#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/97/7029794.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7029794
loop_
_publ_author_name
'Zhang, Lei'
'Kuang, Xiaofei'
'Wu, Xiaoyuan'
'Yang, Wenbin'
'Lu, Canzhong'
_publ_section_title
;
 Supramolecular interactions induced hinge-like motion of a metal-organic
 framework accompanied by anisotropic thermal expansion.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7146
_journal_page_last               7152
_journal_paper_doi               10.1039/c3dt53580k
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C72 H51 Ag4 Mo8 N24 O27.5'
_chemical_formula_weight         2891.37
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 115.386(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   22.0121(6)
_cell_length_b                   16.5301(6)
_cell_length_c                   25.6641(9)
_cell_measurement_reflns_used    17083
_cell_measurement_temperature    280.00(10)
_cell_measurement_theta_max      28.9940
_cell_measurement_theta_min      3.3140
_cell_volume                     8436.5(6)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      280.00(10)
_diffrn_detector_area_resol_mean 10.3503
_diffrn_measured_fraction_theta_full 0.971
_diffrn_measured_fraction_theta_max 0.971
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0338
_diffrn_reflns_av_sigmaI/netI    0.0433
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            19597
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.07
_exptl_absorpt_coefficient_mu    2.146
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.75338
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            kermesinus
_exptl_crystal_density_diffrn    2.276
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block-like
_exptl_crystal_F_000             5580
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.277
_refine_diff_density_min         -1.196
_refine_diff_density_rms         0.109
_refine_ls_extinction_coef       0.000035(11)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.111
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     621
_refine_ls_number_reflns         7230
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.111
_refine_ls_R_factor_all          0.0372
_refine_ls_R_factor_gt           0.0309
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0316P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0732
_refine_ls_wR_factor_ref         0.0782
_reflns_number_gt                6321
_reflns_number_total             7230
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt53580k2.cif
_cod_data_source_block           A_280K
_cod_depositor_comments
;Adding full bibliography for
 ./tmp-cod-update-bibliographies-12899/cifs/7029794.cif.
;
_cod_original_cell_volume        8436.5(5)
_cod_original_sg_symbol_H-M      C2/c
_cod_original_formula_sum        'C72 H51 Ag4 Mo8 N24 O27.50'
_cod_database_code               7029794
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag -0.226084(16) 0.70883(2) -0.631747(15) 0.03475(11) Uani 1 1 d .
Ag2 Ag 0.294821(17) 1.00096(2) -0.132307(15) 0.03984(12) Uani 1 1 d .
C16 C -0.07686(19) 1.4005(3) -0.10736(19) 0.0266(10) Uani 1 1 d .
H16A H -0.0962 1.4056 -0.1473 0.032 Uiso 1 1 calc R
C19 C 0.1280(2) 1.0618(3) -0.58873(19) 0.0288(10) Uani 1 1 d .
H19A H 0.0856 1.0398 -0.6100 0.035 Uiso 1 1 calc R
C21 C 0.15399(18) 1.2193(2) 0.00136(18) 0.0206(9) Uani 1 1 d .
C22 C 0.12825(18) 1.0072(2) -0.49744(18) 0.0205(9) Uani 1 1 d .
C25 C -0.0968(2) 0.8167(3) -0.61092(19) 0.0282(10) Uani 1 1 d .
H25A H -0.1149 0.8106 -0.6508 0.034 Uiso 1 1 calc R
C27 C -0.0184(2) 1.3872(3) 0.00948(19) 0.0303(10) Uani 1 1 d .
H27A H 0.0007 1.3842 0.0495 0.036 Uiso 1 1 calc R
C29 C 0.07521(19) 1.3008(2) 0.00726(18) 0.0222(9) Uani 1 1 d .
C31 C 0.15995(19) 1.0526(2) -0.52958(18) 0.0226(9) Uani 1 1 d .
C32 C 0.24355(19) 1.1335(3) -0.00322(18) 0.0261(9) Uani 1 1 d .
