#------------------------------------------------------------------------------
#$Date: 2017-01-09 05:18:09 +0200 (Mon, 09 Jan 2017) $
#$Revision: 190121 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/10/7041056.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7041056
loop_
_publ_author_name
'Wei, Yongqin'
'Sa, Rongjian'
'Wu, Kechen'
_publ_section_title
;
 A highly stable and white-light-emitting Eu(iii) MOF.
;
_journal_issue                   46
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              18661
_journal_page_last               18667
_journal_paper_doi               10.1039/c6dt03655d
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C20 H16 Eu N4 O11 S2'
_chemical_formula_weight         704.45
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2016-09-20 deposited with the CCDC.
2016-10-26 downloaded from the CCDC.
;
_cell_angle_alpha                97.866(8)
_cell_angle_beta                 91.933(3)
_cell_angle_gamma                115.337(14)
_cell_formula_units_Z            2
_cell_length_a                   9.912(8)
_cell_length_b                   10.882(9)
_cell_length_c                   11.977(9)
_cell_measurement_reflns_used    3642
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.5087
_cell_measurement_theta_min      2.1004
_cell_volume                     1150.4(16)
_computing_cell_refinement       'CrystalClear (Rigaku Inc., 2007)'
_computing_data_collection       'CrystalClear (Rigaku Inc., 2007)'
_computing_data_reduction        'CrystalClear (Rigaku Inc., 2007)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.922
_diffrn_measured_fraction_theta_max 0.952
_diffrn_measurement_device_type  CCD_Profile_fitting
_diffrn_measurement_method       'ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0367
_diffrn_reflns_av_sigmaI/netI    0.0696
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            8853
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.49
_diffrn_reflns_theta_min         2.83
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.980
_exptl_absorpt_correction_T_max  0.893
_exptl_absorpt_correction_T_min  0.801
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Sphere (Rigaku CrystalClear)'
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    2.034
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             694
_exptl_crystal_size_max          0.252
_exptl_crystal_size_mid          0.062
_exptl_crystal_size_min          0.038
_refine_diff_density_max         1.188
_refine_diff_density_min         -0.993
_refine_diff_density_rms         0.152
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.989
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     347
_refine_ls_number_reflns         4878
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.989
_refine_ls_R_factor_all          0.0402
_refine_ls_R_factor_gt           0.0336
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0312P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0713
_refine_ls_wR_factor_ref         0.0743
_reflns_number_gt                4358
_reflns_number_total             4878
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6dt03655d2.cif
_cod_data_source_block           2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7041055--7041056.cif.
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7041056
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu Eu 0.04534(2) 0.745942(19) 0.396222(17) 0.00791(7) Uani 1 1 d .
S1 S 0.74792(10) 0.43444(9) -0.50885(9) 0.0083(2) Uani 1 1 d .
S2 S 0.27986(10) 0.22910(10) -0.26778(9) 0.0089(2) Uani 1 1 d .
O1 O 0.8224(3) 0.5608(3) -0.5562(2) 0.0103(6) Uani 1 1 d .
O2 O 0.8589(3) 0.4028(3) -0.4504(2) 0.0111(6) Uani 1 1 d .
O3 O 0.6445(3) 0.3182(3) -0.5904(2) 0.0137(6) Uani 1 1 d .
O4 O 0.1548(3) 0.2658(3) -0.2779(2) 0.0115(6) Uani 1 1 d .
O5 O 0.3014(3) 0.2051(3) -0.1535(2) 0.0107(6) Uani 1 1 d .
O7 O -0.0479(3) 0.8430(3) 0.5462(2) 0.0122(6) Uani 1 1 d .
O8 O -0.0965(3) 1.0198(3) 0.6147(2) 0.0092(6) Uani 1 1 d .
O9 O 0.2681(3) 0.8822(3) 0.5297(3) 0.0166(7) Uani 1 1 d .
N1 N 0.2431(4) 0.8274(3) 0.2574(3) 0.0100(7) Uani 1 1 d .
N2 N 0.0222(3) 0.5659(3) 0.2254(3) 0.0092(7) Uani 1 1 d .
