#------------------------------------------------------------------------------
#$Date: 2016-03-25 16:59:06 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179998 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/92/7029207.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7029207
loop_
_publ_author_name
'Ovsyannikov, A.'
'Ferlay, S.'
'Solovieva, S. E.'
'Antipin, I. S.'
'Konovalov, A. I.'
'Kyritsakas, N.'
'Hosseini, M. W.'
_publ_section_title
;
 Molecular tectonics: anion control of dimensionality and connectivity in
 meta-pyridyl appended tetramercaptotetrathiacalix[4]arene based silver
 coordination networks.
;
_journal_issue                   1
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              158
_journal_page_last               165
_journal_paper_doi               10.1039/c3dt52654b
_journal_volume                  43
_journal_year                    2014
_chemical_formula_moiety         'C32 H34 Ag N3 O3 S4,C H Cl3,C H4 O'
_chemical_formula_sum            'C34 H39 Ag Cl3 N3 O4 S4'
_chemical_formula_weight         896.14
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 97.8830(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   17.4196(3)
_cell_length_b                   15.7381(3)
_cell_length_c                   29.2392(6)
_cell_measurement_reflns_used    9563
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.79
_cell_measurement_theta_min      2.35
_cell_volume                     7940.2(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0387
_diffrn_reflns_av_sigmaI/netI    0.0416
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       41
_diffrn_reflns_limit_l_min       -41
_diffrn_reflns_number            45043
_diffrn_reflns_theta_full        30.11
_diffrn_reflns_theta_max         30.11
_diffrn_reflns_theta_min         1.41
_exptl_absorpt_coefficient_mu    0.960
_exptl_absorpt_correction_T_max  0.9536
_exptl_absorpt_correction_T_min  0.9359
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.499
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             3664
_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.023
_refine_diff_density_min         -0.675
_refine_diff_density_rms         0.132
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     452
_refine_ls_number_reflns         11678
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.0714
_refine_ls_R_factor_gt           0.0420
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0600P)²+9.1330P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1048
_refine_ls_wR_factor_ref         0.1283
_reflns_number_gt                8204
_reflns_number_total             11678
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt52654b.txt
_cod_data_source_block           e2682a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/automatic-downloads/current/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'none' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7029207
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.169435(15) 0.686995(17) 0.041907(8) 0.04828(9) Uani 1 1 d . . .
S1 S 0.0000 0.65301(5) 0.2500 0.0296(2) Uani 1 2 d S . .
C1 C 0.05210(14) 0.58408(15) 0.29129(7) 0.0218(5) Uani 1 1 d . . .
C2 C 0.10813(13) 0.52715(15) 0.28030(7) 0.0228(5) Uani 1 1 d . . .
C3 C 0.14785(13) 0.47832(16) 0.31618(8) 0.0243(5) Uani 1 1 d . . .
C4 C 0.13443(14) 0.49061(16) 0.36148(8) 0.0255(5) Uani 1 1 d . . .
H4 H 0.1633 0.4583 0.3854 0.031 Uiso 1 1 calc R . .
C5 C 0.08018(13) 0.54867(15) 0.37282(7) 0.0222(5) Uani 1 1 d . A .
C6 C 0.03901(14) 0.59415(15) 0.33697(8) 0.0235(5) Uani 1 1 d . . .
H6 H 0.0007 0.6334 0.3437 0.028 Uiso 1 1 calc R . .
S2 S 0.12801(4) 0.51612(4) 0.222680(19) 0.02877(14) Uani 1 1 d . . .
C7 C 0.21376(16) 0.58241(19) 0.22412(9) 0.0348(6) Uani 1 1 d . . .
H7A H 0.2012 0.6426 0.2295 0.042 Uiso 1 1 calc R . .
H7B H 0.2548 0.5636 0.2489 0.042 Uiso 1 1 calc R . .
C8 C 0.23947(15) 0.57152(17) 0.17750(8) 0.0292(5) Uani 1 1 d . . .
C9 C 0.20436(15) 0.61748(17) 0.14011(8) 0.0300(5) Uani 1 1 d . . .
