#------------------------------------------------------------------------------
#$Date: 2016-03-25 22:21:48 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180009 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/03/7030308.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7030308
loop_
_publ_author_name
'Adams, Jeramie J.'
'Gruver, Brian C.'
'Donohoue, Rose'
'Arulsamy, Navamoney'
'Roddick, Dean M.'
_publ_section_title
;
 Acceptor pincer Ru(II) chemistry.
;
_journal_issue                   40
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12601
_journal_page_last               12611
_journal_paper_doi               10.1039/c2dt31234d
_journal_volume                  41
_journal_year                    2012
_chemical_formula_moiety         'C26 H14 F18 O6 P4 Ru2'
_chemical_formula_sum            'C26 H14 F18 O6 P4 Ru2'
_chemical_formula_weight         1090.39
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                87.327(3)
_cell_angle_beta                 80.705(3)
_cell_angle_gamma                64.441(3)
_cell_formula_units_Z            2
_cell_length_a                   10.4378(6)
_cell_length_b                   10.7359(6)
_cell_length_c                   17.9606(10)
_cell_measurement_reflns_used    9949
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      35.21
_cell_measurement_theta_min      2.37
_cell_volume                     1791.25(18)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0230
_diffrn_reflns_av_sigmaI/netI    0.0240
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            45442
_diffrn_reflns_theta_full        33.73
_diffrn_reflns_theta_max         33.73
_diffrn_reflns_theta_min         2.10
_exptl_absorpt_coefficient_mu    1.156
_exptl_absorpt_correction_T_max  0.8709
_exptl_absorpt_correction_T_min  0.7364
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker AXS Inc., 2008)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.022
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rectangular
_exptl_crystal_F_000             1056
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.797
_refine_diff_density_min         -0.723
_refine_diff_density_rms         0.075
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.021
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_parameters     561
_refine_ls_number_reflns         14207
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.021
_refine_ls_R_factor_all          0.0321
_refine_ls_R_factor_gt           0.0256
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0299P)²+0.8503P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0618
_refine_ls_wR_factor_ref         0.0658
_reflns_number_gt                12296
_reflns_number_total             14207
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt31234d.txt
_cod_data_source_block           bcg02
