#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/97/7029788.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7029788
loop_
_publ_author_name
'Zhang, Lei'
'Kuang, Xiaofei'
'Wu, Xiaoyuan'
'Yang, Wenbin'
'Lu, Canzhong'
_publ_section_title
;
 Supramolecular interactions induced hinge-like motion of a metal-organic
 framework accompanied by anisotropic thermal expansion.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7146
_journal_page_last               7152
_journal_paper_doi               10.1039/c3dt53580k
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C72 H51 Ag4 Mo8 N24 O27.5'
_chemical_formula_weight         2891.37
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 115.416(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   22.0765(5)
_cell_length_b                   16.3158(5)
_cell_length_c                   25.6800(8)
_cell_measurement_reflns_used    19879
_cell_measurement_temperature    100.01(15)
_cell_measurement_theta_max      29.4130
_cell_measurement_theta_min      3.3040
_cell_volume                     8354.6(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100.01(15)
_diffrn_detector_area_resol_mean 10.3503
_diffrn_measured_fraction_theta_full 0.970
_diffrn_measured_fraction_theta_max 0.970
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0377
_diffrn_reflns_av_sigmaI/netI    0.0350
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            19300
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.07
_exptl_absorpt_coefficient_mu    2.167
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.80965
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            pale-yellow
_exptl_crystal_density_diffrn    2.299
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block-like
_exptl_crystal_F_000             5580
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.709
_refine_diff_density_min         -1.843
_refine_diff_density_rms         0.128
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.043
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     616
_refine_ls_number_reflns         7157
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.043
_refine_ls_R_factor_all          0.0340
_refine_ls_R_factor_gt           0.0300
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0369P)²+34.6944P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0732
_refine_ls_wR_factor_ref         0.0758
_reflns_number_gt                6525
_reflns_number_total             7157
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt53580k2.cif
_cod_data_source_block           A_100K
_cod_depositor_comments
;Adding full bibliography for
 ./tmp-cod-update-bibliographies-12899/cifs/7029788.cif.
;
_cod_original_cell_volume        8354.6(4)
_cod_original_sg_symbol_H-M      C2/c
_cod_original_formula_sum        'C72 H51 Ag4 Mo8 N24 O27.50'
_cod_database_code               7029788
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag -0.177200(15) 1.24959(2) -0.132587(13) 0.01787(9) Uani 1 1 d .
Ag2 Ag 0.343480(14) 1.45725(2) 0.367674(13) 0.01576(9) Uani 1 1 d .
C21 C 0.00206(19) 1.3827(2) -0.00329(17) 0.0132(8) Uani 1 1 d .
H21A H 0.0215 1.3818 0.0368 0.016 Uiso 1 1 calc R
C22 C 0.03290(19) 1.8120(2) 0.41119(17) 0.0141(8) Uani 1 1 d .
H22A H 0.0544 1.7905 0.3900 0.017 Uiso 1 1 calc R
C23 C 0.12390(18) 1.7575(2) 0.50268(17) 0.0107(8) Uani 1 1 d .
C24 C 0.05978(18) 1.8021(2) 0.47046(17) 0.0118(8) Uani 1 1 d .
C25 C 0.27750(19) 1.6369(2) 0.00955(18) 0.0147(8) Uani 1 1 d .
H25A H 0.2983 1.6338 0.0496 0.018 Uiso 1 1 calc R
C26 C 0.23588(19) 1.5667(2) 0.38856(17) 0.0139(8) Uani 1 1 d .
H26A H 0.2140 1.5604 0.3488 0.017 Uiso 1 1 calc R
C27 C 0.21950(19) 1.6505(2) -0.10753(18) 0.0136(8) Uani 1 1 d .
H27A H 0.1993 1.6553 -0.1475 0.016 Uiso 1 1 calc R
C28 C -0.05734(19) 1.3424(2) -0.03449(18) 0.0138(8) Uani 1 1 d .
H28A H -0.0777 1.3152 -0.0144 0.017 Uiso 1 1 calc R
C30 C 0.09703(18) 1.4686(2) 0.00150(17) 0.0103(8) Uani 1 1 d .
