#------------------------------------------------------------------------------
#$Date: 2025-08-21 15:03:24 +0300 (Thu, 21 Aug 2025) $
#$Revision: 301848 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/02/89/7028924.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7028924
loop_
_publ_author_name
'Bolli, Christoph'
'Gellhaar, Jorit'
'Jenne, Carsten'
'Keßler, Mathias'
'Scherer, Harald'
'Seeger, Helene'
'Uzun, Rabiya'
_publ_section_title
;
 Bis(triphenyl-λ(5)-phosphanylidene)ammonium fluoride: a reactive
 fluoride source to access the hypervalent silicates [MenSiF5-n](-) (n =
 0-3).
;
_journal_issue                   11
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4326
_journal_page_last               4334
_journal_paper_doi               10.1039/c3dt52617h
_journal_volume                  43
_journal_year                    2014
_chemical_formula_moiety         'C36 H30 N P2, F5 Si'
_chemical_formula_sum            'C36 H30 F5 N P2 Si'
_chemical_formula_weight         661.64
_space_group_IT_number           13
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yc'
_symmetry_space_group_name_H-M   'P 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 123.1050(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   15.7907(3)
_cell_length_b                   13.8468(3)
_cell_length_c                   17.3811(3)
_cell_measurement_reflns_used    9969
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      25.72
_cell_measurement_theta_min      2.77
_cell_volume                     3183.48(11)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    Diamond
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker SMART APEX-II CCD area detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  'double mirrors'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0603
_diffrn_reflns_av_sigmaI/netI    0.0364
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            50173
_diffrn_reflns_theta_full        25.83
_diffrn_reflns_theta_max         25.83
_diffrn_reflns_theta_min         2.03
_diffrn_source                   'ImuS microsource'
_diffrn_source_target            Mo
_exptl_absorpt_coefficient_mu    0.231
_exptl_absorpt_correction_T_max  0.9977
_exptl_absorpt_correction_T_min  0.9297
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS; Sheldrick, 1996
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.380
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1368
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.01
_refine_diff_density_max         0.446
_refine_diff_density_min         -0.330
_refine_diff_density_rms         0.053
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.085
_refine_ls_hydrogen_treatment    refU
_refine_ls_matrix_type           full
_refine_ls_number_parameters     409
_refine_ls_number_reflns         6130
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.085
_refine_ls_R_factor_all          0.0640
_refine_ls_R_factor_gt           0.0448
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0267P)²+3.1687P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0923
_refine_ls_wR_factor_ref         0.0994
_reflns_number_gt                4805
_reflns_number_total             6130
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt52617h.txt
_cod_data_source_block           shelxl
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/automatic-downloads/current/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_cell_volume        3183.47(11)
_cod_original_sg_symbol_H-M      P2/c
_cod_database_code               7028924
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
P1 P 0.40167(4) 0.34985(4) 0.66148(4) 0.01713(14) Uani 1 1 d .
N1 N 0.5000 0.39178(18) 0.7500 0.0196(6) Uani 1 2 d S
C1 C 0.41467(17) 0.35175(16) 0.56472(14) 0.0204(5) Uani 1 1 d .
C2 C 0.3350(2) 0.32587(16) 0.47736(15) 0.0261(6) Uani 1 1 d .
H2 H 0.2716 0.3078 0.4673 0.031 Uiso 1 1 calc R
C3 C 0.3486(2) 0.32650(17) 0.40479(16) 0.0316(6) Uani 1 1 d .
H3 H 0.2941 0.3093 0.3449 0.038 Uiso 1 1 calc R
C4 C 0.4408(2) 0.35210(19) 0.41938(17) 0.0357(7) Uani 1 1 d .
H4 H 0.4501 0.3510 0.3698 0.043 Uiso 1 1 calc R
C5 C 0.5193(2) 0.3792(2) 0.50564(18) 0.0375(7) Uani 1 1 d .
H5 H 0.5823 0.3977 0.5152 0.045 Uiso 1 1 calc R
C6 C 0.50683(19) 0.37971(18) 0.57863(16) 0.0291(6) Uani 1 1 d .
H6 H 0.5609 0.3990 0.6380 0.035 Uiso 1 1 calc R
C7 C 0.29758(17) 0.42629(16) 0.63762(14) 0.0194(5) Uani 1 1 d .