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/automatic-downloads/retrospective/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_cell_volume        1791.2(2)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7030308
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
Ru1 Ru 0.762682(13) 0.624248(11) 0.535820(7) 0.02412(3) Uani 1 1 d
P1 P 0.67059(4) 0.78977(4) 0.63376(2) 0.02648(7) Uani 1 1 d
P2 P 0.89095(4) 0.52147(4) 0.42184(2) 0.02551(7) Uani 1 1 d
C1 C 0.81174(14) 0.78273(13) 0.48395(8) 0.0210(2) Uani 1 1 d
C12 C 0.7359(3) 0.4628(2) 0.58062(12) 0.0462(5) Uani 1 1 d
C13 C 0.59338(19) 0.69041(19) 0.49481(11) 0.0357(3) Uani 1 1 d
O1 O 1.05116(13) 0.42770(12) 0.41326(7) 0.0358(3) Uani 1 1 d
C2 C 0.85796(16) 0.77823(14) 0.40555(8) 0.0243(3) Uani 1 1 d
O2 O 0.7210(3) 0.3693(2) 0.60257(12) 0.0756(6) Uani 1 1 d
O3 O 0.49029(16) 0.73387(18) 0.46909(11) 0.0569(4) Uani 1 1 d
C3 C 0.90176(18) 0.87589(16) 0.37197(9) 0.0307(3) Uani 1 1 d
H3 H 0.942(2) 0.865(2) 0.3187(13) 0.034(5) Uiso 1 1 d
C4 C 0.8926(2) 0.98398(18) 0.41529(11) 0.0345(3) Uani 1 1 d
H4 H 0.918(3) 1.051(3) 0.3918(14) 0.049(7) Uiso 1 1 d
C5 C 0.84401(17) 0.99287(16) 0.49207(10) 0.0299(3) Uani 1 1 d
H5 H 0.838(3) 1.068(2) 0.5228(13) 0.042(6) Uiso 1 1 d
C6 C 0.80678(15) 0.89195(14) 0.52668(8) 0.0231(2) Uani 1 1 d
C7 C 0.76477(18) 0.89821(17) 0.61160(9) 0.0285(3) Uani 1 1 d
H7A H 0.855(3) 0.853(2) 0.6364(13) 0.043(6) Uiso 1 1 d
H7B H 0.707(3) 0.985(3) 0.6347(15) 0.050(7) Uiso 1 1 d
C8 C 0.47637(18) 0.91554(19) 0.64301(10) 0.0341(3) Uani 1 1 d
F8A F 0.39137(13) 0.85235(14) 0.66302(8) 0.0508(3) Uani 1 1 d
F8B F 0.45152(12) 0.97088(12) 0.57618(6) 0.0436(3) Uani 1 1 d
F8C F 0.43634(13) 1.01888(13) 0.69294(7) 0.0496(3) Uani 1 1 d
C9 C 0.6817(2) 0.7498(2) 0.73637(10) 0.0438(4) Uani 1 1 d
F9A F 0.6004(3) 0.6898(3) 0.76324(10) 0.1146(9) Uani 1 1 d
F9B F 0.81321(17) 0.6703(2) 0.74613(8) 0.0807(6) Uani 1 1 d
F9C F 0.6431(3) 0.86021(19) 0.78008(8) 0.1037(8) Uani 1 1 d
C10 C 0.8589(2) 0.66436(15) 0.35852(9) 0.0303(3) Uani 1 1 d
H10A H 0.933(3) 0.638(2) 0.3138(14) 0.042(6) Uiso 1 1 d
H10B H 0.764(2) 0.693(2) 0.3445(12) 0.032(5) Uiso 1 1 d
C11 C 0.8227(3) 0.4144(2) 0.37563(14) 0.0491(5) Uani 1 1 d
F11A F 0.68368(16) 0.48331(16) 0.36900(11) 0.0711(5) Uani 1 1 d
F11B F 0.89465(18) 0.36870(18) 0.30733(10) 0.0748(5) Uani 1 1 d
F11C F 0.8358(2) 0.30316(16) 0.41565(13) 0.0890(6) Uani 1 1 d
Ru2 Ru 0.882850(11) 1.023226(10) -0.097975(6) 0.01852(3) Uani 1 1 d
P3 P 0.66132(4) 1.20908(4) -0.10622(2) 0.02607(7) Uani 1 1 d
P4 P 1.12426(4) 0.91618(4) -0.090650(19) 0.02008(6) Uani 1 1 d
C14 C 0.94360(16) 1.18810(15) -0.12034(8) 0.0237(2) Uani 1 1 d
C25 C 0.83701(17) 0.86453(16) -0.06921(9) 0.0282(3) Uani 1 1 d
C26 C 0.92200(17) 0.97251(16) -0.19922(8) 0.0268(3) Uani 1 1 d
O4 O 1.17777(11) 0.90202(11) -0.01550(6) 0.02492(19) Uani 1 1 d
O5 O 0.81635(17) 0.77086(15) -0.05533(10) 0.0491(4) Uani 1 1 d
O6 O 0.94367(16) 0.94242(15) -0.26162(7) 0.0403(3) Uani 1 1 d
C15 C 1.08882(17) 1.16113(17) -0.14280(8) 0.0273(3) Uani 1 1 d
C16 C 1.1299(2) 1.2696(2) -0.15172(10) 0.0382(4) Uani 1 1 d