H32A H 0.2642 1.1332 0.0369 0.031 Uiso 1 1 calc R
C33 C 0.2233(2) 1.0863(3) -0.50016(19) 0.0287(10) Uani 1 1 d .
H33A H 0.2461 1.0817 -0.4603 0.034 Uiso 1 1 calc R
C35 C 0.15821(19) 0.9867(3) -0.34837(18) 0.0242(9) Uani 1 1 d .
C36 C -0.0391(2) 0.8616(3) -0.58412(18) 0.0260(9) Uani 1 1 d .
H36A H -0.0190 0.8851 -0.6058 0.031 Uiso 1 1 calc R
C37 C 0.12806(18) 0.9763(2) -0.41174(17) 0.0216(9) Uani 1 1 d .
C38 C 0.2719(2) 1.0926(3) -0.03433(19) 0.0282(10) Uani 1 1 d .
H38A H 0.3121 1.0651 -0.0141 0.034 Uiso 1 1 calc R
C39 C 0.2520(2) 1.1264(3) -0.5305(2) 0.0347(11) Uani 1 1 d .
H39A H 0.2945 1.1487 -0.5102 0.042 Uiso 1 1 calc R
C40 C 0.05010(19) 0.9227(2) -0.49413(18) 0.0211(9) Uani 1 1 d .
C41 C 0.2796(2) 1.1983(3) 0.2406(2) 0.0390(12) Uani 1 1 d .
H41A H 0.3216 1.1743 0.2597 0.047 Uiso 1 1 calc R
C42 C 0.18403(19) 1.1749(2) -0.03273(17) 0.0211(9) Uani 1 1 d .
C43 C 0.1904(2) 1.2426(3) 0.15193(18) 0.0281(10) Uani 1 1 d .
C44 C -0.01794(19) 1.3582(2) -0.08116(18) 0.0243(9) Uani 1 1 d .
H44A H 0.0015 1.3349 -0.1033 0.029 Uiso 1 1 calc R
C45 C 0.15897(19) 1.2525(2) 0.08851(18) 0.0231(9) Uani 1 1 d .
C46 C 0.1607(2) 1.1048(3) -0.61567(19) 0.0319(11) Uani 1 1 d .
H46A H 0.1383 1.1127 -0.6553 0.038 Uiso 1 1 calc R
C47 C 0.1867(2) 1.2573(3) 0.2428(2) 0.0383(12) Uani 1 1 d .
H47A H 0.1637 1.2748 0.2638 0.046 Uiso 1 1 calc R
C48 C -0.04290(19) 0.8339(2) -0.49464(18) 0.0233(9) Uani 1 1 d .
H48A H -0.0253 0.8378 -0.4547 0.028 Uiso 1 1 calc R
C49 C 0.2529(2) 1.2072(3) 0.18124(19) 0.0343(11) Uani 1 1 d .
H49A H 0.2769 1.1894 0.1612 0.041 Uiso 1 1 calc R
C50 C 0.2121(2) 1.0379(3) -0.3216(2) 0.0345(11) Uani 1 1 d .
H50A H 0.2284 1.0683 -0.3434 0.041 Uiso 1 1 calc R
C51 C 0.01259(19) 1.3501(2) -0.02197(18) 0.0216(9) Uani 1 1 d .
C52 C 0.2417(2) 1.0437(3) -0.2624(2) 0.0382(12) Uani 1 1 d .
H52A H 0.2775 1.0793 -0.2451 0.046 Uiso 1 1 calc R
C53 C 0.1565(2) 1.2683(3) 0.1841(2) 0.0344(11) Uani 1 1 d .
H53A H 0.1143 1.2923 0.1662 0.041 Uiso 1 1 calc R
C54 C -0.1010(2) 0.7907(2) -0.52529(19) 0.0254(9) Uani 1 1 d .
H54A H -0.1224 0.7669 -0.5048 0.030 Uiso 1 1 calc R
C55 C -0.0779(2) 1.4284(3) -0.0203(2) 0.0318(11) Uani 1 1 d .
