#------------------------------------------------------------------------------
#$Date: 2016-02-13 14:50:18 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176428 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/48/7034810.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7034810
loop_
_publ_author_name
'Li, Zuo-Xi'
'Ye, Gan'
'Han, Juan'
'Yang, Ying'
'Zou, Kang-Yu'
'Wang, Xin'
'Wang, Xiao-Ling'
'Gou, Xiao-Feng'
_publ_section_title
;
 1D-3D mixed-ligand frameworks with an unusual dmp topology tuned by
 intersection angles of isomeric benzenedicarboxylates: magnetic
 properties, gas-dependent calcination-thermolysis and energy storage
 performances.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9209
_journal_page_last               9220
_journal_paper_doi               10.1039/c5dt00963d
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C26 H18 Co N4 O4'
_chemical_formula_weight         509.37
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2014-09-14 deposited with the CCDC.
2015-04-24 downloaded from the CCDC.
;
_cell_angle_alpha                92.603(6)
_cell_angle_beta                 92.028(6)
_cell_angle_gamma                97.537(7)
_cell_formula_units_Z            2
_cell_length_a                   9.990(4)
_cell_length_b                   10.046(4)
_cell_length_c                   11.176(5)
_cell_measurement_reflns_used    4530
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.67
_cell_measurement_theta_min      2.7
_cell_volume                     1109.8(8)
_computing_cell_refinement       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_collection       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 9
_diffrn_measured_fraction_theta_full 0.972
_diffrn_measured_fraction_theta_max 0.972
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0186
_diffrn_reflns_av_sigmaI/netI    0.0303
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            8467
_diffrn_reflns_theta_full        28.80
_diffrn_reflns_theta_max         28.80
_diffrn_reflns_theta_min         3.09
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.816
_exptl_absorpt_correction_T_max  0.843
_exptl_absorpt_correction_T_min  0.783
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   CrystalClear
_exptl_crystal_colour            pink
_exptl_crystal_density_diffrn    1.524
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             522
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.21
_refine_diff_density_max         0.331
_refine_diff_density_min         -0.334
_refine_diff_density_rms         0.070
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.088
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     316
_refine_ls_number_reflns         5639
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.088
_refine_ls_R_factor_all          0.0408
_refine_ls_R_factor_gt           0.0345
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0487P)²+0.2957P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0898
_refine_ls_wR_factor_ref         0.0939
_reflns_number_gt                4961
_reflns_number_total             5639
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5dt00963d2.cif
_cod_data_source_block           2
_cod_depositor_comments
'Adding full bibliography for 7034809--7034811.cif.'
_cod_original_cell_volume        1109.9(8)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7034810
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Co1 Co 0.48352(2) 0.319725(19) 0.383280(18) 0.02580(8) Uani 1 1 d .
N1 N 0.66920(16) 0.38007(15) 0.29891(13) 0.0351(3) Uani 1 1 d .
N2 N 0.81517(15) 0.50088(15) 0.18927(13) 0.0344(3) Uani 1 1 d .
N3 N 1.15941(14) 1.16309(15) -0.39978(13) 0.0335(3) Uani 1 1 d .
N4 N 1.30146(15) 1.26524(15) -0.52408(13) 0.0332(3) Uani 1 1 d .
O1 O 0.41129(13) 0.61717(12) 0.46082(10) 0.0362(3) Uani 1 1 d .
O2 O 0.40823(13) 0.47572(11) 0.30217(11) 0.0351(3) Uani 1 1 d .
O3 O 0.51817(12) 1.10867(11) 0.38985(10) 0.0320(2) Uani 1 1 d .
O4 O 0.41613(13) 1.17787(11) 0.23156(11) 0.0342(3) Uani 1 1 d .
C1 C 0.68519(18) 0.47599(19) 0.22250(16) 0.0371(4) Uani 1 1 d .
H1 H 0.6159 0.5213 0.1946 0.045 Uiso 1 1 calc R
C2 C 0.7949(2) 0.3419(2) 0.31655(19) 0.0459(5) Uani 1 1 d .
H2 H 0.8148 0.2751 0.3667 0.055 Uiso 1 1 calc R
C3 C 0.8861(2) 0.4153(2) 0.25063(19) 0.0469(5) Uani 1 1 d .
H3 H 0.9780 0.4091 0.2476 0.056 Uiso 1 1 calc R
C4 C 0.86446(17) 0.59897(17) 0.10730(15) 0.0327(3) Uani 1 1 d .
