#------------------------------------------------------------------------------
#$Date: 2016-03-25 23:37:57 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180047 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/41/7034127.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7034127
loop_
_publ_author_name
'Sobieray, Miriam'
'Gode, Jens'
'Seidel, Christiane'
'Poß, Marieke'
'Feldmann, Claus'
'Ruschewitz, Uwe'
_publ_section_title
;
 Bright luminescence in lanthanide coordination polymers with
 tetrafluoroterephthalate as a bridging ligand.
;
_journal_issue                   13
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6249
_journal_page_last               6259
_journal_paper_doi               10.1039/c4dt03733b
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C17 H21 Eu F4 N4 O10'
_chemical_formula_weight         669.34
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2013-08-28 deposited with the CCDC.
2015-02-20 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 111.243(11)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   22.085(3)
_cell_length_b                   11.3940(13)
_cell_length_c                   20.578(3)
_cell_measurement_temperature    293(2)
_cell_volume                     4826.3(12)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.890
_diffrn_measured_fraction_theta_max 0.890
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0316
_diffrn_reflns_av_sigmaI/netI    0.0694
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            9149
_diffrn_reflns_theta_full        28.07
_diffrn_reflns_theta_max         28.07
_diffrn_reflns_theta_min         2.68
_exptl_absorpt_coefficient_mu    2.688
_exptl_absorpt_correction_T_max  0.7397
_exptl_absorpt_correction_T_min  0.6081
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'X-Red, X-Shape'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.842
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2640
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.081
_refine_diff_density_min         -1.377
_refine_diff_density_rms         0.134
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.920
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     335
_refine_ls_number_reflns         5224
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.920
_refine_ls_R_factor_all          0.0565
_refine_ls_R_factor_gt           0.0329
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0344P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0706
_refine_ls_wR_factor_ref         0.0752
_reflns_number_gt                3597
_reflns_number_total             5224
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            c4dt03733b2.cif
_cod_data_source_block           ms001
_cod_depositor_comments
'Adding full bibliography for 7034127--7034136.cif.'
_cod_original_cell_volume        4826.3(11)
_cod_original_sg_symbol_H-M      'C2 /c'
_cod_database_code               7034127
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.402407(11) 0.46086(2) 0.696769(11) 0.01790(6) Uani 1 1 d .
F3 F 0.4233(2) 0.0763(3) 0.8054(2) 0.0520(11) Uani 1 1 d .
F4 F 0.4221(2) -0.1549(3) 0.8034(2) 0.0568(12) Uani 1 1 d .
F9 F 0.4991(2) 0.6877(4) 0.58023(16) 0.0513(10) Uani 1 1 d .
F10 F 0.54249(18) 0.2885(3) 0.55832(16) 0.0439(9) Uani 1 1 d .
O1 O 0.44545(17) 0.2674(4) 0.72713(19) 0.0302(9) Uani 1 1 d .
O6 O 0.44544(19) -0.3452(4) 0.7233(2) 0.0341(10) Uani 1 1 d .
O7A O 0.50435(16) 0.4630(4) 0.68012(14) 0.0276(7) Uani 1 1 d .
O7B O 0.60474(17) 0.4721(5) 0.68493(17) 0.0433(11) Uani 1 1 d .
O11 O 0.30853(19) 0.5822(4) 0.6714(2) 0.0380(10) Uani 1 1 d .
O14 O 0.3117(2) 0.3372(4) 0.6867(2) 0.0443(11) Uani 1 1 d .
O17 O 0.3495(4) -0.0818(9) 0.5955(4) 0.129(4) Uani 1 1 d .
O21 O 0.3784(3) 0.3479(5) 0.5861(2) 0.0582(15) Uani 1 1 d .
O22 O 0.3548(3) 0.4222(5) 0.4830(2) 0.0686(18) Uani 1 1 d .
O23 O 0.3720(2) 0.5342(5) 0.57318(19) 0.0505(12) Uani 1 1 d .
