#------------------------------------------------------------------------------
#$Date: 2017-02-04 15:55:35 +0200 (Sat, 04 Feb 2017) $
#$Revision: 191625 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/13/7041352.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7041352
loop_
_publ_author_name
'Hanf, S.'
'García-Rodríguez, R'
'Feldmann, S.'
'Bond, A. D.'
'Hey-Hawkins, E'
'Wright, D. S.'
_publ_section_title
;
 Multidentate 2-pyridyl-phosphine ligands - towards ligand tuning and
 chirality.
;
_journal_issue                   3
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              814
_journal_page_last               824
_journal_paper_doi               10.1039/c6dt04390a
_journal_volume                  46
_journal_year                    2017
_chemical_formula_moiety         'C40 H60 Cl6 Li6 N6 O4 P2'
_chemical_formula_sum            'C40 H60 Cl6 Li6 N6 O4 P2'
_chemical_formula_weight         1005.22
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-09-22 deposited with the CCDC.
2016-12-07 downloaded from the CCDC.
;
_cell_angle_alpha                105.4860(14)
_cell_angle_beta                 99.1063(14)
_cell_angle_gamma                115.1390(13)
_cell_formula_units_Z            1
_cell_length_a                   10.9913(3)
_cell_length_b                   11.7487(3)
_cell_length_c                   12.2632(4)
_cell_measurement_reflns_used    9912
_cell_measurement_temperature    180(2)
_cell_measurement_theta_max      66.61
_cell_measurement_theta_min      3.94
_cell_volume                     1312.84(7)
_computing_cell_refinement       'SAINT (Bruker, 2014)'
_computing_data_collection       'APEX2 (Bruker, 2014)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'Mercury (Macrae et al., 2008)'
_computing_publication_material  SHELXL
_computing_structure_refinement  'SHELXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      180(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker D8-QUEST PHOTON-100'
_diffrn_measurement_method       'ω and φ-scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0529
_diffrn_reflns_av_unetI/netI     0.0311
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            36815
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        66.733
_diffrn_reflns_theta_max         66.733
_diffrn_reflns_theta_min         3.936
_diffrn_source                   'Incoatec I\mS Cu microsource'
_exptl_absorpt_coefficient_mu    3.894
_exptl_absorpt_correction_T_max  0.7528
_exptl_absorpt_correction_T_min  0.5921
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 2014)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.271
_exptl_crystal_description       block
_exptl_crystal_F_000             524
_exptl_crystal_size_max          0.130
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.090
_refine_diff_density_max         0.808
_refine_diff_density_min         -0.419
_refine_diff_density_rms         0.065
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     291
_refine_ls_number_reflns         4628
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.046
_refine_ls_R_factor_all          0.0625
_refine_ls_R_factor_gt           0.0455
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0564P)²+1.7735P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1153
_refine_ls_wR_factor_ref         0.1246
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3711
_reflns_number_total             4628
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6dt04390a2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 7041350--7041357.cif.'
_cod_database_code               7041352
_cambridge_user_name             'Schirin Hanf'
_cambridge_user_crsid            sh811
_cambridge_supervisor_name       'Dominic Wright'
_cambridge_supervisor_crsid      dsw1000
_cambridge_crystallographer_name 'Andrew Bond'
_cambridge_crystallographer_crsid adb29
_cambridge_sample_id             SH142
_cambridge_data_id               DW_B1_0137
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.631
_shelx_estimated_absorpt_t_max   0.721
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Cl1 Cl 0.57931(8) 0.32960(8) 0.55476(7) 0.0349(2) Uani 1 1 d . .
Cl2 Cl 0.30843(7) 0.46902(7) 0.61887(6) 0.02755(18) Uani 1 1 d . .
Cl3 Cl 0.27237(8) 0.26653(8) 0.27761(7) 0.0383(2) Uani 1 1 d . .
Li1 Li 0.4053(5) 0.3290(5) 0.6368(4) 0.0285(11) Uani 1 1 d . .
Li2 Li 0.4940(6) 0.6848(5) 0.6431(5) 0.0351(12) Uani 1 1 d . .
Li3 Li 0.2608(5) 0.4433(5) 0.4153(5) 0.0320(11) Uani 1 1 d . .