C5 C 0.77709(19) 0.6410(2) 0.02325(19) 0.0459(5) Uani 1 1 d .
H5 H 0.6862 0.6054 0.0203 0.055 Uiso 1 1 calc R
C6 C 0.82344(19) 0.7361(2) -0.05685(19) 0.0466(5) Uani 1 1 d .
H6 H 0.7630 0.7634 -0.1129 0.056 Uiso 1 1 calc R
C7 C 0.95864(16) 0.79138(17) -0.05509(15) 0.0319(3) Uani 1 1 d .
C8 C 1.04409(19) 0.7483(3) 0.03068(19) 0.0540(6) Uani 1 1 d .
H8 H 1.1349 0.7843 0.0346 0.065 Uiso 1 1 calc R
C9 C 0.99855(19) 0.6530(3) 0.11096(19) 0.0539(6) Uani 1 1 d .
H9 H 1.0586 0.6256 0.1673 0.065 Uiso 1 1 calc R
C10 C 1.00956(16) 0.89090(17) -0.14350(15) 0.0313(3) Uani 1 1 d .
C11 C 0.92581(19) 0.9257(3) -0.23503(19) 0.0515(6) Uani 1 1 d .
H11 H 0.8354 0.8883 -0.2400 0.062 Uiso 1 1 calc R
C12 C 0.9739(2) 1.0150(3) -0.31945(19) 0.0531(6) Uani 1 1 d .
H12 H 0.9159 1.0372 -0.3802 0.064 Uiso 1 1 calc R
C13 C 1.10763(17) 1.07081(17) -0.31323(15) 0.0325(3) Uani 1 1 d .
C14 C 1.19260(18) 1.0394(2) -0.22277(19) 0.0460(5) Uani 1 1 d .
H14 H 1.2826 1.0780 -0.2175 0.055 Uiso 1 1 calc R
C15 C 1.14333(19) 0.9498(2) -0.13937(19) 0.0486(5) Uani 1 1 d .
H15 H 1.2017 0.9283 -0.0787 0.058 Uiso 1 1 calc R
C16 C 1.27756(17) 1.16208(17) -0.45564(15) 0.0326(3) Uani 1 1 d .
H16 H 1.3346 1.0968 -0.4468 0.039 Uiso 1 1 calc R
C17 C 1.1049(2) 1.2742(2) -0.43654(19) 0.0454(5) Uani 1 1 d .
H17 H 1.0234 1.3013 -0.4143 0.054 Uiso 1 1 calc R
C18 C 1.1935(2) 1.3357(2) -0.51127(19) 0.0435(4) Uani 1 1 d .
H18 H 1.1830 1.4147 -0.5488 0.052 Uiso 1 1 calc R
C19 C 0.40738(15) 0.70527(14) 0.26767(13) 0.0253(3) Uani 1 1 d .
C20 C 0.42233(15) 0.83710(14) 0.31517(13) 0.0235(3) Uani 1 1 d .
H20 H 0.4280 0.8542 0.3978 0.028 Uiso 1 1 calc R
C21 C 0.42869(14) 0.94305(14) 0.23928(13) 0.0230(3) Uani 1 1 d .
C22 C 0.41600(16) 0.91771(16) 0.11584(14) 0.0287(3) Uani 1 1 d .
H22 H 0.4154 0.9887 0.0653 0.034 Uiso 1 1 calc R
C23 C 0.40423(19) 0.78675(17) 0.06791(14) 0.0352(4) Uani 1 1 d .
H23 H 0.3992 0.7700 -0.0148 0.042 Uiso 1 1 calc R
C24 C 0.40002(18) 0.68100(16) 0.14369(15) 0.0327(3) Uani 1 1 d .
H24 H 0.3922 0.5932 0.1116 0.039 Uiso 1 1 calc R
C25 C 0.40909(15) 0.59122(15) 0.35051(14) 0.0263(3) Uani 1 1 d .
C26 C 0.45572(15) 1.08509(14) 0.28963(13) 0.0238(3) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Co1 O2 111.70(5) 2_666 .
O1 Co1 N1 85.35(6) 2_666 .
O2 Co1 N1 87.21(6) . .