N3 N 0.4626(4) 0.6768(3) -0.0691(3) 0.0095(7) Uani 1 1 d .
N4 N 0.3089(4) 0.4557(3) -0.0686(3) 0.0105(7) Uani 1 1 d .
H4B H 0.2682 0.3673 -0.0866 0.013 Uiso 1 1 calc R
C1 C 0.3452(4) 0.9586(4) 0.2682(4) 0.0130(9) Uani 1 1 d .
H1B H 0.3412 1.0223 0.3267 0.016 Uiso 1 1 calc R
C2 C 0.4579(4) 1.0048(4) 0.1959(4) 0.0131(9) Uani 1 1 d .
H2B H 0.5246 1.0978 0.2050 0.016 Uiso 1 1 calc R
C3 C 0.4694(4) 0.9129(4) 0.1120(4) 0.0116(9) Uani 1 1 d .
H3C H 0.5452 0.9418 0.0644 0.014 Uiso 1 1 calc R
C4 C 0.3647(4) 0.7732(4) 0.0986(4) 0.0091(8) Uani 1 1 d .
C5 C 0.3704(4) 0.6668(4) 0.0150(3) 0.0094(8) Uani 1 1 d .
C6 C 0.2722(4) 0.5305(4) 0.0160(4) 0.0098(9) Uani 1 1 d .
C7 C 0.1506(4) 0.4877(4) 0.0844(3) 0.0104(9) Uani 1 1 d .
C8 C 0.0383(4) 0.3524(4) 0.0756(4) 0.0135(9) Uani 1 1 d .
H8A H 0.0438 0.2808 0.0268 0.016 Uiso 1 1 calc R
C9 C -0.0798(5) 0.3270(4) 0.1397(4) 0.0141(9) Uani 1 1 d .
H9B H -0.1560 0.2381 0.1345 0.017 Uiso 1 1 calc R
C10 C -0.0839(4) 0.4365(4) 0.2130(4) 0.0118(9) Uani 1 1 d .
H10A H -0.1651 0.4181 0.2555 0.014 Uiso 1 1 calc R
C11 C 0.2526(4) 0.7356(4) 0.1723(3) 0.0086(8) Uani 1 1 d .
C12 C 0.1393(4) 0.5918(4) 0.1605(3) 0.0080(8) Uani 1 1 d .
C13 C 0.4219(4) 0.5470(4) -0.1190(3) 0.0096(9) Uani 1 1 d .
C14 C 0.4921(4) 0.5101(4) -0.2166(3) 0.0081(8) Uani 1 1 d .
C15 C 0.6200(4) 0.6181(4) -0.2452(4) 0.0129(9) Uani 1 1 d .
H15A H 0.6541 0.7056 -0.2022 0.015 Uiso 1 1 calc R
C16 C 0.6973(4) 0.5992(4) -0.3352(4) 0.0122(9) Uani 1 1 d .
H16A H 0.7824 0.6725 -0.3515 0.015 Uiso 1 1 calc R
C18 C 0.5183(4) 0.3598(4) -0.3765(4) 0.0110(9) Uani 1 1 d .
H18A H 0.4840 0.2733 -0.4213 0.013 Uiso 1 1 calc R
C19 C 0.4421(4) 0.3793(4) -0.2859(4) 0.0091(8) Uani 1 1 d .
C20 C -0.0418(4) 0.9604(4) 0.5465(3) 0.0094(9) Uani 1 1 d .
O6 O 0.2677(3) 0.1189(3) -0.3565(3) 0.0122(6) Uani 1 1 d .
C17 C 0.6456(4) 0.4693(4) -0.4004(3) 0.0091(8) Uani 1 1 d .
O1W O -0.1733(4) 0.0183(3) 0.0375(3) 0.0238(8) Uani 1 1 d .
O2W O 0.9018(4) 0.9285(3) -0.1655(3) 0.0282(8) Uani 1 1 d .
