#------------------------------------------------------------------------------
#$Date: 2016-02-13 21:28:24 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176429 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/48/7034872.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7034872
loop_
_publ_author_name
'Dong, Yongkwan'
'Eckert, Brian'
'Wang, Hsin'
'Zeng, Xiaoyu'
'Tritt, Terry M.'
'Nolas, George S.'
_publ_section_title
;
 Synthesis, crystal structure, and transport properties of
 Cu2.2Zn0.8SnSe4-xTex (0.1 ≤ x ≤ 0.4).
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9014
_journal_page_last               9019
_journal_paper_doi               10.1039/c5dt00910c
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'Cu2.2 Se3.63 Sn Te0.37 Zn0.8'
_chemical_formula_weight         644.48
_chemical_name_systematic        ' ?'
_space_group_IT_number           121
_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_Hall  'I -4 2'
_symmetry_space_group_name_H-M   'I -4 2 m'
_audit_creation_date             2014-12-15T15:02
_audit_creation_method           'from EXP file using GSAS2CIF'
_audit_update_record
' 2014-12-15T15:02  Initial CIF as created by GSAS2CIF'
_cell_angle_alpha                90.0
_cell_angle_beta                 90.0
_cell_angle_gamma                90.0
_cell_formula_units_Z            2
_cell_length_a                   5.7151(8)
_cell_length_b                   5.7151
_cell_length_c                   11.3974(21)
_cell_volume                     372.27(9)
_computing_structure_refinement  GSAS
_diffrn_radiation_polarisn_ratio 0.87
_diffrn_radiation_probe          x-ray
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  1.00000
_exptl_absorpt_process_details
;   GSAS Absorption/surface roughness correction: function number 0
 No correction is applied.
;
_pd_block_id
2014-12-15T15:02|SE34TE06_1|Se34Te06.cif|Bruker_D8
_pd_calc_method                  'Rietveld Refinement'
_pd_instr_location               ' ?'
_pd_meas_2theta_range_inc        0.01998
_pd_meas_2theta_range_max        100.00214
_pd_meas_2theta_range_min        15.0
_pd_meas_number_of_points        4256
_pd_phase_name
'from E:/USF/USF data/PXRD/YD143/refinements/Se34Te06/Se34Te06.cel'
_pd_proc_2theta_range_inc        0.01998
_pd_proc_2theta_range_max        100.00214
_pd_proc_2theta_range_min        15.0
_pd_proc_info_datetime           2014-12-15T15:02:52
_pd_proc_info_excluded_regions   ' ?'
_pd_proc_ls_background_function
;   GSAS Background function number 2 with  3 terms.
 Cosine Fourier series
      1:    3430.70     2:   -821.940     3:    721.953    
;
_pd_proc_ls_peak_cutoff          0.00100
_pd_proc_ls_profile_function
;
 CW Profile function number 3 with  19 terms
 Pseudovoigt profile coefficients as parameterized in
 P. Thompson, D.E. Cox & J.B. Hastings (1987). J. Appl. Cryst.,20,79-83.
 Asymmetry correction of L.W. Finger, D.E. Cox & A. P. Jephcoat (1994).
 J. Appl. Cryst.,27,892-900.
 Peak tails are ignored  where the intensity is below 0.0010 times the peak
   Aniso. broadening axis   0.0   0.0   1.0
;
_pd_proc_ls_prof_R_factor        0.0507
_pd_proc_ls_prof_wR_expected     0.0167
_pd_proc_ls_prof_wR_factor       0.0708
_pd_proc_number_of_points        4256
_pd_spec_mounting                ' ?'
