.366(4) .
C8 H8A 0.9300 .
C9 C10 1.469(4) .
C10 C11 1.393(4) .
C11 C12 1.384(4) .
C11 H11A 0.9300 .
C12 C13 1.374(4) .
C12 H12A 0.9300 .
C13 C14 1.381(4) .
C13 H13A 0.9300 .
Ag3 N22 2.246(3) 2_556
Ag3 N23 2.260(3) .
Br5 C42 1.889(3) .
Br6 C29 1.892(3) .
N21 C34 1.364(4) .
N21 C37 1.382(4) .
N21 H21A 0.8600 .
N22 C29 1.338(4) .
N22 C33 1.356(4) .
N22 Ag3 2.246(3) 2_556
N23 C42 1.339(4) .
N23 C38 1.364(4) .
C29 C30 1.377(4) .
C30 C31 1.377(5) .
C30 H30A 0.9300 .
C31 C32 1.381(4) .
C31 H31A 0.9300 .
C32 C33 1.395(4) .
C32 H32A 0.9300 .
C33 C34 1.465(4) .
C34 C35 1.384(4) .
C35 C36 1.406(4) .
C35 H35A 0.9300 .
C36 C37 1.384(4) .
C36 H36A 0.9300 .
C37 C38 1.455(4) .
C38 C39 1.395(4) .
C39 C40 1.380(4) .
C39 H39A 0.9300 .
C40 C41 1.383(4) .
C40 H40A 0.9300 .
C41 C42 1.371(4) .
C41 H41A 0.9300 .
S3 O7 1.435(2) .
S3 O9 1.440(3) .
S3 O8 1.440(2) .
S3 C73 1.820(4) .
F7 C73 1.339(4) .
F8 C73 1.334(4) .
F9 C73 1.329(4) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
N3 Ag1 N2 C1 -27.6(19) 2_655
N3 Ag1 N2 C5 143.8(17) 2_655
C5 N2 C1 C2 -1.2(5) .
Ag1 N2 C1 C2 170.9(3) .
C5 N2 C1 Br1 177.7(2) .
Ag1 N2 C1 Br1 -10.2(3) .
N2 C1 C2 C3 0.1(5) .
Br1 C1 C2 C3 -178.7(3) .
C1 C2 C3 C4 1.0(5) .
C2 C3 C4 C5 -1.0(5) .
C1 N2 C5 C4 1.1(4) .
Ag1 N2 C5 C4 -170.4(2) .
C1 N2 C5 C6 -178.1(3) .
Ag1 N2 C5 C6 10.4(4) .
C3 C4 C5 N2 -0.1(5) .
C3 C4 C5 C6 179.1(3) .
C9 N1 C6 C7 1.2(3) .
C9 N1 C6 C5 178.7(3) .
N2 C5 C6 N1 148.0(3) .
C4 C5 C6 N1 -31.2(4) .
N2 C5 C6 C7 -35.2(5) .
C4 C5 C6 C7 145.6(3) .
N1 C6 C7 C8 -0.8(3) .
C5 C6 C7 C8 -177.9(3) .
C6 C7 C8 C9 0.1(3) .
C7 C8 C9 N1 0.6(3) .
C7 C8 C9 C10 176.0(3) .
C6 N1 C9 C8 -1.2(3) .
C6 N1 C9 C10 -177.2(3) .
C14 N3 C10 C11 0.2(4) .
Ag1 N3 C10 C11 167.4(2) 2_655
C14 N3 C10 C9 -178.3(3) .
Ag1 N3 C10 C9 -11.1(4) 2_655
C8 C9 C10 N3 35.0(5) .
N1 C9 C10 N3 -150.0(3) .
C8 C9 C10 C11 -143.6(3) .
N1 C9 C10 C11 31.4(4) .
N3 C10 C11 C12 0.3(4) .
C9 C10 C11 C12 178.8(3) .