H1 H 0.2456 0.9316 0.5804 0.056(9) Uiso 1 1 d R
H6 H 0.9339 0.9558 -0.2268 0.056(9) Uiso 1 1 d R
H5 H 0.9920 0.9427 -0.1497 0.056(9) Uiso 1 1 d R
H2 H 0.2956 0.8411 0.5746 0.056(9) Uiso 1 1 d R
H4 H -0.1477 -0.0087 -0.0251 0.056(9) Uiso 1 1 d R
H3 H -0.231(7) -0.060(6) 0.057(5) 0.056(9) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O4 Eu O2 138.64(9) 2_565 2_665
O4 Eu O7 86.80(11) 2_565 .
O2 Eu O7 113.57(11) 2_665 .
O4 Eu O8 74.00(9) 2_565 2_576
O2 Eu O8 146.15(9) 2_665 2_576
O7 Eu O8 68.07(10) . 2_576
O4 Eu O1 74.11(11) 2_565 1_456
O2 Eu O1 78.24(11) 2_665 1_456
O7 Eu O1 72.72(11) . 1_456
O8 Eu O1 130.05(10) 2_576 1_456
O4 Eu O9 149.53(10) 2_565 .
O2 Eu O9 71.83(11) 2_665 .
O7 Eu O9 76.95(12) . .
O8 Eu O9 76.05(10) 2_576 .
O1 Eu O9 123.41(11) 1_456 .
O4 Eu N1 96.32(12) 2_565 .
O2 Eu N1 90.88(11) 2_665 .
O7 Eu N1 138.61(10) . .
O8 Eu N1 73.20(10) 2_576 .
O1 Eu N1 147.68(10) 1_456 .
O9 Eu N1 80.17(12) . .
O4 Eu N2 76.86(11) 2_565 .
O2 Eu N2 70.01(11) 2_665 .
O7 Eu N2 154.33(10) . .
O8 Eu N2 124.18(11) 2_576 .
O1 Eu N2 83.73(11) 1_456 .
O9 Eu N2 126.07(11) . .
N1 Eu N2 63.97(11) . .
O4 Eu C20 79.49(11) 2_565 .
O2 Eu C20 130.29(11) 2_665 .
O7 Eu C20 20.06(9) . .
O8 Eu C20 48.16(10) 2_576 .
O1 Eu C20 88.81(11) 1_456 .
O9 Eu C20 76.50(11) . .
N1 Eu C20 120.32(11) . .
N2 Eu C20 156.32(10) . .
O4 Eu C20 73.92(10) 2_565 2_576
O2 Eu C20 146.42(10) 2_665 2_576
O7 Eu C20 48.05(9) . 2_576
O8 Eu C20 20.17(10) 2_576 2_576
O1 Eu C20 112.76(11) 1_456 2_576
O9 Eu C20 76.06(10) . 2_576
N1 Eu C20 93.15(11) . 2_576
N2 Eu C20 140.31(10) . 2_576
C20 Eu C20 28.04(14) . 2_576
O4 Eu H1 136.9 2_565 .
O2 Eu H1 83.1 2_665 .
O7 Eu H1 60.5 . .
O8 Eu H1 68.3 2_576 .
O1 Eu H1 116.1 1_456 .
O9 Eu H1 16.8 . .
N1 Eu H1 92.2 . .
N2 Eu H1 142.8 . .
C20 Eu H1 60.0 . .
C20 Eu H1 63.5 2_576 .
O3 S1 O1 113.73(18) . .
O3 S1 O2 112.02(17) . .
O1 S1 O2 110.52(16) . .
O3 S1 C17 108.32(18) . .
O1 S1 C17 106.92(18) . .
O2 S1 C17 104.78(19) . .
O6 S2 O5 114.40(17) . .
O6 S2 O4 112.88(17) . .
O5 S2 O4 110.10(17) . .
O6 S2 C19 107.02(19) . .
O5 S2 C19 106.50(17) . .
O4 S2 C19 105.25(18) . .
S1 O1 Eu 151.65(17) . 1_654
S1 O2 Eu 153.99(17) . 2_665
S2 O4 Eu 146.43(18) . 2_565
C20 O7 Eu 119.4(3) . .
C20 O8 Eu 118.4(2) . 2_576
Eu O9 H1 107.8 . .
