#------------------------------------------------------------------------------
#$Date: 2016-10-08 01:08:46 +0300 (Sat, 08 Oct 2016) $
#$Revision: 187087 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/04/7040490.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7040490
loop_
_publ_author_name
'Li, Chuan-Ti'
'Zhao, Yi-Fan'
'Hu, Huai-Ming'
'Zhao, Hui'
'Wang, Xiaofang'
'Xue, Ganglin'
_publ_section_title
;
 Lanthanide coordination frameworks constructed from
 3,3',4,4'-diphenylsulfonetetracarboxylic and 1,10-phenanthroline:
 synthesis, crystal structures and luminescence properties.
;
_journal_issue                   39
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15436
_journal_paper_doi               10.1039/c6dt02646j
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C56 H38 Eu2 N4 O25 S2'
_chemical_formula_weight         1534.94
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2016-07-01 deposited with the CCDC.
2016-08-25 downloaded from the CCDC.
;
_cell_angle_alpha                108.843(2)
_cell_angle_beta                 105.804(2)
_cell_angle_gamma                90.751(2)
_cell_formula_units_Z            1
_cell_length_a                   10.6041(15)
_cell_length_b                   11.5157(17)
_cell_length_c                   12.0048(17)
_cell_measurement_reflns_used    2271
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      23.85
_cell_measurement_theta_min      2.71
_cell_volume                     1326.7(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0279
_diffrn_reflns_av_sigmaI/netI    0.0592
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            6644
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         1.88
_exptl_absorpt_coefficient_mu    2.519
_exptl_absorpt_correction_T_max  0.778
_exptl_absorpt_correction_T_min  0.671
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.921
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             760
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.09
_refine_diff_density_max         0.629
_refine_diff_density_min         -0.829
_refine_diff_density_rms         0.115
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.002
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     419
_refine_ls_number_reflns         4619
_refine_ls_number_restraints     4
_refine_ls_restrained_S_all      1.001
_refine_ls_R_factor_all          0.0392
_refine_ls_R_factor_gt           0.0329
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0248P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0642
_refine_ls_wR_factor_ref         0.0674
_reflns_number_gt                4075
_reflns_number_total             4619
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6dt02646j2.cif
_cod_data_source_block           nw2057_0m
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7040480--7040491.cif.
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7040490
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.50478(2) -0.252904(19) 0.46394(2) 0.01678(8) Uani 1 1 d .
S1 S 1.01335(11) 0.20016(11) 1.17912(10) 0.0234(3) Uani 1 1 d .
N1 N 0.5900(4) -0.1942(3) 0.3021(3) 0.0274(9) Uani 1 1 d .
N2 N 0.3763(4) -0.3629(3) 0.2305(3) 0.0232(9) Uani 1 1 d .
O1 O 0.6361(3) -0.0757(3) 0.6049(3) 0.0314(8) Uani 1 1 d .
O2 O 0.6354(3) 0.1145(3) 0.5972(3) 0.0288(8) Uani 1 1 d .
O3 O 0.9190(3) 0.1081(3) 0.6272(3) 0.0320(8) Uani 1 1 d .
H3 H 0.9561 0.1326 0.5860 0.048 Uiso 1 1 calc R
O4 O 0.9942(4) 0.2965(3) 0.7642(3) 0.0480(11) Uani 1 1 d .
O5 O 0.7443(3) 0.6900(3) 1.4851(3) 0.0311(8) Uani 1 1 d .
O6 O 0.5804(3) 0.5429(3) 1.3820(3) 0.0267(7) Uani 1 1 d .
O7 O 0.6669(3) 0.3938(3) 1.5357(3) 0.0268(7) Uani 1 1 d .
O8 O 0.6437(3) 0.2076(3) 1.4002(3) 0.0344(8) Uani 1 1 d .
O9 O 1.1376(3) 0.2561(3) 1.1830(3) 0.0320(8) Uani 1 1 d .
O10 O 1.0086(3) 0.0921(3) 1.2139(3) 0.0336(8) Uani 1 1 d .
C1 C 0.6903(5) -0.1093(4) 0.3344(5) 0.0343(12) Uani 1 1 d .
H1 H 0.7246 -0.0627 0.4173 0.041 Uiso 1 1 calc R
C2 C 0.7480(5) -0.0854(5) 0.2515(6) 0.0429(14) Uani 1 1 d .
