#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/97/7029795.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7029795
loop_
_publ_author_name
'Zhang, Lei'
'Kuang, Xiaofei'
'Wu, Xiaoyuan'
'Yang, Wenbin'
'Lu, Canzhong'
_publ_section_title
;
 Supramolecular interactions induced hinge-like motion of a metal-organic
 framework accompanied by anisotropic thermal expansion.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7146
_journal_page_last               7152
_journal_paper_doi               10.1039/c3dt53580k
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C72 H51 Ag4 Mo8 N24 O27.5'
_chemical_formula_weight         2891.37
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 115.366(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   21.9848(6)
_cell_length_b                   16.5617(6)
_cell_length_c                   25.6443(9)
_cell_measurement_reflns_used    16419
_cell_measurement_temperature    310.00(10)
_cell_measurement_theta_max      29.3900
_cell_measurement_theta_min      3.3190
_cell_volume                     8437.0(6)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      310.00(10)
_diffrn_detector_area_resol_mean 10.3503
_diffrn_measured_fraction_theta_full 0.971
_diffrn_measured_fraction_theta_max 0.971
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0354
_diffrn_reflns_av_sigmaI/netI    0.0439
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            19614
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.07
_exptl_absorpt_coefficient_mu    2.146
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.77945
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            kermesinus
_exptl_crystal_density_diffrn    2.276
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block-like
_exptl_crystal_F_000             5580
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.230
_refine_diff_density_min         -1.315
_refine_diff_density_rms         0.115
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.104
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     613
_refine_ls_number_reflns         7228
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.104
_refine_ls_R_factor_all          0.0406
_refine_ls_R_factor_gt           0.0336
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0361P)²+5.0566P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0803
_refine_ls_wR_factor_ref         0.0867
_reflns_number_gt                6237
_reflns_number_total             7228
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt53580k2.cif
_cod_data_source_block           A_310K
_cod_depositor_comments
;Adding full bibliography for
 ./tmp-cod-update-bibliographies-12899/cifs/7029795.cif.
;
_cod_original_cell_volume        8437.0(5)
_cod_original_sg_symbol_H-M      C2/c
_cod_original_formula_sum        'C72 H51 Ag4 Mo8 N24 O27.50'
_cod_database_code               7029795
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.273896(18) 0.20897(3) -0.131754(16) 0.03893(12) Uani 1 1 d .
Ag2 Ag 0.794995(19) 0.50132(3) 0.367687(17) 0.04467(13) Uani 1 1 d .
C6 C 0.6278(2) 0.4760(3) 0.08782(19) 0.0239(9) Uani 1 1 d .
C17 C 0.4227(2) 0.9004(3) 0.3926(2) 0.0302(10) Uani 1 1 d .
H17A H 0.4029 0.9050 0.3526 0.036 Uiso 1 1 calc R
C18 C 0.6538(2) 0.7197(3) 0.50129(19) 0.0239(9) Uani 1 1 d .
C19 C 0.6280(2) 0.5616(3) -0.0887(2) 0.0313(11) Uani 1 1 d .
H19A H 0.5855 0.5398 -0.1100 0.038 Uiso 1 1 calc R
C21 C 0.6280(2) 0.5070(3) 0.00244(19) 0.0227(9) Uani 1 1 d .
C24 C 0.4821(2) 0.8872(3) 0.5094(2) 0.0325(11) Uani 1 1 d .
H24A H 0.5014 0.8842 0.5495 0.039 Uiso 1 1 calc R
C25 C 0.4031(2) 0.3169(3) -0.1108(2) 0.0321(11) Uani 1 1 d .
H25A H 0.3846 0.3113 -0.1507 0.039 Uiso 1 1 calc R
C28 C 0.7434(2) 0.6335(3) 0.49629(19) 0.0283(10) Uani 1 1 d .
H28A H 0.7639 0.6330 0.5364 0.034 Uiso 1 1 calc R
C31 C 0.5753(2) 0.8007(3) 0.5072(2) 0.0255(10) Uani 1 1 d .
