#------------------------------------------------------------------------------
#$Date: 2025-08-21 16:10:22 +0300 (Thu, 21 Aug 2025) $
#$Revision: 301849 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/03/46/7034678.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7034678
loop_
_publ_author_name
'Guchhait, Tapas'
'Barua, Bhagyasree'
'Biswas, Aritra'
'Basak, Biswanath'
'Mani, Ganesan'
_publ_section_title
;
 Synthesis and structural characterization of silver(i), copper(i)
 coordination polymers and a helicate palladium(ii) complex of
 dipyrrolylmethane-based dipyrazole ligands: the effect of meso
 substituents on structural formation.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9091
_journal_page_last               9102
_journal_paper_doi               10.1039/c5dt00430f
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C51 H70 Ag2 B2 Cl2 F8 N12'
_chemical_formula_weight         1311.45
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-01-28 deposited with the CCDC.
2015-04-01 downloaded from the CCDC.
;
_cell_angle_alpha                94.048(5)
_cell_angle_beta                 95.837(5)
_cell_angle_gamma                105.845(5)
_cell_formula_units_Z            2
_cell_length_a                   13.881(5)
_cell_length_b                   14.747(5)
_cell_length_c                   14.992(5)
_cell_measurement_reflns_used    35491
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.00
_cell_measurement_theta_min      1.37
_cell_volume                     2921.4(17)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    sir92
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker CCD APEX 2'
_diffrn_measurement_method       hemisphere
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1623
_diffrn_reflns_av_sigmaI/netI    0.1939
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            35491
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.37
_exptl_absorpt_coefficient_mu    0.833
_exptl_absorpt_correction_T_max  0.9364
_exptl_absorpt_correction_T_min  0.9067
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.491
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1340
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.694
_refine_diff_density_min         -0.618
_refine_diff_density_rms         0.089
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.958
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     717
_refine_ls_number_reflns         10268
_refine_ls_number_restraints     79
_refine_ls_restrained_S_all      0.970
_refine_ls_R_factor_all          0.2173
_refine_ls_R_factor_gt           0.0709
_refine_ls_shift/su_max          0.019
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0630P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1354
_refine_ls_wR_factor_ref         0.1894
_reflns_number_gt                3780
_reflns_number_total             10268
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            c5dt00430f2.cif
_cod_data_source_block           complex4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 

 Adding full bibliography for 7034676--7034681.cif.
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7034678
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.8280(6) 0.2286(6) -0.0020(7) 0.045(2) Uani 1 1 d . . .
C2 C 0.8655(7) 0.2654(6) 0.0834(7) 0.062(3) Uani 1 1 d . . .
H2 H 0.8281 0.2782 0.1283 0.075 Uiso 1 1 calc R . .
C3 C 0.9726(7) 0.2813(6) 0.0934(6) 0.060(3) Uani 1 1 d . . .
H3 H 1.0172 0.3054 0.1457 0.072 Uiso 1 1 calc R . .
C4 C 0.9967(7) 0.2546(6) 0.0120(6) 0.043(2) Uani 1 1 d . . .
C5 C 0.7239(6) 0.2099(7) -0.0487(7) 0.066(3) Uani 1 1 d . . .
H5A H 0.6847 0.2365 -0.0096 0.079 Uiso 1 1 calc R . .
H5B H 0.7268 0.2427 -0.1027 0.079 Uiso 1 1 calc R . .
C6 C 0.6119(8) 0.0654(10) -0.1520(6) 0.061(3) Uani 1 1 d . . .
C7 C 0.6094(8) 0.1174(9) -0.2351(7) 0.108(4) Uani 1 1 d . . .
H7A H 0.6529 0.1809 -0.2219 0.162 Uiso 1 1 calc R . .
H7B H 0.5416 0.1192 -0.2531 0.162 Uiso 1 1 calc R . .
H7C H 0.6321 0.0851 -0.2830 0.162 Uiso 1 1 calc R . .
C8 C 0.5657(8) -0.0231(9) -0.1364(7) 0.067(3) Uani 1 1 d . . .
H8 H 0.5209 -0.0690 -0.1780 0.080 Uiso 1 1 calc R . .
C9 C 0.5957(7) -0.0351(8) -0.0480(7) 0.053(3) Uani 1 1 d . . .
C10 C 0.5667(7) -0.1187(7) 0.0028(7) 0.074(3) Uani 1 1 d . . .
H10A H 0.6014 -0.1036 0.0630 0.111 Uiso 1 1 calc R . .
H10B H 0.5848 -0.1706 -0.0265 0.111 Uiso 1 1 calc R . .
H10C H 0.4952 -0.1361 0.0050 0.111 Uiso 1 1 calc R . .
C11 C 0.7899(7) 0.0842(6) 0.3280(6) 0.052(3) Uani 1 1 d . . .
C12 C 0.6863(7) 0.0930(7) 0.3297(6) 0.073(3) Uani 1 1 d . . .
H12A H 0.6538 0.0872 0.2691 0.109 Uiso 1 1 calc R . .
H12B H 0.6894 0.1537 0.3596 0.109 Uiso 1 1 calc R . .
H12C H 0.6485 0.0438 0.3616 0.109 Uiso 1 1 calc R . .
C13 C 0.8646(7) 0.0874(6) 0.3989(6) 0.056(3) Uani 1 1 d . . .
H13 H 0.8603 0.0960 0.4603 0.067 Uiso 1 1 calc R . .
C14 C 0.9453(7) 0.0753(6) 0.3595(6) 0.051(2) Uani 1 1 d . . .
C15 C 1.0477(7) 0.0739(7) 0.4018(7) 0.083(3) Uani 1 1 d . . .
H15A H 1.0873 0.0632 0.3554 0.124 Uiso 1 1 calc R . .
