#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/41/7034188.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7034188
loop_
_publ_author_name
'Palacios, Laura'
'Di Giuseppe, Andrea'
'Castarlenas, Ricardo'
'Lahoz, Fernando J.'
'Pérez-Torrente, Jesús J'
'Oro, Luis A.'
_publ_section_title
;
 Pyridine versus acetonitrile coordination in rhodium-N-heterocyclic
 carbene square-planar complexes.
;
_journal_issue                   12
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5777
_journal_page_last               5789
_journal_paper_doi               10.1039/c5dt00182j
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C32 H41 Cl N3 O2 Rh'
_chemical_formula_sum            'C32 H41 Cl N3 O2 Rh'
_chemical_formula_weight         638.06
_chemical_name_systematic
;
 ?
;
_chemical_properties_physical    Moisture-sensitive
_space_group_IT_number           62
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2014-11-25 deposited with the CCDC.
2015-02-10 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   17.4494(10)
_cell_length_b                   17.1900(10)
_cell_length_c                   10.1596(6)
_cell_measurement_reflns_used    881
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      24.785
_cell_measurement_theta_min      2.319
_cell_volume                     3047.4(3)
_computing_cell_refinement       'APEX2 v. 2009.7 (Bruker AXS, 2008)'
_computing_data_collection       'APEX2 v. 2009.7 (Bruker AXS, 2008)'
_computing_data_reduction        'APEX2 v. 2009.7 (Bruker AXS, 2008)'
_computing_molecular_graphics    ORTEP
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.961
_diffrn_measurement_device_type  'Bruker APEX DUO system'
_diffrn_measurement_method       'ω rotations with narrow frames'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0652
_diffrn_reflns_av_sigmaI/netI    0.0439
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            34652
_diffrn_reflns_theta_full        29.00
_diffrn_reflns_theta_max         30.54
_diffrn_reflns_theta_min         2.32
_exptl_absorpt_coefficient_mu    0.681
_exptl_absorpt_correction_T_max  0.9572
_exptl_absorpt_correction_T_min  0.8573
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
; 
 Multi-scan correction included in APEX2 package (Bruker AXS, 2008)
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.391
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1328
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: toluene/hexane'
_exptl_crystal_size_max          0.142
_exptl_crystal_size_mid          0.065
_exptl_crystal_size_min          0.050
_refine_diff_density_max         0.598
_refine_diff_density_min         -0.553
_refine_diff_density_rms         0.080
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_parameters     296
_refine_ls_number_reflns         4620
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0781
_refine_ls_R_factor_gt           0.0348
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0330P)²+1.3328P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0715
_refine_ls_wR_factor_ref         0.0861
_reflns_number_gt                2699
_reflns_number_total             4620
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5dt00182j2.cif
_cod_data_source_block           compnd_18
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

 Adding full bibliography for 7034186--7034189.cif.
;
_cod_original_sg_symbol_Hall     '-P 2ac 2n '
_cod_original_sg_symbol_H-M      Pnma
_cod_database_code               7034188
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Rh1 Rh 0.003065(14) 0.2500 0.00111(3) 0.02052(7) Uani 1 2 d SD
Cl1A Cl -0.07050(13) 0.2500 -0.1852(2) 0.0499(9) Uani 0.616(6) 2 d SPD
Cl1B Cl 0.0805(3) 0.2500 0.1821(5) 0.0574(17) Uani 0.384(6) 2 d SPD
O1A O 0.0638(3) 0.2086(3) 0.1474(6) 0.086(2) Uani 0.616(6) 1 d PD
O1B O -0.0571(3) 0.2090(3) -0.1449(6) 0.0345(15) Uani 0.384(6) 1 d PD
N1 N 0.10486(17) 0.2500 -0.1174(3) 0.0284(7) Uani 1 2 d S
N2 N -0.13527(10) 0.18751(10) 0.14408(18) 0.0210(4) Uani 1 1 d .