Eu O9 H2 118.3 . .
H1 O9 H2 96.6 . .
C1 N1 C11 117.4(4) . .
C1 N1 Eu 122.0(3) . .
C11 N1 Eu 120.5(2) . .
C10 N2 C12 117.5(4) . .
C10 N2 Eu 121.3(3) . .
C12 N2 Eu 119.4(2) . .
C13 N3 C5 104.9(3) . .
C13 N4 C6 107.5(3) . .
C13 N4 H4B 126.3 . .
C6 N4 H4B 126.3 . .
N1 C1 C2 123.2(4) . .
N1 C1 H1B 118.4 . .
C2 C1 H1B 118.4 . .
C3 C2 C1 119.6(4) . .
C3 C2 H2B 120.2 . .
C1 C2 H2B 120.2 . .
C2 C3 C4 119.0(4) . .
C2 C3 H3C 120.5 . .
C4 C3 H3C 120.5 . .
C11 C4 C3 118.1(4) . .
C11 C4 C5 118.6(3) . .
C3 C4 C5 123.3(4) . .
N3 C5 C6 110.9(4) . .
N3 C5 C4 130.1(4) . .
C6 C5 C4 119.0(4) . .
N4 C6 C5 105.2(4) . .
N4 C6 C7 130.3(4) . .
C5 C6 C7 124.2(4) . .
C8 C7 C12 118.5(4) . .
C8 C7 C6 125.0(4) . .
C12 C7 C6 116.4(4) . .
C9 C8 C7 119.1(4) . .
C9 C8 H8A 120.4 . .
C7 C8 H8A 120.4 . .
C8 C9 C10 119.0(4) . .
C8 C9 H9B 120.5 . .
C10 C9 H9B 120.5 . .
N2 C10 C9 123.6(4) . .
N2 C10 H10A 118.2 . .
C9 C10 H10A 118.2 . .
N1 C11 C4 122.8(4) . .
N1 C11 C12 117.1(4) . .
C4 C11 C12 120.2(4) . .
N2 C12 C7 122.2(4) . .
N2 C12 C11 116.8(4) . .
C7 C12 C11 120.9(4) . .
N3 C13 N4 111.5(4) . .
N3 C13 C14 123.1(3) . .
N4 C13 C14 125.4(4) . .
C15 C14 C19 116.9(4) . .
C15 C14 C13 115.9(4) . .
C19 C14 C13 127.2(3) . .
C16 C15 C14 122.5(4) . .
C16 C15 H15A 118.8 . .
C14 C15 H15A 118.8 . .
C15 C16 C17 119.0(4) . .
C15 C16 H16A 120.5 . .
C17 C16 H16A 120.5 . .
C19 C18 C17 120.0(4) . .
C19 C18 H18A 120.0 . .
C17 C18 H18A 120.0 . .
C18 C19 C14 121.0(3) . .
C18 C19 S2 114.4(3) . .
C14 C19 S2 124.6(3) . .
O8 C20 O7 126.5(4) . .
O8 C20 C20 116.9(4) . 2_576
O7 C20 C20 116.7(5) . 2_576
O8 C20 Eu 166.3(3) . .
O7 C20 Eu 40.5(2) . .
C20 C20 Eu 76.4(3) 2_576 .
O8 C20 Eu 41.42(18) . 2_576
O7 C20 Eu 167.2(3) . 2_576
C20 C20 Eu 75.6(3) 2_576 2_576
Eu C20 Eu 151.96(14) . 2_576
C18 C17 C16 120.7(4) . .
C18 C17 S1 117.8(3) . .
C16 C17 S1 121.3(3) . .
H4 O1W H3 101.4 . .
H6 O2W H5 83.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu O4 2.346(3) 2_565
Eu O2 2.346(3) 2_665
Eu O7 2.372(3) .
Eu O8 2.400(3) 2_576
Eu O1 2.420(3) 1_456
Eu O9 2.437(3) .
Eu N1 2.555(4) .
Eu N2 2.562(4) .
Eu C20 3.180(5) .