H16 H 1.230(3) 1.247(2) -0.1667(13) 0.041(6) Uiso 1 1 d
C17 C 1.0274(3) 1.4048(2) -0.13929(12) 0.0457(5) Uani 1 1 d
H17 H 1.054(3) 1.473(3) -0.1452(16) 0.064(8) Uiso 1 1 d
C18 C 0.8841(2) 1.43396(19) -0.11759(11) 0.0401(4) Uani 1 1 d
H18 H 0.820(3) 1.523(3) -0.1087(13) 0.043(6) Uiso 1 1 d
C19 C 0.84123(19) 1.32663(16) -0.10793(9) 0.0293(3) Uani 1 1 d
C20 C 0.6845(2) 1.36035(17) -0.08187(11) 0.0326(3) Uani 1 1 d
H20A H 0.666(3) 1.369(2) -0.0308(14) 0.041(6) Uiso 1 1 d
H20B H 0.623(3) 1.441(3) -0.1044(14) 0.050(7) Uiso 1 1 d
C21 C 0.6008(2) 1.2522(2) -0.20087(12) 0.0451(5) Uani 1 1 d
F21A F 0.4867(2) 1.37186(17) -0.20150(10) 0.0870(6) Uani 1 1 d
F21B F 0.5686(2) 1.15671(17) -0.22552(9) 0.0702(4) Uani 1 1 d
F21C F 0.7065(2) 1.2564(2) -0.25001(8) 0.0788(5) Uani 1 1 d
C22 C 0.48628(18) 1.2302(2) -0.04742(12) 0.0378(4) Uani 1 1 d
F22A F 0.50078(14) 1.2088(2) 0.02387(8) 0.0663(4) Uani 1 1 d
F22B F 0.44427(15) 1.13945(16) -0.06967(9) 0.0616(4) Uani 1 1 d
F22C F 0.37916(14) 1.35358(15) -0.05124(12) 0.0768(5) Uani 1 1 d
C23 C 1.19859(17) 1.01224(18) -0.15513(9) 0.0295(3) Uani 1 1 d
H23A H 1.207(2) 0.982(2) -0.2051(13) 0.037(6) Uiso 1 1 d
H23B H 1.292(2) 0.996(2) -0.1459(13) 0.036(6) Uiso 1 1 d
C24 C 1.22506(18) 0.73483(18) -0.13065(10) 0.0340(3) Uani 1 1 d
F24A F 1.36524(12) 0.68219(13) -0.12658(7) 0.0475(3) Uani 1 1 d
F24B F 1.17595(15) 0.65040(12) -0.09239(9) 0.0575(4) Uani 1 1 d
F24C F 1.21371(16) 0.72633(15) -0.20270(8) 0.0614(4) Uani 1 1 d
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C13 Ru1 C12 93.16(9) . .
C13 Ru1 C1 90.51(7) . .
C12 Ru1 C1 174.49(8) . .
C13 Ru1 O1 173.46(6) . 2_766
C12 Ru1 O1 91.50(8) . 2_766
C1 Ru1 O1 85.19(5) . 2_766
C13 Ru1 P2 89.93(6) . .
C12 Ru1 P2 97.41(7) . .
C1 Ru1 P2 78.47(4) . .
O1 Ru1 P2 94.02(3) 2_766 .
C13 Ru1 P1 94.95(6) . .
C12 Ru1 P1 104.63(7) . .
C1 Ru1 P1 79.12(4) . .
O1 Ru1 P1 79.42(3) 2_766 .
P2 Ru1 P1 157.091(16) . .
C13 Ru1 Ru1 139.20(6) . 2_766
C12 Ru1 Ru1 93.05(7) . 2_766
C1 Ru1 Ru1 81.49(4) . 2_766
O1 Ru1 Ru1 44.93(3) 2_766 2_766
P2 Ru1 Ru1 49.271(10) . 2_766
P1 Ru1 Ru1 122.161(12) . 2_766
C7 P1 C8 103.46(8) . .
C7 P1 C9 104.37(9) . .
C8 P1 C9 99.03(8) . .
C7 P1 Ru1 105.02(5) . .
C8 P1 Ru1 117.94(6) . .
C9 P1 Ru1 124.65(7) . .
O1 P2 C10 109.81(8) . .
O1 P2 C11 101.85(9) . .
C10 P2 C11 102.10(9) . .
O1 P2 Ru1 121.21(5) . .
C10 P2 Ru1 104.09(5) . .
C11 P2 Ru1 116.26(8) . .
C2 C1 C6 117.75(13) . .
C2 C1 Ru1 120.70(10) . .
C6 C1 Ru1 121.47(10) . .
O2 C12 Ru1 176.7(2) . .
O3 C13 Ru1 178.21(19) . .
P2 O1 Ru1 143.09(7) . 2_766
C3 C2 C1 120.98(14) . .
C3 C2 C10 120.66(14) . .
C1 C2 C10 118.36(13) . .
C4 C3 C2 119.86(15) . .
C4 C3 H3 120.6(13) . .
C2 C3 H3 119.5(13) . .
C5 C4 C3 120.27(15) . .
C5 C4 H4 120.6(16) . .
C3 C4 H4 119.1(16) . .
C4 C5 C6 120.21(14) . .
C4 C5 H5 120.4(14) . .
C6 C5 H5 119.4(14) . .
C5 C6 C1 120.82(14) . .
C5 C6 C7 119.13(13) . .
C1 C6 C7 120.03(13) . .
C6 C7 P1 106.91(10) . .
C6 C7 H7A 109.7(14) . .
