#------------------------------------------------------------------------------
#$Date: 2017-03-05 07:22:10 +0200 (Sun, 05 Mar 2017) $
#$Revision: 193853 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/19/7041926.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7041926
loop_
_publ_author_name
'Tatikonda, Rajendhraprasad'
'Bertula, Kia'
'Nonappa, ?'
'Hietala, Sami'
'Rissanen, Kari'
'Haukka, Matti'
_publ_section_title
;
 Bipyridine based metallogels: an unprecedented difference in
 photochemical and chemical reduction in the in situ nanoparticle
 formation.
;
_journal_issue                   9
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2793
_journal_page_last               2802
_journal_paper_doi               10.1039/c6dt04253h
_journal_volume                  46
_journal_year                    2017
_chemical_formula_moiety         '2(C11 H9 N2 O)'
_chemical_formula_sum            'C22 H18 N4 O2'
_chemical_formula_weight         370.40
_chemical_name_systematic
;
 ? 
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   difmap
_audit_creation_date             2016-03-31
_audit_creation_method
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_audit_update_record
;
2016-08-23 deposited with the CCDC.
2017-02-02 downloaded from the CCDC.
;
_cell_angle_alpha                114.646(6)
_cell_angle_beta                 103.516(5)
_cell_angle_gamma                93.852(5)
_cell_formula_units_Z            2
_cell_length_a                   6.2801(4)
_cell_length_b                   12.0904(8)
_cell_length_c                   13.3168(8)
_cell_measurement_reflns_used    5160
_cell_measurement_temperature    120
_cell_measurement_theta_max      28.7750
_cell_measurement_theta_min      3.8970
_cell_volume                     877.92(11)
_computing_cell_refinement       'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution
;
Superflip (Palatinus & Chapuis, 2007;Palatinus & van der Lee, 2008;
Palatinus et al., 2012)
;
_diffrn_ambient_environment      air
_diffrn_ambient_temperature      120
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 8.0053
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -47.00  47.00   1.00   30.00    --  -18.14  77.00-120.00   94
  2  ω    -37.00  54.00   1.00   30.00    --  -18.14  37.00  30.00   91
  3  ω    -83.00  -9.00   1.00   30.00    --  -18.14 137.00  27.90   74
  4  ω     -2.00  88.00   1.00   30.00    --   19.23  57.00 -90.00   90
  5  ω    -50.00  41.00   1.00   30.00    --   19.23 -57.00 120.00   91
  6  ω     10.00  61.00   1.00   30.00    --   19.23 -99.00 -60.00   51
  7  ω     -2.00  88.00   1.00   30.00    --   19.23  57.00  30.00   90
  8  ω    -10.00  87.00   1.00   30.00    --   19.23  77.00 120.00   97
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Single source at offset, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0078966000
_diffrn_orient_matrix_UB_12      -0.0627688000
_diffrn_orient_matrix_UB_13      -0.0101131000
_diffrn_orient_matrix_UB_21      -0.0843059000
_diffrn_orient_matrix_UB_22      0.0065729000
_diffrn_orient_matrix_UB_23      0.0283404000
_diffrn_orient_matrix_UB_31      -0.0825145000
_diffrn_orient_matrix_UB_32      -0.0182458000
_diffrn_orient_matrix_UB_33      -0.0532993000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0231
_diffrn_reflns_av_unetI/netI     0.0247
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            11863
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         27.00
_diffrn_reflns_theta_min         3.10
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    0.093
_exptl_absorpt_correction_T_max  0.997
_exptl_absorpt_correction_T_min  0.995
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
Numerical absorption correction based on gaussian integration over
            a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.401
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             388
_exptl_crystal_size_max          0.215
_exptl_crystal_size_mid          0.124
_exptl_crystal_size_min          0.093
_refine_diff_density_max         0.353
_refine_diff_density_min         -0.221
_refine_diff_density_rms         0.044
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     253
_refine_ls_number_reflns         3787
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.048
_refine_ls_R_factor_all          0.0487
_refine_ls_R_factor_gt           0.0398
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0363P)²+0.4698P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0934
_refine_ls_wR_factor_ref         0.0985
_reflns_number_gt                3201
_reflns_number_total             3787
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6dt04253h2.cif
_cod_data_source_block           3
_cod_depositor_comments
'Adding full bibliography for 7041926--7041928.cif.'