O1 O 0.0746(2) 0.4257(2) 0.3543(2) 0.0457(6) Uani 1 1 d . .
O2 O 0.4734(3) 0.8369(3) 0.7369(3) 0.0619(8) Uani 1 1 d . .
P1 P 0.19684(8) 0.22827(7) 0.79144(7) 0.02558(19) Uani 1 1 d . .
N1 N 0.2564(2) 0.1313(2) 0.5919(2) 0.0254(5) Uani 1 1 d . .
N2 N 0.1145(3) 0.1487(3) 0.8734(2) 0.0361(6) Uani 1 1 d . .
N3 N 0.4756(2) 0.3503(2) 0.8091(2) 0.0263(5) Uani 1 1 d . .
C1 C -0.0315(4) 0.3191(4) 0.2515(4) 0.0723(15) Uani 1 1 d . .
H1A H -0.1042 0.2521 0.2737 0.087 Uiso 1 1 calc R U
H1B H 0.0095 0.2726 0.2027 0.087 Uiso 1 1 calc R U
C2 C -0.0953(7) 0.3764(5) 0.1838(5) 0.120(3) Uani 1 1 d . .
H2A H -0.1956 0.3430 0.1806 0.144 Uiso 1 1 calc R U
H2B H -0.0909 0.3509 0.1013 0.144 Uiso 1 1 calc R U
C3 C -0.0105(5) 0.5276(4) 0.2485(4) 0.0601(11) Uani 1 1 d . .
H3A H 0.0648 0.5694 0.2142 0.072 Uiso 1 1 calc R U
H3B H -0.0714 0.5700 0.2474 0.072 Uiso 1 1 calc R U
C4 C 0.0495(4) 0.5389(4) 0.3706(4) 0.0538(10) Uani 1 1 d . .
H4A H 0.1389 0.6257 0.4136 0.065 Uiso 1 1 calc R U
H4B H -0.0180 0.5340 0.4163 0.065 Uiso 1 1 calc R U
C5 C 0.4116(6) 0.9045(6) 0.6860(5) 0.112(3) Uani 1 1 d . .
H5A H 0.3887 0.8695 0.5983 0.135 Uiso 1 1 calc R U
H5B H 0.3237 0.8903 0.7060 0.135 Uiso 1 1 calc R U
C6 C 0.5143(11) 1.0434(7) 0.7361(8) 0.167(4) Uani 1 1 d . .
H6A H 0.5711 1.0670 0.6825 0.200 Uiso 1 1 calc R U
H6B H 0.4680 1.1000 0.7484 0.200 Uiso 1 1 calc R U
C7 C 0.5997(7) 1.0658(6) 0.8438(8) 0.154(4) Uani 1 1 d . .
H7A H 0.5800 1.1168 0.9106 0.185 Uiso 1 1 calc R U
H7B H 0.7006 1.1188 0.8508 0.185 Uiso 1 1 calc R U
C8 C 0.5676(8) 0.9327(6) 0.8467(4) 0.108(2) Uani 1 1 d . .
H8A H 0.6551 0.9262 0.8623 0.129 Uiso 1 1 calc R U
H8B H 0.5251 0.9181 0.9106 0.129 Uiso 1 1 calc R U
C11 C 0.1742(3) 0.0911(3) 0.6597(3) 0.0249(6) Uani 1 1 d . .
C12 C 0.0684(3) -0.0430(3) 0.6247(3) 0.0294(7) Uani 1 1 d . .
H12 H 0.0089 -0.0685 0.6721 0.035 Uiso 1 1 calc R U
C13 C 0.0512(3) -0.1386(3) 0.5201(3) 0.0352(7) Uani 1 1 d . .
H13 H -0.0197 -0.2307 0.4951 0.042 Uiso 1 1 calc R U
C14 C 0.1382(3) -0.0983(3) 0.4531(3) 0.0350(7) Uani 1 1 d . .
H14 H 0.1296 -0.1623 0.3818 0.042 Uiso 1 1 calc R U
C15 C 0.2384(3) 0.0370(3) 0.4914(3) 0.0312(7) Uani 1 1 d . .
H15 H 0.2975 0.0645 0.4442 0.037 Uiso 1 1 calc R U
C21 C 0.1361(4) 0.0490(3) 0.9119(3) 0.0450(9) Uani 1 1 d . .