C32 C 0.02603(19) 1.8362(3) 0.50012(18) 0.0154(8) Uani 1 1 d .
H32A H 0.0436 1.8320 0.5400 0.018 Uiso 1 1 calc R
C33 C 0.20969(18) 1.7263(2) 0.58792(17) 0.0119(8) Uani 1 1 d .
C36 C -0.03372(19) 1.8761(3) 0.46948(18) 0.0171(9) Uani 1 1 d .
H36A H -0.0563 1.8979 0.4896 0.020 Uiso 1 1 calc R
C37 C 0.03248(18) 1.4247(2) -0.03260(17) 0.0109(8) Uani 1 1 d .
C38 C 0.3058(2) 1.5069(3) 0.24289(19) 0.0199(9) Uani 1 1 d .
H38A H 0.3498 1.5243 0.2638 0.024 Uiso 1 1 calc R
C39 C 0.21522(18) 1.5998(2) -0.02187(17) 0.0124(8) Uani 1 1 d .
C40 C 0.1774(2) 1.4567(3) 0.18173(18) 0.0172(9) Uani 1 1 d .
H40A H 0.1334 1.4386 0.1618 0.021 Uiso 1 1 calc R
C41 C 0.00162(19) 1.4245(3) -0.09251(17) 0.0148(8) Uani 1 1 d .
H41A H 0.0202 1.4532 -0.1134 0.018 Uiso 1 1 calc R
C42 C 0.32611(19) 1.5406(2) 0.47437(17) 0.0124(8) Uani 1 1 d .
H42A H 0.3678 1.5164 0.4948 0.015 Uiso 1 1 calc R
C43 C 0.24281(19) 1.7361(2) 0.65192(17) 0.0135(8) Uani 1 1 d .
C44 C 0.3266(2) 1.7025(3) 0.74469(19) 0.0212(10) Uani 1 1 d .
H44A H 0.3653 1.6734 0.7672 0.025 Uiso 1 1 calc R
C45 C 0.30760(19) 1.6787(2) -0.02037(18) 0.0150(9) Uani 1 1 d .
H45A H 0.3490 1.7034 0.0006 0.018 Uiso 1 1 calc R
C46 C 0.29848(18) 1.5844(2) 0.50512(17) 0.0124(8) Uani 1 1 d .
H46A H 0.3209 1.5886 0.5450 0.015 Uiso 1 1 calc R
C47 C -0.02652(19) 1.8545(3) 0.38442(18) 0.0165(9) Uani 1 1 d .
H47A H -0.0436 1.8625 0.3448 0.020 Uiso 1 1 calc R
C48 C 0.17909(18) 1.5021(2) 0.08844(17) 0.0126(8) Uani 1 1 d .
C49 C 0.20600(18) 1.6727(2) 0.50572(17) 0.0109(8) Uani 1 1 d .
C50 C -0.05727(19) 1.3810(2) -0.12033(18) 0.0153(9) Uani 1 1 d .
H50A H -0.0770 1.3798 -0.1604 0.018 Uiso 1 1 calc R
C51 C 0.2768(2) 1.5177(3) 0.18374(18) 0.0179(9) Uani 1 1 d .
H51A H 0.3010 1.5412 0.1655 0.021 Uiso 1 1 calc R
C52 C 0.18585(18) 1.6080(2) -0.08147(17) 0.0116(8) Uani 1 1 d .
H52A H 0.1440 1.5851 -0.1036 0.014 Uiso 1 1 calc R
C53 C 0.18198(18) 1.5504(2) 0.00718(17) 0.0110(8) Uani 1 1 d .
C54 C 0.2102(2) 1.4482(3) 0.24074(18) 0.0202(9) Uani 1 1 d .
H54A H 0.1873 1.4245 0.2600 0.024 Uiso 1 1 calc R
C55 C 0.23636(18) 1.6220(2) 0.47502(17) 0.0121(8) Uani 1 1 d .
C56 C 0.21073(19) 1.4928(2) 0.15211(17) 0.0145(8) Uani 1 1 d .
C58 C 0.20471(19) 1.6117(2) 0.41534(17) 0.0130(8) Uani 1 1 d .
