#------------------------------------------------------------------------------
#$Date: 2016-03-25 22:56:22 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180019 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/13/7031329.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7031329
loop_
_publ_author_name
'Bikas, Rahman'
'Hosseini-Monfared, Hassan'
'Vasylyeva, Vera'
'Sanchiz, Joaquín'
'Alonso, Javier'
'Barandiaran, Jose Manuel'
'Janiak, Christoph'
_publ_section_title
;
 Heteronuclear, mixed-metal Ag(i)-Mn(ii) coordination polymers with
 bridging N-pyridinylisonicotinohydrazide ligands: synthesis, crystal
 structures, magnetic and photoluminescence properties.
;
_journal_issue                   31
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11925
_journal_page_last               11935
_journal_paper_doi               10.1039/c4dt01390e
_journal_volume                  43
_journal_year                    2014
_chemical_formula_moiety         'C42 H34 Ag2 Cl2 Mn3 N12 O4'
_chemical_formula_sum            'C42 H34 Ag2 Cl2 Mn3 N12 O4'
_chemical_formula_weight         1222.27
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.411(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   10.7323(8)
_cell_length_b                   12.8099(10)
_cell_length_c                   17.3311(13)
_cell_measurement_reflns_used    6044
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      65.83
_cell_measurement_theta_min      4.22
_cell_volume                     2327.0(3)
_computing_cell_refinement       'SAINT (Bruker, 2006)'
_computing_data_collection       'APEX2 (Bruker, 2006)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'DIAMOND (Crystal Impact, 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.959
_diffrn_measured_fraction_theta_max 0.960
_diffrn_measurement_device_type  'Bruker Kappa APEX-II CCD area detector'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'microfocus sealed tube'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0569
_diffrn_reflns_av_sigmaI/netI    0.0508
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            16411
_diffrn_reflns_theta_full        64.73
_diffrn_reflns_theta_max         65.83
_diffrn_reflns_theta_min         4.22
_exptl_absorpt_coefficient_mu    14.591
_exptl_absorpt_correction_T_max  0.3232
_exptl_absorpt_correction_T_min  0.2182
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.744
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prisme
_exptl_crystal_F_000             1210
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.896
_refine_diff_density_min         -0.656
_refine_diff_density_rms         0.090
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     347
_refine_ls_number_reflns         3788
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.028
_refine_ls_R_factor_all          0.0730
_refine_ls_R_factor_gt           0.0485
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0260P)²+6.7093P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0863
_refine_ls_wR_factor_ref         0.0941
_reflns_number_gt                2914
_reflns_number_total             3833
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4dt01390e2.cif
_cod_data_source_block           b187-2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 7031329--7031330.cif.
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7031329
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.08315(5) 0.49067(4) 0.20951(3) 0.06163(19) Uani 1 1 d .
Mn1 Mn 0.27892(7) 0.42241(6) -0.03998(5) 0.0316(2) Uani 1 1 d .
Mn2 Mn 0.0000 0.5000 0.5000 0.0238(2) Uani 1 2 d S
Cl1 Cl 0.11805(13) 0.31391(11) -0.11660(9) 0.0547(4) Uani 1 1 d .
N1 N -0.0058(4) 0.5023(3) 0.3735(3) 0.0397(11) Uani 1 1 d .
N2 N 0.2121(4) 0.4551(4) 0.0619(3) 0.0455(12) Uani 1 1 d .
N3 N 0.2261(3) 0.5823(3) -0.0967(2) 0.0300(9) Uani 1 1 d .
N4 N 0.4168(3) 0.4637(3) -0.1097(2) 0.0268(9) Uani 1 1 d .
N5 N 0.5194(3) 0.3978(3) -0.1062(2) 0.0297(9) Uani 1 1 d .
N6 N 0.8258(3) 0.1055(3) -0.0236(2) 0.0282(9) Uani 1 1 d .
O1 O 0.4375(3) 0.3162(3) -0.0084(2) 0.0351(8) Uani 1 1 d .