H2 H 0.8202 -0.0260 0.2796 0.052 Uiso 1 1 calc R
C3 C 0.6980(6) -0.1493(5) 0.1300(6) 0.0471(15) Uani 1 1 d .
H3A H 0.7368 -0.1357 0.0739 0.057 Uiso 1 1 calc R
C4 C 0.5872(5) -0.2361(5) 0.0894(5) 0.0395(13) Uani 1 1 d .
C5 C 0.5234(6) -0.3045(6) -0.0385(5) 0.0544(17) Uani 1 1 d .
H5 H 0.5584 -0.2938 -0.0981 0.065 Uiso 1 1 calc R
C6 C 0.4148(7) -0.3829(6) -0.0733(5) 0.0556(17) Uani 1 1 d .
H6 H 0.3741 -0.4236 -0.1567 0.067 Uiso 1 1 calc R
C7 C 0.3603(6) -0.4056(5) 0.0141(5) 0.0402(14) Uani 1 1 d .
C8 C 0.2456(6) -0.4875(5) -0.0171(5) 0.0494(16) Uani 1 1 d .
H8 H 0.2019 -0.5304 -0.0994 0.059 Uiso 1 1 calc R
C9 C 0.1994(5) -0.5037(5) 0.0709(5) 0.0434(14) Uani 1 1 d .
H9 H 0.1226 -0.5558 0.0501 0.052 Uiso 1 1 calc R
C10 C 0.2678(5) -0.4415(4) 0.1937(5) 0.0331(12) Uani 1 1 d .
H10 H 0.2360 -0.4557 0.2537 0.040 Uiso 1 1 calc R
C11 C 0.4212(4) -0.3443(4) 0.1417(4) 0.0249(11) Uani 1 1 d .
C12 C 0.5352(5) -0.2567(4) 0.1784(4) 0.0258(11) Uani 1 1 d .
C13 C 0.6689(4) 0.0382(4) 0.6503(4) 0.0199(10) Uani 1 1 d .
C14 C 0.7564(4) 0.0838(4) 0.7823(4) 0.0198(10) Uani 1 1 d .
C15 C 0.7149(5) 0.0519(4) 0.8688(4) 0.0287(11) Uani 1 1 d .
H15 H 0.6350 0.0032 0.8445 0.034 Uiso 1 1 calc R
C16 C 0.7892(5) 0.0905(4) 0.9908(4) 0.0294(11) Uani 1 1 d .
H16 H 0.7596 0.0690 1.0484 0.035 Uiso 1 1 calc R
C17 C 0.9091(4) 0.1622(4) 1.0258(4) 0.0201(10) Uani 1 1 d .
C18 C 0.9513(4) 0.1972(4) 0.9418(4) 0.0213(10) Uani 1 1 d .
H18 H 1.0309 0.2466 0.9670 0.026 Uiso 1 1 calc R
C19 C 0.8755(4) 0.1591(4) 0.8187(4) 0.0195(10) Uani 1 1 d .
C20 C 0.9338(4) 0.1960(4) 0.7336(4) 0.0250(11) Uani 1 1 d .
C21 C 0.7012(5) 0.5780(4) 1.4244(4) 0.0217(10) Uani 1 1 d .
C22 C 0.7963(4) 0.4872(4) 1.3892(4) 0.0190(10) Uani 1 1 d .
C23 C 0.8928(4) 0.5231(4) 1.3454(4) 0.0248(11) Uani 1 1 d .
H23 H 0.9103 0.6061 1.3569 0.030 Uiso 1 1 calc R
C24 C 0.9641(4) 0.4376(4) 1.2848(4) 0.0257(11) Uani 1 1 d .
H24 H 1.0287 0.4625 1.2555 0.031 Uiso 1 1 calc R
C25 C 0.9368(4) 0.3137(4) 1.2688(4) 0.0218(10) Uani 1 1 d .
C26 C 0.8464(4) 0.2781(4) 1.3191(4) 0.0215(10) Uani 1 1 d .
H26 H 0.8320 0.1955 1.3110 0.026 Uiso 1 1 calc R
C27 C 0.7777(4) 0.3635(4) 1.3809(4) 0.0205(10) Uani 1 1 d .
C28 C 0.6905(4) 0.3183(4) 1.4429(4) 0.0243(10) Uani 1 1 d .