H58A H 0.1629 1.6351 0.3938 0.016 Uiso 1 1 calc R
C59 C 0.2151(2) 1.7878(3) 0.67851(18) 0.0181(9) Uani 1 1 d .
H59A H 0.1773 1.8188 0.6567 0.022 Uiso 1 1 calc R
C60 C 0.2444(2) 1.7929(3) 0.73784(19) 0.0204(9) Uani 1 1 d .
H60A H 0.2255 1.8280 0.7553 0.024 Uiso 1 1 calc R
C61 C 0.3012(2) 1.6945(3) 0.68564(18) 0.0169(9) Uani 1 1 d .
H61A H 0.3227 1.6621 0.6689 0.020 Uiso 1 1 calc R
N1 N -0.08766(16) 1.3401(2) -0.09254(15) 0.0139(7) Uani 1 1 d .
N2 N 0.27410(17) 1.4726(2) 0.27180(15) 0.0188(8) Uani 1 1 d .
N3 N 0.27963(16) 1.68523(19) -0.07840(15) 0.0130(7) Uani 1 1 d .
N4 N 0.12583(15) 1.5094(2) -0.02662(14) 0.0124(7) Uani 1 1 d .
N5 N 0.12131(15) 1.4620(2) 0.05897(14) 0.0128(7) Uani 1 1 d .
N6 N 0.21046(16) 1.5488(2) 0.06488(14) 0.0139(7) Uani 1 1 d .
N7 N 0.29632(15) 1.5311(2) 0.41691(14) 0.0122(7) Uani 1 1 d .
N8 N -0.06114(16) 1.8851(2) 0.41184(15) 0.0145(7) Uani 1 1 d .
N9 N 0.29904(17) 1.7494(2) 0.77171(15) 0.0189(8) Uani 1 1 d .
N10 N 0.14806(15) 1.7105(2) 0.47292(14) 0.0118(7) Uani 1 1 d .
N11 N 0.15314(15) 1.7683(2) 0.55984(14) 0.0128(7) Uani 1 1 d .
N12 N 0.23848(15) 1.6773(2) 0.56333(14) 0.0115(7) Uani 1 1 d .
Mo1 Mo 0.5000 1.46345(4) 0.2500 0.02750(15) Uani 1 2 d S
Mo2 Mo 0.497785(16) 1.58688(2) 0.360431(14) 0.01240(9) Uani 1 1 d .
Mo3 Mo 0.488833(16) 1.79132(2) 0.356519(14) 0.01148(9) Uani 1 1 d .
Mo4 Mo 0.5000 1.90013(3) 0.2500 0.01678(12) Uani 1 2 d S
Mo5 Mo 0.408560(16) 1.69242(2) 0.209286(15) 0.01125(9) Uani 1 1 d .
O1 O 0.5615(2) 1.3999(3) 0.2956(2) 0.0614(13) Uani 1 1 d .
O2 O 0.46259(15) 1.51334(18) 0.29279(13) 0.0228(7) Uani 1 1 d .
O3 O 0.55209(14) 1.52264(19) 0.41165(13) 0.0234(7) Uani 1 1 d .
O4 O 0.42634(14) 1.58240(19) 0.37081(13) 0.0237(7) Uani 1 1 d .
O5 O 0.53351(14) 1.68947(18) 0.39218(12) 0.0188(6) Uani 1 1 d .
O6 O 0.44393(17) 1.68508(19) 0.28594(13) 0.0284(8) Uani 1 1 d .
O7 O 0.42167(14) 1.78734(19) 0.37269(14) 0.0238(7) Uani 1 1 d .
O8 O 0.54188(15) 1.85726(19) 0.40568(13) 0.0240(7) Uani 1 1 d .
O9 O 0.42804(17) 1.6027(2) 0.18056(16) 0.0340(8) Uani 1 1 d .
O10 O 0.32338(14) 1.69845(19) 0.18113(15) 0.0288(8) Uani 1 1 d .
O11 O 0.44904(14) 1.85831(17) 0.28793(12) 0.0188(6) Uani 1 1 d .