O2 O -0.1299(4) 0.6354(3) 0.4900(3) 0.0518(12) Uani 1 1 d .
C1 C 0.0182(5) 0.4983(4) 0.3130(4) 0.0427(13) Uani 1 1 d .
C2 C 0.1672(5) 0.4726(4) 0.1143(4) 0.0450(14) Uani 1 1 d .
C3 C 0.1247(5) 0.6392(4) -0.0902(3) 0.0373(13) Uani 1 1 d .
C4 C 0.0798(5) 0.7200(4) -0.1409(4) 0.0482(16) Uani 1 1 d .
C5 C 0.1394(6) 0.7427(5) -0.2005(4) 0.0509(16) Uani 1 1 d .
C6 C 0.2453(5) 0.6861(4) -0.2075(3) 0.0395(13) Uani 1 1 d .
C7 C 0.2889(4) 0.6074(4) -0.1542(3) 0.0280(11) Uani 1 1 d .
C8 C 0.5422(5) 0.6654(4) -0.2110(4) 0.0400(13) Uani 1 1 d .
C9 C 0.6191(6) 0.6897(5) -0.2631(4) 0.0499(16) Uani 1 1 d .
C10 C 0.6393(6) 0.6185(6) -0.3165(4) 0.0584(18) Uani 1 1 d .
C11 C 0.5853(7) 0.5221(6) -0.3181(5) 0.071(2) Uani 1 1 d .
C12 C 0.5096(6) 0.4963(5) -0.2661(4) 0.0533(16) Uani 1 1 d .
C13 C 0.4864(4) 0.5685(4) -0.2120(3) 0.0280(11) Uani 1 1 d .
C14 C 0.4016(4) 0.5425(3) -0.1576(3) 0.0249(10) Uani 1 1 d .
C15 C 0.5186(4) 0.3256(3) -0.0515(3) 0.0249(10) Uani 1 1 d .
C16 C 0.6245(4) 0.2483(3) -0.0437(3) 0.0243(10) Uani 1 1 d .
C17 C 0.7200(4) 0.2576(4) -0.0854(3) 0.0296(12) Uani 1 1 d .
C18 C 0.8170(4) 0.1856(4) -0.0739(3) 0.0306(11) Uani 1 1 d .
H18 H 0.8801 0.1929 -0.1028 0.037 Uiso 1 1 calc R
C19 C 0.7328(5) 0.0970(4) 0.0162(3) 0.0376(13) Uani 1 1 d .
C20 C 0.6318(5) 0.1658(4) 0.0081(3) 0.0362(13) Uani 1 1 d .
C21 C -0.2347(5) 0.6585(5) 0.4276(4) 0.0605(18) Uani 1 1 d .
H21A H -0.2741 0.7223 0.4391 0.091 Uiso 1 1 calc R
H21B H -0.2956 0.6027 0.4221 0.091 Uiso 1 1 calc R
H21C H -0.2055 0.6664 0.3793 0.091 Uiso 1 1 calc R
H2 H -0.121(5) 0.667(4) 0.526(3) 0.035(17) Uiso 1 1 d .
H3 H 0.078(5) 0.613(4) -0.048(4) 0.063(18) Uiso 1 1 d .
H4 H 0.005(5) 0.759(4) -0.134(3) 0.060(17) Uiso 1 1 d .
H5 H 0.107(5) 0.795(5) -0.237(4) 0.064(18) Uiso 1 1 d .
H6 H 0.281(4) 0.699(4) -0.245(3) 0.024(14) Uiso 1 1 d .
H8 H 0.523(5) 0.714(4) -0.177(3) 0.042(16) Uiso 1 1 d .
H9 H 0.661(6) 0.754(5) -0.260(4) 0.07(2) Uiso 1 1 d .
H10 H 0.700(6) 0.636(5) -0.352(4) 0.08(2) Uiso 1 1 d .