C1 C 0.1742(3) 0.2500 -0.0614(6) 0.0468(11) Uani 1 2 d S
H1 H 0.170(2) 0.2500 0.019(4) 0.040(15) Uiso 1 2 d S
C2 C 0.2404(3) 0.2500 -0.1323(9) 0.0733(19) Uani 1 2 d S
H2 H 0.284(3) 0.2500 -0.086(6) 0.10(2) Uiso 1 2 d S
C3 C 0.2388(4) 0.2500 -0.2645(9) 0.083(2) Uani 1 2 d S
H3 H 0.282(4) 0.2500 -0.311(6) 0.12(2) Uiso 1 2 d S
C4 C 0.1685(5) 0.2500 -0.3241(7) 0.077(2) Uani 1 2 d S
H4 H 0.161(3) 0.2500 -0.401(5) 0.07(2) Uiso 1 2 d S
C5 C 0.1023(3) 0.2500 -0.2485(5) 0.0453(11) Uani 1 2 d S
H5 H 0.056(2) 0.2500 -0.284(4) 0.031(12) Uiso 1 2 d S
C6 C -0.09287(18) 0.2500 0.1059(3) 0.0199(7) Uani 1 2 d S
C7 C -0.20305(14) 0.21113(14) 0.2023(2) 0.0263(5) Uani 1 1 d .
H7 H -0.2374(14) 0.1785(15) 0.227(2) 0.028(7) Uiso 1 1 d .
C8 C -0.10957(13) 0.10689(13) 0.1401(2) 0.0232(5) Uani 1 1 d .
C9 C -0.13554(14) 0.05800(14) 0.0396(2) 0.0264(5) Uani 1 1 d .
C10 C -0.10980(17) -0.01870(15) 0.0415(3) 0.0335(6) Uani 1 1 d .
H10 H -0.1234(13) -0.0500(15) -0.031(2) 0.023(6) Uiso 1 1 d .
C11 C -0.06198(17) -0.04507(15) 0.1381(3) 0.0363(6) Uani 1 1 d .
H11 H -0.0461(15) -0.0953(17) 0.134(3) 0.041(8) Uiso 1 1 d .
C12 C -0.03883(16) 0.00362(15) 0.2387(3) 0.0342(6) Uani 1 1 d .
H12 H -0.0061(15) -0.0130(16) 0.305(3) 0.044(9) Uiso 1 1 d .
C13 C -0.06223(14) 0.08090(13) 0.2433(2) 0.0271(5) Uani 1 1 d .
C14 C -0.03998(16) 0.13251(15) 0.3580(3) 0.0321(6) Uani 1 1 d .
H14 H -0.0396(14) 0.1854(15) 0.329(2) 0.026(7) Uiso 1 1 d .
C15 C 0.0403(2) 0.1160(2) 0.4099(4) 0.0473(8) Uani 1 1 d .
H15A H 0.0519(18) 0.1541(19) 0.471(3) 0.049(9) Uiso 1 1 d .
H15B H 0.074(2) 0.115(2) 0.344(4) 0.072(13) Uiso 1 1 d .
H15C H 0.0431(17) 0.068(2) 0.453(3) 0.050(9) Uiso 1 1 d .
C16 C -0.0980(2) 0.1252(2) 0.4693(3) 0.0449(8) Uani 1 1 d .
H16A H -0.0987(16) 0.0733(18) 0.499(2) 0.041(8) Uiso 1 1 d .
H16B H -0.1501(16) 0.1352(16) 0.442(3) 0.042(8) Uiso 1 1 d .
H16C H -0.0829(17) 0.1598(19) 0.537(3) 0.057(10) Uiso 1 1 d .
C17 C -0.19154(15) 0.08471(15) -0.0647(3) 0.0314(6) Uani 1 1 d .
H17 H -0.1948(14) 0.1398(15) -0.064(3) 0.031(7) Uiso 1 1 d .
C18 C -0.1684(2) 0.0608(2) -0.2035(3) 0.0473(8) Uani 1 1 d .
