#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/97/7029790.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7029790
loop_
_publ_author_name
'Zhang, Lei'
'Kuang, Xiaofei'
'Wu, Xiaoyuan'
'Yang, Wenbin'
'Lu, Canzhong'
_publ_section_title
;
 Supramolecular interactions induced hinge-like motion of a metal-organic
 framework accompanied by anisotropic thermal expansion.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7146
_journal_page_last               7152
_journal_paper_doi               10.1039/c3dt53580k
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C72 H51 Ag4 Mo8 N24 O27.5'
_chemical_formula_weight         2891.37
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 115.391(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   22.0532(5)
_cell_length_b                   16.3828(5)
_cell_length_c                   25.6809(8)
_cell_measurement_reflns_used    19189
_cell_measurement_temperature    160.01(10)
_cell_measurement_theta_max      29.4520
_cell_measurement_theta_min      3.3120
_cell_volume                     8382.1(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      160.01(10)
_diffrn_detector_area_resol_mean 10.3503
_diffrn_measured_fraction_theta_full 0.971
_diffrn_measured_fraction_theta_max 0.971
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0400
_diffrn_reflns_av_sigmaI/netI    0.0463
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            19437
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.07
_exptl_absorpt_coefficient_mu    2.160
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.74529
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            pale-yellow
_exptl_crystal_density_diffrn    2.291
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block-like
_exptl_crystal_F_000             5580
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.625
_refine_diff_density_min         -1.445
_refine_diff_density_rms         0.117
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.104
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     616
_refine_ls_number_reflns         7188
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.104
_refine_ls_R_factor_all          0.0343
_refine_ls_R_factor_gt           0.0297
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0267P)²+0.9577P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0687
_refine_ls_wR_factor_ref         0.0720
_reflns_number_gt                6452
_reflns_number_total             7188
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt53580k2.cif
_cod_data_source_block           A_160K
_cod_depositor_comments
;Adding full bibliography for
 ./tmp-cod-update-bibliographies-12899/cifs/7029790.cif.
;
_cod_original_cell_volume        8382.1(4)
_cod_original_sg_symbol_H-M      C2/c
_cod_original_formula_sum        'C72 H51 Ag4 Mo8 N24 O27.50'
_cod_database_code               7029790
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.343888(14) 0.45794(2) 0.367957(14) 0.02169(9) Uani 1 1 d .
Ag2 Ag 0.823012(14) 0.25006(2) 0.867545(14) 0.02461(10) Uani 1 1 d .
Mo1 Mo 0.5000 0.46264(4) 0.2500 0.03239(15) Uani 1 2 d S
Mo2 Mo 0.498184(15) 0.58777(2) 0.360364(15) 0.01595(9) Uani 1 1 d .
Mo3 Mo 0.488896(15) 0.79128(2) 0.356366(15) 0.01564(9) Uani 1 1 d .
Mo4 Mo 0.5000 0.90106(3) 0.2500 0.02271(13) Uani 1 2 d S
Mo5 Mo 0.408358(15) 0.69313(2) 0.209001(15) 0.01468(9) Uani 1 1 d .
C19 C 0.62426(17) 0.2573(2) 0.50269(17) 0.0136(8) Uani 1 1 d .
C20 C 1.00246(17) 0.3828(2) 0.99685(17) 0.0167(9) Uani 1 1 d .
H20A H 1.0218 0.3820 1.0369 0.020 Uiso 1 1 calc R
C24 C 0.53329(18) 0.3116(2) 0.41154(18) 0.0192(9) Uani 1 1 d .
H24A H 0.5547 0.2898 0.3904 0.023 Uiso 1 1 calc R
C25 C 1.27767(18) 0.6371(2) 1.00952(18) 0.0184(9) Uani 1 1 d .
H25A H 1.2985 0.6339 1.0495 0.022 Uiso 1 1 calc R
C26 C 0.73574(17) 0.0667(2) 0.38882(18) 0.0182(9) Uani 1 1 d .