H15B H 1.0404 0.0240 0.4405 0.124 Uiso 1 1 calc R . .
H15C H 1.0807 0.1336 0.4364 0.124 Uiso 1 1 calc R . .
C16 C 0.9825(6) 0.0617(7) 0.1966(6) 0.058(3) Uani 1 1 d . . .
H16A H 1.0451 0.0513 0.2222 0.070 Uiso 1 1 calc R . .
H16B H 0.9993 0.1228 0.1728 0.070 Uiso 1 1 calc R . .
C17 C 0.9356(6) -0.0132(7) 0.1201(6) 0.043(2) Uani 1 1 d . . .
C18 C 0.8913(7) -0.0053(7) 0.0373(7) 0.053(3) Uani 1 1 d . . .
H18 H 0.8799 0.0494 0.0168 0.064 Uiso 1 1 calc R . .
C19 C 0.8658(6) -0.0952(7) -0.0120(6) 0.048(2) Uani 1 1 d . . .
H19 H 0.8328 -0.1102 -0.0706 0.057 Uiso 1 1 calc R . .
C20 C 0.8971(6) -0.1573(7) 0.0400(6) 0.042(2) Uani 1 1 d . . .
C21 C 0.9002(6) -0.2585(6) 0.0172(5) 0.038(2) Uani 1 1 d . . .
C22 C 0.8175(6) -0.3067(6) -0.0605(6) 0.055(3) Uani 1 1 d . . .
H22A H 0.8263 -0.3677 -0.0800 0.066 Uiso 1 1 calc R . .
H22B H 0.8264 -0.2685 -0.1108 0.066 Uiso 1 1 calc R . .
C23 C 0.7091(7) -0.3219(7) -0.0380(7) 0.079(3) Uani 1 1 d . . .
H23A H 0.6623 -0.3521 -0.0902 0.119 Uiso 1 1 calc R . .
H23B H 0.6987 -0.2618 -0.0202 0.119 Uiso 1 1 calc R . .
H23C H 0.6984 -0.3614 0.0103 0.119 Uiso 1 1 calc R . .
C24 C 0.8863(6) -0.3127(6) 0.1023(6) 0.052(2) Uani 1 1 d . . .
H24A H 0.9397 -0.2803 0.1500 0.062 Uiso 1 1 calc R . .
H24B H 0.8225 -0.3113 0.1227 0.062 Uiso 1 1 calc R . .
C25 C 0.8877(7) -0.4158(6) 0.0855(7) 0.076(3) Uani 1 1 d . . .
H25A H 0.8788 -0.4457 0.1401 0.114 Uiso 1 1 calc R . .
H25B H 0.9512 -0.4176 0.0667 0.114 Uiso 1 1 calc R . .
H25C H 0.8340 -0.4487 0.0393 0.114 Uiso 1 1 calc R . .
C26 C 1.4619(7) 0.7464(6) 0.5380(6) 0.050(2) Uani 1 1 d . . .
C27 C 1.4294(7) 0.7693(7) 0.4567(7) 0.063(3) Uani 1 1 d . . .
H27 H 1.4699 0.7992 0.4156 0.076 Uiso 1 1 calc R . .
C28 C 1.3222(7) 0.7393(6) 0.4457(7) 0.056(3) Uani 1 1 d . . .
H28 H 1.2803 0.7469 0.3960 0.068 Uiso 1 1 calc R . .
C29 C 1.2912(7) 0.6977(7) 0.5195(7) 0.056(3) Uani 1 1 d . . .
C30 C 1.1881(8) 0.6651(8) 0.5440(7) 0.075(3) Uani 1 1 d . . .
H30A H 1.1865 0.6963 0.6028 0.090 Uiso 1 1 calc R . .
H30B H 1.1427 0.6847 0.5009 0.090 Uiso 1 1 calc R . .
C31 C 1.1063(9) 0.5146(15) 0.6109(10) 0.104(5) Uani 1 1 d . . .
C32 C 1.0907(10) 0.5592(14) 0.6987(9) 0.194(10) Uani 1 1 d . . .
H32A H 1.1189 0.6266 0.7021 0.291 Uiso 1 1 calc R . .
H32B H 1.1234 0.5349 0.7473 0.291 Uiso 1 1 calc R . .
H32C H 1.0197 0.5446 0.7033 0.291 Uiso 1 1 calc R . .
C33 C 1.0775(10) 0.4229(14) 0.5807(15) 0.124(7) Uani 1 1 d . . .
H33 H 1.0448 0.3732 0.6115 0.149 Uiso 1 1 calc R . .
C34 C 1.1052(8) 0.4155(10) 0.4952(13) 0.096(5) Uani 1 1 d . . .
C35 C 1.0963(9) 0.3337(9) 0.4298(14) 0.194(10) Uani 1 1 d . . .
H35A H 1.1228 0.3554 0.3760 0.292 Uiso 1 1 calc R . .
H35B H 1.0265 0.2984 0.4153 0.292 Uiso 1 1 calc R . .
H35C H 1.1337 0.2937 0.4553 0.292 Uiso 1 1 calc R . .
C36 C 1.2564(7) 0.5693(6) 0.1610(7) 0.057(3) Uani 1 1 d . . .
C37 C 1.1479(7) 0.5688(7) 0.1474(7) 0.071(3) Uani 1 1 d . . .
H37A H 1.1208 0.5628 0.2038 0.107 Uiso 1 1 calc R . .
H37B H 1.1105 0.5163 0.1047 0.107 Uiso 1 1 calc R . .
H37C H 1.1429 0.6270 0.1250 0.107 Uiso 1 1 calc R . .
C38 C 1.3259(8) 0.5774(6) 0.0996(6) 0.058(3) Uani 1 1 d . . .