H18A H -0.1676(19) 0.0043(19) -0.205(3) 0.060(10) Uiso 1 1 d .
H18B H -0.1188(18) 0.0784(18) -0.219(3) 0.054(10) Uiso 1 1 d .
H18C H -0.2028(17) 0.0807(17) -0.263(3) 0.045(9) Uiso 1 1 d .
C19 C -0.27161(19) 0.0544(3) -0.0327(4) 0.0537(9) Uani 1 1 d .
H19A H -0.3065(17) 0.0716(18) -0.094(3) 0.053(9) Uiso 1 1 d .
H19B H -0.2884(18) 0.0722(19) 0.052(3) 0.066(11) Uiso 1 1 d .
H19C H -0.270(2) 0.000(2) -0.039(4) 0.074(13) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0030 0.0020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0060 0.0030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0110 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1480 0.1590 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1180 0.9190 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1B Rh1 O1B 42.4(3) . 7_565
O1B Rh1 O1A 179.8(3) . 7_565
O1B Rh1 O1A 137.5(2) 7_565 7_565
O1B Rh1 O1A 137.5(2) . .
O1B Rh1 O1A 179.8(3) 7_565 .
O1A Rh1 O1A 42.6(3) 7_565 .
O1B Rh1 C6 87.37(17) . .
O1B Rh1 C6 87.37(17) 7_565 .
O1A Rh1 C6 92.83(17) 7_565 .
O1A Rh1 C6 92.83(17) . .
O1B Rh1 N1 91.07(17) . .
O1B Rh1 N1 91.07(17) 7_565 .
O1A Rh1 N1 88.73(17) 7_565 .
O1A Rh1 N1 88.73(17) . .
C6 Rh1 N1 178.33(12) . .
O1B Rh1 Cl1B 158.76(17) . .
O1B Rh1 Cl1B 158.76(17) 7_565 .
O1A Rh1 Cl1B 21.33(17) 7_565 .
O1A Rh1 Cl1B 21.33(17) . .
C6 Rh1 Cl1B 93.85(17) . .
N1 Rh1 Cl1B 87.83(17) . .
O1B Rh1 Cl1A 21.25(17) . .
O1B Rh1 Cl1A 21.25(17) 7_565 .
O1A Rh1 Cl1A 158.65(17) 7_565 .
O1A Rh1 Cl1A 158.65(17) . .
C6 Rh1 Cl1A 88.32(10) . .
N1 Rh1 Cl1A 90.01(10) . .
Cl1B Rh1 Cl1A 177.84(16) . .
O1B Cl1A O1B 112.5(8) 7_565 .
O1B Cl1A Rh1 56.4(4) 7_565 .
O1B Cl1A Rh1 56.4(4) . .
O1A Cl1B O1A 114.5(11) . 7_565
O1A Cl1B Rh1 57.3(6) . .
O1A Cl1B Rh1 57.3(6) 7_565 .
Cl1B O1A Rh1 101.3(6) . .
O1A O1A Rh1 68.69(17) 7_565 .
Cl1A O1B Rh1 102.4(5) . .
O1B O1B Rh1 68.78(17) 7_565 .
C5 N1 C1 117.2(4) . .
C5 N1 Rh1 122.2(3) . .
C1 N1 Rh1 120.7(3) . .
C6 N2 C7 110.80(19) . .
C6 N2 C8 125.13(18) . .
C7 N2 C8 123.65(19) . .
N1 C1 C2 122.8(6) . .
N1 C1 H1 110(3) . .
C2 C1 H1 127(3) . .
C3 C2 C1 120.8(7) . .
C3 C2 H2 123(4) . .
C1 C2 H2 117(4) . .
C2 C3 C4 117.5(6) . .
C2 C3 H3 121(4) . .
C4 C3 H3 122(4) . .
C3 C4 C5 120.1(6) . .
C3 C4 H4 126(4) . .