H21A H 0.1668 0.0821 0.9991 0.067 Uiso 1 1 calc R U
H21B H 0.2087 0.0355 0.8825 0.067 Uiso 1 1 calc R U
H21C H 0.0472 -0.0372 0.8799 0.067 Uiso 1 1 calc R U
C22 C 0.0084(5) 0.1744(5) 0.9115(5) 0.0717(14) Uani 1 1 d . .
H22A H -0.0825 0.0900 0.8785 0.108 Uiso 1 1 calc R U
H22B H -0.0005 0.2419 0.8834 0.108 Uiso 1 1 calc R U
H22C H 0.0358 0.2086 0.9987 0.108 Uiso 1 1 calc R U
C31 C 0.3869(3) 0.3026(3) 0.8702(3) 0.0252(6) Uani 1 1 d . .
C32 C 0.4366(3) 0.3229(3) 0.9892(3) 0.0313(7) Uani 1 1 d . .
H32 H 0.3724 0.2918 1.0318 0.038 Uiso 1 1 calc R U
C33 C 0.5812(4) 0.3891(3) 1.0445(3) 0.0369(8) Uani 1 1 d . .
H33 H 0.6173 0.4031 1.1255 0.044 Uiso 1 1 calc R U
C34 C 0.6720(3) 0.4343(3) 0.9815(3) 0.0363(8) Uani 1 1 d . .
H34 H 0.7715 0.4786 1.0175 0.044 Uiso 1 1 calc R U
C35 C 0.6150(3) 0.4136(3) 0.8647(3) 0.0318(7) Uani 1 1 d . .
H35 H 0.6779 0.4459 0.8215 0.038 Uiso 1 1 calc R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li 0.0008 0.0003 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Li1 Cl1 Li2 107.15(18) . 2_666
Li1 Cl1 Li3 108.43(18) . 2_666
Li2 Cl1 Li3 82.37(18) 2_666 2_666
Li1 Cl2 Li3 105.40(18) . .
Li1 Cl2 Li2 108.72(18) . .
Li3 Cl2 Li2 81.93(18) . .
Li2 Cl3 Li3 102.42(18) 2_666 .
N3 Li1 N1 91.5(2) . .
N3 Li1 Cl1 106.2(2) . .
N1 Li1 Cl1 107.6(2) . .
N3 Li1 Cl2 112.5(2) . .
N1 Li1 Cl2 113.5(2) . .
Cl1 Li1 Cl2 121.3(2) . .
O2 Li2 Cl3 107.6(2) . 2_666
O2 Li2 Cl1 103.0(2) . 2_666
Cl3 Li2 Cl1 118.1(2) 2_666 2_666
O2 Li2 Cl2 112.8(3) . .
Cl3 Li2 Cl2 117.3(2) 2_666 .
Cl1 Li2 Cl2 97.11(19) 2_666 .
O2 Li2 Li3 124.2(3) . .
Cl3 Li2 Li3 127.9(2) 2_666 .
Cl1 Li2 Li3 48.87(14) 2_666 .
Cl2 Li2 Li3 48.92(14) . .
O1 Li3 Cl3 107.5(2) . .
O1 Li3 Cl1 103.3(2) . 2_666
Cl3 Li3 Cl1 118.3(2) . 2_666
O1 Li3 Cl2 110.4(2) . .
Cl3 Li3 Cl2 118.9(2) . .
Cl1 Li3 Cl2 97.22(19) 2_666 .
O1 Li3 Li2 122.6(3) . .
Cl3 Li3 Li2 129.7(2) . .
Cl1 Li3 Li2 48.76(14) 2_666 .
Cl2 Li3 Li2 49.15(14) . .
C1 O1 C4 106.9(3) . .
C1 O1 Li3 123.8(3) . .
C4 O1 Li3 123.9(3) . .
C8 O2 C5 105.3(3) . .
C8 O2 Li2 123.9(3) . .
C5 O2 Li2 124.3(3) . .
N2 P1 C11 104.55(13) . .
N2 P1 C31 104.24(14) . .
C11 P1 C31 100.13(13) . .
C15 N1 C11 118.0(2) . .
C15 N1 Li1 119.4(2) . .
C11 N1 Li1 122.6(2) . .
C22 N2 C21 113.5(3) . .
C22 N2 P1 119.7(2) . .