_refine_ls_goodness_of_fit_all   4.25
_refine_ls_matrix_type           full
_refine_ls_number_parameters     13
_refine_ls_number_restraints     0
_refine_ls_R_Fsqd_factor         0.11299
_refine_ls_shift/su_max          0.00
_refine_ls_shift/su_mean         0.00
_reflns_d_resolution_high        1.009
_reflns_d_resolution_low         5.699
_reflns_limit_h_max              5
_reflns_limit_h_min              0
_reflns_limit_k_max              4
_reflns_limit_k_min              0
_reflns_limit_l_max              11
_reflns_limit_l_min              0
_reflns_number_total             152
_cod_data_source_file            c5dt00910c1.cif
_cod_data_source_block           SE34TE06_1_publ
_cod_depositor_comments
;
The following automatic conversions were performed:

'_geom_bond_publ_flag' value 'N' changed to 'n' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26 (42
times).

'_geom_angle_publ_flag' value 'N' changed to 'n' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26 (132
times).

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

 Adding full bibliography for 7034870--7034873.cif.
;
_cod_original_cell_volume        372.26(15)
_cod_original_formula_sum        'Cu2.20 Se3.63 Sn Te0.37 Zn0.80'
_cod_database_code               7034872
#BEGIN Tags that were not found in dictionaries:
_gsas_exptl_extinct_corr_t_min   1.00000
_gsas_exptl_extinct_corr_t_max   1.00000
#END Tags that were not found in dictionaries
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 +x,+y,+z
2 +y,-x,-z
3 -x,-y,+z
4 -y,+x,-z
5 -x,+y,-z
6 +y,+x,+z
7 +x,-y,-z
8 -y,-x,+z
101 +x+1/2,+y+1/2,+z+1/2
102 +y+1/2,-x+1/2,-z+1/2
103 -x+1/2,-y+1/2,+z+1/2
104 -y+1/2,+x+1/2,-z+1/2
105 -x+1/2,+y+1/2,-z+1/2
106 +y+1/2,+x+1/2,+z+1/2
107 +x+1/2,-y+1/2,-z+1/2
108 -y+1/2,-x+1/2,+z+1/2
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_thermal_displace_type
_atom_site_U_iso_or_equiv
_atom_site_symmetry_multiplicity
Cu Cu1 0.0 0.5 0.25 1.0 Uiso 0.02949 4
Cu Cu2 0.0 0.0 0.0 0.1999 Uiso 0.03992 2
Zn Zn 0.0 0.0 0.0 0.80014 Uiso 0.03992 2
Sn Sn 0.0 0.0 0.5 1.0 Uiso 0.03099 2
Se Se 0.24251 0.24251 0.12934 0.90829 Uiso 0.03001 8
Te Te 0.24251 0.24251 0.12934 0.09171 Uiso 0.03001 8
loop_
_atom_type_symbol
_atom_type_number_in_cell
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_Cromer_Mann_a1
_atom_type_scat_Cromer_Mann_a2
_atom_type_scat_Cromer_Mann_a3
_atom_type_scat_Cromer_Mann_a4
_atom_type_scat_Cromer_Mann_b1
_atom_type_scat_Cromer_Mann_b2
_atom_type_scat_Cromer_Mann_b3
_atom_type_scat_Cromer_Mann_b4
