#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/97/7029793.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7029793
loop_
_publ_author_name
'Zhang, Lei'
'Kuang, Xiaofei'
'Wu, Xiaoyuan'
'Yang, Wenbin'
'Lu, Canzhong'
_publ_section_title
;
 Supramolecular interactions induced hinge-like motion of a metal-organic
 framework accompanied by anisotropic thermal expansion.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7146
_journal_page_last               7152
_journal_paper_doi               10.1039/c3dt53580k
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C72 H51 Ag4 Mo8 N24 O27.5'
_chemical_formula_weight         2891.37
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 115.385(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   22.0248(6)
_cell_length_b                   16.4933(6)
_cell_length_c                   25.6766(8)
_cell_measurement_reflns_used    17715
_cell_measurement_temperature    250.01(10)
_cell_measurement_theta_max      29.2160
_cell_measurement_theta_min      3.3090
_cell_volume                     8426.7(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      250.01(10)
_diffrn_detector_area_resol_mean 10.3503
_diffrn_measured_fraction_theta_full 0.971
_diffrn_measured_fraction_theta_max 0.971
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0353
_diffrn_reflns_av_sigmaI/netI    0.0441
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            19551
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.07
_exptl_absorpt_coefficient_mu    2.149
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.77748
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            kermesinus
_exptl_crystal_density_diffrn    2.279
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block-like
_exptl_crystal_F_000             5580
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.297
_refine_diff_density_min         -1.191
_refine_diff_density_rms         0.107
_refine_ls_extinction_coef       0.000031(9)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.101
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     614
_refine_ls_number_reflns         7214
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.101
_refine_ls_R_factor_all          0.0356
_refine_ls_R_factor_gt           0.0296
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0240P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0647
_refine_ls_wR_factor_ref         0.0687
_reflns_number_gt                6334
_reflns_number_total             7214
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt53580k2.cif
_cod_data_source_block           A_250K
_cod_depositor_comments
;Adding full bibliography for
 ./tmp-cod-update-bibliographies-12899/cifs/7029793.cif.
;
_cod_original_sg_symbol_H-M      C2/c
_cod_original_formula_sum        'C72 H51 Ag4 Mo8 N24 O27.50'
_cod_database_code               7029793
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.273961(15) 0.70871(2) -0.131752(14) 0.03117(10) Uani 1 1 d .
Ag2 Ag 0.794718(16) 1.00057(2) 0.367701(14) 0.03586(11) Uani 1 1 d .
C18 C 0.62799(19) 1.0622(2) -0.08869(18) 0.0249(9) Uani 1 1 d .
H18A H 0.5853 1.0408 -0.1100 0.030 Uiso 1 1 calc R
C19 C 0.42269(19) 1.4000(2) 0.39269(18) 0.0243(9) Uani 1 1 d .
H19A H 0.4030 1.4043 0.3527 0.029 Uiso 1 1 calc R
C20 C 0.65417(18) 1.2191(2) 0.50159(17) 0.0190(8) Uani 1 1 d .
C23 C 0.62828(17) 1.0072(2) 0.00273(17) 0.0190(8) Uani 1 1 d .
C26 C 0.48185(18) 1.3869(2) 0.50967(18) 0.0262(9) Uani 1 1 d .
H26A H 0.5011 1.3839 0.5497 0.031 Uiso 1 1 calc R
C27 C 0.40318(18) 0.8164(2) -0.11073(18) 0.0255(9) Uani 1 1 d .
H27A H 0.3851 0.8105 -0.1506 0.031 Uiso 1 1 calc R
C30 C 0.74352(18) 1.1332(2) 0.49657(17) 0.0223(9) Uani 1 1 d .
H30A H 0.7641 1.1327 0.5367 0.027 Uiso 1 1 calc R
C31 C 0.57522(18) 1.3010(2) 0.50741(17) 0.0199(8) Uani 1 1 d .
C32 C 0.72338(18) 1.0867(3) 0.00010(18) 0.0272(10) Uani 1 1 d .