N11 N 0.2261(2) 0.6978(5) 0.6089(2) 0.0379(12) Uani 1 1 d .
N14 N 0.2531(2) 0.1730(5) 0.6819(2) 0.0361(11) Uani 1 1 d .
N17 N 0.3702(3) 0.0533(8) 0.5254(4) 0.072(2) Uani 1 1 d .
N20 N 0.3681(2) 0.4349(5) 0.5457(2) 0.0380(14) Uani 1 1 d .
C1 C 0.5000 0.2185(7) 0.7500 0.0224(16) Uani 1 2 d S
C2 C 0.5000 0.0862(7) 0.7500 0.0226(16) Uani 1 2 d S
C3 C 0.4607(3) 0.0207(5) 0.7760(3) 0.0265(13) Uani 1 1 d .
C4 C 0.4607(3) -0.0993(6) 0.7760(3) 0.0313(13) Uani 1 1 d .
C5 C 0.5000 -0.1640(7) 0.7500 0.0266(18) Uani 1 2 d S
C6 C 0.5000 -0.2975(7) 0.7500 0.0269(17) Uani 1 2 d S
C7 C 0.5461(2) 0.4735(5) 0.6516(2) 0.0231(11) Uani 1 1 d .
C8 C 0.5216(2) 0.4876(5) 0.5730(2) 0.0270(13) Uani 1 1 d .
C9 C 0.4997(3) 0.5931(5) 0.5415(2) 0.0290(12) Uani 1 1 d .
C10 C 0.5217(3) 0.3933(5) 0.5305(2) 0.0288(12) Uani 1 1 d .
C11 C 0.2865(3) 0.6670(6) 0.6315(3) 0.0375(14) Uani 1 1 d .
H11 H 0.3151 0.7103 0.6171 0.062(14) Uiso 1 1 calc R
C12 C 0.1791(3) 0.6376(8) 0.6303(4) 0.059(2) Uani 1 1 d .
H12A H 0.1982 0.5676 0.6552 0.106(8) Uiso 1 1 calc R
H12B H 0.1420 0.6173 0.5898 0.106(8) Uiso 1 1 calc R
H12C H 0.1657 0.6880 0.6600 0.106(8) Uiso 1 1 calc R
C13 C 0.2017(4) 0.7953(7) 0.5595(4) 0.059(2) Uani 1 1 d .
H13A H 0.2374 0.8315 0.5509 0.106(8) Uiso 1 1 calc R
H13B H 0.1809 0.8521 0.5788 0.106(8) Uiso 1 1 calc R
H13C H 0.1710 0.7659 0.5165 0.106(8) Uiso 1 1 calc R
C14 C 0.3051(3) 0.2283(6) 0.6827(3) 0.0375(14) Uani 1 1 d .
H14 H 0.3394 0.1837 0.6802 0.062(14) Uiso 1 1 calc R
C15 C 0.2494(3) 0.0460(7) 0.6792(3) 0.0519(17) Uani 1 1 d .
H15A H 0.2893 0.0146 0.6778 0.106(8) Uiso 1 1 calc R
H15B H 0.2139 0.0221 0.6383 0.106(8) Uiso 1 1 calc R
H15C H 0.2427 0.0172 0.7199 0.106(8) Uiso 1 1 calc R
C16 C 0.1969(3) 0.2362(7) 0.6828(4) 0.056(2) Uani 1 1 d .
H16A H 0.2061 0.3187 0.6870 0.106(8) Uiso 1 1 calc R
H16B H 0.1861 0.2104 0.7217 0.106(8) Uiso 1 1 calc R
H16C H 0.1609 0.2214 0.6403 0.106(8) Uiso 1 1 calc R
C17 C 0.3860(5) -0.0336(13) 0.5718(5) 0.094(3) Uani 1 1 d .
H17 H 0.4288 -0.0597 0.5874 0.062(14) Uiso 1 1 calc R
C18 C 0.4185(6) 0.1083(13) 0.5047(8) 0.124(5) Uani 1 1 d .