O11 O 0.5915(3) -0.3223(3) 0.6473(3) 0.0319(8) Uani 1 1 d D
H11A H 0.563(5) -0.393(3) 0.643(5) 0.038 Uiso 1 1 d D
H11B H 0.669(2) -0.297(4) 0.693(4) 0.038 Uiso 1 1 d D
O12 O 0.0422(3) 0.1515(3) 0.4834(3) 0.0358(9) Uani 1 1 d D
H12A H 0.103(4) 0.210(3) 0.508(5) 0.043 Uiso 1 1 d D
H12B H 0.048(5) 0.088(3) 0.428(4) 0.043 Uiso 1 1 d D
O13 O 0.444(3) 0.910(3) 0.860(3) 0.393(18) Uani 0.50 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Eu1 O2 84.46(11) . 2_656
O1 Eu1 O7 135.94(11) . 2_657
O2 Eu1 O7 96.30(11) 2_656 2_657
O1 Eu1 O6 126.17(11) . 1_544
O2 Eu1 O6 141.85(10) 2_656 1_544
O7 Eu1 O6 77.37(10) 2_657 1_544
O1 Eu1 O8 85.94(11) . 2_657
O2 Eu1 O8 73.72(11) 2_656 2_657
O7 Eu1 O8 52.86(10) 2_657 2_657
O6 Eu1 O8 124.61(10) 1_544 2_657
O1 Eu1 O11 79.26(11) . .
O2 Eu1 O11 139.92(11) 2_656 .
O7 Eu1 O11 72.16(11) 2_657 .
O6 Eu1 O11 74.50(11) 1_544 .
O8 Eu1 O11 68.83(12) 2_657 .
O1 Eu1 O5 75.65(10) . 1_544
O2 Eu1 O5 141.19(11) 2_656 1_544
O7 Eu1 O5 121.17(10) 2_657 1_544
O6 Eu1 O5 51.20(9) 1_544 1_544
O8 Eu1 O5 135.90(11) 2_657 1_544
O11 Eu1 O5 68.54(11) . 1_544
O1 Eu1 N1 84.83(11) . .
O2 Eu1 N1 73.84(11) 2_656 .
O7 Eu1 N1 137.82(11) 2_657 .
O6 Eu1 N1 85.81(11) 1_544 .
O8 Eu1 N1 146.95(11) 2_657 .
O11 Eu1 N1 139.48(12) . .
O5 Eu1 N1 71.49(11) 1_544 .
O1 Eu1 N2 144.13(11) . .
O2 Eu1 N2 73.00(11) 2_656 .
O7 Eu1 N2 75.34(11) 2_657 .
O6 Eu1 N2 68.99(11) 1_544 .
O8 Eu1 N2 112.88(11) 2_657 .
O11 Eu1 N2 135.25(11) . .
O5 Eu1 N2 105.00(11) 1_544 .
N1 Eu1 N2 62.52(11) . .
O1 Eu1 C28 110.28(12) . 2_657
O2 Eu1 C28 86.78(12) 2_656 2_657
O7 Eu1 C28 26.67(11) 2_657 2_657
O6 Eu1 C28 100.24(12) 1_544 2_657
O8 Eu1 C28 26.43(11) 2_657 2_657
O11 Eu1 C28 65.55(12) . 2_657
O5 Eu1 C28 131.23(12) 1_544 2_657
N1 Eu1 C28 154.38(13) . 2_657
N2 Eu1 C28 96.20(12) . 2_657
O1 Eu1 C21 101.13(12) . 1_544
O2 Eu1 C21 150.53(11) 2_656 1_544
O7 Eu1 C21 99.18(11) 2_657 1_544
O6 Eu1 C21 25.35(11) 1_544 1_544
O8 Eu1 C21 135.14(12) 2_657 1_544
O11 Eu1 C21 69.19(12) . 1_544
O5 Eu1 C21 25.85(11) 1_544 1_544
N1 Eu1 C21 77.85(12) . 1_544
N2 Eu1 C21 86.86(12) . 1_544
C28 Eu1 C21 117.26(13) 2_657 1_544
O10 S1 O9 120.2(2) . .
O10 S1 C25 108.0(2) . .
O9 S1 C25 108.6(2) . .
O10 S1 C17 107.5(2) . .