O12 O 0.43929(14) 1.78214(18) 0.18781(13) 0.0200(6) Uani 1 1 d .
O13 O 0.55669(15) 1.96360(19) 0.29996(14) 0.0261(7) Uani 1 1 d .
O14 O 0.5994(4) 2.1143(5) 0.2670(3) 0.0418(19) Uani 0.50 1 d P
H14A H 0.5707 2.1517 0.2623 0.063 Uiso 0.50 1 d PR
H14B H 0.5860 2.0704 0.2765 0.063 Uiso 0.50 1 d PR
O15 O 0.5000 1.2463(12) 0.2500 0.112(6) Uiso 0.50 2 d SP
H15A H 0.5293 1.2093 0.2555 0.168 Uiso 0.25 1 d PR
H15B H 0.5201 1.2908 0.2645 0.168 Uiso 0.25 1 d PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N3 Ag1 N9 134.52(12) 3_445 3_444
N3 Ag1 N1 121.82(12) 3_445 .
N9 Ag1 N1 103.65(12) 3_444 .
N8 Ag2 N2 130.51(12) 3_545 .
N8 Ag2 N7 123.03(12) 3_545 .
N2 Ag2 N7 106.45(12) . .
C28 C21 C37 118.9(4) . .
C47 C22 C24 118.3(4) . .
N11 C23 N10 125.2(3) . .
N11 C23 C24 116.2(3) . .
N10 C23 C24 118.5(3) . .
C22 C24 C32 118.5(4) . .
C22 C24 C23 121.7(3) . .
C32 C24 C23 119.8(4) . .
C45 C25 C39 118.6(4) . .
N7 C26 C58 123.5(4) . .
N3 C27 C52 123.5(4) . .
N1 C28 C21 123.7(4) . .
N4 C30 N5 125.5(4) . .
N4 C30 C37 118.7(3) . .
N5 C30 C37 115.9(3) . .
C36 C32 C24 118.9(4) . .
N11 C33 N12 125.3(4) . .
N11 C33 C43 116.3(3) . .
N12 C33 C43 118.5(3) . .
N8 C36 C32 123.3(4) . .
C21 C37 C41 118.6(4) . .
C21 C37 C30 118.7(3) . .
C41 C37 C30 122.7(3) . .
N2 C38 C51 123.8(4) . .
C52 C39 C25 118.2(4) . .
C52 C39 C53 120.5(3) . .
C25 C39 C53 121.3(4) . .
C54 C40 C56 119.4(4) . .
C50 C41 C37 118.6(4) . .
N7 C42 C46 124.0(4) . .
C61 C43 C59 118.7(4) . .
C61 C43 C33 121.4(4) . .
C59 C43 C33 119.8(4) . .
N9 C44 C61 124.2(4) . .
N3 C45 C25 123.2(4) . .
C42 C46 C55 118.7(4) . .
N8 C47 C22 124.1(4) . .
N6 C48 N5 125.1(4) . .
N6 C48 C56 117.8(3) . .
N5 C48 C56 117.1(3) . .
N10 C49 N12 125.5(4) . .
N10 C49 C55 116.6(3) . .
N12 C49 C55 117.8(3) . .
N1 C50 C41 123.6(4) . .
C38 C51 C56 118.6(4) . .
C27 C52 C39 119.2(4) . .
N6 C53 N4 124.6(4) . .
N6 C53 C39 117.9(3) . .
N4 C53 C39 117.5(3) . .
N2 C54 C40 122.9(4) . .
C46 C55 C58 117.8(4) . .
C46 C55 C49 120.7(4) . .
C58 C55 C49 121.5(3) . .
C51 C56 C40 118.1(4) . .
C51 C56 C48 119.5(4) . .
C40 C56 C48 122.3(4) . .
C26 C58 C55 119.4(4) . .
C60 C59 C43 119.1(4) . .
N9 C60 C59 123.2(4) . .
C43 C61 C44 118.2(4) . .
C28 N1 C50 116.6(3) . .
C28 N1 Ag1 115.6(3) . .
C50 N1 Ag1 127.1(3) . .
