#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/97/7029796.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7029796
loop_
_publ_author_name
'Zhang, Lei'
'Kuang, Xiaofei'
'Wu, Xiaoyuan'
'Yang, Wenbin'
'Lu, Canzhong'
_publ_section_title
;
 Supramolecular interactions induced hinge-like motion of a metal-organic
 framework accompanied by anisotropic thermal expansion.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7146
_journal_page_last               7152
_journal_paper_doi               10.1039/c3dt53580k
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C72 H51 Ag4 Mo8 N24 O27.5'
_chemical_formula_weight         2891.37
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 115.351(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   21.9777(6)
_cell_length_b                   16.6111(6)
_cell_length_c                   25.6344(9)
_cell_measurement_reflns_used    15647
_cell_measurement_temperature    340.01(10)
_cell_measurement_theta_max      29.5180
_cell_measurement_theta_min      3.1940
_cell_volume                     8457.2(6)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      340.01(10)
_diffrn_detector_area_resol_mean 10.3503
_diffrn_measured_fraction_theta_full 0.972
_diffrn_measured_fraction_theta_max 0.972
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0343
_diffrn_reflns_av_sigmaI/netI    0.0438
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            19666
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.07
_exptl_absorpt_coefficient_mu    2.141
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.75936
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            kermesinus
_exptl_crystal_density_diffrn    2.271
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block-like
_exptl_crystal_F_000             5580
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.177
_refine_diff_density_min         -1.434
_refine_diff_density_rms         0.115
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     623
_refine_ls_number_reflns         7249
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.048
_refine_ls_R_factor_all          0.0429
_refine_ls_R_factor_gt           0.0353
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0434P)²+13.5429P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0879
_refine_ls_wR_factor_ref         0.0948
_reflns_number_gt                6188
_reflns_number_total             7249
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt53580k2.cif
_cod_data_source_block           A_340K
_cod_depositor_comments
;Adding full bibliography for
 ./tmp-cod-update-bibliographies-12899/cifs/7029796.cif.
;
_cod_original_cell_volume        8457.2(5)
_cod_original_sg_symbol_H-M      C2/c
_cod_original_formula_sum        'C72 H51 Ag4 Mo8 N24 O27.50'
_cod_database_code               7029796
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag -0.22614(2) 0.20904(3) -0.631791(18) 0.04301(13) Uani 1 1 d .
Ag2 Ag 0.29517(2) 0.50170(3) -0.132346(18) 0.04947(14) Uani 1 1 d .
C12 C 0.1534(2) 0.7199(3) 0.0011(2) 0.0246(10) Uani 1 1 d .
C15 C -0.0770(2) 0.9002(3) -0.1075(2) 0.0307(11) Uani 1 1 d .
H15A H -0.0967 0.9050 -0.1475 0.037 Uiso 1 1 calc R
C19 C 0.1281(2) 0.5071(3) -0.4976(2) 0.0252(10) Uani 1 1 d .
C21 C 0.1279(2) 0.5617(3) -0.5889(2) 0.0358(12) Uani 1 1 d .
H21A H 0.0854 0.5397 -0.6101 0.043 Uiso 1 1 calc R
C24 C -0.0969(2) 0.3169(3) -0.6109(2) 0.0355(12) Uani 1 1 d .
H24A H -0.1153 0.3111 -0.6509 0.043 Uiso 1 1 calc R
C26 C 0.0753(2) 0.8014(3) 0.0070(2) 0.0259(10) Uani 1 1 d .
C28 C -0.0177(2) 0.8875(3) 0.0095(2) 0.0362(12) Uani 1 1 d .
H28A H 0.0016 0.8848 0.0495 0.043 Uiso 1 1 calc R
C29 C 0.1598(2) 0.5527(3) -0.5298(2) 0.0276(10) Uani 1 1 d .
C31 C 0.2431(2) 0.6337(3) -0.0037(2) 0.0311(11) Uani 1 1 d .