H38 H 1.3152 0.5839 0.0385 0.069 Uiso 1 1 calc R . .
C39 C 1.4134(9) 0.5736(7) 0.1480(8) 0.064(3) Uani 1 1 d . . .
C40 C 1.5128(8) 0.5798(8) 0.1146(7) 0.094(4) Uani 1 1 d . . .
H40A H 1.5607 0.5745 0.1634 0.141 Uiso 1 1 calc R . .
H40B H 1.5370 0.6396 0.0910 0.141 Uiso 1 1 calc R . .
H40C H 1.5046 0.5293 0.0679 0.141 Uiso 1 1 calc R . .
C41 C 1.4659(7) 0.5638(7) 0.3120(6) 0.061(3) Uani 1 1 d . . .
H41A H 1.4773 0.6231 0.3495 0.073 Uiso 1 1 calc R . .
H41B H 1.5300 0.5622 0.2924 0.073 Uiso 1 1 calc R . .
C42 C 1.4324(7) 0.4838(7) 0.3682(6) 0.052(3) Uani 1 1 d . . .
C43 C 1.3902(7) 0.4816(8) 0.4459(6) 0.063(3) Uani 1 1 d . . .
H43 H 1.3732 0.5314 0.4758 0.076 Uiso 1 1 calc R . .
C44 C 1.3768(6) 0.3909(8) 0.4731(6) 0.055(3) Uani 1 1 d . . .
H44 H 1.3472 0.3693 0.5234 0.066 Uiso 1 1 calc R . .
C45 C 1.4146(6) 0.3383(7) 0.4131(6) 0.048(2) Uani 1 1 d . . .
C46 C 1.4311(6) 0.2408(7) 0.4152(6) 0.048(2) Uani 1 1 d . . .
C47 C 1.4226(7) 0.1920(7) 0.3191(6) 0.063(3) Uani 1 1 d . . .
H47A H 1.4375 0.1317 0.3228 0.076 Uiso 1 1 calc R . .
H47B H 1.4725 0.2311 0.2866 0.076 Uiso 1 1 calc R . .
C48 C 1.3164(7) 0.1748(7) 0.2661(6) 0.081(3) Uani 1 1 d . . .
H48A H 1.3147 0.1442 0.2070 0.121 Uiso 1 1 calc R . .
H48B H 1.3020 0.2344 0.2608 0.121 Uiso 1 1 calc R . .
H48C H 1.2669 0.1352 0.2975 0.121 Uiso 1 1 calc R . .
C49 C 1.3565(7) 0.1818(7) 0.4717(6) 0.068(3) Uani 1 1 d . . .
H49A H 1.2895 0.1857 0.4503 0.082 Uiso 1 1 calc R . .
H49B H 1.3730 0.2108 0.5335 0.082 Uiso 1 1 calc R . .
C50 C 1.3520(9) 0.0762(8) 0.4719(8) 0.103(4) Uani 1 1 d . . .
H50A H 1.3028 0.0465 0.5092 0.154 Uiso 1 1 calc R . .
H50B H 1.4170 0.0708 0.4951 0.154 Uiso 1 1 calc R . .
H50C H 1.3335 0.0457 0.4114 0.154 Uiso 1 1 calc R . .
C51 C 0.7583(9) -0.1779(8) 0.2888(10) 0.126(5) Uani 1 1 d . . .
H51A H 0.7881 -0.1312 0.3400 0.151 Uiso 1 1 calc R . .
H51B H 0.7992 -0.1621 0.2403 0.151 Uiso 1 1 calc R . .
N1 N 0.9095(5) 0.2223(5) -0.0469(5) 0.0430(18) Uani 1 1 d . . .
H1 H 0.9057 0.2015 -0.1025 0.052 Uiso 1 1 calc R . .
N2 N 0.6710(5) 0.1091(6) -0.0742(6) 0.059(2) Uani 1 1 d . . .
N3 N 0.6584(5) 0.0476(6) -0.0087(5) 0.048(2) Uani 1 1 d . . .
N4 N 0.8241(6) 0.0729(5) 0.2488(5) 0.050(2) Uani 1 1 d . . .
N5 N 0.9194(6) 0.0660(5) 0.2700(5) 0.0493(19) Uani 1 1 d . . .
N6 N 0.9389(5) -0.1038(5) 0.1221(5) 0.0451(19) Uani 1 1 d . . .
H6 H 0.9636 -0.1256 0.1681 0.054 Uiso 1 1 calc R . .
N7 N 1.3767(5) 0.7026(5) 0.5755(5) 0.0473(19) Uani 1 1 d . . .
H7 H 1.3773 0.6812 0.6274 0.057 Uiso 1 1 calc R . .
N8 N 1.1506(6) 0.5629(8) 0.5465(6) 0.062(2) Uani 1 1 d . . .
N9 N 1.1495(5) 0.5030(6) 0.4719(6) 0.059(2) Uani 1 1 d . . .
N10 N 1.2982(6) 0.5608(5) 0.2434(5) 0.058(2) Uani 1 1 d . . .
N11 N 1.3956(6) 0.5629(5) 0.2332(5) 0.055(2) Uani 1 1 d . . .
N12 N 1.4495(5) 0.3986(6) 0.3493(5) 0.050(2) Uani 1 1 d . . .
H12 H 1.4780 0.3841 0.3041 0.060 Uiso 1 1 calc R . .
Cl1 Cl 0.6393(4) -0.1719(3) 0.2552(3) 0.1531(16) Uani 1 1 d . . .
Cl2 Cl 0.7610(3) -0.2872(3) 0.3180(3) 0.1449(16) Uani 1 1 d . . .
Ag1 Ag 1.23665(6) 0.54547(6) 0.36580(5) 0.0770(3) Uani 1 1 d . . .