_atom_type_scat_Cromer_Mann_c
_atom_type_scat_source
Cu 4.4 0.000 0.000 13.3380 3.58280 7.16760 0.24700 5.61580 11.3966 1.67350
64.8126 1.19100 International_Tables_Vol_C
Zn 1.6 0.000 0.000 14.0743 3.26550 7.03180 0.23330 5.16520 10.3163 2.41000
58.7097 1.30410 International_Tables_Vol_C
Sn 2.0 0.000 0.000 19.1889 5.83030 19.1005 0.50310 4.45850 26.8909 2.46630
83.9571 4.78210 International_Tables_Vol_C
Se 7.266 0.000 0.000 17.0006 2.40980 5.81960 0.27260 3.97310 15.2372 4.35430
43.8163 2.84090 International_Tables_Vol_C
Te 0.734 0.000 0.000 19.9644 4.81742 19.0138 0.42088 6.14487 28.5284 2.52390
70.8403 4.35200 International_Tables_Vol_C
loop_
_diffrn_radiation_wavelength
_diffrn_radiation_wavelength_wt
_diffrn_radiation_type
_diffrn_radiation_wavelength_id
1.540600 1.000 K\a~1~ 1
1.544400 0.500 K\a~2~ 2
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Se Cu1 Se 111.547(12) 1_555 3_565 n
Se Cu1 Se 108.444(6) 1_555 102_455 n
Se Cu1 Se 108.444(6) 1_555 104_555 n
Se Cu1 Te 0.0 1_555 1_555 n
Se Cu1 Te 111.547(12) 1_555 3_565 n
Se Cu1 Te 108.444(6) 1_555 102_455 n
Se Cu1 Te 108.444(6) 1_555 104_555 n
Se Cu1 Se 108.444(6) 3_565 102_455 n
Se Cu1 Se 108.444(6) 3_565 104_555 n
Se Cu1 Te 111.547(12) 3_565 1_555 n
Se Cu1 Te 0.0 3_565 3_565 n
Se Cu1 Te 108.444(6) 3_565 102_455 n
Se Cu1 Te 108.444(6) 3_565 104_555 n
Se Cu1 Se 111.547(12) 102_455 104_555 n
Se Cu1 Te 108.444(6) 102_455 1_555 n
Se Cu1 Te 108.444(6) 102_455 3_565 n
Se Cu1 Te 0.0 102_455 102_455 n
Se Cu1 Te 111.547(12) 102_455 104_555 n
Se Cu1 Te 108.444(6) 104_555 1_555 n
Se Cu1 Te 108.444(6) 104_555 3_565 n
Se Cu1 Te 111.547(12) 104_555 102_455 n
Se Cu1 Te 0.0 104_555 104_555 n
Te Cu1 Te 111.547(12) 1_555 3_565 n
Te Cu1 Te 108.444(6) 1_555 102_455 n
Te Cu1 Te 108.444(6) 1_555 104_555 n
Te Cu1 Te 108.444(6) 3_565 102_455 n
Te Cu1 Te 108.444(6) 3_565 104_555 n
Te Cu1 Te 111.547(12) 102_455 104_555 n
Se Cu2 Se 111.179(7) 1_555 2_555 n
Se Cu2 Se 106.107(13) 1_555 3_555 n
Se Cu2 Se 111.179(7) 1_555 4_555 n
Se Cu2 Te 0.0 1_555 1_555 n
Se Cu2 Te 111.179(7) 1_555 2_555 n
Se Cu2 Te 106.107(13) 1_555 3_555 n
Se Cu2 Te 111.179(7) 1_555 4_555 n
Se Cu2 Se 111.179(7) 2_555 3_555 n
Se Cu2 Se 106.107(13) 2_555 4_555 n
Se Cu2 Te 111.179(7) 2_555 1_555 n
Se Cu2 Te 0.0 2_555 2_555 n
Se Cu2 Te 111.179(7) 2_555 3_555 n
Se Cu2 Te 106.107(13) 2_555 4_555 n
Se Cu2 Se 111.179(7) 3_555 4_555 n
Se Cu2 Te 106.107(13) 3_555 1_555 n
Se Cu2 Te 111.179(7) 3_555 2_555 n
Se Cu2 Te 0.0 3_555 3_555 n
Se Cu2 Te 111.179(7) 3_555 4_555 n