_cod_original_cell_volume        877.92(10)
_cod_database_code               7041926
_chemical_oxdiff_formula         'C11 H18 N4 O2 '
_chemical_oxdiff_usercomment     'Clear, Colorless, Block'
_reflns_odcompleteness_completeness 99.89
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C6(H6A,H6B), C17(H17A,H17B)
2.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C13(H13), C22(H22), C15(H15), C4(H4), C20(H20), C8(H8), C5(H5),
 C9(H9), C21(H21), C11(H11), C19(H19), C16(H16), C10(H10)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.148
_oxdiff_exptl_absorpt_empirical_full_min 0.921
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags_posn
O2 O 0.40646(16) 0.12502(9) 0.39024(8) 0.0204(2) Uani 1 d .
O1 O 0.65147(16) 0.53562(9) 0.21655(9) 0.0237(2) Uani 1 d .
N3 N 0.99151(19) 0.13913(11) 0.62288(10) 0.0190(3) Uani 1 d .
N1 N 0.1585(2) 0.64602(11) 0.02925(10) 0.0200(3) Uani 1 d .
N2 N 1.2238(2) 0.45156(11) 0.36313(11) 0.0227(3) Uani 1 d .
N4 N -0.2573(2) 0.00339(12) 0.12256(11) 0.0251(3) Uani 1 d .
C1 C 0.1151(2) 0.53718(12) 0.03235(11) 0.0171(3) Uani 1 d .
C12 C 0.9257(2) 0.04658(12) 0.51513(11) 0.0159(3) Uani 1 d .
C14 C 0.5978(2) 0.12379(13) 0.46298(12) 0.0169(3) Uani 1 d .
C7 C 0.8221(2) 0.40731(12) 0.29414(11) 0.0174(3) Uani 1 d .
C18 C 0.1413(2) 0.05057(12) 0.20575(11) 0.0170(3) Uani 1 d .
C2 C 0.2719(2) 0.49271(12) 0.09236(11) 0.0177(3) Uani 1 d .
H2 H 0.2352 0.4147 0.0914 0.021 Uiso 1 calc R
C13 C 0.7303(2) 0.03454(12) 0.43267(12) 0.0165(3) Uani 1 d .
H13 H 0.6887 -0.0330 0.3576 0.020 Uiso 1 calc R
C22 C 0.1595(2) 0.13564(13) 0.16177(12) 0.0196(3) Uani 1 d .
H22 H 0.3015 0.1801 0.1744 0.024 Uiso 1 calc R
C6 C 0.6124(2) 0.41865(13) 0.21967(12) 0.0192(3) Uani 1 d .
H6A H 0.5740 0.3499 0.1407 0.023 Uiso 1 calc R
H6B H 0.4869 0.4148 0.2521 0.023 Uiso 1 calc R
C17 C 0.3427(2) 0.02598(13) 0.27385(12) 0.0186(3) Uani 1 d .
H17A H 0.3076 -0.0547 0.2745 0.022 Uiso 1 calc R
H17B H 0.4662 0.0235 0.2389 0.022 Uiso 1 calc R
C15 C 0.6617(2) 0.22007(13) 0.57487(12) 0.0197(3) Uani 1 d .
H15 H 0.5736 0.2817 0.5987 0.024 Uiso 1 calc R
C4 C 0.5299(2) 0.67923(13) 0.15192(12) 0.0209(3) Uani 1 d .
H4 H 0.6719 0.7315 0.1933 0.025 Uiso 1 calc R
C20 C -0.2344(2) 0.08691(13) 0.08226(12) 0.0219(3) Uani 1 d .
H20 H -0.3652 0.1003 0.0394 0.026 Uiso 1 calc R
C8 C 1.0306(2) 0.45863(13) 0.29887(12) 0.0196(3) Uani 1 d .
H8 H 1.0371 0.5016 0.2537 0.024 Uiso 1 calc R
C5 C 0.3645(2) 0.71346(13) 0.08853(12) 0.0208(3) Uani 1 d .
H5 H 0.3986 0.7902 0.0867 0.025 Uiso 1 calc R
C9 C 1.2111(2) 0.38880(13) 0.42440(13) 0.0223(3) Uani 1 d .
H9 H 1.3460 0.3826 0.4704 0.027 Uiso 1 calc R
C21 C -0.0314(2) 0.15477(13) 0.09937(12) 0.0204(3) Uani 1 d .
H21 H -0.0235 0.2130 0.0690 0.024 Uiso 1 calc R
C11 C 0.8138(2) 0.34283(13) 0.35908(12) 0.0208(3) Uani 1 d .
H11 H 0.6746 0.3065 0.3587 0.025 Uiso 1 calc R
C19 C -0.0695(2) -0.01283(14) 0.18334(12) 0.0219(3) Uani 1 d .