C8 C 0.31864(19) 0.52273(16) 0.66607(15) 0.0248(5) Uani 1 1 d .
H8 H 0.3856 0.5467 0.6946 0.030 Uiso 1 1 calc R
C9 C 0.2417(2) 0.58325(18) 0.65256(16) 0.0301(6) Uani 1 1 d .
H9 H 0.2559 0.6489 0.6713 0.036 Uiso 1 1 calc R
C10 C 0.1447(2) 0.54831(18) 0.61196(16) 0.0311(6) Uani 1 1 d .
H10 H 0.0925 0.5893 0.6046 0.037 Uiso 1 1 calc R
C11 C 0.1232(2) 0.45335(18) 0.58174(17) 0.0317(6) Uani 1 1 d .
H11 H 0.0559 0.4301 0.5525 0.038 Uiso 1 1 calc R
C12 C 0.19912(18) 0.39213(17) 0.59388(16) 0.0253(5) Uani 1 1 d .
H12 H 0.1839 0.3274 0.5724 0.030 Uiso 1 1 calc R
C13 C 0.37119(17) 0.22845(15) 0.67579(14) 0.0192(5) Uani 1 1 d .
C14 C 0.34256(18) 0.21390(16) 0.73789(15) 0.0232(5) Uani 1 1 d .
H14 H 0.3327 0.2680 0.7658 0.028 Uiso 1 1 calc R
C15 C 0.32834(19) 0.12172(17) 0.75925(16) 0.0270(6) Uani 1 1 d .
H15 H 0.3081 0.1125 0.8011 0.032 Uiso 1 1 calc R
C16 C 0.34370(19) 0.04272(17) 0.71931(17) 0.0273(6) Uani 1 1 d .
H16 H 0.3346 -0.0208 0.7343 0.033 Uiso 1 1 calc R
C17 C 0.3720(2) 0.05625(17) 0.65807(16) 0.0280(6) Uani 1 1 d .
H17 H 0.3824 0.0019 0.6308 0.034 Uiso 1 1 calc R
C18 C 0.38565(18) 0.14879(16) 0.63568(15) 0.0242(5) Uani 1 1 d .
H18 H 0.4048 0.1575 0.5930 0.029 Uiso 1 1 calc R
P2 P -0.08708(5) 0.15587(4) 0.65192(4) 0.01786(14) Uani 1 1 d .
N2 N 0.0000 0.12004(18) 0.7500 0.0204(6) Uani 1 2 d S
C19 C -0.19484(17) 0.08020(17) 0.61579(14) 0.0218(5) Uani 1 1 d .
C20 C -0.17808(19) -0.00957(16) 0.65870(16) 0.0255(5) Uani 1 1 d .
H20 H -0.1114 -0.0278 0.7060 0.031 Uiso 1 1 calc R
C21 C -0.2575(2) -0.07196(19) 0.63291(19) 0.0353(6) Uani 1 1 d .
H21 H -0.2451 -0.1329 0.6623 0.042 Uiso 1 1 calc R
C22 C -0.3541(2) -0.0464(2) 0.56507(19) 0.0406(7) Uani 1 1 d .
H22 H -0.4086 -0.0893 0.5481 0.049 Uiso 1 1 calc R
C23 C -0.3723(2) 0.0418(2) 0.52129(18) 0.0432(8) Uani 1 1 d .
H23 H -0.4394 0.0589 0.4739 0.052 Uiso 1 1 calc R
C24 C -0.29308(19) 0.1060(2) 0.54608(16) 0.0319(6) Uani 1 1 d .
H24 H -0.3059 0.1665 0.5159 0.038 Uiso 1 1 calc R
C25 C -0.12396(18) 0.27925(16) 0.64829(14) 0.0217(5) Uani 1 1 d .
C26 C -0.17749(19) 0.30392(17) 0.68763(17) 0.0284(6) Uani 1 1 d .
H26 H -0.1999 0.2547 0.7106 0.034 Uiso 1 1 calc R
C27 C -0.1984(2) 0.39944(17) 0.69355(17) 0.0302(6) Uani 1 1 d .