H9 H 0.1664 0.6585 0.1452 0.036 Uiso 1 1 calc R . .
N1 N 0.22117(14) 0.60713(15) 0.09698(7) 0.0340(5) Uani 1 1 d . . .
C10 C 0.27526(18) 0.54914(19) 0.09020(10) 0.0398(7) Uani 1 1 d . . .
H10 H 0.2876 0.5406 0.0599 0.048 Uiso 1 1 calc R . .
C11 C 0.31305(19) 0.5022(2) 0.12570(11) 0.0449(8) Uani 1 1 d . . .
H11 H 0.3514 0.4621 0.1199 0.054 Uiso 1 1 calc R . .
C12 C 0.29547(17) 0.51308(19) 0.16966(10) 0.0382(6) Uani 1 1 d . . .
H12 H 0.3216 0.4808 0.1945 0.046 Uiso 1 1 calc R . .
C13 C 0.06177(15) 0.55607(17) 0.42237(8) 0.0302(6) Uani 1 1 d D . .
C14 C 0.0438(5) 0.6477(5) 0.4338(2) 0.0590(9) Uani 0.560(4) 1 d PD A 1
H14A H 0.0210 0.6494 0.4626 0.089 Uiso 0.560(4) 1 calc PR A 1
H14B H 0.0071 0.6717 0.4087 0.089 Uiso 0.560(4) 1 calc PR A 1
H14C H 0.0918 0.6811 0.4374 0.089 Uiso 0.560(4) 1 calc PR A 1
C15 C -0.0157(4) 0.5038(5) 0.42320(19) 0.0590(9) Uani 0.560(4) 1 d PD A 1
H15A H -0.0086 0.4457 0.4125 0.089 Uiso 0.560(4) 1 calc PR A 1
H15B H -0.0580 0.5312 0.4029 0.089 Uiso 0.560(4) 1 calc PR A 1
H15C H -0.0286 0.5022 0.4548 0.089 Uiso 0.560(4) 1 calc PR A 1
C16 C 0.1218(4) 0.5172(5) 0.45801(18) 0.0590(9) Uani 0.560(4) 1 d PD A 1
H16A H 0.1178 0.4552 0.4564 0.089 Uiso 0.560(4) 1 calc PR A 1
H16B H 0.1134 0.5364 0.4888 0.089 Uiso 0.560(4) 1 calc PR A 1
H16C H 0.1736 0.5347 0.4521 0.089 Uiso 0.560(4) 1 calc PR A 1
C14A C 0.0278(5) 0.4710(5) 0.4351(2) 0.0590(9) Uani 0.440(4) 1 d PD A 2
H14D H 0.0694 0.4289 0.4410 0.089 Uiso 0.440(4) 1 calc PR A 2
H14E H -0.0106 0.4516 0.4096 0.089 Uiso 0.440(4) 1 calc PR A 2
H14F H 0.0029 0.4781 0.4630 0.089 Uiso 0.440(4) 1 calc PR A 2
C15A C 0.0047(5) 0.6286(6) 0.4290(3) 0.0590(9) Uani 0.440(4) 1 d PD A 2
H15D H 0.0040 0.6382 0.4620 0.089 Uiso 0.440(4) 1 calc PR A 2
H15E H -0.0473 0.6131 0.4143 0.089 Uiso 0.440(4) 1 calc PR A 2
H15F H 0.0214 0.6807 0.4148 0.089 Uiso 0.440(4) 1 calc PR A 2
C16A C 0.1377(4) 0.5753(7) 0.4548(2) 0.0590(9) Uani 0.440(4) 1 d PD A 2
H16D H 0.1263 0.5819 0.4865 0.089 Uiso 0.440(4) 1 calc PR A 2
H16E H 0.1607 0.6278 0.4449 0.089 Uiso 0.440(4) 1 calc PR A 2
H16F H 0.1742 0.5282 0.4535 0.089 Uiso 0.440(4) 1 calc PR A 2
S3 S 0.22104(4) 0.40376(5) 0.30746(2) 0.03212(15) Uani 1 1 d . . .