H55A H -0.0981 1.4529 0.0009 0.038 Uiso 1 1 calc R
C56 C 0.1337(2) 0.9450(3) -0.3145(2) 0.0348(11) Uani 1 1 d .
H56A H 0.0959 0.9121 -0.3311 0.042 Uiso 1 1 calc R
C57 C -0.01086(19) 0.8720(2) -0.52517(18) 0.0228(9) Uani 1 1 d .
C58 C 0.1553(2) 1.1746(3) -0.09224(19) 0.0283(10) Uani 1 1 d .
H58A H 0.1159 1.2031 -0.1132 0.034 Uiso 1 1 calc R
C59 C 0.1668(2) 0.9535(3) -0.2558(2) 0.0415(12) Uani 1 1 d .
H59A H 0.1504 0.9248 -0.2334 0.050 Uiso 1 1 calc R
C60 C 0.1864(2) 1.1310(3) -0.12001(19) 0.0327(10) Uani 1 1 d .
H60A H 0.1659 1.1296 -0.1601 0.039 Uiso 1 1 calc R
N1 N -0.12859(16) 0.7809(2) -0.58231(15) 0.0243(8) Uani 1 1 d .
N2 N 0.22223(16) 1.1354(2) -0.58802(16) 0.0286(8) Uani 1 1 d .
N3 N 0.22110(19) 1.0002(2) -0.22825(16) 0.0363(9) Uani 1 1 d .
N4 N 0.07457(16) 0.9608(2) -0.52723(15) 0.0236(8) Uani 1 1 d .
N5 N 0.15590(16) 1.0184(2) -0.44058(15) 0.0246(8) Uani 1 1 d .
N6 N 0.07492(16) 0.9276(2) -0.43688(15) 0.0237(8) Uani 1 1 d .
N7 N 0.24452(17) 1.0905(2) -0.09229(16) 0.0288(8) Uani 1 1 d .
N8 N 0.24695(19) 1.2232(2) 0.27181(16) 0.0368(10) Uani 1 1 d .
N9 N -0.10831(16) 1.4354(2) -0.07793(16) 0.0275(8) Uani 1 1 d .
N10 N 0.09757(16) 1.2605(2) -0.02662(15) 0.0237(8) Uani 1 1 d .
N11 N 0.18686(16) 1.2127(2) 0.05897(15) 0.0245(8) Uani 1 1 d .
N12 N 0.10392(16) 1.2990(2) 0.06458(15) 0.0275(8) Uani 1 1 d .
Mo1 Mo -0.5000 0.71396(4) -0.7500 0.04447(18) Uani 1 2 d S
Mo2 Mo -0.388005(17) 0.83898(2) -0.639608(15) 0.02439(11) Uani 1 1 d .
Mo3 Mo -0.382905(17) 1.04087(2) -0.643557(16) 0.02496(11) Uani 1 1 d .
Mo4 Mo -0.5000 1.15172(4) -0.7500 0.03510(15) Uani 1 2 d S
Mo5 Mo -0.449209(17) 0.94361(2) -0.791227(16) 0.02266(11) Uani 1 1 d .
O1 O -0.5176(2) 0.6523(3) -0.7052(3) 0.119(2) Uani 1 1 d .
O2 O -0.42149(15) 0.76527(19) -0.70668(14) 0.0380(8) Uani 1 1 d .
O3 O -0.39009(17) 0.7767(2) -0.58779(15) 0.0486(9) Uani 1 1 d .
O4 O -0.30670(15) 0.8335(2) -0.63042(15) 0.0437(9) Uani 1 1 d .
O5 O -0.39030(14) 0.94029(19) -0.60713(13) 0.0352(8) Uani 1 1 d .
O6 O -0.41101(18) 0.93566(19) -0.71455(14) 0.0438(8) Uani 1 1 d .
O7 O -0.49707(15) 0.8555(2) -0.82179(16) 0.0461(9) Uani 1 1 d .
O8 O -0.39043(16) 0.9497(2) -0.81725(16) 0.0456(9) Uani 1 1 d .