H27 H -0.2362 0.4157 0.7194 0.036 Uiso 1 1 calc R
C28 C -0.1642(2) 0.47137(18) 0.66185(16) 0.0327(6) Uani 1 1 d .
H28 H -0.1772 0.5372 0.6671 0.039 Uiso 1 1 calc R
C29 C -0.1114(2) 0.44738(18) 0.62271(19) 0.0409(7) Uani 1 1 d .
H29 H -0.0887 0.4969 0.6004 0.049 Uiso 1 1 calc R
C30 C -0.0912(2) 0.35186(18) 0.61558(17) 0.0339(6) Uani 1 1 d .
H30 H -0.0548 0.3359 0.5883 0.041 Uiso 1 1 calc R
C31 C -0.05150(18) 0.14419(16) 0.57013(15) 0.0210(5) Uani 1 1 d .
C32 C -0.1223(2) 0.16092(17) 0.47670(16) 0.0283(6) Uani 1 1 d .
H32 H -0.1902 0.1764 0.4555 0.034 Uiso 1 1 calc R
C33 C -0.0924(2) 0.15465(19) 0.41538(17) 0.0352(6) Uani 1 1 d .
H33 H -0.1401 0.1663 0.3519 0.042 Uiso 1 1 calc R
C34 C 0.0062(2) 0.13154(18) 0.44570(17) 0.0342(6) Uani 1 1 d .
H34 H 0.0260 0.1280 0.4030 0.041 Uiso 1 1 calc R
C35 C 0.0763(2) 0.11362(18) 0.53760(17) 0.0318(6) Uani 1 1 d .
H35 H 0.1438 0.0968 0.5580 0.038 Uiso 1 1 calc R
C36 C 0.04744(19) 0.12025(17) 0.60014(16) 0.0263(5) Uani 1 1 d .
H36 H 0.0955 0.1084 0.6635 0.032 Uiso 1 1 calc R
Si1 Si 0.0000 0.28028(7) 0.2500 0.0309(2) Uani 1 2 d S
F1 F -0.11174(14) 0.28108(13) 0.23587(13) 0.0570(5) Uani 1 1 d .
F2 F 0.0000 0.16471(13) 0.2500 0.0343(5) Uani 1 2 d S
F3 F -0.04586(15) 0.33506(12) 0.15416(12) 0.0583(5) Uani 1 1 d .
Si2 Si 0.5000 0.79587(7) 0.7500 0.0295(2) Uani 1 2 d S
F4 F 0.62336(13) 0.79727(12) 0.82149(13) 0.0629(5) Uani 1 1 d .
F5 F 0.5000 0.68002(13) 0.7500 0.0333(5) Uani 1 2 d S
F6 F 0.48875(15) 0.85211(11) 0.82431(12) 0.0571(5) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 P1 C1 110.51(8) . .
N1 P1 C7 107.18(10) . .
C1 P1 C7 109.33(10) . .
N1 P1 C13 113.70(11) . .
C1 P1 C13 108.51(10) . .
C7 P1 C13 107.50(11) . .
P1 N1 P1 136.97(17) . 2_656
C2 C1 C6 119.9(2) . .
C2 C1 P1 121.29(18) . .
C6 C1 P1 118.85(17) . .
C1 C2 C3 119.6(2) . .
C1 C2 H2 120.2 . .
C3 C2 H2 120.2 . .
C4 C3 C2 120.3(2) . .
C4 C3 H3 119.8 . .
C2 C3 H3 119.8 . .
C5 C4 C3 120.1(2) . .
C5 C4 H4 120.0 . .
C3 C4 H4 120.0 . .
C4 C5 C6 120.3(3) . .
C4 C5 H5 119.8 . .
C6 C5 H5 119.8 . .
C5 C6 C1 119.8(2) . .
C5 C6 H6 120.1 . .
C1 C6 H6 120.1 . .
C12 C7 C8 119.8(2) . .
C12 C7 P1 122.25(17) . .
C8 C7 P1 117.92(18) . .
C9 C8 C7 120.0(2) . .
C9 C8 H8 120.0 . .
C7 C8 H8 120.0 . .
C10 C9 C8 120.0(2) . .
C10 C9 H9 120.0 . .
C8 C9 H9 120.0 . .