P1 C7 H7A 105.5(13) . .
C6 C7 H7B 117.5(16) . .
P1 C7 H7B 108.4(16) . .
H7A C7 H7B 108(2) . .
F8B C8 F8A 108.18(15) . .
F8B C8 F8C 107.54(15) . .
F8A C8 F8C 107.18(14) . .
F8B C8 P1 108.11(11) . .
F8A C8 P1 111.03(13) . .
F8C C8 P1 114.59(13) . .
F9A C9 F9B 108.7(2) . .
F9A C9 F9C 107.0(2) . .
F9B C9 F9C 104.6(2) . .
F9A C9 P1 111.22(16) . .
F9B C9 P1 111.21(14) . .
F9C C9 P1 113.77(15) . .
C2 C10 P2 104.52(10) . .
C2 C10 H10A 112.6(14) . .
P2 C10 H10A 111.2(14) . .
C2 C10 H10B 109.4(12) . .
P2 C10 H10B 108.0(12) . .
H10A C10 H10B 110.8(19) . .
F11B C11 F11C 106.40(18) . .
F11B C11 F11A 107.29(19) . .
F11C C11 F11A 106.8(2) . .
F11B C11 P2 112.59(17) . .
F11C C11 P2 110.80(16) . .
F11A C11 P2 112.55(13) . .
C26 Ru2 C25 91.39(7) . .
C26 Ru2 O4 174.78(6) . 2_775
C25 Ru2 O4 90.89(6) . 2_775
C26 Ru2 C14 92.39(6) . .
C25 Ru2 C14 174.59(6) . .
O4 Ru2 C14 85.67(5) 2_775 .
C26 Ru2 P4 90.21(5) . .
C25 Ru2 P4 97.97(5) . .
O4 Ru2 P4 94.13(3) 2_775 .
C14 Ru2 P4 78.15(4) . .
C26 Ru2 P3 94.81(5) . .
C25 Ru2 P3 105.05(5) . .
O4 Ru2 P3 80.05(3) 2_775 .
C14 Ru2 P3 78.49(4) . .
P4 Ru2 P3 156.276(14) . .
C26 Ru2 Ru2 139.48(5) . 2_775
C25 Ru2 Ru2 93.58(5) . 2_775
O4 Ru2 Ru2 44.98(3) 2_775 2_775
C14 Ru2 Ru2 81.04(4) . 2_775
P4 Ru2 Ru2 49.269(9) . 2_775
P3 Ru2 Ru2 122.337(11) . 2_775
C20 P3 C21 102.98(9) . .
C20 P3 C22 104.69(9) . .
C21 P3 C22 99.19(10) . .
C20 P3 Ru2 104.48(6) . .
C21 P3 Ru2 118.91(7) . .
C22 P3 Ru2 124.14(6) . .
O4 P4 C23 110.18(7) . .
O4 P4 C24 101.66(7) . .
C23 P4 C24 102.86(8) . .
O4 P4 Ru2 121.13(4) . .
C23 P4 Ru2 103.41(6) . .
C24 P4 Ru2 116.28(6) . .
C15 C14 C19 118.34(13) . .
C15 C14 Ru2 120.59(11) . .
C19 C14 Ru2 120.92(11) . .
O5 C25 Ru2 176.76(15) . .
O6 C26 Ru2 178.84(16) . .
P4 O4 Ru2 143.59(7) . 2_775
C16 C15 C14 120.49(16) . .
C16 C15 C23 121.31(15) . .
C14 C15 C23 118.18(13) . .
C17 C16 C15 120.12(18) . .
C17 C16 H16 121.9(14) . .
C15 C16 H16 118.0(14) . .
C18 C17 C16 120.44(16) . .
C18 C17 H17 119.6(19) . .
C16 C17 H17 119.9(19) . .
C17 C18 C19 120.18(18) . .
C17 C18 H18 118.7(15) . .
C19 C18 H18 121.1(16) . .
C18 C19 C14 120.42(17) . .
C18 C19 C20 119.38(16) . .
C14 C19 C20 120.18(13) . .
C19 C20 P3 106.14(11) . .
C19 C20 H20A 108.7(15) . .
P3 C20 H20A 106.9(15) . .
C19 C20 H20B 112.1(15) . .
P3 C20 H20B 111.6(15) . .
H20A C20 H20B 111(2) . .
F21C C21 F21B 107.1(2) . .