H32A H 0.7459 1.0825 0.0400 0.033 Uiso 1 1 calc R
C34 C 0.77208(19) 1.0923(2) 0.46552(18) 0.0252(9) Uani 1 1 d .
H34A H 0.8123 1.0648 0.4857 0.030 Uiso 1 1 calc R
C35 C 0.62797(18) 0.9767(2) 0.08817(17) 0.0214(9) Uani 1 1 d .
C36 C 0.66035(18) 1.0524(2) -0.02940(17) 0.0201(9) Uani 1 1 d .
C37 C 0.46102(18) 0.8612(2) -0.08406(17) 0.0227(9) Uani 1 1 d .
H37A H 0.4813 0.8842 -0.1057 0.027 Uiso 1 1 calc R
C38 C 0.7520(2) 1.1269(3) -0.03051(19) 0.0306(10) Uani 1 1 d .
H38A H 0.7944 1.1494 -0.0103 0.037 Uiso 1 1 calc R
C39 C 0.68396(17) 1.1750(2) 0.46714(16) 0.0189(8) Uani 1 1 d .
C40 C 0.65826(18) 0.9866(2) 0.15177(17) 0.0223(9) Uani 1 1 d .
C41 C 0.45707(18) 0.8341(2) 0.00551(17) 0.0214(9) Uani 1 1 d .
H41A H 0.4746 0.8381 0.0454 0.026 Uiso 1 1 calc R
C42 C 0.7798(2) 1.1986(3) 0.74071(19) 0.0343(11) Uani 1 1 d .
H42A H 0.8219 1.1746 0.7598 0.041 Uiso 1 1 calc R
C43 C 0.7123(2) 1.0384(3) 0.17844(18) 0.0311(10) Uani 1 1 d .
H43A H 0.7285 1.0689 0.1567 0.037 Uiso 1 1 calc R
C44 C 0.48227(18) 1.3578(2) 0.41911(17) 0.0219(9) Uani 1 1 d .
H44A H 0.5020 1.3348 0.3970 0.026 Uiso 1 1 calc R
C45 C 0.69074(19) 1.2427(3) 0.65224(17) 0.0250(9) Uani 1 1 d .
C46 C 0.66105(19) 1.1047(3) -0.11525(18) 0.0284(10) Uani 1 1 d .
H46A H 0.6389 1.1121 -0.1549 0.034 Uiso 1 1 calc R
C47 C 0.54988(18) 0.9227(2) 0.00579(17) 0.0193(8) Uani 1 1 d .
C48 C 0.7534(2) 1.2074(3) 0.68172(18) 0.0312(10) Uani 1 1 d .
H48A H 0.7775 1.1898 0.6617 0.037 Uiso 1 1 calc R
C49 C 0.6566(2) 1.2681(3) 0.68412(19) 0.0303(10) Uani 1 1 d .
H49A H 0.6144 1.2921 0.6661 0.036 Uiso 1 1 calc R
C50 C 0.6868(2) 1.2571(3) 0.74319(19) 0.0339(11) Uani 1 1 d .
H50A H 0.6637 1.2742 0.7641 0.041 Uiso 1 1 calc R
C51 C 0.7417(2) 1.0439(3) 0.23765(19) 0.0344(11) Uani 1 1 d .
H51A H 0.7775 1.0795 0.2551 0.041 Uiso 1 1 calc R
C52 C 0.39890(19) 0.7906(2) -0.02508(18) 0.0235(9) Uani 1 1 d .
H52A H 0.3776 0.7666 -0.0046 0.028 Uiso 1 1 calc R
C53 C 0.51252(18) 1.3499(2) 0.47817(17) 0.0211(9) Uani 1 1 d .
C54 C 0.65874(18) 1.2524(2) 0.58861(17) 0.0226(9) Uani 1 1 d .
C55 C 0.6556(2) 1.1746(3) 0.40785(18) 0.0271(9) Uani 1 1 d .