H31A H 0.2637 0.6332 0.0365 0.037 Uiso 1 1 calc R
C32 C 0.2229(2) 0.5861(3) -0.5007(2) 0.0348(12) Uani 1 1 d .
H32A H 0.2457 0.5813 -0.4608 0.042 Uiso 1 1 calc R
C33 C 0.1581(2) 0.4857(3) -0.3486(2) 0.0304(11) Uani 1 1 d .
C36 C 0.1276(2) 0.4760(3) -0.4122(2) 0.0271(10) Uani 1 1 d .
C37 C 0.2716(2) 0.5928(3) -0.0347(2) 0.0327(11) Uani 1 1 d .
H37A H 0.3118 0.5654 -0.0144 0.039 Uiso 1 1 calc R
C38 C -0.0391(2) 0.3613(3) -0.5845(2) 0.0325(11) Uani 1 1 d .
H38A H -0.0188 0.3839 -0.6062 0.039 Uiso 1 1 calc R
C39 C 0.1838(2) 0.6755(3) -0.03319(19) 0.0246(10) Uani 1 1 d .
C40 C 0.1904(2) 0.7426(3) 0.1520(2) 0.0329(11) Uani 1 1 d .
C41 C -0.0428(2) 0.3341(3) -0.4946(2) 0.0303(11) Uani 1 1 d .
H41A H -0.0250 0.3375 -0.4546 0.036 Uiso 1 1 calc R
C42 C 0.2527(3) 0.7074(4) 0.1810(2) 0.0429(14) Uani 1 1 d .
H42A H 0.2767 0.6897 0.1608 0.051 Uiso 1 1 calc R
C43 C 0.2514(3) 0.6266(4) -0.5312(2) 0.0423(13) Uani 1 1 d .
H43A H 0.2937 0.6493 -0.5109 0.051 Uiso 1 1 calc R
C44 C 0.0501(2) 0.4229(3) -0.4946(2) 0.0267(10) Uani 1 1 d .
C45 C -0.0176(2) 0.8577(3) -0.0814(2) 0.0297(11) Uani 1 1 d .
H45A H 0.0019 0.8344 -0.1036 0.036 Uiso 1 1 calc R
C46 C 0.1584(2) 0.7522(3) 0.0880(2) 0.0296(11) Uani 1 1 d .
C47 C 0.2795(3) 0.6985(4) 0.2404(2) 0.0463(14) Uani 1 1 d .
H47A H 0.3215 0.6744 0.2595 0.056 Uiso 1 1 calc R
C48 C 0.1867(3) 0.7575(4) 0.2428(2) 0.0462(14) Uani 1 1 d .
H48A H 0.1638 0.7754 0.2638 0.055 Uiso 1 1 calc R
C49 C 0.1563(3) 0.7675(3) 0.1837(2) 0.0421(13) Uani 1 1 d .
H49A H 0.1138 0.7907 0.1655 0.050 Uiso 1 1 calc R
C50 C 0.1605(3) 0.6043(3) -0.6160(2) 0.0397(13) Uani 1 1 d .
H50A H 0.1383 0.6117 -0.6557 0.048 Uiso 1 1 calc R
C51 C 0.2118(3) 0.5373(3) -0.3220(2) 0.0396(13) Uani 1 1 d .
H51A H 0.2278 0.5677 -0.3439 0.047 Uiso 1 1 calc R
C52 C -0.1010(2) 0.2910(3) -0.5254(2) 0.0319(11) Uani 1 1 d .
H52A H -0.1224 0.2673 -0.5049 0.038 Uiso 1 1 calc R
C53 C 0.2413(3) 0.5434(4) -0.2628(2) 0.0475(14) Uani 1 1 d .
H53A H 0.2772 0.5788 -0.2455 0.057 Uiso 1 1 calc R
C54 C 0.0127(2) 0.8500(3) -0.0221(2) 0.0271(10) Uani 1 1 d .
C55 C -0.0110(2) 0.3724(3) -0.5249(2) 0.0270(10) Uani 1 1 d .