Ag2 Ag 0.75375(6) 0.07008(6) 0.11585(5) 0.0679(3) Uani 1 1 d . . .
B1 B 1.6239(8) 0.3541(9) 0.1783(9) 0.095(5) Uani 1 1 d D . .
B2 B 1.1020(8) -0.1663(8) 0.3123(8) 0.082(5) Uani 1 1 d D . .
F1 F 1.530(2) 0.347(4) 0.201(5) 0.145(4) Uani 0.123(9) 1 d PD A 1
F2 F 1.660(4) 0.443(2) 0.157(6) 0.135(4) Uani 0.123(9) 1 d PD A 1
F3 F 1.678(3) 0.445(2) 0.204(5) 0.169(5) Uani 0.123(9) 1 d PD A 1
F4 F 1.611(5) 0.298(5) 0.101(3) 0.180(5) Uani 0.123(9) 1 d PD A 1
F1' F 1.5262(6) 0.3460(7) 0.1614(6) 0.145(4) Uani 0.877(9) 1 d PD A 2
F2' F 1.6782(7) 0.3967(8) 0.1181(6) 0.135(4) Uani 0.877(9) 1 d PD A 2
F3' F 1.6511(7) 0.3949(9) 0.2626(5) 0.169(5) Uani 0.877(9) 1 d PD A 2
F4' F 1.6416(7) 0.2701(8) 0.1898(9) 0.180(5) Uani 0.877(9) 1 d PD A 2
F6 F 1.1670(6) -0.1169(7) 0.3793(5) 0.105(3) Uani 0.820(8) 1 d PD B 1
F7 F 1.0947(8) -0.2596(7) 0.3102(11) 0.194(7) Uani 0.820(8) 1 d PD B 1
F8 F 1.1358(7) -0.1465(12) 0.2329(6) 0.181(6) Uani 0.820(8) 1 d PD B 1
F6' F 1.111(2) -0.204(3) 0.3921(17) 0.105(3) Uani 0.180(8) 1 d PD B 2
F7' F 1.111(3) -0.228(5) 0.247(4) 0.194(7) Uani 0.180(8) 1 d PD B 2
F8' F 1.1674(16) -0.085(2) 0.296(3) 0.181(6) Uani 0.180(8) 1 d PD B 2
F5 F 1.0096(5) -0.1535(5) 0.3045(5) 0.131(3) Uani 1 1 d D B .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 C1 N1 107.2(8) . .
C2 C1 C5 129.3(9) . .
N1 C1 C5 123.0(9) . .
C1 C2 C3 108.5(9) . .
C1 C2 H2 125.8 . .
C3 C2 H2 125.8 . .
C4 C3 C2 106.9(8) . .
C4 C3 H3 126.6 . .
C2 C3 H3 126.6 . .
C3 C4 N1 108.4(8) . .
C3 C4 C21 129.7(8) . 2_755
N1 C4 C21 121.9(8) . 2_755
N2 C5 C1 114.5(8) . .
N2 C5 H5A 108.6 . .
C1 C5 H5A 108.6 . .
N2 C5 H5B 108.6 . .
C1 C5 H5B 108.6 . .
H5A C5 H5B 107.6 . .
C8 C6 N2 107.1(9) . .
C8 C6 C7 132.2(11) . .
N2 C6 C7 120.7(11) . .
C6 C7 H7A 109.5 . .
C6 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C6 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C6 C8 C9 108.6(10) . .
C6 C8 H8 125.7 . .
C9 C8 H8 125.7 . .
N3 C9 C8 108.2(10) . .
N3 C9 C10 121.4(9) . .
C8 C9 C10 130.4(11) . .
C9 C10 H10A 109.5 . .
C9 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C9 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
N4 C11 C13 110.2(8) . .
N4 C11 C12 119.6(9) . .
C13 C11 C12 130.2(9) . .
C11 C12 H12A 109.5 . .
C11 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C11 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C14 C13 C11 105.8(8) . .
C14 C13 H13 127.1 . .
C11 C13 H13 127.1 . .
N5 C14 C13 107.4(8) . .
N5 C14 C15 122.6(9) . .
C13 C14 C15 130.0(9) . .
C14 C15 H15A 109.5 . .
C14 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C14 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
N5 C16 C17 115.5(7) . .
N5 C16 H16A 108.4 . .
C17 C16 H16A 108.4 . .
N5 C16 H16B 108.4 . .
C17 C16 H16B 108.4 . .
H16A C16 H16B 107.5 . .
N6 C17 C18 107.6(8) . .
N6 C17 C16 122.6(9) . .
C18 C17 C16 129.6(9) . .
C17 C18 C19 107.4(9) . .
C17 C18 H18 126.3 . .
C19 C18 H18 126.3 . .
C20 C19 C18 109.3(8) . .
C20 C19 H19 125.4 . .
C18 C19 H19 125.4 . .
C19 C20 N6 104.4(8) . .
C19 C20 C21 131.3(8) . .
N6 C20 C21 124.0(8) . .
C20 C21 C4 107.9(6) . 2_755
C20 C21 C22 109.4(7) . .
C4 C21 C22 109.4(7) 2_755 .
C20 C21 C24 109.3(7) . .
C4 C21 C24 109.5(6) 2_755 .
C22 C21 C24 111.2(7) . .
C21 C22 C23 114.9(7) . .
C21 C22 H22A 108.5 . .
C23 C22 H22A 108.5 . .
C21 C22 H22B 108.5 . .
C23 C22 H22B 108.5 . .
H22A C22 H22B 107.5 . .
C22 C23 H23A 109.5 . .
C22 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C22 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C25 C24 C21 113.0(7) . .
C25 C24 H24A 109.0 . .
C21 C24 H24A 109.0 . .