H19 H -0.0820 -0.0715 0.2128 0.026 Uiso 1 calc R
C3 C 0.4828(2) 0.56559(13) 0.15347(12) 0.0183(3) Uani 1 d .
C16 C 0.8577(2) 0.22256(13) 0.64979(12) 0.0206(3) Uani 1 d .
H16 H 0.9011 0.2881 0.7260 0.025 Uiso 1 calc R
C10 C 1.0117(2) 0.33232(13) 0.42440(12) 0.0224(3) Uani 1 d .
H10 H 1.0104 0.2873 0.4682 0.027 Uiso 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
-7 2 13 0.0547
9 -3 0 0.0813
0 -1 17 0.0551
-9 3 6 0.0850
1 1 -17 0.0659
5 -1 -16 0.0631
-1 -17 7 0.0476
1 17 -7 0.0459
-3 -13 0 0.0638
-2 14 -14 0.0884
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
C14 O2 C17 116.17(10) .
C3 O1 C6 118.12(11) .
C12 N3 C16 116.57(11) .
C5 N1 C1 116.50(12) .
C9 N2 C8 116.90(13) .
C20 N4 C19 116.57(12) .
N1 C1 C1 116.53(15) 2_565
N1 C1 C2 123.47(12) .
C2 C1 C1 120.00(15) 2_565
N3 C12 C12 116.70(14) 2_756
N3 C12 C13 123.45(12) .
C13 C12 C12 119.84(15) 2_756
O2 C14 C13 124.47(12) .
O2 C14 C15 116.41(12) .
C13 C14 C15 119.13(12) .
C8 C7 C6 121.28(12) .
C8 C7 C11 117.59(13) .
C11 C7 C6 121.12(12) .
C22 C18 C17 121.51(12) .
C19 C18 C22 117.89(12) .
C19 C18 C17 120.59(12) .
C1 C2 H2 120.8 .
C3 C2 C1 118.36(13) .
C3 C2 H2 120.8 .
C12 C13 H13 120.8 .
C14 C13 C12 118.40(12) .
C14 C13 H13 120.8 .
C18 C22 H22 120.4 .
C21 C22 C18 119.24(13) .
C21 C22 H22 120.4 .
O1 C6 C7 107.92(11) .
O1 C6 H6A 110.1 .
O1 C6 H6B 110.1 .
C7 C6 H6A 110.1 .
C7 C6 H6B 110.1 .
H6A C6 H6B 108.4 .
O2 C17 C18 107.67(11) .
O2 C17 H17A 110.2 .
O2 C17 H17B 110.2 .
C18 C17 H17A 110.2 .
C18 C17 H17B 110.2 .
H17A C17 H17B 108.5 .
C14 C15 H15 121.2 .
C16 C15 C14 117.62(13) .
C16 C15 H15 121.2 .
C5 C4 H4 120.9 .
C5 C4 C3 118.11(13) .
C3 C4 H4 120.9 .
N4 C20 H20 118.1 .
N4 C20 C21 123.89(13) .
C21 C20 H20 118.1 .
N2 C8 C7 124.26(13) .
N2 C8 H8 117.9 .
C7 C8 H8 117.9 .
N1 C5 C4 124.67(13) .
N1 C5 H5 117.7 .
C4 C5 H5 117.7 .
N2 C9 H9 118.3 .
N2 C9 C10 123.49(13) .
C10 C9 H9 118.3 .
C22 C21 C20 118.29(13) .
C22 C21 H21 120.9 .
C20 C21 H21 120.9 .
C7 C11 H11 120.4 .
C10 C11 C7 119.12(13) .
C10 C11 H11 120.4 .
N4 C19 C18 124.11(13) .
N4 C19 H19 117.9 .
C18 C19 H19 117.9 .
O1 C3 C2 125.18(12) .
O1 C3 C4 115.95(12) .
C2 C3 C4 118.87(12) .
N3 C16 C15 124.82(13) .
N3 C16 H16 117.6 .
C15 C16 H16 117.6 .
C9 C10 C11 118.62(13) .
C9 C10 H10 120.7 .
C11 C10 H10 120.7 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
O2 C14 1.3610(15) .
O2 C17 1.4471(16) .
O1 C6 1.4384(16) .
O1 C3 1.3595(16) .
N3 C12 1.3429(18) .
N3 C16 1.3435(18) .
N1 C1 1.3453(17) .
N1 C5 1.3436(18) .
N2 C8 1.3424(18) .
N2 C9 1.3366(19) .
N4 C20 1.3404(19) .
N4 C19 1.3423(18) .
C1 C1 1.496(3) 2_565
C1 C2 1.3997(19) .