C17 C 0.17380(14) 0.32867(16) 0.26779(8) 0.0257(5) Uani 1 1 d . . .
C18 C 0.10814(14) 0.28248(16) 0.27601(8) 0.0242(5) Uani 1 1 d . . .
C19 C 0.07897(15) 0.22206(15) 0.24301(8) 0.0252(5) Uani 1 1 d . . .
C20 C 0.11564(15) 0.20701(15) 0.20429(8) 0.0268(5) Uani 1 1 d . . .
H20 H 0.0948 0.1654 0.1825 0.032 Uiso 1 1 calc R . .
C21 C 0.18142(14) 0.25087(15) 0.19660(8) 0.0246(5) Uani 1 1 d . . .
C22 C 0.20945(15) 0.31212(16) 0.22885(8) 0.0279(5) Uani 1 1 d . . .
H22 H 0.2542 0.3437 0.2242 0.033 Uiso 1 1 calc R . .
S4 S 0.06564(4) 0.29650(4) 0.32722(2) 0.02821(14) Uani 1 1 d . . .
C23 C 0.1224(2) 0.2174(2) 0.36122(9) 0.0517(9) Uani 1 1 d . . .
H23A H 0.1192 0.1627 0.3443 0.062 Uiso 1 1 calc R . .
H23B H 0.1774 0.2352 0.3666 0.062 Uiso 1 1 calc R . .
C24 C 0.09267(17) 0.20623(18) 0.40672(8) 0.0338(6) Uani 1 1 d . . .
C25 C 0.12380(16) 0.25493(18) 0.44349(9) 0.0331(6) Uani 1 1 d . . .
H25 H 0.1628 0.2951 0.4389 0.040 Uiso 1 1 calc R . .
N2 N 0.10219(14) 0.24887(16) 0.48541(7) 0.0376(6) Uani 1 1 d . . .
C26 C 0.04750(19) 0.1921(2) 0.49147(10) 0.0445(8) Uani 1 1 d . . .
H26 H 0.0312 0.1874 0.5211 0.053 Uiso 1 1 calc R . .
C27 C 0.01395(19) 0.1402(2) 0.45667(12) 0.0495(8) Uani 1 1 d . . .
H27 H -0.0244 0.1000 0.4622 0.059 Uiso 1 1 calc R . .
C28 C 0.03679(19) 0.1475(2) 0.41344(11) 0.0453(7) Uani 1 1 d . . .
H28 H 0.0143 0.1125 0.3887 0.054 Uiso 1 1 calc R . .
C29 C 0.21681(16) 0.23859(17) 0.15183(8) 0.0304(6) Uani 1 1 d . . .
C30 C 0.30397(17) 0.2577(2) 0.15923(10) 0.0451(8) Uani 1 1 d . . .
H30A H 0.3123 0.3174 0.1681 0.068 Uiso 1 1 calc R . .
H30B H 0.3255 0.2469 0.1305 0.068 Uiso 1 1 calc R . .
H30C H 0.3298 0.2211 0.1838 0.068 Uiso 1 1 calc R . .
C31 C 0.1758(2) 0.3001(2) 0.11584(10) 0.0473(8) Uani 1 1 d . . .
H31A H 0.1199 0.2891 0.1118 0.071 Uiso 1 1 calc R . .
H31B H 0.1956 0.2918 0.0864 0.071 Uiso 1 1 calc R . .
H31C H 0.1857 0.3587 0.1264 0.071 Uiso 1 1 calc R . .
C32 C 0.2040(2) 0.1471(2) 0.13342(11) 0.0488(8) Uani 1 1 d . . .
H32A H 0.2263 0.1068 0.1571 0.073 Uiso 1 1 calc R . .
H32B H 0.2293 0.1402 0.1057 0.073 Uiso 1 1 calc R . .
H32C H 0.1484 0.1363 0.1257 0.073 Uiso 1 1 calc R . .
S5 S 0.0000 0.15390(6) 0.2500 0.0333(2) Uani 1 2 d S . .
N3 N 0.19684(14) 0.89866(17) 0.05256(8) 0.0376(5) Uani 1 1 d . . .