C10 C11 C12 C13 -0.7(5) .
C11 C12 C13 C14 0.5(4) .
C10 N3 C14 C13 -0.4(4) .
Ag1 N3 C14 C13 -168.8(2) 2_655
C10 N3 C14 Br2 179.0(2) .
Ag1 N3 C14 Br2 10.6(3) 2_655
C12 C13 C14 N3 0.0(5) .
C12 C13 C14 Br2 -179.4(2) .
O2 S1 C71 F1 174.1(2) .
O1 S1 C71 F1 -65.1(2) .
O3 S1 C71 F1 54.0(2) .
O2 S1 C71 F2 -64.8(3) .
O1 S1 C71 F2 55.9(3) .
O3 S1 C71 F2 175.0(2) .
O2 S1 C71 F3 54.8(3) .
O1 S1 C71 F3 175.5(2) .
O3 S1 C71 F3 -65.4(3) .
N22 Ag3 N23 C42 -20.2(9) 2_556
N22 Ag3 N23 C38 132.7(7) 2_556
C33 N22 C29 C30 4.8(5) .
Ag3 N22 C29 C30 -165.2(3) 2_556
C33 N22 C29 Br6 -175.2(2) .
Ag3 N22 C29 Br6 14.8(3) 2_556
N22 C29 C30 C31 -1.9(5) .
Br6 C29 C30 C31 178.1(2) .
C29 C30 C31 C32 -2.2(5) .
C30 C31 C32 C33 3.2(5) .
C29 N22 C33 C32 -3.7(4) .
Ag3 N22 C33 C32 165.5(2) 2_556
C29 N22 C33 C34 174.4(3) .
Ag3 N22 C33 C34 -16.4(4) 2_556
C31 C32 C33 N22 -0.1(5) .
C31 C32 C33 C34 -178.2(3) .
C37 N21 C34 C35 1.0(3) .
C37 N21 C34 C33 176.4(3) .
N22 C33 C34 N21 157.7(3) .
C32 C33 C34 N21 -24.2(4) .
N22 C33 C34 C35 -28.1(5) .
C32 C33 C34 C35 150.0(3) .
N21 C34 C35 C36 -0.3(3) .
C33 C34 C35 C36 -175.1(3) .
C34 C35 C36 C37 -0.5(4) .
C34 N21 C37 C36 -1.3(3) .
C34 N21 C37 C38 -177.6(3) .
C35 C36 C37 N21 1.1(3) .
C35 C36 C37 C38 176.8(3) .
C42 N23 C38 C39 6.9(4) .
Ag3 N23 C38 C39 -146.1(2) .
C42 N23 C38 C37 -170.9(3) .
Ag3 N23 C38 C37 36.1(3) .
N21 C37 C38 N23 -178.8(3) .
C36 C37 C38 N23 6.0(5) .
N21 C37 C38 C39 3.4(5) .
C36 C37 C38 C39 -171.8(3) .
N23 C38 C39 C40 -3.7(5) .
C37 C38 C39 C40 174.0(3) .
C38 C39 C40 C41 -1.9(6) .
C39 C40 C41 C42 3.9(5) .
C38 N23 C42 C41 -5.0(5) .
Ag3 N23 C42 C41 148.9(3) .
C38 N23 C42 Br5 174.6(2) .
Ag3 N23 C42 Br5 -31.5(3) .
C40 C41 C42 N23 -0.5(5) .
C40 C41 C42 Br5 179.9(3) .
O7 S3 C73 F9 -60.4(3) .
O9 S3 C73 F9 178.3(2) .
O8 S3 C73 F9 59.7(3) .
O7 S3 C73 F8 60.6(3) .
O9 S3 C73 F8 -60.7(3) .
O8 S3 C73 F8 -179.3(2) .
O7 S3 C73 F7 -179.1(2) .
O9 S3 C73 F7 59.6(3) .
O8 S3 C73 F7 -59.1(3) .