H18A H 0.4280 0.1848 0.5255 0.106(8) Uiso 1 1 calc R
H18B H 0.4026 0.1155 0.4549 0.106(8) Uiso 1 1 calc R
H18C H 0.4573 0.0615 0.5200 0.106(8) Uiso 1 1 calc R
C19 C 0.3054(5) 0.0953(10) 0.4972(6) 0.092(3) Uani 1 1 d .
H19A H 0.2865 0.0743 0.4488 0.106(8) Uiso 1 1 calc R
H19B H 0.3053 0.1792 0.5017 0.106(8) Uiso 1 1 calc R
H19C H 0.2804 0.0610 0.5220 0.106(8) Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O11 Eu1 O6 75.90(15) . 1_565
O11 Eu1 O1 145.30(14) . .
O6 Eu1 O1 134.85(11) 1_565 .
O11 Eu1 O14 71.86(14) . .
O6 Eu1 O14 144.54(15) 1_565 .
O1 Eu1 O14 73.82(14) . .
O11 Eu1 O7A 138.52(14) . .
O6 Eu1 O7A 72.94(15) 1_565 .
O1 Eu1 O7A 75.04(14) . .
O14 Eu1 O7A 142.46(16) . .
O11 Eu1 O7B 80.05(14) . 2_656
O6 Eu1 O7B 83.74(16) 1_565 2_656
O1 Eu1 O7B 87.25(15) . 2_656
O14 Eu1 O7B 76.60(16) . 2_656
O7A Eu1 O7B 122.20(10) . 2_656
O11 Eu1 O21 102.61(17) . .
O6 Eu1 O21 128.27(15) 1_565 .
O1 Eu1 O21 72.33(15) . .
O14 Eu1 O21 73.99(17) . .
O7A Eu1 O21 76.99(16) . .
O7B Eu1 O21 147.82(17) 2_656 .
O11 Eu1 O23 72.26(14) . .
O6 Eu1 O23 82.08(17) 1_565 .
O1 Eu1 O23 120.21(15) . .
O14 Eu1 O23 101.46(17) . .
O7A Eu1 O23 76.90(13) . .
O7B Eu1 O23 151.21(16) 2_656 .
O21 Eu1 O23 50.33(18) . .
O11 Eu1 O7A 121.45(13) . 2_656
O6 Eu1 O7A 70.30(13) 1_565 2_656
O1 Eu1 O7A 69.98(13) . 2_656
O14 Eu1 O7A 115.35(14) . 2_656
O7A Eu1 O7A 71.86(11) . 2_656
O7B Eu1 O7A 50.45(10) 2_656 2_656
O21 Eu1 O7A 135.87(16) . 2_656
O23 Eu1 O7A 143.00(15) . 2_656
O11 Eu1 C7 100.20(14) . 2_656
O6 Eu1 C7 74.99(15) 1_565 2_656
O1 Eu1 C7 78.57(15) . 2_656
O14 Eu1 C7 96.42(15) . 2_656
O7A Eu1 C7 97.46(11) . 2_656
O7B Eu1 C7 24.75(12) 2_656 2_656
O21 Eu1 C7 150.85(17) . 2_656
O23 Eu1 C7 157.02(19) . 2_656
O7A Eu1 C7 25.73(11) 2_656 2_656
O11 Eu1 N20 87.50(14) . .
O6 Eu1 N20 105.27(15) 1_565 .
O1 Eu1 N20 96.27(14) . .
O14 Eu1 N20 87.86(15) . .
O7A Eu1 N20 75.21(12) . .
O7B Eu1 N20 162.46(13) 2_656 .
O21 Eu1 N20 25.21(15) . .
O23 Eu1 N20 25.13(17) . .
O7A Eu1 N20 146.58(12) 2_656 .
C7 Eu1 N20 172.04(14) 2_656 .