O1 Co1 N4 91.84(6) 2_666 1_446
O2 Co1 N4 93.05(6) . 1_446
N1 Co1 N4 177.07(6) . 1_446
O1 Co1 O4 155.15(5) 2_666 1_545
O2 Co1 O4 92.50(5) . 1_545
N1 Co1 O4 90.48(6) . 1_545
N4 Co1 O4 92.43(6) 1_446 1_545
O1 Co1 O3 95.75(5) 2_666 1_545
O2 Co1 O3 152.51(5) . 1_545
N1 Co1 O3 93.78(5) . 1_545
N4 Co1 O3 87.33(5) 1_446 1_545
O4 Co1 O3 60.04(5) 1_545 1_545
O1 Co1 C26 125.80(5) 2_666 1_545
O2 Co1 C26 122.41(5) . 1_545
N1 Co1 C26 93.99(5) . 1_545
N4 Co1 C26 88.33(5) 1_446 1_545
O4 Co1 C26 30.02(4) 1_545 1_545
O3 Co1 C26 30.09(5) 1_545 1_545
C1 N1 C2 105.27(15) . .
C1 N1 Co1 123.81(13) . .
C2 N1 Co1 130.69(12) . .
C1 N2 C3 106.46(15) . .
C1 N2 C4 125.19(15) . .
C3 N2 C4 128.34(15) . .
C16 N3 C17 106.63(14) . .
C16 N3 C13 125.92(15) . .
C17 N3 C13 127.31(15) . .
C16 N4 C18 105.33(14) . .
C16 N4 Co1 125.83(12) . 1_664
C18 N4 Co1 128.45(12) . 1_664
C25 O1 Co1 149.92(12) . 2_666
C25 O2 Co1 124.36(11) . .
C26 O3 Co1 88.96(9) . 1_565
C26 O4 Co1 89.22(10) . 1_565
N1 C1 N2 111.82(16) . .
N1 C1 H1 124.1 . .
N2 C1 H1 124.1 . .
C3 C2 N1 110.41(17) . .
C3 C2 H2 124.8 . .
N1 C2 H2 124.8 . .
C2 C3 N2 106.03(17) . .
C2 C3 H3 127.0 . .
N2 C3 H3 127.0 . .
C9 C4 C5 119.10(16) . .
C9 C4 N2 121.01(16) . .
C5 C4 N2 119.89(16) . .
C4 C5 C6 120.54(17) . .
C4 C5 H5 119.7 . .
C6 C5 H5 119.7 . .
C5 C6 C7 121.26(18) . .
C5 C6 H6 119.4 . .
C7 C6 H6 119.4 . .
C8 C7 C6 117.10(16) . .
C8 C7 C10 121.54(16) . .
C6 C7 C10 121.36(16) . .
C7 C8 C9 121.99(18) . .
C7 C8 H8 119.0 . .
C9 C8 H8 119.0 . .
C4 C9 C8 120.01(18) . .
C4 C9 H9 120.0 . .
C8 C9 H9 120.0 . .
C11 C10 C15 117.23(16) . .
C11 C10 C7 121.26(15) . .
C15 C10 C7 121.49(16) . .
C10 C11 C12 121.39(17) . .
C10 C11 H11 119.3 . .
C12 C11 H11 119.3 . .
C13 C12 C11 119.86(18) . .
C13 C12 H12 120.1 . .
C11 C12 H12 120.1 . .
C14 C13 C12 120.04(16) . .
C14 C13 N3 119.21(15) . .
C12 C13 N3 120.74(16) . .
C13 C14 C15 119.45(17) . .
C13 C14 H14 120.3 . .
C15 C14 H14 120.3 . .
C14 C15 C10 122.02(17) . .
C14 C15 H15 119.0 . .
C10 C15 H15 119.0 . .
N4 C16 N3 111.51(15) . .
N4 C16 H16 124.2 . .
N3 C16 H16 124.2 . .
C18 C17 N3 106.16(16) . .
C18 C17 H17 126.9 . .
N3 C17 H17 126.9 . .
C17 C18 N4 110.36(17) . .
C17 C18 H18 124.8 . .
N4 C18 H18 124.8 . .
C20 C19 C24 119.46(13) . .
C20 C19 C25 119.65(13) . .
C24 C19 C25 120.76(14) . .
C21 C20 C19 120.02(14) . .
C21 C20 H20 120.0 . .
C19 C20 H20 120.0 . .
C20 C21 C22 120.11(14) . .
C20 C21 C26 120.17(13) . .
C22 C21 C26 119.66(13) . .