O1 O 0.19517(13) 0.83803(15) 0.08018(7) 0.0473(5) Uani 1 1 d . . .
O2 O 0.23001(15) 0.88974(17) 0.01765(8) 0.0611(7) Uani 1 1 d . . .
O3 O 0.16599(16) 0.96630(16) 0.06007(9) 0.0599(7) Uani 1 1 d . . .
C33 C 0.07468(17) 0.89846(17) 0.14772(10) 0.0364(6) Uani 1 1 d . . .
H33 H 0.1250 0.9059 0.1353 0.044 Uiso 1 1 calc R . .
Cl1 Cl 0.07739(7) 0.80330(5) 0.17890(4) 0.0650(3) Uani 1 1 d . . .
Cl2 Cl 0.06169(6) 0.98346(5) 0.18472(3) 0.0559(2) Uani 1 1 d . . .
Cl3 Cl -0.00153(5) 0.89846(7) 0.10146(3) 0.0595(3) Uani 1 1 d . . .
C34 C 0.1744(3) 0.1449(3) 0.98646(16) 0.0792(13) Uani 1 1 d . . .
H34A H 0.1690 0.1698 1.0166 0.119 Uiso 1 1 calc R . .
H34B H 0.1560 0.1856 0.9620 0.119 Uiso 1 1 calc R . .
H34C H 0.2291 0.1316 0.9852 0.119 Uiso 1 1 calc R . .
O4 O 0.13079(17) 0.07106(19) 0.98026(9) 0.0680(7) Uani 1 1 d . . .
H4A H 0.1466 0.0362 1.0012 0.102 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag1 N1 170.23(9) 6_565 .
C1 S1 C1 104.75(15) . 2
C2 C1 C6 120.3(2) . .
C2 C1 S1 122.96(16) . .
C6 C1 S1 116.49(18) . .
C1 C2 C3 117.93(19) . .
C1 C2 S2 121.04(18) . .
C3 C2 S2 121.03(18) . .
C4 C3 C2 120.4(2) . .
C4 C3 S3 116.51(19) . .
C2 C3 S3 122.97(17) . .
C5 C4 C3 121.9(2) . .
C5 C4 H4 119.0 . .
C3 C4 H4 119.0 . .
C6 C5 C4 117.3(2) . .
C6 C5 C13 121.5(2) . .
C4 C5 C13 121.0(2) . .
C5 C6 C1 122.0(2) . .
C5 C6 H6 119.0 . .
C1 C6 H6 119.0 . .
C2 S2 C7 100.88(11) . .
C8 C7 S2 105.07(18) . .
C8 C7 H7A 110.7 . .
S2 C7 H7A 110.7 . .
C8 C7 H7B 110.7 . .
S2 C7 H7B 110.7 . .
H7A C7 H7B 108.8 . .
C9 C8 C12 117.6(2) . .
C9 C8 C7 120.2(2) . .
C12 C8 C7 122.1(3) . .
N1 C9 C8 123.3(3) . .
N1 C9 H9 118.3 . .
C8 C9 H9 118.3 . .
C9 N1 C10 117.9(2) . .
C9 N1 Ag1 120.8(2) . .
C10 N1 Ag1 121.22(18) . .
N1 C10 C11 121.9(2) . .
N1 C10 H10 119.0 . .
C11 C10 H10 119.0 . .
C10 C11 C12 119.8(3) . .
C10 C11 H11 120.1 . .
C12 C11 H11 120.1 . .
C11 C12 C8 119.5(3) . .
C11 C12 H12 120.3 . .
C8 C12 H12 120.3 . .
C16 C13 C14 112.2(4) . .
C16 C13 C14A 74.4(5) . .
C14 C13 C14A 132.6(4) . .
C16 C13 C5 114.2(3) . .
C14 C13 C5 110.8(3) . .
C14A C13 C5 107.6(3) . .
C14A C13 C16A 110.4(5) . .
C5 C13 C16A 108.8(3) . .
C16 C13 C15A 127.8(4) . .
C14A C13 C15A 109.9(5) . .