Se Cu2 Te 111.179(7) 4_555 1_555 n
Se Cu2 Te 106.107(13) 4_555 2_555 n
Se Cu2 Te 111.179(7) 4_555 3_555 n
Se Cu2 Te 0.0 4_555 4_555 n
Te Cu2 Te 111.179(7) 1_555 2_555 n
Te Cu2 Te 106.107(13) 1_555 3_555 n
Te Cu2 Te 111.179(7) 1_555 4_555 n
Te Cu2 Te 111.179(7) 2_555 3_555 n
Te Cu2 Te 106.107(13) 2_555 4_555 n
Te Cu2 Te 111.179(7) 3_555 4_555 n
Se Zn Se 111.179(7) 1_555 2_555 n
Se Zn Se 106.107(13) 1_555 3_555 n
Se Zn Se 111.179(7) 1_555 4_555 n
Se Zn Te 0.0 1_555 1_555 n
Se Zn Te 111.179(7) 1_555 2_555 n
Se Zn Te 106.107(13) 1_555 3_555 n
Se Zn Te 111.179(7) 1_555 4_555 n
Se Zn Se 111.179(7) 2_555 3_555 n
Se Zn Se 106.107(13) 2_555 4_555 n
Se Zn Te 111.179(7) 2_555 1_555 n
Se Zn Te 0.0 2_555 2_555 n
Se Zn Te 111.179(7) 2_555 3_555 n
Se Zn Te 106.107(13) 2_555 4_555 n
Se Zn Se 111.179(7) 3_555 4_555 n
Se Zn Te 106.107(13) 3_555 1_555 n
Se Zn Te 111.179(7) 3_555 2_555 n
Se Zn Te 0.0 3_555 3_555 n
Se Zn Te 111.179(7) 3_555 4_555 n
Se Zn Te 111.179(7) 4_555 1_555 n
Se Zn Te 106.107(13) 4_555 2_555 n
Se Zn Te 111.179(7) 4_555 3_555 n
Se Zn Te 0.0 4_555 4_555 n
Te Zn Te 111.179(7) 1_555 2_555 n
Te Zn Te 106.107(13) 1_555 3_555 n
Te Zn Te 111.179(7) 1_555 4_555 n
Te Zn Te 111.179(7) 2_555 3_555 n
Te Zn Te 106.107(13) 2_555 4_555 n
Te Zn Te 111.179(7) 3_555 4_555 n
Se Sn Se 109.519(6) 101_445 102_455 n
Se Sn Se 109.376(13) 101_445 103_555 n
Se Sn Se 109.519(6) 101_445 104_545 n
Se Sn Te 0.0 101_445 101_445 n
Se Sn Te 109.519(6) 101_445 102_455 n
Se Sn Te 109.376(13) 101_445 103_555 n
Se Sn Te 109.519(6) 101_445 104_545 n
Se Sn Se 109.519(6) 102_455 103_555 n
Se Sn Se 109.376(13) 102_455 104_545 n
Se Sn Te 109.519(6) 102_455 101_445 n
Se Sn Te 0.0 102_455 102_455 n
Se Sn Te 109.519(6) 102_455 103_555 n
Se Sn Te 109.376(13) 102_455 104_545 n
Se Sn Se 109.519(6) 103_555 104_545 n
Se Sn Te 109.376(13) 103_555 101_445 n
Se Sn Te 109.519(6) 103_555 102_455 n
Se Sn Te 0.0 103_555 103_555 n
Se Sn Te 109.519(6) 103_555 104_545 n
Se Sn Te 109.519(6) 104_545 101_445 n
Se Sn Te 109.376(13) 104_545 102_455 n
Se Sn Te 109.519(6) 104_545 103_555 n
Se Sn Te 0.0 104_545 104_545 n
Te Sn Te 109.519(6) 101_445 102_455 n
Te Sn Te 109.376(13) 101_445 103_555 n
Te Sn Te 109.519(6) 101_445 104_545 n
Te Sn Te 109.519(6) 102_455 103_555 n
Te Sn Te 109.376(13) 102_455 104_545 n
Te Sn Te 109.519(6) 103_555 104_545 n
Cu1 Se Cu1 111.471(12) 1_555 6_555 n
Cu1 Se Cu2 110.969(6) 1_555 1_555 n
Cu1 Se Zn 110.969(6) 1_555 1_555 n
Cu1 Se Sn 107.754(6) 1_555 101_554 n
Cu1 Se Cu2 110.969(6) 6_555 1_555 n