H26A H 0.7140 0.0609 0.3490 0.022 Uiso 1 1 calc R
C28 C 0.56003(17) 0.3025(2) 0.47056(17) 0.0139(8) Uani 1 1 d .
C29 C 1.09731(17) 0.4691(2) 1.00160(17) 0.0142(8) Uani 1 1 d .
C30 C 1.21965(18) 0.6506(2) 0.89287(18) 0.0191(9) Uani 1 1 d .
H30A H 1.1993 0.6558 0.8530 0.023 Uiso 1 1 calc R
C31 C 0.71001(17) 0.2265(2) 0.58794(17) 0.0145(8) Uani 1 1 d .
C33 C 0.94336(17) 0.3424(2) 0.96570(18) 0.0178(9) Uani 1 1 d .
H33A H 0.9232 0.3149 0.9858 0.021 Uiso 1 1 calc R
C34 C 0.52662(18) 0.3359(3) 0.50049(18) 0.0201(9) Uani 1 1 d .
H34A H 0.5439 0.3310 0.5403 0.024 Uiso 1 1 calc R
C36 C 0.74322(17) 0.2368(3) 0.65183(17) 0.0173(9) Uani 1 1 d .
C37 C 1.17820(18) 0.4572(3) 1.18188(18) 0.0221(10) Uani 1 1 d .
H37A H 1.1341 0.4395 1.1620 0.026 Uiso 1 1 calc R
C38 C 1.3061(2) 0.5068(3) 1.24296(19) 0.0259(10) Uani 1 1 d .
H38A H 1.3503 0.5237 1.2638 0.031 Uiso 1 1 calc R
C39 C 1.21544(17) 0.6003(2) 0.97815(17) 0.0146(8) Uani 1 1 d .
C40 C 0.46710(18) 0.3765(3) 0.46970(19) 0.0231(10) Uani 1 1 d .
H40A H 0.4449 0.3991 0.4900 0.028 Uiso 1 1 calc R
C41 C 1.17955(17) 0.5024(2) 1.08870(17) 0.0160(9) Uani 1 1 d .
C42 C 1.03272(17) 0.4248(2) 0.96747(17) 0.0135(8) Uani 1 1 d .
C43 C 0.82586(18) 0.0407(2) 0.47462(17) 0.0152(8) Uani 1 1 d .
H43A H 0.8676 0.0164 0.4950 0.018 Uiso 1 1 calc R
C44 C 0.8270(2) 0.2028(3) 0.7448(2) 0.0278(10) Uani 1 1 d .
H44A H 0.8655 0.1736 0.7674 0.033 Uiso 1 1 calc R
C45 C 1.18608(17) 0.6080(2) 0.91861(17) 0.0157(8) Uani 1 1 d .
H45A H 1.1444 0.5847 0.8965 0.019 Uiso 1 1 calc R
C46 C 0.79855(17) 0.0842(2) 0.50551(18) 0.0172(9) Uani 1 1 d .
H46A H 0.8209 0.0884 0.5454 0.021 Uiso 1 1 calc R
C47 C 0.70600(17) 0.1725(2) 0.50584(17) 0.0142(8) Uani 1 1 d .
C48 C 1.18210(17) 0.5509(2) 1.00720(17) 0.0141(8) Uani 1 1 d .
C49 C 1.30779(18) 0.6784(2) 0.97975(18) 0.0188(9) Uani 1 1 d .
H49A H 1.3493 0.7026 1.0008 0.023 Uiso 1 1 calc R
C50 C 0.47327(18) 0.3545(3) 0.38447(18) 0.0206(9) Uani 1 1 d .
H50A H 0.4559 0.3620 0.3448 0.025 Uiso 1 1 calc R
C51 C 1.21077(19) 0.4484(3) 1.24078(18) 0.0248(10) Uani 1 1 d .
H51A H 1.1878 0.4245 1.2599 0.030 Uiso 1 1 calc R
C52 C 1.00208(18) 0.4247(3) 0.90778(18) 0.0207(9) Uani 1 1 d .