F21C C21 F21A 108.2(2) . .
F21B C21 F21A 106.97(19) . .
F21C C21 P3 108.87(14) . .
F21B C21 P3 111.56(15) . .
F21A C21 P3 113.84(15) . .
F22A C22 F22C 107.35(18) . .
F22A C22 F22B 107.67(18) . .
F22C C22 F22B 106.49(16) . .
F22A C22 P3 110.62(12) . .
F22C C22 P3 113.96(15) . .
F22B C22 P3 110.46(13) . .
C15 C23 P4 104.66(10) . .
C15 C23 H23A 110.5(14) . .
P4 C23 H23A 108.7(14) . .
C15 C23 H23B 113.8(13) . .
P4 C23 H23B 111.0(13) . .
H23A C23 H23B 108.2(19) . .
F24C C24 F24A 106.98(14) . .
F24C C24 F24B 107.48(16) . .
F24A C24 F24B 106.27(16) . .
F24C C24 P4 112.48(13) . .
F24A C24 P4 112.41(12) . .
F24B C24 P4 110.88(12) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ru1 C13 1.8597(18) .
Ru1 C12 1.9864(19) .
Ru1 C1 2.1154(14) .
Ru1 O1 2.1247(12) 2_766
Ru1 P2 2.2916(4) .
Ru1 P1 2.3339(4) .
Ru1 Ru1 4.4914(4) 2_766
P1 C7 1.8161(17) .
P1 C8 1.8736(17) .
P1 C9 1.8834(18) .
P2 O1 1.5206(13) .
P2 C10 1.8100(16) .
P2 C11 1.8718(19) .
C1 C2 1.409(2) .
C1 C6 1.4090(19) .
C12 O2 1.125(2) .
C13 O3 1.138(2) .
O1 Ru1 2.1247(12) 2_766
C2 C3 1.392(2) .
C2 C10 1.514(2) .
C3 C4 1.388(2) .
C3 H3 0.97(2) .
C4 C5 1.383(3) .
C4 H4 0.93(3) .
C5 C6 1.391(2) .
C5 H5 0.98(2) .
C6 C7 1.514(2) .
C7 H7A 1.02(2) .
C7 H7B 0.94(3) .
C8 F8B 1.327(2) .
C8 F8A 1.330(2) .
C8 F8C 1.335(2) .
C9 F9A 1.296(3) .
C9 F9B 1.302(3) .
C9 F9C 1.325(3) .
C10 H10A 0.98(2) .
C10 H10B 0.98(2) .
C11 F11B 1.323(3) .
C11 F11C 1.331(3) .
C11 F11A 1.338(3) .
Ru2 C26 1.8522(15) .
Ru2 C25 1.9850(15) .
Ru2 O4 2.1203(10) 2_775
Ru2 C14 2.1252(14) .
Ru2 P4 2.2982(4) .
Ru2 P3 2.3350(4) .
Ru2 Ru2 4.4922(3) 2_775
P3 C20 1.8238(17) .
P3 C21 1.8772(19) .
P3 C22 1.8832(19) .
P4 O4 1.5192(11) .
P4 C23 1.8153(15) .
P4 C24 1.8795(17) .
C14 C15 1.407(2) .
C14 C19 1.409(2) .
C25 O5 1.1253(19) .
C26 O6 1.1403(19) .
O4 Ru2 2.1203(10) 2_775
C15 C16 1.399(2) .
C15 C23 1.512(2) .
C16 C17 1.384(3) .
C16 H16 0.96(2) .
C17 C18 1.381(3) .
C17 H17 0.89(3) .
C18 C19 1.400(2) .
C18 H18 0.90(2) .
C19 C20 1.511(3) .
C20 H20A 0.91(2) .
C20 H20B 0.95(3) .
C21 F21C 1.313(3) .
C21 F21B 1.322(3) .
C21 F21A 1.324(2) .
C22 F22A 1.312(2) .
C22 F22C 1.322(2) .
C22 F22B 1.328(2) .
C23 H23A 0.95(2) .
C23 H23B 0.96(2) .
C24 F24C 1.329(2) .
C24 F24A 1.335(2) .
C24 F24B 1.336(2) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C1 C6 C7 P1 -19.52(17)
C1 C2 C10 P2 -29.79(17)
C14 C19 C20 P3 -20.40(18)
C14 C15 C23 P4 -29.82(16)