Cu1 Se Zn 110.969(6) 6_555 1_555 n
Cu1 Se Sn 107.754(6) 6_555 101_554 n
Cu2 Se Zn 0.0 1_555 1_555 n
Cu2 Se Sn 107.741(13) 1_555 101_554 n
Zn Se Sn 107.741(13) 1_555 101_554 n
Cu1 Te Cu1 111.471(12) 1_555 6_555 n
Cu1 Te Cu2 110.969(6) 1_555 1_555 n
Cu1 Te Zn 110.969(6) 1_555 1_555 n
Cu1 Te Sn 107.754(6) 1_555 101_554 n
Cu1 Te Cu2 110.969(6) 6_555 1_555 n
Cu1 Te Zn 110.969(6) 6_555 1_555 n
Cu1 Te Sn 107.754(6) 6_555 101_554 n
Cu2 Te Zn 0.0 1_555 1_555 n
Cu2 Te Sn 107.741(13) 1_555 101_554 n
Zn Te Sn 107.741(13) 1_555 101_554 n
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu1 Se 2.44490(28) 1_555 n
Cu1 Se 2.44490(28) 3_565 n
Cu1 Se 2.44490(28) 102_455 n
Cu1 Se 2.44490(28) 104_555 n
Cu1 Te 2.44490(28) 1_555 n
Cu1 Te 2.44490(28) 3_565 n
Cu1 Te 2.44490(28) 102_455 n
Cu1 Te 2.44490(28) 104_555 n
Cu2 Se 2.45255(28) 1_555 n
Cu2 Se 2.45255(28) 2_555 n
Cu2 Se 2.45255(28) 3_555 n
Cu2 Se 2.45255(28) 4_555 n
Cu2 Te 2.45255(28) 1_555 n
Cu2 Te 2.45255(28) 2_555 n
Cu2 Te 2.45255(28) 3_555 n
Cu2 Te 2.45255(28) 4_555 n
Zn Se 2.45255(28) 1_555 n
Zn Se 2.45255(28) 2_555 n
Zn Se 2.45255(28) 3_555 n
Zn Se 2.45255(28) 4_555 n
Zn Te 2.45255(28) 1_555 n
Zn Te 2.45255(28) 2_555 n
Zn Te 2.45255(28) 3_555 n
Zn Te 2.45255(28) 4_555 n
Sn Se 2.55032(29) 101_445 n
Sn Se 2.55032(29) 102_455 n
Sn Se 2.55032(29) 103_555 n
Sn Se 2.55032(29) 104_545 n
Sn Te 2.55032(29) 101_445 n
Sn Te 2.55032(29) 102_455 n
Sn Te 2.55032(29) 103_555 n
Sn Te 2.55032(29) 104_545 n
Se Cu1 2.44490(28) 1_555 n
Se Cu1 2.44490(28) 6_555 n
Se Cu2 2.45255(28) 1_555 n
Se Zn 2.45255(28) 1_555 n
Se Sn 2.55032(29) 101_554 n
Te Cu1 2.44490(28) 1_555 n
Te Cu1 2.44490(28) 6_555 n
Te Cu2 2.45255(28) 1_555 n
Te Zn 2.45255(28) 1_555 n
Te Sn 2.55032(29) 101_554 n
loop_
_pd_meas_counts_total
_pd_proc_ls_weight
_pd_proc_intensity_bkg_calc
_pd_calc_intensity_total
4253.0 0.0002351 3261.99658 3272.50122
4310.0 0.0002320 3261.81885 3273.11035
4382.0 0.0002282 3261.64111 3273.80981
4371.0 0.0002288 3261.46289 3275.95532
4250.0 0.0002353 3261.28467 3276.90503
4233.0 0.0002362 3261.10620 3278.66382
4347.0 0.0002300 3260.92749 3279.93872
4213.0 0.0002374 3260.74854 3281.41650
4177.0 0.0002394 3260.56958 3283.14185
4107.0 0.0002435 3260.39014 3285.17651
4380.0 0.0002283 3260.21069 3287.61157
4298.0 0.0002327 3260.03101 3290.58960
4293.0 0.0002329 3259.85107 3294.33862
4352.0 0.0002298 3259.67090 3299.22046
4261.0 0.0002347 3259.49048 3305.80371
4207.0 0.0002377 3259.31006 3314.93701
4290.0 0.0002331 3259.12939 3327.81372