O11 Eu1 Eu1 141.73(11) . 2_656
O6 Eu1 Eu1 67.72(9) 1_565 2_656
O1 Eu1 Eu1 67.42(9) . 2_656
O14 Eu1 Eu1 137.43(11) . 2_656
O7A Eu1 Eu1 37.80(7) . 2_656
O7B Eu1 Eu1 84.49(8) 2_656 2_656
O21 Eu1 Eu1 108.91(14) . 2_656
O23 Eu1 Eu1 112.67(11) . 2_656
O7A Eu1 Eu1 34.07(7) 2_656 2_656
C7 Eu1 Eu1 59.75(9) 2_656 2_656
N20 Eu1 Eu1 112.75(10) . 2_656
C1 O1 Eu1 138.1(4) . .
C6 O6 Eu1 137.8(4) . 1_545
C7 O7A Eu1 161.3(3) . .
C7 O7A Eu1 90.0(2) . 2_656
Eu1 O7A Eu1 108.13(10) . 2_656
C7 O7B Eu1 96.8(3) . 2_656
C11 O11 Eu1 133.9(4) . .
C14 O14 Eu1 131.6(4) . .
N20 O21 Eu1 97.1(3) . .
N20 O23 Eu1 96.0(4) . .
C11 N11 C12 121.8(5) . .
C11 N11 C13 121.6(6) . .
C12 N11 C13 116.6(5) . .
C14 N14 C16 121.2(6) . .
C14 N14 C15 121.4(6) . .
C16 N14 C15 117.5(6) . .
C17 N17 C19 120.6(9) . .
C17 N17 C18 120.6(10) . .
C19 N17 C18 118.8(10) . .
O22 N20 O23 122.2(6) . .
O22 N20 O21 121.3(6) . .
O23 N20 O21 116.5(4) . .
O22 N20 Eu1 178.7(5) . .
O23 N20 Eu1 58.8(3) . .
O21 N20 Eu1 57.7(3) . .
O1 C1 O1 127.3(8) 2_656 .
O1 C1 C2 116.4(4) 2_656 .
O1 C1 C2 116.4(4) . .
C3 C2 C3 115.1(7) 2_656 .
C3 C2 C1 122.4(4) 2_656 .
C3 C2 C1 122.4(4) . .
F3 C3 C4 118.1(5) . .
F3 C3 C2 119.4(6) . .
C4 C3 C2 122.5(6) . .
F4 C4 C3 118.2(5) . .
F4 C4 C5 119.7(6) . .
C3 C4 C5 122.1(6) . .
C4 C5 C4 115.7(8) 2_656 .
C4 C5 C6 122.1(4) 2_656 .
C4 C5 C6 122.1(4) . .
O6 C6 O6 128.6(8) . 2_656
O6 C6 C5 115.7(4) . .
O6 C6 C5 115.7(4) 2_656 .
O7B C7 O7A 122.7(4) . .
O7B C7 C8 119.5(4) . .
O7A C7 C8 117.8(4) . .
O7B C7 Eu1 58.5(2) . 2_656
O7A C7 Eu1 64.3(2) . 2_656
C8 C7 Eu1 176.3(4) . 2_656
C9 C8 C10 117.6(4) . .
C9 C8 C7 121.7(5) . .
C10 C8 C7 120.7(5) . .
F9 C9 C8 120.1(4) . .
F9 C9 C10 118.0(5) . 5_666
C8 C9 C10 121.8(5) . 5_666
F10 C10 C8 120.2(4) . .
F10 C10 C9 119.3(5) . 5_666
C8 C10 C9 120.6(5) . 5_666
O11 C11 N11 123.5(6) . .
O11 C11 H11 118.3 . .
N11 C11 H11 118.3 . .
N11 C12 H12A 109.5 . .
N11 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
N11 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
N11 C13 H13A 109.5 . .
N11 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
N11 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
O14 C14 N14 124.2(6) . .
O14 C14 H14 117.9 . .
N14 C14 H14 117.9 . .
N14 C15 H15A 109.5 . .
N14 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
N14 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
N14 C16 H16A 109.5 . .