C21 N2 P1 126.8(2) . .
C35 N3 C31 118.0(3) . .
C35 N3 Li1 119.4(2) . .
C31 N3 Li1 122.5(2) . .
O1 C1 C2 108.1(3) . .
O1 C1 H1A 110.1 . .
C2 C1 H1A 110.1 . .
O1 C1 H1B 110.1 . .
C2 C1 H1B 110.1 . .
H1A C1 H1B 108.4 . .
C1 C2 C3 106.0(4) . .
C1 C2 H2A 110.5 . .
C3 C2 H2A 110.5 . .
C1 C2 H2B 110.5 . .
C3 C2 H2B 110.5 . .
H2A C2 H2B 108.7 . .
C4 C3 C2 101.6(3) . .
C4 C3 H3A 111.4 . .
C2 C3 H3A 111.4 . .
C4 C3 H3B 111.4 . .
C2 C3 H3B 111.4 . .
H3A C3 H3B 109.3 . .
O1 C4 C3 105.1(3) . .
O1 C4 H4A 110.7 . .
C3 C4 H4A 110.7 . .
O1 C4 H4B 110.7 . .
C3 C4 H4B 110.7 . .
H4A C4 H4B 108.8 . .
C6 C5 O2 105.9(5) . .
C6 C5 H5A 110.6 . .
O2 C5 H5A 110.6 . .
C6 C5 H5B 110.6 . .
O2 C5 H5B 110.6 . .
H5A C5 H5B 108.7 . .
C7 C6 C5 107.2(6) . .
C7 C6 H6A 110.3 . .
C5 C6 H6A 110.3 . .
C7 C6 H6B 110.3 . .
C5 C6 H6B 110.3 . .
H6A C6 H6B 108.5 . .
C6 C7 C8 106.9(5) . .
C6 C7 H7A 110.3 . .
C8 C7 H7A 110.3 . .
C6 C7 H7B 110.3 . .
C8 C7 H7B 110.3 . .
H7A C7 H7B 108.6 . .
O2 C8 C7 107.3(5) . .
O2 C8 H8A 110.3 . .
C7 C8 H8A 110.3 . .
O2 C8 H8B 110.3 . .
C7 C8 H8B 110.3 . .
H8A C8 H8B 108.5 . .
N1 C11 C12 121.7(3) . .
N1 C11 P1 115.5(2) . .
C12 C11 P1 122.4(2) . .
C13 C12 C11 119.2(3) . .
C13 C12 H12 120.4 . .
C11 C12 H12 120.4 . .
C14 C13 C12 119.0(3) . .
C14 C13 H13 120.5 . .
C12 C13 H13 120.5 . .
C13 C14 C15 118.8(3) . .
C13 C14 H14 120.6 . .
C15 C14 H14 120.6 . .
N1 C15 C14 123.2(3) . .
N1 C15 H15 118.4 . .
C14 C15 H15 118.4 . .
N2 C21 H21A 109.5 . .
N2 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
N2 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
N2 C22 H22A 109.5 . .
N2 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
N2 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
N3 C31 C32 121.8(3) . .
N3 C31 P1 115.5(2) . .
C32 C31 P1 122.3(2) . .
C33 C32 C31 118.8(3) . .
C33 C32 H32 120.6 . .
C31 C32 H32 120.6 . .
C34 C33 C32 119.6(3) . .
C34 C33 H33 120.2 . .
C32 C33 H33 120.2 . .
C33 C34 C35 118.3(3) . .
C33 C34 H34 120.8 . .
C35 C34 H34 120.8 . .
N3 C35 C34 123.4(3) . .
N3 C35 H35 118.3 . .
C34 C35 H35 118.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cl1 Li1 2.296(5) .
Cl1 Li2 2.368(6) 2_666
Cl1 Li3 2.373(5) 2_666
Cl2 Li1 2.344(5) .
Cl2 Li3 2.377(5) .
Cl2 Li2 2.385(5) .
Cl3 Li2 2.353(5) 2_666
Cl3 Li3 2.367(5) .
Li1 N3 2.040(5) .
Li1 N1 2.045(5) .
Li2 O2 1.974(6) .
Li2 Cl3 2.353(5) 2_666
Li2 Cl1 2.368(6) 2_666
Li2 Li3 3.122(7) .