C56 C 0.1554(2) 0.6749(3) -0.0926(2) 0.0365(12) Uani 1 1 d .
H56A H 0.1161 0.7035 -0.1138 0.044 Uiso 1 1 calc R
C57 C -0.0778(3) 0.9291(3) -0.0206(2) 0.0386(13) Uani 1 1 d .
H57A H -0.0979 0.9541 0.0005 0.046 Uiso 1 1 calc R
C58 C 0.1337(3) 0.4452(3) -0.3147(2) 0.0413(13) Uani 1 1 d .
H58A H 0.0956 0.4130 -0.3313 0.050 Uiso 1 1 calc R
C59 C 0.1672(3) 0.4536(4) -0.2557(2) 0.0527(16) Uani 1 1 d .
H59A H 0.1511 0.4246 -0.2332 0.063 Uiso 1 1 calc R
C60 C 0.1863(3) 0.6310(3) -0.1202(2) 0.0398(13) Uani 1 1 d .
H60A H 0.1657 0.6293 -0.1603 0.048 Uiso 1 1 calc R
N1 N -0.12838(19) 0.2813(2) -0.58232(18) 0.0309(9) Uani 1 1 d .
N2 N 0.2220(2) 0.6351(2) -0.58817(18) 0.0335(9) Uani 1 1 d .
N3 N 0.2208(2) 0.5003(3) -0.22868(19) 0.0434(11) Uani 1 1 d .
N4 N 0.07450(19) 0.4607(2) -0.52713(17) 0.0294(9) Uani 1 1 d .
N5 N 0.15623(19) 0.5175(2) -0.44071(17) 0.0301(9) Uani 1 1 d .
N6 N 0.07486(19) 0.4271(2) -0.43713(17) 0.0299(9) Uani 1 1 d .
N7 N 0.2442(2) 0.5905(3) -0.09255(18) 0.0354(10) Uani 1 1 d .
N8 N 0.2468(2) 0.7234(3) 0.27139(19) 0.0435(11) Uani 1 1 d .
N9 N -0.1078(2) 0.9350(2) -0.07791(18) 0.0339(10) Uani 1 1 d .
N10 N 0.09769(18) 0.7607(2) -0.02689(17) 0.0279(9) Uani 1 1 d .
N11 N 0.18629(19) 0.7126(2) 0.05876(17) 0.0301(9) Uani 1 1 d .
N12 N 0.1039(2) 0.7989(3) 0.06457(18) 0.0337(10) Uani 1 1 d .
Mo1 Mo -0.5000 0.21525(5) -0.7500 0.0515(2) Uani 1 2 d S
Mo2 Mo -0.38803(2) 0.33959(3) -0.639537(18) 0.02966(12) Uani 1 1 d .
Mo3 Mo -0.38326(2) 0.54054(3) -0.643367(18) 0.03090(12) Uani 1 1 d .
Mo4 Mo -0.5000 0.65197(5) -0.7500 0.04327(18) Uani 1 2 d S
Mo5 Mo -0.44883(2) 0.44352(2) -0.791075(18) 0.02803(12) Uani 1 1 d .
O1 O -0.5188(3) 0.1538(4) -0.7057(4) 0.144(3) Uani 1 1 d .
O2 O -0.42162(19) 0.2660(2) -0.70638(17) 0.0487(10) Uani 1 1 d .
O3 O -0.30687(19) 0.3333(3) -0.63044(18) 0.0534(10) Uani 1 1 d .
O4 O -0.3901(2) 0.2778(3) -0.58741(19) 0.0625(12) Uani 1 1 d .
O5 O -0.39013(18) 0.4403(2) -0.60722(16) 0.0440(9) Uani 1 1 d .
O6 O -0.4112(2) 0.4361(2) -0.71476(17) 0.0528(10) Uani 1 1 d .
O7 O -0.49670(19) 0.3560(2) -0.82210(19) 0.0544(11) Uani 1 1 d .
O8 O -0.3903(2) 0.4492(2) -0.8175(2) 0.0556(12) Uani 1 1 d .