H11 H 0.597(6) 0.472(5) -0.352(4) 0.08(2) Uiso 1 1 d .
H12 H 0.477(5) 0.432(5) -0.266(3) 0.056(18) Uiso 1 1 d .
H17 H 0.720(5) 0.308(4) -0.117(3) 0.049(17) Uiso 1 1 d .
H19 H 0.747(5) 0.037(5) 0.054(3) 0.059(17) Uiso 1 1 d .
H20 H 0.567(4) 0.156(3) 0.032(3) 0.024(13) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn -0.5299 2.8052 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 Ag1 C1 172.8(2) . .
N2 Mn1 O1 107.92(16) . .
N2 Mn1 N4 145.39(16) . .
O1 Mn1 N4 72.52(13) . .
N2 Mn1 N3 94.90(16) . .
O1 Mn1 N3 141.53(13) . .
N4 Mn1 N3 71.22(13) . .
N2 Mn1 Cl1 104.40(13) . .
O1 Mn1 Cl1 102.19(10) . .
N4 Mn1 Cl1 109.33(11) . .
N3 Mn1 Cl1 101.49(10) . .
N1 Mn2 N1 180.0(2) . 3_566
N1 Mn2 O2 91.70(17) . .
N1 Mn2 O2 88.30(17) 3_566 .
N1 Mn2 O2 88.30(17) . 3_566
N1 Mn2 O2 91.70(17) 3_566 3_566
O2 Mn2 O2 179.999(1) . 3_566
N1 Mn2 N6 91.03(15) . 2_655
N1 Mn2 N6 88.97(15) 3_566 2_655
O2 Mn2 N6 91.60(15) . 2_655
O2 Mn2 N6 88.40(15) 3_566 2_655
N1 Mn2 N6 88.97(15) . 4_466
N1 Mn2 N6 91.03(15) 3_566 4_466
O2 Mn2 N6 88.40(15) . 4_466
O2 Mn2 N6 91.60(15) 3_566 4_466
N6 Mn2 N6 180.00(15) 2_655 4_466
C1 N1 Mn2 165.2(5) . .
C2 N2 Mn1 175.2(5) . .
C3 N3 C7 118.4(4) . .
C3 N3 Mn1 125.7(4) . .
C7 N3 Mn1 114.3(3) . .
C14 N4 N5 119.7(4) . .
C14 N4 Mn1 122.7(3) . .
N5 N4 Mn1 117.4(3) . .
C15 N5 N4 109.4(4) . .
C19 N6 C18 116.4(4) . .
C19 N6 Mn2 122.4(3) . 2_645
C18 N6 Mn2 121.0(3) . 2_645
C15 O1 Mn1 113.2(3) . .
C21 O2 Mn2 127.5(4) . .
C21 O2 H2 118(4) . .
Mn2 O2 H2 114(4) . .
N1 C1 Ag1 173.5(5) . .
N2 C2 Ag1 175.0(5) . .
N3 C3 C4 122.5(6) . .
N3 C3 H3 114(3) . .
C4 C3 H3 123(3) . .
C5 C4 C3 119.3(5) . .
C5 C4 H4 121(3) . .
C3 C4 H4 119(3) . .
C4 C5 C6 119.1(6) . .
C4 C5 H5 121(4) . .
C6 C5 H5 120(4) . .
C5 C6 C7 119.6(6) . .
C5 C6 H6 119(3) . .
C7 C6 H6 122(3) . .
N3 C7 C6 121.0(4) . .
N3 C7 C14 115.8(4) . .
C6 C7 C14 123.1(5) . .
C13 C8 C9 120.9(6) . .
C13 C8 H8 118(3) . .
C9 C8 H8 121(3) . .
C10 C9 C8 120.0(6) . .
C10 C9 H9 119(4) . .
C8 C9 H9 120(4) . .
C9 C10 C11 119.8(6) . .
C9 C10 H10 119(4) . .
C11 C10 H10 121(4) . .