C5 C4 H4 114(4) . .
N1 C5 C4 121.7(6) . .
N1 C5 H5 116(3) . .
C4 C5 H5 122(3) . .
N2 C6 N2 104.3(3) 7_565 .
N2 C6 Rh1 127.71(13) 7_565 .
N2 C6 Rh1 127.71(13) . .
C7 C7 N2 107.07(13) 7_565 .
C7 C7 H7 130.8(17) 7_565 .
N2 C7 H7 122.1(17) . .
C9 C8 C13 122.9(2) . .
C9 C8 N2 119.5(2) . .
C13 C8 N2 117.5(2) . .
C10 C9 C8 117.0(2) . .
C10 C9 C17 120.3(2) . .
C8 C9 C17 122.6(2) . .
C11 C10 C9 121.4(2) . .
C11 C10 H10 121.7(15) . .
C9 C10 H10 116.7(15) . .
C10 C11 C12 120.6(2) . .
C10 C11 H11 118.0(18) . .
C12 C11 H11 121.4(18) . .
C11 C12 C13 121.2(3) . .
C11 C12 H12 122.0(19) . .
C13 C12 H12 116.8(19) . .
C12 C13 C8 116.8(2) . .
C12 C13 C14 120.7(2) . .
C8 C13 C14 122.5(2) . .
C13 C14 C16 110.6(2) . .
C13 C14 C15 113.1(2) . .
C16 C14 C15 109.8(3) . .
C13 C14 H14 108.8(14) . .
C16 C14 H14 108.2(15) . .
C15 C14 H14 106.1(15) . .
C14 C15 H15A 108(2) . .
C14 C15 H15B 111(2) . .
H15A C15 H15B 112(3) . .
C14 C15 H15C 112.0(19) . .
H15A C15 H15C 108(3) . .
H15B C15 H15C 107(3) . .
C14 C16 H16A 108.8(17) . .
C14 C16 H16B 113.7(17) . .
H16A C16 H16B 104(2) . .
C14 C16 H16C 107.6(19) . .
H16A C16 H16C 112(2) . .
H16B C16 H16C 111(3) . .
C9 C17 C18 113.3(2) . .
C9 C17 C19 109.8(2) . .
C18 C17 C19 110.3(3) . .
C9 C17 H17 109.7(16) . .
C18 C17 H17 106.9(16) . .
C19 C17 H17 106.5(15) . .
C17 C18 H18A 107.0(19) . .
C17 C18 H18B 108.2(19) . .
H18A C18 H18B 108(3) . .
C17 C18 H18C 109.6(18) . .
H18A C18 H18C 112(3) . .
H18B C18 H18C 112(3) . .
C17 C19 H19A 110.5(19) . .
C17 C19 H19B 111(2) . .
H19A C19 H19B 108(3) . .
C17 C19 H19C 107(2) . .
H19A C19 H19C 107(3) . .
H19B C19 H19C 113(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rh1 O1B 1.949(6) .
Rh1 O1B 1.949(6) 7_565
Rh1 O1A 1.959(5) 7_565
Rh1 O1A 1.959(5) .
Rh1 C6 1.984(3) .
Rh1 N1 2.146(3) .
Rh1 Cl1B 2.282(5) .
Rh1 Cl1A 2.287(2) .
Cl1A O1B 0.849(6) 7_565
Cl1A O1B 0.849(6) .
Cl1B O1A 0.846(6) .
Cl1B O1A 0.846(6) 7_565
O1A O1A 1.424(11) 7_565
O1B O1B 1.411(10) 7_565
N1 C5 1.332(5) .
N1 C1 1.338(5) .
N2 C6 1.361(3) .
N2 C7 1.383(3) .
N2 C8 1.457(3) .
C1 C2 1.361(7) .
C1 H1 0.82(4) .
C2 C3 1.343(10) .
C2 H2 0.90(6) .
C3 C4 1.369(10) .
C3 H3 0.89(7) .
C4 C5 1.388(7) .