Eu C20 3.191(5) 2_576
Eu H1 2.8176 .
S1 O3 1.445(3) .
S1 O1 1.460(3) .
S1 O2 1.468(3) .
S1 C17 1.773(4) .
S2 O6 1.449(3) .
S2 O5 1.453(3) .
S2 O4 1.463(3) .
S2 C19 1.782(4) .
O1 Eu 2.420(3) 1_654
O2 Eu 2.346(3) 2_665
O4 Eu 2.346(3) 2_565
O7 C20 1.252(5) .
O8 C20 1.251(5) .
O8 Eu 2.400(3) 2_576
O9 H1 0.8535 .
O9 H2 0.8511 .
N1 C1 1.336(5) .
N1 C11 1.361(5) .
N2 C10 1.333(5) .
N2 C12 1.368(5) .
N3 C13 1.335(5) .
N3 C5 1.367(5) .
N4 C13 1.365(5) .
N4 C6 1.369(5) .
N4 H4B 0.8600 .
C1 C2 1.398(6) .
C1 H1B 0.9300 .
C2 C3 1.361(6) .
C2 H2B 0.9300 .
C3 C4 1.409(5) .
C3 H3C 0.9300 .
C4 C11 1.400(6) .
C4 C5 1.445(6) .
C5 C6 1.384(5) .
C6 C7 1.425(6) .
C7 C8 1.402(5) .
C7 C12 1.400(6) .
C8 C9 1.370(6) .
C8 H8A 0.9300 .
C9 C10 1.396(6) .
C9 H9B 0.9300 .
C10 H10A 0.9300 .
C11 C12 1.467(5) .
C13 C14 1.476(6) .
C14 C15 1.404(5) .
C14 C19 1.416(5) .
C15 C16 1.386(6) .
C15 H15A 0.9300 .
C16 C17 1.386(6) .
C16 H16A 0.9300 .
C18 C19 1.387(6) .
C18 C17 1.388(5) .
C18 H18A 0.9300 .
C20 C20 1.544(8) 2_576
C20 Eu 3.191(5) 2_576
O1W H4 0.8545 .
O1W H3 0.87(6) .
O2W H6 0.8500 .
O2W H5 0.8500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O3 S1 O1 Eu -118.0(4) . 1_654
O2 S1 O1 Eu 9.0(4) . 1_654
C17 S1 O1 Eu 122.5(4) . 1_654
O3 S1 O2 Eu -14.0(5) . 2_665
O1 S1 O2 Eu -141.9(4) . 2_665
C17 S1 O2 Eu 103.2(4) . 2_665
O6 S2 O4 Eu -18.0(4) . 2_565
O5 S2 O4 Eu -147.2(3) . 2_565
C19 S2 O4 Eu 98.4(3) . 2_565
O4 Eu O7 C20 -67.7(3) 2_565 .
O2 Eu O7 C20 149.6(3) 2_665 .
O8 Eu O7 C20 6.3(3) 2_576 .
O1 Eu O7 C20 -142.1(3) 1_456 .
O9 Eu O7 C20 86.3(3) . .
N1 Eu O7 C20 28.2(3) . .
N2 Eu O7 C20 -117.8(3) . .
C20 Eu O7 C20 3.5(3) 2_576 .
O4 Eu N1 C1 102.9(3) 2_565 .
O2 Eu N1 C1 -117.9(3) 2_665 .
O7 Eu N1 C1 10.5(4) . .
O8 Eu N1 C1 31.7(3) 2_576 .
O1 Eu N1 C1 173.0(3) 1_456 .
O9 Eu N1 C1 -46.6(3) . .
N2 Eu N1 C1 174.9(3) . .
C20 Eu N1 C1 21.4(3) . .
C20 Eu N1 C1 28.7(3) 2_576 .
O4 Eu N1 C11 -80.6(3) 2_565 .
O2 Eu N1 C11 58.6(3) 2_665 .
O7 Eu N1 C11 -173.0(2) . .
O8 Eu N1 C11 -151.8(3) 2_576 .
O1 Eu N1 C11 -10.5(4) 1_456 .
O9 Eu N1 C11 130.0(3) . .