O9 O -0.3002(2) 0.5377(3) -0.6292(2) 0.0605(12) Uani 1 1 d .
O10 O -0.38554(19) 0.6045(3) -0.59358(19) 0.0600(12) Uani 1 1 d .
O11 O -0.41298(18) 0.6074(2) -0.71181(17) 0.0491(10) Uani 1 1 d .
O12 O -0.50085(17) 0.5318(2) -0.81476(18) 0.0473(9) Uani 1 1 d .
O13 O -0.5086(2) 0.7128(3) -0.7010(2) 0.0712(13) Uani 1 1 d .
O14 O -0.5777(9) 0.8649(10) -0.7320(6) 0.156(7) Uani 0.50 1 d P
H14A H -0.5575 0.8199 -0.7230 0.188 Uiso 0.50 1 d PR
H14B H -0.5490 0.9009 -0.7294 0.188 Uiso 0.50 1 d PR
O15 O -0.4835(18) 0.9842(17) -0.7218(14) 0.164(17) Uani 0.25 1 d P
H15B H -0.4960 1.0307 -0.7165 0.197 Uiso 0.25 1 d PR
H15C H -0.5133 0.9502 -0.7237 0.197 Uiso 0.25 1 d PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag1 N8 129.41(16) 3_445 3_444
N2 Ag1 N1 123.81(15) 3_445 .
N8 Ag1 N1 106.72(15) 3_444 .
N9 Ag2 N3 134.50(16) 3_545 .
N9 Ag2 N7 122.61(15) 3_545 .
N3 Ag2 N7 102.79(15) . .
N10 C12 N11 125.7(4) . .
N10 C12 C39 118.6(4) . .
N11 C12 C39 115.8(4) . .
N9 C15 C45 123.1(5) . .
N5 C19 N4 125.3(4) . .
N5 C19 C29 115.7(4) . .
N4 C19 C29 119.0(4) . .
C29 C21 C50 118.5(5) . .
N1 C24 C38 123.4(5) . .
N12 C26 N10 124.6(4) . .
N12 C26 C54 117.8(4) . .
N10 C26 C54 117.6(4) . .
C57 C28 C54 118.4(5) . .
C21 C29 C32 118.2(4) . .
C21 C29 C19 121.6(4) . .
C32 C29 C19 120.2(4) . .
C39 C31 C37 119.1(4) . .
C43 C32 C29 119.2(5) . .
C58 C33 C51 118.2(5) . .
C58 C33 C36 121.8(5) . .
C51 C33 C36 120.0(4) . .
N5 C36 N6 124.5(4) . .
N5 C36 C33 116.5(4) . .
N6 C36 C33 119.0(4) . .
N7 C37 C31 123.4(4) . .
C24 C38 C55 119.8(4) . .
C31 C39 C56 118.4(4) . .
C31 C39 C12 118.5(4) . .
C56 C39 C12 123.1(4) . .
C42 C40 C49 118.3(5) . .
C42 C40 C46 122.0(4) . .
C49 C40 C46 119.7(5) . .
C52 C41 C55 118.7(4) . .
C40 C42 C47 119.6(5) . .
N2 C43 C32 123.7(5) . .
N4 C44 N6 125.7(4) . .
N4 C44 C55 117.0(4) . .
N6 C44 C55 117.2(4) . .
C15 C45 C54 119.5(4) . .
N11 C46 N12 125.2(4) . .
N11 C46 C40 117.0(4) . .
N12 C46 C40 117.8(4) . .
N8 C47 C42 122.3(5) . .
N8 C48 C49 123.7(5) . .
C48 C49 C40 118.6(5) . .
N2 C50 C21 123.5(5) . .
C53 C51 C33 119.4(5) . .
N1 C52 C41 124.3(4) . .
N3 C53 C51 123.1(5) . .
C45 C54 C28 118.1(4) . .
C45 C54 C26 120.5(4) . .
C28 C54 C26 121.4(4) . .
C38 C55 C41 117.0(4) . .