C9 C10 C11 120.0(2) . .
C9 C10 H10 120.0 . .
C11 C10 H10 120.0 . .
C12 C11 C10 120.6(2) . .
C12 C11 H11 119.7 . .
C10 C11 H11 119.7 . .
C11 C12 C7 119.4(2) . .
C11 C12 H12 120.3 . .
C7 C12 H12 120.3 . .
C18 C13 C14 119.1(2) . .
C18 C13 P1 122.81(17) . .
C14 C13 P1 117.74(16) . .
C15 C14 C13 120.7(2) . .
C15 C14 H14 119.6 . .
C13 C14 H14 119.6 . .
C14 C15 C16 119.7(2) . .
C14 C15 H15 120.1 . .
C16 C15 H15 120.1 . .
C17 C16 C15 120.0(2) . .
C17 C16 H16 120.0 . .
C15 C16 H16 120.0 . .
C16 C17 C18 120.6(2) . .
C16 C17 H17 119.7 . .
C18 C17 H17 119.7 . .
C13 C18 C17 119.9(2) . .
C13 C18 H18 120.0 . .
C17 C18 H18 120.0 . .
N2 P2 C19 107.16(10) . .
N2 P2 C25 114.35(11) . .
C19 P2 C25 108.41(11) . .
N2 P2 C31 111.23(8) . .
C19 P2 C31 108.47(10) . .
C25 P2 C31 107.06(10) . .
P2 N2 P2 143.29(18) . 2_556
C24 C19 C20 119.2(2) . .
C24 C19 P2 123.07(19) . .
C20 C19 P2 117.73(18) . .
C21 C20 C19 120.6(2) . .
C21 C20 H20 119.7 . .
C19 C20 H20 119.7 . .
C22 C21 C20 120.3(3) . .
C22 C21 H21 119.8 . .
C20 C21 H21 119.8 . .
C21 C22 C23 120.0(3) . .
C21 C22 H22 120.0 . .
C23 C22 H22 120.0 . .
C22 C23 C24 120.7(3) . .
C22 C23 H23 119.7 . .
C24 C23 H23 119.7 . .
C19 C24 C23 119.2(3) . .
C19 C24 H24 120.4 . .
C23 C24 H24 120.4 . .
C30 C25 C26 119.2(2) . .
C30 C25 P2 121.17(19) . .
C26 C25 P2 119.32(17) . .
C27 C26 C25 120.4(2) . .
C27 C26 H26 119.8 . .
C25 C26 H26 119.8 . .
C26 C27 C28 119.9(2) . .
C26 C27 H27 120.0 . .
C28 C27 H27 120.0 . .
C29 C28 C27 119.8(2) . .
C29 C28 H28 120.1 . .
C27 C28 H28 120.1 . .
C28 C29 C30 120.6(2) . .
C28 C29 H29 119.7 . .
C30 C29 H29 119.7 . .
C29 C30 C25 120.0(2) . .
C29 C30 H30 120.0 . .
C25 C30 H30 120.0 . .
C36 C31 C32 119.8(2) . .
C36 C31 P2 119.80(17) . .
C32 C31 P2 120.41(18) . .
C33 C32 C31 119.4(2) . .
C33 C32 H32 120.3 . .
C31 C32 H32 120.3 . .
C34 C33 C32 120.5(2) . .
C34 C33 H33 119.7 . .
C32 C33 H33 119.7 . .
C35 C34 C33 120.4(2) . .
C35 C34 H34 119.8 . .
C33 C34 H34 119.8 . .
C34 C35 C36 119.7(2) . .
C34 C35 H35 120.2 . .
C36 C35 H35 120.2 . .
C31 C36 C35 120.2(2) . .
C31 C36 H36 119.9 . .
C35 C36 H36 119.9 . .
F3 Si1 F3 123.36(14) 2 .
F3 Si1 F2 118.32(7) 2 .
F3 Si1 F2 118.32(7) . .
F3 Si1 F1 89.48(10) 2 .
F3 Si1 F1 90.16(10) . .
F2 Si1 F1 90.39(7) . .
F3 Si1 F1 90.16(10) 2 2
F3 Si1 F1 89.47(10) . 2
F2 Si1 F1 90.39(7) . 2
F1 Si1 F1 179.23(14) . 2
F6 Si2 F6 121.71(13) . 2_656
F6 Si2 F5 119.14(7) . .