C33 C 0.6599(2) 0.5523(3) -0.02968(19) 0.0227(9) Uani 1 1 d .
C34 C 0.7229(2) 0.5865(3) -0.0006(2) 0.0323(11) Uani 1 1 d .
H34A H 0.7455 0.5821 0.0394 0.039 Uiso 1 1 calc R
C35 C 0.7719(2) 0.5927(3) 0.4656(2) 0.0308(11) Uani 1 1 d .
H35A H 0.8122 0.5654 0.4858 0.037 Uiso 1 1 calc R
C37 C 0.7517(2) 0.6266(3) -0.0308(2) 0.0370(12) Uani 1 1 d .
H37A H 0.7942 0.6490 -0.0104 0.044 Uiso 1 1 calc R
C38 C 0.4573(2) 0.3341(3) 0.0056(2) 0.0275(10) Uani 1 1 d .
H38A H 0.4750 0.3380 0.0456 0.033 Uiso 1 1 calc R
C39 C 0.6583(2) 0.4862(3) 0.1518(2) 0.0275(10) Uani 1 1 d .
C40 C 0.4609(2) 0.3610(3) -0.0844(2) 0.0297(10) Uani 1 1 d .
H40A H 0.4813 0.3836 -0.1061 0.036 Uiso 1 1 calc R
C41 C 0.6837(2) 0.6751(3) 0.46686(18) 0.0221(9) Uani 1 1 d .
C42 C 0.6902(2) 0.7426(3) 0.6519(2) 0.0303(11) Uani 1 1 d .
C43 C 0.4823(2) 0.8576(3) 0.41865(19) 0.0261(10) Uani 1 1 d .
H43A H 0.5016 0.8341 0.3964 0.031 Uiso 1 1 calc R
C44 C 0.5498(2) 0.4228(3) 0.00565(19) 0.0234(9) Uani 1 1 d .
C45 C 0.7793(3) 0.6987(3) 0.7403(2) 0.0432(13) Uani 1 1 d .
H45A H 0.8215 0.6750 0.7594 0.052 Uiso 1 1 calc R
C46 C 0.7527(2) 0.7070(3) 0.6811(2) 0.0390(12) Uani 1 1 d .
H46A H 0.7767 0.6889 0.6610 0.047 Uiso 1 1 calc R
C47 C 0.6610(2) 0.6042(3) -0.1156(2) 0.0355(11) Uani 1 1 d .
H47A H 0.6388 0.6112 -0.1554 0.043 Uiso 1 1 calc R
C48 C 0.6565(3) 0.7680(3) 0.6841(2) 0.0381(12) Uani 1 1 d .
H48A H 0.6142 0.7918 0.6662 0.046 Uiso 1 1 calc R
C49 C 0.7122(2) 0.5380(3) 0.1783(2) 0.0376(12) Uani 1 1 d .
H49A H 0.7284 0.5686 0.1566 0.045 Uiso 1 1 calc R
C50 C 0.6869(3) 0.7573(3) 0.7429(2) 0.0428(13) Uani 1 1 d .
H50A H 0.6640 0.7750 0.7640 0.051 Uiso 1 1 calc R
C51 C 0.3989(2) 0.2906(3) -0.0253(2) 0.0275(10) Uani 1 1 d .
H51A H 0.3776 0.2664 -0.0049 0.033 Uiso 1 1 calc R
C52 C 0.6583(2) 0.7522(3) 0.5879(2) 0.0272(10) Uani 1 1 d .
C53 C 0.7414(3) 0.5434(3) 0.2377(2) 0.0420(13) Uani 1 1 d .
H53A H 0.7773 0.5788 0.2553 0.050 Uiso 1 1 calc R
C54 C 0.5127(2) 0.8502(3) 0.47797(19) 0.0249(10) Uani 1 1 d .
C55 C 0.6556(2) 0.6746(3) 0.4075(2) 0.0319(11) Uani 1 1 d .