H55A H 0.6162 1.2031 0.3868 0.032 Uiso 1 1 calc R
C56 C 0.6335(2) 0.9445(3) 0.18542(18) 0.0304(10) Uani 1 1 d .
H56A H 0.5957 0.9117 0.1688 0.036 Uiso 1 1 calc R
C57 C 0.4221(2) 1.4283(3) 0.47993(19) 0.0285(10) Uani 1 1 d .
H57A H 0.4019 1.4528 0.5011 0.034 Uiso 1 1 calc R
C58 C 0.48923(17) 0.8720(2) -0.02469(17) 0.0191(8) Uani 1 1 d .
C59 C 0.6672(2) 0.9533(3) 0.2444(2) 0.0391(12) Uani 1 1 d .
H59A H 0.6511 0.9242 0.2669 0.047 Uiso 1 1 calc R
C60 C 0.6867(2) 1.1311(3) 0.38010(18) 0.0304(10) Uani 1 1 d .
H60A H 0.6665 1.1299 0.3400 0.036 Uiso 1 1 calc R
N1 N 0.37125(15) 0.78079(19) -0.08238(14) 0.0218(7) Uani 1 1 d .
N2 N 0.72237(16) 1.1356(2) -0.08782(15) 0.0252(8) Uani 1 1 d .
N3 N 0.72120(17) 1.0002(2) 0.27180(15) 0.0331(9) Uani 1 1 d .
N4 N 0.57468(15) 0.9610(2) -0.02700(14) 0.0207(7) Uani 1 1 d .
N5 N 0.65627(15) 1.0185(2) 0.05984(14) 0.0220(7) Uani 1 1 d .
N6 N 0.57488(15) 0.9275(2) 0.06315(14) 0.0219(7) Uani 1 1 d .
N7 N 0.74471(16) 1.0902(2) 0.40804(15) 0.0267(8) Uani 1 1 d .
N8 N 0.74701(17) 1.2233(2) 0.77197(15) 0.0309(9) Uani 1 1 d .
N9 N 0.39173(15) 1.4352(2) 0.42212(15) 0.0245(8) Uani 1 1 d .
N10 N 0.59751(15) 1.2602(2) 0.47349(14) 0.0214(7) Uani 1 1 d .
N11 N 0.68699(15) 1.21260(19) 0.55933(14) 0.0213(7) Uani 1 1 d .
N12 N 0.60405(16) 1.2993(2) 0.56481(14) 0.0247(8) Uani 1 1 d .
Mo1 Mo 0.0000 0.71338(4) -0.2500 0.04103(16) Uani 1 2 d S
Mo2 Mo 0.112037(16) 0.83872(2) -0.139639(15) 0.02227(10) Uani 1 1 d .
Mo3 Mo 0.117262(16) 1.04102(2) -0.143662(15) 0.02255(10) Uani 1 1 d .
Mo4 Mo 0.0000 1.15149(4) -0.2500 0.03176(14) Uani 1 2 d S
Mo5 Mo 0.050635(16) 0.94357(2) -0.291292(15) 0.02049(10) Uani 1 1 d .
O1 O -0.01738(19) 0.6515(3) -0.2053(2) 0.109(2) Uani 1 1 d .
O2 O 0.07886(14) 0.76483(18) -0.20661(13) 0.0336(7) Uani 1 1 d .
O3 O 0.11004(15) 0.7763(2) -0.08785(14) 0.0422(8) Uani 1 1 d .
O4 O 0.19354(14) 0.83352(19) -0.13027(14) 0.0384(8) Uani 1 1 d .
O5 O 0.10965(13) 0.94039(17) -0.10726(12) 0.0304(7) Uani 1 1 d .
O6 O 0.08928(16) 0.93571(18) -0.21440(13) 0.0388(8) Uani 1 1 d .
O7 O 0.10955(15) 0.94995(18) -0.31722(15) 0.0415(9) Uani 1 1 d .
O8 O 0.00306(14) 0.85547(19) -0.32157(14) 0.0406(8) Uani 1 1 d .