H52A H 1.0208 0.4532 0.8869 0.025 Uiso 1 1 calc R
C53 C 1.27737(18) 0.5183(3) 1.18389(18) 0.0214(9) Uani 1 1 d .
H53A H 1.3014 0.5425 1.1658 0.026 Uiso 1 1 calc R
C54 C 0.70463(18) 0.1111(2) 0.41562(18) 0.0172(9) Uani 1 1 d .
H54A H 0.6626 0.1339 0.3942 0.021 Uiso 1 1 calc R
C55 C 0.94299(18) 0.3813(3) 0.87979(18) 0.0203(9) Uani 1 1 d .
H55A H 0.9231 0.3803 0.8397 0.024 Uiso 1 1 calc R
C56 C 1.21120(18) 0.4925(3) 1.15223(17) 0.0180(9) Uani 1 1 d .
C57 C 0.73634(17) 0.1219(2) 0.47507(17) 0.0144(8) Uani 1 1 d .
C58 C 0.7452(2) 0.2935(3) 0.73782(19) 0.0264(10) Uani 1 1 d .
H58A H 0.7266 0.3286 0.7554 0.032 Uiso 1 1 calc R
C59 C 0.71564(19) 0.2884(3) 0.67849(18) 0.0222(9) Uani 1 1 d .
H59A H 0.6778 0.3193 0.6568 0.027 Uiso 1 1 calc R
C60 C 0.80146(19) 0.1946(3) 0.68548(18) 0.0214(9) Uani 1 1 d .
H60A H 0.8227 0.1618 0.6688 0.026 Uiso 1 1 calc R
N1 N 0.43924(14) 0.3854(2) 0.41206(15) 0.0188(8) Uani 1 1 d .
N2 N 0.79631(14) 0.03108(19) 0.41731(14) 0.0145(7) Uani 1 1 d .
N3 N 0.79971(16) 0.2501(2) 0.77150(15) 0.0229(8) Uani 1 1 d .
N4 N 0.64818(14) 0.2108(2) 0.47294(14) 0.0153(7) Uani 1 1 d .
N5 N 0.73866(14) 0.17717(19) 0.56336(14) 0.0148(7) Uani 1 1 d .
N6 N 0.65333(14) 0.2683(2) 0.55991(14) 0.0152(7) Uani 1 1 d .
N7 N 0.91294(14) 0.3404(2) 0.90776(15) 0.0191(7) Uani 1 1 d .
N8 N 1.28001(15) 0.6853(2) 0.92195(15) 0.0170(8) Uani 1 1 d .
N9 N 1.27483(16) 0.4731(2) 1.27201(15) 0.0238(8) Uani 1 1 d .
N10 N 1.12603(14) 0.5099(2) 0.97341(14) 0.0158(7) Uani 1 1 d .
N11 N 1.21081(14) 0.5491(2) 1.06505(15) 0.0178(7) Uani 1 1 d .
N12 N 1.12185(14) 0.4624(2) 1.05918(14) 0.0158(7) Uani 1 1 d .
O1 O 0.5618(2) 0.3994(3) 0.2951(2) 0.0833(17) Uani 1 1 d .
O2 O 0.46390(13) 0.51390(18) 0.29297(12) 0.0267(7) Uani 1 1 d .
O3 O 0.55219(13) 0.52423(19) 0.41186(13) 0.0320(8) Uani 1 1 d .
O4 O 0.42641(13) 0.58255(19) 0.37022(13) 0.0292(7) Uani 1 1 d .
O5 O 0.32348(13) 0.69965(18) 0.18235(15) 0.0320(8) Uani 1 1 d .
O6 O 0.42639(14) 0.60415(19) 0.17914(15) 0.0341(8) Uani 1 1 d .
O7 O 0.44537(15) 0.68531(18) 0.28571(13) 0.0322(8) Uani 1 1 d .
O8 O 0.53343(12) 0.69001(17) 0.39257(12) 0.0230(7) Uani 1 1 d .