C25 C24 H24B 109.0 . .
C21 C24 H24B 109.0 . .
H24A C24 H24B 107.8 . .
C24 C25 H25A 109.5 . .
C24 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
C24 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
C27 C26 N7 106.4(8) . .
C27 C26 C46 131.0(9) . 2_866
N7 C26 C46 122.6(8) . 2_866
C26 C27 C28 107.6(9) . .
C26 C27 H27 126.2 . .
C28 C27 H27 126.2 . .
C29 C28 C27 108.6(8) . .
C29 C28 H28 125.7 . .
C27 C28 H28 125.7 . .
C28 C29 N7 106.2(8) . .
C28 C29 C30 128.8(9) . .
N7 C29 C30 124.5(10) . .
N8 C30 C29 114.5(8) . .
N8 C30 H30A 108.6 . .
C29 C30 H30A 108.6 . .
N8 C30 H30B 108.6 . .
C29 C30 H30B 108.6 . .
H30A C30 H30B 107.6 . .
C33 C31 N8 107.9(16) . .
C33 C31 C32 127.7(18) . .
N8 C31 C32 124.4(18) . .
C31 C32 H32A 109.5 . .
C31 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
C31 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
C31 C33 C34 107.2(15) . .
C31 C33 H33 126.4 . .
C34 C33 H33 126.4 . .
N9 C34 C33 109.8(14) . .
N9 C34 C35 117.7(16) . .
C33 C34 C35 132.5(17) . .
C34 C35 H35A 109.5 . .
C34 C35 H35B 109.5 . .
H35A C35 H35B 109.5 . .
C34 C35 H35C 109.5 . .
H35A C35 H35C 109.5 . .
H35B C35 H35C 109.5 . .
N10 C36 C38 110.9(9) . .
N10 C36 C37 119.1(9) . .
C38 C36 C37 130.0(10) . .
C36 C37 H37A 109.5 . .
C36 C37 H37B 109.5 . .
H37A C37 H37B 109.5 . .
C36 C37 H37C 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
C39 C38 C36 105.5(9) . .
C39 C38 H38 127.3 . .
C36 C38 H38 127.3 . .
N11 C39 C38 107.8(9) . .
N11 C39 C40 124.5(10) . .
C38 C39 C40 127.7(10) . .
C39 C40 H40A 109.5 . .
C39 C40 H40B 109.5 . .
H40A C40 H40B 109.5 . .
C39 C40 H40C 109.5 . .
H40A C40 H40C 109.5 . .
H40B C40 H40C 109.5 . .
N11 C41 C42 114.8(8) . .
N11 C41 H41A 108.6 . .
C42 C41 H41A 108.6 . .
N11 C41 H41B 108.6 . .
C42 C41 H41B 108.6 . .
H41A C41 H41B 107.6 . .
C43 C42 N12 108.1(9) . .
C43 C42 C41 130.0(10) . .
N12 C42 C41 121.7(9) . .
C42 C43 C44 107.4(9) . .
C42 C43 H43 126.3 . .
C44 C43 H43 126.3 . .
C45 C44 C43 109.0(9) . .
C45 C44 H44 125.5 . .
C43 C44 H44 125.5 . .
C44 C45 N12 105.1(8) . .
C44 C45 C46 131.6(9) . .
N12 C45 C46 122.9(8) . .
C45 C46 C49 109.1(7) . .
C45 C46 C26 107.7(7) . 2_866
C49 C46 C26 108.0(8) . 2_866
C45 C46 C47 111.3(7) . .
C49 C46 C47 112.2(8) . .
C26 C46 C47 108.3(7) 2_866 .
C46 C47 C48 112.4(7) . .
C46 C47 H47A 109.1 . .
C48 C47 H47A 109.1 . .
C46 C47 H47B 109.1 . .
C48 C47 H47B 109.1 . .
H47A C47 H47B 107.8 . .
C47 C48 H48A 109.5 . .
C47 C48 H48B 109.5 . .
H48A C48 H48B 109.5 . .
C47 C48 H48C 109.5 . .
H48A C48 H48C 109.5 . .
H48B C48 H48C 109.5 . .
C46 C49 C50 116.8(9) . .
C46 C49 H49A 108.1 . .
C50 C49 H49A 108.1 . .
C46 C49 H49B 108.1 . .
C50 C49 H49B 108.1 . .
H49A C49 H49B 107.3 . .
C49 C50 H50A 109.5 . .
C49 C50 H50B 109.5 . .
H50A C50 H50B 109.5 . .
C49 C50 H50C 109.5 . .
H50A C50 H50C 109.5 . .
H50B C50 H50C 109.5 . .
Cl1 C51 Cl2 113.0(6) . .
Cl1 C51 H51A 109.0 . .
Cl2 C51 H51A 109.0 . .
Cl1 C51 H51B 109.0 . .
Cl2 C51 H51B 109.0 . .
H51A C51 H51B 107.8 . .
C4 N1 C1 109.1(7) . .
C4 N1 H1 125.4 . .
C1 N1 H1 125.4 . .
C6 N2 N3 109.3(8) . .
C6 N2 C5 129.8(10) . .
N3 N2 C5 119.5(8) . .
C9 N3 N2 106.7(8) . .
C9 N3 Ag2 127.0(7) . .
N2 N3 Ag2 124.2(6) . .
C11 N4 N5 105.3(7) . .
C11 N4 Ag2 129.9(7) . .
N5 N4 Ag2 124.8(6) . .
C14 N5 N4 111.3(7) . .
C14 N5 C16 129.3(8) . .
N4 N5 C16 118.9(7) . .
C17 N6 C20 111.3(7) . .
C17 N6 H6 124.4 . .
C20 N6 H6 124.4 . .
C29 N7 C26 111.2(8) . .