O9 O 0.20021(14) 1.0374(2) -0.12912(14) 0.0412(8) Uani 1 1 d .
O10 O 0.11462(14) 1.10640(19) -0.09421(13) 0.0408(8) Uani 1 1 d .
O11 O 0.08774(14) 1.10801(18) -0.21214(13) 0.0344(7) Uani 1 1 d .
O12 O -0.00101(13) 1.03250(18) -0.31390(13) 0.0331(7) Uani 1 1 d .
O13 O -0.00761(17) 1.2136(2) -0.20059(15) 0.0512(9) Uani 1 1 d .
O14 O -0.0808(5) 1.3629(6) -0.2326(4) 0.094(3) Uiso 0.50 1 d P
H14A H -0.0523 1.4004 -0.2272 0.142 Uiso 0.50 1 d PR
H14B H -0.0600 1.3180 -0.2234 0.142 Uiso 0.50 1 d PR
O15 O 0.0114(13) 1.4836(14) -0.2230(9) 0.133(9) Uiso 0.25 1 d P
H15A H -0.0015 1.5315 -0.2207 0.200 Uiso 0.25 1 d PR
H15B H -0.0208 1.4511 -0.2287 0.200 Uiso 0.25 1 d PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag1 N8 129.80(12) 3_445 3_444
N2 Ag1 N1 123.34(12) 3_445 .
N8 Ag1 N1 106.82(12) 3_444 .
N9 Ag2 N3 134.93(12) 3_545 .
N9 Ag2 N7 121.88(12) 3_545 .
N3 Ag2 N7 103.17(12) . .
C46 C18 C36 118.0(4) . .
N9 C19 C44 123.0(4) . .
N10 C20 N11 125.1(3) . .
N10 C20 C39 118.4(3) . .
N11 C20 C39 116.6(3) . .
N4 C23 N5 125.8(3) . .
N4 C23 C36 118.7(3) . .
N5 C23 C36 115.6(3) . .
C57 C26 C53 118.5(4) . .
N1 C27 C37 123.6(4) . .
C39 C30 C34 119.1(4) . .
N12 C31 N10 124.8(3) . .
N12 C31 C53 117.9(3) . .
N10 C31 C53 117.3(3) . .
C38 C32 C36 118.9(4) . .
N7 C34 C30 123.2(4) . .
N5 C35 N6 124.5(4) . .
N5 C35 C40 116.6(3) . .
N6 C35 C40 118.8(3) . .
C18 C36 C32 118.4(3) . .
C18 C36 C23 121.5(3) . .
C32 C36 C23 120.1(3) . .
C27 C37 C58 119.9(3) . .
N2 C38 C32 123.7(4) . .
C55 C39 C30 118.4(3) . .
C55 C39 C20 123.4(3) . .
C30 C39 C20 118.2(3) . .
C43 C40 C56 118.9(4) . .
C43 C40 C35 119.9(3) . .
C56 C40 C35 121.2(4) . .
C52 C41 C58 118.8(4) . .
N8 C42 C48 122.6(4) . .
C51 C43 C40 119.1(4) . .
C19 C44 C53 119.9(3) . .
C48 C45 C49 117.9(4) . .
C48 C45 C54 122.6(3) . .
C49 C45 C54 119.5(4) . .
N2 C46 C18 124.3(4) . .
N6 C47 N4 125.3(3) . .
N6 C47 C58 117.9(3) . .
N4 C47 C58 116.8(3) . .
C42 C48 C45 119.9(4) . .
C50 C49 C45 118.5(4) . .
N8 C50 C49 124.1(4) . .
N3 C51 C43 123.3(4) . .
N1 C52 C41 124.1(3) . .
C44 C53 C26 118.1(4) . .
C44 C53 C31 120.8(3) . .
C26 C53 C31 121.1(4) . .
N11 C54 N12 124.9(4) . .
N11 C54 C45 116.8(3) . .
N12 C54 C45 118.3(3) . .
C39 C55 C60 118.9(4) . .
C59 C56 C40 117.5(4) . .