C38 C55 C44 121.8(4) . .
C41 C55 C44 121.2(4) . .
C60 C56 C39 118.8(5) . .
N9 C57 C28 123.5(5) . .
C59 C58 C33 118.4(5) . .
N3 C59 C58 124.6(5) . .
N7 C60 C56 124.0(5) . .
C52 N1 C24 116.7(4) . .
C52 N1 Ag1 122.9(3) . .
C24 N1 Ag1 120.3(3) . .
C43 N2 C50 116.9(4) . .
C43 N2 Ag1 119.3(3) . 3
C50 N2 Ag1 123.6(3) . 3
C59 N3 C53 116.0(5) . .
C59 N3 Ag2 128.9(4) . .
C53 N3 Ag2 114.1(3) . .
C19 N4 C44 114.4(4) . .
C19 N5 C36 115.2(4) . .
C44 N6 C36 115.0(4) . .
C37 N7 C60 116.4(4) . .
C37 N7 Ag2 115.4(3) . .
C60 N7 Ag2 127.6(3) . .
C48 N8 C47 117.4(5) . .
C48 N8 Ag1 112.0(3) . 3_556
C47 N8 Ag1 130.4(4) . 3_556
C57 N9 C15 117.3(4) . .
C57 N9 Ag2 127.2(3) . 3_455
C15 N9 Ag2 115.4(3) . 3_455
C12 N10 C26 114.8(4) . .
C46 N11 C12 114.6(4) . .
C46 N12 C26 115.0(4) . .
O1 Mo1 O1 106.4(6) 2_453 .
O1 Mo1 O2 104.7(2) 2_453 .
O1 Mo1 O2 107.8(3) . .
O1 Mo1 O2 107.8(3) 2_453 2_453
O1 Mo1 O2 104.7(2) . 2_453
O2 Mo1 O2 124.5(3) . 2_453
O4 Mo2 O3 103.6(2) . .
O4 Mo2 O5 100.24(19) . .
O3 Mo2 O5 102.51(18) . .
O4 Mo2 O2 100.5(2) . .
O3 Mo2 O2 93.54(18) . .
O5 Mo2 O2 149.91(17) . .
O4 Mo2 O7 90.69(18) . 2_453
O3 Mo2 O7 164.04(17) . 2_453
O5 Mo2 O7 81.54(15) . 2_453
O2 Mo2 O7 76.63(16) . 2_453
O4 Mo2 O6 166.14(18) . .
O3 Mo2 O6 90.02(18) . .
O5 Mo2 O6 73.79(14) . .
O2 Mo2 O6 81.00(15) . .
O7 Mo2 O6 76.17(15) 2_453 .
O10 Mo3 O9 103.5(2) . .
O10 Mo3 O11 102.6(2) . .
O9 Mo3 O11 97.11(19) . .
O10 Mo3 O5 98.4(2) . .
O9 Mo3 O5 99.79(19) . .
O11 Mo3 O5 149.08(16) . .
O10 Mo3 O12 90.40(16) . 2_453
O9 Mo3 O12 165.27(19) . 2_453
O11 Mo3 O12 74.79(15) . 2_453
O5 Mo3 O12 82.66(15) . 2_453
O10 Mo3 O6 162.81(18) . .
O9 Mo3 O6 92.52(19) . .
O11 Mo3 O6 81.21(15) . .
O5 Mo3 O6 72.40(14) . .
O12 Mo3 O6 74.27(15) 2_453 .
O13 Mo4 O13 106.3(3) . 2_453
O13 Mo4 O11 102.1(2) . 2_453
O13 Mo4 O11 105.1(2) 2_453 2_453
O13 Mo4 O11 105.1(2) . .
O13 Mo4 O11 102.1(2) 2_453 .
O11 Mo4 O11 133.8(2) 2_453 .
O8 Mo5 O7 105.8(2) . .
O8 Mo5 O6 111.7(2) . .
O7 Mo5 O6 110.18(19) . .
O8 Mo5 O12 107.57(18) . .