N14 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
N14 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
O17 C17 N17 125.7(11) . .
O17 C17 H17 117.1 . .
N17 C17 H17 117.1 . .
N17 C18 H18A 109.5 . .
N17 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
N17 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
N17 C19 H19A 109.5 . .
N17 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
N17 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O11 2.387(4) .
Eu1 O6 2.390(4) 1_565
Eu1 O1 2.393(4) .
Eu1 O14 2.396(4) .
Eu1 O7A 2.397(3) .
Eu1 O7B 2.499(3) 2_656
Eu1 O21 2.500(5) .
Eu1 O23 2.526(4) .
Eu1 O7A 2.623(3) 2_656
Eu1 C7 2.911(4) 2_656
Eu1 N20 2.936(4) .
Eu1 Eu1 4.0667(8) 2_656
F3 C3 1.345(6) .
F4 C4 1.340(6) .
F9 C9 1.344(6) .
F10 C10 1.332(6) .
O1 C1 1.254(5) .
O6 C6 1.253(5) .
O6 Eu1 2.390(4) 1_545
O7A C7 1.264(5) .
O7A Eu1 2.623(3) 2_656
O7B C7 1.227(5) .
O7B Eu1 2.499(3) 2_656
O11 C11 1.247(7) .
O14 C14 1.249(8) .
O17 C17 1.215(13) .
O21 N20 1.260(7) .
O22 N20 1.222(5) .
O23 N20 1.254(7) .
N11 C11 1.293(7) .
N11 C12 1.439(8) .
N11 C13 1.470(8) .
N14 C14 1.303(7) .
N14 C16 1.442(9) .
N14 C15 1.450(9) .
N17 C17 1.330(14) .
N17 C19 1.419(11) .
N17 C18 1.428(13) .
C1 O1 1.254(5) 2_656
C1 C2 1.508(11) .
C2 C3 1.390(7) 2_656
C2 C3 1.390(7) .
C3 C4 1.368(7) .
C4 C5 1.386(7) .
C5 C4 1.386(7) 2_656
C5 C6 1.520(11) .
C6 O6 1.253(5) 2_656
C7 C8 1.518(6) .
C7 Eu1 2.911(4) 2_656
C8 C9 1.368(8) .
C8 C10 1.385(8) .
C9 C10 1.391(6) 5_666
C10 C9 1.391(6) 5_666
C11 H11 0.9300 .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C13 H13A 0.9600 .
C13 H13B 0.9600 .
C13 H13C 0.9600 .
C14 H14 0.9300 .
C15 H15A 0.9600 .
C15 H15B 0.9600 .
C15 H15C 0.9600 .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C17 H17 0.9300 .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O11 Eu1 O1 C1 -165.3(3) . .
O6 Eu1 O1 C1 -18.9(5) 1_565 .
O14 Eu1 O1 C1 -174.1(4) . .
O7A Eu1 O1 C1 27.2(4) . .
O7B Eu1 O1 C1 -97.2(4) 2_656 .
O21 Eu1 O1 C1 108.0(4) . .
O23 Eu1 O1 C1 91.9(4) . .
O7A Eu1 O1 C1 -48.6(4) 2_656 .
C7 Eu1 O1 C1 -73.8(4) 2_656 .
N20 Eu1 O1 C1 100.0(4) . .
Eu1 Eu1 O1 C1 -12.1(3) 2_656 .
O11 Eu1 O7A C7 -46.9(13) . .
O6 Eu1 O7A C7 -89.9(13) 1_565 .
O1 Eu1 O7A C7 122.4(13) . .
O14 Eu1 O7A C7 87.6(13) . .
O7B Eu1 O7A C7 -160.7(12) 2_656 .
O21 Eu1 O7A C7 47.5(13) . .
O23 Eu1 O7A C7 -4.3(13) . .
O7A Eu1 O7A C7 -164.2(12) 2_656 .
C7 Eu1 O7A C7 -161.6(13) 2_656 .
N20 Eu1 O7A C7 21.6(13) . .