O9 O -0.30004(16) 1.0376(2) -0.62938(16) 0.0470(9) Uani 1 1 d .
O10 O -0.38546(15) 1.1059(2) -0.59404(15) 0.0470(9) Uani 1 1 d .
O11 O -0.41240(14) 1.10795(19) -0.71207(14) 0.0378(8) Uani 1 1 d .
O12 O -0.50101(14) 1.03231(19) -0.81420(14) 0.0365(8) Uani 1 1 d .
O13 O -0.50787(19) 1.2138(2) -0.70064(16) 0.0566(10) Uani 1 1 d .
O14 O -0.5794(6) 1.3636(7) -0.7322(4) 0.117(4) Uani 0.50 1 d P
H14A H -0.5509 1.4002 -0.7292 0.175 Uiso 0.50 1 d PR
H14B H -0.5588 1.3186 -0.7229 0.175 Uiso 0.50 1 d PR
O15 O -0.4861(14) 1.4828(15) -0.7216(10) 0.132(9) Uiso 0.25 1 d P
H15A H -0.4985 1.5298 -0.7167 0.198 Uiso 0.25 1 d PR
H15B H -0.5166 1.4492 -0.7244 0.198 Uiso 0.25 1 d PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag1 N8 129.59(13) 3_445 3_444
N2 Ag1 N1 123.52(13) 3_445 .
N8 Ag1 N1 106.83(13) 3_444 .
N9 Ag2 N3 134.82(13) 3_545 .
N9 Ag2 N7 122.14(13) 3_545 .
N3 Ag2 N7 103.00(13) . .
N9 C16 C44 123.2(4) . .
C31 C19 C46 118.4(4) . .
N10 C21 N11 125.2(4) . .
N10 C21 C42 118.8(4) . .
N11 C21 C42 116.0(3) . .
N5 C22 N4 125.6(3) . .
N5 C22 C31 115.8(3) . .
N4 C22 C31 118.7(4) . .
N1 C25 C36 123.3(4) . .
C55 C27 C51 118.5(4) . .
N12 C29 N10 124.9(4) . .
N12 C29 C51 117.8(3) . .
N10 C29 C51 117.4(4) . .
C19 C31 C33 118.2(4) . .
C19 C31 C22 121.7(4) . .
C33 C31 C22 120.1(4) . .
C42 C32 C38 118.8(4) . .
C39 C33 C31 119.1(4) . .
C50 C35 C56 118.5(4) . .
C50 C35 C37 120.2(4) . .
C56 C35 C37 121.3(4) . .
C25 C36 C57 120.1(4) . .
N6 C37 N5 124.0(4) . .
N6 C37 C35 119.2(3) . .
N5 C37 C35 116.8(4) . .
N7 C38 C32 123.5(4) . .
N2 C39 C33 123.7(4) . .
N6 C40 N4 125.7(4) . .
N6 C40 C57 118.2(3) . .
N4 C40 C57 116.1(4) . .
N8 C41 C49 122.5(4) . .
C32 C42 C58 118.8(4) . .
C32 C42 C21 118.4(4) . .
C58 C42 C21 122.8(4) . .
C49 C43 C53 117.8(4) . .
C49 C43 C45 122.1(4) . .
C53 C43 C45 120.1(4) . .
C16 C44 C51 120.1(4) . .
N11 C45 N12 124.6(4) . .
N11 C45 C43 117.3(4) . .
N12 C45 C43 118.1(4) . .
N2 C46 C19 123.7(4) . .
N8 C47 C53 124.4(4) . .
C54 C48 C57 118.5(4) . .
C43 C49 C41 119.8(4) . .
C35 C50 C52 119.4(4) . .
C44 C51 C27 117.7(4) . .
C44 C51 C29 120.9(3) . .
C27 C51 C29 121.4(4) . .
N3 C52 C50 123.1(4) . .
C47 C53 C43 118.6(4) . .
N1 C54 C48 124.4(4) . .
N9 C55 C27 124.0(4) . .