C12 C12 1.497(3) 2_756
C12 C13 1.3947(18) .
C14 C13 1.3908(19) .
C14 C15 1.3955(19) .
C7 C6 1.5047(18) .
C7 C8 1.3866(19) .
C7 C11 1.3915(19) .
C18 C22 1.3900(19) .
C18 C17 1.5001(18) .
C18 C19 1.3845(19) .
C2 H2 0.9500 .
C2 C3 1.3909(19) .
C13 H13 0.9500 .
C22 H22 0.9500 .
C22 C21 1.3834(19) .
C6 H6A 0.9900 .
C6 H6B 0.9900 .
C17 H17A 0.9900 .
C17 H17B 0.9900 .
C15 H15 0.9500 .
C15 C16 1.3812(19) .
C4 H4 0.9500 .
C4 C5 1.379(2) .
C4 C3 1.3955(19) .
C20 H20 0.9500 .
C20 C21 1.385(2) .
C8 H8 0.9500 .
C5 H5 0.9500 .
C9 H9 0.9500 .
C9 C10 1.386(2) .
C21 H21 0.9500 .
C11 H11 0.9500 .
C11 C10 1.387(2) .
C19 H19 0.9500 .
C16 H16 0.9500 .
C10 H10 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O2 C14 C13 C12 178.24(12) . .
O2 C14 C15 C16 -178.67(12) . .
N3 C12 C13 C14 0.8(2) . .
N1 C1 C2 C3 1.0(2) . .
N2 C9 C10 C11 -1.1(2) . .
N4 C20 C21 C22 -0.1(2) . .
C1 N1 C5 C4 -0.6(2) . .
C1 C1 C2 C3 -178.69(15) 2_565 .
C1 C2 C3 O1 179.35(13) . .
C1 C2 C3 C4 -0.4(2) . .
C12 N3 C16 C15 -0.7(2) . .
C12 C12 C13 C14 -178.95(15) 2_756 .
C14 O2 C17 C18 -175.03(11) . .
C14 C15 C16 N3 0.0(2) . .
C7 C11 C10 C9 1.3(2) . .
C18 C22 C21 C20 -0.6(2) . .
C13 C14 C15 C16 1.1(2) . .
C22 C18 C17 O2 79.68(16) . .
C22 C18 C19 N4 -0.5(2) . .
C6 O1 C3 C2 1.1(2) . .
C6 O1 C3 C4 -179.17(12) . .
C6 C7 C8 N2 -179.79(13) . .
C6 C7 C11 C10 178.51(13) . .
C17 O2 C14 C13 -0.58(19) . .
C17 O2 C14 C15 179.12(12) . .
C17 C18 C22 C21 179.90(12) . .
C17 C18 C19 N4 -179.57(13) . .
C15 C14 C13 C12 -1.45(19) . .
C20 N4 C19 C18 -0.1(2) . .
C8 N2 C9 C10 -0.1(2) . .
C8 C7 C6 O1 -32.84(18) . .
C8 C7 C11 C10 -0.3(2) . .
C5 N1 C1 C1 179.22(14) . 2_565
C5 N1 C1 C2 -0.5(2) . .
C5 C4 C3 O1 179.63(13) . .
C5 C4 C3 C2 -0.6(2) . .
C9 N2 C8 C7 1.2(2) . .
C11 C7 C6 O1 148.41(13) . .
C11 C7 C8 N2 -1.0(2) . .
C19 N4 C20 C21 0.4(2) . .
C19 C18 C22 C21 0.9(2) . .
C19 C18 C17 O2 -101.30(15) . .
C3 O1 C6 C7 179.88(12) . .
C3 C4 C5 N1 1.2(2) . .
C16 N3 C12 C12 -179.98(14) . 2_756
C16 N3 C12 C13 0.2(2) . .
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
-7.0000 2.0000 13.0000 -0.2017 0.9717 -0.1518
9.0000 -3.0000 -0.0000 0.1172 -0.7785 -0.6879
-0.0000 -1.0000 17.0000 -0.1092 0.4752 -0.8878
-9.0000 3.0000 6.0000 -0.1779 0.9485 0.3681
1.0000 1.0000 -17.0000 0.1013 -0.5595 0.8053
5.0000 -1.0000 -16.0000 0.1851 -0.8815 0.4585
-1.0000 -17.0000 7.0000 1.0042 0.1709 0.0196
1.0000 17.0000 -7.0000 -1.0042 -0.1709 -0.0196
-3.0000 -13.0000 -0.0000 0.8397 0.1675 0.4847
-2.0000 14.0000 -14.0000 -0.7214 -0.1361 0.6558