O9 S1 C17 106.8(2) . .
C25 S1 C17 104.7(2) . .
C1 N1 C12 117.2(4) . .
C1 N1 Eu1 122.3(3) . .
C12 N1 Eu1 120.4(3) . .
C10 N2 C11 117.1(4) . .
C10 N2 Eu1 122.4(3) . .
C11 N2 Eu1 120.5(3) . .
C13 O1 Eu1 154.1(3) . .
C13 O2 Eu1 154.0(3) . 2_656
C20 O3 H3 109.5 . .
C21 O5 Eu1 90.5(3) . 1_566
C21 O6 Eu1 96.6(3) . 1_566
C28 O7 Eu1 93.7(3) . 2_657
C28 O8 Eu1 90.3(3) . 2_657
N1 C1 C2 123.9(5) . .
N1 C1 H1 118.1 . .
C2 C1 H1 118.1 . .
C3 C2 C1 119.4(5) . .
C3 C2 H2 120.3 . .
C1 C2 H2 120.3 . .
C2 C3 C4 119.4(5) . .
C2 C3 H3A 120.3 . .
C4 C3 H3A 120.3 . .
C3 C4 C12 118.1(5) . .
C3 C4 C5 123.4(5) . .
C12 C4 C5 118.5(5) . .
C6 C5 C4 121.3(5) . .
C6 C5 H5 119.4 . .
C4 C5 H5 119.4 . .
C5 C6 C7 121.5(5) . .
C5 C6 H6 119.3 . .
C7 C6 H6 119.3 . .
C8 C7 C6 124.0(5) . .
C8 C7 C11 116.0(5) . .
C6 C7 C11 120.0(5) . .
C9 C8 C7 120.6(5) . .
C9 C8 H8 119.7 . .
C7 C8 H8 119.7 . .
C8 C9 C10 119.1(5) . .
C8 C9 H9 120.4 . .
C10 C9 H9 120.4 . .
N2 C10 C9 123.8(5) . .
N2 C10 H10 118.1 . .
C9 C10 H10 118.1 . .
N2 C11 C7 123.3(4) . .
N2 C11 C12 118.4(4) . .
C7 C11 C12 118.3(4) . .
N1 C12 C4 121.8(4) . .
N1 C12 C11 117.7(4) . .
C4 C12 C11 120.5(4) . .
O2 C13 O1 125.9(4) . .
O2 C13 C14 119.0(4) . .
O1 C13 C14 115.1(4) . .
C15 C14 C19 119.6(4) . .
C15 C14 C13 118.3(4) . .
C19 C14 C13 122.0(4) . .
C14 C15 C16 121.5(4) . .
C14 C15 H15 119.2 . .
C16 C15 H15 119.2 . .
C15 C16 C17 118.7(4) . .
C15 C16 H16 120.7 . .
C17 C16 H16 120.7 . .
C18 C17 C16 120.9(4) . .
C18 C17 S1 119.8(3) . .
C16 C17 S1 119.2(3) . .
C17 C18 C19 120.4(4) . .
C17 C18 H18 119.8 . .
C19 C18 H18 119.8 . .
C18 C19 C14 118.9(4) . .
C18 C19 C20 116.2(4) . .
C14 C19 C20 124.8(4) . .
O4 C20 O3 124.2(4) . .
O4 C20 C19 121.7(4) . .
O3 C20 C19 114.0(4) . .
O6 C21 O5 121.7(4) . .
O6 C21 C22 118.6(4) . .
O5 C21 C22 119.3(4) . .
O6 C21 Eu1 58.0(2) . 1_566
O5 C21 Eu1 63.7(2) . 1_566
C22 C21 Eu1 173.8(3) . 1_566
C23 C22 C27 119.1(4) . .
C23 C22 C21 117.8(4) . .
C27 C22 C21 122.3(4) . .
C22 C23 C24 121.4(4) . .
C22 C23 H23 119.3 . .
C24 C23 H23 119.3 . .
C23 C24 C25 118.4(4) . .
C23 C24 H24 120.8 . .
C25 C24 H24 120.8 . .
C26 C25 C24 120.5(4) . .
C26 C25 S1 119.5(3) . .
C24 C25 S1 119.9(3) . .
C27 C26 C25 120.6(4) . .
C27 C26 H26 119.7 . .
C25 C26 H26 119.7 . .