C4 H4 0.80(5) .
C5 H5 0.88(4) .
C6 N2 1.361(3) 7_565
C7 C7 1.336(5) 7_565
C7 H7 0.86(2) .
C8 C9 1.398(3) .
C8 C13 1.407(3) .
C9 C10 1.393(4) .
C9 C17 1.513(4) .
C10 C11 1.365(4) .
C10 H10 0.94(2) .
C11 C12 1.381(4) .
C11 H11 0.91(3) .
C12 C13 1.391(3) .
C12 H12 0.93(3) .
C13 C14 1.516(3) .
C14 C16 1.523(4) .
C14 C15 1.523(4) .
C14 H14 0.96(2) .
C15 H15A 0.93(3) .
C15 H15B 0.89(3) .
C15 H15C 0.93(3) .
C16 H16A 0.94(3) .
C16 H16B 0.96(3) .
C16 H16C 0.95(3) .
C17 C18 1.524(4) .
C17 C19 1.526(4) .
C17 H17 0.95(2) .
C18 H18A 0.97(3) .
C18 H18B 0.93(3) .
C18 H18C 0.92(3) .
C19 H19A 0.92(3) .
C19 H19B 0.95(3) .
C19 H19C 0.94(3) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1B Rh1 Cl1A O1B 174.2(10) . 7_565
O1A Rh1 Cl1A O1B -6.4(7) 7_565 7_565
O1A Rh1 Cl1A O1B -179.5(6) . 7_565
C6 Rh1 Cl1A O1B 87.1(5) . 7_565
N1 Rh1 Cl1A O1B -92.9(5) . 7_565
O1B Rh1 Cl1A O1B -174.2(10) 7_565 .
O1A Rh1 Cl1A O1B 179.5(6) 7_565 .
O1A Rh1 Cl1A O1B 6.4(7) . .
C6 Rh1 Cl1A O1B -87.1(5) . .
N1 Rh1 Cl1A O1B 92.9(5) . .
O1B Rh1 Cl1B O1A -4.7(11) . .
O1B Rh1 Cl1B O1A -179.4(6) 7_565 .
O1A Rh1 Cl1B O1A 175.9(14) 7_565 .
C6 Rh1 Cl1B O1A 87.9(7) . .
N1 Rh1 Cl1B O1A -92.1(7) . .
O1B Rh1 Cl1B O1A 4.7(11) 7_565 7_565
O1A Rh1 Cl1B O1A -175.9(14) . 7_565
C6 Rh1 Cl1B O1A -87.9(7) . 7_565
N1 Rh1 Cl1B O1A 92.1(7) . 7_565
Rh1 Cl1B O1A O1A -3.8(13) . 7_565
O1A Cl1B O1A Rh1 3.8(13) 7_565 .
O1A Rh1 O1A Cl1B -2.2(8) 7_565 .
C6 Rh1 O1A Cl1B -93.3(7) . .
N1 Rh1 O1A Cl1B 87.3(7) . .
Cl1A Rh1 O1A Cl1B 174.1(4) . .
C6 Rh1 O1A O1A -91.11(7) . 7_565
N1 Rh1 O1A O1A 89.50(7) . 7_565
Cl1B Rh1 O1A O1A 2.2(8) . 7_565
Cl1A Rh1 O1A O1A 176.3(5) . 7_565
Rh1 Cl1A O1B O1B 5.3(9) . 7_565
O1B Cl1A O1B Rh1 -5.3(9) 7_565 .
O1B Rh1 O1B Cl1A 3.1(5) 7_565 .
O1A Rh1 O1B Cl1A -176.6(4) . .
C6 Rh1 O1B Cl1A 92.1(5) . .
N1 Rh1 O1B Cl1A -87.3(5) . .
Cl1B Rh1 O1B Cl1A -174.0(4) . .