O9 O 0.42120(13) 0.78742(19) 0.37168(14) 0.0305(7) Uani 1 1 d .
O10 O 0.54140(13) 0.85717(19) 0.40567(14) 0.0311(7) Uani 1 1 d .
O11 O 0.43827(13) 0.78249(19) 0.18693(13) 0.0249(7) Uani 1 1 d .
O12 O 0.44952(12) 0.85823(17) 0.28791(13) 0.0243(7) Uani 1 1 d .
O13 O 0.55687(15) 0.9640(2) 0.30001(14) 0.0364(8) Uani 1 1 d .
O14 O 0.5995(4) 1.1143(5) 0.2677(3) 0.069(3) Uani 0.50 1 d P
H14A H 0.5866 1.0700 0.2770 0.104 Uiso 0.50 1 d PR
H14B H 0.5699 1.1506 0.2624 0.104 Uiso 0.50 1 d PR
O15 O 0.5000 1.2387(16) 0.2500 0.193(10) Uiso 0.50 2 d SP
H15A H 0.4813 1.2842 0.2368 0.289 Uiso 0.25 1 d PR
H15B H 0.4696 1.2034 0.2443 0.289 Uiso 0.25 1 d PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N9 130.20(12) . 1_454
N1 Ag1 N2 123.11(12) . 3_455
N9 Ag1 N2 106.67(12) 1_454 3_455
N8 Ag2 N3 134.81(12) 3_445 .
N8 Ag2 N7 121.78(12) 3_445 .
N3 Ag2 N7 103.41(12) . .
O1 Mo1 O1 105.3(4) 2_655 .
O1 Mo1 O2 107.32(18) 2_655 2_655
O1 Mo1 O2 105.19(15) . 2_655
O1 Mo1 O2 105.19(15) 2_655 .
O1 Mo1 O2 107.32(18) . .
O2 Mo1 O2 125.02(19) 2_655 .
O3 Mo2 O4 103.78(14) . .
O3 Mo2 O8 100.56(14) . .
O4 Mo2 O8 102.34(13) . .
O3 Mo2 O2 100.55(14) . .
O4 Mo2 O2 93.91(13) . .
O8 Mo2 O2 149.34(13) . .
O3 Mo2 O6 90.95(12) . 2_655
O4 Mo2 O6 163.71(13) . 2_655
O8 Mo2 O6 81.37(12) . 2_655
O2 Mo2 O6 76.31(12) . 2_655
O3 Mo2 O7 166.69(12) . .
O4 Mo2 O7 89.34(13) . .
O8 Mo2 O7 73.97(11) . .
O2 Mo2 O7 80.48(11) . .
O6 Mo2 O7 76.33(11) 2_655 .
O10 Mo3 O9 103.77(14) . .
O10 Mo3 O12 102.43(14) . .
O9 Mo3 O12 97.75(13) . .
O10 Mo3 O8 98.24(14) . .
O9 Mo3 O8 99.84(13) . .
O12 Mo3 O8 148.72(12) . .
O10 Mo3 O11 90.34(12) . 2_655
O9 Mo3 O11 165.19(13) . 2_655
O12 Mo3 O11 74.48(10) . 2_655
O8 Mo3 O11 82.23(11) . 2_655
O10 Mo3 O7 162.70(12) . .
O9 Mo3 O7 92.40(13) . .
O12 Mo3 O7 81.05(11) . .
O8 Mo3 O7 72.58(11) . .
O11 Mo3 O7 74.12(11) 2_655 .
O13 Mo4 O13 105.5(2) . 2_655
O13 Mo4 O12 101.90(13) . 2_655
O13 Mo4 O12 103.93(14) 2_655 2_655
O13 Mo4 O12 103.93(14) . .
O13 Mo4 O12 101.90(13) 2_655 .
O12 Mo4 O12 136.64(17) 2_655 .
O5 Mo5 O6 106.90(15) . .
O5 Mo5 O7 110.66(16) . .