C38 N2 C54 117.2(4) . .
C38 N2 Ag2 112.0(3) . .
C54 N2 Ag2 130.6(3) . .
C27 N3 C45 117.3(3) . .
C27 N3 Ag1 115.6(3) . 3
C45 N3 Ag1 127.1(3) . 3
C30 N4 C53 114.9(3) . .
C48 N5 C30 114.6(3) . .
C48 N6 C53 115.1(3) . .
C42 N7 C26 116.6(3) . .
C42 N7 Ag2 122.9(3) . .
C26 N7 Ag2 120.5(3) . .
C47 N8 C36 116.7(3) . .
C47 N8 Ag2 123.5(3) . 3_455
C36 N8 Ag2 119.6(3) . 3_455
C44 N9 C60 116.5(4) . .
C44 N9 Ag1 127.7(3) . 3_556
C60 N9 Ag1 115.0(3) . 3_556
C49 N10 C23 114.1(3) . .
C33 N11 C23 115.1(3) . .
C33 N12 C49 114.6(3) . .
O1 Mo1 O1 105.3(4) 2_655 .
O1 Mo1 O2 104.58(16) 2_655 .
O1 Mo1 O2 106.81(17) . .
O1 Mo1 O2 106.81(17) 2_655 2_655
O1 Mo1 O2 104.58(16) . 2_655
O2 Mo1 O2 127.03(19) . 2_655
O3 Mo2 O4 104.09(15) . .
O3 Mo2 O5 100.80(14) . .
O4 Mo2 O5 102.34(13) . .
O3 Mo2 O2 100.71(14) . .
O4 Mo2 O2 94.02(14) . .
O5 Mo2 O2 148.80(13) . .
O3 Mo2 O9 91.10(13) . 2_655
O4 Mo2 O9 163.20(14) . 2_655
O5 Mo2 O9 81.40(13) . 2_655
O2 Mo2 O9 75.85(13) . 2_655
O3 Mo2 O6 166.98(13) . .
O4 Mo2 O6 88.74(14) . .
O5 Mo2 O6 73.84(11) . .
O2 Mo2 O6 80.23(11) . .
O9 Mo2 O6 76.47(12) 2_655 .
O8 Mo3 O7 103.81(15) . .
O8 Mo3 O11 102.65(14) . .
O7 Mo3 O11 98.09(13) . .
O8 Mo3 O5 98.23(14) . .
O7 Mo3 O5 99.83(13) . .
O11 Mo3 O5 148.25(12) . .
O8 Mo3 O12 90.41(12) . 2_655
O7 Mo3 O12 165.16(13) . 2_655
O11 Mo3 O12 74.26(11) . 2_655
O5 Mo3 O12 82.00(11) . 2_655
O8 Mo3 O6 162.95(13) . .
O7 Mo3 O6 92.06(14) . .
O11 Mo3 O6 80.85(11) . .
O5 Mo3 O6 72.54(11) . .
O12 Mo3 O6 74.34(11) 2_655 .
O13 Mo4 O13 105.2(2) . 2_655
O13 Mo4 O11 101.46(13) . 2_655
O13 Mo4 O11 103.70(14) 2_655 2_655
O13 Mo4 O11 103.70(14) . .
O13 Mo4 O11 101.46(13) 2_655 .
O11 Mo4 O11 137.97(17) 2_655 .
O13 Mo4 O12 166.00(13) . .
O13 Mo4 O12 88.15(13) 2_655 .
O11 Mo4 O12 70.65(10) 2_655 .
O11 Mo4 O12 77.15(11) . .
O13 Mo4 O12 88.15(13) . 2_655
O13 Mo4 O12 166.00(13) 2_655 2_655
O11 Mo4 O12 77.15(11) 2_655 2_655
O11 Mo4 O12 70.65(10) . 2_655
O12 Mo4 O12 78.90(14) . 2_655
O10 Mo5 O9 106.96(16) . .
O10 Mo5 O6 110.67(17) . .
O9 Mo5 O6 109.54(16) . .
O10 Mo5 O12 108.43(14) . .
O9 Mo5 O12 110.72(14) . .