N2 Eu N1 C11 -8.6(3) . .
C20 Eu N1 C11 -162.1(3) . .
C20 Eu N1 C11 -154.8(3) 2_576 .
O4 Eu N2 C10 -78.5(3) 2_565 .
O2 Eu N2 C10 76.3(3) 2_665 .
O7 Eu N2 C10 -26.7(4) . .
O8 Eu N2 C10 -138.5(3) 2_576 .
O1 Eu N2 C10 -3.4(3) 1_456 .
O9 Eu N2 C10 123.8(3) . .
N1 Eu N2 C10 177.6(3) . .
C20 Eu N2 C10 -75.8(4) . .
C20 Eu N2 C10 -121.9(3) 2_576 .
O4 Eu N2 C12 117.2(3) 2_565 .
O2 Eu N2 C12 -87.9(3) 2_665 .
O7 Eu N2 C12 169.0(2) . .
O8 Eu N2 C12 57.3(3) 2_576 .
O1 Eu N2 C12 -167.7(3) 1_456 .
O9 Eu N2 C12 -40.4(3) . .
N1 Eu N2 C12 13.3(3) . .
C20 Eu N2 C12 119.9(3) . .
C20 Eu N2 C12 73.8(3) 2_576 .
C11 N1 C1 C2 1.0(6) . .
Eu N1 C1 C2 177.6(3) . .
N1 C1 C2 C3 -2.2(6) . .
C1 C2 C3 C4 1.4(6) . .
C2 C3 C4 C11 0.3(6) . .
C2 C3 C4 C5 -177.7(4) . .
C13 N3 C5 C6 -0.5(4) . .
C13 N3 C5 C4 178.3(4) . .
C11 C4 C5 N3 176.5(4) . .
C3 C4 C5 N3 -5.4(6) . .
C11 C4 C5 C6 -4.8(5) . .
C3 C4 C5 C6 173.3(4) . .
C13 N4 C6 C5 -1.8(4) . .
C13 N4 C6 C7 171.1(4) . .
N3 C5 C6 N4 1.4(4) . .
C4 C5 C6 N4 -177.5(3) . .
N3 C5 C6 C7 -172.0(3) . .
C4 C5 C6 C7 9.0(6) . .
N4 C6 C7 C8 -0.9(7) . .
C5 C6 C7 C8 170.8(4) . .
N4 C6 C7 C12 -176.6(4) . .
C5 C6 C7 C12 -4.8(6) . .
C12 C7 C8 C9 1.2(6) . .
C6 C7 C8 C9 -174.4(4) . .
C7 C8 C9 C10 -0.7(6) . .
C12 N2 C10 C9 1.4(6) . .
Eu N2 C10 C9 -163.2(3) . .
C8 C9 C10 N2 -0.7(6) . .
C1 N1 C11 C4 0.9(6) . .
Eu N1 C11 C4 -175.7(3) . .
C1 N1 C11 C12 -179.5(3) . .
Eu N1 C11 C12 3.8(4) . .
C3 C4 C11 N1 -1.6(6) . .
C5 C4 C11 N1 176.6(3) . .
C3 C4 C11 C12 178.9(3) . .
C5 C4 C11 C12 -3.0(5) . .
C10 N2 C12 C7 -0.8(5) . .
Eu N2 C12 C7 164.1(3) . .
C10 N2 C12 C11 178.0(3) . .
Eu N2 C12 C11 -17.1(4) . .
C8 C7 C12 N2 -0.5(6) . .
C6 C7 C12 N2 175.5(3) . .
C8 C7 C12 C11 -179.3(3) . .
C6 C7 C12 C11 -3.3(5) . .
N1 C11 C12 N2 8.8(5) . .
C4 C11 C12 N2 -171.7(3) . .
N1 C11 C12 C7 -172.4(3) . .
C4 C11 C12 C7 7.2(6) . .
C5 N3 C13 N4 -0.7(4) . .
C5 N3 C13 C14 179.0(3) . .
C6 N4 C13 N3 1.7(4) . .
C6 N4 C13 C14 -178.1(4) . .