O7 Mo5 O12 110.39(18) . .
O6 Mo5 O12 111.00(19) . .
Mo1 O2 Mo2 136.7(2) . .
Mo2 O5 Mo3 122.15(19) . .
Mo5 O6 Mo2 140.8(2) . .
Mo5 O6 Mo3 129.5(2) . .
Mo2 O6 Mo3 88.46(13) . .
Mo5 O7 Mo2 128.38(19) . 2_453
Mo4 O11 Mo3 124.63(19) . .
Mo5 O12 Mo3 128.6(2) . 2_453
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N2 2.269(4) 3_445
Ag1 N8 2.304(4) 3_444
Ag1 N1 2.309(4) .
Ag2 N9 2.275(4) 3_545
Ag2 N3 2.305(4) .
Ag2 N7 2.334(4) .
C12 N10 1.312(6) .
C12 N11 1.345(6) .
C12 C39 1.503(6) .
C15 N9 1.345(6) .
C15 C45 1.379(6) .
C19 N5 1.330(6) .
C19 N4 1.338(6) .
C19 C29 1.494(6) .
C21 C29 1.378(7) .
C21 C50 1.387(7) .
C24 N1 1.342(6) .
C24 C38 1.371(7) .
C26 N12 1.334(6) .
C26 N10 1.350(6) .
C26 C54 1.490(6) .
C28 C57 1.393(7) .
C28 C54 1.397(6) .
C29 C32 1.379(6) .
C31 C39 1.383(6) .
C31 C37 1.383(6) .
C32 C43 1.370(7) .
C33 C58 1.376(7) .
C33 C51 1.379(7) .
C33 C36 1.481(7) .
C36 N5 1.342(6) .
C36 N6 1.333(6) .
C37 N7 1.341(6) .
C38 C55 1.392(7) .
C39 C56 1.377(7) .
C40 C42 1.379(7) .
C40 C49 1.382(7) .
C40 C46 1.492(7) .
C41 C52 1.381(7) .
C41 C55 1.400(6) .
C42 C47 1.385(7) .
C43 N2 1.327(7) .
C44 N4 1.328(6) .
C44 N6 1.335(6) .
C44 C55 1.488(6) .
C45 C54 1.380(7) .
C46 N11 1.329(6) .
C46 N12 1.335(6) .
C47 N8 1.343(7) .
C48 N8 1.332(7) .
C48 C49 1.379(8) .
C50 N2 1.331(6) .
C51 C53 1.375(7) .
C52 N1 1.329(6) .
C53 N3 1.348(7) .
C56 C60 1.378(7) .
C57 N9 1.331(7) .
C58 C59 1.376(8) .
C59 N3 1.332(7) .
C60 N7 1.343(6) .
N2 Ag1 2.269(4) 3
N8 Ag1 2.304(4) 3_556
N9 Ag2 2.275(4) 3_455
Mo1 O1 1.704(6) 2_453
Mo1 O1 1.704(6) .
Mo1 O2 1.811(4) .
Mo1 O2 1.811(4) 2_453
Mo2 O4 1.702(4) .
Mo2 O3 1.700(4) .
Mo2 O5 1.877(4) .
Mo2 O2 1.973(4) .
Mo2 O7 2.308(4) 2_453
Mo2 O6 2.388(4) .
Mo3 O10 1.678(4) .
Mo3 O9 1.702(4) .
Mo3 O11 1.938(4) .
Mo3 O5 1.942(4) .
Mo3 O12 2.306(4) 2_453
Mo3 O6 2.403(4) .
Mo4 O13 1.684(5) .
Mo4 O13 1.684(5) 2_453
Mo4 O11 1.887(4) 2_453
Mo4 O11 1.887(4) .
Mo5 O8 1.694(3) .
Mo5 O7 1.771(4) .
Mo5 O6 1.772(4) .
Mo5 O12 1.798(4) .
O7 Mo2 2.308(4) 2_453
O12 Mo3 2.306(3) 2_453
O15 O15 1.31(6) 2_453