C29 N7 H7 124.4 . .
C26 N7 H7 124.4 . .
C31 N8 N9 110.9(12) . .
C31 N8 C30 129.2(13) . .
N9 N8 C30 119.6(8) . .
C34 N9 N8 104.1(10) . .
C34 N9 Ag1 130.8(10) . .
N8 N9 Ag1 123.1(7) . .
C36 N10 N11 104.8(7) . .
C36 N10 Ag1 130.8(7) . .
N11 N10 Ag1 124.4(6) . .
C39 N11 N10 111.0(8) . .
C39 N11 C41 129.1(9) . .
N10 N11 C41 119.5(8) . .
C42 N12 C45 110.3(8) . .
C42 N12 H12 124.8 . .
C45 N12 H12 124.8 . .
N10 Ag1 N9 166.8(3) . .
N4 Ag2 N3 168.6(3) . .
F2' B1 F1' 114.1(10) . .
F2' B1 F2 43(3) . .
F1' B1 F2 99(3) . .
F2' B1 F4' 110.2(11) . .
F1' B1 F4' 112.0(11) . .
F2 B1 F4' 147(2) . .
F2' B1 F3 65(3) . .
F1' B1 F3 112(3) . .
F2 B1 F3 31(5) . .
F4' B1 F3 133(3) . .
F2' B1 F1 136(4) . .
F1' B1 F1 25(3) . .
F2 B1 F1 106.3(18) . .
F4' B1 F1 106(3) . .
F3 B1 F1 105.9(18) . .
F2' B1 F3' 115.2(11) . .
F1' B1 F3' 105.2(10) . .
F2 B1 F3' 83(4) . .
F4' B1 F3' 99.1(11) . .
F3 B1 F3' 53(3) . .
F1 B1 F3' 82(3) . .
F2' B1 F4 68(3) . .
F1' B1 F4 86(3) . .
F2 B1 F4 106(5) . .
F4' B1 F4 67(3) . .
F3 B1 F4 133(4) . .
F1 B1 F4 105.9(18) . .
F3' B1 F4 165(3) . .
F6 B2 F7' 131.3(18) . .
F6 B2 F7 111.7(11) . .
F7' B2 F7 49(3) . .
F6 B2 F8 110.8(10) . .
F7' B2 F8 53(3) . .
F7 B2 F8 101.2(11) . .
F6 B2 F8' 62(2) . .
F7' B2 F8' 103(4) . .
F7 B2 F8' 139.1(19) . .
F8 B2 F8' 53.7(19) . .
F6 B2 F5 117.0(9) . .
F7' B2 F5 111.7(16) . .
F7 B2 F5 110.0(9) . .
F8 B2 F5 104.9(9) . .
F8' B2 F5 107.8(14) . .
F6 B2 F6' 60.7(18) . .
F7' B2 F6' 108(4) . .
F7 B2 F6' 61.5(18) . .
F8 B2 F6' 149.5(16) . .
F8' B2 F6' 122(3) . .
F5 B2 F6' 104.7(12) . .
F3 F2 B1 75(3) . .
F2 F3 B1 74(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.348(11) .
C1 N1 1.394(10) .
C1 C5 1.485(11) .
C2 C3 1.431(12) .
C2 H2 0.9300 .
C3 C4 1.358(11) .
C3 H3 0.9300 .
C4 N1 1.371(9) .
C4 C21 1.526(11) 2_755
C5 N2 1.471(11) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C6 C8 1.337(13) .
C6 N2 1.364(11) .
C6 C7 1.510(13) .
C7 H7A 0.9600 .
C7 H7B 0.9600 .
C7 H7C 0.9600 .
C8 C9 1.387(12) .
C8 H8 0.9300 .
C9 N3 1.344(11) .
C9 C10 1.478(12) .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
C11 N4 1.339(10) .
C11 C13 1.396(11) .
C11 C12 1.482(12) .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C13 C14 1.364(11) .
C13 H13 0.9300 .
C14 N5 1.341(10) .
C14 C15 1.502(12) .
C15 H15A 0.9600 .
C15 H15B 0.9600 .
C15 H15C 0.9600 .
C16 N5 1.483(10) .
C16 C17 1.495(11) .
C16 H16A 0.9700 .
C16 H16B 0.9700 .
C17 N6 1.352(10) .
C17 C18 1.355(11) .
C18 C19 1.408(11) .
C18 H18 0.9300 .
C19 C20 1.373(11) .
C19 H19 0.9300 .
C20 N6 1.393(10) .
C20 C21 1.521(11) .
C21 C4 1.526(11) 2_755
C21 C22 1.531(11) .
C21 C24 1.553(11) .
C22 C23 1.535(11) .
C22 H22A 0.9700 .
C22 H22B 0.9700 .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
C24 C25 1.529(11) .
C24 H24A 0.9700 .
C24 H24B 0.9700 .
C25 H25A 0.9600 .
C25 H25B 0.9600 .
C25 H25C 0.9600 .
C26 C27 1.353(11) .
C26 N7 1.380(10) .
C26 C46 1.533(12) 2_866
C27 C28 1.420(11) .
C27 H27 0.9300 .
C28 C29 1.356(12) .
C28 H28 0.9300 .
C29 N7 1.363(10) .
C29 C30 1.473(12) .
C30 N8 1.458(12) .
C30 H30A 0.9700 .
C30 H30B 0.9700 .
C31 C33 1.332(19) .
C31 N8 1.339(14) .
C31 C32 1.49(2) .
C32 H32A 0.9600 .
C32 H32B 0.9600 .
C32 H32C 0.9600 .
C33 C34 1.381(19) .
C33 H33 0.9300 .
C34 N9 1.356(14) .
C34 C35 1.470(19) .
C35 H35A 0.9600 .