Eu1 Eu1 O7A C7 -165.3(14) 2_656 .
O11 Eu1 O7A Eu1 118.40(19) . 2_656
O6 Eu1 O7A Eu1 75.43(16) 1_565 2_656
O1 Eu1 O7A Eu1 -72.31(16) . 2_656
O14 Eu1 O7A Eu1 -107.1(2) . 2_656
O7B Eu1 O7A Eu1 4.6(3) 2_656 2_656
O21 Eu1 O7A Eu1 -147.2(2) . 2_656
O23 Eu1 O7A Eu1 161.0(2) . 2_656
O7A Eu1 O7A Eu1 1.1(2) 2_656 2_656
C7 Eu1 O7A Eu1 3.7(2) 2_656 2_656
N20 Eu1 O7A Eu1 -173.1(2) . 2_656
O6 Eu1 O11 C11 58.1(6) 1_565 .
O1 Eu1 O11 C11 -145.8(5) . .
O14 Eu1 O11 C11 -136.9(6) . .
O7A Eu1 O11 C11 15.9(7) . .
O7B Eu1 O11 C11 144.1(6) 2_656 .
O21 Eu1 O11 C11 -68.7(6) . .
O23 Eu1 O11 C11 -28.0(6) . .
O7A Eu1 O11 C11 114.0(6) 2_656 .
C7 Eu1 O11 C11 129.6(6) 2_656 .
N20 Eu1 O11 C11 -48.3(6) . .
Eu1 Eu1 O11 C11 76.4(6) 2_656 .
O11 Eu1 O14 C14 168.5(6) . .
O6 Eu1 O14 C14 -165.9(5) 1_565 .
O1 Eu1 O14 C14 -16.7(5) . .
O7A Eu1 O14 C14 18.3(7) . .
O7B Eu1 O14 C14 -107.7(6) 2_656 .
O21 Eu1 O14 C14 59.1(5) . .
O23 Eu1 O14 C14 101.7(5) . .
O7A Eu1 O14 C14 -74.6(6) 2_656 .
C7 Eu1 O14 C14 -92.8(5) 2_656 .
N20 Eu1 O14 C14 80.4(5) . .
Eu1 Eu1 O14 C14 -41.6(6) 2_656 .
O11 Eu1 O21 N20 54.6(4) . .
O6 Eu1 O21 N20 -27.3(5) 1_565 .
O1 Eu1 O21 N20 -161.1(4) . .
O14 Eu1 O21 N20 121.2(4) . .
O7A Eu1 O21 N20 -82.9(4) . .
O7B Eu1 O21 N20 145.9(3) 2_656 .
O23 Eu1 O21 N20 0.8(3) . .
O7A Eu1 O21 N20 -128.7(4) 2_656 .
C7 Eu1 O21 N20 -164.8(3) 2_656 .
Eu1 Eu1 O21 N20 -103.4(4) 2_656 .
O11 Eu1 O23 N20 -125.0(4) . .
O6 Eu1 O23 N20 157.3(3) 1_565 .
O1 Eu1 O23 N20 19.3(4) . .
O14 Eu1 O23 N20 -58.5(3) . .
O7A Eu1 O23 N20 83.1(3) . .
O7B Eu1 O23 N20 -141.5(3) 2_656 .
O21 Eu1 O23 N20 -0.8(3) . .
O7A Eu1 O23 N20 115.9(4) 2_656 .
C7 Eu1 O23 N20 161.1(3) 2_656 .
Eu1 Eu1 O23 N20 95.5(3) 2_656 .
Eu1 O23 N20 O22 -179.0(5) . .
Eu1 O23 N20 O21 1.3(6) . .
Eu1 O21 N20 O22 179.0(5) . .
Eu1 O21 N20 O23 -1.4(6) . .
O11 Eu1 N20 O23 51.3(3) . .
O6 Eu1 N20 O23 -23.3(4) 1_565 .
O1 Eu1 N20 O23 -163.3(3) . .