H55A H 0.6163 0.7033 0.3864 0.038 Uiso 1 1 calc R
C56 C 0.4891(2) 0.3720(3) -0.02489(19) 0.0241(10) Uani 1 1 d .
C57 C 0.6335(3) 0.4450(3) 0.1853(2) 0.0375(12) Uani 1 1 d .
H57A H 0.5953 0.4127 0.1687 0.045 Uiso 1 1 calc R
C58 C 0.4223(2) 0.9286(3) 0.4797(2) 0.0341(11) Uani 1 1 d .
H58A H 0.4021 0.9530 0.5010 0.041 Uiso 1 1 calc R
C59 C 0.6675(3) 0.4535(4) 0.2445(2) 0.0485(14) Uani 1 1 d .
H59A H 0.6518 0.4243 0.2671 0.058 Uiso 1 1 calc R
C60 C 0.6864(2) 0.6312(3) 0.3799(2) 0.0376(12) Uani 1 1 d .
H60A H 0.6660 0.6299 0.3398 0.045 Uiso 1 1 calc R
N1 N 0.37154(17) 0.2813(2) -0.08233(17) 0.0280(9) Uani 1 1 d .
N2 N 0.72209(18) 0.6356(2) -0.08816(17) 0.0314(9) Uani 1 1 d .
N3 N 0.7209(2) 0.5003(3) 0.27143(18) 0.0405(11) Uani 1 1 d .
N4 N 0.57474(17) 0.4610(2) -0.02712(16) 0.0258(8) Uani 1 1 d .
N5 N 0.65628(17) 0.5182(2) 0.05968(16) 0.0268(8) Uani 1 1 d .
N6 N 0.57504(18) 0.4275(2) 0.06315(16) 0.0266(8) Uani 1 1 d .
N7 N 0.74411(18) 0.5905(2) 0.40749(17) 0.0315(9) Uani 1 1 d .
N8 N 0.7468(2) 0.7234(3) 0.77159(18) 0.0396(10) Uani 1 1 d .
N9 N 0.39200(18) 0.9355(2) 0.42218(17) 0.0301(9) Uani 1 1 d .
N10 N 0.59761(17) 0.7604(2) 0.47329(16) 0.0249(8) Uani 1 1 d .
N11 N 0.68682(18) 0.7124(2) 0.55894(16) 0.0273(8) Uani 1 1 d .
N12 N 0.60415(18) 0.7989(2) 0.56459(16) 0.0306(9) Uani 1 1 d .
Mo1 Mo 0.0000 0.21450(4) -0.2500 0.04796(19) Uani 1 2 d S
Mo2 Mo 0.111959(19) 0.33930(2) -0.139579(17) 0.02719(11) Uani 1 1 d .
Mo3 Mo 0.116913(19) 0.54071(2) -0.143492(18) 0.02817(11) Uani 1 1 d .
Mo4 Mo 0.0000 0.65180(4) -0.2500 0.03941(17) Uani 1 2 d S
Mo5 Mo 0.050971(18) 0.44357(2) -0.291149(17) 0.02551(11) Uani 1 1 d .
O1 O -0.0179(3) 0.1532(4) -0.2052(3) 0.135(3) Uani 1 1 d .
O2 O 0.07850(17) 0.2656(2) -0.20652(16) 0.0431(9) Uani 1 1 d .
O3 O 0.11010(19) 0.2772(2) -0.08750(17) 0.0538(10) Uani 1 1 d .
O4 O 0.19331(17) 0.3333(2) -0.13050(16) 0.0484(10) Uani 1 1 d .
O5 O 0.10996(16) 0.4402(2) -0.10699(15) 0.0386(8) Uani 1 1 d .
O6 O 0.0890(2) 0.4361(2) -0.21441(15) 0.0472(9) Uani 1 1 d .
O7 O 0.10981(18) 0.4495(2) -0.31721(18) 0.0503(10) Uani 1 1 d .
O8 O 0.00321(17) 0.3556(2) -0.32212(17) 0.0504(10) Uani 1 1 d .