C26 C27 C22 119.6(4) . .
C26 C27 C28 116.9(4) . .
C22 C27 C28 123.4(4) . .
O8 C28 O7 122.0(4) . .
O8 C28 C27 118.9(4) . .
O7 C28 C27 119.0(4) . .
O8 C28 Eu1 63.3(2) . 2_657
O7 C28 Eu1 59.6(2) . 2_657
C27 C28 Eu1 170.3(3) . 2_657
Eu1 O11 H11A 118(4) . .
Eu1 O11 H11B 120(4) . .
H11A O11 H11B 115(5) . .
H12A O12 H12B 117(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O1 2.320(3) .
Eu1 O2 2.348(3) 2_656
Eu1 O7 2.425(3) 2_657
Eu1 O6 2.475(3) 1_544
Eu1 O8 2.506(3) 2_657
Eu1 O11 2.527(3) .
Eu1 O5 2.597(3) 1_544
Eu1 N1 2.615(4) .
Eu1 N2 2.626(4) .
Eu1 C28 2.805(4) 2_657
Eu1 C21 2.898(4) 1_544
S1 O10 1.440(3) .
S1 O9 1.441(3) .
S1 C25 1.768(4) .
S1 C17 1.778(4) .
N1 C1 1.319(6) .
N1 C12 1.375(5) .
N2 C10 1.332(5) .
N2 C11 1.353(6) .
O1 C13 1.249(5) .
O2 C13 1.245(5) .
O2 Eu1 2.348(3) 2_656
O3 C20 1.316(5) .
O3 H3 0.8200 .
O4 C20 1.209(5) .
O5 C21 1.264(5) .
O5 Eu1 2.597(3) 1_566
O6 C21 1.249(5) .
O6 Eu1 2.475(3) 1_566
O7 C28 1.262(5) .
O7 Eu1 2.425(3) 2_657
O8 C28 1.248(5) .
O8 Eu1 2.506(3) 2_657
C1 C2 1.394(7) .
C1 H1 0.9300 .
C2 C3 1.351(7) .
C2 H2 0.9300 .
C3 C4 1.399(7) .
C3 H3A 0.9300 .
C4 C12 1.408(7) .
C4 C5 1.441(7) .
C5 C6 1.335(8) .
C5 H5 0.9300 .
C6 C7 1.416(8) .
C6 H6 0.9300 .
C7 C8 1.415(7) .
C7 C11 1.419(6) .
C8 C9 1.341(8) .
C8 H8 0.9300 .
C9 C10 1.391(6) .
C9 H9 0.9300 .
C10 H10 0.9300 .
C11 C12 1.437(6) .
C13 C14 1.516(6) .
C14 C15 1.378(6) .
C14 C19 1.401(6) .
C15 C16 1.380(6) .
C15 H15 0.9300 .
C16 C17 1.390(6) .
C16 H16 0.9300 .
C17 C18 1.372(6) .
C18 C19 1.395(6) .
C18 H18 0.9300 .
C19 C20 1.491(6) .
C21 C22 1.504(6) .
C21 Eu1 2.898(4) 1_566
C22 C23 1.384(6) .
C22 C27 1.403(6) .
C23 C24 1.388(6) .
C23 H23 0.9300 .
C24 C25 1.392(6) .
C24 H24 0.9300 .
C25 C26 1.384(6) .
C26 C27 1.375(6) .
C26 H26 0.9300 .
C27 C28 1.515(6) .
C28 Eu1 2.805(4) 2_657
O11 H11A 0.839(19) .
O11 H11B 0.843(19) .
O12 H12A 0.845(19) .
O12 H12B 0.831(19) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 Eu1 N1 C1 12.8(4) . .
O2 Eu1 N1 C1 98.5(4) 2_656 .
O7 Eu1 N1 C1 179.9(3) 2_657 .
O6 Eu1 N1 C1 -114.2(4) 1_544 .
O8 Eu1 N1 C1 87.1(4) 2_657 .
O11 Eu1 N1 C1 -54.0(4) . .
O5 Eu1 N1 C1 -63.8(3) 1_544 .
N2 Eu1 N1 C1 177.4(4) . .
C28 Eu1 N1 C1 140.8(4) 2_657 .
C21 Eu1 N1 C1 -89.8(4) 1_544 .
O1 Eu1 N1 C12 -170.8(3) . .