O6 Mo5 O7 109.74(15) . .
O5 Mo5 O11 108.20(13) . .
O6 Mo5 O11 110.71(14) . .
O7 Mo5 O11 110.56(14) . .
N4 C19 N6 125.7(3) . .
N4 C19 C28 118.7(3) . .
N6 C19 C28 115.7(3) . .
C33 C20 C42 118.8(4) . .
C28 C24 C50 118.1(4) . .
C49 C25 C39 118.6(4) . .
N2 C26 C54 123.3(4) . .
C24 C28 C34 119.3(3) . .
C24 C28 C19 121.2(3) . .
C34 C28 C19 119.6(4) . .
N10 C29 N12 125.4(3) . .
N10 C29 C42 118.7(3) . .
N12 C29 C42 115.9(3) . .
N8 C30 C45 123.9(4) . .
N6 C31 N5 125.3(4) . .
N6 C31 C36 116.1(3) . .
N5 C31 C36 118.5(3) . .
N7 C33 C20 123.8(4) . .
C40 C34 C28 118.3(4) . .
C59 C36 C60 118.9(4) . .
C59 C36 C31 120.0(3) . .
C60 C36 C31 121.1(4) . .
C51 C37 C56 119.9(4) . .
N9 C38 C53 124.4(4) . .
C45 C39 C25 118.4(4) . .
C45 C39 C48 120.3(3) . .
C25 C39 C48 121.3(4) . .
N1 C40 C34 123.8(4) . .
N12 C41 N11 124.9(4) . .
N12 C41 C56 117.0(3) . .
N11 C41 C56 118.1(3) . .
C52 C42 C20 118.8(3) . .
C52 C42 C29 122.5(3) . .
C20 C42 C29 118.7(3) . .
N2 C43 C46 124.4(3) . .
N3 C44 C60 124.0(4) . .
C30 C45 C39 118.9(3) . .
C43 C46 C57 118.1(4) . .
N5 C47 N4 125.7(4) . .
N5 C47 C57 117.7(3) . .
N4 C47 C57 116.6(3) . .
N11 C48 N10 124.7(3) . .
N11 C48 C39 117.8(3) . .
N10 C48 C39 117.5(3) . .
N8 C49 C25 123.4(3) . .
N1 C50 C24 123.9(4) . .
N9 C51 C37 122.7(4) . .
C55 C52 C42 118.6(4) . .
C38 C53 C56 118.1(4) . .
C26 C54 C57 119.6(3) . .
N7 C55 C52 123.2(4) . .
C37 C56 C53 118.1(4) . .
C37 C56 C41 122.7(3) . .
C53 C56 C41 119.2(4) . .
C54 C57 C46 118.0(4) . .
C54 C57 C47 121.6(3) . .
C46 C57 C47 120.4(4) . .
N3 C58 C59 123.3(4) . .
C58 C59 C36 118.9(4) . .
C36 C60 C44 117.9(4) . .
C50 N1 C40 116.6(3) . .
C50 N1 Ag1 123.4(3) . .
C40 N1 Ag1 119.8(3) . .
C43 N2 C26 116.6(3) . .
C43 N2 Ag1 123.0(2) . 3_545
C26 N2 Ag1 120.4(3) . 3_545
C44 N3 C58 116.8(4) . .
C44 N3 Ag2 127.5(3) . .
C58 N3 Ag2 114.8(3) . .
C19 N4 C47 114.0(3) . .
C47 N5 C31 114.5(3) . .
C31 N6 C19 114.8(3) . .
C55 N7 C33 116.9(3) . .
C55 N7 Ag2 126.8(3) . .
C33 N7 Ag2 115.6(3) . .
C30 N8 C49 116.9(3) . .
C30 N8 Ag2 115.7(3) . 3
C49 N8 Ag2 127.4(2) . 3
C38 N9 C51 116.8(4) . .
C38 N9 Ag1 112.5(3) . 1_656
C51 N9 Ag1 130.5(3) . 1_656
C29 N10 C48 114.9(3) . .