C59 C56 C35 118.1(4) . .
C36 C57 C48 117.2(4) . .
C36 C57 C40 122.4(3) . .
C48 C57 C40 120.3(4) . .
C60 C58 C42 118.6(4) . .
N3 C59 C56 125.0(4) . .
N7 C60 C58 123.7(4) . .
C54 N1 C25 116.5(4) . .
C54 N1 Ag1 123.2(3) . .
C25 N1 Ag1 120.4(3) . .
C46 N2 C39 116.7(3) . .
C46 N2 Ag1 123.5(3) . 3
C39 N2 Ag1 119.5(3) . 3
C59 N3 C52 115.7(4) . .
C59 N3 Ag2 129.0(3) . .
C52 N3 Ag2 114.4(3) . .
C40 N4 C22 113.7(3) . .
C22 N5 C37 115.5(3) . .
C37 N6 C40 115.4(3) . .
C38 N7 C60 116.5(3) . .
C38 N7 Ag2 115.5(3) . .
C60 N7 Ag2 127.3(3) . .
C47 N8 C41 116.9(4) . .
C47 N8 Ag1 112.4(3) . 3_556
C41 N8 Ag1 130.6(3) . 3_556
C55 N9 C16 116.5(4) . .
C55 N9 Ag2 127.9(3) . 3_455
C16 N9 Ag2 115.6(3) . 3_455
C21 N10 C29 115.0(4) . .
C45 N11 C21 115.0(3) . .
C29 N12 C45 115.3(3) . .
O1 Mo1 O1 106.4(5) . 2_453
O1 Mo1 O2 107.4(2) . .
O1 Mo1 O2 105.11(18) 2_453 .
O1 Mo1 O2 105.11(18) . 2_453
O1 Mo1 O2 107.4(2) 2_453 2_453
O2 Mo1 O2 124.3(2) . 2_453
O3 Mo2 O4 103.80(16) . .
O3 Mo2 O5 100.27(15) . .
O4 Mo2 O5 102.25(15) . .
O3 Mo2 O2 100.55(16) . .
O4 Mo2 O2 93.73(14) . .
O5 Mo2 O2 149.80(14) . .
O3 Mo2 O7 90.88(14) . 2_453
O4 Mo2 O7 163.78(14) . 2_453
O5 Mo2 O7 81.49(13) . 2_453
O2 Mo2 O7 76.56(13) . 2_453
O3 Mo2 O6 166.27(14) . .
O4 Mo2 O6 89.69(15) . .
O5 Mo2 O6 73.95(12) . .
O2 Mo2 O6 80.76(12) . .
O7 Mo2 O6 76.06(12) 2_453 .
O10 Mo3 O9 103.81(16) . .
O10 Mo3 O11 102.28(16) . .
O9 Mo3 O11 97.11(15) . .
O10 Mo3 O5 98.39(15) . .
O9 Mo3 O5 99.93(15) . .
O11 Mo3 O5 149.13(13) . .
O10 Mo3 O12 90.30(13) . 2_453
O9 Mo3 O12 165.06(15) . 2_453
O11 Mo3 O12 74.75(12) . 2_453
O5 Mo3 O12 82.53(12) . 2_453
O10 Mo3 O6 162.63(14) . .
O9 Mo3 O6 92.46(15) . .
O11 Mo3 O6 81.32(12) . .
O5 Mo3 O6 72.45(12) . .
O12 Mo3 O6 74.12(12) 2_453 .
O13 Mo4 O13 105.6(3) . 2_453
O13 Mo4 O11 101.98(15) . 2_453
O13 Mo4 O11 104.77(16) 2_453 2_453
O13 Mo4 O11 104.77(16) . .
O13 Mo4 O11 101.98(15) 2_453 .
O11 Mo4 O11 135.03(19) 2_453 .
O8 Mo5 O7 106.50(16) . .
O8 Mo5 O6 111.16(17) . .
O7 Mo5 O6 109.73(16) . .
O8 Mo5 O12 107.87(14) . .