C23 C22 C21 120.10(14) . .
C23 C22 H22 119.9 . .
C21 C22 H22 119.9 . .
C24 C23 C22 119.73(15) . .
C24 C23 H23 120.1 . .
C22 C23 H23 120.1 . .
C23 C24 C19 120.51(15) . .
C23 C24 H24 119.7 . .
C19 C24 H24 119.7 . .
O1 C25 O2 124.74(14) . .
O1 C25 C19 118.53(14) . .
O2 C25 C19 116.74(14) . .
O4 C26 O3 121.49(14) . .
O4 C26 C21 119.66(14) . .
O3 C26 C21 118.84(13) . .
O4 C26 Co1 60.77(8) . 1_565
O3 C26 Co1 60.95(8) . 1_565
C21 C26 Co1 175.29(10) . 1_565
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Co1 O1 2.0340(14) 2_666
Co1 O2 2.0575(13) .
Co1 N1 2.1398(16) .
Co1 N4 2.1456(15) 1_446
Co1 O4 2.1927(14) 1_545
Co1 O3 2.1967(14) 1_545
Co1 C26 2.5124(17) 1_545
N1 C1 1.314(2) .
N1 C2 1.370(3) .
N2 C1 1.358(2) .
N2 C3 1.375(2) .
N2 C4 1.428(2) .
N3 C16 1.356(2) .
N3 C17 1.377(2) .
N3 C13 1.433(2) .
N4 C16 1.318(2) .
N4 C18 1.374(2) .
N4 Co1 2.1456(15) 1_664
O1 C25 1.247(2) .
O1 Co1 2.0341(14) 2_666
O2 C25 1.2563(19) .
O3 C26 1.2600(19) .
O3 Co1 2.1967(14) 1_565
O4 C26 1.2569(18) .
O4 Co1 2.1926(14) 1_565
C1 H1 0.9300 .
C2 C3 1.356(3) .
C2 H2 0.9300 .
C3 H3 0.9300 .
C4 C9 1.376(3) .
C4 C5 1.378(3) .
C5 C6 1.385(3) .
C5 H5 0.9300 .
C6 C7 1.391(2) .
C6 H6 0.9300 .
C7 C8 1.383(3) .
C7 C10 1.492(2) .
C8 C9 1.386(3) .
C8 H8 0.9300 .
C9 H9 0.9300 .
C10 C11 1.385(3) .
C10 C15 1.387(2) .
C11 C12 1.386(3) .
C11 H11 0.9300 .
C12 C13 1.378(3) .
C12 H12 0.9300 .
C13 C14 1.371(3) .
C14 C15 1.384(2) .
C14 H14 0.9300 .
C15 H15 0.9300 .
C16 H16 0.9300 .
C17 C18 1.349(3) .
C17 H17 0.9300 .
C18 H18 0.9300 .
C19 C20 1.392(2) .
C19 C24 1.394(2) .
C19 C25 1.507(2) .
C20 C21 1.3872(19) .
C20 H20 0.9300 .
C21 C22 1.390(2) .
C21 C26 1.497(2) .
C22 C23 1.387(2) .
C22 H22 0.9300 .
C23 C24 1.386(2) .
C23 H23 0.9300 .
C24 H24 0.9300 .
C26 Co1 2.5124(17) 1_565
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 Co1 N1 C1 -117.01(15) 2_666 .
O2 Co1 N1 C1 -4.96(15) . .
N4 Co1 N1 C1 -100.2(10) 1_446 .
O4 Co1 N1 C1 87.51(15) 1_545 .
O3 Co1 N1 C1 147.52(15) 1_545 .
C26 Co1 N1 C1 117.35(15) 1_545 .
O1 Co1 N1 C2 56.55(18) 2_666 .
O2 Co1 N1 C2 168.61(18) . .
N4 Co1 N1 C2 73.4(11) 1_446 .
O4 Co1 N1 C2 -98.92(18) 1_545 .
O3 Co1 N1 C2 -38.92(18) 1_545 .
C26 Co1 N1 C2 -69.08(18) 1_545 .
O1 Co1 O2 C25 -9.94(14) 2_666 .
N1 Co1 O2 C25 -93.81(14) . .
N4 Co1 O2 C25 83.27(14) 1_446 .
O4 Co1 O2 C25 175.83(13) 1_545 .
O3 Co1 O2 C25 173.35(11) 1_545 .