N9 C57 C26 123.7(4) . .
C37 C58 C41 117.1(3) . .
C37 C58 C47 122.0(3) . .
C41 C58 C47 120.9(3) . .
N3 C59 C56 125.2(4) . .
N7 C60 C55 123.5(4) . .
C52 N1 C27 116.4(3) . .
C52 N1 Ag1 123.1(2) . .
C27 N1 Ag1 120.5(3) . .
C46 N2 C38 116.6(3) . .
C46 N2 Ag1 123.7(3) . 3
C38 N2 Ag1 119.6(3) . 3
C59 N3 C51 115.8(4) . .
C59 N3 Ag2 128.7(3) . .
C51 N3 Ag2 114.5(3) . .
C23 N4 C47 114.1(3) . .
C35 N5 C23 115.0(3) . .
C47 N6 C35 115.3(3) . .
C34 N7 C60 116.9(3) . .
C34 N7 Ag2 115.5(3) . .
C60 N7 Ag2 126.9(3) . .
C50 N8 C42 117.0(4) . .
C50 N8 Ag1 112.2(3) . 3_556
C42 N8 Ag1 130.6(3) . 3_556
C57 N9 C19 116.8(3) . .
C57 N9 Ag2 127.8(2) . 3_455
C19 N9 Ag2 115.5(3) . 3_455
C20 N10 C31 114.9(3) . .
C54 N11 C20 114.9(3) . .
C31 N12 C54 115.2(3) . .
O1 Mo1 O1 106.1(4) 2_554 .
O1 Mo1 O2 105.14(16) 2_554 .
O1 Mo1 O2 107.37(19) . .
O1 Mo1 O2 107.37(19) 2_554 2_554
O1 Mo1 O2 105.14(16) . 2_554
O2 Mo1 O2 124.48(19) . 2_554
O3 Mo2 O4 103.76(15) . .
O3 Mo2 O5 100.33(14) . .
O4 Mo2 O5 102.07(13) . .
O3 Mo2 O2 100.58(14) . .
O4 Mo2 O2 93.78(13) . .
O5 Mo2 O2 149.82(12) . .
O3 Mo2 O8 91.04(13) . 2_554
O4 Mo2 O8 163.77(13) . 2_554
O5 Mo2 O8 81.40(12) . 2_554
O2 Mo2 O8 76.72(11) . 2_554
O3 Mo2 O6 166.40(13) . .
O4 Mo2 O6 89.57(13) . .
O5 Mo2 O6 73.83(11) . .
O2 Mo2 O6 80.86(11) . .
O8 Mo2 O6 76.06(11) 2_554 .
O10 Mo3 O9 103.74(15) . .
O10 Mo3 O11 102.26(15) . .
O9 Mo3 O11 97.47(13) . .
O10 Mo3 O5 98.38(14) . .
O9 Mo3 O5 99.80(13) . .
O11 Mo3 O5 149.00(12) . .
O10 Mo3 O12 90.29(12) . 2_554
O9 Mo3 O12 165.20(13) . 2_554
O11 Mo3 O12 74.61(11) . 2_554
O5 Mo3 O12 82.47(11) . 2_554
O10 Mo3 O6 162.63(12) . .
O9 Mo3 O6 92.52(13) . .
O11 Mo3 O6 81.27(11) . .
O5 Mo3 O6 72.46(11) . .
O12 Mo3 O6 74.11(11) 2_554 .
O13 Mo4 O13 105.6(2) . 2_554
O13 Mo4 O11 101.93(14) . 2_554
O13 Mo4 O11 104.57(15) 2_554 2_554
O13 Mo4 O11 104.57(15) . .
O13 Mo4 O11 101.93(14) 2_554 .
O11 Mo4 O11 135.48(18) 2_554 .
O7 Mo5 O8 106.72(15) . .
O7 Mo5 O6 110.83(16) . .
O8 Mo5 O6 109.78(15) . .
O7 Mo5 O12 107.93(13) . .