O1A Rh1 O1B O1B -179.7(3) . 7_565
C6 Rh1 O1B O1B 88.98(7) . 7_565
N1 Rh1 O1B O1B -90.41(7) . 7_565
Cl1B Rh1 O1B O1B -177.2(6) . 7_565
Cl1A Rh1 O1B O1B -3.1(5) . 7_565
O1B Rh1 N1 C5 21.22(17) . .
O1B Rh1 N1 C5 -21.22(17) 7_565 .
O1A Rh1 N1 C5 -158.68(17) 7_565 .
O1A Rh1 N1 C5 158.68(17) . .
Cl1B Rh1 N1 C5 180.0 . .
Cl1A Rh1 N1 C5 0.0 . .
O1B Rh1 N1 C1 -158.78(17) . .
O1B Rh1 N1 C1 158.78(17) 7_565 .
O1A Rh1 N1 C1 21.32(17) 7_565 .
O1A Rh1 N1 C1 -21.32(17) . .
Cl1B Rh1 N1 C1 0.0 . .
Cl1A Rh1 N1 C1 180.0 . .
C5 N1 C1 C2 0.0 . .
Rh1 N1 C1 C2 180.0 . .
N1 C1 C2 C3 0.0 . .
C1 C2 C3 C4 0.0 . .
C2 C3 C4 C5 0.0 . .
C1 N1 C5 C4 0.0 . .
Rh1 N1 C5 C4 180.0 . .
C3 C4 C5 N1 0.0 . .
C7 N2 C6 N2 1.1(3) . 7_565
C8 N2 C6 N2 -171.68(14) . 7_565
C7 N2 C6 Rh1 -172.8(2) . .
C8 N2 C6 Rh1 14.4(4) . .
O1B Rh1 C6 N2 -107.5(3) . 7_565
O1B Rh1 C6 N2 -65.0(3) 7_565 7_565
O1A Rh1 C6 N2 72.4(3) 7_565 7_565
O1A Rh1 C6 N2 115.1(3) . 7_565
Cl1B Rh1 C6 N2 93.7(2) . 7_565
Cl1A Rh1 C6 N2 -86.3(2) . 7_565
O1B Rh1 C6 N2 65.0(3) . .
O1B Rh1 C6 N2 107.5(3) 7_565 .
O1A Rh1 C6 N2 -115.1(3) 7_565 .
O1A Rh1 C6 N2 -72.4(3) . .
Cl1B Rh1 C6 N2 -93.7(2) . .
Cl1A Rh1 C6 N2 86.3(2) . .
C6 N2 C7 C7 -0.7(2) . 7_565
C8 N2 C7 C7 172.21(17) . 7_565
C6 N2 C8 C9 -103.0(3) . .
C7 N2 C8 C9 85.1(3) . .
C6 N2 C8 C13 80.3(3) . .
C7 N2 C8 C13 -91.6(3) . .
C13 C8 C9 C10 -2.7(4) . .
N2 C8 C9 C10 -179.3(2) . .
C13 C8 C9 C17 174.9(2) . .
N2 C8 C9 C17 -1.7(3) . .
C8 C9 C10 C11 0.7(4) . .
C17 C9 C10 C11 -177.0(3) . .
C9 C10 C11 C12 1.2(4) . .
C10 C11 C12 C13 -1.2(4) . .
C11 C12 C13 C8 -0.7(4) . .
C11 C12 C13 C14 176.7(3) . .
C9 C8 C13 C12 2.8(4) . .
N2 C8 C13 C12 179.4(2) . .
C9 C8 C13 C14 -174.6(2) . .
N2 C8 C13 C14 2.1(3) . .
C12 C13 C14 C16 -87.3(3) . .
C8 C13 C14 C16 90.0(3) . .
C12 C13 C14 C15 36.4(4) . .
C8 C13 C14 C15 -146.4(3) . .
C10 C9 C17 C18 -48.2(3) . .
C8 C9 C17 C18 134.2(3) . .
C10 C9 C17 C19 75.6(3) . .
C8 C9 C17 C19 -102.0(3) . .