4171.0 0.0002398 3258.94824 3345.99683
4187.0 0.0002388 3258.76733 3371.33325
4139.0 0.0002416 3258.58594 3405.76636
4104.0 0.0002437 3258.40405 3450.95190
4325.0 0.0002312 3258.22241 3507.78467
4268.0 0.0002343 3258.04053 3575.78857
4225.0 0.0002367 3257.85815 3652.39893
4231.0 0.0002364 3257.67578 3732.19458
4280.0 0.0002336 3257.49341 3806.14453
4245.0 0.0002356 3257.31055 3862.24268
4251.0 0.0002352 3257.12744 3888.85840
4167.0 0.0002400 3256.94434 3880.08765
4220.0 0.0002370 3256.76099 3838.47803
4267.0 0.0002344 3256.57715 3773.20044
4298.0 0.0002327 3256.39331 3695.90405
4300.0 0.0002326 3256.20923 3617.03247
4243.0 0.0002357 3256.02515 3543.88770
4230.0 0.0002364 3255.84082 3480.60596
4219.0 0.0002370 3255.65601 3428.79199
4150.0 0.0002410 3255.47119 3388.26196
4137.0 0.0002417 3255.28613 3357.75513
4213.0 0.0002374 3255.10107 3335.45972
4213.0 0.0002374 3254.91553 3319.47461
4090.0 0.0002445 3254.72998 3308.08008
4149.0 0.0002410 3254.54395 3299.88452
4193.0 0.0002385 3254.35791 3293.85596
4103.0 0.0002437 3254.17163 3289.27490
4076.0 0.0002453 3253.98535 3285.66919
4165.0 0.0002401 3253.79858 3282.73584
4121.0 0.0002427 3253.61157 3280.28760
4132.0 0.0002420 3253.42456 3278.20459
4134.0 0.0002419 3253.23730 3276.40869
4270.0 0.0002342 3253.05005 3274.84644
4109.0 0.0002434 3252.86206 3273.47852
4174.0 0.0002396 3252.67432 3272.27539
4295.0 0.0002328 3252.48633 3271.21387
4233.0 0.0002362 3252.29785 3270.27441
4051.0 0.0002469 3252.10938 3269.44238
4103.0 0.0002437 3251.92090 3268.70483
4093.0 0.0002443 3251.73193 3268.05127
4192.0 0.0002385 3251.54272 3267.47266
4212.0 0.0002374 3251.35352 3266.96191
4003.0 0.0002498 3251.16406 3266.51294
4164.0 0.0002402 3250.97437 3266.12134
4055.0 0.0002466 3250.78467 3265.78223
3967.0 0.0002521 3250.59448 3265.49243
4062.0 0.0002462 3250.40405 3265.24951
4029.0 0.0002482 3250.21362 3265.05151
4050.0 0.0002469 3250.02295 3264.89648
4022.0 0.0002486 3249.83203 3264.78320
4085.0 0.0002448 3249.64087 3264.71118
4009.0 0.0002494 3249.44946 3264.68042
4147.0 0.0002411 3249.25806 3264.69092
3988.0 0.0002508 3249.06641 3264.74268
4196.0 0.0002383 3248.87451 3264.83740
4106.0 0.0002435 3248.68262 3264.97583
4057.0 0.0002465 3248.49023 3265.16016
4022.0 0.0002486 3248.29761 3265.39185
4064.0 0.0002461 3248.10498 3265.67383
3979.0 0.0002513 3247.91235 3266.00879
4138.0 0.0002417 3247.71924 3266.40112
4102.0 0.0002438 3247.52588 3266.85400
4035.0 0.0002478 3247.33228 3267.37305
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3532.0 . . .