O7 Mo5 O12 110.66(15) . .
O6 Mo5 O12 110.81(15) . .
Mo1 O2 Mo2 136.34(16) . .
Mo2 O5 Mo3 121.58(15) . .
Mo5 O6 Mo2 141.00(17) . .
Mo5 O6 Mo3 129.10(16) . .
Mo2 O6 Mo3 88.67(11) . .
Mo5 O7 Mo2 128.52(16) . 2_453
Mo4 O11 Mo3 123.79(14) . .
Mo5 O12 Mo3 128.50(16) . 2_453
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N2 2.263(3) 3_445
Ag1 N8 2.297(4) 3_444
Ag1 N1 2.302(3) .
Ag2 N9 2.262(3) 3_545
Ag2 N3 2.296(4) .
Ag2 N7 2.334(3) .
C16 N9 1.353(5) .
C16 C44 1.370(6) .
C19 C31 1.381(6) .
C19 C46 1.388(6) .
C21 N10 1.325(5) .
C21 N11 1.343(5) .
C21 C42 1.496(5) .
C22 N5 1.331(5) .
C22 N4 1.340(5) .
C22 C31 1.491(5) .
C25 N1 1.348(5) .
C25 C36 1.376(6) .
C27 C55 1.379(6) .
C27 C51 1.402(5) .
C29 N12 1.329(5) .
C29 N10 1.345(5) .
C29 C51 1.497(5) .
C31 C33 1.388(6) .
C32 C42 1.381(5) .
C32 C38 1.383(5) .
C33 C39 1.365(6) .
C35 C50 1.378(6) .
C35 C56 1.387(6) .
C35 C37 1.480(6) .
C36 C57 1.378(6) .
C37 N6 1.336(5) .
C37 N5 1.340(5) .
C38 N7 1.345(5) .
C39 N2 1.342(6) .
C40 N6 1.332(5) .
C40 N4 1.342(5) .
C40 C57 1.490(6) .
C41 N8 1.348(5) .
C41 C49 1.386(6) .
C42 C58 1.380(6) .
C43 C49 1.383(6) .
C43 C53 1.395(6) .
C43 C45 1.480(6) .
C44 C51 1.379(6) .
C45 N11 1.336(5) .
C45 N12 1.341(5) .
C46 N2 1.330(5) .
C47 N8 1.335(6) .
C47 C53 1.373(7) .
C48 C54 1.379(6) .
C48 C57 1.408(5) .
C50 C52 1.376(6) .
C52 N3 1.354(6) .
C54 N1 1.332(5) .
C55 N9 1.343(6) .
C56 C59 1.370(7) .
C58 C60 1.383(6) .
C59 N3 1.341(6) .
C60 N7 1.347(5) .
N2 Ag1 2.263(3) 3
N8 Ag1 2.297(4) 3_556
N9 Ag2 2.262(3) 3_455
Mo1 O1 1.702(5) .
Mo1 O1 1.702(5) 2_453
Mo1 O2 1.815(3) .
Mo1 O2 1.815(3) 2_453
Mo2 O3 1.698(3) .
Mo2 O4 1.704(3) .
Mo2 O5 1.881(3) .
Mo2 O2 1.976(3) .
Mo2 O7 2.304(3) 2_453
Mo2 O6 2.382(3) .
Mo3 O10 1.684(3) .
Mo3 O9 1.701(3) .
Mo3 O11 1.940(3) .
Mo3 O5 1.948(3) .
Mo3 O12 2.313(3) 2_453
Mo3 O6 2.400(3) .
Mo4 O13 1.696(4) .
Mo4 O13 1.696(4) 2_453
Mo4 O11 1.892(3) 2_453
Mo4 O11 1.892(3) .
Mo5 O8 1.694(3) .
Mo5 O7 1.772(3) .
Mo5 O6 1.783(3) .
Mo5 O12 1.795(3) .
O7 Mo2 2.304(3) 2_453
O12 Mo3 2.313(3) 2_453
O15 O15 1.32(4) 2_453