F6 Si2 F5 119.15(7) 2_656 .
F6 Si2 F4 89.79(10) . 2_656
F6 Si2 F4 89.56(10) 2_656 2_656
F5 Si2 F4 90.68(7) . 2_656
F6 Si2 F4 89.56(10) . .
F6 Si2 F4 89.79(10) 2_656 .
F5 Si2 F4 90.68(7) . .
F4 Si2 F4 178.65(14) 2_656 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
P1 N1 1.5830(11) .
P1 C1 1.802(2) .
P1 C7 1.803(2) .
P1 C13 1.803(2) .
N1 P1 1.5830(11) 2_656
C1 C2 1.389(3) .
C1 C6 1.393(3) .
C2 C3 1.390(3) .
C2 H2 0.9500 .
C3 C4 1.381(4) .
C3 H3 0.9500 .
C4 C5 1.377(4) .
C4 H4 0.9500 .
C5 C6 1.386(3) .
C5 H5 0.9500 .
C6 H6 0.9500 .
C7 C12 1.388(3) .
C7 C8 1.400(3) .
C8 C9 1.386(3) .
C8 H8 0.9500 .
C9 C10 1.377(4) .
C9 H9 0.9500 .
C10 C11 1.388(4) .
C10 H10 0.9500 .
C11 C12 1.387(3) .
C11 H11 0.9500 .
C12 H12 0.9500 .
C13 C18 1.389(3) .
C13 C14 1.394(3) .
C14 C15 1.381(3) .
C14 H14 0.9500 .
C15 C16 1.386(3) .
C15 H15 0.9500 .
C16 C17 1.374(3) .
C16 H16 0.9500 .
C17 C18 1.390(3) .
C17 H17 0.9500 .
C18 H18 0.9500 .
P2 N2 1.5756(10) .
P2 C19 1.795(2) .
P2 C25 1.795(2) .
P2 C31 1.799(2) .
N2 P2 1.5756(10) 2_556
C19 C24 1.396(3) .
C19 C20 1.398(3) .
C20 C21 1.380(3) .
C20 H20 0.9500 .
C21 C22 1.370(4) .
C21 H21 0.9500 .
C22 C23 1.384(4) .
C22 H22 0.9500 .
C23 C24 1.398(4) .
C23 H23 0.9500 .
C24 H24 0.9500 .
C25 C30 1.387(3) .
C25 C26 1.389(3) .
C26 C27 1.381(3) .
C26 H26 0.9500 .
C27 C28 1.383(4) .
C27 H27 0.9500 .
C28 C29 1.374(4) .
C28 H28 0.9500 .
C29 C30 1.382(4) .
C29 H29 0.9500 .
C30 H30 0.9500 .
C31 C36 1.390(3) .
C31 C32 1.399(3) .
C32 C33 1.384(3) .
C32 H32 0.9500 .
C33 C34 1.382(4) .
C33 H33 0.9500 .
C34 C35 1.381(4) .
C34 H34 0.9500 .
C35 C36 1.392(3) .
C35 H35 0.9500 .
C36 H36 0.9500 .
Si1 F3 1.5990(16) 2
Si1 F3 1.5990(16) .
Si1 F2 1.600(2) .
Si1 F1 1.6433(18) .
Si1 F1 1.6434(18) 2
Si2 F6 1.5991(17) .
Si2 F6 1.5991(17) 2_656
Si2 F5 1.604(2) .
Si2 F4 1.6416(17) 2_656
Si2 F4 1.6417(17) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
C1 P1 N1 P1 -99.46(9) 2_656
C7 P1 N1 P1 141.49(8) 2_656
C13 P1 N1 P1 22.84(8) 2_656
N1 P1 C1 C2 -174.71(19) .
C7 P1 C1 C2 -57.0(2) .
C13 P1 C1 C2 60.0(2) .
N1 P1 C1 C6 5.4(2) .
C7 P1 C1 C6 123.13(19) .
C13 P1 C1 C6 -119.90(19) .
C6 C1 C2 C3 1.1(3) .
P1 C1 C2 C3 -178.79(18) .