O14 Eu1 N20 O23 123.2(3) . .
O7A Eu1 N20 O23 -90.6(3) . .
O7B Eu1 N20 O23 95.9(6) 2_656 .
O21 Eu1 N20 O23 178.6(6) . .
O7A Eu1 N20 O23 -100.6(4) 2_656 .
Eu1 Eu1 N20 O23 -95.2(3) 2_656 .
O11 Eu1 N20 O21 -127.3(4) . .
O6 Eu1 N20 O21 158.1(4) 1_565 .
O1 Eu1 N20 O21 18.1(4) . .
O14 Eu1 N20 O21 -55.3(4) . .
O7A Eu1 N20 O21 90.8(4) . .
O7B Eu1 N20 O21 -82.7(7) 2_656 .
O23 Eu1 N20 O21 -178.6(6) . .
O7A Eu1 N20 O21 80.8(5) 2_656 .
Eu1 Eu1 N20 O21 86.2(4) 2_656 .
Eu1 O1 C1 O1 9.1(3) . 2_656
Eu1 O1 C1 C2 -170.9(3) . .
O1 C1 C2 C3 -48.2(3) 2_656 2_656
O1 C1 C2 C3 131.8(3) . 2_656
O1 C1 C2 C3 131.8(3) 2_656 .
O1 C1 C2 C3 -48.2(3) . .
C3 C2 C3 F3 176.9(6) 2_656 .
C1 C2 C3 F3 -3.1(6) . .
C3 C2 C3 C4 0.0(4) 2_656 .
C1 C2 C3 C4 180.0(4) . .
F3 C3 C4 F4 1.9(9) . .
C2 C3 C4 F4 178.8(4) . .
F3 C3 C4 C5 -176.9(4) . .
C2 C3 C4 C5 0.0(9) . .
F4 C4 C5 C4 -178.8(6) . 2_656
C3 C4 C5 C4 0.0(4) . 2_656
F4 C4 C5 C6 1.2(6) . .
C3 C4 C5 C6 180.0(4) . .
Eu1 O6 C6 O6 -3.9(3) 1_545 2_656
Eu1 O6 C6 C5 176.1(3) 1_545 .
C4 C5 C6 O6 -127.8(3) 2_656 .
C4 C5 C6 O6 52.2(3) . .
C4 C5 C6 O6 52.2(3) 2_656 2_656
C4 C5 C6 O6 -127.8(3) . 2_656
Eu1 O7B C7 O7A -4.1(7) 2_656 .
Eu1 O7B C7 C8 176.3(5) 2_656 .
Eu1 O7A C7 O7B 170.0(9) . .
Eu1 O7A C7 O7B 3.9(6) 2_656 .
Eu1 O7A C7 C8 -10.5(16) . .
Eu1 O7A C7 C8 -176.6(5) 2_656 .
Eu1 O7A C7 Eu1 166.0(13) . 2_656
O7B C7 C8 C9 -100.8(7) . .
O7A C7 C8 C9 79.7(7) . .
O7B C7 C8 C10 78.3(8) . .
O7A C7 C8 C10 -101.3(7) . .
C10 C8 C9 F9 -179.4(5) . .
C7 C8 C9 F9 -0.3(8) . .
C10 C8 C9 C10 -0.3(9) . 5_666
C7 C8 C9 C10 178.8(5) . 5_666
C9 C8 C10 F10 180.0(5) . .
C7 C8 C10 F10 0.9(8) . .
C9 C8 C10 C9 0.3(9) . 5_666
C7 C8 C10 C9 -178.8(5) . 5_666
Eu1 O11 C11 N11 157.5(5) . .
C12 N11 C11 O11 2.0(10) . .
C13 N11 C11 O11 -177.3(6) . .
Eu1 O14 C14 N14 175.4(4) . .
C16 N14 C14 O14 2.5(9) . .
C15 N14 C14 O14 -178.2(6) . .
C19 N17 C17 O17 -2.2(18) . .
C18 N17 C17 O17 175.8(12) . .