O9 O 0.19994(18) 0.5376(2) -0.12923(18) 0.0537(10) Uani 1 1 d .
O10 O 0.11474(17) 0.6054(2) -0.09374(17) 0.0539(10) Uani 1 1 d .
O11 O 0.08746(16) 0.6076(2) -0.21197(16) 0.0435(9) Uani 1 1 d .
O12 O -0.00102(16) 0.5320(2) -0.31469(16) 0.0432(9) Uani 1 1 d .
O13 O -0.0081(2) 0.7135(3) -0.20078(19) 0.0652(12) Uani 1 1 d .
O14 O -0.0788(6) 0.8639(8) -0.2324(6) 0.121(4) Uiso 0.50 1 d P
H14A H -0.0572 0.8197 -0.2227 0.181 Uiso 0.50 1 d PR
H14B H -0.0509 0.9017 -0.2283 0.181 Uiso 0.50 1 d PR
O15 O 0.0123(16) 0.9842(18) -0.2206(11) 0.144(11) Uiso 0.25 1 d P
H15A H 0.0000 1.0314 -0.2161 0.216 Uiso 0.25 1 d PR
H15B H -0.0187 0.9511 -0.2241 0.216 Uiso 0.25 1 d PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag1 N8 129.47(15) 3_445 3_444
N2 Ag1 N1 123.70(14) 3_445 .
N8 Ag1 N1 106.77(14) 3_444 .
N9 Ag2 N3 134.76(14) 3_545 .
N9 Ag2 N7 122.35(14) 3_545 .
N3 Ag2 N7 102.83(14) . .
N6 C6 N5 125.0(4) . .
N6 C6 C39 118.9(4) . .
N5 C6 C39 116.1(4) . .
N9 C17 C43 123.3(4) . .
N10 C18 N11 125.6(4) . .
N10 C18 C41 118.4(4) . .
N11 C18 C41 115.9(4) . .
C33 C19 C47 118.3(4) . .
N4 C21 N5 125.8(4) . .
N4 C21 C33 118.7(4) . .
N5 C21 C33 115.4(4) . .
C58 C24 C54 118.6(4) . .
N1 C25 C40 123.6(4) . .
C35 C28 C41 119.3(4) . .
N12 C31 N10 124.8(4) . .
N12 C31 C54 117.8(4) . .
N10 C31 C54 117.4(4) . .
C19 C33 C34 118.0(4) . .
C19 C33 C21 121.6(4) . .
C34 C33 C21 120.4(4) . .
C37 C34 C33 119.6(4) . .
N7 C35 C28 123.0(4) . .
N2 C37 C34 123.5(4) . .
C51 C38 C56 118.3(4) . .
C49 C39 C57 118.9(4) . .
C49 C39 C6 119.9(4) . .
C57 C39 C6 121.1(4) . .
C25 C40 C56 119.7(4) . .
C55 C41 C28 118.2(4) . .
C55 C41 C18 123.4(4) . .
C28 C41 C18 118.4(4) . .
C48 C42 C46 117.7(4) . .
C48 C42 C52 120.2(4) . .
C46 C42 C52 122.1(4) . .
C54 C43 C17 119.3(4) . .
N6 C44 N4 125.1(4) . .
N6 C44 C56 118.0(4) . .
N4 C44 C56 116.9(4) . .
N8 C45 C46 122.8(5) . .
C45 C46 C42 119.5(4) . .
N2 C47 C19 124.1(4) . .
C50 C48 C42 118.7(5) . .
C39 C49 C53 118.7(4) . .
N8 C50 C48 124.3(5) . .
N1 C51 C38 124.1(4) . .
N12 C52 N11 125.6(4) . .
N12 C52 C42 117.7(4) . .
N11 C52 C42 116.7(4) . .
N3 C53 C49 123.5(5) . .
C43 C54 C24 118.2(4) . .
C43 C54 C31 120.5(4) . .
C24 C54 C31 121.2(4) . .
C60 C55 C41 119.1(4) . .