C35 H35B 0.9600 .
C35 H35C 0.9600 .
C36 N10 1.340(11) .
C36 C38 1.388(12) .
C36 C37 1.496(12) .
C37 H37A 0.9600 .
C37 H37B 0.9600 .
C37 H37C 0.9600 .
C38 C39 1.366(13) .
C38 H38 0.9300 .
C39 N11 1.338(11) .
C39 C40 1.498(13) .
C40 H40A 0.9600 .
C40 H40B 0.9600 .
C40 H40C 0.9600 .
C41 N11 1.450(10) .
C41 C42 1.496(12) .
C41 H41A 0.9700 .
C41 H41B 0.9700 .
C42 C43 1.356(12) .
C42 N12 1.358(10) .
C43 C44 1.396(12) .
C43 H43 0.9300 .
C44 C45 1.381(11) .
C44 H44 0.9300 .
C45 N12 1.385(10) .
C45 C46 1.518(12) .
C46 C49 1.528(11) .
C46 C26 1.533(11) 2_866
C46 C47 1.543(11) .
C47 C48 1.548(11) .
C47 H47A 0.9700 .
C47 H47B 0.9700 .
C48 H48A 0.9600 .
C48 H48B 0.9600 .
C48 H48C 0.9600 .
C49 C50 1.542(13) .
C49 H49A 0.9700 .
C49 H49B 0.9700 .
C50 H50A 0.9600 .
C50 H50B 0.9600 .
C50 H50C 0.9600 .
C51 Cl1 1.705(13) .
C51 Cl2 1.709(12) .
C51 H51A 0.9700 .
C51 H51B 0.9700 .
N1 H1 0.8600 .
N2 N3 1.375(9) .
N3 Ag2 2.126(7) .
N4 N5 1.360(9) .
N4 Ag2 2.121(7) .
N6 H6 0.8600 .
N7 H7 0.8600 .
N8 N9 1.373(10) .
N9 Ag1 2.122(8) .
N10 N11 1.368(9) .
N10 Ag1 2.102(8) .
N12 H12 0.8600 .
B1 F2' 1.318(11) .
B1 F1' 1.325(10) .
B1 F2 1.348(16) .
B1 F4' 1.345(11) .
B1 F3 1.350(16) .
B1 F1 1.356(16) .
B1 F3' 1.331(12) .
B1 F4 1.344(16) .
B2 F6 1.306(10) .
B2 F7' 1.319(16) .
B2 F7 1.350(11) .
B2 F8 1.345(11) .
B2 F8' 1.343(16) .
B2 F5 1.340(9) .
B2 F6' 1.364(15) .
F2 F3 0.72(10) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 C1 C2 C3 -1.0(10) . .
C5 C1 C2 C3 -172.3(9) . .
C1 C2 C3 C4 1.0(11) . .
C2 C3 C4 N1 -0.6(10) . .
C2 C3 C4 C21 178.2(8) . 2_755
C2 C1 C5 N2 -114.3(11) . .
N1 C1 C5 N2 75.6(11) . .
N2 C6 C8 C9 0.3(11) . .
C7 C6 C8 C9 179.1(9) . .
C6 C8 C9 N3 1.7(10) . .
C6 C8 C9 C10 179.7(9) . .
N4 C11 C13 C14 -1.4(11) . .
C12 C11 C13 C14 179.9(9) . .
C11 C13 C14 N5 0.3(10) . .
C11 C13 C14 C15 178.9(9) . .
N5 C16 C17 N6 -84.3(10) . .
N5 C16 C17 C18 101.4(11) . .
N6 C17 C18 C19 0.8(9) . .
C16 C17 C18 C19 175.8(8) . .
C17 C18 C19 C20 -1.7(10) . .
C18 C19 C20 N6 1.8(9) . .
C18 C19 C20 C21 -171.8(8) . .
C19 C20 C21 C4 91.1(10) . 2_755
N6 C20 C21 C4 -81.4(9) . 2_755
C19 C20 C21 C22 -27.8(12) . .
N6 C20 C21 C22 159.6(7) . .
C19 C20 C21 C24 -149.9(9) . .
N6 C20 C21 C24 37.5(10) . .
C20 C21 C22 C23 -66.2(9) . .
C4 C21 C22 C23 175.7(7) 2_755 .
C24 C21 C22 C23 54.7(10) . .
C20 C21 C24 C25 179.7(7) . .
C4 C21 C24 C25 -62.3(9) 2_755 .
C22 C21 C24 C25 58.7(9) . .
N7 C26 C27 C28 0.5(10) . .
C46 C26 C27 C28 178.5(9) 2_866 .
C26 C27 C28 C29 -0.8(11) . .
C27 C28 C29 N7 0.7(10) . .
C27 C28 C29 C30 172.6(10) . .
C28 C29 C30 N8 115.0(12) . .
N7 C29 C30 N8 -74.5(12) . .
N8 C31 C33 C34 0.0(16) . .
C32 C31 C33 C34 178.1(11) . .
C31 C33 C34 N9 -1.2(16) . .
C31 C33 C34 C35 178.0(13) . .
N10 C36 C38 C39 -0.1(11) . .
C37 C36 C38 C39 -180.0(9) . .
C36 C38 C39 N11 0.7(11) . .
C36 C38 C39 C40 -179.6(10) . .
N11 C41 C42 C43 -100.2(12) . .
N11 C41 C42 N12 85.6(10) . .
N12 C42 C43 C44 -2.8(10) . .
C41 C42 C43 C44 -177.6(9) . .
C42 C43 C44 C45 2.2(11) . .
C43 C44 C45 N12 -0.7(10) . .
C43 C44 C45 C46 171.9(8) . .
C44 C45 C46 C49 26.7(13) . .