C48 N11 C41 115.1(3) . .
C41 N12 C29 114.8(3) . .
Mo1 O2 Mo2 135.31(15) . .
Mo5 O6 Mo2 128.68(15) . 2_655
Mo5 O7 Mo2 140.47(16) . .
Mo5 O7 Mo3 129.01(15) . .
Mo2 O7 Mo3 88.72(10) . .
Mo2 O8 Mo3 121.28(14) . .
Mo5 O11 Mo3 128.81(15) . 2_655
Mo4 O12 Mo3 122.83(13) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.253(3) .
Ag1 N9 2.288(3) 1_454
Ag1 N2 2.299(3) 3_455
Ag2 N8 2.262(3) 3_445
Ag2 N3 2.294(4) .
Ag2 N7 2.331(3) .
Mo1 O1 1.707(4) 2_655
Mo1 O1 1.707(4) .
Mo1 O2 1.819(3) 2_655
Mo1 O2 1.819(3) .
Mo2 O3 1.703(3) .
Mo2 O4 1.709(3) .
Mo2 O8 1.882(3) .
Mo2 O2 1.977(3) .
Mo2 O6 2.306(3) 2_655
Mo2 O7 2.381(3) .
Mo3 O10 1.689(3) .
Mo3 O9 1.700(3) .
Mo3 O12 1.934(3) .
Mo3 O8 1.949(3) .
Mo3 O11 2.317(3) 2_655
Mo3 O7 2.395(3) .
Mo4 O13 1.704(3) .
Mo4 O13 1.704(3) 2_655
Mo4 O12 1.900(3) 2_655
Mo4 O12 1.900(3) .
Mo5 O5 1.699(3) .
Mo5 O6 1.770(3) .
Mo5 O7 1.784(3) .
Mo5 O11 1.795(3) .
C19 N4 1.337(5) .
C19 N6 1.340(5) .
C19 C28 1.495(5) .
C20 C33 1.372(5) .
C20 C42 1.385(5) .
C24 C28 1.379(6) .
C24 C50 1.393(5) .
C25 C49 1.385(5) .
C25 C39 1.396(5) .
C26 N2 1.350(5) .
C26 C54 1.370(5) .
C28 C34 1.385(5) .
C29 N10 1.329(5) .
C29 N12 1.344(5) .
C29 C42 1.501(5) .
C30 N8 1.341(5) .
C30 C45 1.376(5) .
C31 N6 1.333(5) .
C31 N5 1.339(5) .
C31 C36 1.492(5) .
C33 N7 1.345(5) .
C34 C40 1.379(5) .
C36 C59 1.383(6) .
C36 C60 1.386(5) .
C37 C51 1.376(6) .
C37 C56 1.385(6) .
C38 N9 1.335(5) .
C38 C53 1.383(6) .
C39 C45 1.387(5) .
C39 C48 1.490(5) .
C40 N1 1.345(5) .
C41 N12 1.340(5) .
C41 N11 1.338(5) .
C41 C56 1.483(5) .
C42 C52 1.385(6) .
C43 N2 1.339(5) .
C43 C46 1.382(5) .
C44 N3 1.337(6) .
C44 C60 1.386(6) .
C46 C57 1.398(5) .
C47 N5 1.340(5) .
C47 N4 1.345(5) .
C47 C57 1.488(5) .
C48 N11 1.342(5) .
C48 N10 1.347(5) .
C49 N8 1.346(5) .
C50 N1 1.333(5) .
C51 N9 1.353(5) .
C52 C55 1.385(5) .
C53 C56 1.397(5) .
C54 C57 1.391(6) .
C55 N7 1.346(5) .
C58 N3 1.343(5) .
C58 C59 1.379(6) .
N2 Ag1 2.299(3) 3_545
N8 Ag2 2.262(3) 3
N9 Ag1 2.288(3) 1_656
O6 Mo2 2.306(3) 2_655
O11 Mo3 2.317(3) 2_655