C10 C11 C12 120.8(7) . .
C10 C11 H11 123(4) . .
C12 C11 H11 117(4) . .
C13 C12 C11 120.1(6) . .
C13 C12 H12 120(4) . .
C11 C12 H12 120(4) . .
C12 C13 C8 118.2(5) . .
C12 C13 C14 120.5(5) . .
C8 C13 C14 121.2(5) . .
N4 C14 C7 113.8(4) . .
N4 C14 C13 124.9(4) . .
C7 C14 C13 121.2(4) . .
O1 C15 N5 126.7(4) . .
O1 C15 C16 119.3(4) . .
N5 C15 C16 114.0(4) . .
C20 C16 C17 117.5(4) . .
C20 C16 C15 120.3(4) . .
C17 C16 C15 122.2(4) . .
C18 C17 C16 119.4(5) . .
C18 C17 H17 121(4) . .
C16 C17 H17 120(4) . .
N6 C18 C17 123.8(4) . .
N6 C18 H18 118.1 . .
C17 C18 H18 118.1 . .
N6 C19 C20 123.6(5) . .
N6 C19 H19 112(3) . .
C20 C19 H19 124(3) . .
C16 C20 C19 119.3(5) . .
C16 C20 H20 118(3) . .
C19 C20 H20 123(3) . .
O2 C21 H21A 109.5 . .
O2 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
O2 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C2 2.057(7) .
Ag1 C1 2.061(6) .
Mn1 N2 2.086(5) .
Mn1 O1 2.155(3) .
Mn1 N4 2.168(4) .
Mn1 N3 2.289(4) .
Mn1 Cl1 2.3855(16) .
Mn2 N1 2.180(4) .
Mn2 N1 2.180(4) 3_566
Mn2 O2 2.208(4) .
Mn2 O2 2.208(4) 3_566
Mn2 N6 2.272(4) 2_655
Mn2 N6 2.272(4) 4_466
N1 C1 1.134(7) .
N2 C2 1.138(7) .
N3 C3 1.335(6) .
N3 C7 1.357(6) .
N4 C14 1.295(5) .
N4 N5 1.379(5) .
N5 C15 1.325(6) .
N6 C19 1.334(6) .
N6 C18 1.336(6) .
N6 Mn2 2.272(3) 2_645
O1 C15 1.270(5) .
O2 C21 1.414(7) .
O2 H2 0.74(5) .
C3 C4 1.376(8) .
C3 H3 1.03(6) .
C4 C5 1.358(8) .
C4 H4 0.98(6) .
C5 C6 1.376(8) .
C5 H5 0.94(6) .
C6 C7 1.380(7) .
C6 H6 0.85(5) .
C7 C14 1.479(6) .
C8 C13 1.376(7) .
C8 C9 1.383(8) .
C8 H8 0.91(5) .
C9 C10 1.350(9) .
C9 H9 0.93(6) .
C10 C11 1.362(10) .
C10 H10 1.02(7) .
C11 C12 1.378(9) .
C11 H11 0.89(7) .
C12 C13 1.376(7) .
C12 H12 0.89(6) .
C13 C14 1.483(6) .
C15 C16 1.492(6) .
C16 C20 1.378(6) .
C16 C17 1.381(6) .
C17 C18 1.373(6) .
C17 H17 0.85(5) .
C18 H18 0.9300 .
C19 C20 1.380(7) .
C19 H19 1.00(6) .
C20 H20 0.89(4) .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O2 H2 Cl1 0.74(5) 2.44(5) 3.152(5) 162(6) 2
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
O2 Mn2 N1 C1 141.2(17) .
O2 Mn2 N1 C1 -38.8(17) 3_566
N6 Mn2 N1 C1 49.5(17) 2_655
N6 Mn2 N1 C1 -130.5(17) 4_466
N2 Mn1 N3 C3 -34.6(4) .
O1 Mn1 N3 C3 -161.8(3) .
N4 Mn1 N3 C3 177.9(4) .