C26 Co1 O2 C25 173.23(12) 1_545 .
C2 N1 C1 N2 0.5(2) . .
Co1 N1 C1 N2 175.41(11) . .
C3 N2 C1 N1 -0.8(2) . .
C4 N2 C1 N1 179.87(16) . .
C1 N1 C2 C3 0.1(2) . .
Co1 N1 C2 C3 -174.40(14) . .
N1 C2 C3 N2 -0.5(3) . .
C1 N2 C3 C2 0.8(2) . .
C4 N2 C3 C2 -179.91(18) . .
C1 N2 C4 C9 155.7(2) . .
C3 N2 C4 C9 -23.5(3) . .
C1 N2 C4 C5 -24.1(3) . .
C3 N2 C4 C5 156.8(2) . .
C9 C4 C5 C6 0.2(3) . .
N2 C4 C5 C6 -180.0(2) . .
C4 C5 C6 C7 0.1(4) . .
C5 C6 C7 C8 -0.6(3) . .
C5 C6 C7 C10 178.26(19) . .
C6 C7 C8 C9 0.8(4) . .
C10 C7 C8 C9 -178.1(2) . .
C5 C4 C9 C8 -0.1(4) . .
N2 C4 C9 C8 -179.9(2) . .
C7 C8 C9 C4 -0.4(4) . .
C8 C7 C10 C11 174.8(2) . .
C6 C7 C10 C11 -4.0(3) . .
C8 C7 C10 C15 -3.5(3) . .
C6 C7 C10 C15 177.7(2) . .
C15 C10 C11 C12 0.4(4) . .
C7 C10 C11 C12 -178.0(2) . .
C10 C11 C12 C13 0.1(4) . .
C11 C12 C13 C14 -0.8(4) . .
C11 C12 C13 N3 179.8(2) . .
C16 N3 C13 C14 45.3(3) . .
C17 N3 C13 C14 -130.0(2) . .
C16 N3 C13 C12 -135.4(2) . .
C17 N3 C13 C12 49.3(3) . .
C12 C13 C14 C15 1.0(3) . .
N3 C13 C14 C15 -179.6(2) . .
C13 C14 C15 C10 -0.5(4) . .
C11 C10 C15 C14 -0.2(3) . .
C7 C10 C15 C14 178.2(2) . .
C18 N4 C16 N3 0.1(2) . .
Co1 N4 C16 N3 173.43(11) 1_664 .
C17 N3 C16 N4 0.5(2) . .
C13 N3 C16 N4 -175.64(16) . .
C16 N3 C17 C18 -0.9(2) . .
C13 N3 C17 C18 175.20(18) . .
N3 C17 C18 N4 0.9(3) . .
C16 N4 C18 C17 -0.6(2) . .
Co1 N4 C18 C17 -173.75(14) 1_664 .
C24 C19 C20 C21 0.5(2) . .
C25 C19 C20 C21 176.28(14) . .
C19 C20 C21 C22 2.0(2) . .
C19 C20 C21 C26 -175.14(13) . .
C20 C21 C22 C23 -3.5(2) . .
C26 C21 C22 C23 173.67(15) . .
C21 C22 C23 C24 2.4(3) . .
C22 C23 C24 C19 0.1(3) . .
C20 C19 C24 C23 -1.5(3) . .
C25 C19 C24 C23 -177.26(16) . .
Co1 O1 C25 O2 97.5(2) 2_666 .
Co1 O1 C25 C19 -82.5(3) 2_666 .
Co1 O2 C25 O1 -25.4(2) . .
Co1 O2 C25 C19 154.60(11) . .
C20 C19 C25 O1 6.6(2) . .
C24 C19 C25 O1 -177.68(16) . .
C20 C19 C25 O2 -173.37(14) . .
C24 C19 C25 O2 2.3(2) . .
Co1 O4 C26 O3 -5.45(15) 1_565 .
Co1 O4 C26 C21 174.62(12) 1_565 .
Co1 O3 C26 O4 5.44(15) 1_565 .
Co1 O3 C26 C21 -174.63(12) 1_565 .
C20 C21 C26 O4 -155.09(14) . .
C22 C21 C26 O4 27.8(2) . .
C20 C21 C26 O3 25.0(2) . .
C22 C21 C26 O3 -152.16(15) . .
C20 C21 C26 Co1 -61.2(14) . 1_565
C22 C21 C26 Co1 121.7(13) . 1_565