C5 C13 C15A 113.4(3) . .
C16A C13 C15A 106.8(5) . .
C16 C13 C15 107.0(4) . .
C14 C13 C15 106.7(4) . .
C5 C13 C15 105.3(3) . .
C16A C13 C15 138.6(4) . .
C13 C14 H14A 109.5 . .
C13 C14 H14B 109.5 . .
C13 C14 H14C 109.5 . .
C13 C15 H15A 109.5 . .
C13 C15 H15B 109.5 . .
C13 C15 H15C 109.5 . .
C13 C16 H16A 109.5 . .
C13 C16 H16B 109.5 . .
C13 C16 H16C 109.5 . .
C13 C14A H14D 109.5 . .
C13 C14A H14E 109.5 . .
H14D C14A H14E 109.5 . .
C13 C14A H14F 109.5 . .
H14D C14A H14F 109.5 . .
H14E C14A H14F 109.5 . .
C13 C15A H15D 109.5 . .
C13 C15A H15E 109.5 . .
H15D C15A H15E 109.5 . .
C13 C15A H15F 109.5 . .
H15D C15A H15F 109.5 . .
H15E C15A H15F 109.5 . .
C13 C16A H16D 109.5 . .
C13 C16A H16E 109.5 . .
H16D C16A H16E 109.5 . .
C13 C16A H16F 109.5 . .
H16D C16A H16F 109.5 . .
H16E C16A H16F 109.5 . .
C17 S3 C3 104.81(11) . .
C22 C17 C18 120.5(2) . .
C22 C17 S3 116.04(19) . .
C18 C17 S3 123.24(17) . .
C19 C18 C17 117.5(2) . .
C19 C18 S4 120.84(18) . .
C17 C18 S4 121.65(19) . .
C20 C19 C18 120.8(2) . .
C20 C19 S5 116.02(19) . .
C18 C19 S5 122.96(17) . .
C21 C20 C19 122.0(2) . .
C21 C20 H20 119.0 . .
C19 C20 H20 119.0 . .
C20 C21 C22 117.3(2) . .
C20 C21 C29 121.0(2) . .
C22 C21 C29 121.5(2) . .
C21 C22 C17 122.0(2) . .
C21 C22 H22 119.0 . .
C17 C22 H22 119.0 . .
C18 S4 C23 96.82(12) . .
C24 C23 S4 109.83(19) . .
C24 C23 H23A 109.7 . .
S4 C23 H23A 109.7 . .
C24 C23 H23B 109.7 . .
S4 C23 H23B 109.7 . .
H23A C23 H23B 108.2 . .
C25 C24 C28 118.4(2) . .
C25 C24 C23 118.8(3) . .
C28 C24 C23 122.8(3) . .
N2 C25 C24 123.3(3) . .
N2 C25 H25 118.3 . .
C24 C25 H25 118.3 . .
C25 N2 C26 117.8(3) . .
C25 N2 Ag1 118.8(2) . 6_566
C26 N2 Ag1 122.51(18) . 6_566
N2 C26 C27 122.6(3) . .
N2 C26 H26 118.7 . .
C27 C26 H26 118.7 . .
C26 C27 C28 118.9(3) . .
C26 C27 H27 120.6 . .
C28 C27 H27 120.6 . .
C24 C28 C27 119.0(3) . .
C24 C28 H28 120.5 . .
C27 C28 H28 120.5 . .
C21 C29 C31 107.6(2) . .
C21 C29 C30 111.1(2) . .
C31 C29 C30 109.4(2) . .
C21 C29 C32 111.1(2) . .
C31 C29 C32 108.6(3) . .
C30 C29 C32 109.0(2) . .
C29 C30 H30A 109.5 . .
C29 C30 H30B 109.5 . .
H30A C30 H30B 109.5 . .
C29 C30 H30C 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
C29 C31 H31A 109.5 . .
C29 C31 H31B 109.5 . .
H31A C31 H31B 109.5 . .
C29 C31 H31C 109.5 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
C29 C32 H32A 109.5 . .