Cl1 Mn1 N3 C3 71.2(4) .
N2 Mn1 N3 C7 160.2(3) .
O1 Mn1 N3 C7 33.1(4) .
N4 Mn1 N3 C7 12.7(3) .
Cl1 Mn1 N3 C7 -94.0(3) .
N2 Mn1 N4 C14 -80.6(5) .
O1 Mn1 N4 C14 -177.0(4) .
N3 Mn1 N4 C14 -10.1(3) .
Cl1 Mn1 N4 C14 85.8(4) .
N2 Mn1 N4 N5 104.2(4) .
O1 Mn1 N4 N5 7.8(3) .
N3 Mn1 N4 N5 174.7(3) .
Cl1 Mn1 N4 N5 -89.4(3) .
C14 N4 N5 C15 177.6(4) .
Mn1 N4 N5 C15 -7.0(5) .
N2 Mn1 O1 C15 -150.7(3) .
N4 Mn1 O1 C15 -7.1(3) .
N3 Mn1 O1 C15 -27.2(4) .
Cl1 Mn1 O1 C15 99.6(3) .
N1 Mn2 O2 C21 36.6(5) .
N1 Mn2 O2 C21 -143.4(5) 3_566
N6 Mn2 O2 C21 127.7(5) 2_655
N6 Mn2 O2 C21 -52.3(5) 4_466
C7 N3 C3 C4 1.9(7) .
Mn1 N3 C3 C4 -162.7(4) .
N3 C3 C4 C5 0.7(8) .
C3 C4 C5 C6 -1.7(9) .
C4 C5 C6 C7 0.2(9) .
C3 N3 C7 C6 -3.5(7) .
Mn1 N3 C7 C6 162.9(4) .
C3 N3 C7 C14 179.0(4) .
Mn1 N3 C7 C14 -14.6(5) .
C5 C6 C7 N3 2.4(8) .
C5 C6 C7 C14 179.7(5) .
C13 C8 C9 C10 0.7(9) .
C8 C9 C10 C11 -1.0(10) .
C9 C10 C11 C12 0.3(11) .
C10 C11 C12 C13 0.7(11) .
C11 C12 C13 C8 -0.9(9) .
C11 C12 C13 C14 178.0(6) .
C9 C8 C13 C12 0.2(8) .
C9 C8 C13 C14 -178.7(5) .
N5 N4 C14 C7 -179.1(4) .
Mn1 N4 C14 C7 5.8(5) .
N5 N4 C14 C13 1.1(7) .
Mn1 N4 C14 C13 -174.0(3) .
N3 C7 C14 N4 6.6(6) .
C6 C7 C14 N4 -170.8(5) .
N3 C7 C14 C13 -173.6(4) .
C6 C7 C14 C13 9.0(7) .
C12 C13 C14 N4 56.0(7) .
C8 C13 C14 N4 -125.2(5) .
C12 C13 C14 C7 -123.8(5) .
C8 C13 C14 C7 55.1(6) .
Mn1 O1 C15 N5 6.5(6) .
Mn1 O1 C15 C16 -172.1(3) .
N4 N5 C15 O1 0.2(6) .
N4 N5 C15 C16 178.8(4) .
O1 C15 C16 C20 2.0(7) .
N5 C15 C16 C20 -176.7(4) .
O1 C15 C16 C17 -176.1(4) .
N5 C15 C16 C17 5.2(6) .
C20 C16 C17 C18 0.0(7) .
C15 C16 C17 C18 178.1(4) .
C19 N6 C18 C17 0.6(7) .
Mn2 N6 C18 C17 -173.9(4) 2_645
C16 C17 C18 N6 -0.4(8) .
C18 N6 C19 C20 -0.5(8) .
Mn2 N6 C19 C20 174.0(4) 2_645
C17 C16 C20 C19 0.1(7) .
C15 C16 C20 C19 -178.0(5) .
N6 C19 C20 C16 0.1(9) .