O2 Eu1 N1 C12 -85.1(3) 2_656 .
O7 Eu1 N1 C12 -3.7(4) 2_657 .
O6 Eu1 N1 C12 62.2(3) 1_544 .
O8 Eu1 N1 C12 -96.5(4) 2_657 .
O11 Eu1 N1 C12 122.4(3) . .
O5 Eu1 N1 C12 112.6(3) 1_544 .
N2 Eu1 N1 C12 -6.2(3) . .
C28 Eu1 N1 C12 -42.8(5) 2_657 .
C21 Eu1 N1 C12 86.6(3) 1_544 .
O1 Eu1 N2 C10 -150.0(3) . .
O2 Eu1 N2 C10 -96.5(4) 2_656 .
O7 Eu1 N2 C10 4.9(3) 2_657 .
O6 Eu1 N2 C10 86.8(3) 1_544 .
O8 Eu1 N2 C10 -33.1(4) 2_657 .
O11 Eu1 N2 C10 49.4(4) . .
O5 Eu1 N2 C10 123.8(3) 1_544 .
N1 Eu1 N2 C10 -176.8(4) . .
C28 Eu1 N2 C10 -11.8(4) 2_657 .
C21 Eu1 N2 C10 105.3(3) 1_544 .
O1 Eu1 N2 C11 32.1(4) . .
O2 Eu1 N2 C11 85.6(3) 2_656 .
O7 Eu1 N2 C11 -173.0(3) 2_657 .
O6 Eu1 N2 C11 -91.1(3) 1_544 .
O8 Eu1 N2 C11 149.0(3) 2_657 .
O11 Eu1 N2 C11 -128.5(3) . .
O5 Eu1 N2 C11 -54.1(3) 1_544 .
N1 Eu1 N2 C11 5.3(3) . .
C28 Eu1 N2 C11 170.3(3) 2_657 .
C21 Eu1 N2 C11 -72.6(3) 1_544 .
O2 Eu1 O1 C13 -9.7(7) 2_656 .
O7 Eu1 O1 C13 -103.1(7) 2_657 .
O6 Eu1 O1 C13 145.4(7) 1_544 .
O8 Eu1 O1 C13 -83.8(7) 2_657 .
O11 Eu1 O1 C13 -153.0(7) . .
O5 Eu1 O1 C13 136.7(7) 1_544 .
N1 Eu1 O1 C13 64.5(7) . .
N2 Eu1 O1 C13 40.8(8) . .
C28 Eu1 O1 C13 -94.2(7) 2_657 .
C21 Eu1 O1 C13 141.0(7) 1_544 .
C12 N1 C1 C2 -4.1(7) . .
Eu1 N1 C1 C2 172.4(4) . .
N1 C1 C2 C3 1.8(8) . .
C1 C2 C3 C4 1.6(8) . .
C2 C3 C4 C12 -2.5(8) . .
C2 C3 C4 C5 177.1(6) . .
C3 C4 C5 C6 -177.4(6) . .
C12 C4 C5 C6 2.1(9) . .
C4 C5 C6 C7 -2.2(10) . .
C5 C6 C7 C8 179.9(6) . .
C5 C6 C7 C11 -0.1(9) . .
C6 C7 C8 C9 -179.7(6) . .
C11 C7 C8 C9 0.3(8) . .
C7 C8 C9 C10 -1.8(9) . .
C11 N2 C10 C9 -0.4(7) . .
Eu1 N2 C10 C9 -178.3(4) . .
C8 C9 C10 N2 1.9(8) . .
C10 N2 C11 C7 -1.3(7) . .
Eu1 N2 C11 C7 176.7(4) . .
C10 N2 C11 C12 177.8(4) . .
Eu1 N2 C11 C12 -4.2(5) . .
C8 C7 C11 N2 1.3(7) . .
C6 C7 C11 N2 -178.7(5) . .
C8 C7 C11 C12 -177.8(4) . .
C6 C7 C11 C12 2.2(7) . .
C1 N1 C12 C4 3.1(7) . .
Eu1 N1 C12 C4 -173.5(4) . .
C1 N1 C12 C11 -176.5(4) . .
Eu1 N1 C12 C11 6.9(5) . .
C3 C4 C12 N1 0.1(7) . .
C5 C4 C12 N1 -179.4(5) . .