C29 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
C29 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
C19 S5 C19 105.79(15) . 2
O3 N3 O2 120.5(3) . .
O3 N3 O1 119.8(2) . .
O2 N3 O1 119.7(3) . .
Cl1 C33 Cl2 109.13(16) . .
Cl1 C33 Cl3 111.34(16) . .
Cl2 C33 Cl3 109.05(16) . .
Cl1 C33 H33 109.1 . .
Cl2 C33 H33 109.1 . .
Cl3 C33 H33 109.1 . .
O4 C34 H34A 109.5 . .
O4 C34 H34B 109.5 . .
H34A C34 H34B 109.5 . .
O4 C34 H34C 109.5 . .
H34A C34 H34C 109.5 . .
H34B C34 H34C 109.5 . .
C34 O4 H4A 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N2 2.142(2) 6_565
Ag1 N1 2.142(2) .
S1 C1 1.777(2) .
S1 C1 1.777(2) 2
C1 C2 1.395(3) .
C1 C6 1.395(3) .
C2 C3 1.404(3) .
C2 S2 1.774(2) .
C3 C4 1.390(3) .
C3 S3 1.777(2) .
C4 C5 1.387(3) .
C4 H4 0.9500 .
C5 C6 1.385(3) .
C5 C13 1.531(3) .
C6 H6 0.9500 .
S2 C7 1.818(3) .
C7 C8 1.502(3) .
C7 H7A 0.9900 .
C7 H7B 0.9900 .
C8 C9 1.382(4) .
C8 C12 1.382(4) .
C9 N1 1.343(3) .
C9 H9 0.9500 .
N1 C10 1.346(4) .
C10 C11 1.367(5) .
C10 H10 0.9500 .
C11 C12 1.372(4) .
C11 H11 0.9500 .
C12 H12 0.9500 .
C13 C16 1.502(6) .
C13 C14 1.523(7) .
C13 C14A 1.530(8) .
C13 C16A 1.548(8) .
C13 C15A 1.543(8) .
C13 C15 1.584(7) .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C14A H14D 0.9800 .
C14A H14E 0.9800 .
C14A H14F 0.9800 .
C15A H15D 0.9800 .
C15A H15E 0.9800 .
C15A H15F 0.9800 .
C16A H16D 0.9800 .
C16A H16E 0.9800 .
C16A H16F 0.9800 .
S3 C17 1.777(3) .
C17 C22 1.394(3) .
C17 C18 1.403(3) .
C18 C19 1.400(3) .
C18 S4 1.773(2) .
C19 C20 1.394(3) .
C19 S5 1.778(3) .
C20 C21 1.382(4) .
C20 H20 0.9500 .
C21 C22 1.389(4) .
C21 C29 1.534(3) .
C22 H22 0.9500 .
S4 C23 1.802(3) .
C23 C24 1.503(4) .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C24 C25 1.370(4) .
C24 C28 1.376(5) .
C25 N2 1.334(3) .
C25 H25 0.9500 .
N2 C26 1.336(4) .
N2 Ag1 2.142(2) 6_566
C26 C27 1.371(5) .
C26 H26 0.9500 .
C27 C28 1.381(4) .
C27 H27 0.9500 .
C28 H28 0.9500 .
C29 C31 1.532(4) .
C29 C30 1.534(4) .
C29 C32 1.542(4) .
C30 H30A 0.9800 .
C30 H30B 0.9800 .
C30 H30C 0.9800 .
C31 H31A 0.9800 .
C31 H31B 0.9800 .
C31 H31C 0.9800 .
C32 H32A 0.9800 .
C32 H32B 0.9800 .
C32 H32C 0.9800 .
S5 C19 1.778(3) 2
N3 O3 1.226(3) .
N3 O2 1.248(3) .
N3 O1 1.253(3) .
C33 Cl1 1.751(3) .
C33 Cl2 1.755(3) .
C33 Cl3 1.761(3) .
C33 H33 1.0000 .
C34 O4 1.387(5) .
C34 H34A 0.9800 .
C34 H34B 0.9800 .
C34 H34C 0.9800 .
O4 H4A 0.8400 .