C40 C56 C38 117.4(4) . .
C40 C56 C44 121.9(4) . .
C38 C56 C44 120.6(4) . .
C59 C57 C39 117.5(5) . .
N9 C58 C24 123.8(4) . .
N3 C59 C57 125.0(5) . .
N7 C60 C55 123.8(4) . .
C51 N1 C25 116.9(4) . .
C51 N1 Ag1 122.7(3) . .
C25 N1 Ag1 120.4(3) . .
C47 N2 C37 116.4(4) . .
C47 N2 Ag1 123.9(3) . 3
C37 N2 Ag1 119.5(3) . 3
C59 N3 C53 116.2(4) . .
C59 N3 Ag2 128.7(3) . .
C53 N3 Ag2 114.1(3) . .
C21 N4 C44 114.2(4) . .
C21 N5 C6 114.5(4) . .
C6 N6 C44 115.3(4) . .
C60 N7 C35 116.6(4) . .
C60 N7 Ag2 127.6(3) . .
C35 N7 Ag2 115.2(3) . .
C50 N8 C45 116.9(4) . .
C50 N8 Ag1 112.3(3) . 3_556
C45 N8 Ag1 130.7(3) . 3_556
C58 N9 C17 116.8(4) . .
C58 N9 Ag2 127.9(3) . 3_455
C17 N9 Ag2 115.3(3) . 3_455
C18 N10 C31 114.8(4) . .
C52 N11 C18 114.0(4) . .
C52 N12 C31 114.9(4) . .
O1 Mo1 O1 106.7(6) . 2_554
O1 Mo1 O2 107.4(2) . .
O1 Mo1 O2 105.0(2) 2_554 .
O1 Mo1 O2 105.0(2) . 2_554
O1 Mo1 O2 107.4(2) 2_554 2_554
O2 Mo1 O2 124.4(2) . 2_554
O3 Mo2 O4 103.55(18) . .
O3 Mo2 O5 100.13(17) . .
O4 Mo2 O5 102.38(16) . .
O3 Mo2 O2 100.58(18) . .
O4 Mo2 O2 93.49(16) . .
O5 Mo2 O2 150.06(15) . .
O3 Mo2 O8 90.81(16) . 2_554
O4 Mo2 O8 164.00(16) . 2_554
O5 Mo2 O8 81.62(14) . 2_554
O2 Mo2 O8 76.71(14) . 2_554
O3 Mo2 O6 166.34(16) . .
O4 Mo2 O6 89.84(16) . .
O5 Mo2 O6 73.89(13) . .
O2 Mo2 O6 81.03(14) . .
O8 Mo2 O6 76.28(13) 2_554 .
O10 Mo3 O9 103.46(18) . .
O10 Mo3 O11 102.48(18) . .
O9 Mo3 O11 97.08(17) . .
O10 Mo3 O5 98.39(18) . .
O9 Mo3 O5 99.71(17) . .
O11 Mo3 O5 149.28(15) . .
O10 Mo3 O12 90.46(15) . 2_554
O9 Mo3 O12 165.31(17) . 2_554
O11 Mo3 O12 74.99(13) . 2_554
O5 Mo3 O12 82.60(13) . 2_554
O10 Mo3 O6 162.90(16) . .
O9 Mo3 O6 92.50(17) . .
O11 Mo3 O6 81.28(14) . .
O5 Mo3 O6 72.49(13) . .
O12 Mo3 O6 74.26(13) 2_554 .
O13 Mo4 O13 105.6(3) 2_554 .
O13 Mo4 O11 104.92(19) 2_554 2_554
O13 Mo4 O11 102.12(18) . 2_554
O13 Mo4 O11 102.11(18) 2_554 .
O13 Mo4 O11 104.92(19) . .
O11 Mo4 O11 134.5(2) 2_554 .
O7 Mo5 O8 106.09(18) . .
O7 Mo5 O6 111.31(19) . .
O8 Mo5 O6 110.19(18) . .
O7 Mo5 O12 107.67(16) . .