Li3 O1 1.965(6) .
Li3 Cl1 2.372(5) 2_666
O1 C1 1.403(4) .
O1 C4 1.440(4) .
O2 C8 1.383(5) .
O2 C5 1.439(6) .
P1 N2 1.665(3) .
P1 C11 1.847(3) .
P1 C31 1.850(3) .
N1 C15 1.339(4) .
N1 C11 1.347(4) .
N2 C22 1.437(5) .
N2 C21 1.466(4) .
N3 C35 1.340(4) .
N3 C31 1.348(4) .
C1 C2 1.467(6) .
C1 H1A 0.9900 .
C1 H1B 0.9900 .
C2 C3 1.503(7) .
C2 H2A 0.9900 .
C2 H2B 0.9900 .
C3 C4 1.483(5) .
C3 H3A 0.9900 .
C3 H3B 0.9900 .
C4 H4A 0.9900 .
C4 H4B 0.9900 .
C5 C6 1.413(9) .
C5 H5A 0.9900 .
C5 H5B 0.9900 .
C6 C7 1.381(10) .
C6 H6A 0.9900 .
C6 H6B 0.9900 .
C7 C8 1.461(8) .
C7 H7A 0.9900 .
C7 H7B 0.9900 .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C11 C12 1.394(4) .
C12 C13 1.384(4) .
C12 H12 0.9500 .
C13 C14 1.373(5) .
C13 H13 0.9500 .
C14 C15 1.383(4) .
C14 H14 0.9500 .
C15 H15 0.9500 .
C21 H21A 0.9800 .
C21 H21B 0.9800 .
C21 H21C 0.9800 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C31 C32 1.392(4) .
C32 C33 1.385(5) .
C32 H32 0.9500 .
C33 C34 1.374(5) .
C33 H33 0.9500 .
C34 C35 1.380(4) .
C34 H34 0.9500 .
C35 H35 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C11 P1 N2 C22 -126.8(3)
C31 P1 N2 C22 128.6(3)
C11 P1 N2 C21 52.1(3)
C31 P1 N2 C21 -52.6(3)
C4 O1 C1 C2 17.3(6)
Li3 O1 C1 C2 -137.5(5)
O1 C1 C2 C3 4.8(7)
C1 C2 C3 C4 -23.9(6)
C1 O1 C4 C3 -33.1(5)
Li3 O1 C4 C3 121.7(3)
C2 C3 C4 O1 34.5(5)
C8 O2 C5 C6 27.8(8)
Li2 O2 C5 C6 -124.7(6)
O2 C5 C6 C7 -24.9(10)
C5 C6 C7 C8 12.5(11)
C5 O2 C8 C7 -20.0(7)
Li2 O2 C8 C7 132.6(5)
C6 C7 C8 O2 5.0(10)
C15 N1 C11 C12 -3.1(4)
Li1 N1 C11 C12 176.7(3)
C15 N1 C11 P1 -176.1(2)
Li1 N1 C11 P1 3.7(3)
N2 P1 C11 N1 -166.7(2)
C31 P1 C11 N1 -59.0(2)
N2 P1 C11 C12 20.3(3)
C31 P1 C11 C12 128.0(2)
N1 C11 C12 C13 2.8(4)
P1 C11 C12 C13 175.3(2)
C11 C12 C13 C14 -0.6(4)
C12 C13 C14 C15 -1.1(5)
C11 N1 C15 C14 1.3(4)
Li1 N1 C15 C14 -178.5(3)
C13 C14 C15 N1 0.8(5)
C35 N3 C31 C32 2.9(4)
Li1 N3 C31 C32 -177.3(3)
C35 N3 C31 P1 175.5(2)
Li1 N3 C31 P1 -4.6(3)
N2 P1 C31 N3 167.6(2)
C11 P1 C31 N3 59.6(2)
N2 P1 C31 C32 -19.8(3)
C11 P1 C31 C32 -127.8(2)
N3 C31 C32 C33 -2.7(4)
P1 C31 C32 C33 -174.8(2)
C31 C32 C33 C34 0.6(4)
C32 C33 C34 C35 1.0(5)
C31 N3 C35 C34 -1.1(4)
Li1 N3 C35 C34 179.0(3)
C33 C34 C35 N3 -0.8(5)