O6 Mo5 O12 110.45(14) . .
Mo1 O2 Mo2 133.75(17) . .
Mo2 O5 Mo3 121.45(15) . .
Mo5 O6 Mo2 139.63(17) . .
Mo5 O6 Mo3 129.05(16) . .
Mo2 O6 Mo3 88.70(10) . .
Mo5 O9 Mo2 128.91(16) . 2_655
Mo4 O11 Mo3 122.11(14) . .
Mo5 O12 Mo3 129.11(15) . 2_655
Mo5 O12 Mo4 127.05(15) . .
Mo3 O12 Mo4 88.38(9) 2_655 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N3 2.255(3) 3_445
Ag1 N9 2.282(4) 3_444
Ag1 N1 2.324(3) .
Ag2 N8 2.249(3) 3_545
Ag2 N2 2.288(3) .
Ag2 N7 2.294(3) .
C21 C28 1.376(6) .
C21 C37 1.386(5) .
C22 C47 1.379(6) .
C22 C24 1.386(6) .
C23 N11 1.338(5) .
C23 N10 1.344(5) .
C23 C24 1.488(5) .
C24 C32 1.390(5) .
C25 C45 1.391(6) .
C25 C39 1.399(6) .
C26 N7 1.347(5) .
C26 C58 1.376(6) .
C27 N3 1.338(5) .
C27 C52 1.381(5) .
C28 N1 1.347(5) .
C30 N4 1.328(5) .
C30 N5 1.341(5) .
C30 C37 1.496(5) .
C32 C36 1.376(6) .
C33 N11 1.333(5) .
C33 N12 1.337(5) .
C33 C43 1.493(5) .
C36 N8 1.345(5) .
C37 C41 1.390(6) .
C38 N2 1.341(6) .
C38 C51 1.383(6) .
C39 C52 1.389(6) .
C39 C53 1.488(5) .
C40 C54 1.378(6) .
C40 C56 1.395(6) .
C41 C50 1.382(6) .
C42 N7 1.342(5) .
C42 C46 1.385(5) .
C43 C61 1.382(6) .
C43 C59 1.382(6) .
C44 N9 1.342(6) .
C44 C61 1.379(6) .
C45 N3 1.350(5) .
C46 C55 1.395(5) .
C47 N8 1.338(5) .
C48 N6 1.336(5) .
C48 N5 1.341(5) .
C48 C56 1.485(6) .
C49 N10 1.342(5) .
C49 N12 1.341(5) .
C49 C55 1.486(5) .
C50 N1 1.347(5) .
C51 C56 1.391(6) .
C53 N6 1.339(5) .
C53 N4 1.347(5) .
C54 N2 1.349(6) .
C55 C58 1.395(6) .
C59 C60 1.379(6) .
C60 N9 1.347(6) .
N3 Ag1 2.255(3) 3
N8 Ag2 2.249(3) 3_455
N9 Ag1 2.282(4) 3_556
Mo1 O1 1.710(4) 2_655
Mo1 O1 1.710(4) .
Mo1 O2 1.825(3) .
Mo1 O2 1.825(3) 2_655
Mo2 O3 1.706(3) .
Mo2 O4 1.710(3) .
Mo2 O5 1.881(3) .
Mo2 O2 1.975(3) .
Mo2 O9 2.310(3) 2_655
Mo2 O6 2.385(3) .
Mo3 O8 1.689(3) .
Mo3 O7 1.704(3) .
Mo3 O11 1.934(3) .
Mo3 O5 1.949(3) .
Mo3 O12 2.321(3) 2_655
Mo3 O6 2.394(3) .
Mo4 O13 1.705(3) .
Mo4 O13 1.705(3) 2_655
Mo4 O11 1.903(3) 2_655
Mo4 O11 1.903(3) .
Mo4 O12 2.493(3) .
Mo4 O12 2.493(3) 2_655
Mo5 O10 1.703(3) .
Mo5 O9 1.773(3) .
Mo5 O6 1.783(3) .
Mo5 O12 1.797(3) .
O9 Mo2 2.310(3) 2_655
O12 Mo3 2.321(3) 2_655