O8 Mo5 O12 110.47(17) . .
O6 Mo5 O12 110.98(17) . .
Mo1 O2 Mo2 136.47(18) . .
Mo2 O5 Mo3 121.68(17) . .
Mo5 O6 Mo2 140.67(19) . .
Mo5 O6 Mo3 129.38(18) . .
Mo2 O6 Mo3 88.74(12) . .
Mo5 O8 Mo2 128.25(18) . 2_554
Mo4 O11 Mo3 124.03(17) . .
Mo5 O12 Mo3 128.67(18) . 2_554
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N2 2.262(3) 3_445
Ag1 N8 2.300(4) 3_444
Ag1 N1 2.307(4) .
Ag2 N9 2.266(4) 3_545
Ag2 N3 2.302(4) .
Ag2 N7 2.335(4) .
C6 N6 1.326(5) .
C6 N5 1.337(5) .
C6 C39 1.491(6) .
C17 N9 1.345(6) .
C17 C43 1.382(6) .
C18 N10 1.318(5) .
C18 N11 1.344(6) .
C18 C41 1.500(6) .
C19 C33 1.377(6) .
C19 C47 1.389(6) .
C21 N4 1.329(5) .
C21 N5 1.339(6) .
C21 C33 1.492(6) .
C24 C58 1.385(6) .
C24 C54 1.394(6) .
C25 N1 1.340(6) .
C25 C40 1.368(6) .
C28 C35 1.377(6) .
C28 C41 1.385(6) .
C31 N12 1.330(6) .
C31 N10 1.345(5) .
C31 C54 1.498(6) .
C33 C34 1.381(6) .
C34 C37 1.366(6) .
C35 N7 1.346(6) .
C37 N2 1.338(6) .
C38 C51 1.387(6) .
C38 C56 1.401(6) .
C39 C49 1.383(7) .
C39 C57 1.381(6) .
C40 C56 1.392(6) .
C41 C55 1.376(6) .
C42 C48 1.389(6) .
C42 C46 1.385(6) .
C42 C52 1.491(6) .
C43 C54 1.380(6) .
C44 N6 1.337(6) .
C44 N4 1.343(5) .
C44 C56 1.485(6) .
C45 N8 1.347(6) .
C45 C46 1.380(7) .
C47 N2 1.326(6) .
C48 C50 1.376(7) .
C49 C53 1.379(7) .
C50 N8 1.326(6) .
C51 N1 1.331(6) .
C52 N12 1.328(6) .
C52 N11 1.333(5) .
C53 N3 1.340(6) .
C55 C60 1.374(6) .
C57 C59 1.382(7) .
C58 N9 1.339(6) .
C59 N3 1.326(7) .
C60 N7 1.341(6) .
N2 Ag1 2.262(3) 3
N8 Ag1 2.300(4) 3_556
N9 Ag2 2.266(4) 3_455
Mo1 O1 1.700(5) .
Mo1 O1 1.700(5) 2_554
Mo1 O2 1.814(4) .
Mo1 O2 1.814(4) 2_554
Mo2 O3 1.700(4) .
Mo2 O4 1.705(3) .
Mo2 O5 1.878(3) .
Mo2 O2 1.974(4) .
Mo2 O8 2.306(3) 2_554
Mo2 O6 2.382(3) .
Mo3 O10 1.682(4) .
Mo3 O9 1.702(3) .
Mo3 O11 1.938(4) .
Mo3 O5 1.947(3) .
Mo3 O12 2.307(3) 2_554
Mo3 O6 2.394(4) .
Mo4 O13 1.692(4) 2_554
Mo4 O13 1.692(4) .
Mo4 O11 1.891(3) 2_554
Mo4 O11 1.891(3) .
Mo5 O7 1.694(3) .
Mo5 O8 1.772(4) .
Mo5 O6 1.782(4) .
Mo5 O12 1.795(4) .
O8 Mo2 2.306(3) 2_554
O12 Mo3 2.307(3) 2_554
O15 O15 1.37(5) 2_554