O8 Mo5 O12 110.88(13) . .
O6 Mo5 O12 110.62(14) . .
Mo1 O2 Mo2 136.05(15) . .
Mo2 O5 Mo3 121.53(14) . .
Mo5 O6 Mo2 140.78(16) . .
Mo5 O6 Mo3 129.10(15) . .
Mo2 O6 Mo3 88.80(10) . .
Mo5 O8 Mo2 128.56(14) . 2_554
Mo4 O11 Mo3 123.61(13) . .
Mo5 O12 Mo3 128.42(15) . 2_554
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N2 2.262(3) 3_445
Ag1 N8 2.294(3) 3_444
Ag1 N1 2.298(3) .
Ag2 N9 2.263(3) 3_545
Ag2 N3 2.295(4) .
Ag2 N7 2.335(3) .
C18 C46 1.383(5) .
C18 C36 1.386(6) .
C19 N9 1.347(5) .
C19 C44 1.379(5) .
C20 N10 1.329(5) .
C20 N11 1.347(5) .
C20 C39 1.496(5) .
C23 N4 1.336(5) .
C23 N5 1.338(5) .
C23 C36 1.494(5) .
C26 C57 1.385(5) .
C26 C53 1.397(5) .
C27 N1 1.345(5) .
C27 C37 1.374(5) .
C30 C39 1.385(5) .
C30 C34 1.385(5) .
C31 N12 1.332(5) .
C31 N10 1.348(5) .
C31 C53 1.494(5) .
C32 C38 1.371(5) .
C32 C36 1.385(5) .
C34 N7 1.334(5) .
C35 N5 1.334(5) .
C35 N6 1.340(5) .
C35 C40 1.485(5) .
C37 C58 1.389(5) .
C38 N2 1.337(5) .
C39 C55 1.376(5) .
C40 C43 1.383(6) .
C40 C56 1.389(5) .
C41 C52 1.382(5) .
C41 C58 1.401(5) .
C42 N8 1.353(5) .
C42 C48 1.378(6) .
C43 C51 1.377(6) .
C44 C53 1.376(5) .
C45 C48 1.385(6) .
C45 C49 1.393(5) .
C45 C54 1.485(5) .
C46 N2 1.328(5) .
C47 N6 1.335(5) .
C47 N4 1.342(5) .
C47 C58 1.484(5) .
C49 C50 1.382(6) .
C50 N8 1.331(5) .
C51 N3 1.355(5) .
C52 N1 1.339(5) .
C54 N11 1.336(5) .
C54 N12 1.338(5) .
C55 C60 1.381(5) .
C56 C59 1.378(6) .
C57 N9 1.346(5) .
C59 N3 1.338(6) .
C60 N7 1.348(5) .
N2 Ag1 2.262(3) 3
N8 Ag1 2.294(3) 3_556
N9 Ag2 2.263(3) 3_455
Mo1 O1 1.698(4) 2_554
Mo1 O1 1.698(4) .
Mo1 O2 1.822(3) .
Mo1 O2 1.822(3) 2_554
Mo2 O3 1.697(3) .
Mo2 O4 1.708(3) .
Mo2 O5 1.882(3) .
Mo2 O2 1.974(3) .
Mo2 O8 2.309(3) 2_554
Mo2 O6 2.381(3) .
Mo3 O10 1.686(3) .
Mo3 O9 1.702(3) .
Mo3 O11 1.938(3) .
Mo3 O5 1.947(3) .
Mo3 O12 2.318(3) 2_554
Mo3 O6 2.395(3) .
Mo4 O13 1.694(3) .
Mo4 O13 1.694(3) 2_554
Mo4 O11 1.893(3) 2_554
Mo4 O11 1.893(3) .
Mo5 O7 1.697(3) .
Mo5 O8 1.765(3) .
Mo5 O6 1.788(3) .
Mo5 O12 1.793(3) .
O8 Mo2 2.309(3) 2_554
O12 Mo3 2.318(3) 2_554
O15 O15 1.26(4) 2_554