N3 C13 C14 C15 8.7(5) . .
N4 C13 C14 C15 -171.5(4) . .
N3 C13 C14 C19 -169.3(4) . .
N4 C13 C14 C19 10.4(6) . .
C19 C14 C15 C16 -1.4(6) . .
C13 C14 C15 C16 -179.6(4) . .
C14 C15 C16 C17 0.8(6) . .
C17 C18 C19 C14 0.1(6) . .
C17 C18 C19 S2 179.3(3) . .
C15 C14 C19 C18 0.9(5) . .
C13 C14 C19 C18 178.9(4) . .
C15 C14 C19 S2 -178.2(3) . .
C13 C14 C19 S2 -0.2(6) . .
O6 S2 C19 C18 0.1(3) . .
O5 S2 C19 C18 122.9(3) . .
O4 S2 C19 C18 -120.2(3) . .
O6 S2 C19 C14 179.2(3) . .
O5 S2 C19 C14 -58.0(4) . .
O4 S2 C19 C14 58.9(4) . .
Eu O8 C20 O7 174.2(3) 2_576 .
Eu O8 C20 C20 -5.6(5) 2_576 2_576
Eu O8 C20 Eu -169.6(10) 2_576 .
Eu O7 C20 O8 174.2(3) . .
Eu O7 C20 C20 -6.0(5) . 2_576
Eu O7 C20 Eu -168.3(10) . 2_576
O4 Eu C20 O8 89.9(11) 2_565 .
O2 Eu C20 O8 -57.6(11) 2_665 .
O7 Eu C20 O8 -20.2(10) . .
O8 Eu C20 O8 167.7(11) 2_576 .
O1 Eu C20 O8 15.8(11) 1_456 .
O9 Eu C20 O8 -109.0(11) . .
N1 Eu C20 O8 -178.9(11) . .
N2 Eu C20 O8 87.2(11) . .
C20 Eu C20 O8 165.3(13) 2_576 .
O4 Eu C20 O7 110.0(3) 2_565 .
O2 Eu C20 O7 -37.5(3) 2_665 .
O8 Eu C20 O7 -172.1(3) 2_576 .
O1 Eu C20 O7 36.0(3) 1_456 .
O9 Eu C20 O7 -88.9(3) . .
N1 Eu C20 O7 -158.8(3) . .
N2 Eu C20 O7 107.3(3) . .
C20 Eu C20 O7 -174.5(5) 2_576 .
O4 Eu C20 C20 -75.5(3) 2_565 2_576
O2 Eu C20 C20 137.0(2) 2_665 2_576
O7 Eu C20 C20 174.5(5) . 2_576
O8 Eu C20 C20 2.4(2) 2_576 2_576
O1 Eu C20 C20 -149.5(3) 1_456 2_576
O9 Eu C20 C20 85.6(3) . 2_576
N1 Eu C20 C20 15.8(3) . 2_576
N2 Eu C20 C20 -78.1(4) . 2_576
O4 Eu C20 Eu -75.5(3) 2_565 2_576
O2 Eu C20 Eu 137.0(2) 2_665 2_576
O7 Eu C20 Eu 174.5(5) . 2_576
O8 Eu C20 Eu 2.4(2) 2_576 2_576
O1 Eu C20 Eu -149.5(3) 1_456 2_576
O9 Eu C20 Eu 85.6(3) . 2_576
N1 Eu C20 Eu 15.7(3) . 2_576
N2 Eu C20 Eu -78.1(4) . 2_576
C20 Eu C20 Eu 0.0 2_576 2_576
C19 C18 C17 C16 -0.7(6) . .
C19 C18 C17 S1 174.2(3) . .
C15 C16 C17 C18 0.2(6) . .
C15 C16 C17 S1 -174.5(3) . .
O3 S1 C17 C18 29.3(4) . .
O1 S1 C17 C18 152.2(3) . .
O2 S1 C17 C18 -90.5(3) . .
O3 S1 C17 C16 -155.9(3) . .
O1 S1 C17 C16 -32.9(4) . .
O2 S1 C17 C16 84.4(3) . .