C3 C4 C12 C11 179.7(5) . .
C5 C4 C12 C11 0.1(7) . .
N2 C11 C12 N1 -1.8(6) . .
C7 C11 C12 N1 177.3(4) . .
N2 C11 C12 C4 178.7(4) . .
C7 C11 C12 C4 -2.2(7) . .
Eu1 O2 C13 O1 88.1(8) 2_656 .
Eu1 O2 C13 C14 -91.3(7) 2_656 .
Eu1 O1 C13 O2 -19.4(10) . .
Eu1 O1 C13 C14 160.1(5) . .
O2 C13 C14 C15 126.0(5) . .
O1 C13 C14 C15 -53.5(5) . .
O2 C13 C14 C19 -52.4(6) . .
O1 C13 C14 C19 128.0(4) . .
C19 C14 C15 C16 -1.3(7) . .
C13 C14 C15 C16 -179.7(4) . .
C14 C15 C16 C17 -0.6(7) . .
C15 C16 C17 C18 1.9(7) . .
C15 C16 C17 S1 -174.0(4) . .
O10 S1 C17 C18 -135.6(4) . .
O9 S1 C17 C18 -5.3(4) . .
C25 S1 C17 C18 109.8(4) . .
O10 S1 C17 C16 40.3(4) . .
O9 S1 C17 C16 170.6(4) . .
C25 S1 C17 C16 -74.3(4) . .
C16 C17 C18 C19 -1.3(7) . .
S1 C17 C18 C19 174.6(3) . .
C17 C18 C19 C14 -0.6(6) . .
C17 C18 C19 C20 -176.5(4) . .
C15 C14 C19 C18 1.9(6) . .
C13 C14 C19 C18 -179.7(4) . .
C15 C14 C19 C20 177.4(4) . .
C13 C14 C19 C20 -4.2(7) . .
C18 C19 C20 O4 -39.3(7) . .
C14 C19 C20 O4 145.0(5) . .
C18 C19 C20 O3 137.4(4) . .
C14 C19 C20 O3 -38.2(6) . .
Eu1 O6 C21 O5 -1.3(5) 1_566 .
Eu1 O6 C21 C22 -174.0(3) 1_566 .
Eu1 O5 C21 O6 1.2(4) 1_566 .
Eu1 O5 C21 C22 173.9(3) 1_566 .
O6 C21 C22 C23 129.5(5) . .
O5 C21 C22 C23 -43.4(6) . .
Eu1 C21 C22 C23 74(3) 1_566 .
O6 C21 C22 C27 -40.2(6) . .
O5 C21 C22 C27 146.9(4) . .
Eu1 C21 C22 C27 -96(3) 1_566 .
C27 C22 C23 C24 5.2(7) . .
C21 C22 C23 C24 -164.8(4) . .
C22 C23 C24 C25 -0.2(7) . .
C23 C24 C25 C26 -4.0(7) . .
C23 C24 C25 S1 173.8(4) . .
O10 S1 C25 C26 -23.3(4) . .
O9 S1 C25 C26 -155.2(4) . .
C17 S1 C25 C26 90.9(4) . .
O10 S1 C25 C24 158.9(4) . .
O9 S1 C25 C24 27.0(4) . .
C17 S1 C25 C24 -86.8(4) . .
C24 C25 C26 C27 3.0(7) . .
S1 C25 C26 C27 -174.8(3) . .
C25 C26 C27 C22 2.2(7) . .
C25 C26 C27 C28 -174.5(4) . .
C23 C22 C27 C26 -6.2(6) . .
C21 C22 C27 C26 163.4(4) . .
C23 C22 C27 C28 170.2(4) . .
C21 C22 C27 C28 -20.2(7) . .
Eu1 O8 C28 O7 10.4(5) 2_657 .
Eu1 O8 C28 C27 -169.3(4) 2_657 .
Eu1 O7 C28 O8 -10.8(5) 2_657 .
Eu1 O7 C28 C27 168.9(4) 2_657 .
C26 C27 C28 O8 -27.4(6) . .
C22 C27 C28 O8 156.0(4) . .
C26 C27 C28 O7 152.9(4) . .
C22 C27 C28 O7 -23.7(7) . .
C26 C27 C28 Eu1 -128.1(17) . 2_657
C22 C27 C28 Eu1 55(2) . 2_657