N12 C45 C46 C49 -161.8(8) . .
C44 C45 C46 C26 -90.4(11) . 2_866
N12 C45 C46 C26 81.1(10) . 2_866
C44 C45 C46 C47 151.0(9) . .
N12 C45 C46 C47 -37.5(11) . .
C45 C46 C47 C48 -62.2(10) . .
C49 C46 C47 C48 60.3(11) . .
C26 C46 C47 C48 179.5(8) 2_866 .
C45 C46 C49 C50 172.4(8) . .
C26 C46 C49 C50 -70.8(10) 2_866 .
C47 C46 C49 C50 48.6(11) . .
C3 C4 N1 C1 0.0(9) . .
C21 C4 N1 C1 -178.9(7) 2_755 .
C2 C1 N1 C4 0.6(9) . .
C5 C1 N1 C4 172.6(8) . .
C8 C6 N2 N3 -2.1(10) . .
C7 C6 N2 N3 178.9(8) . .
C8 C6 N2 C5 -168.2(9) . .
C7 C6 N2 C5 12.9(14) . .
C1 C5 N2 C6 -137.5(9) . .
C1 C5 N2 N3 57.7(11) . .
C8 C9 N3 N2 -3.0(9) . .
C10 C9 N3 N2 178.9(7) . .
C8 C9 N3 Ag2 -166.5(6) . .
C10 C9 N3 Ag2 15.4(11) . .
C6 N2 N3 C9 3.2(9) . .
C5 N2 N3 C9 170.9(7) . .
C6 N2 N3 Ag2 167.3(6) . .
C5 N2 N3 Ag2 -25.0(10) . .
C13 C11 N4 N5 1.8(10) . .
C12 C11 N4 N5 -179.3(8) . .
C13 C11 N4 Ag2 -176.2(6) . .
C12 C11 N4 Ag2 2.7(13) . .
C13 C14 N5 N4 0.8(10) . .
C15 C14 N5 N4 -177.9(8) . .
C13 C14 N5 C16 172.7(8) . .
C15 C14 N5 C16 -6.0(14) . .
C11 N4 N5 C14 -1.6(9) . .
Ag2 N4 N5 C14 176.5(6) . .
C11 N4 N5 C16 -174.4(7) . .
Ag2 N4 N5 C16 3.7(10) . .
C17 C16 N5 C14 135.5(9) . .
C17 C16 N5 N4 -53.1(11) . .
C18 C17 N6 C20 0.3(9) . .
C16 C17 N6 C20 -175.1(7) . .
C19 C20 N6 C17 -1.4(9) . .
C21 C20 N6 C17 172.9(7) . .
C28 C29 N7 C26 -0.4(10) . .
C30 C29 N7 C26 -172.7(9) . .
C27 C26 N7 C29 -0.1(10) . .
C46 C26 N7 C29 -178.3(8) 2_866 .
C33 C31 N8 N9 1.2(14) . .
C32 C31 N8 N9 -177.0(10) . .
C33 C31 N8 C30 175.0(10) . .
C32 C31 N8 C30 -3.1(17) . .
C29 C30 N8 C31 131.0(11) . .
C29 C30 N8 N9 -55.6(11) . .
C33 C34 N9 N8 1.8(12) . .
C35 C34 N9 N8 -177.5(9) . .
C33 C34 N9 Ag1 165.6(8) . .
C35 C34 N9 Ag1 -13.8(15) . .
C31 N8 N9 C34 -1.8(10) . .
C30 N8 N9 C34 -176.4(8) . .
C31 N8 N9 Ag1 -167.2(7) . .
C30 N8 N9 Ag1 18.3(10) . .
C38 C36 N10 N11 -0.5(10) . .
C37 C36 N10 N11 179.4(8) . .
C38 C36 N10 Ag1 -179.7(6) . .
C37 C36 N10 Ag1 0.2(13) . .
C38 C39 N11 N10 -1.0(11) . .
C40 C39 N11 N10 179.2(9) . .
C38 C39 N11 C41 -173.7(9) . .
C40 C39 N11 C41 6.5(16) . .
C36 N10 N11 C39 0.9(10) . .
Ag1 N10 N11 C39 -179.8(6) . .
C36 N10 N11 C41 174.4(8) . .
Ag1 N10 N11 C41 -6.3(11) . .
C42 C41 N11 C39 -132.2(10) . .
C42 C41 N11 N10 55.6(11) . .
C43 C42 N12 C45 2.4(10) . .
C41 C42 N12 C45 177.7(7) . .
C44 C45 N12 C42 -1.0(9) . .
C46 C45 N12 C42 -174.4(8) . .
C36 N10 Ag1 N9 55.0(17) . .
N11 N10 Ag1 N9 -124.2(13) . .
C34 N9 Ag1 N10 40.5(18) . .
N8 N9 Ag1 N10 -158.3(11) . .
C11 N4 Ag2 N3 -49.4(18) . .
N5 N4 Ag2 N3 132.9(13) . .
C9 N3 Ag2 N4 -39.5(18) . .
N2 N3 Ag2 N4 159.7(12) . .
F2' B1 F2 F3 -125(6) . .
F1' B1 F2 F3 118(5) . .
F4' B1 F2 F3 -82(8) . .
F1 B1 F2 F3 94(3) . .
F3' B1 F2 F3 14(5) . .
F4 B1 F2 F3 -154(4) . .
F2' B1 F3 F2 38(4) . .
F1' B1 F3 F2 -69(5) . .
F4' B1 F3 F2 133(5) . .
F1 B1 F3 F2 -95(3) . .
F3' B1 F3 F2 -163(6) . .
F4 B1 F3 F2 35(6) . .
loop_
_cod_related_entry_id
_cod_related_entry_database
_cod_related_entry_code
1 PubChem 139166148