C1 C2 C3 C4 0.4(4) .
C2 C3 C4 C5 -1.4(4) .
C3 C4 C5 C6 1.0(4) .
C4 C5 C6 C1 0.6(4) .
C2 C1 C6 C5 -1.6(4) .
P1 C1 C6 C5 178.3(2) .
N1 P1 C7 C12 -151.51(18) .
C1 P1 C7 C12 88.7(2) .
C13 P1 C7 C12 -28.9(2) .
N1 P1 C7 C8 27.43(19) .
C1 P1 C7 C8 -92.38(19) .
C13 P1 C7 C8 150.02(17) .
C12 C7 C8 C9 1.6(3) .
P1 C7 C8 C9 -177.40(18) .
C7 C8 C9 C10 0.6(4) .
C8 C9 C10 C11 -2.1(4) .
C9 C10 C11 C12 1.5(4) .
C10 C11 C12 C7 0.7(4) .
C8 C7 C12 C11 -2.2(3) .
P1 C7 C12 C11 176.70(18) .
N1 P1 C13 C18 -106.49(19) .
C1 P1 C13 C18 16.9(2) .
C7 P1 C13 C18 135.04(19) .
N1 P1 C13 C14 66.3(2) .
C1 P1 C13 C14 -170.31(18) .
C7 P1 C13 C14 -52.2(2) .
C18 C13 C14 C15 -0.2(4) .
P1 C13 C14 C15 -173.27(19) .
C13 C14 C15 C16 0.7(4) .
C14 C15 C16 C17 -0.6(4) .
C15 C16 C17 C18 0.1(4) .
C14 C13 C18 C17 -0.3(3) .
P1 C13 C18 C17 172.37(19) .
C16 C17 C18 C13 0.4(4) .
C19 P2 N2 P2 -138.27(8) 2_556
C25 P2 N2 P2 -18.09(9) 2_556
C31 P2 N2 P2 103.33(9) 2_556
N2 P2 C19 C24 161.22(18) .
C25 P2 C19 C24 37.3(2) .
C31 P2 C19 C24 -78.6(2) .
N2 P2 C19 C20 -20.3(2) .
C25 P2 C19 C20 -144.18(17) .
C31 P2 C19 C20 99.90(19) .
C24 C19 C20 C21 -0.2(3) .
P2 C19 C20 C21 -178.77(18) .
C19 C20 C21 C22 -0.3(4) .
C20 C21 C22 C23 0.7(4) .
C21 C22 C23 C24 -0.6(4) .
C20 C19 C24 C23 0.4(3) .
P2 C19 C24 C23 178.87(18) .
C22 C23 C24 C19 0.0(4) .
N2 P2 C25 C30 101.7(2) .
C19 P2 C25 C30 -138.8(2) .
C31 P2 C25 C30 -22.0(2) .
N2 P2 C25 C26 -71.6(2) .
C19 P2 C25 C26 47.9(2) .
C31 P2 C25 C26 164.74(19) .
C30 C25 C26 C27 0.4(4) .
P2 C25 C26 C27 173.82(19) .
C25 C26 C27 C28 -1.3(4) .
C26 C27 C28 C29 1.4(4) .
C27 C28 C29 C30 -0.7(4) .
C28 C29 C30 C25 -0.2(4) .
C26 C25 C30 C29 0.3(4) .
P2 C25 C30 C29 -173.0(2) .
N2 P2 C31 C36 -9.0(2) .
C19 P2 C31 C36 -126.64(19) .
C25 P2 C31 C36 116.56(19) .
N2 P2 C31 C32 172.25(19) .
C19 P2 C31 C32 54.6(2) .
C25 P2 C31 C32 -62.2(2) .
C36 C31 C32 C33 -0.9(4) .
P2 C31 C32 C33 177.86(19) .
C31 C32 C33 C34 0.4(4) .
C32 C33 C34 C35 0.5(4) .
C33 C34 C35 C36 -0.9(4) .
C32 C31 C36 C35 0.5(4) .
P2 C31 C36 C35 -178.26(19) .
C34 C35 C36 C31 0.4(4) .
loop_
_cod_related_entry_id
_cod_related_entry_database
_cod_related_entry_code
1 PubChem 139163372
